Updated on 2023/05/23

写真a

 
NAKANO Ryo
 
Organization
Graduate School of Engineering Molecular and Macromolecular Chemistry 1 Assistant Professor
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Chemistry and Biotechnology
Title
Assistant Professor

Degree 1

  1. Doctor of Engineering ( 2016.3   The University of Tokyo ) 

Research Areas 2

  1. Nanotechnology/Materials / Inorganic/coordination chemistry

  2. Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

Current Research Project and SDGs 1

  1. development of coupling reaction of carbon dioxide with alkenes

Research History 4

  1. Nagoya University   Graduate School of Engineering Molecular and Macromolecular Chemistry   Assistant Professor

    2020.5

  2. Nagoya University   Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering   Designated assistant professor

    2018.7 - 2020.4

  3. University of California, San Diego   Department of Chemistry and Biochemistry

    2016.4 - 2018.6

  4. 日本学術振興会   特別研究員(DC2)

    2014.4 - 2016.3

Education 2

  1. The University of Tokyo   Graduate School of Engineering   Department of Chemistry and Biotechnology

    - 2016.3

  2. The University of Tokyo   School of Engineering   Department of Chemistry and Biotechnology

    - 2011.3

Professional Memberships 3

  1. The Society of Physical Organic Chemistry

    2020.11

  2. The Society of Synthetic Organic Chemistry, Japan

    2019.4

  3. THE CHEMICAL SOCIETY OF JAPAN

    2014.1

Awards 6

  1. 2017 Reaxys PhD Prize Finalist

    2017  

    Ryo Nakano

  2. Inoue Research Award for Young Scientists

    2017  

    Ryo Nakano

  3. Dr. Yinan Wang Award for Excellence in Research

    2017   UCSD 3rd Annual Chemistry & Biochemistry Postdoctoral Research Symposium  

    Ryo Nakano

  4. Dean’s Award for Dissertation Thesis

    2016   Graduate School of Engineering, The University of Tokyo  

    Ryo Nakano

  5. CSJ Student Presentation Award 2015

    2015   The Chemical Society of Japan  

    Ryo Nakano

  6. Otsu Conference Fellow

    2014   Otsu Conference  

    Ryo Nakano

▼display all

 

Papers 15

  1. Low-Temperature Dehydrogenation of Cyclooctane by Using Pincer Iridium Complexes Bearing an N,N′-Diarylated PNCNP Ligand Reviewed

    Naoto Uno, Ryo Nakano, Makoto Yamashita

    ACS Catalysis     2023.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.3c01739

  2. Base-Stabilized Neutral Oxoborane and Thioxoborane Supported by a Bis(oxazolinyl)(phenyl)methanide Ligand Reviewed

    Nakano Ryo, Yamanashi Ryotaro, Yamashita Makoto

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 29 ( 9 ) page: e202203280   2022.12

     More details

    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Chemistry - A European Journal  

    Base-stabilized neutral oxoborane and thioxoborane supported by a bis(oxazolinyl)(phenyl)methanide ligand have been synthesized and structurally characterized. While previous synthetic attempts of oxoborane ligated by β-diketiminate (NacNac) did not allow for its isolation in acid-free form, oxoborane supported by a bis(oxazolinyl)(phenyl)methanide ligand is isolable, due to the absence of imine ɑ-protons and steric protection of enamine carbon. Crystallographic analysis revealed the presence of a B−O double bond close to the shortest end of the reported lengths. Its reactivity has also been examined, and it was majorly governed by the nucleophilicity and basicity of the oxygen atom. The chemical inertness and synthetic convenience of the bis(oxazolinyl)(phenyl)methanide scaffold presented in this work suggest its utility as an innocent alternative to the NacNac scaffold.

    DOI: 10.1002/chem.202203280

    Web of Science

    Scopus

    PubMed

  3. Lipophilic N-Hydroxyimide Derivatives: Design, Synthesis, and Application to Aerobic Alkane Oxidation Under Neat Conditions Reviewed

    Kaneiwa Takaya, Yamada Kaito, Nakano Ryo, Yamashita Makoto

    CHEMPLUSCHEM   Vol. 88 ( 4 ) page: e202200380   2022.12

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:ChemPlusChem  

    This work reports the design and synthesis of a series of 5-membered and 6-membered N-hydroxyimides flanked by lipophilic alkyl groups adjacent to carbonyl groups, aiming to endow lipophilicity and tolerance toward ring opening degradation. Their solubility in cyclohexane was 5–20 times higher than those of unsubstituted N-hydroxyphthalimide (NHPI) and even 3–10 times higher than a formerly known lipophilic NHPI analog bearing a long alkyl ester. UV-Vis spectroscopy determined the rate constants of first-order decay of N-oxyls, which revealed enhanced stability of 3,5-di-tert-butyl-NHPI and N-hydroxyglutarimide flanked by spiro-cyclohexanes compared with that of NHPI. Their bond dissociation energies were assessed by EPR spectroscopy and DFT calculation, suggesting these lipophilic N-hydroxyimides catalyzed aerobic cyclohexane oxidation under neat conditions with up to 60 turnovers, which is the highest among hitherto reported reactions under neat conditions.

    DOI: 10.1002/cplu.202200380

    Web of Science

    Scopus

    PubMed

  4. Rhodium-Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine-Based Pincer Ligand: Perturbing Occupied d-Orbitals by p pi-d pi Repulsion Makes a Difference Reviewed

    Takegasa Shinnosuke, Lee Ming Min, Tokuhiro Kei, Nakano Ryo, Yamashita Makoto

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 28 ( 58 ) page: e202201870   2022.10

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Chemistry - A European Journal  

    Rhodium-catalyzed acrylate synthesis from CO2 and ethylene was accomplished by using a guanidine-based NCN pincer ligand. The repulsion between pπ-electron of guanidine sidearms and occupied dπ orbital of rhodium center raised the level of d-electrons close to those of formerly known d8-ruthenium catalyst, thereby promoting the metallalactone formation from carbon dioxide and ethylene. This work fills the absence of group-9 metal based catalyst for the acrylate synthesis and provides a designing approach for pincer-ligated d8-metal catalysts to utilize pπ-dπ interaction for promoting desirable redox processes.

    DOI: 10.1002/chem.202201870

    Web of Science

    Scopus

    PubMed

  5. A meta ‐Selective C−H Alumination of Mono‐Substituted Benzene by Using An Alkyl‐Substituted Al Anion through Hydride‐Eliminating S N Ar Reaction Reviewed

    Satoshi Kurumada, Kengo Sugita, Ryo Nakano, Makoto Yamashita

    Angewandte Chemie International Edition   Vol. 59 ( 46 ) page: 20381 - 20384   2020.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202009138

    Web of Science

    Scopus

    PubMed

  6. Cycloaddition of Dialkylalumanyl Anion toward Unsaturated Hydrocarbons in (1+2) and (1+4) Modes Reviewed

    Kengo Sugita, Ryo Nakano, Makoto Yamashita

    Chemistry – A European Journal   Vol. 26 ( 10 ) page: 2174 - 2177   2020.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/chem.201905830

    Web of Science

    Scopus

    PubMed

  7. Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen Reviewed

    Erik A. Romero, Tianxiang Zhao, Ryo Nakano, Xingbang Hu, Youting Wu, Rodolphe Jazzar, Guy Bertrand

    Nature Catalysis   Vol. 1 ( 10 ) page: 743 - 747   2018.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Springer Nature America, Inc  

    DOI: 10.1038/s41929-018-0140-3

    Web of Science

    Scopus

  8. A crystalline monosubstituted carbene Reviewed

    Ryo Nakano, Rodolphe Jazzar, Guy Bertrand

    Nature Chemistry   Vol. 10 ( 12 ) page: 1196 - 1200   2018.10

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41557-018-0153-1

    Web of Science

    Scopus

    PubMed

  9. Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand Reviewed

    Shumpei Akita, Ryo Nakano, Shingo Ito, Kyoko Nozaki

    Organometallics   Vol. 37 ( 14 ) page: 2286 - 2296   2018.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    © 2018 American Chemical Society. A saturated N-heterocyclic carbene-phenolate bidentate ligand, 3,3a,4,5-tetrahydroimidazo[1,5-a]quinolin-9-olate-1-ylidene (SIzQO), was synthesized and characterized. The SIzQO ligand was then treated with PdClMe(pyridine)2 and [Pd(μ-Cl)Me(2,6-lutidine)]2, which afforded C,C-cis-(SIzQO)PdMe(pyridine) and the thermodynamically unstable trans isomer C,C-trans-(SIzQO)PdMe(2,6-lutidine), respectively. The latter isomerizes at 40 °C into the corresponding cis isomer via a dissociative mechanism. These palladium/SIzQO complexes catalyze the polymerization of ethylene at 100-120 °C, although the catalytic activity is lower than that of a previously reported palladium/imidazo[1,5-a]quinolin-9-olate-1-ylidene (IzQO) system.

    DOI: 10.1021/acs.organomet.8b00263

    Web of Science

    Scopus

  10. Palladium/IzQO-Catalyzed coordination-insertion copolymerization of ethylene and 1,1-disubstituted ethylenes bearing a polar functional group Reviewed

    Hina Yasuda, Ryo Nakano, Shingo Ito, Kyoko Nozaki

    Journal of the American Chemical Society   Vol. 140 ( 5 ) page: 1876 - 1883   2018.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    © 2018 American Chemical Society. Coordination-insertion copolymerization of ethylene with 1,1-disubstituted ethylenes bearing a polar functional group, such as methyl methacrylate (MMA), is a long-standing challenge in catalytic polymerization. The major obstacle for this process is the huge difference in reactivity of ethylene versus 1,1-disubstituted ethylenes toward both coordination and insertion. Herein we report the copolymerization of ethylene and 1,1-disubstituted ethylenes by using an imidazo[1,5-a]quinolin-9-olate-1-ylidene-supported palladium catalyst. Various types of 1,1-disubstituted ethylenes were successfully incorporated into the polyethylene chain. In-depth characterization of the obtained copolymers and mechanistic inferences drawn from stoichiometric reactions of alkylpalladium complexes with methyl methacrylate and ethylene indicate that the copolymerization proceeds by the same coordination-insertion mechanism that has been postulated for ethylene.

    DOI: 10.1021/jacs.7b12593

    Web of Science

    Scopus

    PubMed

  11. Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand Reviewed

    W. Tao, S. Akita, R. Nakano, S. Ito, Y. Hoshimoto, S. Ogoshi, K. Nozaki

    CHEMICAL COMMUNICATIONS   Vol. 53 ( 17 ) page: 2630 - 2633   2017.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    We report the synthesis and characterisation of palladium complexes bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand and their use as catalysts for ethylene polymerisation and ethylene/polar monomer copolymerisation.

    DOI: 10.1039/c7cc00002b

    Web of Science

    PubMed

  12. Elucidating the Key Role of Phosphine-Sulfonate Ligands in Palladium-Catalyzed Ethylene Polymerization: Effect of Ligand Structure on the Molecular Weight and Linearity of Polyethylene Reviewed

    Ryo Nakano, Lung Wa Chung, Yumiko Watanabe, Yoshishige Okuno, Yoshikuni Okumura, Shingo Ito, Keiji Morokuma, Kyoko Nozaki

    ACS CATALYSIS   Vol. 6 ( 9 ) page: 6101 - 6113   2016.9

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    The mechanism of linear polyethylene formation catalyzed by palladium/phosphine sulfonate and the effect of the ligand structure on the catalytic performance, such as linearity and molecular weight of the polyethylene, were reinvestigated theoretically and experimentally. We used dispersion-corrected density functional theory (DFT-D3) to study the entire mechanism of polyethylene formation from (R2PC6H4SO3)PdMe(2,6-lutidine) (R = Me, t-Bu) and elucidated the key steps that determine the molecular weight and linearity of the polyethylene. The alkylpalladium ethylene complex is the key intermediate for both linear propagation and fi-hydride elimination from the growing polymer chain. On the basis of the key species, the effects of substituents on the phosphorus atom (R = t-Bu, i-Pr, Cy, Men, Ph, 2-MeOC6H4, biAr) were further investigated theoretically to explain the experimental results in a comprehensive manner. Thus, the experimental trend of molecular weights of polyethylene could be correlated to the AA G* value between (i) the transition state of linear propagation and (ii) the transition state of the path for ethylene dissociation leading to fi-hydride elimination. Moreover, the experimental behavior of the catalysts under varied ethylene pressure was well explained by our computation on the small set of key species elucidated from the entire mechanism. In our additional experimental investigations, [o-Ani(2)PC(6)H(4)SO(3)]PdH[P(t-Bu)(3)] catalyzed a hydrogen/ deuterium exchange reaction between ethylene and Me0D. The deuterium incorporation from Me0D into the main chain of polyethylene, therefore, can be explained by the incorporation of deuterated ethylene formed by a small amount of Pd H species. These insights into the palladium/phosphine sulfonate system provide a comprehensive understanding of how the phosphine sulfonate ligands function to produce linear polyethylene.

    DOI: 10.1021/acscatal.6b00911

    Web of Science

  13. Copolymerization of Ethylene and Polar Monomers by Using Ni/IzQO Catalysts Reviewed

    Wenjie Tao, Ryo Nakano, Shingo Ito, Kyoko Nozaki

    Angewandte Chemie International Edition   Vol. 55 ( 8 ) page: 2835 - 2839   2016.1

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201510077

  14. Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts Reviewed

    Ryo Nakano, Kyoko Nozaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 137 ( 34 ) page: 10934 - 10937   2015.9

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    Palladium catalysts bearing imidazo[1,5-a]quinolin-9-olate-1-ylidene (IzQO) ligands polymerize alpha-olefins while incorporating polar monomers. The steric environment provided by N-heterocyclic-carbene (NHC) enables regioselective insertion of alpha-olefins and polar monomers, yielding polypropylene, propylene/allyl carboxylate copolymers, and propylene/methyl acrylate copolymer. Known polymerization catalysts bearing NHC-based ligands decompose rapidly, whereas the present catalyst is durable because of structural confinement, wherein the NHC-plane is coplanar to the metal square plane. The present catalyst system enables facile access to a new class of functionalized polyolefins and helps conceive a new fundamental principle for designing NHC-based ligands.

    DOI: 10.1021/jacs.5b06948

    Web of Science

    Scopus

    PubMed

  15. Copolymerization of carbon dioxide and butadiene via a lactone intermediate Reviewed

    Ryo Nakano, Shingo Ito, Kyoko Nozaki

    NATURE CHEMISTRY   Vol. 6 ( 4 ) page: 325 - 331   2014.4

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:NATURE PUBLISHING GROUP  

    Although carbon dioxide has attracted broad interest as a renewable carbon feedstock, its use as a monomer in copolymerization with olefins has long been an elusive endeavour. A major obstacle for this process is that the propagation step involving carbon dioxide is endothermic; typically, attempted reactions between carbon dioxide and an olefin preferentially yield olefin homopolymerization. Here we report a strategy to circumvent the thermodynamic and kinetic barriers for copolymerizations of carbon dioxide and olefins by using a metastable lactone intermediate, 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one, which is formed by the palladium-catalysed condensation of carbon dioxide and 1,3-butadiene. Subsequent free-radical polymerization of the lactone intermediate afforded polymers of high molecular weight with a carbon dioxide content of 33 mol% (29 wt%). Furthermore, the protocol was applied successfully to a one-pot copolymerization of carbon dioxide and 1,3-butadiene, and one-pot terpolymerizations of carbon dioxide, butadiene and another 1,3-diene. This copolymerization technique provides access to a new class of polymeric materials made from carbon dioxide.

    DOI: 10.1038/NCHEM.1882

    Web of Science

    PubMed

    Other Link: http://orcid.org/0000-0002-3705-0381

▼display all

MISC 1

  1. Carbon Dioxide-Based Polymers Reviewed

    Ryo Nakano, Kyoko Nozaki

    Encyclopedia of Polymeric Nanomaterials     page: 299   2015

     More details

    Language:English   Publisher:Springer Science $\mathplus$ Business Media  

    DOI: 10.1007/978-3-642-29648-2_330

Presentations 29

  1. Attempt on Mechanochemical Synthesis of Boryl Anions

    熊田春輝・中野遼・山下誠

    学際統合物質科学研究機構(IRCCS) 成果報告会・産学ワークショップ  2023.2.27  学際統合物質科学研究機構(IRCCS)

     More details

    Event date: 2023.2

    Language:Japanese   Presentation type:Poster presentation  

    Venue:京都大学宇治キャンパスきはだホール  

  2. Low-Temperature Dehydrogenation of Cyclooctane by using Pincer Iridium Complexes Bearing an N,N'-diarylated PNCNP Ligand

    宇野直人・中野遼・山下誠

    学際統合物質科学研究機構(IRCCS) 成果報告会・産学ワークショップ  2023.2.27  学際統合物質科学研究機構(IRCCS)

     More details

    Event date: 2023.2

    Language:Japanese   Presentation type:Poster presentation  

    Venue:京都大学宇治キャンパスきはだホール  

  3. グアニジン配位部位を有するピンサーRh錯体を用いた二酸化炭素とエチレンからのアクリル酸合成とその反応機構解析

    中野遼・武笠真之介・Lee MingMin・徳弘圭・山下誠

    第53回中部化学関係学協会支部連合秋季大会  2022.11.6  中部化学関係学協会支部連合協議会

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  4. N-アリールリンカーを有するPCPピンサーIr錯体の合成と触媒応用

    宇野直人・中野遼・山下誠

    錯体化学会第72回討論会  2022.9.26  錯体化学会

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:九州大学伊都キャンパス・福岡国際会議場  

  5. アダマンタン中心を有するイリジウムピンサー錯体の合成とアルカンの脱水素移動触媒としての応用

    依田崇義・中野遼・山下誠

    日本化学会 第102春季年会(2022)  2022.3.23  日本化学会

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  6. A Monomeric Gallylene Supported by A Bis(oxazolinyl)methanide Ligand

    Tao Ding, Ryo Nakano, Makoto Yamashita

    2022.3.23 

     More details

    Event date: 2022.3

    Language:English   Presentation type:Oral presentation (general)  

  7. Base-stabilized neutral neutral B=X (X = O, NH) species supported by a bis(oxazolinyl)methanide ligand

    Ryotaro Yamanashi, Ryo Nakano, Makoto Yamashita

    2022.1.7 

     More details

    Event date: 2022.1

    Language:Japanese   Presentation type:Poster presentation  

  8. ビスオキサゾリニルメタニド配位子を用いた中性オキソボランの合成

    山梨遼太朗・中野遼・山下誠

    第48回 有機典型元素化学討論会  2021.12.2  日本化学会・日本薬学会

     More details

    Event date: 2021.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  9. ピンサーRu 触媒によるメタンを炭素源としたアルケンの一炭素増炭反応

    徳弘圭・中野遼・山下誠

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.31  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  10. グアニジン配位部位を有するピンサーRh 錯体を用いた二酸化炭素とエチレ ンからのアクリル酸合成

    武笠真之介・Lee Ming Min・中野遼・山下誠

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.30  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  11. ビスオキサゾリニルメタニド配位子を用いた中性オキソボランの合成

    山梨遼太朗・中野遼・山下誠

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.31  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  12. Acrylate Formation from CO2 and Ethylene by using Rhodium Complexes bearing a Guanidine-based Pincer Ligand

    Shinnosuke Takegasa, Ryo Nakano, Makoto Yamashita

    2021.9.7 

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  13. ピンサーRu触媒によるメタンとエチレンの脱水素型クロスカップリング

    中野遼・徳弘圭・山下誠

    第67回有機金属化学討論会  2021.9.10  近畿化学協会有機金属部会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  14. グアニジン配位部位を有するピンサーRh/Ru錯体の合成とその反応性

    武笠 真之介・中野 遼・山下 誠

    日本化学会 第101春季年会(2021)  2021.3.21  日本化学会

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  15. ピンサーRu触媒によるメタンを炭素源としたアルケンの⼀炭素増炭反応

    徳弘 圭・中野 遼・山下 誠

    日本化学会 第101春季年会(2021)  2021.3.20  日本化学会

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  16. 塩基安定化中性オキソボラン

    山梨 遼太朗・中野 遼・山下 誠

    日本化学会 第101春季年会(2021)  2021.3.19  日本化学会

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  17. 炭素置換Alアニオンの反応性

    車田怜史・杉田健吾・中野遼・山下誠

    日本化学会 第101春季年会(2021)  2021.3.19  日本化学会

     More details

    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  18. A meta-selective C-H Alumination of Mono-substituted Benzene by Using An Alkyl-substituted Al Anion International conference

    Satoshi Kurumada, Kengo Sugita, Ryo, Nakano, Makoto Yamashita

    2021#RSCPoster Twitter Conference  2021.3.2 

     More details

    Event date: 2021.3

    Language:English   Presentation type:Poster presentation  

  19. 炭素置換Alアニオンの反応性

    車田怜史・杉田健吾・中野遼・山下誠

    第47回有機典型元素化学討論会  2020.12.3  有機典型元素化学討論会実行委員会

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  20. ジホスホリルカルベン-遷移金属錯体の合成検討

    谷口わか乃・中野遼・山下誠

    第47回有機典型元素化学討論会  2020.12.3  有機典型元素化学討論会実行委員会

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  21. Monomeric Alumylene Supported by Bis(oxazolinyl)methanide [BoxmAl]

    Ding Tao, Ryo Nakano, Makoto Yamashita

    2020.10.20 

     More details

    Event date: 2020.10

    Language:English   Presentation type:Poster presentation  

  22. 環状ルイス塩基一配位ボリレン及びその合成等価体の合成検討

    山梨 遼太朗・佐藤 克海・中野 遼・山下 誠

    第10回CSJ化学フェスタ2020  2020.10.22  日本化学会

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  23. ビス(オキサゾリニル)メタニド配位子を有する後周期金属錯体の合成および反応

    山梨 遼太朗・中野遼・山下誠

    日本化学会 第100春季年会(2020)  2020.3.23  日本化学会

     More details

    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  24. Reactivity of Alkyl-substituted Al Anion toward Unsaturated Hydrocarbons and Early Metal Complexes

    Kengo Sugita, Ryo Nakano, Makoto Yamashita

    2020.3.24 

     More details

    Event date: 2020.3

    Language:English   Presentation type:Oral presentation (general)  

  25. Synthesis and Property of Alkyl-Substituted Al Anion

    atoshi Kurumada, Kengo Sugita, Ryo Nakano, Makoto Yamashita

    2020.3.24 

     More details

    Event date: 2020.3

    Language:English   Presentation type:Oral presentation (general)  

  26. Synthesis and Application of Cyclic Guanidine-based NCN Pincer Complex

    Ming Min Lee・Ryo Nakano・Makoto Yamashita

    日本化学会 第100春季年会(2020)  2020.3.23  日本化学会

     More details

    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス  

  27. Ligation Behavior of a Pyridine-Tethered Cyclic Guanidine to Late Transition Metals International conference

    Ming min Lee, Ryo Nakano, Makoto Yamashita

    2019.10.15 

     More details

    Event date: 2019.10

    Language:English   Presentation type:Poster presentation  

  28. 中性B-O二重結合種の合成と性質

    中野遼・山下誠

    第30回基礎有機化学討論会  2019.9.26  基礎有機化学会

     More details

    Event date: 2019.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:大阪国際交流センター  

  29. バナジル錯体による超臨界メタンの酸素酸化

    山田海人・中野遼・山下誠

    日本化学会 第99春季年会(2019)  2019.3.19  日本化学会

     More details

    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学 岡本キャンパス  

▼display all

Research Project for Joint Research, Competitive Funding, etc. 4

  1. 非10族金属触媒を用いた汎用オレフィンと二酸化炭素のカップリング反応の開発

    Grant number:NJ202213  2023.4 - 2024.3

    野口遵研究助成 

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2200000 ( Direct Cost: \2200000 )

  2. 水素移動型カップリングによるメタンのC2、C3炭化水素への変換

    2021.4 - 2024.3

    ENEOS東燃ゼネラル研究奨励・奨学会 研究助成 

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1500000 ( Direct Cost: \1500000 )

  3. Synthesis and application of cyclic borylene

    Grant number:1436  2021.3 - 2023.3

    Hitachi Global Foundation  The Kurata Grants 

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000 ( Direct Cost: \1000000 )

  4. Synthesis and application of a stable cyclic borylene

    Grant number:19-JA-009  2019.9 - 2020.8

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000 ( Direct Cost: \1000000 )

KAKENHI (Grants-in-Aid for Scientific Research) 3

  1. 金属配位子協働作用によるアルカンC-C結合の切断と触媒的変換

    Grant number:22K14678  2022.4 - 2024.3

    科学研究費助成事業  若手研究

    中野 遼

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4680000 ( Direct Cost: \3600000 、 Indirect Cost:\1080000 )

    アルカンのC-C単結合は極めて安定な結合であるが、その選択的な切断反応が実現されれば、有機分子逆合成経路の新規開拓や枯渇しゆく炭素資源の効率的変換に繋がることが期待される。本研究はそのアルカンC-C単結合の選択的切断を金属配位子協働触媒作用によって実現することを目指す。実際に本手法を開拓する際には、有機金属化学・典型元素化学・計算化学の最先端の知見を活用することでその目的を達成する計画である。

  2. Alkane transformation via 1,2-addition of C-H bods

    Grant number:19K15561  2019.4 - 2021.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Early-Career Scientists

    Nakano Ryo

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4160000 ( Direct Cost: \3200000 、 Indirect Cost:\960000 )

    In this study, we have focused on the elementary reaction of 1,2-addition of alkane C-H to metal-heteroatom multiple bonds, which is known with early metals, and have examined the application of this elementary reaction with middle and late metals. First, we developed bidentate and tridentate ligands bearing guanidine moieties and synthesized metal complexes of Fe, Ru, Co, Rh, and Pd. The Rh complex was investigated in detail, and it was found by deuterium labeling experiments, that the metal ligand cooperative C-H activation is possible by deprotonating the guanidine with a strong base. In addition, the π-electron-donating nature of the guanidine moiety was utilized for the first rhodium-catalyzed synthesis of acrylates from carbon dioxide and ethylene.

  3. 二酸化炭素と汎用オレフィンの直接共重合

    Grant number: 14J11101  2014.4 - 2016.3

    科学研究費助成事業  特別研究員奨励費

    中野 遼

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2200000 ( Direct Cost: \2200000 )

Industrial property rights 3

  1. 極性基含有オレフィン共重合体、及びその製造方法

    野崎 京子, 伊藤 慎庫, 中野 遼, 安田 妃那, 小林 稔, 田谷野 孝夫

     More details

    Application no:2018-012758  Date applied:2018.1

    Announcement no:2018-141138  Date announced:2018.9

    Patent/Registration no:7004972 

  2. 新規なカルベン前駆体化合物及びそれらによるオレフィン系重合用触媒並びにオレフィン系共重合体の製造方法

    野崎 京子, 伊藤 慎庫, 中野 遼, タオ ウェンジェ, 田谷野 孝夫, 小西 洋平

     More details

    Application no:2016-006685  Date applied:2016.1

    Announcement no:2016-135777  Date announced:2016.7

    Patent/Registration no:6581912  Date registered:2019.9 

  3. 重合体及び重合体の製造方法

    細川 隆史, 芳谷 俊英, 伊藤 慎庫, 野崎 京子, 中野 遼

     More details

    Application no:2013-262358  Date applied:2013.12

    Announcement no:2014-240476  Date announced:2014.12

    Patent/Registration no:6017407  Date issued:2016.11

    Country of applicant:International (PCT) application  

 

Teaching Experience (On-campus) 42

  1. Chemistry and Biotechnology Laboratory 2

    2022

  2. Organic Chemistry Laboratory I

    2022

  3. Advanced Experiments and Exercises in Molecular Chemistry II

    2022

  4. Advanced Experiments and Exercises in Molecular Chemistry I

    2022

  5. Seminar on Molecular Chemistry 1C

    2022

  6. Seminar on Molecular Chemistry 1A

    2022

  7. Seminar on Molecular Chemistry 2E

    2022

  8. Seminar on Molecular Chemistry 2C

    2022

  9. Seminar on Molecular Chemistry 2A

    2022

  10. Seminar on Molecular Chemistry 1D

    2022

  11. Seminar on Molecular Chemistry 1B

    2022

  12. Chemistry and Biotechnology Laboratory 3

    2022

  13. Organic Chemistry 1 with Exercises

    2022

  14. Biotechnology Laboratory

    2022

  15. Elements of Organic Chemistry

    2022

  16. Seminar on Molecular Chemistry 2D

    2022

  17. Seminar on Molecular Chemistry 2B

    2022

  18. Advanced Experiments and Exercises in Molecular Chemistry II

    2021

  19. Advanced Experiments and Exercises in Molecular Chemistry I

    2021

  20. Seminar on Molecular Chemistry 1C

    2021

  21. Seminar on Molecular Chemistry 1A

    2021

  22. Chemistry and Biotechnology Laboratory 2

    2021

  23. Chemistry and Biotechnology Laboratory 2

    2021

  24. Organic Chemistry Laboratory I

    2021

  25. Seminar on Molecular Chemistry 2E

    2021

  26. Seminar on Molecular Chemistry 2C

    2021

  27. Seminar on Molecular Chemistry 2A

    2021

  28. Seminar on Molecular Chemistry 1D

    2021

  29. Seminar on Molecular Chemistry 1B

    2021

  30. Chemistry and Biotechnology Laboratory 3

    2021

  31. Chemistry and Biotechnology Laboratory 3

    2021

  32. Organic Chemistry 1 with Exercises

    2021

  33. Biotechnology Laboratory

    2021

  34. Organic Chemistry Laboratory II

    2021

  35. Elements of Organic Chemistry

    2021

  36. Seminar on Molecular Chemistry 2D

    2021

  37. Seminar on Molecular Chemistry 2B

    2021

  38. Organic Chemistry 4 with Exercises

    2020

  39. Organic Chemistry III

    2020

  40. Seminar on Molecular Chemistry 1D

    2020

  41. Organic Chemistry 4 with Exercises

    2019

  42. Organic Chemistry 4 with Exercises

    2018

▼display all

 

Academic Activities 3

  1. 基礎有機化学会 若手オンラインシンポジウム (第1回)

    Role(s):Planning, management, etc.

    基礎有機化学会  ( オンライン ) 2021.11

     More details

    Type:Academic society, research group, etc. 

  2. 基礎有機化学会 若手オンラインシンポジウム (第0回)

    Role(s):Planning, management, etc.

    基礎有機化学会  ( オンライン ) 2020.11

     More details

    Type:Academic society, research group, etc. 

  3. The 69th Conference of Japan Society of Coordination Chemistry

    Role(s):Planning, management, etc.

    Japan Society of Coordination Chemistry  2019.9