Faculty Profiles - OSADA Minoru

Papers - OSADA Minoru

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Improved energy storage performance of PVDF nanocapacitors by utilizing 2D inorganic barrier Reviewed

Byun Ki-Nam, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

Chemistry Letters Vol. 52 ( 1 ) page： 51 - 54 2023.1

Advances in dielectric performance of atomically engineered Sr1. 8Bi0. 2Nb3O10 perovskite nanosheet thin films Reviewed International coauthorship

Haena Yim, So Yeon Yoo, Haneul Choi, Hye Jung Chang, Seong-Ju Hwang, Sahn Nahm, Minoru Osada, Ji-Won Choi

Journal of Alloys and Compounds Vol. 925 page： 166606 2022.12

Tailored synthesis of molecularly thin platinum nanosheets using designed 2D surfactant solids Reviewed

Eisuke Yamamoto, Akiko Suzuki, Makoto Kobayashi, Minoru Osada

Nanoscale Vol. 14 page： 11561 - 11567 2022.6

無機２次元ナノシートが拓く原子層技術 Invited Reviewed

長田　実

まてりあ Vol. 60 ( 10 ) page： 628 - 633 2021.10

Construction of multilayer films and superlattice-and mosaic-like heterostructures of 2D metal oxide nanosheets via a facile spin-coating process Reviewed

Hitomi Yano, Nobuyuki Sakai, Yasuo Ebina, Renzhi Ma, Minoru Osada, Kenjiro Fujimoto, Takayoshi Sasaki

ACS Applied Materials & Interfaces Vol. 13 ( 36 ) page： 43258 - 43265 2021.8

Solution-Processed Two-Dimensional Metal Oxide Anticorrosion Nanocoating Reviewed

Leanddas Nurdiwijayanto, Hiroki Nishijima, Yoshiharu Miyake, Nobuyuki Sakai, Minoru Osada, Takayoshi Sasaki, and Takaaki Taniguchi

Nano Lett. Vol. 21 ( 16 ) page： 7044 - 7049 2021.8

Facile titania nanocoating using single droplet assembly of 2D nanosheets Reviewed

Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

J. Ceram. Soc. Jpn. Vol. 129 ( 7 ) page： 359 - 364 2021.7

Reversible hydrogenation and irreversible epoxidation induced by graphene oxide electrolysis

T. Taniguchi, K-C. Wong, L. Nurdiwijayanto, K. Hatakeyama, K. Awaya, S. Ida, K. Koiumuma, S. Ueda, M. Osada, H. Yokoi

Carbon Vol. 177 page： 26 - 34 2021.2

Rational assembly of two-dimensional perovskite nanosheets as building blocks for new ferroelectrics Reviewed International journal

Muhammad Shuaib Khan, Minoru Osada, Lei Dong, Yoon-Hyun Kim, Yasuo Ebina, Takayoshi Sasaki

ACS Appl. Mater. Interfaces Vol. 13 ( 1 ) page： 1783 - 1790 2021.1

Authorship：Corresponding author Language：English Publishing type：Research paper (scientific journal)

Artificial materials in the form of superlattices have been studied actively in quest of new engineering methods or design rules for the development of desired functionalities, in particular high-k ferroelectricity, ferromagnetism, and high mobility electron gas. This work presents a controlled assembly strategy for fabricating atomically precise interfaces of two-dimensional (2D) homologous perovskite nanosheets (Ca2Nam-3Nb
m
O3m+1-; m = 3-6) to construct artificial superlattices. The distinctive thickness of each 2D homologous perovskite nanosheets attributed to the presence of different number of NbO6 octahedra provides an exquisite control to engineer interfacial properties for tailored design of superior high-k properties and emergence of ferroelectricity. The higher dielectric constant (εr = 427) and development of ferroelectricity for (Ca2Nb3O10-/Ca2Na2Nb5O16-)6 superlattice indicate that superlattice films with both odd number of NbO6 octahedra possess extended polarization due to the potential effect of heterointerface and ferroelectric instabilities. Furthermore, the increased discontinuities/offsets in Ca2Nb3O10- and Ca2Na3Nb6O19- nanosheets band alignment results in superior insulating properties (∼1 × 10-11 A cm-2 at 1 V) for (Ca2Nb3O10-/Ca2Na3Nb6O19-)6 superlattice. These findings exhibit new research opportunities for the development of novel artificial high-k dielectric/ferroelectric via precise control of interfaces at the atomic level and can be extended to the large family of 2D perovskite compounds.

DOI： 10.1021/acsami.0c16967

PubMed

焼かずに機能性セラミックスをつくる Invited Reviewed

長田　実

化学と教育 Vol. 69 ( 1 ) page： 24 - 27 2021.1

Single droplet assembly for two-dimensional nanosheet tiling Reviewed International journal

Shi Yue, Osada Minoru, Ebina Yasuo, Sasaki Takayoshi

ACS Nano Vol. 14 ( 11 ) page： 15216 - 15226 2020.11

無機ナノシートを利用した室温セラミックスコーティング Invited Reviewed

長田　実

セラミックス Vol. 55 ( 10 ) page： 741 - 745 2020.10

Scalable design of two-dimensional oxide nanosheets for construction of ultrathin multilayer nanocapacitors Reviewed International journal

Muhammad Shuaib Khan, Hyung-Jun Kim, Yoon-Hyun Kim, Yasuo Ebina, Wataru Sugimoto, Takayoshi Sasaki, Minoru Osada

Small Vol. 16 page： 2003485 2020.8

Authorship：Last author,　Corresponding author Language：English Publishing type：Research paper (scientific journal)

Large size of capacitors is the main hurdle in miniaturization of current electronic devices. Herein, a scalable solution-based layer-by-layer engineering of metallic and high-κ dielectric nanosheets into multilayer nanosheet capacitors (MNCs) with overall thickness of ≈20 nm is presented. The MNCs are built through neat tiling of 2D metallic Ru0.95 O20.2- and high-κ dielectric Ca2 NaNb4 O13- nanosheets via the Langmuir-Blodgett (LB) approach at room temperature which is verified by cross-sectional high-resolution transmission electron microscopy (HRTEM). The resultant MNCs demonstrate a high capacitance of 40-52 µF cm-2 and low leakage currents down to 10-5 -10-6 A cm-2 . Such MNCs also possess complimentary in situ robust dielectric properties under high-temperature measurements up to 250 °C. Based on capacitance normalized by the thickness, the developed MNC outperforms state-of-the-art multilayer ceramic capacitors (MLCC, ≈22 µF cm-2 /5 × 104 nm) present in the market. The strategy is effective due to the advantages of facile, economical, and ambient temperature solution assembly.

DOI： 10.1002/smll.202003485

PubMed

Synthesis of NaMoO3F and Na5W3O9F5 with morphological controllability in non-aqueous solvents. Reviewed International journal

Y. Asakura, T. Akahira, M. Kobayashi, M. Osada, S. Yin

Inorganic Chemistry Vol. 59 ( 15 ) page： 10707 - 10716 2020.8

Publishing type：Research paper (scientific journal)

NaMoO3F and Na5W3O9F5 were synthesized by solvothermal reaction of MoO3 and WO3, respectively, with NaF in nonaqueous solvents. These reactions were realized at low temperatures (150-200 °C) without the use of HF. This synthesis method is much more facile and safe procedure compared with general synthesis methods for oxyfluorides which includes hydrothermal reaction under a presence of HF or solid-state reaction at high temperatures in vacuum sealed tube or under high pressure. In the case of the reaction of MoO3 with NaF, the kind of solvent largely affected the obtained morphologies of NaMoO3F. The morphology in the case of acetonitrile as a solvent was rodlike with a micrometer-scale size, while that in the case of ethanol was polyhedral with a size of several hundred nanometers. In addition, the solvothermal reaction of WO3 with NaF led to the formation of Na5W3O9F5. Also, the difference of solvents for the solvothermal reaction affected the obtained particle sizes. The effect of the solvents on the morphologies of the obtained oxyfluorides probably resulted from the difference of the solubility of NaF and the subsequent dissolution ratio of MoO3 or WO3 in the used solvents. Our synthesis method can expand the applicability of oxyfluorides by providing a new phase and/or unique morphology.

DOI： 10.1021/acs.inorgchem.0c01175

Web of Science

Scopus

PubMed

Graphitic carbon nitride-based low-dimensional heterostructures for photocatalytic applications Reviewed International journal

M-S. Khan, F. Zhang, M. Osada, S-S. Mao, S. Shen

Solar RRL Vol. 4 ( 8 ) 2020.8

無機ナノシートの精密集積と電子デバイスへの応用 Invited Reviewed

長田　実

機能材料 Vol. 40 ( 7 ) page： 15 - 21 2020.7

On/off boundary of photocatalytic activity between single- and bilayer MoS2 Reviewed International journal

Takaaki Taniguchi, Leanddas Nurdiwijayanto, Shisheng Li, Hong En Lim, Yasumitsu Miyata, Xueyi Lu, Renzhi Ma, Dang-Ming Tang, Shigenori Ueda, Kazuhito Tsukagoshi, Takayoshi Sasaki, Minoru Osada

ACS Nano Vol. 14 ( 6 ) page： 6663 - 6672 2020.6

Hard-template synthesis of hollow mesoporous silica nanoplates using layered double hydroxide Reviewed International journal

Shi Y.

Chemistry Letters Vol. 49 ( 9 ) page： 1078 - 1080 2020.6

2次元ナノシートの形態制御と機能材料への応用 Invited Reviewed

長田　実

セラミックス Vol. 55 ( 5 ) page： 390 - 394 2020.5

van der Waals force layered multiferroic hybrid perovskite (CH3NH3)2CuCl4 single crystals Reviewed International journal

Zhao Hu, Hongyang Zhao, Zhenxiang Cheng, Jianxu Ding, Han Gao, Yibo Han, Shengao Wang, Zhiwen Xu, Yucheng Zhou, Tingting Jia, Hideo Kimura, Minoru Osada

Physical chemistry chemical physics : PCCP Vol. 22 ( 7 ) page： 4235 - 4239 2020.4

Authorship：Last author Publishing type：Research paper (scientific journal)

In inorganic-organic perovskites, the three-dimensional arrangement of the organic group results in more subtle balance of charge, spin and space, thereby providing an attractive route toward new multiferroics. Here we report the existing of multiple ferroic orderings in inorganic-organic layered perovskites with relative strong hydrogen bond ordering of the organic chains intra plane. In addition, the inter plane in perovskite is stacking via van der Waals force. However, such magnetoelectric coupling properties for this compound have not been reported since it is difficult to characterize the properties in single crystals since most of the hybrid perovskites are usually deliquescent and unstable when exposed to air. To deal with these problems, we synthesized a (CH3NH3)2CuCl4 single crystal by using a simple evaporation technique, and demonstrated ferroelectric, magnetic and magneto-electric properties of (CH3NH3)2CuCl4. The internal hydrogen bonding of easily tunable organic unit combined with 3d transition-metal layers in such hybrid perovskites make (CH3NH3)2CuCl4 a multiferroic crystal with magnetoelectrical coupling and offer an new way to engineer multifunctional multiferroic.

DOI： 10.1039/c9cp05976h

Web of Science

PubMed

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Papers - OSADA Minoru