Faculty Profiles - OSADA Minoru

Papers - OSADA Minoru

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Site occupancy analysis on the enhancement in Dy-substituted Pb(Zr,Ti)O-3 film Reviewed

Ken Nishida, Minoru Osada, Hiroshi Uchida, Hiroshi Nakaki, Seiichiro Koda, Hiroshi Funaku, Takashi Katoda

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS Vol. 45 ( 9B ) page： 7548 - 7551 2006.9

Language：English Publishing type：Research paper (scientific journal) Publisher：INST PURE APPLIED PHYSICS

The effect of site selectivity on the ferroelectric polarization property was investigated in Dy-substituted Pb(Zr0.4Ti0.6)O-3 films prepared on (111)Pt/Ti/SiO2/(100)Si substrates by a chemical solution method. Dy ions were introduced, assuming Pb or Zr and Ti site substitutions in Pb(Zr0.40Ti0.60)O-3 with x ranging from 0 to 0.06. Site occupation was determined by Raman spectroscopy. Dy ions selectively replaced the assumed sites at a low x value; however, these ions interdiffused to opposite sites at a high x value. Remnant polarization was enhanced when Dy ions selectivity substituted the Zr and Ti sites at a low x value, while it was contrarily degraded by Ph site substitution. These results provide useful guidelines for ferroelectric property improvement by ion substitution in Pb(Zr0.4Ti0.6)O-3.

DOI： 10.1143/JJAP.45.7548

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Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification Reviewed

Narumi Ohta, Kazunori Takada, Lianqi Zhang, Renzhi Ma, Minoru Osada, Takayoshi Sasaki

ADVANCED MATERIALS Vol. 18 ( 17 ) page： 2226 - + 2006.9

Language：English Publishing type：Research paper (scientific journal) Publisher：WILEY-BLACKWELL

The high-rate capability of solid-state, rechargeable lithium batteries with sulfide electrolytes is significantly improved when the LiCoO(2) particles are spray-coated with a Li(4)Ti(5)O(12) film with a thickness of several nanometers (see figure). The power densities of the solid-state battery with the coated LiCoO(2) are comparable to those of commercialized lithium-ion cells.

DOI： 10.1002/adma.200502604

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Investigation of domain distribution in patterned PZT thin films using Raman spectroscopy Reviewed

Ken Nishida, Minoru Osada, Shintaro Yokoyama, Kenji Takahashi, Hiroshi Funakubo, Takashi Katoda

Transactions of the Materials Research Society of Japan, Vol 31, No 1 Vol. 31 ( 1 ) page： 27 - 30 2006

Language：English Publishing type：Research paper (international conference proceedings) Publisher：ELSEVIER SCIENCE BV

Domain distribution, crystallinity and ferroelectric properties of micro-patterned PZT thin films were characterized with polarized Raman spectroscopy. The patterned PZT film grown on the Pt bottom electrode had good crystallinity independent of the pattern size. On the other hand, the PZT film grown outside the Pt bottom electrode had poor crystallinity or almost amorphous. The c-domain volume was estimated to be 55% from the polarized Raman spectra on the Pt bottom electrode. These results demonstrate that Raman spectroscopy is a very useful means to characterize micro-patterned PZT films.

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Characterization of superconducting sodium cobalt oxide bilayer-hydrate Reviewed

K Takada, K Fukuda, M Osada, Nakai, I, F Izumi, RA Dilanian, K Kato, M Takata, H Sakurai, E Takayama-Muromachi, T Sasaki

CHINESE JOURNAL OF PHYSICS Vol. 43 ( 3 ) page： 556 - 565 2005.6

Language：English Publishing type：Research paper (scientific journal) Publisher：PHYSICAL SOC REPUBLIC CHINA

new superconductor of sodium cobalt oxide bilayer-hydrate, Na(X)COo(2)center dot yH(2)O (X approximate to 0.35), was characterized by chemical and structure analyses. The chemical analyses showed that the formal valence of Co was +3.4, which was much lower than +3.65 that had been estimated from the Na content, x. The deviation from the charge neutralization was considered to be compensated by oxonium (H3O+) ions, which were evidenced by Raman spectroscopy. Structural studies based on Raman spectroscopy and synchrotron X-ray powder diffraction suggested that the H3O+ ions occupy the same crystallographic sites as the Na+ ions.

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Synthesis and electrochemistry of layered (1-x)LiNi0.5Mn0.5O2 • xLi[Li1/3Mn2/3]O2 • yLiCoO2 (0≦x=y≦0.3 and x+y=0.5) cathode materials Reviewed

Zhang, L, Takada, K, Ohta, N, Osada, M, Fukuda, K, Wang, L, Sasaki, T, Watanabe, M

( 146 ) page： 598 - 601 2005

Synthesis and Electrical Properties of Sr- and Nb-Cosubstituted Bi4-xSrxTi3-xNbxO12 Polycrystalline Thin Films Reviewed

Hirofumi MATSUDA, Takashi IIJIMA, Hiroshi UCHIDA, Isao OKADA, Takayuki WATANABE, Hiroshi FUNAKUBO, Minoru OSADA, Masato KAKIHANA

Jpn. J. Apply. Phys. Vol. 42 ( 8 ) page： 949 - 952 2003.8

Raman scattering in YBa2Cu4O8 and PrBa2Cu4O8: Indications of pseudogap effects in nonsuperconducting PrBa2Cu4O8 Reviewed

J Backstrom, M Rubhausen, M Kall, L Borjesson, AP Litvinchuk, M Kakihana, M Osada, B Dabrowski

PHYSICAL REVIEW B Vol. 61 ( 10 ) page： 7049 - 7054 2000.3

Language：English Publishing type：Research paper (scientific journal) Publisher：AMER PHYSICAL SOC

By analysis of the Raman spectra of superconducting YBa2Cu4O8 (Y-124), we observe a suppression of low-energy electronic density of states that we link to changes in the Linewidth of the Ba-phonon mode. These effects occur at a temperature below 150 K, where also anomalies in resistivity and other physical properties take place. We argue that these changes in the Raman spectra of Y-124 are connected to the opening of a pseudogap. Analogous anomalies in resistivity and the Ba-phonon width in the nonsuperconducting homologue PrBa2Cu4O8 (Pr-124) below 150 K suggest that similar pseudogap effects can occur without a following transition to a superconducting state at st lower temperature.

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CuO-chain Raman scattering and photoinduced metastability in YBa2Cu3Ox Reviewed

M Kall, M Osada, M Kakihana, L Borjesson, T Frello, J Madsen, NH Andersen, R Liang, P Dosanjh, WN Hardy

PHYSICAL REVIEW B Vol. 57 ( 22 ) page： 14072 - 14075 1998.6

Language：English Publishing type：Research paper (scientific journal) Publisher：AMER PHYSICAL SOC

Raman measurements in YBa2Cu3Ox (x=6.72-6.82) high-T-c superconductors reveal intense phonon scattering due to an electronic resonance localized near oxygen vacancies on the CuO chains. Below room temperature the resonance can be photobleached in a manner similar to reported persistent photoinduced superconductivity effects, indicating photon-assisted oxygen ordering or electron vacancy capture. By comparing Raman and x-ray diffraction data we establish a correlation between the stability of the photoinduced state and the oxygen-ordering kinetics in the CuO chains.

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Raman-active phonons in Bi2Sr2-xLaxCuO6+d: Phonon assignment and charge-redistribution effects Reviewed

M Osada, M Kakihana, M Kall, L Borjesson, A Inoue, M Yashima

PHYSICAL REVIEW B Vol. 56 ( 5 ) page： 2847 - 2851 1997.8

Language：English Publishing type：Research paper (scientific journal) Publisher：AMERICAN PHYSICAL SOC

Phonon Raman spectra of Bi2Sr2-xLaxCuO6+d single crystals with x values close to 0, 0.4, and 0.8 have been investigated. Room-temperature measurements were performed in the five main polarization geometries, including the c-axis polarized configuration. We identify the 4A(1g) symmetry modes that are Raman allowed within the ideal body-centered-tetragonal unit cell, as well as several disorder activated phonon bands from the BiO and/or SrO layers. For an increasing degree of La doping, the O(2)(Sr) A(1g) mode at 624 cm(-1) softens by 12 cm(-1) between x = 0 and x = 0.8. We attribute this softening to a weakening of the Cu-O(2)(Sr)-Bi bond due to a reduction in Cu and Bi valences when going from the overdoped (x = 0) to the underdoped (x = 0.8) regime.

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Raman-active phonons in Bi2Sr2Ca1-xYxCu2O8+d (x=0-1): Effects of hole filling and internal pressure induced by Y doping for Ca, and implications for phonon assignments Reviewed

M Kakihana, M Osada, M Kall, L Borjesson, H Mazaki, H Yasuoka, M Yashima, M Yoshimura

PHYSICAL REVIEW B Vol. 53 ( 17 ) page： 11796 - 11806 1996.5

Language：English Publishing type：Research paper (scientific journal) Publisher：AMERICAN PHYSICAL SOC

The phonon Raman spectra of Bi2Sr2Ca1-xYxCu2O8+d (x=0-1) have been investigated in a number of well-defined single-crystal and polycrystalline samples. From the polarization and Y-doping dependence, and from a comparison with previous reports on Bi-based cuprates, we identify the (6A(1g)+1B(1g)) symmetry modes that are Raman allowed within the ideal body-centered-tetragonal unit cell. A large number of extra ''disorder-induced'' phonon bands are observed in the ab-plane polarized spectra. In contrast to most previous reports, we argue that the c-axis polarized phonon band around 629 cm(-1) is due to the O(2)(Sr)A(1g) vibration, while the exclusively ab-plane polarized band around 463 cm(-1) is induced by the O(3)(Bi)A(1g) vibration. With increasing Y doping we find that the vibrational modes involving atoms in the CuO2 planes rapidly increase in intensity as a result of the reduced metallic screening in the hole-depleted Y-doped samples. We also find that Y substitution gives rise to a substantial hardening of the O(1)(Cu)A(1g) and B-1g phonons by similar to 40 cm(-1), whereas the O(2)(Sr)A(1g) phonon is found to soften by similar to 20 cm(-1), when x increases from 0 to 1. The phonon frequency changes can be explained by the ''internal pressure'' induced by the decrease in the average Ca/Y ion size and an additional ''charge-transfer'' induced by the change in the Cu and Bi valences with Y doping.

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Phonon Raman scattering in Y1-xPrxBa2Cu4O8 (x=0-1) and (Y1-xPrx)(2)Ba4Cu7O15-delta (x=0-0.6) Reviewed

M Kall, AP Litvinchuk, P Berastegui, LG Johansson, L Borjesson, M Kakihana, M Osada

PHYSICAL REVIEW B Vol. 53 ( 6 ) page： 3590 - 3597 1996.2

Language：English Publishing type：Research paper (scientific journal) Publisher：AMERICAN PHYSICAL SOC

We report on a Raman-scattering investigation of phonons in ceramic Y1-xPrxBa2Cu4O8 (Y(1-x)Pr(x)124) with x=0-1, and (Y1-xPrx)(2)Ba4Cu7O15-delta (Y(1-x)Pr(x)247) with x=0-0.6. It is found that the A(g) symmetry phonons of the BaO layers and the CuO double-chain layers increase in frequency with Pr content x, while B-2g and B-3g symmetry phonons decrease in frequency. In the Y(1-x)Pr(x)247 samples we are able to identify two symmetry allowed apical oxygen A(g) modes. The B-1g-like plane oxygen phonon softens by similar to 12% from x=0 to x=1, and exhibits a two-mode behavior at intermediate x in both Y(1-x)Pr(x)124 and Y(1-x)Pr(x)247. Polarized micro-Raman spectra of Pr124 crystallites show that several phonons are asymmetric, exhibiting Fano line shapes similar to what has been found in superconducting Y124. The variation in phonon frequencies with Pr content is similar to what has been reported for the single-chain cuprate Y1-xPrxBa2Cu3O7-delta (Y(1-x)Pr(x)123), and the changes can be understood from the variation in structural parameters. We do not observe any peculiarities that can explain the disappearance of superconductivity, or the different rates of T-c suppression in the three different Y-Ba-Cu-O systems, upon Pr substitution.

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