Updated on 2025/03/28

写真a

 
NAGAOKA Katsutoshi
 
Organization
Graduate School of Engineering Chemical Systems Engineering 1 Professor
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Materials Science and Engineering
Title
Professor
Contact information
メールアドレス
External link

Degree 1

  1. 博士(工学) ( 2001.3   東京工業大学 ) 

Research Interests 10

  1. 水電解

  2. マイクロ波

  3. アンモニア合成分解

  4. CO2変換

  5. 水素貯蔵・製造

  6. 再生可能エネルギー

  7. 触媒

  8. 希土類元素

  9. アンモニア

  10. エネルギーキャリア

Research Areas 5

  1. Nanotechnology/Materials / Nanometer-scale chemistry

  2. Nanotechnology/Materials / Green sustainable chemistry and environmental chemistry

  3. Nanotechnology/Materials / Nanomaterials

  4. Nanotechnology/Materials / Nanomaterials

  5. Nanotechnology/Materials / Energy chemistry

Current Research Project and SDGs 6

  1. 温和な条件でアンモニアを合成する触媒の開発

  2. アンモニア酸化分解による水素製造の無加熱・瞬時起動プロセスの開発

  3. H2/COから炭化水素燃料を合成するための触媒開発

  4. 水の電気分解による水素製造に用いる電極触媒の開発

  5. CO2のメタン化触媒の開発

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Research History 12

  1. Nagoya University   Professor

    2019.4

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    Country:Japan

  2. Oita University   Associate professor

    2017.4 - 2019.3

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    Country:Japan

  3. Oita University   Faculty of Science and Technology   Associate professor

    2017.4

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  4. Oita University   Associate professor

    2017.1 - 2017.3

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    Country:Japan

  5. Oita University   Associate professor

    2007.4 - 2016.12

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    Country:Japan

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Education 3

  1. Tokyo Institute of Technology

    1992.4 - 1996.3

  2. Tokyo Institute of Technology

    1996.4 - 1998.3

  3. Tokyo Institute of Technology   Graduate School, Division of Integrated Science and Engineering

    1998.4 - 2001.3

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    Country: Japan

Professional Memberships 9

  1. 触媒学会

  2. 石油学会

  3. 水素エネルギー協会

  4. 日本化学会

  5. 化学工学会

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Committee Memberships 10

  1. 触媒学会   第134回触媒討論会実行委員長  

    2024.9   

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    Committee type:Academic society

  2. 触媒学会   代議員  

    2023.4   

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    Committee type:Academic society

  3. 触媒学会 西日本支部    庶務幹事  

    2023.3   

  4. 石油学会 東海支部   幹事  

    2022.4   

  5. 化学交流財団 カーボンニュートラル関連技術研究会    座長  

    2022.4 - 2024.3   

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Awards 3

  1. MMS賞

    2016.3   田中貴金属記念財団  

    永岡 勝俊

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    Award type:Award from Japanese society, conference, symposium, etc. 

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  2. 触媒学会奨励賞

    2011   触媒学会   炭化水素の改質反応用新規触媒の開発

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  3. 石油学会奨励賞

    2010   石油学会   酸素欠陥利用による炭化水素改質反応用触媒の機能向上に関する研究

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

 

Papers 121

  1. Realization of Ideal Ba Promoter State by Simultaneous Incorporation with Co into Carbon‐protective Framework for Ammonia Synthesis Catalyst Reviewed

    K. Kanishka, H. De Silva, Katsutoshi Sato, Takahiro Naito, Takaaki Toriyama, Tomokazu Yamamoto, Ryotaro Aso, Yasukazu Murakami, Pradeep R. Varadwaj, Ryoji Asahi, Koji Inazu, Katsutoshi Nagaoka

    Advanced Energy Materials   Vol. 15 ( 8 )   2024.12

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/aenm.202404030

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  2. Efficient metallic Ni as a bifunctional electrocatalyst for integrating continuous PET plastic upcycling with hydrogen production Reviewed International coauthorship

    Xin Li, Jiyi Sun, Huijing Ma, Xia Long, Tianqi Li, Yuto Shimoyama, Takahiro Naito, Katsutoshi Sato, Hiroshi Yamada, Katsutoshi Nagaoka, Yixin Zhao, Xufang Qian

    Applied Catalysis B: Environment and Energy   Vol. 371   2025.8

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.apcatb.2025.125211

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  3. Atomic behaviors in PdRu solid-solution nanoparticles on CeO2-ZrO2 support for the three-way catalytic reaction Reviewed Open Access

    Okkyun Seo, Akhil Tayal, Jaemyung Kim, Kohei Kusada, Tomokazu Yamamoto, Jiayi Tang, Satoshi Hiroi, Chulho Song, Katsutoshi Sato, Katsutoshi Nagaoka, Masaaki Haneda, Kazuo Kato, Syo Matsumura, Hiroshi Kitagawa, Osami Sakata

    Materials Today Catalysis   Vol. 7   page: 100078 - 100078   2024.12

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.mtcata.2024.100078

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  4. Significant low-temperature activity of tetragonal type ZrO2-supported Ru catalysts for CO2 methanation Reviewed

    Katsutoshi Sato, Hitomi Higuchi, Katsutoshi Nagaoka

    Chemistry Letters   Vol. 53 ( 10 )   2024.10

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Oxford University Press (OUP)  

    Abstract

    Conversion of CO2 with H2 to CH4 is a potential route for the utilization of CO2. Because CO2 methanation is an exothermic reaction, the equilibrium yield decreases with increasing temperature. A catalyst that exhibits high activity at low temperatures is thus highly desirable. We report here that a tetragonal-type ZrO2 supported Ru catalyst prepared by low-temperature calcination showed significant low-temperature activity for CO2 methanation. We surmise that an intermediate formate species formed over the tetragonal-type ZrO2 and enhanced the catalytic activity.

    DOI: 10.1093/chemle/upae178

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  5. Rapid start-up of carbon-free H2 production by ammonia oxidative decomposition over Co/Ce0.5Zr0.5O2 with microwave irradiation Reviewed Open Access

    Takahiro Matsunaga, Sachika Hayashi, Hiroshi Yamada, Katsutoshi Sato, Katsutoshi Nagaoka

    iScience   Vol. 27 ( 8 ) page: 110452 - 110452   2024.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.isci.2024.110452

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Books 3

  1. Rare Earth Oxide-Supported Ru Catalysts for Ammonia Synthesis

    Nagaoka K., Sato K.( Role: Joint author)

    CO2 Free Ammonia as an Energy Carrier: Japan's Insights  2022.1  ( ISBN:9789811947674

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    Language:Japanese

    A catalyst that can produce ammonia under mild reaction conditions (below 400 °C and 10 MPa) is needed to achieve green ammonia synthesis using renewable energy. From an industrial point of view, the catalyst should be easily prepared and can be handled in air. Ru shows unparalleled activity compared to Fe, Co, and Ni under mild reaction conditions, and Ru catalysts supported on oxides are suitable for this purpose because of their high stability and ease of handling in air. As a component of oxide supports, rare earth elements with redox properties have attracted attention because of their strong electron-donating ability and high-surface area. In this chapter, recent progress in the study of Ru catalysts supported on rare earth oxides (pure or composite oxide) is summarized with respect to their catalytic performance and physicochemical properties. In particular, the activity of Ru catalysts has been found to be high-under mild reaction conditions, and hydrogen poisoning, a typical drawback of Ru catalysts, is satisfactorily suppressed.

    DOI: 10.1007/978-981-19-4767-4_20

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  2. 触媒の劣化対策、長寿命化 ~劣化の発生メカニズム/触媒のナノ微粒子化/貴金属の低減化、フリー化~

    佐藤勝俊, 永岡勝俊( Role: Contributor)

    技術情報協会  2020.11  ( ISBN:978-4-86104-814-2

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    Language:Japanese Book type:Scholarly book

  3. 水素の製造、輸送・貯蔵技術と 材料開発 事例集

    佐藤勝俊, 永岡勝俊( Role: Contributor)

    技術情報協会  2019.4  ( ISBN: 978-4-86104-745-9

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    Language:Japanese Book type:Scholarly book

MISC 311

  1. NiMo系水電解用水素発生触媒への第三元素添加効果

    李天麒, 内藤剛大, 山田博史, 佐藤勝俊, 永岡勝俊

    触媒討論会予稿集(CD-ROM)   Vol. 133rd   2024

  2. Structural observation of materials for ammonia decomposition using STEM

    佐藤勝俊, 永岡勝俊

    名古屋大学電子光学研究のあゆみ   ( 35 )   2024

  3. 酸素濃度変動条件下における白金-汎用金属複合触媒の排ガス浄化活性

    佐藤勝俊, 森尻康介, 山田博史, 永岡勝俊

    触媒討論会予稿集(CD-ROM)   Vol. 133rd   2024

  4. 担持型アンモニア合成触媒における活性抑制因子の速度論的検討

    惠良康平, 宮原伸一郎, 内藤剛大, DE SILVA K., AKRAMI S., 山田博史, 佐藤勝俊, 秋鹿研一, 稲津晃司, 永岡勝俊, 永岡勝俊

    触媒討論会予稿集(CD-ROM)   Vol. 133rd   2024

  5. Role of C-Coated Co-nanoparticle Hybridization to Control the Product Selectivity in Fischer-Tropsch Synthesis

    KUTUBI Md.Shahajahan, 佐藤勝俊, 志村泰充, 稲垣怜史, 窪田好浩, 永岡勝俊

    触媒討論会予稿集(CD-ROM)   Vol. 132nd   2023

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Presentations 15

  1. FT合成や水素・アンモニア等に関わる 触媒化学 Invited

    永岡 勝俊

    産業技術総合研究所 中部センター講演会  2024.8.2 

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    Event date: 2024.8

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  2. カーボンフリー燃料としてのアンモニアを合成・分解するための触媒開発 Invited

    永岡 勝俊

    第43回無機高分子シンポジウム  2024.7.5 

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    Event date: 2024.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  3. FT合成に用いる選択性制御触媒の研究開発 Invited

    永岡 勝俊

    2024年度 JPECフォーラム  2024.5.14 

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    Event date: 2024.5

    Language:Japanese  

    Venue:東京  

  4. 元素資源循環触媒の研究開発

    永岡 勝俊

    カーボンニュートラル社会の実現に向けて  2023.11 

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    Event date: 2023.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  5. 環境・エネルギー問題の解決を志向した固体触媒の研究開発 Invited

    永岡 勝俊

    「機械×化学:ナノテクの最前線」 講演会  2023.10  関西大学

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    Event date: 2023.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

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Research Project for Joint Research, Competitive Funding, etc. 4

  1. 貴金属フリーアンモニア合成触媒の高活性化に関する研究開発

    2020.4 - 2023.3

    水素社会構築に向けた革新研究助成 

    永岡勝俊

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    Authorship:Principal investigator 

  2. バナジウム合金メンブレンリアクターを用いた高効率アンモニア分解による高純度水素製造技術の開発

    2019.12 - 2020.11

    A-STEP機能検証フェーズ 試験研究タイプ  

    永岡 勝俊

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1010000 ( Direct Cost: \730000 、 Indirect Cost:\280000 )

  3. コークス炉ガス中のアンモニアを水素リソースとして利用するための機 能性触媒開発

    2019.1 - 2020.12

    2019年度 技術研究助成  

    永岡勝俊

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    Authorship:Principal investigator  Grant type:Other

    Grant amount:\2000000 ( Direct Cost: \2000000 )

  4. エネルギーキャリアとしてのアンモニアを合成・分解するための特殊反応場の構築に関する基盤技術の創成

    2013.4 - 2020.3

    CREST 

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    Grant type:Competitive

KAKENHI (Grants-in-Aid for Scientific Research) 8

  1. H2 production from NH3 and O2 over supported transition metal catgalysts triggered by using microwave irradiation

    Grant number:21K18847  2021.7 - 2023.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Challenging Research (Exploratory)

    Nagaoka Katsutoshi

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    Authorship:Principal investigator 

    Grant amount:\6370000 ( Direct Cost: \4900000 、 Indirect Cost:\1470000 )

    Ammonia has attracted a lot of attentions as hydrogen carrier. In this research, the catalytic process which enables rapid H2 production by ammonia oxidative decomposition was investigated. We show that H2 production by the reaction is triggered rapidly over Ce0.5Zr0.5O2 supported transition metal catalysts with microwave irradiation. Especially, the microwave irradiation rapidly heats Co3O4/Ce0.5Zr0.5O2 catalyst to auto-ignition temperature of the reaction within 10 s and the reaction starts afterwards. Once the oxidative decomposition of ammonia is triggered, the reaction proceeds without any external heat input. Furthermore, the ammonia oxidative decomposition is triggered over the catalyst repeatedly for 4 cycles with the microwave irradiation. Oxygen is consumed completely and ammonia conversion more than 90 % is obtained at all cycles.

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  2. Understanding of the formation of active N2 reduction sites by oxide migration during high-temperature reduction

    Grant number:20H02522  2020.4 - 2023.3

    Japan Society for the Promotion of Science  Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)  Grant-in-Aid for Scientific Research (B)

    Nagaoka Katsutoshi

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\18070000 ( Direct Cost: \13900000 、 Indirect Cost:\4170000 )

    The ammonia synthesis rate of Ru/Ba/La0.5Ce0.5O1.75 is one of the highest among oxide-supported Ru catalysts reported so far. It has been found that the active site is a strongly electron-donating Ru site covered by the oxide nano-fractionations of the support and formed during high-temperature reduction.
    In this study, we investigated formation mechanism of the active sites. We have revealed that Ba(CO3)2 is hydrogenated to Ba(OH)2 during the reduction. Then, this compound melts and migrates to the surface of Ru nanoparticles at hier temperature. Furthermore, it is transformed to BaO and solidified at higher temperatures, resulting in a core - shell structure.

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  3. Chemical conversion of shale gas over supported multi-element catalysts

    Grant number:15H04188  2015.4 - 2018.3

    Grant-in-Aid for Scientific Research 

    Katsutoshi Nagaoka

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    Grant amount:\16250000 ( Direct Cost: \12500000 、 Indirect Cost:\3750000 )

    Due to shale-gas revolution, new process using methane as a natural resource instead of oil is highly demanded. In this research, we developed non-noble metal catalysts for dry reforming methane which is able to produce synthetic gas with lower H2/CO ratio than conventional methane steam reforming. At first, influence of Al3+ addition to Co-Mg-O solid solution catalyst was investigated. Addition of small amount of Al3+ increased reduction degree of Co2+ drastically and the catalysts shows high activity and stability for the reaction. However, when Al3+ amount is too large, it formed MgAl2O4, which results in decrease in the number of basic sites retarding coke formation. Furthermore, it was revealed that doping of small amount of SrO to the Co-Al-Mg-O solid solution catalyst is effective for further inhibition of coking. The catalyst exhibits high activity and stability in dry reforming under high pressure and low temperature, where coking is highly favored.

  4. 元素間融合を基軸とする物質開発と応用展開

    2015 - 2019

    JST  ACCEL 

    KITAGAWA Hiroshi

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    Grant type:Competitive

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  5. Development of catalysts for H2 production by ammonia decomposition under mild reaction condition

    Grant number:24760641  2012.4 - 2014.3

    Grant-in-Aid for Scientific Research 

    NAGAOKA Katsutoshi

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    Authorship:Principal investigator 

    Grant amount:\4550000 ( Direct Cost: \3500000 、 Indirect Cost:\1050000 )

    Nowadays NH3 has been regarded as one of the potential H2-storage materials. In this research, novel supported metal catalysts for producing renewable hydrogen by ammonia decomposition under mild reaction condition was developed. For that purpose, basic hydrotalcite-like compound was used as precursor for Mg-Al oxide support. It was revealed that 5 wt%Ru/Cs2O/Mg-Al-oxide converts 51% of NH3 even at 573 K with a space velocity of 3000 h-1. Furthermore, Ru-free Ni catalyst, CeO2/15wt%Ni/ Mg-Al-oxide, was found to exhibit almost complete conversion of NH3 even at 773 K.

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Industrial property rights 31

  1. メタンの脱水素芳香族化反応用触媒及び芳香族化合物の製造方法

    永岡 勝俊, 佐藤 勝俊, 西 信宏, 細木 康弘, 奥村 吉邦, 太田 啓介

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    Applicant:国立大学法人 大分大学

    Application no:特願2019-164379  Date applied:2019.9

    Announcement no:特開2021-041329  Date announced:2021.3

    J-GLOBAL

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  2. アンモニア酸化分解-水素生成触媒、及び水素製造装置

    永岡 勝俊, 佐藤 勝俊

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    Applicant:国立大学法人 大分大学

    Application no:特願2019-140228  Date applied:2019.7

    Announcement no:特開2019-177381  Date announced:2019.10

    Patent/Registration no:特許第6795804号  Date registered:2020.11 

    J-GLOBAL

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  3. 排気ガス浄化装置及び排気ガス浄化方法

    山田 啓司, 佐藤 義志, 松村 益寛, 川端 久也, 重津 雅彦, 永岡 勝俊

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    Applicant:マツダ株式会社

    Application no:特願2019-136944  Date applied:2019.7

    Announcement no:特開2021-021352  Date announced:2021.2

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  4. 複合酸化物、金属担持物及びアンモニア合成触媒

    永岡 勝俊, 小倉 優太, 佐藤 勝俊

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    Applicant:国立研究開発法人科学技術振興機構

    Application no:JP2019018225  Date applied:2019.5

    Publication no:WO2019-216304  Date published:2019.11

    J-GLOBAL

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  5. アンモニア製造用触媒組成物、アンモニア製造用触媒組成物の製造方法及びアンモニア製造方法

    永岡 勝俊, 河野 まなみ, 北川 進, 北川 宏, 樋口 雅一, 山内 美穂, 梶原 隆史, 東村 秀之, 渡部 大輔, 大島 伸司, 三津家 由子, 永島 和郎

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    Applicant:住友化学株式会社, JXエネルギー株式会社, 昭栄化学工業株式会社, 国立大学法人 大分大学, 国立大学法人京都大学, 国立大学法人北海道大学

    Application no:特願2016-192154  Date applied:2016.9

    Announcement no:特開2017-001037  Date announced:2017.1

    Country of applicant:Domestic  

    J-GLOBAL

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Teaching Experience (On-campus) 10

  1. First Year Seminar

    2022

  2. Seminars on Chemical Systems Engineering 2D

    2022

  3. Automobile Chemical Systems I

    2022

  4. Catalytic Chemistry

    2022

  5. Metallic and Ceramic Materials

    2020

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Media Coverage 8

  1. 鳥かごの中に、おはぎ?アンモニアをより簡単に作れる「触媒」とは? Internet

    名古屋大研究フロントライン  ポッドキャスト, X, Instagram,   https://www.nagoya-u.ac.jp/researchinfo/result/2024/12/post-767.html  2025.3

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    Author:Other 

  2. アンモニアを温和な条件で高効率に合成することが可能な新触媒と製造方法を開発 Newspaper, magazine

    読売新聞 宮崎  読売新聞 宮崎  2025.2

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    Author:Myself 

  3. アンモニアを温和な条件で合成する高活性な新触媒を開発 ~炭素フレームにコバルトと助触媒を理想的な状態で内包・安定化~ Internet

    名古屋大学  名古屋大学 研究発信サイト  https://www.nagoya-u.ac.jp/researchinfo/result/2024/12/post-767.html  2024.12

  4. アンモニア、新触媒で省エネ生産 名古屋大・費用15%減 Internet

    日経GX  2024.2

  5. 低温・低圧条件下でのアンモニア合成を目指したMgO担持鉄触媒の開発 Internet

    石油学会  2023.10

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Academic Activities 1

  1. 第134回触媒討論会 International contribution

    Role(s):Planning, management, etc.

    触媒学会  2024.9

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    Type:Competition, symposium, etc.