Updated on 2022/10/31

写真a

 
SUDA Jun
 
Organization
Graduate School of Engineering Electronics 2 Professor
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Electrical Engineering, Electronics, and Information Engineering
Title
Professor
External link

Degree 1

  1. 博士(工学) ( 1997.3   京都大学 ) 

Research Interests 9

  1. 結晶欠陥

  2. 分子線エピタキシー

  3. エピタキシャル成長

  4. 電子物性

  5. 界面

  6. 点欠陥

  7. パワーデバイス

  8. 窒化アルミニウム

  9. 窒化ガリウム

Research Areas 3

  1. Nanotechnology/Materials / Crystal engineering

  2. Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Electric and electronic materials

  3. Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Electron device and electronic equipment

Research History 5

  1. Nagoya University   Institute of Materials and Systems for Sustainability Center for Integrated Research of Future Electronics Innovative Devices Section

    2018.4

  2. 名古屋大学大学院   工学研究科   教授

    2017.4

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    Country:Japan

  3. 京都大学大学院   工学研究科   准教授

    2008.4 - 2017.3

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    Country:Japan

  4. 京都大学大学院   工学研究科   講師

    2002.10 - 2008.3

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    Country:Japan

  5. 京都大学大学院   工学研究科   助手

    1997.4 - 2002.9

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    Country:Japan

Education 3

  1. Kyoto University   Graduate School, Division of Engineering

    1994.4 - 1997.3

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    Country: Japan

  2. Kyoto University   Graduate School, Division of Engineering

    1992.4 - 1994.3

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    Country: Japan

  3. Kyoto University   Faculty of Engineering

    1988.4 - 1992.3

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    Country: Japan

Professional Memberships 5

  1. 応用物理学会

  2. IEEE

  3. 電気学会

  4. 電子情報通信学会

  5. 日本結晶成長学会

 

Papers 339

  1. Impact Ionization Coefficients in GaN Measured by Above- and Sub-E<inf>g</inf> Illuminations for p<sup>-</sup>/n<sup>+</sup> Junction

    Maeda T., Narita T., Yamada S., Kachi T., Kimoto T., Horita M., Suda J.

    Technical Digest - International Electron Devices Meeting, IEDM   Vol. 2019-December   2019.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Technical Digest - International Electron Devices Meeting, IEDM  

    We propose a novel method to extract impact ionization coefficients of electrons and holes using above-and sub-bandgap illuminations for a p-/n+ junction diode. For above-bandgap illumination, the light is absorbed near p-GaN surface. Then, generated minority carriers diffuse and reach the edge of the depletion layer, resulting in an electron-injected photocurrent. On the other hand, for sub-bandgap illumination, the light is selectively absorbed near the p-n junction interface by the Franz-Keldysh effect, resulting in a hole-injected photocurrent. The electron- and hole-initiated multiplication factors are obtained as the ratios of the measured photocurrents to the calculated unmultiplicated photocurrents. By analyzing the electron- and hole-initiated multiplication factors, the impact ionization coefficients of electrons and holes in GaN are extracted separately.

    DOI: 10.1109/IEDM19573.2019.8993438

    Scopus

  2. Demonstration of Conductivity Modulation in SiC Bipolar Junction Transistors With Reduced Base Spreading Resistance

    Asada Satoshi, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 66 ( 11 ) page: 4870 - 4874   2019.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IEEE Transactions on Electron Devices  

    SiC bipolar junction transistors (BJTs) were fabricated based on the design criterion proposed in our previous study, which quantitatively proved the importance of decreasing a base spreading resistance. To reduce the base spreading resistance, Al+-implantation was performed in the parasitic base region. No negative influences due to the implantation damage on the current gain were confirmed when the implantation is performed sufficiently apart from the emitter mesa sidewall, the distance of which is longer than 3μ m. Since the fabricated BJTs satisfied the design criterion, clear conductivity modulation was achieved, resulting in a reduced collector-resistance, that is, 50% of the unipolar resistance. In addition, we experimentally demonstrated that the conductivity modulation in SiC BJTs could be enhanced by decreasing the base spreading resistance.

    DOI: 10.1109/TED.2019.2941884

    Web of Science

    Scopus

  3. Measurement of avalanche multiplication utilizing Franz-Keldysh effect in GaN p-n junction diodes with double-side-depleted shallow bevel termination

    Maeda Takuya, Narita Tetsuo, Ueda Hiroyuki, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    APPLIED PHYSICS LETTERS   Vol. 115 ( 14 )   2019.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Applied Physics Letters  

    Avalanche multiplication characteristics of GaN p-n junction diodes (PNDs) with double-side-depleted shallow bevel termination, which exhibit nearly ideal avalanche breakdown, were investigated by photomultiplication measurements using sub-bandgap light. In GaN PNDs under reverse bias conditions, optical absorption induced by the Franz-Keldysh (FK) effect is observed, resulting in a predictable photocurrent. The avalanche multiplication factors were extracted as a ratio of the measured values to the calculated FK-induced photocurrent. In addition, the temperature dependences of the avalanche multiplications were also investigated.

    DOI: 10.1063/1.5114844

    Web of Science

    Scopus

  4. Franz-Keldysh effect in 4H-SiC p-n junction diodes under high electric field along the < 11(2)over-bar0 > direction

    Maeda Takuya, Chi Xilun, Tanaka Hajime, Horita Masahiro, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 58 ( 9 )   2019.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics  

    Electric-field dependence of optical absorption induced by Franz-Keldysh (FK) effect strongly depends on the value of the reduced effective mass along electric field. In this study, reverse current-voltage characteristics of 4H-SiC{1120} p-n junction diodes under sub-bandgap illumination were investigated. Under a reverse bias condition, a photocurrent induced by FK effect was observed and increased with the reverse voltage. We calculated a photocurrent with consideration of phonon-assisted optical absorption induced by FK effect in a depletion region using the reduced effective mass perpendicular to the c-axis (μ⊥ = 0.26 m0), and the calculated values showed good agreement with the experimental values. This result indicates that the anisotropy of optical absorption induced by FK effect in 4H-SiC is small, since the reduced effective mass perpendicular to the c-axis (μ⊥ = 0.26 m0) is close to that parallel to the c-axis (μ∥ m = 0.28 m0).

    DOI: 10.7567/1347-4065/ab3873

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  5. Deep-level transient spectroscopy studies of electron and hole traps in n-type GaN homoepitaxial layers grown by quartz-free hydride-vapor-phase epitaxy

    Kanegae Kazutaka, Fujikura Hajime, Otoki Yohei, Konno Taichiro, Yoshida Takehiro, Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS LETTERS   Vol. 115 ( 1 )   2019.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Applied Physics Letters  

    We studied deep levels in quartz-free hydride-vapor-phase epitaxy (QF-HVPE)-grown homoepitaxial n-type GaN layers within which three electron and eight hole traps were detected. The dominant electron and hole traps observed in the QF-HVPE-grown GaN layers were E3 (EC - 0.60 eV) and H1 (EV + 0.87 eV), respectively. We found that the E3 trap density of QF-HVPE-grown GaN (∼1014 cm-3) was comparable with that of MOVPE-grown GaN layers, whereas the H1 trap density of QF-HVPE-grown GaN (∼1014 cm-3) was much smaller than that of an MOVPE-grown GaN layer with a low-residual-carbon growth condition. A detailed analysis of the QF-HVPE-grown GaN layers revealed that the H1 trap density is almost equal to the carbon impurity concentration and other impurities that compensate the Si donors besides the carbon impurity were hardly detected in the QF-HVPE-grown GaN layers.

    DOI: 10.1063/1.5098965

    Web of Science

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  6. Shockley-Read-Hall lifetime in homoepitaxial p-GaN extracted from recombination current in GaN p-n(+) junction diodes

    Maeda Takuya, Narita Tetsuo, Ueda Hiroyuki, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 58 ( SC )   2019.6

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics  

    The Shockley-Read-Hall (SRH) lifetime in homoepitaxial p-GaN (N a = 1 × 1017 cm-3) is investigated by analyzing forward current-voltage (I-V) characteristics in GaN-on-GaN p-n+ junction diodes with mesa-isolation structure. The ideality factor around 2 due to recombination current was obtained in the 1.8-2.7 V window, which is different from the characteristic of a p+-n- junction involving considerable diffusion current. The recombination current was proportional to the junction area, indicating that the recombination current is a bulk component, not a mesa-surface component. Analyzing the recombination current with consideration of the SRH recombination rate in the depletion layer, we obtained an SRH lifetime of 46 ps at 298 K. The temperature dependence of the I-V characteristics was also investigated and the SRH lifetimes were extracted in the range of 223-573 K. The SRH lifetime in homoepitaxial p-GaN followed the empirical power law of = 1.2 × 10-16 × T 2.25 (s).

    DOI: 10.7567/1347-4065/ab07ad

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  7. Frontiers of Nitride Semiconductor Research FOREWORD

    Chichibu Shigefusa F., Kumagai Yoshinao, Kojima Kazunobu, Deura Momoko, Akiyama Toru, Arita Munetaka, Fujioka Hiroshi, Fujiwara Yasufumi, Hara Naoki, Hashizume Tamotsu, Hirayama Hideki, Holmes Mark, Honda Yoshio, Imura Masataka, Ishii Ryota, Ishitani Yoshihiro, Iwaya Motoaki, Kamiyama Satoshi, Kangawa Yoshihiro, Katayama Ryuji, Kawakami Yoichi, Kawamura Takahiro, Kobayashi Atsushi, Kuzuhara Masaaki, Matsumoto Koh, Mori Yusuke, Mukai Takashi, Murakami Hisashi, Murotani Hideaki, Nakazawa Satoshi, Okada Narihito, Saito Yoshiki, Sakai Akira, Sekiguchi Hiroto, Shiozaki Koji, Shojiki Kanako, Suda Jun, Takeuchi Tetsuya, Tanikawa Tomoyuki, Tatebayashi Jun, Tomiya Shigetaka, Yamada Yoichi

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 58   2019.6

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/1347-4065/ab1411

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  8. Design and Fabrication of GaN p-n Junction Diodes With Negative Beveled-Mesa Termination

    Maeda Takuya, Narita Tetsuo, Ueda Hiroyuki, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 40 ( 6 ) page: 941 - 944   2019.6

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IEEE Electron Device Letters  

    We report on homoepitaxial GaN p-n junction diodes with a negative beveled-mesa termination. The electric field distribution in a beveled-mesa was investigated using TCAD simulation, and the devices were designed using currently available GaN growth techniques. Shallow-angle (ca. 10°) negative bevel GaN p-n junction diodes were fabricated with various Mg acceptor concentrations in the p-layers. The suppression of electric field crowding and improvement of the breakdown voltage were observed, as the Mg concentration was decreased. The parallel-plane breakdown field of 2.86 MV/cm was obtained for a device with the breakdown voltage of 425 V.

    DOI: 10.1109/LED.2019.2912395

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  9. Estimation of Impact Ionization Coefficient in GaN by Photomulitiplication Measurement Utilizing Franz-Keldysh Effect

    Maeda T., Narita T., Ueda H., Kanechika M., Uesugi T., Kachi T., Kimoto T., Horita M., Suda J.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs   Vol. 2019-May   page: 59 - 62   2019.5

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Proceedings of the International Symposium on Power Semiconductor Devices and ICs  

    A valanche multiplication characteristics in GaN p-n junction diodes (PNDs) under high reverse bias conditions were investigated. The GaN-on-GaN PNDs with double-side-depleted shallow bevel termination, which showed low reverse leakage current and excellent avalanche capability, were used for the measurements. Under sub-bandgap light illumination, the photocurrents induced by Franz-Keldysh (FK) effect, which can be well reproduced by the theoretical calculations of the optical absorption, and their avalanche multiplications were observed. The multiplication factors were extracted as the ratios of the experimental photocurrents to the calculated FK-induced photocurrent. Under an assumption of equal impact ionization coefficients of electrons and holes, the electric-field dependence of an impact ionization coefficient in GaN were estimated.

    DOI: 10.1109/ISPSD.2019.8757676

    Scopus

  10. Parallel-Plane Breakdown Fields of 2.8-3.5 MV/cm in GaN-on-GaN p-n Junction Diodes with Double-Side-Depleted Shallow Bevel Termination

    Maeda T., Narita T., Ueda H., Kanechika M., Uesugi T., Kachi T., Kimoto T., Horita M., Suda J.

    Technical Digest - International Electron Devices Meeting, IEDM   Vol. 2018-December   page: 30.1.1 - 30.1.4   2019.1

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Technical Digest - International Electron Devices Meeting, IEDM  

    We report homoepitaxial GaN p-n junction diodes with novel beveled-mesa structures. The n-layers and p-layers, the doping concentrations of which are comparable, were prepared. We found that electric field crowding does not occur in the structure using TCAD simulation. The fabricated devices showed the breakdown voltages of 180-480 V, small leakage currents, and excellent avalanche capabilities. The breakdown voltages increased at elevated temperature. At the breakdown, nearly uniform luminescence in the entire p-n junctions was observed in all the devices. These results are strong evidences that the uniform avalanche breakdowns occurred in the devices. We carefully characterized the depletion layer width at the breakdown, and the parallel-plane breakdown electric fields of 2.8-3.5 MV/cm were obtained, which are among the best of the reported non-punch-through GaN vertical devices.

    DOI: 10.1109/IEDM.2018.8614669

    Scopus

  11. Impact Ionization Coefficients in GaN Measured by Above- and Sub-E-g Illuminations for p(-)/n(+) Junction

    Maeda Takuya, Narita Tetsuo, Yamada Shinji, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    2019 IEEE INTERNATIONAL ELECTRON DEVICES MEETING (IEDM)     2019

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    Web of Science

  12. Estimation of Impact Ionization Coefficient in GaN by Photomulitiplication Measurement Utilizing Franz-Keldysh Effect

    Maeda Takuya, Narita Tetsuo, Ueda Hiroyuki, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    2019 31ST INTERNATIONAL SYMPOSIUM ON POWER SEMICONDUCTOR DEVICES AND ICS (ISPSD)     page: 59 - 62   2019

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

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  13. Determination of Surface Recombination Velocity From Current-Voltage Characteristics in SiC p-n Diodes

    Asada Satoshi, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 65 ( 11 ) page: 4786 - 4791   2018.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IEEE Transactions on Electron Devices  

    Surface recombination velocity on mesa sidewalls of SiC p-n diodes with various surface passivation conditions was evaluated from the device-size-dependent preexponential factor of recombination current (J0rec). The diodes passivated by SiO2 with postoxidation nitridation were dipped into HF to eliminate a shunt current, which is evoked by the nitrided SiO2 layer and disturbs the analysis of the recombination current. For accurate determination of the surface recombination velocity, an effective recombination zone width was precisely derived taking account of the distribution of carrier density in the depletion layer. The surface recombination velocity of the diodes without any passivation and with the postoxidation nitridation (NO annealing at 1250 °C for 70 min) was determined as 1.2 × 107 and 6.0 × 105 cm/s, respectively, which indicates that the postoxidation nitridation can reduce the surface recombination by a factor of about 20. We confirmed that TCAD simulation could reproduce the current-voltage characteristics by utilizing the extracted parameters. In addition, an evaluation method was proposed to determine the surface recombination velocity from the high-current region, where diffusion current is dominant.

    DOI: 10.1109/TED.2018.2867545

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  14. Carrier lifetime and breakdown phenomena in SiC power device material

    Kimoto T., Niwa H., Okuda T., Saito E., Zhao Y., Asada S., Suda J.

    JOURNAL OF PHYSICS D-APPLIED PHYSICS   Vol. 51 ( 36 )   2018.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of Physics D: Applied Physics  

    Recent progress and current understanding of carrier lifetimes and avalanche phenomena in silicon carbide (SiC) are reviewed. The acceptor level of carbon vacancy (V C), called the Z 1/2 center, has been identified to be the primary carrier lifetime killer in SiC. The V C defects can be eliminated by the introduction of excess carbon atoms followed by carbon diffusion in the bulk region. The true bulk lifetime after V C elimination was estimated to be approximately 110 μs. The doping dependence of carrier lifetimes in n- and p-type SiC is also presented. The impact ionization coefficients of electrons and holes were extracted in the temperature range of 298 to 423 K. The intrinsic critical electric field strength of SiC0 0 0 1 was determined to be 2.0, 2.5, and 3.3 MV cm-1 for doping densities of 1 × 1015, 1 × 1016, and 1 × 1017 cm-3, respectively, at room temperature; it slightly increased at elevated temperature. The obtained set of impact ionization coefficients has enabled us to accurately predict the breakdown voltage of SiC devices, including its temperature dependence. Due to the unusually low impact ionization coefficient of electrons, the breakdown voltage of a SiC p+n junction is about 6%-9% higher than that of an n+p junction with a given doping density.

    DOI: 10.1088/1361-6463/aad26a

    Web of Science

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  15. Phonon-assisted optical absorption due to Franz-Keldysh effect in 4H-SiC p-n junction diode under high reverse bias voltage

    Maeda Takuya, Chi Xilun, Horita Masahiro, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 11 ( 9 )   2018.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/APEX.11.091302

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  16. Analytical formula for temperature dependence of resistivity in p-type 4H-SiC with wide-range doping concentrations

    Asada Satoshi, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 57 ( 8 )   2018.8

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics  

    Temperature dependence of resistivity from 250 to 900K in p-type 4H-SiC with various doping concentrations (5.8 × 1014-7.1 × 1018cm-3) was presented. The resistivity was obtained by the van der Pauw method in samples, whose doping concentrations were precisely determined in our previous work. From the experimental results, coefficients for a fitting formula with polynomial approximation were derived. We confirmed that the fitting formula can accurately estimate the resistivity of p-type SiC with wide-range doping concentrations.

    DOI: 10.7567/JJAP.57.088002

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  17. Accurate method for estimating hole trap concentration in n-type GaN via minority carrier transient spectroscopy

    Kanegae Kazutaka, Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 11 ( 7 )   2018.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/APEX.11.071002

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  18. Characterization of carrier concentration and mobility of GaN bulk substrates by Raman scattering and infrared reflectance spectroscopies

    Kanegae Kazutaka, Kaneko Mitsuaki, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 57 ( 7 )   2018.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/JJAP.57.070309

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  19. Impacts of Finger Numbers on ON-State Characteristics in Multifinger SiC BJTs With Low Base Spreading Resistance

    Asada Satoshi, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 65 ( 7 ) page: 2771 - 2777   2018.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IEEE Transactions on Electron Devices  

    Impacts of finger numbers on ON-state characteristics in multifinger 10-kV-class SiC bipolar junction transistors (BJTs), whose base spreading resistance is sufficiently reduced by using aluminum ion implantation, were investigated by performing TCAD simulations. Common-emitter current-voltage characteristics of the BJTs with different base current densities and carrier lifetimes in the collector layer were analyzed. The simulation results exhibited that the BJTs with fewer finger numbers could achieve superior characteristics owing to an expansion of a conductivity-modulated region and to a higher current density per finger. In addition, we showed that BJTs with a punchthrough structure have a potential to achieve superior characteristics suitable for power device applications under a certain condition, where strong conductivity modulation occurs. The presented results indicate that the appropriate finger numbers should be designed for a better performance of the multifinger SiC BJTs.

    DOI: 10.1109/TED.2018.2834354

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  20. Theoretical analysis of Hall factor and hole mobility in p-type 4H-SiC considering anisotropic valence band structure

    Tanaka H., Asada S., Kimoto T., Suda J.

    JOURNAL OF APPLIED PHYSICS   Vol. 123 ( 24 )   2018.6

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of Applied Physics  

    The temperature dependencies of hole density and hole mobility of p-type 4H-SiC obtained by Hall effect measurement were theoretically analyzed taking account of its anisotropic valence band structure. The experimental Hall factor, which was derived from the ratio of theoretical hole density to experimental Hall hole density, was reproduced by theoretical Hall factor computed using the valence band structure and relaxation times of scattering mechanisms. The product of the theoretical Hall factor and drift mobility computed by the same transport model agreed well with the experimental Hall mobility. Based on analyses of the results, it was revealed that the temperature dependence of Hall factor can be explained by considering the anisotropic valence band structure along with consideration of anisotropic relaxation times. The contribution of each scattering mechanism was also discussed, and empirical formulas for Hall and drift mobilities are presented.

    DOI: 10.1063/1.5025776

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  21. Franz-Keldysh effect in GaN p-n junction diode under high reverse bias voltage

    Maeda Takuya, Narita Tetsuo, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    APPLIED PHYSICS LETTERS   Vol. 112 ( 25 )   2018.6

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    DOI: 10.1063/1.5031215

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  22. A comparative study on electrical characteristics of 1-kV pnp and npn SiC bipolar junction transistors

    Okuda Takafumi, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 57 ( 4 )   2018.4

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    DOI: 10.7567/JJAP.57.04FR04

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  23. Sources of carrier compensation in metalorganic vapor phase epitaxy-grown homoepitaxial n-type GaN layers with various doping concentrations

    Sawada Naoki, Narita Tetsuo, Kanechika Masakazu, Uesugi Tsutomu, Kachi Tetsu, Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 11 ( 4 )   2018.4

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    DOI: 10.7567/APEX.11.041001

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  24. Impacts of energy relaxation process on quasi-ballistic hole transport capability in germanium and silicon nanowires

    Tanaka H., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 123 ( 2 )   2018.1

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of Applied Physics  

    The quasi-ballistic hole transport in germanium and silicon nanowires was theoretically investigated by solving the Boltzmann transport equation taking account of phonon scattering in an atomistic framework. Comparison of quasi-ballistic hole transport capabilities between germanium and silicon nanowires showed that the transmission coefficients for the two materials are similar. Then, the behavior of forward and backward current fluxes was analyzed focusing on the impact of energy relaxation process. The slower energy relaxation of holes in germanium nanowires leads to a longer distance where backscattering enables holes to return to the source. This cancels the benefit of the longer mean free path of holes in germanium nanowires, resulting in similar transmission coefficients in germanium and silicon nanowires.

    DOI: 10.1063/1.5010052

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  25. Deep-ultraviolet light emission from 4H-AlN/4H-GaN short-period superlattice grown on 4H-SiC(11(2)over-bar0)

    Kaneko M., Ueta S., Horita M., Kimoto T., Suda J.

    APPLIED PHYSICS LETTERS   Vol. 112 ( 1 )   2018.1

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Applied Physics Letters  

    AlN/GaN short-period superlattices (SPSLs) were grown on 4H-SiC(112-0) substrates with a 4H-AlN template layer. The thickness of the GaN layers was controlled to be less than 1 nm to suppress the generation of extended defects. The stacking fault and threading dislocation density were found to be 3 × 105 cm-1 and 6 × 107 cm-2, respectively, which were as low as those for a 4H-AlN single layer. The superlattice replicated the polytype of the underlying 4H-AlN layer (4H-SiC substrate), meaning that a 4H-AlN/4H-GaN SPSL was grown. Roomerature cathodoluminescence measurements revealed that the 4H-AlN/4H-GaN SPSLs exhibited intense luminescence in the deep ultraviolet region of 4.4-5.0 eV, depending on the GaN layer thickness. The emission wavelengths of the SPSLs fairly agreed with the estimation based on the Kronig-Penney model.

    DOI: 10.1063/1.5006435

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  26. Effects of parasitic region in SiC bipolar junction transistors on forced current gain

    Asada S., Suda J., Kimoto T.

    Materials Science Forum   Vol. 924 MSF   page: 629 - 632   2018

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Materials Science Forum  

    Effects of a parasitic region in SiC BJTs on conductivity modulation and a forced current gain (βF) were investigated by using TCAD simulation with various device structures. By introducing an Al+-implanted region below the base parasitic region, βF can be improved because the implanted region can reduce the base spreading resistance, leading to alleviation of debiasing effect. βF in devices with various parasitic areas, whose base spreading resistances were reduced by the Al+-implantation, were compared. We found that βF can be enhanced by expanding the parasitic area if the base spreading resistance is sufficiently reduced. The higher βF is attributed to an expanded conductivity-modulated region. The collector current spreading in the collector layer and hole injection from the parasitic region as well as from the intrinsic region can play a role to evoke conductivity modulation. Thus, the larger parasitic region can expand the conductivity-modulated region, which results in expansion of an active area and the enhancement of βF, though a higher base voltage is required.

    DOI: 10.4028/www.scientific.net/MSF.924.629

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  27. Parallel-Plane Breakdown Fields of 2.8-3.5 MV/cm in GaN-on-GaN p-n Junction Diodes with Double-Side-Depleted Shallow Bevel Termination

    Maeda T., Narita T., Ueda H., Kanechika M., Uesugi T., Kachi T., Kimoto T., Horita M., Suda J.

    2018 IEEE INTERNATIONAL ELECTRON DEVICES MEETING (IEDM)     2018

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  28. Theoretical analysis of quasi-ballistic hole transport in Ge and Si nanowires focusing on energy relaxation process

    Tanaka H., Suda J., Kimoto T.

    2017 Silicon Nanoelectronics Workshop, SNW 2017   Vol. 2017-January   page: 35 - 36   2017.12

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    The quasi-ballistic hole transport capabilities of Ge and Si NWs were calculated using atomistic electron-phonon coupling and Boltzmann transport equation. Analyzing the forward and backward current fluxes, it was shown that the positive impact of high mobility of Ge is canceled by its slower energy relaxation, which results in comparable transmission coefficients and current transport capabilities between Ge and Si NWs.

    DOI: 10.23919/SNW.2017.8242284

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  29. Carrier Lifetimes in Lightly-Doped p-Type 4H-SiC Epitaxial Layers Enhanced by Post-growth Processes and Surface Passivation

    Okuda T., Miyazawa T., Tsuchida H., Kimoto T., Suda J.

    JOURNAL OF ELECTRONIC MATERIALS   Vol. 46 ( 11 ) page: 6411 - 6417   2017.11

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    We investigated limiting factors of carrier lifetimes and their enhancement by post-growth processes in lightly-doped p-type 4H-SiC epitaxial layers (NA ∼ 2 × 1014 cm−3). We focused on bulk recombination, surface recombination, and interface recombination at the epilayer/substrate, respectively. The carrier lifetime of 2.8 μs in an as-grown epilayer was improved to 10 μs by the combination of VC-elimination processes and hydrogen annealing. By employing surface passivation with deposited SiO2 followed by POCl3 annealing, a long carrier lifetime of 16 μs was obtained in an oxidized epilayer. By investigating carrier lifetimes in a self-standing p-type epilayer, it was revealed that the interface recombination at the epilayer/substrate was smaller than the surface recombination on a bare surface. We found that the VC-elimination process, hydrogen annealing, and surface passivation are all important for improving carrier lifetimes in lightly-doped p-type epilayers.

    DOI: 10.1007/s11664-017-5677-4

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  30. Analysis of quasi-ballistic hole transport capability of Ge and Si nanowire pMOSFETs by a quantum-corrected Boltzmann transport equation

    Tanaka H., Suda J., Kimoto T.

    International Conference on Simulation of Semiconductor Processes and Devices, SISPAD   Vol. 2017-September   page: 277 - 280   2017.10

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    The quasi-ballistic hole transport capabilities of Ge and Si nanowire pMOSFETs were analyzed based on a quantum-corrected Boltzmann transport equation. A new formalism of quantum-correction potential was proposed, and using this model, the current drive capabilities of Ge and Si nanowire pMOSFETs were compared. Though the ON-current was larger in the Ge nanowire pMOSFET, the transmission coefficients are similar between Ge and Si, because the higher hole mobility of Ge is canceled by its slower energy relaxation. Thus, the larger current of the Ge nanowire pMOSFET was attributed to its larger injection current. The impact of device geometry on the performance was also investigated, and the [110]-oriented Ge nanowire pMOSFET with a 15 nm gate length exhibited the highest performance among the devices considered in this study.

    DOI: 10.23919/SISPAD.2017.8085318

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  31. Characterization of lightly-doped n- and p-type homoepitaxial GaN on free-standing substrates

    Horita M., Suda J.

    IMFEDK 2017 - 2017 International Meeting for Future of Electron Devices, Kansai     page: 86 - 87   2017.7

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    Hall-effect measurements for n-type and p-type GaN with low doping concentration are presented. The GaN layers were grown by metal-organic vapor phase epitaxy on hydride-vapor-phase-epitaxy-grown free-standing GaN substrates. For n-GaN, the origin of acceptor which compensating donor is not only C but also native defects for the Si doping concentration of 1016 cm-3 level. The electron mobility is mainly limited by ionized impurity scattering or polar optical phonon scattering in the temperature less or higher than 200 K, respectively. For p-GaN, lightly Mg doping of mid 1016 cm-3 was achieved, which shows the donor concentration of 3.2×1016 cm-3 and the mobility of 31 cm2/Vs at 300 K.

    DOI: 10.1109/IMFEDK.2017.7998055

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  32. Effect of Postoxidation Nitridation on Forward Current-Voltage Characteristics in 4H-SiC Mesa p-n Diodes Passivated With SiO2

    Asada Satoshi, Kimoto Tsunenobu, Suda Jun

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 64 ( 7 ) page: 3016 - 3018   2017.7

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    An origin of shunt current, a ledge in forward current-voltage ( ${I}$ - ${V}$ ) characteristics, in 4H-SiC mesa p-n diodes was investigated by adopting various surface passivation processes. Experimental results indicated that the shunt current path is located along the mesa sidewall and the shunt current is enlarged with increasing NO-annealing period and temperature. Based on these results, we qualitatively explain that nitrogen-related positive charges near the SiC/SiO2 interface, which are formed by postoxidation nitridation, induce band bending and lowering of the diffusion potential along the mesa sidewall, resulting in occurrence of the shunt current.

    DOI: 10.1109/TED.2017.2700336

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  33. Electrical properties of n- and p-type 4H-SiC formed by ion implantation into high-purity semi-insulating substrates

    Fujihara Hiroaki, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 56 ( 7 )   2017.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics  

    Phosphorus or aluminum ions were directly implanted into semi-insulating 4H-SiC substrates with no epitaxial layers to form n- or p-type layers, respectively, with doping densities in the range from 1017 to 1019 cm-3. The electrical properties of these implanted layers annealed at 1650°C were characterized by Hall effect measurements in the temperature range of 160-900K. The electrical activation ratios of implanted dopants were 88-98%. The density of compensating defects was higher in Al+-implanted layers than in P+-implanted ones. The mobilities of the implanted layers were mostly comparable to those of epitaxial layers in the doping range investigated.

    DOI: 10.7567/JJAP.56.070306

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  34. Design Criterion for SiC BJTs to Avoid ON-Characteristics Degradation Due to Base Spreading Resistance

    Asada Satoshi, Kimoto Tsunenobu, Suda Jun

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 64 ( 5 ) page: 2086 - 2091   2017.5

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    It is empirically known that the ON-resistance (voltage) of the SiC bipolar junction transistors (BJTs) with a thin-base layer is prone to be larger than the resistance of a voltage-blocking collector layer. In this paper, we explain the mechanism of this degradation of ON-characteristics by focusing on a high base spreading resistance and a parasitic diode existing below the base contact. An equivalent circuit model of the SiC BJT was proposed, and SPICE simulation was performed.In addition, TCAD simulation confirmed the validity of the model well. Based on the model, a design criterion to avoid the unwanted increase of the ON-resistance is proposed.

    DOI: 10.1109/TED.2017.2684181

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  35. Temperature dependence of barrier height in Ni/n-GaN Schottky barrier diode

    Maeda Takuya, Okada Masaya, Ueno Masaki, Yamamoto Yoshiyuki, Kimoto Tsunenobu, Horita Masahiro, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 10 ( 5 )   2017.5

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    The temperature dependence of barrier height in a Ni/n-GaN Schottky barrier diode fabricated on a GaN homoepitaxial layer was investigated by capacitance-voltage, current-voltage, and internal photoemission measurements in the range of 223-573 K. The barrier height obtained by these methods linearly decreased with increasing temperature. The temperature coefficient was %(1.7-2.3) ' 10-4 eV/K, which is about half of the temperature coefficient of the band gap reported previously. This indicates that the decrease in the barrier height may mainly reflect the shrinkage of the band gap (lowering of the conduction band edge) in GaN with increasing temperature.

    DOI: 10.7567/APEX.10.051002

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  36. Interface properties of NO-annealed 4H-SiC (0001), (11(2)over-bar0), and (1(1)over-bar00) MOS structures with heavily doped p-bodies

    Kobayashi Takuma, Nakazawa Seiya, Okuda Takafumi, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 121 ( 14 )   2017.4

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    We investigated electrical characteristics of nitric oxide (NO)-annealed silicon carbide (SiC) (0001 ), (11 2 ¯ 0 ), and (1 1 ¯ 00 ) metal-oxide-semiconductor field effect transistors (MOSFETs) with heavily doped p-bodies (NA = 1 × 1017-3 × 1018 cm−3). Regardless of crystal faces or off-direction, the channel mobility decreased for higher acceptor density. We evaluated the interface state density (Dit) very near the bottom edge of 2-dimensional density of states (2D-DOS) in the conduction band of SiC from the low-temperature subthreshold slope of the MOSFETs. When the acceptor density of the p-body of the MOSFET is increased, the energy levels of 2D-DOS increase due to a stronger quantum confinement effect. Accordingly, the carriers in the heavily doped channel are influenced by the interface states located at higher energy levels. In the SiC MOS structures, the Dit values significantly increase near the conduction band edge (EC). Thus, MOSFETs on heavily doped p-bodies are affected by the higher density of Dit, leading to substantially lower mobility.

    DOI: 10.1063/1.4981127

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  37. Reduction of interface state density in SiC (0001) MOS structures by post-oxidation Ar annealing at high temperature

    Kobayashi Takuma, Suda Jun, Kimoto Tsunenobu

    AIP ADVANCES   Vol. 7 ( 4 )   2017.4

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    We found that post-oxidation Ar annealing at high temperature is effective in reducing the interface state density (Dit) near the conduction band edge (EC) of SiC (0001) MOS structures. The Dit reduction effect is comparable to that of nitridation process (annealing in nitric oxide (NO)) which has been a standard in SiC MOS technologies, without introducing any foreign atoms into the interface/oxide. The generation of fast interface states, which have been pointed out as a problem of nitridation process, is suppressed in the case of Ar annealing. In the proposed method, the final Dit values are mainly determined by the Ar annealing temperature rather than the initial oxidation temperature. The Dit values are not sensitive to the cooling speed, which means that rapid cooling is not necessary in the proposed method.

    DOI: 10.1063/1.4980024

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  38. Ultrahigh-Voltage SiC MPS Diodes With Hybrid Unipolar/Bipolar Operation

    Niwa Hiroki, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 64 ( 3 ) page: 874 - 881   2017.3

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    In this paper, ultrahigh-voltage (UHV) SiC devices with hybrid unipolar/bipolar operation are introduced and demonstrated. As the first step of such a device, a merged p-i-n Schottky (MPS) diode with an epitaxial p+-anode layer is proposed to reduce the conduction loss of a bipolar device in the low current region. A 'snapback' phenomenon is intensively investigated by analytical modeling, device simulation, and experiment and a design guideline of snapback-free hybrid operating MPS diodes is presented. Using the design guideline, snapback-free MPS diodes are fabricated and forward characteristics are investigated. By using a proper edge termination structure, a UHV SiC MPS diode with breakdown voltage of 11.3 kV is demonstrated.

    DOI: 10.1109/TED.2016.2636573

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  39. Hall-effect measurements of metalorganic vapor-phase epitaxy-grown p-type homoepitaxial GaN layers with various Mg concentrations

    Horita Masahiro, Takashima Shinya, Tanaka Ryo, Matsuyama Hideaki, Ueno Katsunori, Edo Masaharu, Takahashi Tokio, Shimizu Mitsuaki, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 56 ( 3 )   2017.3

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    DOI: 10.7567/JJAP.56.031001

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  40. Analysis of High-Field Hole Transport in Germanium and Silicon Nanowires Based on Boltzmann's Transport Equation

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON NANOTECHNOLOGY   Vol. 16 ( 1 ) page: 118 - 125   2017.1

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    In this paper, high-field hole transport in germanium nanowires was studied by using Boltzmann's transport equation in an atomistic framework. The scattering mechanisms taken into account are phonon and surface roughness. The hole drift velocities of [110], [111], and [112]-oriented germanium nanowires showed negative-differential characteristics, while that of the [001] nanowire did not. The behavior of hole drift velocity was analyzed based on the highly nonparabolic and orientation-dependent valence band structure. High-field hole transport properties in silicon nanowires were also calculated, and the differences between germanium and silicon nanowires were discussed, focusing mainly on momentum and energy relaxation times. The [110], [111], and [112] silicon nanowires showed faster hole drift velocity at high field than the germanium nanowires with the same orientation. This was attributed to faster energy relaxation in silicon nanowires, which mitigates the negative differential mobility in silicon nanowires compared to germanium nanowires.

    DOI: 10.1109/TNANO.2016.2635110

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  41. Phonon frequencies of a highly strained AIN layer coherently grown on 6H-SiC (0001)

    Kaneko M., Kimoto T., Suda J.

    AIP ADVANCES   Vol. 7 ( 1 )   2017.1

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    Phonon frequencies of a high-quality AlN layer coherently grown on a 6H-SiC (0001) substrate are investigated by Raman scattering. Owing to the largest strain in our coherent AlN layer among heteroepitaxially grown AlN layers ever reported, phonon frequencies of the E2 (low), E2 (high), and A1 (LO) modes are considerably shifted to 244.5 (−3.3, compared with bulk AlN), 672.1 (+16.3), and 899 (+11)cm−1, respectively. Full widths at half maximum of the phonon modes in the coherent AlN are almost equal to those of high-quality bulk AlN, clearly indicating its high crystalline quality and uniform strain. We discuss accuracy of phonon deformation potentials reported by several other groups thorough comparing our experimental results.

    DOI: 10.1063/1.4974500

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  42. Characterization of lightly-doped n- and p-type homoepitaxial GaN on free-standing substrates

    Horita Masahiro, Suda Jun

    2017 IEEE INTERNATIONAL MEETING FOR FUTURE OF ELECTRON DEVICES, KANSAI (IMFEDK)     page: 86-87   2017

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  43. Analysis of quasi-ballistic hole transport capability of Ge and Si nanowire pMOSFETs by a quantum-corrected Boltzmann transport equation

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    2017 INTERNATIONAL CONFERENCE ON SIMULATION OF SEMICONDUCTOR PROCESSES AND DEVICES (SISPAD 2017)     page: 277 - 280   2017

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  44. Correlation between shapes of Shockley stacking faults and structures of basal plane dislocations in 4H-SiC epilayers

    Iijima Akifumi, Kamata Isaho, Tsuchida Hidekazu, Suda Jun, Kimoto Tsunenobu

    PHILOSOPHICAL MAGAZINE   Vol. 97 ( 30 ) page: 2736 - 2752   2017

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    Shockley-type stacking faults expanded in 4H–SiC epilayers induced by ultraviolet illumination were investigated using a photoluminescence imaging method, a photoluminescence mapping method and X-ray topography. After ultraviolet illumination, more than 30 patterns of Shockley-type stacking faults which expanded from perfect basal plane dislocations were observed by photoluminescence imaging. The initial basal plane dislocations were crystallographically classified, and individual shapes of expanded Shockley-type stacking faults were predicted. The correspondence between the predicted shapes and observed ones was discussed.

    DOI: 10.1080/14786435.2017.1350788

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  45. Insight into phonon scattering in Si nanowires through high-field hole transport: Impacts of boundary condition and comparison with bulk phonon approximation

    Tanaka H., Suda J., Kimoto T.

    33RD INTERNATIONAL CONFERENCE ON THE PHYSICS OF SEMICONDUCTORS   Vol. 864 ( 1 )   2017

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    The impact of how to model phonon scattering on hole transport in Si nanowires was studied based on Boltzmann's transport equation. Boundary conditions for atomistic description of phonons in nanowires and approximation by bulk acoustic and optical phonons were analyzed in terms of their impacts on high-field hole transport. The boundary conditions for phonons influence the drift velocity and momentum relaxation time, especially at low electric field, but the energy relaxation time hardly depends on the boundary conditions. The impacts by the change of boundary conditions can be approximated by the change of the strength of acoustic phonon scattering in bulk phonon picture, though the behavior of energy relaxation and distribution function of holes can not be reproduced by bulk phonon approximation.

    DOI: 10.1088/1742-6596/864/1/012046

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  46. Theoretical Analysis of Quasi-ballistic Hole Transport in Ge and Si Nanowires Focusing on Energy Relaxation Process

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    2017 SILICON NANOELECTRONICS WORKSHOP (SNW)     page: 35 - 36   2017

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  47. Impact of annealing temperature on surface passivation of SiC epitaxial layers with deposited SiO<inf>2</inf> followed by POCl<inf>3</inf> annealing

    Okuda T., Kobayashi T., Kimoto T., Suda J.

    WiPDA 2016 - 4th IEEE Workshop on Wide Bandgap Power Devices and Applications     page: 233 - 235   2016.12

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    We investigate an impact of annealing temperature on surface passivation of SiC epitaxial layers with deposited SiO2 followed by POCl3 annealing. The POCl3 annealing process consists of two steps: (i) thermal annealing in POCl3 and (ii) subsequent thermal annealing in pure N2. We find that the annealing temperature of the subsequent N2 annealing is important to reduce surface recombination on SiC. For surface passivation, N2 annealing at high temperature at 1000° C is necessary.

    DOI: 10.1109/WiPDA.2016.7799944

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  48. Control of carbon vacancy in SiC toward ultrahigh-voltage power devices

    Kimoto T., Kawahara K., Zippelius B., Saito E., Suda J.

    SUPERLATTICES AND MICROSTRUCTURES   Vol. 99   page: 151 - 157   2016.11

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    A carbon vacancy defect is one of the most abundant point defects in SiC (as-grown, irradiated, annealed) and of technological importance because the acceptor-like level of a carbon monovacancy (Z1/2 center: EC – 0.63 eV) works as the primary carrier-lifetime killer in 4H–SiC. The carbon vacancy defects can be preferentially generated by either low-energy electron irradiation or high-temperature treatment in an inert gas ambient. On the other hand, the carbon vacancy defects can be almost eliminated by either a carbon-ion implantation process or thermal oxidation. By combination of these techniques, the density of carbon vacancy defects can be controlled in the wide range from 1011 cm−3 to 1015 cm−3 or even higher.

    DOI: 10.1016/j.spmi.2016.03.029

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  49. Promise and Challenges of High-Voltage SiC Bipolar Power Devices

    Kimoto Tsunenobu, Yamada Kyosuke, Niwa Hiroki, Suda Jun

    ENERGIES   Vol. 9 ( 11 )   2016.11

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    Although various silicon carbide (SiC) power devices with very high blocking voltages over 10 kV have been demonstrated, basic issues associated with the device operation are still not well understood. In this paper, the promise and limitations of high-voltage SiC bipolar devices are presented, taking account of the injection-level dependence of carrier lifetimes. It is shown that the major limitation of SiC bipolar devices originates from band-to-band recombination, which becomes significant at a high-injection level. A trial of unipolar/bipolar hybrid operation to reduce power loss is introduced, and an 11 kV SiC hybrid (merged pin-Schottky) diodes is experimentally demonstrated. The fabricated diodes with an epitaxial anode exhibit much better forward characteristics than diodes with an implanted anode. The temperature dependence of forward characteristics is discussed.

    DOI: 10.3390/en9110908

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  50. Hall-effect measurements of metalorganic vapor-phase epitaxy-grown p-type homoepitaxial GaN layers with various Mg concentrations (Retraction of vol 55, 05FH03, 2016)

    Horita Masahiro, Takashima Shinya, Tanaka Ryo, Matsuyama Hideaki, Ueno Katsunori, Edo Masaharu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 55 ( 11 )   2016.11

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    DOI: 10.7567/JJAP.55.119201

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  51. Franz-Keldysh effect in n-type GaN Schottky barrier diode under high reverse bias voltage (vol 9, 091002, 2016)

    Maeda Takuya, Okada Masaya, Ueno Masaki, Yamamoto Yoshiyuki, Horita Masahiro, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 10 )   2016.10

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    The reduced effective masses (μhh-e and μlh-e) were incorrect in the original manuscript. Table I and Fig. 4 should be replaced with the table and the figure shown below. The description "using a reduced effective mass of 0.14m0, which is calculated from the masses reported for electrons and holes in GaN" in line 44, column 1, page 1 should be replaced with "using the effective masses reported for electrons and holes in GaN, which are listed in Table I", and "a reduced effective mass of GaN (μ∥ = 0.14m0) was used" in line 34, column 2, page 3 should be replaced with "calculation was done by the two-band-model using the effective masses listed in Table I". The calculations of the absorption coefficient and the photocurrent was done by the two-hole-band-model using me, mhh, and mlh. The correction does not affect the results and conclusions in this paper.

    DOI: 10.7567/APEX.9.109201

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  52. Theoretical analysis of high-field hole transport in germanium and silicon nanowires

    Tanaka H., Suda J., Kimoto T.

    2016 IEEE Silicon Nanoelectronics Workshop, SNW 2016     page: 192 - 193   2016.9

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    High-field hole transport in Ge nanowires was studied using Boltzmann's transport equation. The behavior of drift velocity was analyzed based on the highly non-parabolic valence band structure. High-field hole transport properties in Si nanowires were also calculated, and the differences between Ge and Si nanowires were discussed.

    DOI: 10.1109/SNW.2016.7578046

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  53. Analysis of ballistic and quasi-ballistic hole transport properties in germanium nanowires based on an extended "Top of the Barrier" model

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    SOLID-STATE ELECTRONICS   Vol. 123   page: 143 - 149   2016.9

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    The ballistic hole transport properties in rectangular cross-sectional germanium nanowire transistors with various geometries were studied based on the “Top of the Barrier” model. Then, by an extension of this model, the quasi-ballistic hole transport was discussed taking into account phonon and surface roughness scattering in the channel and source-to-drain direct tunneling. Among several nanowire geometries targeted in this study, the [1 1 0]-oriented nanowire with large height along [11¯0] ([1 1 0]/(1 1¯ 0) NW) exhibited the largest ballistic current. This was understood from its large density of states and resulting high hole density. Large density of states, however, enhances backscattering in the channel. An approximation analysis of quasi-ballistic transport suggested that the [1 1 0]/(0 0 1) NW with higher mobility can outperform [1 1 0]/(1 1¯ 0) NW when scattering and tunneling are considered.

    DOI: 10.1016/j.sse.2016.04.015

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  54. Franz-Keldysh effect in n-type GaN Schottky barrier diode under high reverse bias voltage

    Maeda Takuya, Okada Masaya, Ueno Masaki, Yamamoto Yoshiyuki, Horita Masahiro, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 9 )   2016.9

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    The photocurrent of GaN vertical Schottky barrier diodes was investigated under sub-bandgap wavelength light irradiation. Under a low reverse bias voltage, the photocurrent is induced by internal photoemission, while under a high reverse bias voltage, the photocurrent increases significantly with the bias voltage. This is due to sub-bandgap optical absorption in a depletion region due to the Franz-Keldysh effect. The voltage and wavelength dependences of the photocurrent are successfully explained quantitatively.

    DOI: 10.7567/APEX.9.091002

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  55. SiC and GaN from the viewpoint of vertical power devices

    Suda J.

    Device Research Conference - Conference Digest, DRC   Vol. 2016-August   2016.8

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    Wide-bandgap (WBG) semiconductors have attracted great attention as materials for the next-generation power devices since they have superior material properties compared to silicon (Si). The most advanced WBG semiconductor for power devices is silicon carbide (SiC). In 1987, the growth technology called 'step-controlled epitaxy', which enables single-phase (polytype) growth, was developed. In 1993-1994, SiC Schottky-barrier diodes (SBDs) which exceeds the Si material limit was demonstrated. In 2001, SiC SBDs were commercialized. Key technologies for SiC SBDs were edge termination to obtain an ideal breakdown voltage and a junction barrier Schottky (JBS) structure to suppress reverse leakage current. For power MOSFETs, it took longer time due to low channel mobility at SiO2/SiC and oxide reliability issues. Channel mobility was much improved by post-oxidation nitridation in NO or N2O ambient. Now, channel mobility and reliability are well controlled (balanced). SiC power MOSFETs as well as power modules with SiC MOSFETs and SiC SBDs, are commercially available. Last 5 years, the implementation of SiC devices into electronic vehicles and railway trains were extensively investigated, demonstrating a significant improvement of power efficiency.

    DOI: 10.1109/DRC.2016.7548292

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  56. Characterization of n-type and p-type GaN layers grown on free-standing GaN substrates

    Suda J., Horita M.

    2016 Compound Semiconductor Week, CSW 2016 - Includes 28th International Conference on Indium Phosphide and Related Materials, IPRM and 43rd International Symposium on Compound Semiconductors, ISCS 2016     2016.8

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:2016 Compound Semiconductor Week, CSW 2016 - Includes 28th International Conference on Indium Phosphide and Related Materials, IPRM and 43rd International Symposium on Compound Semiconductors, ISCS 2016  

    Electrical characterization of low-doped n-type and p-type GaN layers grown by metal-organic vapor phase epitaxy are presented. The GaN layers were grown on hydride-vapor-phase-epitaxy-grown free-standing GaN substrates. For n-type GaN, the impact of electron trap on electrical characterization is discussed. Charging of trap in a depletion layer affects C-V characteristics. Correction is needed for depth profiling of net donor concentration. For p-type GaN, hole mobility for various Mg doping concentrations at various temperatures are presented. At 300 K, 33 cm2/Vs is obtained for p-type GaN with Mg doping concentration of mid 1016 cm-3.

    DOI: 10.1109/ICIPRM.2016.7528835

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  57. Ion implantation technology in SiC for high-voltage/high-temperature devices

    Kimoto T., Kawahara K., Kaji N., Fujihara H., Suda J.

    2016 16th International Workshop on Junction Technology, IWJT 2016     page: 54 - 58   2016.6

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    Electrical activation of implanted dopants and defect generation in SiC have been investigated. A nearly perfect (> 95%) electrical activation can be obtained including the implant tail region after annealing at 1650-1700 °C. The majority of point defects generated in implanted SiC can remarkably be reduced by thermal oxidation. The high activation ratio of implanted Al acceptors is a key factor for fabricating effective junction termination structures in high-voltage SiC devices. Recent high-quality semi-insulating SiC wafers offer the opportunity of high-temperature SiC integrated devices, which can be fabricated by only ion implantation without an epitaxial growth process.

    DOI: 10.1109/IWJT.2016.7486673

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  58. Control of carrier lifetime of thick n-type 4H-SiC epilayers by high-temperature Ar annealing

    Saito Eiji, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 6 )   2016.6

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    We investigated the carrier lifetime and Z1/2 center density of thick n-type 4H-SiC epilayers, which were oxidized and subsequently annealed in Ar at high temperatures. The Z1/2 center density decreased below the detection limit in the region to, at least, a 130μm depth by thermal oxidation. After subsequent high-temperature annealing, the Z1/2 center density increased with increasing annealing temperature, while the distribution of the Z1/2 center density was nearly uniform to a 130μm depth. The carrier lifetime could be controlled from 26 to 2.4 μs by changing the annealing temperature from 1600 to 1800 °C.

    DOI: 10.7567/APEX.9.061303

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  59. Hall-effect measurements of metalorganic vapor-phase epitaxy-grown p-type homoepitaxial GaN layers with various Mg concentrations

    Horita Masahiro, Takashima Shinya, Tanaka Ryo, Matsuyama Hideaki, Ueno Katsunori, Edo Masaharu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 55 ( 5 )   2016.5

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    Mg-doped p-type gallium nitride (GaN) layers with doping concentrations in the range from 6.5 × 1016cm-3 (lightly doped) to 3.8 × 1019cm-3 (heavily doped) were investigated by Hall-effect measurement for the analysis of hole concentration and mobility. p-GaN was homoepitaxially grown on a GaN free-standing substrate by metalorganic vapor-phase epitaxy. The threading dislocation density of the p-GaN was 4 × 106cm-2 measured by cathodoluminescence mapping. Hall-effect measurements of p-GaN were carried out at a temperature in the range from 160 to 450 K. A low compensation ratio of less than 1-was revealed. We also obtained the depth of the Mg acceptor level of 235 meV considering the lowering effect by the Coulomb potential of ionized acceptors. The hole mobilities of 33 cm2V-1 s-1 at 300K and 72cm2V-1 s-1 at 200K were observed in lightly doped p-GaN.

    DOI: 10.7567/JJAP.55.05FH03

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  60. Strain control in AlN top layer by inserting an ultrathin GaN interlayer on an AlN template coherently grown on SiC(0001) by PAMBE

    Kaneko Mitsuaki, Kimoto Tsunenobu, Suda Jun

    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS   Vol. 253 ( 5 ) page: 814 - 818   2016.5

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    Abstractauthoren We propose partially relaxed ultrathin GaN interlayer for strain control of AlN on SiC substrates. According to the degree of relaxation of the GaN interlayer, the lattice constant of the interlayer changes from that of SiC to that of bulk GaN, which leads to strain control of an AlN top layer grown on the interlayer. Growth of these layers is conducted by plasma-assisted molecular beam epitaxy. Before growing the interlayer, an AlN layer coherently grown on SiC is used as a template layer. The interlayers that have different degrees of relaxation are successfully obtained by changing the interlayer thickness. As a result, strain values of the AlN top layer grown on the interlayers are widely controlled from compressive (-0.53%) to tensile (+ 0.07%). TEM observation revealed the relaxation is induced by U-shaped half-loop dislocations originating from the GaN interlayer.

    DOI: 10.1002/pssb.201552649

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  61. Surface passivation on 4H-SiC epitaxial layers by SiO2 with POCl3 annealing

    Okuda Takafumi, Kobayashi Takuma, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 5 )   2016.5

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    We investigated surface passivation on 4H-SiC epitaxial layers with deposited or thermally grown SiO2 followed by POCl3 annealing. The measured carrier lifetime in a p-type epilayer with deposited SiO2 was limited to 0.5 μs and it was improved to 3.0 μs after POCl3 annealing. In an n-type epilayer, a measured carrier lifetime of 5.8 μs was improved to 12 μs after POCl3 annealing. We found a clear relationship between the measured carrier lifetime and the interface state density at SiO2/n-SiC after POCl3 annealing, suggesting that the reduction in interface state density lowered the surface recombination velocity on the 4H-SiC.

    DOI: 10.7567/APEX.9.051301

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  62. Interface state density of SiO2/p-type 4H-SiC (0001), (11(2)over-bar0), (1(1)over-bar00) metal-oxide-semiconductor structures characterized by low-temperature subthreshold slopes

    Kobayashi Takuma, Nakazawa Seiya, Okuda Takafumi, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 108 ( 15 )   2016.4

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    Interface properties of heavily Al-doped 4H-SiC (0001) (Si-face), (1120) (a-face), and (1100) (m-face) metal-oxide-semiconductor (MOS) structures were characterized from the low-temperature gate characteristics of metal-oxide-semiconductor field-effect transistors (MOSFETs). From low-temperature subthreshold slopes, interface state density (Dit) at very shallow energy levels (ET) near the conduction band edge (Ec) was evaluated. We discovered that the Dit near Ec (Ec - 0.01 eV < ET < Ec) increases in MOS structures with higher Al doping density for every crystal face (Si-, a-, and m-face). Linear correlation is observed between the channel mobility and Dit near Ec, and we concluded that the mobility drop observed in heavily doped MOSFETs is mainly caused by the increase of Dit near Ec.

    DOI: 10.1063/1.4946863

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  63. Modeling of surface roughness scattering in nanowires based on atomistic wave function: Application to hole mobility in rectangular germanium nanowires

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    PHYSICAL REVIEW B   Vol. 93 ( 15 )   2016.4

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    The authors present a calculation model of surface roughness scattering (SRS) in nanowires (NWs) based on atomistic description of electronic states by an sp3d5s∗ tight-binding scheme, and then this model is applied to hole transport in rectangular cross-sectional germanium (Ge) NWs. In this SRS model, the change of electronic band structures due to width or height reduction is first computed, and then it is expressed using an equivalent potential near the surface. The perturbation corresponding to a surface roughness is calculated from this equivalent potential. Using the aforementioned SRS model, hole mobility in Ge NWs was computed taking into account phonon scattering and SRS. The impacts of SRS on hole mobility in Ge NWs were analyzed, focusing on the valence band structure and hole states of NWs. The main results are as follows. At low hole density, the impacts of SRS are strongly dependent on NW geometry, and Ge NWs with high phonon-limited hole mobility, such as rectangular cross-sectional [110]-oriented NWs with large height along the [001] direction and square cross-sectional [111]-oriented NWs, tend to be less affected by SRS. At high hole density, however, the geometry dependence of hole mobility becomes weaker. These are understood from the nature of hole states and the valence band structure.

    DOI: 10.1103/PhysRevB.93.155303

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  64. Hall scattering factors in p-type 4H-SiC with various doping concentrations

    Asada Satoshi, Okuda Takafumi, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 4 )   2016.4

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    The Hall scattering factor (γH) in p-type 4H-SiC with various aluminum doping concentrations of 5.8 ' 1014-7.1 ' 1018cm%3 was investigated from 300 to 900 K. γH was determined by comparing the Hall coefficient with the theoretical carrier concentration derived from acceptor and donor concentrations obtained from secondary ion mab spectrometry and capacitance-voltage measurements. γH decreased with increasing temperature or doping concentration; γH = 1-0.4 for the doping concentration of 5.8 ' 1014cm%3 and γH = 0.5-0.2 for the doping concentration of 7.1 ' 1018cm%3. The dependence might be caused by the anisotropic and nonparabolic valence band structure of 4H-SiC.

    DOI: 10.7567/APEX.9.041301

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  65. Special issue on wide-bandgap semiconductor power electronics Preface

    Suda Jun

    SEMICONDUCTOR SCIENCE AND TECHNOLOGY   Vol. 31 ( 3 )   2016.3

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    Publishing type:Research paper (scientific journal)   Publisher:Semiconductor Science and Technology  

    DOI: 10.1088/0268-1242/31/3/030301

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  66. Strong impact of the initial III/V ratio on the crystalline quality of an AlN layer grown by rf-plasma-assisted molecular-beam epitaxy

    Kaneko Mitsuaki, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 9 ( 2 )   2016.2

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    The initial Al/N ratio for AlN growth of plasma-assisted molecular-beam epitaxy without plasma stabilization is investigated. The in situ growth rate of AlN gradually increased and its temporal variation corresponded to that of nitrogen atoms, which indicated that the initial Al/N ratio was excessively Al-rich. For AlN growth, such a high-Al/N-ratio condition resulted in a three-dimensional growth mode in the initial stage of the growth, and AlN with high threading dislocation density was obtained. By controlling the initial Al/N ratio by introducing a short standby time, the resulting two-dimensional initial growth mode leads to high-quality growth of AlN.

    DOI: 10.7567/APEX.9.025502

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  67. Characterization of N-Type and P-Type GaN Layers Grown on Free-Standing GaN Substrates

    Suda Jun, Horita Masahiro

    2016 COMPOUND SEMICONDUCTOR WEEK (CSW) INCLUDES 28TH INTERNATIONAL CONFERENCE ON INDIUM PHOSPHIDE & RELATED MATERIALS (IPRM) & 43RD INTERNATIONAL SYMPOSIUM ON COMPOUND SEMICONDUCTORS (ISCS)     2016

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  68. ESR study on hydrogen passivation of intrinsic defects in p-type and semi-insulating 4H-SiC

    Murakami K., Tanai S., Okuda T., Suda J., Kimoto T., Umeda T.

    Materials Science Forum   Vol. 858   page: 318 - 321   2016

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    We studied the hydrogen passivation/depassivation of four types of intrinsic defects (EI5/6, HEI7/8, HEI9/10, and P6/7) in p-type and semi-insulating 4H-SiC by means of electron spin resonance (ESR) for examining the origin of carrier-lifetime-killing defects. We suggest that the HEI7/8 and P6/7 centers are the strongest candidate for the origin of the lifetime-killing defects.

    DOI: 10.4028/www.scientific.net/MSF.858.318

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  69. Impact of Annealing Temperature on Surface Passivation of SiC Epitaxial Layers with Deposited SiO2 Followed by POCl3 Annealing

    Okuda Takafumi, Kobayashi Takuma, Kimoto Tsunenobu, Suda Jun

    2016 IEEE 4TH WORKSHOP ON WIDE BANDGAP POWER DEVICES AND APPLICATIONS (WIPDA)     page: 233 - 235   2016

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  70. SiC and GaN from the Viewpoint of Vertical Power Devices

    Suda Jun

    2016 74TH ANNUAL DEVICE RESEARCH CONFERENCE (DRC)     2016

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  71. Theoretical Analysis of High-field Hole Transport in Germanium and Silicon Nanowires

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    2016 IEEE SILICON NANOELECTRONICS WORKSHOP (SNW)     page: 192 - 193   2016

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  72. Ion Implantation Technology in SiC for High-Voltage/High-Temperature Devices

    Kimoto T., Kawahara K., Kaji N., Fujihara H., Suda J.

    2016 16TH INTERNATIONAL WORKSHOP ON JUNCTION TECHNOLOGY (IWJT)     page: 54 - 58   2016

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  73. Orientation and size effects on phonon-limited hole mobility in rectangular cross-sectional germanium nanowires

    Tanaka H., Mori S., Morioka N., Suda J., Kimoto T.

    2014 Silicon Nanoelectronics Workshop, SNW 2014     2015.12

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    The phonon-limited hole mobility in rectangular cross-sectional [001], [110], [111], and [112]-oriented germanium nanowires was calculated and the hole transport characteristics were compared. The calculation revealed that [110] germanium nanowires with larger height along [001] show high hole mobility and are favorable for p-channel FETs.

    DOI: 10.1109/SNW.2014.7348616

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  74. Oxidation-induced majority and minority carrier traps in n- and p-type 4H-SiC

    Okuda Takafumi, Alfieri Giovanni, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 8 ( 11 )   2015.11

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    We investigated majority and minority carrier traps in lightly doped n-and p-type 4H-SiC epitaxial layers before and after thermal oxidation using deep level transient spectroscopy and minority carrier transient spectroscopy. We detected oxidation-induced new minority carrier traps, HO1 (EV + 0.36 eV) and HO2 (EV + 0.54 eV) for n-type 4H-SiC, and EO1 (EC % 0.59 eV) and EO2 (EC % 0.84 eV) for p-type 4H-SiC after thermal oxidation at 1300 °C. After subsequent Ar annealing at 1550 °C, the HO1, HO2, and EO1 centers disappeared, whereas the concentration of the EO2 center increased. The properties of these carrier traps are discussed.

    DOI: 10.7567/APEX.8.111301

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  75. Impact Ionization Coefficients in 4H-SiC Toward Ultrahigh-Voltage Power Devices

    Niwa Hiroki, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 62 ( 10 ) page: 3326 - 3333   2015.10

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    A temperature dependence of impact ionization coefficients in 4H-SiC was studied in a wide range of electric field toward the accurate designing of ultrahigh-voltage devices. The photomultiplication measurement was conducted for various photodiodes with different multiplication layer structures to obtain multiplication factors and ionization coefficients in a wide range of electric field strength. Especially, using multiplication layer structure with low doping concentration, the hole impact ionization coefficient was extracted at low electric field of 1 MV/cm. In high-temperature measurement, the hole ionization coefficient decreased with the increase of temperature, as observed in other semiconductor materials. For the electron ionization coefficient, however, its temperature dependence was very small and values obtained at room temperature could be used, at least up to 150 °C.

    DOI: 10.1109/TED.2015.2466445

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  76. Impacts of surface roughness scattering on hole mobility in germanium nanowires

    Tanaka H., Suda J., Kimoto T.

    2015 Silicon Nanoelectronics Workshop, SNW 2015     2015.9

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    The hole mobility in rectangular cross-sectional germanium nanowires was calculated taking into account phonon and surface roughness scattering (SRS). SRS was modeled based on atomistic description of electronic states, and the impacts of SRS on hole mobility were analyzed.

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  77. Temperature dependence of forward characteristics for ultrahigh-voltage SiC p-i-n diodes with a long carrier lifetime

    Kaji Naoki, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 54 ( 9 )   2015.9

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    Forward characteristics of ultrahigh-voltage 4H-SiC p-i-n diodes having four different n--layer (i-layer) thicknesses from 48 to 198μm were investigated in the temperature range from room temperature to 573 K. After enhancement of carrier lifetimes in i-layers, nearly ideal forward characteristics (differential on-resistance = 1.1-5.5mΩcm2 at 100A/cm2) were obtained at room temperature. The forward voltage drop decreased with temperature, which is consistent with the temperature dependence of junction voltage. The differential on-resistance exhibited a slight increase at elevated temperatures, which can mainly be ascribed to the increase in substrate resistance.

    DOI: 10.7567/JJAP.54.098004

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  78. Impacts of orientation and cross-sectional shape on hole mobility of Si nanowire MOSFETs

    Fujihara H., Morioka N., Tanaka H., Suda J., Kimoto T.

    IMFEDK 2015 - 2015 International Meeting for Future of Electron Devices, Kansai     page: 106 - 107   2015.7

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    We fabricated 〈100〉, 〈110〉, 〈111〉, and 〈112〉 p-channel gate-all-around Si nanowire (SiNW) MOSFETs, cross sections of which are rectangles with various widths, and investigated the hole mobility of the SiNW MOSFETs using the double Lm method. Measured hole mobilities of SiNW MOSFETs were about 80-140 cm2/Vs at surface carrier density of 1 × 1013 cm-2. The dependences of the hole mobility on orientations and cross-sectional shapes of nanowires were analyzed. The orientation and geometry dependences can be explained by the band structures calculated by tight-binding approximation.

    DOI: 10.1109/IMFEDK.2015.7158572

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  79. Temperature dependence of current gain in 4H-SiC bipolar junction transistors

    Asada Satoshi, Okuda Takafumi, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 54 ( 4 )   2015.4

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    The temperature dependence of current gain from 140 to 460K in 4H-SiC bipolar junction transistors (SiC BJTs) was investigated. The current gain increased from 110 to 1200 with decreasing temperature from 460 to 200 K. The high current gain at the low temperature can be ascribed to the enhanced incomplete ionization of aluminum acceptors in the base layer, resulting in the increase in injection efficiency. However, when the temperature was further reduced from 200 to 140 K, the current gain decreased from 1200 to 515, which is caused by high injection condition in the base layer, because of a very low hole concentration below 200 K.

    DOI: 10.7567/JJAP.54.04DP13

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  80. Progress in ultrahigh-voltage SiC devices for future power infrastructure

    Kimoto T., Suda J., Yonezawa Y., Asano K., Fukuda K., Okumura H.

    Technical Digest - International Electron Devices Meeting, IEDM   Vol. 2015-February ( February ) page: 2.5.1 - 2.5.4   2015.2

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    UHV (> 15 kV) SiC PiN diodes and IGBTs with improved on-state performance are presented. Through enhancement of carrier lifetime and optimization of junction termination, a breakdown voltage over 26.9 kV and a differential on-resistance of 9.7 mΩcm2 were achieved for PiN diodes. Flip-type n-channel IGBTs with a chip size of 8 mm × 8 mm exhibited a breakdown voltage over 16 kV, and 6.5 kV - 60 A switching at 250°C was demonstrated.

    DOI: 10.1109/IEDM.2014.7046967

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  81. Interface Properties of 4H-SiC (11(2)over-bar0) and (1(1)over-bar00) MOS Structures Annealed in NO

    Nakazawa Seiya, Okuda Takafumi, Suda Jun, Nakamura Takashi, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 62 ( 2 ) page: 309 - 315   2015.2

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    Interface properties of 4H-SiC (1120) and (1100) metal-oxide-semiconductor (MOS) structures annealed in nitric oxide are characterized by conductance, high-low, and C-Ψs methods. Compared with 4H-SiC (0001) MOS structures, generation of very fast interface states by nitridation is much smaller in 4H-SiC (1120) and (1100). The effective mobility of planar MOSFETs fabricated on Al+-implanted p-body doped to 1×1017 cm-3 is 103 cm2/Vs on (1100), 92 cm2/Vs on (1120), and 20 cm2/Vs on (0001). The mobility-limiting factors are discussed on the basis of experimental results. The high channel mobilities for (1120) and (1100) MOSFETs can be correlated with the lower density of fast interface states generated by nitridation.

    DOI: 10.1109/TED.2014.2352117

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  82. Ultrahigh- Voltage SiC p-i-n Diodes With Improved Forward Characteristics

    Kaji Naoki, Niwa Hiroki, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 62 ( 2 ) page: 374 - 381   2015.2

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    Silicon carbide (SiC) p-i-n diodes having five different n--layer ( i-layer) thicknesses from 48 to 268 μm are fabricated. The forward characteristics of SiC p-i-n diodes are significantly improved by carrier-lifetime enhancement. After this improvement, the differential on-resistance is inversely proportional to the square root of current density for all the diodes with different thicknesses of n--layer. As a result, the forward current density-voltage characteristics can be approximately expressed by a parabolic function, as in the case of Si p-i-n diodes. Using a 268- μm-thick n--layer, the lifetime enhancement, and an improved space-modulated junction termination extension structure, a very high blocking voltage over 26.9 kV and low differential on-resistance of 9.7 mΩ·cm2 are achieved.

    DOI: 10.1109/TED.2014.2352279

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  83. High-temperature operation of electrostatically-excited single-crystalline 4H-SiC microcantilever resonators

    Sato K., Adachi K., Okamoto H., Yamaguchi H., Kimoto T., Suda J.

    Materials Science Forum   Vol. 821-823   page: 914 - 918   2015

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    We fabricated electrostatically-excited single-crystalline 4H-SiC microcantilever resonators with various thicknesses and lengths. Their resonant characteristics were investigated from room temperature (RT) up to 600°C. The resonant frequency of the cantilevers decreased with increasing temperature. From the results, the temperature dependence of Young’s modulus of single-crystalline 4H-SiC was obtained, i.e., 3% decrement with increasing temperature from RT to 600°C. The cantilevers with different thicknesses showed different temperature dependences of the quality factor. A 2-μm-thick cantilever exhibited a high quality factor (Q) (250,000) at RT and the Q decreased to 6,000 at 600°C, which can be explained by thermoelastic damping. On the other hand, a Q of a 0.45-μm-thick cantilever was still high (50,000) even at 600°C.

    DOI: 10.4028/www.scientific.net/MSF.821-823.914

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  84. Influence of conduction-type on thermal oxidation rate in SiC(0001) with various doping densities

    Kobayashi T., Suda J., Kimoto T.

    Materials Science Forum   Vol. 821-823   page: 456 - 459   2015

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    It was discovered that the oxidation rate for SiC depended on the conduction type. The oxidation was performed for SiC(0001) with nitrogen doping (n-type) in the range from 2×1016 cm-3 to 1×1019 cm-3, and aluminum doping (p-type) in the range from 2×1015 cm-3 to 1×1019 cm-3, exhibiting a clear dependence. For n-type SiC the oxide thickness increases for higher doping density, and for p-type the thickness decreases. Note that in the case of Si oxidation, there exists very little difference of oxidation rate between the conduction types in such low doping density, and the dependence is peculiar to SiC.

    DOI: 10.4028/www.scientific.net/MSF.821-823.456

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  85. Impacts of Surface Roughness Scattering on Hole Mobility in Germanium Nanowires

    Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    2015 SILICON NANOELECTRONICS WORKSHOP (SNW)     2015

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  86. Impacts of Orientation and Cross-sectional Shape on Hole Mobility of Si Nanowire MOSFETs

    Fujihara Hiroaki, Morioka Naoya, Tanaka Hajime, Suda Jun, Kimoto Tsunenobu

    2015 IEEE INTERNATIONAL MEETING FOR FUTURE OF ELECTRON DEVICES, KANSAI (IMFEDK)     2015

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  87. Geometrical and band-structure effects on phonon-limited hole mobility in rectangular cross-sectional germanium nanowires

    Tanaka H., Mori S., Morioka N., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 116 ( 23 )   2014.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of Applied Physics  

    We calculated the phonon-limited hole mobility in rectangular cross-sectional [001], [110], [111], and [112]-oriented germanium nanowires, and the hole transport characteristics were investigated. A tight-binding approximation was used for holes, and phonons were described by a valence force field model. Then, scattering probability of holes by phonons was calculated taking account of hole-phonon interaction atomistically, and the linearized Boltzmann's transport equation was solved to calculate the hole mobility at low longitudinal field. The dependence of the hole mobility on nanowire geometry was analyzed in terms of the valence band structure of germanium nanowires, and it was found that the dependence was qualitatively reproduced by considering an average effective mass and the density of states of holes. The calculation revealed that [110] germanium nanowires with large height along the [001] direction show high hole mobility. Germanium nanowires with this geometry are also expected to exhibit high electron mobility in our previous work, and thus they are promising for complementary metal-oxide-semiconductor (CMOS) applications.

    DOI: 10.1063/1.4904844

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  88. Impact of conduction type and doping density on thermal oxidation rate of SiC(0001)

    Kobayashi Takuma, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 7 ( 12 )   2014.12

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    We discovered that the oxidation rate of SiC depends on the conduction type. The oxidation was faster in n-type SiC than in p-type SiC. The linear rate constant B/A was higher for n-type SiC than for p-type SiC, which may be caused by the stability of Si vacancies. The parabolic rate constant B was nearly constant for n-type SiC, whereas it decreased dramatically for heavily doped p-type SiC. Secondary-ion mass spectrometry measurements revealed that a high density of Al atoms was incorporated in the oxide of p-type SiC, which may hinder the diffusion of O2 or COx.

    DOI: 10.7567/APEX.7.121301

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  89. Decay curve analyses in carrier lifetime measurements of p- and n-type 4H-SiC epilayers

    Hayashi Toshihiko, Okuda Takafumi, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 53 ( 11 )   2014.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics  

    The impacts of the ambipolar diffusion constant and surface recombination in carrier lifetime measurements of p- and n-type 4H-SiC epilayers are investigated in detail by comparing a numerical simulation based on a diffusion equation and the measurement of microwave photoconductance decay (μ-PCD) curves measured from 4H-SiC epilayers. The simulation reveals that the shapes of decay curves of excess carrier concentration in epilayers, which defines the effective carrier lifetime, are different between p- and n-type 4H-SiC under a low-level injection condition, even when the bulk lifetime and the surface recombination velocity are fixed to the same values for p- and n-type epilayers. In experiments, the shapes of the microwave photoconductance decay curves measured from p- and n-type 4H-SiC epilayers show a similar tendency to the simulation results under a low-level injection condition. This is attributed to the difference in the dependence of the ambipolar diffusion constant on the excess carrier concentration for p- and n-type 4H-SiC. The comparison of μ-PCD decay curves obtained from 50-μm-thick epilayers with different surface passivation indicates that the surface recombination velocity on the epilayer passivated with deposited SiO2 followed by NO annealing is about one order of magnitude lower than that of the epilayer passivated with the dry oxide.

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  90. Temperature dependence of optical absorption coefficient of 4H-and 6H-SiC from room temperature to 300 degrees C

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 53 ( 10 )   2014.10

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    Optical absorption coefficients of 4H- and 6H-SiC were measured at cutoff wavelengths from a value of 0 to 400-500cm-1 at various temperatures that is from room temperature to 300 °C. The redshift of the absorption edge with increasing temperature was observed. It is caused by a decrease in bandgap energy and a change in phonon occupation with increasing temperature. By considering TA-, LA-, and TO-mode phonon-assisted indirect transitions, the measured data are well fitted using a theoretical model. The obtained parameters are reported.

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  91. Formation mechanism of threading-dislocation array in AlN layers grown on 6H-SiC (0001) substrates with 3-bilayer-high surface steps

    Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS LETTERS   Vol. 105 ( 7 )   2014.8

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    We grew AlN layers on 6H-SiC (0001) substrates with three Si-C bilayer high (0.75nm) steps. In the AlN layers, most of the threading dislocations (TDs) were arranged in rows. The TD row consisted of arrays of a half-loop dislocation, which was formed by an AlN/SiC interfacial dislocation along the step edges of the SiC substrate surfaces and a TD pair at both ends. The configuration of the interfacial dislocation was highly relevant with two-dimensional AlN nuclei at the initial stage of growth. We concluded that the half-loop dislocation arrays were generated in the AlN nucleus coalescence over the SiC step edges. © 2014 AIP Publishing LLC.

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  92. Enhancement of carrier lifetime in lightly Al-doped p-type 4H-SiC epitaxial layers by combination of thermal oxidation and hydrogen annealing

    Okuda Takafumi, Miyazawa Tetsuya, Tsuchida Hidekazu, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 7 ( 8 )   2014.8

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    We investigated the enhancement of carrier lifetime in lightly Al-doped p-type 4H-SiC epilayers (NA ≃ 2 × 1014cm-3) by postgrowth processing. A carrier lifetime of 2.8 ìs in an as-grown epilayer is increased to 5.1 μs by carbon vacancy elimination, i.e., thermal oxidation at 1400 °C for 48 h. It reaches 10 μs by subsequent hydrogen annealing at 1000 °C for 10 min. The carrier lifetime in the as-grown epilayer is also increased to 4.0 μs by only hydrogen annealing. These results suggest that, in addition to carbon vacancy, there is another lifetime killer in p-type SiC, which cannot be eliminated by thermal oxidation but can be passivated by hydrogen annealing. © 2014 The Japan Society of Applied Physics.

    DOI: 10.7567/APEX.7.085501

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  93. Conduction-type dependence of thermal oxidation rate on SiC(0001)

    Kobayashi T., Suda J., Kimoto T.

    IMFEDK 2014 - 2014 International Meeting for Future of Electron Devices, Kansai     2014.7

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    The conduction-type dependent thermal oxidation rate in SiC was discovered. The oxidation was performed for SiC(0001) with nitrogen doping (n-type) in the range from 2.0×1016cm-3to 1.0×1019cm-3, and aluminum doping (p-type) in the range from 2.0×1015cm-3to 1.0×1019cm-3, exhibiting a clear dependence. For n-type SiC the oxide thickness increases for higher doping density, and for p-type the thickness decreases. Note that in the case of Si oxidation, there exists very little difference of oxidation rate between the conduction types in such low doping density, and the dependence is peculiar to SiC. The authors speculate the difference originates from the difference in carrier (electron/hole) density during the oxidation, which can reasonably explain the difference in the oxidation rate between Si and SiC.

    DOI: 10.1109/IMFEDK.2014.6867060

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  94. Phonon-Limited Electron Mobility in Rectangular Cross-Sectional Ge Nanowires

    Tanaka Hajime, Mori Seigo, Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 61 ( 6 ) page: 1993 - 1998   2014.6

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    The phonon-limited electron mobility in rectangular cross-sectional germanium (Ge) nanowires (NWs) with various orientations was theoretically investigated. The electronic states were calculated by a tight-binding model and the phononic states were calculated by a valence force field model. Then, transition probability was calculated by Fermi's golden rule, and Boltzmann's transport equation was solved for calculating lowfield mobility. The electron mobility of Ge NWs strongly depends on the wire orientations and cross-sectional shapes, and this dependence can be explained by the conduction band structure of Ge NWs. Among several geometries investigated in this paper, [110]-oriented NWs with wider width along [001] showed the highest electron mobility at low carrier concentration, and [112] NWs with wider width along [110] showed the highest electron mobility at high carrier concentration. This result indicates that these kinds of Ge NWs are suitable as n-channel material. © 1963-2012 IEEE.

    DOI: 10.1109/TED.2014.2318896

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  95. Quantitative comparison between Z(1/2) center and carbon vacancy in 4H-SiC

    Kawahara Koutarou, Xuan Thang Trinh, Nguyen Tien Son, Janzen Erik, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 115 ( 14 )   2014.4

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    In this study, to reveal the origin of the Z1/2 center, a lifetime killer in n-type 4H-SiC, the concentrations of the Z1/2 center and point defects are compared in the same samples, using deep level transient spectroscopy (DLTS) and electron paramagnetic resonance (EPR). The Z1/2 concentration in the samples is varied by irradiation with 250 keV electrons with various fluences. The concentration of a single carbon vacancy (VC) measured by EPR under light illumination can well be explained with the Z1/2 concentration derived from C-V and DLTS irrespective of the doping concentration and the electron fluence, indicating that the Z1/2 center originates from a single VC. © 2014 AIP Publishing LLC.

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  96. 4H-SiC MISFETs With 4H-AlN Gate Insulator Isopolytypically Grown on 4H-SiC (11(2)over-bar0)

    Horita Masahiro, Noborio Masato, Kimoto Tsunenobu, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 35 ( 3 ) page: 339 - 341   2014.3

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    4H silicon carbide (4H-SiC) metal-insulator-semiconductor field-effect transistors (MISFETs) with 4H aluminum nitride (4H-AlN) gate insulators have been demonstrated. The 4H-AlN layers are isopolytypically grown on 4H-SiC (1120) by molecular-beam epitaxy. Gate controlled transistor operation was realized using the AlN/SiC MISFETs. The MISFETs exhibit a low gate leakage current (<10-10~A) and normally on characteristics with a threshold voltage of approximately-10~V and a field-effect mobility of 0.5 cm 2V-1s-1. Capacitance-voltage measurements of AlN/SiC MIS capacitors reveal a large negative flat band shift of-10.9~V, which is consistent with the normally on characteristics. © 2014 IEEE.

    DOI: 10.1109/LED.2014.2299557

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  97. Effect of ultrathin AIN spacer on electronic properties of GaN/SiC heterojunction bipolar transistors

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 53 ( 3 )   2014.3

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    GaN/SiC heterojunction bipolar transistors (HBTs) with an ultrathin AlN spacer layer at the n-GaN/p-SiC emitter junction are proposed for the control of the electronic properties of GaN/SiC heterojunctions. The insertion of an AlN spacer is found to be promising in terms of improving electron injection efficiency owing to the reduced potential barrier (0.54 eV) to electron injection and reduced recombination via interface traps. We also investigated the effect of pre-irradiation of active nitrogen atoms (N*) prior to AlN growth for the control of the electronic properties of GaN/ AlN/SiC heterojunctions. We found that the potential barrier was further reduced to 0.46 eV by N* pre-irradiation. The HBT structure was successfully fabricated using our newly developed process featuring ion implantation and Pd ohmic contacts to obtain a low contact resistivity to a p-SiC base at a temperature as low as 600 °C. A fabricated HBT without an AlN layer showed a low current gain (α ∼ 0.001), whereas the GaN/ AlN/SiC HBT showed improved current gains of 0.1 in the case of using a 1-nm-thick AlN spacer without N* pre-irradiation and 0.2 in the case of using a 2-nm-thick AlN spacer with N* pre-irradiation. © 2014 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.53.034101

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  98. Quantum-confinement effects on conduction band structure of rectangular cross-sectional GaAs nanowires

    Tanaka H., Morioka N., Mori S., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 115 ( 5 )   2014.2

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    The conduction band structure and electron effective mass of GaAs nanowires with various cross-sectional shapes and orientations were calculated by two methods, a tight-binding method and an effective mass equation taking the bulk full-band structure into account. The effective mass of nanowires increases as the cross-sectional size decreases, and this increase in effective mass depends on the orientations and substrate faces of nanowires. Among [001], [110], and [111]-oriented rectangular cross-sectional GaAs nanowires, [110]-oriented nanowires with wider width along the [001] direction showed the lightest effective mass. This dependence originates from the anisotropy of the Γ valley of bulk GaAs. The relationship between effective mass and bulk band structure is discussed. © 2014 AIP Publishing LLC.

    DOI: 10.1063/1.4864490

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  99. Identification of dislocations in 4H-SiC epitaxial layers and substrates using photoluminescence imaging

    Kawahara Chihiro, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 53 ( 2 )   2014.2

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    Dislocations in n- and p-type substrates as well as in epitaxial layers (epilayers) were clearly identified using a photoluminescence (PL) imaging technique. Dislocations in epilayers show large/small bright spots or lines in infrared PL images, which correspond to threading screw/edge dislocations (TSDs/TEDs) or basal plane dislocations (BPDs), respectively. In contrast, dislocations in substrates exhibit large/small dark spots or dark lines in infrared PL images, corresponding to TSDs/TEDs or BPDs, respectively. These different features (bright/dark contrast) of dislocations may originate from the different densities of point defects or impurities. © 2014 The Japan Society of Applied Physics.

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  100. Etching-limiting process and origin of loading effects in silicon etching with hydrogen chloride gas

    Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 53 ( 1 )   2014.1

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    The etching-limiting step in slow Si etching with HCl/H2 at atmospheric pressure was investigated. The etching was performed at a low etching rate below 10nm/min in the temperature range of 1000-1100 °C. In the case of bare Si etching, it was confirmed that the etching rate showed little temperature dependence and was proportional to the equilibrium pressure of the etching by-product SiCl2 calculated by thermochemical analysis. In addition, the etching rates of Si(100) and (110) faces were almost the same. These results indicate that SiCl2 diffusion in the gas phase is the rate-limiting step. In the etching of the Si surface with SiO2 mask patterns, a strong loading effect (mask/opening pattern dependence of the etching rate) was observed. The simulation of the diffusion of gas species immediately above the Si surface revealed that the loading effect was attributed to the pattern-dependent diffusion of SiCl2.© 2014 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.53.016502

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  101. Conduction-Type Dependence of Thermal Oxidation Rate on SiC(0001)

    Kobayashi Takuma, Suda Jun, Kimoto Tsunenobu

    2014 IEEE INTERNATIONAL MEETING FOR FUTURE OF ELECTRON DEVICES, KANSAI (IMFEDK)     2014

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  102. Fabrication of electrostatically actuated 4H-SiC microcantilever resonators by using n/p/n epitaxial structures and doping-selective electrochemical etching

    Sato K., Adachi K., Okamoto H., Yamaguchi H., Kimoto T., Suda J.

    Materials Science Forum   Vol. 778-780   page: 780 - 783   2014

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    We fabricated electrostatically actuated single-crystalline 4H-SiC microcantilever resonators. To realize a narrow gap between cantilevers and substrate, we etched a thin p-type SiC layer in n/p/n multilayer structure by doping-selective electrochemical etching. The resonant characteristics of the fabricated 4H-SiC microcantilevers were investigated under a vacuum condition. Electrostatic actuation of microcantilevers was successfully performed by applying 10 mVrms ac voltage with 20 mV dc bias. The quality factor of 4H-SiC microcantilevers was above 100,000, which is about ten times higher than the quality factor of Si cantilevers with the same structure. Resonant characteristics were almost identical for mechanical actuation and electrostatic actuation. © (2014) Trans Tech Publications, Switzerland.

    DOI: 10.4028/www.scientific.net/MSF.778-780.780

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  103. Identification of the negative carbon vacancy at quasi-cubic site in 4H-SIC by EPR and theoretical calculations

    Trinh X.T., Szász K., Hornos T., Kawahara K., Suda J., Kimoto T., Gali A., Janzén E., Son N.T.

    Materials Science Forum   Vol. 778-780   page: 285 - 288   2014

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    In freestanding n-type 4H-SiC epilayers irradiated with low-energy (250 keV) electrons at room temperature, the electron paramagnetic resonance (EPR) spectrum of the negative carbon vacancy at the hexagonal site, V-C(h), and a new signal were observed. From the similarity in defect formation and the spin-Hamiltonian parameters of the two defects, the new center is suggested to be the negative C vacancy at the quasi-cubic site, V-C (k). The identification is further supported by hyperfine calculations. © (2014) Trans Tech Publications, Switzerland.

    DOI: 10.4028/www.scientific.net/MSF.778-780.285

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  104. Ion implantation technology in SiC for power device applications

    Kimoto T., Kawahara K., Niwa H., Kaji N., Suda J.

    2014 International Workshop on Junction Technology, IWJT 2014     page: 1 - 6   2014

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    Silicon carbide (SiC) is a newly-emerging wide bandgap semiconductor, by which high-voltage, low-loss power devices can be realized owing to its superior properties. Because of its strong bonding energy and thermal stability, however, special cares must be paid to form high-quality junctions by ion implantation. This paper reviews present status and remaining issues of ion implantation technology in SiC. Requirements of hot implantation and high-temperature annealing are discussed in terms of electrical activation, defect generation, and junction characteristics. Furthermore, recent progress in junction termination for high-voltage SiC devices by using ion implantation is described. © 2014 IEEE.

    DOI: 10.1109/IWJT.2014.6842018

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  105. Ion Implantation Technology in SiC for Power Device Applications

    Kimoto Tsunenobu, Kawahara Koutaro, Niwa Hiroki, Kaji Naoki, Suda Jun

    2014 INTERNATIONAL WORKSHOP ON JUNCTION TECHNOLOGY (IWJT)     page: 1 - 6   2014

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  106. Orientation and Size Effects on Phonon-limited Hole Mobility in Rectangular Cross-sectional Germanium Nanowires

    Tanaka Hajime, Mori Seigo, Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    2014 IEEE SILICON NANOELECTRONICS WORKSHOP (SNW)     2014

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  107. 100 mm diameter mono-crystalline 4H-SiC/polycrystalline-SiC bonded wafers fabricated by SAB for power device

    Yagi K., Hatta N., Sakata T., Minami A., Kawahara T., Uchida H., Imaoka K., Okuda T., Suda J., Kurashima Y., Takagi H.

    Proceedings of 2014 4th IEEE International Workshop on Low Temperature Bonding for 3D Integration, LTB-3D 2014     2014

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    We have developed 100mm in diameter 4H-SiC/poly-SiC bonded wafer by SAB method. The SiC bonded wafer demonstrated an excellent thermal stability against device processing temperature. SBDs fabricated on the SiC bonded wafer exhibited good I-V characteristics. These results suggest that it is a promising alternative wafer for SiC power device. © 2014 IEEE.

    DOI: 10.1109/LTB-3D.2014.6886195

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  108. 100 mm diameter mono-crystalline 4H-SiC/polycrystalline-SiC bonded wafers fabricated by SAB for power device

    Yagi Kuniaki, Hatta Naoki, Sakata Toyokazu, Minami Akiyuki, Kawahara Takamitsu, Uchida Hidetsugu, Imaoka Kou, Okuda Takafumi, Suda Jun, Kurashima Yuichi, Takagi Hideki

    2014 4TH IEEE INTERNATIONAL WORKSHOP ON LOW TEMPERATURE BONDING FOR 3D INTEGRATION (LTB-3D)     page: 56 - 56   2014

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  109. Progress in Ultrahigh-Voltage SiC Devices for Future Power Infrastructure

    Kimoto T., Suda J., Yonezawa Y., Asano K., Fukuda K., Okumura H.

    2014 IEEE INTERNATIONAL ELECTRON DEVICES MEETING (IEDM)     2014

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  110. Negative-U carbon vacancy in 4H-SiC: Assessment of charge correction schemes and identification of the negative carbon vacancy at the quasicubic site

    Trinh X. T., Szasz K., Hornos T., Kawahara K., Suda J., Kimoto T., Gali A., Janzen E., Son N. T.

    PHYSICAL REVIEW B   Vol. 88 ( 23 )   2013.12

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    The carbon vacancy (VC) has been suggested by different studies to be involved in the Z1/Z2 defect-a carrier lifetime killer in SiC. However, the correlation between the Z1/Z2 deep level with VC is not possible since only the negative carbon vacancy (VC-) at the hexagonal site, VC-(h), with unclear negative-U behaviors was identified by electron paramagnetic resonance (EPR). Using freestanding n-type 4H-SiC epilayers irradiated with low energy (250 keV) electrons at room temperature to introduce mainly VC and defects in the C sublattice, we observed the strong EPR signals of VC-(h) and another S = 1/2 center. Electron paramagnetic resonance experiments show a negative-U behavior of the two centers and their similar symmetry lowering from C3v to C1h at low temperatures. Comparing the 29Si and 13C ligand hyperfine constants observed by EPR and first principles calculations, the new center is identified as VC-(k). The negative-U behavior is further confirmed by large scale density functional theory supercell calculations using different charge correction schemes. The results support the identification of the lifetime limiting Z1/Z2 defect to be related to acceptor states of the carbon vacancy. © 2013 American Physical Society.

    DOI: 10.1103/PhysRevB.88.235209

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  111. Growth, Electrical Characterization, and Electroluminescence of GaN/SiC Heterojunction Diodes and Bipolar Transistors Fabricated on SiC Off-Axis Substrates

    Miyake Hiroki, Amari Koichi, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 52 ( 12 )   2013.12

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    The growth, electrical characterization, and electroluminescence (EL) of GaN/SiC heterojunction bipolar transistors (HBTs) are presented. GaN grown on off-axis SiC by molecular beam epitaxy showed step bunching owing to the large off-angle of SiC substrates, which contributed to the annihilation of edge dislocations. We investigated the impact of base doping concentration and SiC polytype (4H and 6H) on the characteristics of GaN/SiC heterojunction diodes. By utilizing a reduced doping concentration of 1 × 1018 cm -3 instead of 1 × 1019 cm-3, we suppressed the tunneling current via interface traps, resulting in an improved rectifying behavior in the diodes. Capacitance-voltage (C-V) and EL characteristics revealed that the band lineup of GaN/SiC is of type II, and 6H-SiC is better for electron injection. In accordance with diode characteristics, the fabricated GaN/SiC HBTs showed an improved common-base current gain of 0.03 by employing a reduced base doping concentration of 1 × 1018 cm-3 and 6H-SiC, whereas a current gain below 1 × 10-4 was obtained in the HBTs with a base doping concentration of 1 × 1019 cm-3. © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.52.124102

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  112. Improvement of Carrier Lifetimes in Highly Al-Doped p-Type 4H-SiC Epitaxial Layers by Hydrogen Passivation

    Okuda Takafumi, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 6 ( 12 )   2013.12

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    Carrier lifetimes in a highly Al-doped p-type epilayer (NA = 1 × 1018 cm-3) are investigated by differential microwave photoconductance decay (μ-PCD) measurements. A carrier lifetime of 310 ns in the as-grown p-type epilayer decreases to 90 ns by thermal treatment in Ar, O2, or N2 atmospheres (>700 °C), and recovers to 300 ns by H2 annealing (>750 °C). Hydrogen is detected at a concentration of (2-3) × 1015 cm-3 in the H2-annealed epilayer. These results suggest that a lifetime killer exists in the p-type epilayer, limiting the carrier lifetime to 90 ns and is passivated by hydrogen annealing, resulting in the improved carrier lifetime of 300 ns. © 2013 The Japan Society of Applied Physics.

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  113. Size and geometric effects on conduction band structure of GaAs nanowires

    Tanaka H., Morioka N., Mori S., Suda J., Kimoto T.

    IMFEDK 2013 - 2013 International Meeting for Future of Electron Devices, Kansai     page: 118 - 119   2013.10

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    The conduction band structure of GaAs nanowires with various cross-sectional shapes and orientations was calculated by a tight-binding model and an effective mass equation taking the bulk full-band structure into account. The effective mass of nanowires increases as the cross-sectional size decreases. However, the amount of the increase in mass is strongly dependent on the wire orientations and substrate faces of nanowires, which originates from the anisotropy of Γ valley of bulk GaAs. © 2013 IEEE.

    DOI: 10.1109/IMFEDK.2013.6602267

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  114. AlGaN/SiC Heterojunction Bipolar Transistors Featuring AlN/GaN Short-Period Superlattice Emitter

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 60 ( 9 ) page: 2768 - 2775   2013.9

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    Growth and electrical characterization of aluminum gallium nitride (AlGaN)/SiC heterojunction bipolar transistors (HBTs) featuring AlN/GaN short-period superlattice as a quasi-AlGaN emitter are presented. The AlN/GaN superlattice emitter was grown by molecular beam epitaxy on off-axis SiC, which showed adequate structural and electronic properties as the emitter of the HBTs. We investigated the impact of Al composition in the emitter on the transport characteristics and current gain of the HBTs. Using Al composition of over 0.5, we achieved type-I band alignment in AlGaN/SiC, and suppressed the tunneling current via interface traps, resulting in an improved current gain of up to 2.7. Toward further improvement of current gain, we also investigated the effect of n-SiC spacer between n-AlGaN and p-SiC and p-SiC base width. Using 200-nm-thick n-SiC spacer and 250-nm-thick p-SiC base layer, we achieved an improved current gain of 13 owing to the reduced interface and bulk recombination. © 1963-2012 IEEE.

    DOI: 10.1109/TED.2013.2273499

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  115. Single-crystalline 4H-SiC micro cantilevers with a high quality factor

    Adachi Kohei, Watanabe Naoki, Okamoto Hajime, Yamaguchi Hiroshi, Kimoto Tsunenobu, Suda Jun

    SENSORS AND ACTUATORS A-PHYSICAL   Vol. 197   page: 122 - 125   2013.8

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    Single-crystalline 4H-SiC micro cantilevers were fabricated by doping-type selective electrochemical etching of 4H-SiC. Using this method, n-type 4H-SiC cantilevers were fabricated on a p-type 4H-SiC substrate, and resonance characteristics of the fabricated 4H-SiC cantilevers were investigated under a vacuum condition. The resonant frequencies agreed very well with the results of numerical simulations. The maximum quality factor in first-mode resonance of the 4H-SiC cantilevers was 230,000. This is 10 times higher than the quality factor of conventional 3C-SiC cantilevers fabricated on an Si substrate. © 2013 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.sna.2013.04.014

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  116. Coherent Growth of AlN/GaN Short-Period Superlattice with Average GaN Mole Fraction of up to 20% on 6H-SiC(0001) Substrates by Plasma-Assisted Molecular-Beam Epitaxy

    Kaneko Mitsuaki, Kikuchi Ryosuke, Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 52 ( 8 )   2013.8

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    To obtain a high-crystalline-quality AlN/GaN short-period superlattice with higher average GaN mole fraction, the effects of the thicknesses of AlN barrier and GaN well layers on the superlattice growth were investigated. Coherent growth with an average GaN mole fraction of 20% was realized by reducing the AlN barrier layer thickness to 8 bilayers (BL) while keeping the GaN well layer thickness at 2 BL. Further reduction in the AlN barrier layer thickness resulted in lattice relaxation and degradation of the crystalline quality. Grown layers with various well and barrier thicknesses were investigated by transmission electron microscopy, X-ray diffraction, and atomic force microscopy. © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.52.08JE21

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  117. Ultrahigh-Voltage SiC PiN Diodes with an Improved Junction Termination Extension Structure and Enhanced Carrier Lifetime

    Kaji Naoki, Niwa Hiroki, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 52 ( 7 )   2013.7

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    Ultrahigh-voltage SiC PiN diodes with an improved junction termination extension (JTE) structure and improved forward characteristics are presented in this paper. An improved space-modulated JTE (SM-JTE) structure was designed by device simulation, and a breakdown voltage of over 17 kV was obtained in a wider range of JTE dose with the improved SM-JTE. In addition, a lifetime enhancement process (thermal oxidation) was performed to improve the forward characteristics. The on-resistance of the SiC PiN diodes with the lifetime enhancement process was reduced to 13m°Cm2 at 150°C compared with that of the SiC PiN diodes with the conventional process (32m°Cm2). © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.52.070204

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  118. Optical Properties of Highly Strained AlN Coherently Grown on 6H-SiC(0001)

    Kaneko Mitsuaki, Okumura Hironori, Ishii Ryota, Funato Mitsuru, Kawakami Yoichi, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 6 ( 6 )   2013.6

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    The optical properties of wurtzite AlN under large compressive strain are investigated by photoluminescence and optical reflectivity measurements with two different geometries. The AlN layer was coherently grown on 6H-SiC(0001), resulting in strains of ∈xx = ∈yy = -9.6 × 10-3 and ∈zz = 5.12 × 10-3, as confirmed by high-resolution X-ray diffraction. Free exciton transitions were clearly observed. The transition energy of A free exciton (with Γ1 symmetry) was estimated to be 6.246 eV at 10 K. The large energy shift of the free exciton transition with respect to the transition in unstrained AlN was well explained by the reported deformation potentials of AlN. © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/APEX.6.062604

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  119. Deep Levels Generated by Thermal Oxidation in n-Type 4H-SiC

    Kawahara Koutarou, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 6 ( 5 )   2013.5

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    The Z1/2 center (EC - 0:67 eV), which is a lifetime killer in n-type 4H-SiC epilayers, is reduced by thermal oxidation. The oxidation, however, simultaneously generates other deep levels: ON1 (E C - 0:84 eV) and ON2 (EC - 1:1 eV) centers. From the behaviors (generation condition, thermal stability, and change in the depth profiles) of the ON1 and ON2 centers in samples (i) oxidized in O2, (ii) implanted with C+ or Si+ atoms, and (iii) oxidized in N2O (or NO), we suggest that these defects may originate from the same defect in different charge states, related to both carbon interstitials and N atoms. © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/APEX.6.051301

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  120. Investigation on origin of Z(1/2) center in SiC by deep level transient spectroscopy and electron paramagnetic resonance

    Kawahara Koutarou, Xuan Thang Trinh, Nguyen Tien Son, Janzen Erik, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 102 ( 11 )   2013.3

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    The Z1/2 center in n-type 4H-SiC epilayers-a dominant deep level limiting the carrier lifetime-has been investigated. Using capacitance versus voltage (C-V) measurements and deep level transient spectroscopy (DLTS), we show that the Z1/2 center is responsible for the carrier compensation in n-type 4H-SiC epilayers irradiated by low-energy (250 keV) electrons. The concentration of the Z1/2 defect obtained by C-V and DLTS correlates well with that of the carbon vacancy (VC) determined by electron paramagnetic resonance, suggesting that the Z1/2 deep level originates from VC. © 2013 American Institute of Physics.

    DOI: 10.1063/1.4796141

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  121. Effects of Nitridation on 4H-SiC MOSFETs Fabricated on Various Crystal Faces

    Nanen Yuichiro, Kato Muneharu, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 60 ( 3 ) page: 1260 - 1262   2013.3

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    Effects of nitric oxide (NO) and nitrous oxide (N2O) annealing on 4H-SiCmetal-oxide-semiconductor field-effect transistors (MOSFETs) fabricated on the (0001), (000-1), and (11-20) faces are investigated. MOSFETs on (11-20) exhibited high channel mobility (108 cm2/V s) compared to those on (0001) (29-37 cm2/V s) and (000-1) (39-46 cm2/V s). The MOSFET characteristics are discussed in terms of oxidation taking place during the nitridation annealing and crystal faces.

    DOI: 10.1109/TED.2012.2236333

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  122. Orientation and Shape Effects on Ballistic Transport Properties in Gate-All-Around Rectangular Germanium Nanowire nFETs

    Mori Seigo, Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 60 ( 3 ) page: 944 - 950   2013.3

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    The electron transport properties of square and rectangular cross-sectional germanium nanowire (GeNW) field-effect transistors (FETs) with [001], [110], [111], and [112] crystal orientations are investigated. The electronic states of GeNWs are calculated by using an sp^{3}d^{5}s\ast tight-binding model coupled to a Poisson equation self-consistently. A semiclassical ballistic FET model is used to evaluate the electron transport characteristics. For the square cross section, electron injection velocity dominates the drive current in GeNW FETs because the inversion electron density in the GeNW channels is mainly determined by the capacitance of the gate insulator, and a [110] GeNW FET achieves the highest drive current of all the orientations. In the case of rectangular cross section, the electron density in GeNWs is dependent on their orientations and cross-sectional geometries due to the small quantum capacitance, and the difference of the density of states of GeNWs significantly affects the drive current. A [112] GeNW FET on a (\hbox{1}\bar{\hbox{1}}\hbox{0} ) face exhibits the highest injection velocity of all the calculated FETs but low drive current because of its insufficient density of states. As a result, a [110] GeNW FET on a (001) face, which has both large density of states and high injection velocity, achieves the highest drive current. © 1963-2012 IEEE.

    DOI: 10.1109/TED.2013.2237779

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  123. Deep levels generated by thermal oxidation in p-type 4H-SiC

    Kawahara Koutarou, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 113 ( 3 )   2013.1

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    Thermal oxidation is an effective method to reduce deep levels, especially the Z1/2-center (EC - 0.67 eV), which strongly suppresses carrier lifetimes in n-type 4H-SiC epilayers. The oxidation, however, simultaneously generates other deep levels, HK0 (EV + 0.79 eV) and HK2 (EV + 0.98 eV) centers, within the lower half of the bandgap of SiC, where the HK0 center is a dominant deep level with a concentration of about 1 × 1013 cm-3 after oxidation. By comparing deep levels observed in three sets of p-type 4H-SiC: oxidized, electron-irradiated, and C+- or Si+-implanted samples, we find that the HK0 and HK2 centers are complexes including carbon interstitials such as the di-carbon interstitial or di-carbon antisite. Other defects observed in p-type 4H-SiC after electron irradiation or after C+/Si+ implantation are also studied. © 2013 American Institute of Physics.

    DOI: 10.1063/1.4776240

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  124. Long Photoconductivity Decay Characteristics in p-Type 4H-SiC Bulk Crystals

    Okuda Takafumi, Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 52 ( 1 )   2013.1

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    We investigated the photoconductivity decay characteristics of p-type 4H-SiC bulk crystals by differential microwave photoconductance decay (μ-PCD) measurements using a 349-nm laser as an excitation source. The decay time at room temperature was 2600 μs, which is much longer than that of n-type 4H-SiC bulk crystals (40 ns). Decay time decreased with increasing temperature, resulting in 120 μs at 250 °C, and the activation energy of decay time was determined to be 140 ± 10 meV. Long decay characteristics were also observed by below-band-gap excitation at 523 nm. © 2013 The Japan Society of Applied Physics.

    DOI: 10.7567/JJAP.52.010202

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  125. Junction technology in SiC for high-voltage power devices

    Kimoto T., Kawahara K., Niwa H., Okuda T., Suda J.

    Extended Abstracts of the 13th International Workshop on Junction Technology 2013, IWJT 2013     page: 54 - 57   2013

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    In electric power conversion systems of power infrastructures, electric vehicles, and power supplies, Si-based power semiconductor devices are employed as a key hardware. Reduction of power dissipation in the conversion systems is strongly required for energy saving. In particular, ultrahigh-voltage power converters with high efficiency are essential to realize a stable and highly efficient electric power network by optimizing the use of solar power and wind-generated power in the future. The efficiency of power converters/inverters strongly relies on the performance of power semiconductor devices employed in the power electronic systems. Silicon carbide (SiC) is a newly-emerging wide bandgap semiconductor, by which high-voltage, low-loss power devices can be realized owing to its superior properties [1-3]. The major features of SiC power devices include high-voltage blocking capability, low on-state resistance, fast switching speed, and high-temperature operation. © 2013 IEEE.

    DOI: 10.1109/IWJT.2013.6644492

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  126. Size and Geometric Effects on Conduction Band Structure of GaAs Nanowires

    Tanaka Hajime, Morioka Naoya, Mori Seigo, Suda Jun, Kimoto Tsunenobu

    2013 IEEE INTERNATIONAL MEETING FOR FUTURE OF ELECTRON DEVICES, KANSAI (IMFEDK2013)     2013

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  127. 21-kV SiC BJTs With Space-Modulated Junction Termination Extension

    Miyake Hiroki, Okuda Takafumi, Niwa Hiroki, Kimoto Tsunenobu, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 33 ( 11 ) page: 1598 - 1600   2012.11

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    We report here 20-kV-class small-area (0.035 mm 2 ) 4H-SiC bipolar junction transistors. We implemented edge termination techniques featuring two-zone junction termination extension and space-modulated rings. on-state characteristics showed a current gain of 63 and a specific on-resistance of 321 mΩ cm 2, which is slightly below the SiC unipolar limit. We achieved the open-base blocking voltage of 21 kV at a leakage current of 0.1 mA/cm 2 , which is the highest blocking voltage among any semiconductor switching devices. © 2012 IEEE.

    DOI: 10.1109/LED.2012.2215004

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  128. Thermo-Optic Coefficients of 4H-SiC, GaN, and AIN for Ultraviolet to Infrared Regions up to 500 degrees C

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 51 ( 11 )   2012.11

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    The temperature dependence of the refractive indices of 4H-SiC, GaN, and AlN were determined in a wavelength range from the near band edge (392 nm for 4H-SiC, 367nm for GaN, and 217nm for AlN) to infrared (1700 nm) and a temperature range from room temperature to 500 °C. Optical interference measurements with vertical incidence along a c-axis configuration were employed to precisely evaluate ordinary refractive indices. Near the band-edge region, the temperature dependence of the refractive index mainly originates from the temperature change of the bandgap. At 450 nm, the thermo-optic coefficients of 4H-SiC, GaN, and AlN were measured to be 7:8 × 10 -5, 1:6 × 10 -4, and 3:6 × 10 -5 K -1, respectively. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.51.112101

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  129. Negative-U System of Carbon Vacancy in 4H-SiC

    Son N. T., Trinh X. T., Lovlie L. S., Svensson B. G., Kawahara K., Suda J., Kimoto T., Umeda T., Isoya J., Makino T., Ohshima T., Janzen E.

    PHYSICAL REVIEW LETTERS   Vol. 109 ( 18 )   2012.10

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    Using electron paramagnetic resonance (EPR), energy levels of the carbon vacancy (V C) in 4H-SiC and its negative-U properties have been determined. Combining EPR and deep-level transient spectroscopy we show that the two most common defects in as-grown 4H-SiC-the Z 1/2 lifetime-limiting defect and the EH 7 deep defect-are related to the double acceptor (2-|0) and single donor (0|+) levels of V C, respectively. © 2012 American Physical Society.

    DOI: 10.1103/PhysRevLett.109.187603

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  130. Orientation and size effects on ballistic electron transport properties in gate-all-around rectangular germanium nanowire FETs

    Mori S., Morioka N., Suda J., Kimoto T.

    2012 IEEE Silicon Nanoelectronics Workshop, SNW 2012     2012.10

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    We calculated the conduction band structure of GeNWs by a tight-binding model and obtained the fundamental understanding of electron transport characteristics in [001], [110], [111], and [112] GeNW FETs. The simulation of ballistic electron transport revealed that [110] GeNW FETs on the (001) face achieve high drive current as well as high injection velocity, being the best choice for n-channel FETs. © 2012 IEEE.

    DOI: 10.1109/SNW.2012.6243360

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  131. Breakdown Characteristics of 15-kV-Class 4H-SiC PiN Diodes With Various Junction Termination Structures

    Niwa Hiroki, Feng Gan, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 59 ( 10 ) page: 2748 - 2752   2012.10

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    15-kV-class 4H-SiC PiN diodes with various junction termination structures have been experimentally investigated. Employment of the space-modulated junction termination extension (SM-JTE) and the two-zone JTE have realized a breakdown voltage over 15 kV, corresponding to 93% of the parallel-plane breakdown voltage. The window of the implanted JTE dose to achieve the ultrahigh voltage has been enlarged, which indicates the robustness to the deviation of effective JTE dose. From the comparison of the experimental JTE-dose dependence of breakdown voltage with the numerical device simulation, a shift toward the heavier JTE-dose region was observed. To explain the phenomenon, effects of the charges at the SiO 2/SiC interface are discussed. © 2012 IEEE.

    DOI: 10.1109/TED.2012.2210044

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  132. Carrier Recombination in n-Type 4H-SiC Epilayers with Long Carrier Lifetimes

    Ichikawa Shuhei, Kawahara Koutarou, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 5 ( 10 )   2012.10

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    A longest carrier lifetime of 33.2 μs was achieved by eliminating the Z 1/2 center via thermal oxidation at 1400 °C for 48 h and subsequent surface passivation with a nitrided oxide on a 220-μm-thick n-type 4H-SiC epilayer. By deep-level elimination, photoluminescence (PL) in the infrared region (wavelength: 700-950 nm) was remarkably enhanced at locations of threading dislocations. A threading screw dislocation exhibited much stronger infrared PL than a threading edge dislocation. The present results indicate that carrier recombination at extended defects becomes pronounced through the elimination of the Z 1/2 center in the epilayers. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.5.101301

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  133. Over-700-nm Critical Thickness of AlN Grown on 6H-SiC(0001) by Molecular Beam Epitaxy

    Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 5 ( 10 )   2012.10

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    We report on the critical thickness of AlN on SiC(0001). AlN was directly grown on 6H-SiC(0001) at 650 °C by rf-plasma-assisted molecular beam epitaxy. The growth layer had a relatively low threading dislocation density of 4 × 10 8-4 × 10 9 cm -2. Although the critical thickness of AlN on SiC(0001) is estimated to be 3.5nm using a Matthews-Blakeslee model, the critical thickness in our experiment was over 700 nm. Low dislocation density, a layer-by-layer growth mode, and low growth temperature may contribute to such a large critical thickness. Sharp and intense free exciton emission was observed in low-temperature PL measurements of the AlN layer. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.5.105502

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  134. Enhancement and control of carrier lifetimes in p-type 4H-SiC epilayers

    Hayashi T., Asano K., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 112 ( 6 )   2012.9

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    Enhancement and control of carrier lifetimes in p-type 4H-SiC have been investigated. In this study, thermal oxidation and carbon ion implantation methods, both of which are effective for lifetime enhancement in n-type SiC, were attempted on 147-μm thick p-type 4H-SiC epilayers. Effects of surface passivation on carrier lifetimes were also investigated. The carrier lifetimes in p-type SiC could be enhanced from 0.9 μs (as-grown) to 2.6 μs by either thermal oxidation or carbon implantation and subsequent Ar annealing, although the improvement effect for the p-type epilayers was smaller than that for the n-type epilayers. After the lifetime enhancement, electron irradiation was performed to control the carrier lifetime. The distribution of carrier lifetimes in each irradiated region was rather uniform, along with successful lifetime control in the p-type epilayer in the range from 0.1 to 1.6 μs. © 2012 American Institute of Physics.

    DOI: 10.1063/1.4748315

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  135. 4H-SiC pn Photodiodes with Temperature-Independent Photoresponse up to 300 degrees C

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 5 ( 9 )   2012.9

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    4H-SiC pn photodiodes were fabricated and the temperature dependence of the photoresponse was measured for various wavelengths (280-365 nm) as a function of reverse-bias voltage. A temperature-independent photoresponse was obtained at 280nm illumination from room temperature to 300 °C under zero-bias condition. By applying reverse-bias voltage up to 150 V, the wavelength of the temperature-independent photoresponse was varied from 280 to 300 nm. The temperature-independent photoresponse was explained by the temperature dependence of optical absorption coefficient together with surface recombination effect. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.5.094101

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  136. Breakdown characteristics of 12-20 kV-class 4H-SiC PiN diodes with improved junction termination structures

    Niwa H., Feng G., Suda J., Kimoto T.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs     page: 381 - 384   2012.8

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    Ultrahigh-voltage 4H-SiC PiN diodes with improved junction termination extension (JTE) structures have been investigated. Breakdown characteristics of 4H-SiC PiN diodes with conventional single-zone JTE was shown to be severely affected by the charge near the SiO 2/SiC interface from experiment and device simulation. Taking the effect of the interface charge into account, and by using "Space-Modulated" JTE structure with a wide optimum JTE-dose window to tolerate the impact of interface charge, we achieved a breakdown voltage of 21.7 kV (81 % of the ideal breakdown voltage calculated from the epilayer structure), which is the highest breakdown voltage among any semiconductor devices ever reported. © 2012 IEEE.

    DOI: 10.1109/ISPSD.2012.6229101

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  137. Fundamental study on junction termination structures for ultrahigh-voltage SiC PiN diodes

    Niwa H., Suda J., Kimoto T.

    IMFEDK 2012 - 2012 International Meeting for Future of Electron Devices, Kansai     page: 56 - 57   2012.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IMFEDK 2012 - 2012 International Meeting for Future of Electron Devices, Kansai  

    15 kV-class 4H-SiC PiN diodes with various junction termination extension (JTE) structures have been experimentally investigated. JTE-dose dependence of the breakdown voltage for conventional single and two-zone JTE showed a narrow window of optimum JTE-dose to obtain high breakdown voltage. To widen this window, space-modulated JTE (SM-JTE) was introduced. 4H-SiC PiN diodes with SM-JTE showed a highest breakdown voltage of 15 kV, and a widening of the optimum JTE-dose window to obtain ultrahigh-voltage was realized at the same time. © 2012 IEEE.

    DOI: 10.1109/IMFEDK.2012.6218579

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  138. 21.7 kV 4H-SiC PiN Diode with a Space-Modulated Junction Termination Extension

    Niwa Hiroki, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 5 ( 6 )   2012.6

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    Ultrahigh-voltage 4H-SiC mesa PiN diodes are fabricated and characterized. An original space-modulated two-zone junction termination extension (SM-two-zone JTE) has realized a laterally tapered profile of the JTE dose, which enlarged the tolerance to the deviation of effective JTE dose compared with a conventional two-zone JTE. We demonstrate a SiC PiN diode with a breakdown voltage of 21.7 kV (81% of the ideal breakdown voltage calculated from the epilayer structure), which is the highest breakdown voltage among any semiconductor devices ever reported. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.5.064001

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  139. Lattice mismatch and crystallographic tilt induced by high-dose ion-implantation into 4H-SiC

    Sasaki S., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 111 ( 10 )   2012.5

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    Lattice parameters of high-dose ion-implanted 4H-SiC were investigated with reciprocal space mapping (RSM). N, P, Al, or (CSi) ions were implanted into lightly doped epilayers to form a (330-520) nm-deep box profile with concentrations of 10 19-10 20 atoms/cm 3. After activation annealing at 1800 °C, RSM measurements were conducted. The RSM images for (0008) reflection revealed that high-dose ion implantation causes c-lattice expansion in implanted layers, irrespective of ion species. In addition, crystallographic tilt was observed after high-dose ion implantation. The tilt direction is the same for all the samples investigated; the c-axis of the implanted layers is inclined toward the ascending direction of the off-cut. The c-lattice mismatch and the tilt angle increased as the implantation dose increases, indicating that the implantation damage is responsible for the lattice parameter change. From these results and transmission electron microscopy observation, the authors conclude that the c-lattice mismatch and the crystallographic tilt are mainly caused by secondary defects formed after the ion-implantation and activation-annealing process. © 2012 American Institute of Physics.

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  140. AlN/GaN Short-Period Superlattice Coherently Grown on 6H-SiC(0001) Substrates by Molecular Beam Epitaxy

    Kikuchi Ryosuke, Okumura Hironori, Kaneko Mitsuaki, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 5 ( 5 )   2012.5

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    We demonstrate the coherent growth of AIN/GaN short-period superlattice (SPSL) on 6H-SiC(0001) substrates by molecular beam epitaxy. A high-quality 5-nm-thick AIN layer was grown on SiC as a template layer, followed by the growth of AIN (12BL)/GaN (2BL) SPSL, which consists of 40 periods (total thickness: 140nm). The SPSL was coherently grown on SiC, and its threading dislocation density (TDD) was as low as 8 × 10 8cm -2. The SPSL, which had 3-BL-thick GaN layers, was relaxed, and the TDD increased to 8 × 10 10cm -2. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.5.051002

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  141. Current Transport Characteristics of Quasi-AlxGa1-xN/SiC Heterojunction Bipolar Transistors with Various Band Discontinuities

    Okuda Takafumi, Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 51 ( 4 )   2012.4

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    The current transport characteristics of quasi-Al xGa 1-xN/SiC heterojunction bipolar transistors (HBTs) with various band discontinuities were investigated in a low-current range using a Gummel plot. In the low-current range, the base currents of the HBTs were dominated by recombination currents. The collector current characteristics of the HBTs in the low-current range were almost the same in spite of the various band discontinuities, and the ideality factor n was 1.0. The band discontinuities at the heterojunction had no effect on electron injection in the lowcurrent range. This is because the collector currents were dominated by diffusion process in the base region rather than by injection process at the AlGaN/SiC interface. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.51.04DP09

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  142. Analytical model for reduction of deep levels in SiC by thermal oxidation

    Kawahara Koutarou, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 111 ( 5 )   2012.3

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    Two trap-reduction processes, thermal oxidation and C + implantation followed by Ar annealing, have been discovered, being effective ways for reducing the Z 12 center (E C - 0.67 eV), which is a lifetime killer in n-type 4H-SiC. In this study, it is shown that new deep levels are generated by the trap-reduction processes in parallel with the reduction of the Z 12 center. A comparison of defect behaviors (reduction, generation, and change of the depth profile) for the two trap-reduction processes shows that the reduction of deep levels by thermal oxidation can be explained by an interstitial diffusion model. Prediction of the defect distributions after oxidation was achieved by a numerical calculation based on a diffusion equation, in which interstitials generated at the SiO 2SiC interface diffuse to the SiC bulk and occupy vacancies related to the origin of the Z 12 center. The prediction based on the proposed analytical model is mostly valid for SiC after oxidation at any temperature, for any oxidation time, and any initial Z 12-concentration. Based on the results, the authors experimentally achieved the elimination of the Z 12 center to a depth of about 90 μm in the sample with a relatively high initial-Z 12-concentration of 10 13 cm -3 by thermal oxidation at 1400°C for 16.5 h. Furthermore, prediction of carrier lifetimes in SiC from the Z 12 profiles was realized through calculation based on a diffusion equation, which considers excited-carrier diffusion and recombination in the epilayer, in the substrate, and at the surface. © 2012 American Institute of Physics.

    DOI: 10.1063/1.3692766

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  143. High temperature annealing of n-type 4H-SiC: Impact on intrinsic defects and carrier lifetime

    Zippelius Bernd, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 111 ( 3 )   2012.2

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    In this paper, the impact of high-temperature annealing of 4H silicon carbide (SiC) on the formation of intrinsic defects, such as Z 1/2 and EH 6/7, and on carrier lifetimes was studied. Four nitrogen-doped epitaxial layers with various initial concentrations of the Z 1/2- and EH 6/7-centers (10 11 - 10 14 cm -3) were investigated by means of deep level transient spectroscopy and microwave photoconductance decay. It turned out that the high-temperature annealing leads to a monotone increase of the Z 1/2- and EH 6/7- concentration starting at temperatures between 1600°C and 1750°C, depending on the initial defect concentration. In the case of samples with high initial defect concentration (10 14 cm -3) a distinct decrease in Z 1/2- and EH 6/7-concentration in the temperature range from 1600°C to 1750°C was observed, being consistent with previous reports. For higher annealing temperatures (T anneal 1750°C), the defect concentration is independent of the samples' initial values. As a consequence, beside the growth conditions, such as C/Si ratio, the thermal post-growth processing has a severe impact on carrier lifetimes, which are strongly reduced for samples annealed at high temperatures. © 2012 American Institute of Physics.

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  144. Growth of Nitrogen-Polar 2H-AlN on Step-Height-Controlled 6H-SiC(000(1)over-bar) Substrate by Molecular-Beam Epitaxy

    Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 51 ( 2 )   2012.2

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    200-nm-thick N-polar AlN layers were grown on 6H-SiC(0001̄) substrates with 6-bilayer-high steps by molecular-beam epitaxy. During N-polar AlN growth, multinucleation growth occured easily, increasing the surface roughness of AlN. By reducing supersaturation (nucleation probability), the surface roughness was improved. The FWHMs of (0002) and (011̄2̄) ω-scan diffraction peaks of the AlN layer were 120 and 210 arcsec, respectively. The formation of stacking-mismatch boundaries (SMBs) was successfully suppressed by step-height control of the SiC substrate and the initial layer-by-layer growth. Most of the threading dislocations (TDs) were generated at the step edges of the SiC surfaces. The density of TDs in the AlN layers was 2 × 10 9 cm -2. © 2012 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.51.02BH02

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  145. Space-Modulated Junction Termination Extension for Ultrahigh-Voltage p-i-n Diodes in 4H-SiC

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 59 ( 2 ) page: 414 - 418   2012.2

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    An edge termination method, referred to as space-modulated junction termination extension (SMJTE) combined with a mesa structure, is presented for ultrahigh-voltage p-i-n diodes in 4H-SiC. Numerical device simulations have been performed for over 15-kV-class 4H-SiC p-i-n diodes with the proposed edge termination. The structure exhibits a high breakdown capability with an improved tolerance for the deviation of impurity dose in the JTE region. Unlike conventional multi-implantation, the proposed termination technique utilizes a single-step implantation with a single mask. A desired laterally tapered doping profile is achieved by fragmenting a conventional JTE region using relatively wide spaces. The simple process of the proposed edge termination makes it applicable to fabrication of various high-voltage devices in 4H-SiC. © 2006 IEEE.

    DOI: 10.1109/TED.2011.2175486

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  146. Breakdown Characteristics of 12-20 kV-class 4H-SiC PiN Diodes with Improved Junction Termination Structures

    Niwa Hiroki, Feng Gan, Suda Jun, Kimoto Tsunenobu

    2012 24TH INTERNATIONAL SYMPOSIUM ON POWER SEMICONDUCTOR DEVICES AND ICS (ISPSD)     page: 381 - 384   2012

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  147. Defect Electronics in SiC and Fabrication of Ultrahigh-Voltage Bipolar Devices

    Kimoto T., Suda J., Feng G., Miyake H., Kawahara K., Niwa H., Okuda T., Ichikawa S., Nishi Y.

    GALLIUM NITRIDE AND SILICON CARBIDE POWER TECHNOLOGIES 2   Vol. 50 ( 3 ) page: 25 - 35   2012

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    Fast epitaxial growth, defect reduction, device designing, and process development in SiC toward ultrahigh-voltage (> 10 kV) bipolar devices are investigated. 100∼200μ-thick 4H-SiC epilayers with a low background doping concentration in the low 1013 cm-3 can be grown at a growth rate greater than 50μ/h. Impacts of extended defects on carrier recombination are clarified in photoluminescence mapping measurements. Generation and reduction of Z1/2 center, the dominant lifetime killer, are summarized. After Z1/2 elimination by thermal oxidation at 1400°C, the carrier lifetime can be enhanced to 25 s or even longer. By utilizing space-modulated junction termination extension, a 21.7 kV PiN diode is demonstrated. Through unique process development, the current gain in bipolar junction transistors is increased to 250∼330. © The Electrochemical Society.

    DOI: 10.1149/05003.0025ecst

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  148. Experimental Study on Various Junction Termination Structures Applied to 15 kV 4H-SiC PiN Diodes

    Niwa Hiroki, Feng Gan, Suda Jun, Kimoto Tsunenobu

    SILICON CARBIDE AND RELATED MATERIALS 2011, PTS 1 AND 2   Vol. 717-720   page: 973 - 976   2012

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    Breakdown characteristics of 4H-SiC PiN diodes with various JTE structures have been investigated. By combining two-zone JTE and Space-Modulated JTE (SM-JTE), a breakdown voltage over 15 kV, corresponding to about 93 % of the parallel-plane breakdown voltage, was realized. The window of optimum JTE dose to obtain high breakdown voltage was widened, which indicates the robustness to the deviation of JTE dose. By comparing the breakdown voltage obtained by simulation and experimental results, impacts of the charge near the SiO 2/SiC interface are discussed. © (2012) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.717-720.973

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  149. Enhanced Current Gain (> 250) in 4H-SiC Bipolar Junction Transistors by A Deep-Level-Reduction Process

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    SILICON CARBIDE AND RELATED MATERIALS 2011, PTS 1 AND 2   Vol. 717-720   page: 1117 - 1122   2012

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    We demonstrate 4H-SiC bipolar junction transistors (BJTs) with an enhanced current gain over 250. High current gain was achieved by utilizing optimized device geometry as well as optimized surface passivation, continuous epitaxial growth of the emitter-base junction, combined with an intentional deep-level-reduction process based on thermal oxidation to improve the lifetime in p-SiC base. We achieved a maximum current gain (β) of 257 at room temperature and 127 at 250°C for 4H-SiC BJTs fabricated on the (0001)Si-face. The gain of 257 is twice as large as the previous record gain. We also demonstrate BJTs on the (000-1)C-face that showed the highest β of 439 among the SiC BJTs ever reported. © (2012) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.717-720.1117

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  150. Elimination of Deep Levels in Thick SiC Epilayers by Thermal Oxidation and Proposal of the Analytical Model

    Kawahara Koutarou, Suda Jun, Kimoto Tsunenobu

    SILICON CARBIDE AND RELATED MATERIALS 2011, PTS 1 AND 2   Vol. 717-720   page: 241 - 246   2012

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    It has been clarified that the Z1/2 center, a well known deep level as a lifetime killer, can be reduced to the concentration below 10 11 cm-3 by thermal oxidation or C+ implantation plus Ar annealing. In this study, the authors investigate the trap-reduction phenomena systematically (experimentally), and propose a model to analyze the phenomena. Furthermore, prediction of the defect distributions is realized by solving a diffusion equation in accordance with the trap reduction model. This analytical model can explain almost all experimental data: oxidation-temperature dependence, oxidation-time dependence, and initial-Z1/2- concentration dependence of the defect reduction. Based on these results, the authors achieved the elimination of the Z1/2 center to a depth of ∼100 μm in a sample with a relatively high initial-Z1/2- concentration of 1013 cm-3 by thermal oxidation at 1400°C for 16.5 h. © (2012) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.717-720.241

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  151. Doping-Induced Lattice Mismatch and Misorientation in 4H-SiC Crystals

    Sasaki S., Suda J., Kimoto T.

    SILICON CARBIDE AND RELATED MATERIALS 2011, PTS 1 AND 2   Vol. 717-720   page: 481 - 484   2012

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    The c- and a-lattice constants of nitrogen-doped 4H-SiC were measured in the wide temperature range (RT - 1100°C). The samples used in this study were heavily doped substrates and lightly-doped free-standing epilayers. The lattice constants at room temperature are almost identical for all the samples. However, the lattice contraction by heavy nitrogen doping was clearly observed at high temperatures, which indicates that the thermal expansion coefficients are dependent on the nitrogen concentration. The lattice mismatch (Δd/d) between a lightly-doped free-standing epilayer (Nd = 6×10 14 cm-3) and a heavily-doped substrate (Nd = 2×1019 cm-3) was calculated as 1.7×10 -4 at 1100°C. The authors also investigated lattice constants of high-dose N+, P+, and Al+-implanted 4H-SiC. Reciprocal space mapping (RSM) was utilized to investigate the lattice mismatch and misorientation. The RSM images show the c-lattice expansion and c-axis tilt of the ion-implanted layers, irrespective of ion species. The authors conclude that the lattice expansion is not caused by heavy doping itself, but by secondary defects formed after the ion-implantation and activation-annealing process. © (2012) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.717-720.481

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  152. On the Formation of Intrinsic Defects in 4H-SiC by High Temperature Annealing Steps

    Zippelius B., Suda J., Kimoto T.

    SILICON CARBIDE AND RELATED MATERIALS 2011, PTS 1 AND 2   Vol. 717-720   page: 247 - 250   2012

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    In this paper the impact of high temperature annealing on the formation of intrinsic defects in 4H-SiC such as Z1/2 and EH6/7 is examined. Three epitaxial layers with various initial concentrations of the Z1/2- and EH6/7-centers (1011 - 1013 cm-3) are investigated by means of deep level transient spectroscopy (DLTS). It turns out that depending on the initial defect concentration, the high temperature annealing leads to a monotonic increase of the Z1/2- and EH6/7-concentration in a temperature range from 1600 to 1750°C. For higher temperatures, the resulting defect concentration is independent of the sample's initial values. Therefore, beside the growth conditions such as C/Si ratio, the thermal post-growth processing has a severe impact on the carrier lifetime and must be taken into account during device fabrication. © (2012) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.717-720.247

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  153. 4H-SiC bipolar junction transistors with record current gains of 257 on (0001) and 335 on (000-1)

    Miyake H., Kimoto T., Suda J.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs     page: 292 - 295   2011.12

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    We demonstrate 4H-SiC bipolar junction transistors (BJTs) with record current gains. Improved current gain was achieved by utilizing optimized device geometry as well as optimized surface passivation and continuous epitaxial growth of the emitter-base junction, combined with an intentional deep-level-reduction process based on thermal oxidation to improve the lifetime in p-SiC base. Current gain (β) of 257 was achieved for 4H-SiC BJTs fabricated on the (0001)Si-face. The gain of 257 is twice as large as the previous record gain. We also demonstrate, for the first time, BJTs on the (000-1)C-face that showed the highest β of 335 among the SiC BJTs ever reported. © 2011 IEEE.

    DOI: 10.1109/ISPSD.2011.5890848

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  154. Epitaxial growth and defect control of SiC for high-voltage power devices

    Kimoto T., Suda J.

    Journal of the Vacuum Society of Japan   Vol. 54 ( 6 ) page: 362 - 368   2011.12

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    Recent progress in fast epitaxial growth and defect control of silicon carbide (SiC) toward development of high-voltage power devices is reviewed. In chemical vapor deposition of 4H-SiC on off-axis (0001), a high growth rate of 85 μm/h and a low background doping of 1 × 10 13 cm -3 are achieved. Conversion of basal-plane dislocations to threading edge dislocations and generation of stacking faults during epitaxial growth are discussed. Deep levels in as-grown n-type and p-type 4H-SiC epitaxial layers have been investigated. A lifetime-killing defect, Z 1/2 center, can be almost eliminated by thermal oxidation, which leads to significant increase in carrier lifetimes. The obtained carrier lifetimes are long enough to fabricate 10 kV-class bipolar devices. Control of carrier lifetimes by lowenergy electron irradiation is demonstrated.

    DOI: 10.3131/jvsj2.54.362

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  155. Reliability of Nitrided Gate Oxides for N- and P-Type 4H-SiC(0001) Metal-Oxide-Semiconductor Devices

    Noborio Masato, Grieb Michael, Bauer Anton J., Peters Dethard, Friedrichs Peter, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 50 ( 9 )   2011.9

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    In this paper, we have investigated reliability of n- and p-type 4H-SiC(0001) metal-oxide-semiconductor (MOS) devices with N2O-grown oxides and deposited oxides annealed in N2O. From the results of time-dependent dielectric breakdown (TDDB) tests, it is revealed that the N 2O-grown oxides have relatively-high reliability (4-30Ccm -2 for n- and p-MOS structures). In addition, the deposited SiO 2 on n- and p-SiC exhibited a high charge-to-breakdown of 70.0 and 54.9Ccm-2, respectively. The n/p-MOS structures with the deposited SiO2 maintained a high charge-tobreakdown of 19.9/15.1Ccm -2 even at 200 °C. The deposited SiO2 annealed in N2O has promise as the gate insulator for n- and p-channel 4HSiC(0001) MOS devices because of its high charge-to-breakdown and good interface properties. © 2011 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.50.090201

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  156. Nonradiative recombination at threading dislocations in 4H-SiC epilayers studied by micro-photoluminescence mapping

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 110 ( 3 )   2011.8

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    Threading dislocations (TDs) in 4H-SiC epilayers have been investigated by means of micro-photoluminescence (-PL) mapping at room temperature. Enhanced nonradiative recombination at TDs was confirmed experimentally, resulting in a reduced local PL emission intensity in the -PL intensity map performed at 390 nm (near band-edge emission). The behavior of nonradiative recombination at TDs depends on the dislocation type: the screw type of TDs shows stronger effect on the nonradiative recombination activity than the edge type, evidencing a larger local reduction of PL emission intensity. Furthermore, the contrast of TDs in the μ-PL intensity map greatly depends on the carrier lifetimes of the 4H-SiC epilayers. Lifetimes longer than 0.5 s are essential to obtain a discernible contrast for the individual TDs. © 2011 American Institute of Physics.

    DOI: 10.1063/1.3622336

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  157. 4H-SiC BJTs With Record Current Gains of 257 on (0001) and 335 on (0001)

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 32 ( 7 ) page: 841 - 843   2011.7

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    We demonstrate 4H-SiC bipolar junction transistors (BJTs) with record current gains. An improved current gain was achieved by utilizing optimized device geometry and continuous epitaxial growth of the emitterbase junction, combined with an intentional deep-level-reduction process based on thermal oxidation to improve the lifetime in p-SiC base. A current gain (β) of 257 was achieved for 4H-SiC BJTs fabricated on the (0001) Si face. A gain of 257 is twice as large as the previous record gain. We also demonstrate BJTs on the (0001) C face that showed the highest β of 335 among the SiC BJTs ever reported. © 2011 IEEE.

    DOI: 10.1109/LED.2011.2142291

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  158. Anomalously low Ga incorporation in high Al-content AlGaN grown on (11(2)over-bar0) non-polar plane by molecular beam epitaxy

    Ueta Shunsaku, Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE   Vol. 208 ( 7 ) page: 1498 - 1500   2011.7

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    Crystalline orientation dependence of Ga incorporation in growth of high Al-content AlGaN was investigated. Growth was carried out by molecular-beam epitaxy (MBE) using elemental Al, Ga, and rf-plasma-excited nitrogen under various V/III ratios. 6H-SiC (0001), 4H-SiC (1√100) and 4H-SiC (11√20) were used as substrates. Ga incorporation increased with increase of V/III ratio in the layers grown on (0001) and (1√100) planes. On the other hand, Ga was not incorporated in the layer grown on (11√20) plane even when the layer was grown under a nitrogen rich condition, indicating much lower Ga incorporation on (11√20) plane than those of other planes. AlGaN with good quality was successfully grown on (1√100) plane. Utilization of (1√100) plane is suitable in MBE growth of AlGaN-based deep-ultraviolet light emitting devices. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssa.201001033

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  159. Impacts of reduction of deep levels and surface passivation on carrier lifetimes in p-type 4H-SiC epilayers

    Hayashi T., Asano K., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 109 ( 11 )   2011.6

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    Impacts of reduction of deep levels and surface passivation on carrier lifetimes in p-type 4H-SiC epilayers are investigated. The authors reported that the carrier lifetime in n-type epilayers increased by reduction of deep levels through thermal oxidation and thermal annealing. However, the carrier lifetimes in p-type epilayers were not significantly enhanced. In this study, in order to investigate the influence of surface passivation on the carrier lifetimes, the epilayer surface was passivated by different oxidation techniques. While the improvement of the carrier lifetime in n-type epilayers was small, the carrier lifetime in p-type epilayers were remarkably improved by appropriate surface passivation. For instance, the carrier lifetime was improved from 1.4 s to 2.6 s by passivation with deposited SiO2 annealed in NO. From these results, it was revealed that surface recombination is a limiting factor of carrier lifetimes in p-type 4H-SiC epilayers. © 2011 American Institute of Physics.

    DOI: 10.1063/1.3583657

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  160. Lifetime-Killing Defects in 4H-SiC Epilayers and Lifetime Control by Low-Energy Electron Irradiation

    Kimoto T.

    Silicon Carbide   Vol. 1   page: 267 - 286   2011.4

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    DOI: 10.1002/9783527629053.ch10

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  161. 4H-SiC MISFETs with Nitrogen-Containing Insulators

    Noborio M.

    Silicon Carbide   Vol. 2   page: 235 - 265   2011.3

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    DOI: 10.1002/9783527629077.ch10

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  162. Bandgap shift by quantum confinement effect in < 100 > Si-nanowires derived from threshold-voltage shift of fabricated metal-oxide-semiconductor field effect transistors and theoretical calculations

    Yoshioka Hironori, Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 109 ( 6 )   2011.3

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    Si-nanowire (Si-NW) MOSFETs, the cross-sectional size (square root of the cross-sectional area of NWs) of which was changed from 18 to 4 nm, were fabricated and characterized. Both n- and p-channel MOSFETs have shown a nearly ideal subthreshold swing of 63 mV/decade. The threshold voltage of n-/p-channel MOSFETs has gradually increased/decreased with decreasing the cross-sectional size. The bandgap shift from bulk Si has been derived from the threshold-voltage shift. The bandgap of Si-NWs was calculated by a density functional theory, tight binding method, and effective mass approximation. The calculated bandgap shows good agreement with that derived from threshold voltage. The theoretical calculation indicates that the bandgap is dominated by the cross-sectional size (area) and is not very sensitive to the shape within the aspect-ratio range of 1.0-2.5. © 2011 American Institute of Physics.

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  163. Quantum-confinement effect on holes in silicon nanowires: Relationship between wave function and band structure

    Morioka Naoya, Yoshioka Hironori, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 109 ( 6 )   2011.3

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    The authors theoretically studied the valence band structure and hole effective mass of rectangular cross-sectional Si nanowires (NWs) with the crystal orientation of [110], [111], and [001]. The E-k dispersion and the wave function were calculated using an sp3d5s tight-binding method and analyzed with the focus on the nature of p orbitals constituting the subbands. In [110] and [111] nanowires, longitudinal/transverse p orbitals are well separated and longitudinal component makes light (top) subbands and transverse component makes heavy subbands. The heavy subbands are located far below the top light band when NW has square cross-section, but they gain their energy with the increase in the NW width and come near the band edge. This energy shift of heavy bands in [110] NWs shows strong anisotropy to the direction of quantum confinement whereas that in [111] NWs does not have such anisotropy. This anisotropic behavior and the difference among orientations are understandable by the character of the wave function of heavy subbands. Regarding the [001] nanowires, the top valence state is formed by the mixture of longitudinal/transverse p orbitals, which results in heavy effective mass and large susceptibility to lateral-size variation. The correlation of the wave function of hole states between nanowires and bulk is also discussed briefly. © 2011 American Institute of Physics.

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  164. Improvement of Current Gain in 4H-SiC BJTs by Surface Passivation With Deposited Oxides Nitrided in N2O or NO

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 32 ( 3 ) page: 285 - 287   2011.3

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    We report the improvement of current gain in 4H-SiC bipolar junction transistors (BJTs) by utilizing deposited oxides as a surface passivation layer. Various postdeposition annealing processes, including annealing ambient (N 2, N2O, and NO) and annealing time, were investigated. We successfully demonstrate SiC BJTs with high current gains β of 73 and 102 using deposited oxides annealed in N2O and NO, respectively, whereas BJTs having conventional thermally grown oxides showed a current gain of 50. © 2006 IEEE.

    DOI: 10.1109/LED.2010.2101575

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  165. Origin of Etch Hillocks Formed on On-Axis SiC(000(1)over-bar) Surfaces by Molten KOH Etching

    Suda Jun, Shoji Haruki, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 50 ( 3 )   2011.3

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    Molten KOH etching of 6H- and 4H-SiC{0001} on-axis substrates was investigated. After molten KOH etching, etch pits originating from threading dislocations (TDs) and basal-plane dislocations (BPDs) were observed on (0001) surfaces. On the other hand, large and small hillocks were observed on (0001̄) surfaces. The etch hillocks consist of SiC, indicating slower etching at TDs. By comparing the (0001) side and (0001̄) side of the same substrate, it was found that large hillocks correspond to edge-type TDs, while small hillocks correspond to screw-type TDs. © 2011 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.50.038002

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  166. Reduction of Threading Dislocation Density in 2H-AlN Grown on 6H-SiC(0001) by Minimizing Unintentional Active-Nitrogen Exposure before Growth

    Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 4 ( 2 )   2011.2

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    300-nm-thick AlN layers were grown directly on 6H-SiC(0001) with six Si-C bilayer-height (1.5 nm) steps by rf-plasma-assisted molecular-beam epitaxy (MBE). To avoid unintentional active-nitrogen exposure, AlN was grown just after the nitrogen plasma ignition. By combining optimized Ga pre-deposition and no active-nitrogen exposure, layer-by-layer growth was realized from the first layer of AlN. Screw-type and edge-type threading dislocation densities in the AlN layer were reduced to 6 × 104 and 4 × 108 cm-2, respectively. Most of the edge-type dislocations were located at the step edge of the SiC substrate. The dislocation density of the AlN grown on the terrace of the SiC substrate was as low as 8 × 107 cm-2. © 2011 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.4.025502

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  167. Temperature and injection level dependencies and impact of thermal oxidation on carrier lifetimes in p-type and n-type 4H-SiC epilayers

    Hayashi T., Asano K., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 109 ( 1 )   2011.1

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    Dependencies of temperature and injection level on carrier lifetimes in 50 μm thick p-type and n-type 4H-SiC epilayers have been investigated. The carrier lifetimes have been measured by differential microwave photoconductance decay measurements at various injection levels and temperatures. In both p-type and n-type epilayers, the carrier lifetimes gradually increased with increasing the injection level, which were naturally expected from the Shockley-Read-Hall (SRH) model, and after taking a maximum, the lifetimes dropped at the very high-injection level. In contrast, the carrier lifetimes exhibited continuous increase with elevating the temperature for both epilayers. In addition, the impact of thermal oxidation process on the carrier lifetimes has been also investigated. The thermal oxidation process, by which the Z1/2 and EH6/7 centers were remarkably reduced that had been observed in n-type 4H-SiC in our previous work, led to the improvement of the carrier lifetimes especially for n-type epilayers. The carrier lifetime reached 4.1 μs in p-type and 6.1 μs in n-type epilayers at 250 °C with an injection level of 1.8×1016 cm-3 through the thermal oxidation processing. © 2011 American Institute of Physics.

    DOI: 10.1063/1.3524266

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  168. 4H-SiC Bipolar Junction Transistors with Record Current Gains of 257 on (0001) and 335 on (000-1)

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    2011 IEEE 23RD INTERNATIONAL SYMPOSIUM ON POWER SEMICONDUCTOR DEVICES AND ICS (ISPSD)     page: 292 - 295   2011

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  169. Fabrication of Electrostatic-actuated Single-crystalline 4H-SiC Bridge Structures by Photoelectrochemical Etching

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    MICROMACHINING AND MICROFABRICATION PROCESS TECHNOLOGY XVI   Vol. 7926   2011

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Proceedings of SPIE - The International Society for Optical Engineering  

    An electrostatic-actuated suspended bridge structure composed by single-crystalline silicon carbide (SiC) is fabricated. The structure is entirely made of homoepitaxially grown single-crystalline 4H-SiC. Electrical isolation between the suspended bridge and the base plate is established with a pnp junction formed by multiple ion implantation. The structure is fabricated by a combination of reactive ion etching (RIE) and doping-selective photoelectrochemical (PEC) etching. The suspended bridge is actuated by applying a voltage between the bridge and the base plate.

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  170. Thermo-optic Coefficients of SiC, GaN, and AlN up to 512 degrees C from Infrared to Ultraviolet Region for Tunable Filter Applications

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    MICROMACHINING AND MICROFABRICATION PROCESS TECHNOLOGY XVI   Vol. 7926   2011

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    The temperature dependence of the refractive indices of 4H-SiC, GaN, and AlN were investigated in a wavelength range from the near band edge (392 nm for SiC, 367 nm for GaN, and 217 nm for AlN) to infrared (1700 nm) and a temperature range from room temperature to 512°C. Optical interference measurements with vertical incident configuration were employed to precisely evaluate ordinary refractive indices. In visible region, the thermo-optic coefficient of GaN has the largest value in these materials. Optical simulation of GaN-based tunable band-pass filter with AlGaN/GaN distributed Bragg reflectors (DBRs) was also carried out by using the obtained thermo-optic coefficients. It revealed that 9 nm red-shift can be obtained from room temperature to 500°C.

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  171. Tight-binding study of size and geometric effects on hole effective mass of silicon nanowires

    Moriokaa N., Yoshioka H., Suda J., Kimoto T.

    2010 Silicon Nanoelectronics Workshop, SNW 2010     2010.10

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    The present tight-binding study of rectangular SiNWs along [001], [110], and [111] revealed that the hole m* of [001] and [110] NWs on the {001} basal face has strong dependence on the width. Because this nature may make the design of devices difficult, these NWs are considered to be unfavorable for p-channel devices. In contrast, rectangular [111] NWs on both (112̄) and (1̄10) basal faces are favorable for p-channel devices because they have the smallest hole m* and its value is very resistant to the variability of the width.

    DOI: 10.1109/SNW.2010.5562567

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  172. Impacts of recombination at the surface and in the substrate on carrier lifetimes of n-type 4H-SiC epilayers

    Kimoto Tsunenobu, Hiyoshi Toru, Hayashi Toshihiko, Suda Jun

    JOURNAL OF APPLIED PHYSICS   Vol. 108 ( 8 )   2010.10

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    After remarkable reduction in the Z1/2 center in n-type 4H-SiC epilayers, the measured carrier lifetimes can be severely affected by other recombination paths. Impacts of carrier recombination at the surface as well as in the substrate are investigated in detail by using numerical simulation based on a diffusion equation. The simulation reveals that a very thick (>100 μm) epilayer is required for accurate measurement of carrier lifetimes if the bulk lifetime in the epilayer is longer than several microsecond, due to the extremely short lifetimes in the substrate. The fast decay often observed at the initial stage of decay curves can be explained by fast recombination at the surface and in the substrate. In experiments, the carrier lifetime is improved from 0.69 to 9.5 μs by reducing the Z1/2 center via two-step thermal treatment (thermal oxidation and Ar annealing) for a 148-μm -thick n-type epilayer. This lifetime must be still, to large extent, affected by the recombination at the surface and in the substrate, and the real bulk lifetime may be much longer. The carrier recombination paths and their impacts on the decay curves are discussed. © 2010 American Institute of Physics.

    DOI: 10.1063/1.3498818

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  173. Accurate measurement of quadratic nonlinear-optical coefficients of gallium nitride

    Abe M., Sato H., Shoji I., Suda J., Yoshimura M., Kitaoka Y., Mori Y., Kondo T.

    Journal of the Optical Society of America B: Optical Physics   Vol. 27 ( 10 ) page: 2026 - 2034   2010.10

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    We have determined all the three independent components of quadratic nonlinear-optical coefficients of GaN by highly accurate Maker-fringe measurements on high-quality bulk samples combined with theoretical analysis taking account of the multiple-reflection effects in slightly misoriented optically anisotropic samples. Especially, the d33 coefficient is determined with sufficient accuracies for the first time, to our knowledge, by using (112̄0)-oriented samples. The obtained values of quadratic nonlinear-optical coefficients are d31 =2.5±0.1 pm/V, d 15=2.5±0.1 pm/V, and d33=-3.8±0.2 pm/V at the fundamental wavelength of 1.064 μm. © 2010 Optical Society of America.

    DOI: 10.1364/JOSAB.27.002026

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  174. Accurate measurement of quadratic nonlinear-optical coefficients of gallium nitride

    Abe Makoto, Sato Hiroaki, Shoji Ichiro, Suda Jun, Yoshimura Masashi, Kitaoka Yasuo, Mori Yusuke, Kondo Takashi

    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS   Vol. 27 ( 10 ) page: 2026 - 2034   2010.10

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  175. Demonstration of Common-Emitter Operation in AlGaN/SiC Heterojunction Bipolar Transistors

    Miyake Hiroki, Kimoto Tsunenobu, Suda Jun

    IEEE ELECTRON DEVICE LETTERS   Vol. 31 ( 9 ) page: 942 - 944   2010.9

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    We report here on the fabrication and characterization of new aluminum gallium nitride (AlGaN)/silicon carbide heterojunction bipolar transistors (HBTs). In the HBTs, AlN/GaN short-period superlattice (quasi-AlGaN) was employed as the widegap emitter. We have successfully demonstrated band-offset control and the first commonemitter-mode operation (β ∼ 2.7) in the HBTs. © 2010 IEEE.

    DOI: 10.1109/LED.2010.2052012

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  176. Reduction of deep levels generated by ion implantation into n- and p-type 4H-SiC

    Kawahara Koutarou, Suda Jun, Pensl Gerhard, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 108 ( 3 )   2010.8

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    The authors have investigated effects of thermal oxidation on deep levels in the whole energy range of the band gap of 4H-SiC by deep level transient spectroscopy. The deep levels are generated by ion implantation. The dominant defects in n-type samples after ion implantation and high-temperature annealing at 1700 °C are IN3 (Z1/2: EC-0.63 eV) and IN9 (EH 6/7: EC-1.5 eV) in low-dose-implanted samples, and IN8 (EC-1.2 eV) in high-dose-implanted samples. These defects can remarkably be reduced by thermal oxidation at 1150 °C. In p-type samples, however, IP8 (HK4: EV +1.4 eV) survives and additional defects such as IP4 (HK0: EV +0.72 eV) appear after thermal oxidation in low-dose-implanted samples. In high-dose-implanted p-type samples, three dominant levels, IP5 (HK2: EV +0.85 eV), IP6 (EV +1.0 eV), and IP7 (HK3: EV +1.3 eV), are remarkably reduced by oxidation at 1150 °C. The dominant defect IP4 observed in p-type 4H-SiC after thermal oxidation can be reduced by subsequent annealing in Ar at 1400 °C. These phenomena are explained by a model that excess interstitials are generated at the oxidizing interface, which diffuse into the bulk region. © 2010 American Institute of Physics.

    DOI: 10.1063/1.3456159

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  177. Sources of Epitaxial Growth-Induced Stacking Faults in 4H-SiC

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF ELECTRONIC MATERIALS   Vol. 39 ( 8 ) page: 1166 - 1169   2010.8

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    Successive reactive-ion etching and microphotoluminescence (PL) intensity mapping have been performed in order to investigate the sources of epitaxial growth-induced stacking faults (SFs) in thick 4H-SiC epilayers. Three kinds of SFs, i.e., 4SSFs, 3SSFs, and 2SSFs, have been identified in the samples. Two of these (3SSFs and 2SSFs) show similar nucleation behaviors, and their formation may be due to stress within the epitaxial layer. In contrast, 4SSFs nucleate at the epilayer-substrate interface and might be related to an unknown dislocation, which shows a rounded-shape etch pit in the substrate. © 2010 TMS.

    DOI: 10.1007/s11664-010-1192-6

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  178. Deep levels induced by reactive ion etching in n- and p-type 4H-SiC

    Kawahara Koutarou, Krieger Michael, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 108 ( 2 )   2010.7

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    In this study, the authors investigate deep levels, which are induced by reactive ion etching (RIE) of n-type/p-type 4H-SiC, by deep level transient spectroscopy (DLTS). The capacitance of a Schottky contact fabricated on as-etched p-type SiC is abnormally small due to compensation or deactivation of acceptors extending to a depth of ∼14 μm, which is nearly equal to the epilayer thickness. The value of the capacitance can recover to that of a Schottky contact on as-grown samples after annealing at 1000 °C. However, various kinds of defects, IN2 (EC-0.30 eV), EN (EC -1.6 eV), IP1 (EV +0.30 eV), IP2 (EV +0.39 eV), IP4 (HK0: EV +0.72 eV), IP5 (EV +0.85 eV), IP7 (EV +1.3 eV), and EP (EV +1.4 eV), remain at a high concentration (average of total defect concentration in the region ranging from 0.3 μm to 1.0 μm:∼5× 1014 cm-3) even after annealing at 1000 °C. The concentration of all these defects generated by RIE, except for the IP4 (HK0) center, remarkably decreases by thermal oxidation. In addition, the HK0 center can also be reduced significantly by a subsequent annealing at 1400 °C in Ar. © 2010 American Institute of Physics.

    DOI: 10.1063/1.3460636

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  179. Electrical characterization and reliability of nitrided-gate insulators for N- and P-Type 4H-SiC MIS devices

    Noborio M., Grieb M., Bauer A.J., Peters D., Friedrichs P., Suda J., Kimoto T.

    Materials Science Forum   Vol. 645-648   page: 825 - 828   2010

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    In this paper, nitrided insulators such as N2O-grown oxides, deposited SiO2 annealed in N2O, and deposited SiN x/SiO2 annealed in N2O on thin-thermal oxides have been investigated for realization of high performance n- and p-type 4H-SiC MIS devices. The MIS capacitors were utilized to evaluate MIS interface characteristics and the insulator reliability. The channel mobility was determined by using the characteristics of planar MISFETs. Although the N 2O-grown oxides are superior to the dry O2-grown oxides, the deposited SiO2 and the deposited SiNx/SiO2 exhibited lower interface state density (n-MIS: below 7×1011 cm-2eV-1 at EC-0.2 eV, p-MIS: below 6×1011 cm-2eV-1 at EV+0.2 eV) and higher channel mobility (n-MIS: over 25 cm2/Vs, p-MIS: over 10 cm2/Vs). In terms of reliability, the deposited SiO2 annealed in N2O exhibits a high charge-to-breakdown over 50 C/cm 2 at room temperature and 15 C/cm2 at 200°C. The nitrided-gate insulators formed by deposition method have superior characteristics than the thermal oxides grown in N2O. © (2010) Trans Tech Publications, Switzerland.

    DOI: 10.4028/www.scientific.net/MSF.645-648.825

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  180. Enhancement of initial layer-by-layer growth and reduction of threading dislocation density by optimized Ga pre-irradiation in molecular-beam epitaxy of 2H-AlN on 6H-SiC (0001)

    Okumura Hironori, Kimoto Tsunenobu, Suda Jun

    PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 7, NO 7-8   Vol. 7 ( 7-8 ) page: 2094 - 2096   2010

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    300-nm-thick AlN layers without a nucleation layer were grown on 6H-SiC (0001) vicinal substrates with 3-bilayer-height steps by rf-plasma-assisted molecular-beam epitaxy. A Ga beam was supplied for 0 to 30 seconds just before growth of AlN. The Ga pre-irradiation for 7 seconds (~1.6 ML) was found to be effective for realization of the AlN layer-by-layer growth mode at an earlier stage of the growth and reduction of threading dislocation densities (TDD) in the AlN layers. The screw-type and edge-type TDDs were ∼106 cm-2 and 6×108 cm-2, respectively. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

    DOI: 10.1002/pssc.200983579

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  181. Enhancement of Carrier Lifetimes in n-Type 4H-SiC Epitaxial Layers by Improved Surface Passivation

    Kimoto Tsunenobu, Nanen Yuichiro, Hayashi Toshihiko, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 3 ( 12 )   2010

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    Carrier lifetimes in n-type 4H-SiC epitaxial layers are limited by several factors such as deep levels, surface recombination, and recombination in the substrate. In this study, the carrier lifetime is significantly improved from 0.68 to 13.1 μs by eliminating deep levels and by improving surface passivation. Deep levels can be almost eliminated by two-step annealing as reported before, and the surface recombination can be reduced by passivating the surface with a deposited oxide annealed in nitric oxide at 1300 °C. Major recombination paths are discussed based on numerical simulation. © 2010 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.3.121201

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  182. Influence of Effective Fixed Charges on Short-Channel Effects in SiC Metal-Oxide-Semiconductor Field-Effect Transistors

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 49 ( 2 )   2010

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    Influence of effective fixed charges, which are located near the metal-oxide-semiconductor (MOS) interface, on short-channel effects in 4H-SiC MOS field-effect transistors (FETs) has been investigated. The relationship between the threshold voltage and the channel length was theoretically calculated by using an original charge-share model, which takes the effective fixed charges into account. As a result, it was revealed that the effective fixed charges, which are attributed to electron trapping at the interface states, affect the relationship. The threshold voltage is decreased by reducing the channel length in the relatively-long channel region when the effective fixed charges exist. The theoretical relationship between the threshold voltage and the channel length calculated by using the proposed model agrees very well with the experimental results. © 2010 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.49.024204

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  183. Lifetime-killing defects in 4H-SiC epilayers and lifetime control by low-energy electron irradiation

    Kimoto Tsunenobu, Danno Katsunori, Suda Jun

    SILICON CARBIDE, VOL 1: GROWTH, DEFECTS, AND NOVEL APPLICATIONS     page: 267 - 286   2010

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  184. Nearly Ideal Current-Voltage Characteristics of Schottky Barrier Diodes Formed on Hydride-Vapor-Phase-Epitaxy-Grown GaN Free-Standing Substrates

    Suda Jun, Yamaji Kazuki, Hayashi Yuichirou, Kimoto Tsunenobu, Shimoyama Kenji, Namita Hideo, Nagao Satoru

    APPLIED PHYSICS EXPRESS   Vol. 3 ( 10 )   2010

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    The current-voltage characteristics of Schottky barrier diodes formed on GaN(0001) free-standing substrates with net donor concentrations of 7:6 × 1015-1:4 × 1017 cm-3 are discussed. The substrates were grown by hydride vapor phase epitaxy. Ni Schottky contacts were directly formed on chemical-mechanical-polished Ga-polar faces of the substrates. Nearly ideal characteristics for both directions were obtained. The ideality factors for forward characteristics are 1.02 -1.05, very close to unity. The reverse characteristics agree well with calculations based on thermionicfield emission theory without any fitting parameter. © 2010 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.3.101003

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  185. Temperature and injection level dependencies of carrier lifetimes in p-type and n-type 4H-SiC epilayers

    Hayashi T., Asano K., Suda J., Kimoto T.

    Materials Science Forum   Vol. 645-648   page: 199 - 202   2010

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    Temperature and injection level dependencies of carrier lifetimes in p-type and n-type 4H-SiC epilayers have been investigated. The carrier lifetimes have been measured by differential microwave photoconductance decay measurements at various injection levels and temperatures. In both p-type and n-type epilayers, the carrier lifetimes gradually increased with increasing the injection level except for the very high injection condition. And the carrier lifetimes exhibited continuous increase with elevating the temperature for both epilayers. The carrier lifetime reached 3.3 μs in p-type and 4.2 μs in n-type epilayers at 250°C and an injection level of 1.8×1016 cm-3. © (2010) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.645-648.199

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  186. Nonpolar 4H-Polytype AlN/AlGaN Multiple Quantum Well Structure Grown on 4H-SiCd(1(1)over-bar00)

    Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 3 ( 5 )   2010

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    Nonpolar 4H-polytype AlN/AlGaN multiple quantum well (MQW) structures were grown on 4H-SiC(11̄00) substrates by molecular-beam epitaxy. Layer-by-layer growth of MQW layers is observed and abrupt AlN/AlGaN interfaces have been achieved. Generation of additional extended defects is not observed at the AlN/AlGaN interfaces and the crystal structure of 4H-polytype is preserved throughout the entire MQW structure. In cathodoluminescence spectra, a band-edge emission peak is observed at 5.41 eV (229 nm). The band edge peak position is not blue-shifted when the irradiation beam current is increased. © 2010 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.3.051001

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  187. Nondestructive Visualization of Individual Dislocations in 4H-SiC Epilayers by Micro Photoluminescence Mapping

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 49 ( 9 )   2010

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    Dislocations in 4H-SiC epilayers were imaged nondestructively by means of micro photoluminescence (μ-PL) mapping at room temperature. The one-to-one correspondence between the individual dislocations and the μ-PL mapping contrast has been consistently obtained. By analyzing the reduction of the intensity in the μ-PL mapping image performed at 390nm (near band-edge emission), we were able to distinguish threading screw dislocations and threading edge dislocations. Furthermore, it was found that a basal plane dislocation dissociates into a single Shockley stacking fault during the measurement. © 2010 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.49.090201

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  188. Non-destructive detection and visualization of extended defects in 4H-SiC epilayers

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    B - SILICON CARBIDE 2010-MATERIALS, PROCESSING AND DEVICES   Vol. 1246   page: 37 - 42   2010

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Materials Research Society Symposium Proceedings  

    The extended defects, such as dislocations and in-grown stacking faults (IGSFs), in 4H-SiC epilayers have been detected and visualized by a non-destructive method, the micro photoluminescence (μ-PL) intensity mapping method, at room temperature. The one-to-one correspondence between the extended defects and the μ-PL mapping contrast has been successfully obtained. A threading dislocation corresponds to a dark circle with the reduced intensity in the μ-PL mapping image performed at 390 nm, while a basal plane dislocation dissociates into a single Shockley SF during the measurements. Three kinds of IGSFs have been identified in the samples. Each kind of IGSF shows the distinct PL emission located at 460 nm, 480 nm, and 500 nm, respectively. The shapes and distributions of IGSFs have also been profiled by μ-PL intensity mapping. © 2010 Materials Research Society.

    DOI: 10.1557/PROC-1246-B03-02

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  189. Characterization of major in-grown stacking faults in 4H-SiC epilayers

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    PHYSICA B-CONDENSED MATTER   Vol. 404 ( 23-24 ) page: 4745 - 4748   2009.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Physica B: Condensed Matter  

    The optical properties of major in-grown stacking faults (IGSFs) in 4H-SiC epilayers have been characterized by micro-photoluminescence (micro-PL) spectroscopy and its intensity mapping. Strong PL emissions from the IGSFs are observed even at room temperature. Three kinds of IGSFs have been identified in the samples based on the micro-PL spectra. Each kind of IGSF shows the distinct PL emission peak located at 460, 480, and 500 nm, respectively. The micro-PL intensity mapping at the emission band of each IGSF has been performed to spatially profile the IGSF. The shapes, distributions, and densities of IGSFs in the epilayers are then presented. The microstructure of each IGSF has been revealed by high-resolution transmission electron microscopy observations. The stacking sequences of three IGSFs are determined as (4,4), (3,5), and (6,0) in the Zhdanov's notation, respectively, which apparently differ from the perfect 4H-SiC, (2,2). Three identified IGSFs are then classified as quadruple Shockley SFs, triple Shockley SFs, and double Shockley SFs, respectively, based on the shear formation model. © 2009 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.physb.2009.08.189

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  190. Demonstration of SiC heterojunction bipolar transistors with AlN/GaN short-period superlattice widegap emitter

    Miyake H., Kimoto T., Suda J.

    Device Research Conference - Conference Digest, DRC     page: 281 - 282   2009.12

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    SiC bipolar-junction transistors (BJTs) are attractive candidates for high-power switching devices due to their high breakdown voltage and low on-resistance. However, SiC BJT has so far suffered from the limited current gain. An alternative device structure would be heterojunction bipolar transistors (HBTs). Because it is impossible to grow SixC 1-x solid solutions with x near 0.5, HBTs cannot be fabricated within group-IV semiconductors. Heteroepitaxial growth of wider bandgap group-III nitride (Al)GaN on SiC is one possible way to realize bandgap engineering in SiC devices. The fabrication of (Al)GaN/SiC HBTs was first reported by Pankove et al. [1] followed by several groups [2]. But any HBTs did not show common-emitter mode operation due to the large leakage at the emitterjunction. © 2009 IEEE.

    DOI: 10.1109/DRC.2009.5354933

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  191. Electrostatic-Actuated Suspended Ribbon Structure Fabricated in Single-Crystalline SiC by Selective Photoelectrochemical Etching

    Suda Jun, Watanabe Naoki, Fukunaga Katsuhiko, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 48 ( 11 )   2009.11

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    An electrostatic-actuated suspended ribbon structure composed of single-crystalline SiC is presented. All the main parts of the structure, namely, a suspended ribbon, posts, base plate, and electrical connections, are made of homoepitaxially grown single-crystalline 4H-SiC with selective ion implantations. Electrical isolation between the ribbon and the base plate is established with a pnp junction. The structure is fabricated by a combination of reactive ion etching (RIE) and doping-selective photoelectrochemical (PEC) etching. The suspended ribbon is actuated by applying a voltage between the ribbon and the base plate. © 2009 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.48.111101

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  192. Enhanced Drain Current of 4H-SiC MOSFETs by Adopting a Three-Dimensional Gate Structure

    Nanen Yuichiro, Yoshioka Hironori, Noborio Masato, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 56 ( 11 ) page: 2632 - 2637   2009.11

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    4H-SiC (0001) metal-oxide-semiconductor field-effect transistors (MOSFETs) with a 3-D gate structure, which has a top channel on the (0001) face and side-wall channels on the {1120} face, have been fabricated. The 3-D gate structures with a 1-5-μm width and a 0.8- μm height have been formed by reactive ion etching, and the gate oxide has been deposited by plasma-enhanced chemical vapor deposition and then annealed in N2O ambient at 1300 °C. The fabricated MOSFETs have exhibited good characteristics: The ION/IOFF ratio, the subthreshold swing, and VTH are 109, 210 mV/decade, and 3.5 V, respectively. The drain current normalized by the gate width is increasing with decreasing the gate width. The normalized drain current of a 1-μm-wide MOSFET is 16 times higher than that of a conventional planar MOSFET. © 2009 IEEE.

    DOI: 10.1109/TED.2009.2030437

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  193. Accurate Measurements of second-order nonlinear optical coefficients of 6H and 4H silicon carbide

    Sato H., Abe M., Shoji I., Suda J., Kondo T.

    Journal of the Optical Society of America B: Optical Physics   Vol. 26 ( 10 ) page: 1892 - 1896   2009.10

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    The second-order nonlinear optical coefficients of 4H-SiC and 6H-SiC have been measured by use of two second-harmonic generation methods, the rotational Maker-fringe and wedge techniques, at the fundamental wavelength of 1.064 μm. Measurements on high-quality (0001) and (112̄0) plane samples as well as rigorous analyses taking into account the multiple-reflection effects allowed us to accurately determine the magnitudes of the nonlinear optical coefficients. The obtained values are d31 = 6.7 pm/V, d15 = 6.5 pm/V, and d33 = -12.5 pm/V for 6H-SiC; and d31 = 6.5 pm/V, d15 = 6.7 pm/V, and d33 = -11.7 pm/V for 4H-SiC. © 2009 Optical Society of America.

    DOI: 10.1364/JOSAB.26.001892

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  194. 4H-SiC MISFETs with nitrogen-containing insulators

    Noborio Masato, Suda Jun, Beljakowa Svetlana, Krieger Michael, Kimoto Tsunenobu

    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE   Vol. 206 ( 10 ) page: 2374 - 2390   2009.10

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    4H-SiC MISFETs with nitrogen-containing insulators have been fabricated and characterized. Several techniques have been explored to incorporate nitrogen in the gate insulator in order to improve the density of interface states and thereby the channel mobility. The techniques are N 2O-grown oxides, the oxidation of a surface layer co-implanted with N + and Al +, deposited SiO 2 annealed in N 2O and NO, and deposited SiN x/SiO 2 annealed in N 2O. By optimizing the formation process of the gate insulators, MIS capacitors with N-containing insulators have demonstrated an interface state density close to the conduction band edge below 2 X10 11 cm -2 eV -1, which is one or two orders-of-magnitude lower than that of MOS capacitors with oxides grown in dry O 2. The channel mobility of the n-channel 4H-SiC(0001) MISFETs with N-containing insulators is increased to about 30 cm 2/Vs. In addition, an even higher channel mobility of 50 cm 2/Vs has been realized by utilizing N-containing insulators adequately processed on the 4H-SiC(0001) face. From the experimental results, the dominant scattering mechanisms in SiC MISFETs have been identified; Coulomb scattering and electron trapping at interface states dominate the channel mobility in SiC MOSFETs with thermally-grown and deposited SiO 2. The application of N- containing insulators to p-channel 4H-SiC MIS devices is also discussed. © 2009 WILEY-VCH Verlag GmbH & Co.

    DOI: 10.1002/pssa.200925247

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  195. A New Class of Step-and-Terrace Structure Observed on 4H-SiC(0001) after High-Temperature Gas Etching

    Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 2 ( 10 )   2009.10

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    Various interesting phenomena related to the step-and-terrace structures of crystal surfaces have been previously observed. In this paper, we report a unique phenomenon not observed previously: the formation of a new class of step-and-terrace structure on the 4H-SiC(0001) surface after high-temperature gas etching. The structure consists of a periodic array of pairs of 1-bilayer-height "down" steps and 5-bilayer-height "up" steps, in contrast to conventional step-and-terrace structures which consist of only "up" (or only "down") steps. We show that the newly observed (5 -1)-bilayer-height step-and-terrace structure originates from spiral etching at a screw dislocation. A mechanism for step-flow etching which conserves the "up"-and-"down" step pairs is also proposed. © 2009 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.2.101603

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  196. Accurate measurements of second-order nonlinear optical coefficients of 6H and 4H silicon carbide

    Sato Hiroaki, Abe Makoto, Shoji Ichiro, Suda Jun, Kondo Takashi

    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS   Vol. 26 ( 10 ) page: 1892 - 1896   2009.10

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  197. Anomalously Large Difference in Ga Incorporation for AlGaN Grown on the (11(2)over-bar0) and (1(1)over-bar00) Planes under Group-III-Rich Conditions

    Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS EXPRESS   Vol. 2 ( 9 )   2009.9

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    The Ga incorporation behavior of AlGaN layers grown on nonpolar planes has been investigated comparing the (112̄0) and (11̄00) planes. AlGaN growth was performed on 4H-SiC(112̄0) and (11̄00) substrates by molecular-beam epitaxy under group-III-rich conditions. The Ga composition of the AlGaN layers was evaluated by energy-dispersive X-ray spectroscopy analysis as well as X-ray diffraction and cathodoluminescence measurements. The GaN mole fraction x of Al1-xGaxN layers grown on the (11̄00) plane is 0.12 for the Ga flux ratio [JGa/(JAl + J Ga)] of 0.32 at 750 °C, while it is negligibly small (x < 0.01) for growth on the (112̄0) plane. © 2009 The Japan Society of Applied Physics.

    DOI: 10.1143/APEX.2.091003

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  198. In situ Gravimetric Monitoring of Thermal Decomposition and Hydrogen Etching Rates of 6H-SiC(0001) Si Face

    Akiyama Kazuhiro, Ishii Yasuhiro, Abe Sohei, Murakami Hisashi, Kumagai Yoshinao, Okumura Hironori, Kimoto Tsunenobu, Suda Jun, Koukitu Akinori

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 48 ( 9 ) page: 0955051 - 0955054   2009.9

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    The thermal decomposition and hydrogen etching of a 6H-SiC(0001) Si-face were directly monitored using an in situ gravimetric monitoring system. The monitoring of the weight change of the 6H-SiC Si-face using this system clarified the dependences of the thermal decomposition and hydrogen etching rates on the substrate temperature. Although the thermal decomposition of the 6H-SiC Si-face above 1400 °C generated a graphite layer since only the Si atom directly desorbs from the surface, the etching of the 6H-SiC Si-face by hydrogen did not form this layer, and both Si and C atoms react with hydrogen. Moreover, the surface reaction of the 6H-SiC Si face with H2 and the resultant surface morphology were found to change at approximately 1250 °C. © 2009 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.48.095505

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  199. P-Channel MOSFETs on 4H-SiC {0001} and Nonbasal Faces Fabricated by Oxide Deposition and N2O Annealing

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 56 ( 9 ) page: 1953 - 1958   2009.9

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    In this paper, we have investigated 4H-SiC p-channel metal-oxide-semiconductor field-effect transistors (MOSFETs) with deposited SiO2 followed by N2O annealing. In addition to deposited oxides, dry-O2-grown oxides and N2O-grown oxides were also adopted as the gate oxides of SiC p-channel MOSFETs. The MOSFETs have been fabricated on the 4H-SiC (0001), (0001), (0338), and (1120) faces. The (0001) MOSFETs with deposited oxides exhibited a relatively high channel mobility of 10 cm2, although a mobility of 7 cm2/V · swas obtained in the (0001) MOSFETs with N2O-grown oxides. The channel mobility was also increased by utilizing the deposited SiO2 in the MOSFETs fabricated on nonbasal faces, although the MOSFETs on (0001) were not operational. Compared with the thermally grown oxides, the deposited oxides annealed in N2O are effective in improving the performance of 4H-SiC p-channel MOSFETs. © 2009 IEEE.

    DOI: 10.1109/TED.2009.2025909

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  200. Mobility oscillation by one-dimensional quantum confinement in Si-nanowire metal-oxide-semiconductor field effect transistors

    Yoshioka Hironori, Morioka Naoya, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 106 ( 3 )   2009.8

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    Si-nanowire p -channel metal-oxide-semiconductor field effect transistors (MOSFETs), in which the typical cross section of the nanowire is a rectangular shape with 3 nm height and 18 nm width, have been fabricated and the current-voltage characteristics have been measured from 101 to 396 K. The transconductance has shown oscillation up to 309 K. The carrier transport has been theoretically analyzed, assuming that the acoustic phonon scattering is dominant. The electronic states have been determined from the effective mass approximation and the mobility from the relaxation time approximation as a function of the Fermi level. Relation between the gate voltage and the Fermi level has been estimated from the MOSFET structure. The calculated mobility has shown the oscillation with change in the Fermi level (the gate voltage), resulting in the transconductance oscillation. The oscillation originates from one-dimensional density of states (∝ E-0.5). © 2009 American Institute of Physics.

    DOI: 10.1063/1.3187803

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  201. 1580-V-40-m Omega . cm(2) Double-RESURF MOSFETs on 4H-SiC (000(1)over-bar)

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    IEEE ELECTRON DEVICE LETTERS   Vol. 30 ( 8 ) page: 831 - 833   2009.8

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    Double-reduced-surface-field (RESURF) MOSFETs with N2O-grown oxides have been fabricated on the 4H-SiC (0001 face. The double-RESURF structure is effective in reducing the drift resistance, as well as in increasing the breakdown voltage. In addition, by utilizing the 4H-SiC (0001̄) face, the channel mobility can be increased to over 30 cm2/V· s, and hence, the channel resistance is decreased. As a result, the fabricated MOSFETs on 4H-SiC (0001) have demonstrated a high breakdown voltage (VB) of 1580 V and a low on-resistance (RON of 40 mΩ · cm2. The figure-of-merit (VB2 of the fabricated device has reached 62 MW/cm2, which is the highest value among any lateral MOSFETs and is more than ten times higher than the "Si limit.". © 2009 IEEE.

    DOI: 10.1109/LED.2009.2023540

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  202. Temperature and doping dependencies of electrical properties in Al-doped 4H-SiC epitaxial layers

    Koizumi Atsushi, Suda Jun, Kimoto Tsunenobu

    JOURNAL OF APPLIED PHYSICS   Vol. 106 ( 1 )   2009.7

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    The free hole concentration and the low-field transport properties of Al-doped 4H-SiC epilayers with several acceptor concentrations grown on semi-insulating substrates have been investigated in the temperature range from 100 to 500 K by Hall-effect measurements. Samples have been grown by cold-wall chemical vapor deposition (CVD) in the Al acceptor concentration range from 3× 1015 to 5.5× 1019 cm-3. The dependencies of the acceptor ionization ratio at 300 K and the ionization energy on the acceptor concentration were estimated. Numerical calculations of the hole Hall mobility and the Hall scattering factor have been performed based on the low-field transport model using relaxation-time approximation. At the low acceptor concentrations, the acoustic phonon scattering dominates the hole mobility at 300 K. At the high acceptor concentrations, on the other hand, the neutral impurity scattering dominates the mobility. A Caughey-Thomas mobility model with temperature dependent parameters is used to describe the dependence of the hole mobilities on the acceptor concentration, and the physical meanings of the parameters are discussed. © 2009 American Institute of Physics.

    DOI: 10.1063/1.3158565

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  203. Observation of novel defect structure in 2H-AlN grown on 6H-SiC(0001) substrates with 3-bilayer-height step-and-terrace structures

    Okumura Hironori, Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE   Vol. 206 ( 6 ) page: 1187 - 1189   2009.6

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    250 nm thick AlN layers without a nucleation layer were grown directly on 6H-SiC(0001) with 3-bilayer-height steps by rf-plasma-assisted molecular-beam epitaxy. The structure and morphology of the AlN layers have been studied using atomic force microscopy, X-ray diffraction and transmission electron microscopy. Two different types of unique defect structures were observed. Rows of pure-edge-type threading dislocations were observed along the pre-existing step-edges of the SiC substrate for AlN grown on as-gas-etched SiC substrates, while the planar defects threading through the AlN layer were observed at the step-edges of the substrate for AlN on SiC with sacrificial oxidation. We concluded that these planar defects were the stacking mismatch boundaries due to the difference in stacking sequence of AlN layers on different SiC terraces. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssa.200880934

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  204. Triple Shockley type stacking faults in 4H-SiC epilayers

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 94 ( 9 )   2009.3

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    4H-SiC epilayers have been characterized by microphotoluminescence (micro-PL) spectroscopy and micro-PL intensity mapping at room temperature. A type of stacking fault (SF) with a peak emission wavelength at 480 nm (2.58 eV) has been identified. The shape of this SF is triangular revealed by the micro-PL intensity mapping. Conventional and high-resolution transmission electron microscopies have been carried out to investigate the structure of this SF. Its stacking sequence is determined as (3,5) in Zhdanov's notation, which is consistent with that of the triple Shockley SF. The formation mechanism of this SF is also discussed. © 2009 American Institute of Physics.

    DOI: 10.1063/1.3095508

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  205. Systematic Investigation of c-Axis Tilt in GaN and AlGaN Grown on Vicinal SiC(0001) Substrates

    Suda Jun, Miyake Hiroki, Amari Koichi, Nakano Yuki, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 48 ( 2 )   2009.2

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    High-resolution X-ray diffraction measurements of GaN and AlGaN grown on 4H- and 6H-SiC(0001) vicinal substrates with rnisorientation angles of up to 9° are presented. Growth of (Al)GaN was carried out by plasma-assisted molecular beam epitaxy. The c-axis tilt, i.e., inclination of the (Al)GaN c-axis relative to that of SiC, was systematically investigated. The inclination angle clearly depended on the SiC substrate misorientation angle, while it was independent of the (Al)GaN growth temperature, SiC polytype, and substrate rnisorientation direction. The behavior observed for both GaN and AlGaN is in excellent agreement with the model proposed previously by Nagai for the InGaAs/GaAs system. © 2009 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.48.020202

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  206. 5 kV lateral double RESURF MOSFETs on 4H-SiC (000-1)C face

    Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 615 617   page: 757 - 760   2009

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    SiC lateral double RESURF MOSFETs have been fabricated on the 4H-SiC (000-1)C face. By utilizing the C face, the channel resistance can be reduced because the C-face MOSFETs show higher channel mobility than the Si-face MOSFETs. In addition, by employing the double RESURF structure, the drift resistance is decreased and the breakdown voltage is increased with increasing the RESURF doses. The fabricated RESURF MOSFETs on the 4H-SiC (000-1)C face have demonstrated a low on-resistance of 40 mΩcm2 at an oxide field of 3 MV/cm and a breakdown voltage of 1580 V at zero gate bias. The figure-of-merit of the MOSFET is 62 MW/cm2, which is more than 10 times better than the conventional "Si limit" and the highest value among any lateral MOSFETs to date. © (2009) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.615-617.757

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  207. Bevel mesa combined with implanted junction termination structure for 10 kV SiC PiN diodes

    Hiyoshi T., Hori T., Suda J., Kimoto T.

    Materials Science Forum   Vol. 600-603   page: 995 - 998   2009

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    A 10 kV 4H-SiC PiN diode with an improved junction termination structure has been fabricated. An improved bevel mesa structure, nearly vertical side-wall at the edge of pn junction and rounded corner at mesa bottom, has been formed by reactive ion etching (RIE). The junction termination extension (JTE) region has been optimized by device simulation, and simulated breakdown voltage has been compared with experimental results. The locations of electric field crowding and diode breakdown have been discussed. © (2009) Trans Tech Publications, Switzerland.

    DOI: 10.4028/3-908453-11-9.995

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  208. Accurate measurements of second-order nonlinear-optical coefficients of silicon carbide

    Sato H., Shoji I., Suda J., Kondo T.

    Materials Science Forum   Vol. 615 617   page: 315 - 318   2009

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    Second-order nonlinear-optical coefficients of 4H and 6H-SiC have been measured with the wedge technique. Using high-quality (11-20) samples as well as performing rigorous measurements and analyses, the three independent components, d31 (= d32), d15 (= d 24), and d33, have been accurately determined. We have found that the nonlinear-optical coefficients are nearly the same between the measured 4H and 6H-SiC samples within the experimental accuracy; d31 = 5.4 pm/V, d15 = 6.2 pm/V, and d33 = 9.7pm/V. © (2009) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.615-617.315

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  209. Determination of the thermo-optic coefficients of GaN and AlN up to 515 degrees C

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 6, SUPPL 2   Vol. 6 ( SUPPL. 2 ) page: S776 - S779   2009

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Physica Status Solidi (C) Current Topics in Solid State Physics  

    The refractive index dispersions of hexagonal GaN and AlN have been investigated to determine the thermo-optic coefficients. Measurements were conducted at temperatures ranging from room temperature up to 515 °C in the wavelength range from the near band-edge to 1000 nm. Optical interference measurements with vertical incident configuration were employed to precisely evaluate the ordinary refractive indices. Optical simulation of AlGaN/GaN distributed Bragg reflectors was also carried out by using the obtained thermo-optic coefficients. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssc.200880937

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  210. Enhanced channel mobility in 4H-SiC MISFETs by utilizing deposited SiN/SiO<inf>2</inf> stack gate structures

    Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 600-603   page: 679 - 682   2009

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    Deposited SiN/SiO2 stack gate structures have been investigated to improve the 4H-SiC MOS interface quality. Capacitance-voltage measurements on fabricated SiN/SiO2 stack gate MIS capacitors have indicated that the interface state density is reduced by post-deposition annealing in N 2O at 1300°C. The usage of thin SiN and increase in N 2O-annealing time lead to a low interface state density of 1×1011 cm-2eV-1 at EC - 0.2 eV. Oxidation of the SiN during N2O annealing has resulted in improvement of SiC MIS interface. The fabricated SiN/SiO2 stack gate MISFETs demonstrate a high channel mobility of 32 cm2/Vs on (0001)Si face and 40 cm2/Vs on (000-1)C face. © (2009) Trans Tech Publications, Switzerland.

    DOI: 10.4028/3-908453-11-9.679

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  211. High channel mobility in P-channel MOSFETs fabricated on 4H-SiC (0001) and non-basal faces

    Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 615 617   page: 789 - 792   2009

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    P-channel MOSFETs have been fabricated on 4H-SiC (0001) face as well as on 4H-SiC (03-38) and (11-20) faces. The gate oxides were formed by thermal oxidation in dry N2O ambient, which is widely accepted to improve the performance of n-channel SiC MOSFETs. The p-channel SiC MOSFETs with N 2O-grown oxides on 4H-SiC (0001), (03-38), and (11-20) faces show a channel mobility of 7 cm2/Vs, 11 cm2/Vs, and 17 cm 2/Vs, respectively. From the quasi-static C-V curves measured by using gate-controlled diodes, the interface state density was calculated by an original method. The interface state density was the lowest at the SiO 2/4H-SiC (03-38) interface (about 1×1012 cm -2eV-1 at EV + 0.2 eV). The authors have applied deposited oxides to the 4H-SiC p-channel MOSFETs. The (0001), (03-38), and (11-20) MOSFETs with deposited oxides exhibit a channel mobility of 10 cm 2/Vs, 13 cm2/Vs, and 17 cm2/Vs, respectively. The deposited oxides are one of effective approaches to improve both n-channel and p-channel 4H-SiC MOS devices. © (2009) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.615-617.789

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  212. Improved on-current of 4H-SiC MOSFETs with a three-dimensional gate structure

    Nanen Y., Yoshioka H., Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 615 617   page: 753 - 756   2009

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    4H-SiC (0001) MOSFETs with a three-dimensional gate structure, which has a top channel on the (0001) face and side-wall channels on the {11-20} face have been fabricated. The three-dimensional gate structures with a 1-5 μm width and 0.8 μm height have been formed by reactive ion etching, and the gate oxide has been deposited by plasma-enhanced chemical vapor deposition and then annealed in N2O ambient at 1300°C. The fabricated MOSFETs have exhibited superior characteristics: ION / IOFF, the subthreshold swing and VTH are 1010, 250 mV/decade and 3.5 V, respectively. The drain current normalized by the gate width is increasing with decreasing the gate width. The normalized drain current of a 1 μm-wide MOSFET is ten times higher than that of a conventional planar MOSFET. © (2009) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.615-617.753

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  213. Improved current gain in GaN/SiC Heterojunction Bipolar Transistors by insertion of ultra-thin AlN layer at emitter-junction

    Miyake H., Kimoto T., Suda J.

    Materials Science Forum   Vol. 615 617   page: 979 - 982   2009

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    GaN/SiC Heterojunction Bipolar Transistors (HBTs) with ultra-thin AlN insertion layers at the n-GaN/p-SiC emitter junction are proposed to improve carrier injection efficiency. The current-voltage characteristics of n-GaN/AlN/p-SiC heterojunctions have exhibited very small reverse leakage and good rectification. The capacitance-voltage measurement have revealed that the conduction band offset between n-GaN and p-SiC has been reduced from -0.74 eV to -0.54 eV by insertion of AlN, indicating that the GaN/AlN/SiC heterojunction may show better electron-injection efficiency. A significantly improved common-base current gain (α∼0.2) is obtained for GaN/AlN/SiC HBTs with initial N* pre-irradiation, while it was very low (α∼0.001) for GaN/SiC HBTs without AlN layers. © (2009) Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/MSF.615-617.979

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  214. Spatial profiling of planar defects in 4H-SiC epilayers using micro-photoluminescence mapping

    Feng G., Suda J., Kimoto T.

    Materials Science Forum   Vol. 615 617   page: 245 - 250   2009

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    The micro-photoluminescence (micro-PL) spectroscopy and its intensity mapping have been utilized to investigate the planar defects, stacking faults (SFs), in 4H-SiC epilayers. Strong PL emissions from the SFs are observed even at room temperature. It is found that each kind of SF shows the distinct PL emission behaviours. Three kinds of SFs: intrinsic Frank SFs, double Shockley SFs, and in-grown SFs, have been identified in the samples based on the micro-PL spectra. At the same time, the micro-PL intensity mapping at the emission band of each SF has been performed to spatially profile the SFs. The shapes, distributions, and densities of SFs in the epilayers are then presented. The PL emission behaviours of each SF at low temperature are also studied. © (2009) Trans Tech Publications, Switzerland.

    DOI: 10.4028/www.scientific.net/MSF.615-617.245

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  215. The temperature dependence of the refractive indices of GaN and AlN from room temperature up to 515 degrees C

    Watanabe Naoki, Kimoto Tsunenobu, Suda Jun

    JOURNAL OF APPLIED PHYSICS   Vol. 104 ( 10 )   2008.11

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    The temperature dependence of the refractive indices of GaN and AlN was investigated in the wavelength range from the near band edge (367 nm for GaN and 217 nm for AlN) to 1000 nm and the temperature range from room temperature to 515 °C. Optical interference measurements with vertical incident configuration were employed to precisely evaluate the ordinary refractive indices. © 2008 American Institute of Physics.

    DOI: 10.1063/1.3021148

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  216. N2O-grown oxides/4H-SiC (0001), (0338), and (1120) interface properties characterized by using p-type gate-controlled diodes

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 93 ( 19 )   2008.11

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    The N2 O -grown SiO2 /4H-SiC (0001), (033̄8), and (112̄0) interface properties in p -channel metal-oxide-semiconductor field-effect transistors (MOSFETs) have been characterized by using gate-controlled diodes. Although the inversion layer is not formed in simple SiC MOS capacitors at room temperature due to its large bandgap, a standard low frequency capacitance-voltage (C-V) curve can be obtained for the gate-controlled diodes, owing to the supply of minority carriers from the source region. From the quasistatic C-V curves measured by using gate-controlled diodes, the interface state density has been evaluated by an original method proposed in this study. The interface state density near the valence band edge evaluated by the method is the lowest at the oxides/ 4H-SiC (033̄8) interface. Comparison with the channel mobility is also discussed. © 2008 American Institute of Physics.

    DOI: 10.1063/1.3028016

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  217. Surface Morphologies of 4H-SiC(11(2)over-bar0) and (1(1)over-bar00) Treated by High-Temperature Gas Etching

    Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 47 ( 11 ) page: 8388 - 8390   2008.11

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    The impact of HCl/H2 high-temperature gas-etching on the surface morphologies of 4H-SiC(1120) and (1100) faces is investigated by atomic force microscopy (AFM). Very flat surfaces are obtained on both (1120) and (11̄00) faces after gas-etching when the substrate surfaces are initially treated by chemical mechanical polishing to remove polishing scratches. The root-mean square roughness values of gas-etched (112̄0) and (11̄00) substrates are 0.07 and 0.11nm, respectively. Within AFM resolution limits no atomic steps are observed on the very flat surfaces of (1120) substrates. On the other hand, clear step-and-terrace structures are observed on (1100) substrates after gas-etching and the height of the steps (2.7Å) corresponding to the lattice spacing between 4H-SiC(1100) planes (= √3a/2). © 2008 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.47.8388

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  218. Comprehensive analysis of multiple-reflection effects on rotational Maker-fringe experiments

    Abe M., Shoji I., Suda J., Kondo T.

    Journal of the Optical Society of America B: Optical Physics   Vol. 25 ( 10 ) page: 1616 - 1624   2008.10

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of the Optical Society of America B: Optical Physics  

    What we believe to be a new mathematical procedure has been proposed for analyzing the rotational Maker-fringe data taking account of the effects of multiple reflections and interferences of the fundamental and second-harmonic beams in anisotropic plane-parallel plates. In the present formalisms partial overlaps of the fundamental and second-harmonic beams are fully included. A comparison between numerical simulations based on the proposed formalisms and experimental data obtained for a high-quality (0001) plane-parallel plate of 6H-SiC revealed the validity of our theory. We have determined the magnitudes of the nonlinear optical coefficients of 6H-SiC as d31=d32 = 6.7±0.8 pm/V, d15=d24 = 6.4±1.1 pm/V, and d33 = -9.7±8.0 pm/V. © 2008 Optical Society of America.

    DOI: 10.1364/JOSAB.25.001616

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  219. Improved Performance of 4H-SiC Double Reduced Surface Field Metal-Oxide-Semiconductor Field-Effect Transistors by Increasing RESURF Doses

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS EXPRESS   Vol. 1 ( 10 ) page: 1014031 - 1014033   2008.10

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    For further improvement of lateral power devices, 4H-SiC double reduced surface field (RESURF) metal-oxide-semiconductor field-effect transistors (MOSFETs) with high doses in RESURF region have been fabricated and characterized. The drift resistance was decreased and the breakdown voltage was increased with increasing RESURF doses, although breakdown occurs in the oxide when the RESURF doses are too high. The increase of drift resistance in double RESURF MOSFETs at elevated temperature was smaller than that in single RESURF MOSFETs, due to the higher doping concentration in the RESURF region. The fabricated 4H-SiC(0001) double RESURF MOSFETs exhibited a breakdown voltage (VB) of 1540V and an on-resistance (RON) of 55mΩcm2. The figure-of-merit (VB2/R ON) of the fabricated device is 43MW/cm2, which is the highest value compared with those reported in lateral MOSFETs. © 2008 The Japan Society of Applied Physics.

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  220. Improvement of Channel Mobility in Inversion-Type n-Channel GaN Metal-Oxide-Semiconductor Field-Effect Transistor by High-Temperature Annealing

    Yamaji Kazuki, Noborio Masato, Suda Jun, Kimoto Tsunenobu

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 47 ( 10 ) page: 7784 - 7787   2008.10

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    Inversion- and depletion-type GaN metal-oxide-semiconductor field-effect transistors (MOSFETs) were fabricated on p- and n--type GaN epitaxial layers, respectively, grown on n+-type on-axis 4H-SiC(0001) substrates. After gate SiO2 was deposited by plasma-enhanced chemical vapor deposition at 350 °C, high-temperature annealing in N2 was carried out to modify the interface. The channel mobility was enhanced with increasing annealing temperature. The device annealed in N2 at 1100 °C after SiO2 deposition showed an inversion channel mobility of 108cm2.V-1.s-1 at a gate voltage of 15 V. The authors also fabricated MOS capacitors on n--type GaN and characterized the interface state density at the SiO2/GaN interface from capacitance-voltage measurements using the Terman method, of which density was estimated to be in the range of (6-10) × 1011 cm -2.eV-1 at an energy level of 0.2eV below the conduction band edge. The interface state density tended to decrease with increasing annealing temperature, resulting in the improvement of the channel mobility. © 2008 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.47.7784

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  221. Comprehensive analysis of multiple-reflection effects on rotational Maker-fringe experiments

    Abe Makoto, Shoji Ichiro, Suda Jun, Kondol Takashi

    JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS   Vol. 25 ( 10 ) page: 1616 - 1624   2008.10

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  222. Impact of surface step heights of 6H-SiC (0001) vicinal substrates in heteroepitaxial growth of 2H-AlN

    Okumura H., Horita M., Kimoto T., Suda J.

    APPLIED SURFACE SCIENCE   Vol. 254 ( 23 ) page: 7858 - 7860   2008.9

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    Impact of step height of silicon carbide (SiC) substrates on heteroepitaxial growth of aluminum nitride (AlN) was investigated. Step-and-terrace structures with various step heights, 6 monolayer (ML), 3ML and 1ML, were formed on 6H-SiC (0 0 0 1) vicinal substrates by high-temperature gas etching. 2H-AlN layers were grown on the substrate by plasma-assisted molecular-beam epitaxy (MBE) and then these layers were characterized by atomic-force microscopy (AFM) and X-ray diffraction (XRD). High-quality AlN can be grown on SiC substrates with 6ML- and 3ML-height step, while AlN grown on SiC substrates with 1ML-height step exhibited inferior crystalline quality. A model for high-quality AlN growth on SiC substrates with 3ML-height step is proposed. © 2008 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.apsusc.2008.02.165

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  223. 4H-SiC double RESURF MOSFETs with a record performance by increasing RESURF dose

    Noborio M., Suda J., Kimoto T.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs     page: 263 - 266   2008.9

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    For further improvement of lateral power devices, 4H-SiC double RESURF MOSFETs with high RESURF doses have been fabricated and characterized. The drift resistance was decreased and the breakdown voltage was increased with increasing RESURF doses, although oxide brekaodown occurs when the RESURF doses are too high. The increase in drift resistance at elevated temperature was smaller for double RESURF MOSFETs than single RESURF MOSFETs, due to the higher doping concentration in the RESURF region. The fabricated 4H-SiC (0001) double RESURF MOSFETs exhibited a breakdown voltage (VB) of 1430 V and an on-resistance (RON) of 57 mΩcm2, and the MOSFETs on 4H-SiC (0001) face demonstrated a higher breakdown voltage of 1550 V and a lower on-resistance of 54 mΩcm2. The figure-of-merit (V B2/RON) of the fabricated device on Si face and C face is 36 MW/cm2 and 44 MW/cm2, respectively, which is the highest value among any lateral MOSFETs ever reported. ©2008 IEEE.

    DOI: 10.1109/ISPSD.2008.4538949

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  224. Nonpolar 4H-AlN grown on 4H-SiC (1(1)over-bar00) with reduced stacking fault density realized by persistent layer-by-layer growth

    Horita Masahiro, Kimoto Tsunenobu, Suda Jun

    APPLIED PHYSICS LETTERS   Vol. 93 ( 8 )   2008.8

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    Nonpolar AlN layers were grown on 4H-SiC (1 1- 00) substrates by plasma-assisted molecular-beam epitaxy. By using SiC substrates with well-formed step-and-terrace structures, stable layer-by-layer growth of 4H-AlN (1 1- 00) can be realized. The layer-by-layer growth is confirmed by observations of anisotropic two-dimensional AlN islands on the grown surface as well as persistent reflection high-energy electron diffraction intensity oscillations. Cross-sectional transmission electron microscopy observations reveal that stacking fault generation during growth is suppressed and the stacking fault density is reduced to 1× 106 cm-1. © 2008 American Institute of Physics.

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  225. 4H-SiC MIS capacitors and MISFETs with deposited SiNx/SiO2 stack-gate structures

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 55 ( 8 ) page: 2054 - 2060   2008.8

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    SiNx/SiO2 stack-gate structures, followed by N2O annealing, have been investigated to improve the 4H-SiC metal - insulator - semiconductor (MIS) interface quality. Capacitance - voltage measurements on fabricated stack-gate MIS capacitors have indicated that the interface trap density is reduced by postdeposition annealing in N2O at 1300 °C. When the MIS capacitor with a SiNx/SiO2 thickness of 10 nm/50 nm was annealed in N2O for 2 h, the interface trap density at EC - 0.2 eV is below 1 × 1011 cm-2eV-1. Oxidation of SiNx during N2O annealing has resulted in the improvement of SiCMIS interface characteristics, as well as dielectric properties. The fabricated MISFETs with SiNx/SiO2 stack-gate structure annealed in N2O demonstrate a reasonably high channel mobility of 32 cm2/V · s on the (0001)Si face and 40 cm2/V · s on the (0001)C face. © 2008 IEEE.

    DOI: 10.1109/TED.2008.926644

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  226. Simulation and experimental study on the junction termination structure for high-voltage 4H-SiC PiN diodes

    Hiyoshi Toru, Hori Tsutomu, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 55 ( 8 ) page: 1841 - 1846   2008.8

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    Designing and fabrication of 10-kV 4H-SiC PiN diodes with an improved junction termination structure have been investigated. An improved bevel mesa structure and a single-zonejunction termination extension (JTE) have been employed to achieve a high breakdown voltage (≥10 kV)). The improved bevel mesa structure, nearly a vertical sidewall at the edge of the p-n junction and a gradual slope at the mesa bottom, has been fabricated by reactive ion etching. The effectiveness of the improved bevel mesa structure has been experimentally demonstrated. The JTE region has been optimized by device simulation, and the JTE dose dependence of the breakdown voltage has been compared with experimental results. A 4H-SiC PiN diode with a JTE dose of 1.1 × 1013 cm-2 has exhibited a high blocking voltage of 10.2 kV. The locations of electric field crowding and breakdown are also discussed. © 2008 IEEE.

    DOI: 10.1109/TED.2008.926643

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  227. Hydrogen implantation and annealing-induced exfoliation process in SiC wafers with various crystal orientations

    Senga Kei, Kimoto Tsunenobu, Suda Jun

    JAPANESE JOURNAL OF APPLIED PHYSICS   Vol. 47 ( 7 ) page: 5352 - 5354   2008.7

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    The influence of time and temperature were investigated in wafer exfoliation process by hydrogen implantation for 4H-SiC wafers with various orientations, on-axis and 8° off-axis (0001), (11̄00), and (112̄0). Void formation occurs isotropically for all the orientations investigated. The blistering rate (R) of 4H-SiC was found to be dependent on the crystal orientation of the wafer; RSiC(0001) on-axis ≲ R SiC(0001) 8° off-axis ≲ RSiC(11̄00) < RSiC(11̄20). The blistering rate of (112̄0) is faster than those of the other three orientations. This result suggests that different annealing conditions are needed when fabricating SiC-on-insulator wafers of different crystal orientations. © 2008 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.47.5352

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  228. Lifetime-killing defects in 4H-SiC epilayers and lifetime control by low-energy electron irradiation

    Kimoto Tsunenobu, Danno Katsunori, Suda Jun

    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS   Vol. 245 ( 7 ) page: 1327 - 1336   2008.7

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    Carrier lifetimes in n-type 4H-SiC epilayers have been investigated by differential microwave photoconductance decay measurements. Through a correlation study between lifetime and various deep levels, the Z1/2 and/or EH6/7 centers have been identified as effective recombination centers. When the Z1/2 (and EH6/7) concentration is higher than 1013 cm-3, the inverse carrier lifetime is in proportion to the trap concentration, and the lifetime increases with increasing excitation intensity (density of irradiated photons). Alternartively, other recombination processes limit the lifetime when the Z1/2 concentration is less than 1013 cm-3. In this case, the carrier lifetime is decreased by increasing the excitation intensity. Surface recombination and recombination in the substrate have been suggested based on numerical analyses as the other recombination paths. By controlling the Z 1/2 (and EH6/7) concentration by low-energy electron irradiation, lifetime control has been achieved. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

    DOI: 10.1002/pssb.200844076

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  229. Characterization of stacking faults in 4H-SiC epilayers by room-temperature microphotoluminescence mapping

    Feng Gan, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 92 ( 22 )   2008.6

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    The stacking faults (SFs) in 4H-SiC epilayers have been characterized by microphotoluminescence spectroscopy and photoluminescence (PL) intensity mapping at room temperature. Three kinds of SFs, intrinsic Frank SFs, double Shockley SFs, and in-grown SFs, have been identified in the samples. Each kind of SF shows the distinct PL emission located at 420, 500, and 455 nm, respectively. The shapes and distributions of SFs have been profiled by micro-PL intensity mapping. The formation mechanisms of each SF are also discussed. © 2008 American Institute of Physics.

    DOI: 10.1063/1.2937097

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  230. 4H-SiC double RESURF MOSFETs with a record performance by increasing RESURF dose

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    ISPSD 08: PROCEEDINGS OF THE 20TH INTERNATIONAL SYMPOSIUM ON POWER SEMICONDUCTOR DEVICES & ICS     page: 263 - 266   2008

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  231. Temperature dependence of electrical properties of NiO thin films for Resistive Random Access Memory

    Suzuki Ryota, Suda Jun, Kimoto Tsunenobu

    MATERIALS SCIENCE AND TECHNOLOGY FOR NONVOLATILE MEMORIES   Vol. 1071   page: 69 - 74   2008

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  232. Fabrication and electronic characteristics of silicon nanowire mosfets

    Yoshioka H., Nanen Y., Suda J., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 1080   page: 90 - 95   2008

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    The n-type silicon nanowire MOSFETs with a nanowire shape being triangular or trapezoidal, have been fabricated on SOI substrates and characterized. The height and bottom-width of the triangular nanowire has been 10 nm and 19 nm, respectively. The devices have shown good gate control, such as a nearly ideal subthreshold slope of 63 mV/decade, high Ion/Ioff ratio of 107, and small drain-induced barrier lowering of 5 mV/V at room temperature. The low field mobility of triangular nanowire has been estimated to be 130 cm2/V·s and shown no difference with the change of the nanowire shape and direction within the investigated range. © 2008 Materials Research Society.

    DOI: 10.1557/proc-1080-o12-02

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  233. Temperature dependence of electrical properties of NiO thin films for resistive random access memory

    Suzuki R., Suda J., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 1071   page: 69 - 74   2008

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    Temperature dependence of electrical properties in NiO thin films for ReRAM applications has been investigated. I-V measurements have been carried out in the temperature range from 100K to 523K. The resistance in the high resistance state (HRS) is almost independent of temperature below 250K, whereas it decreases with an activation energy of 300 meV above 250K. Hopping conduction and band conduction may be dominant in the low- and high-temperature range, respectively. Admittance spectroscopy on the NiO/n+-Si structure reveals the existence of a high density of traps, which may contribute to the conduction in HRS. In the low resistance state (LRS), however, the resistance slightly increased in the whole temperature range and the trend is similar to that of metallic Ni film, indicating the metallic Ni defects is related to the conduction in LRS. The Pt/NiO/Pt structure demonstrated stable resistance switching even at temperature as high as 250°C or higher. Since other competitive nonvolatile memories will face severe difficulty in high-temperature operation, the present ReRAM shows promise for high-temperature application. © 2008 Materials Research Society.

    DOI: 10.1557/proc-1071-f08-08

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  234. 4H-SiC lateral double RESURF MOSFETs with low ON resistance

    Noborio Masato, Suda Jun, Kimoto Tsunenobu

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 54 ( 5 ) page: 1216 - 1223   2007.5

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    Designing and fabrication of 4H-SiC (0001) lateral MOSFETs with a double reduced surface field (RESURF) structure have been investigated to reduce on resistance. In order to achieve high breakdown voltage, a two-zone RESURF structure was also employed in addition to the double RESURF structure. The simulated double RESURF MOSFETs with optimum doses exhibit slightly higher breakdown voltage and lower drift resistance than the simulated single RESURF MOSFETs. The double RESURF structure is attractive to suppress oxide breakdown at gate edge. After the device simulation for dose optimization, the 4H-SiC two-zone double RESURF MOSFETs have been fabricated by using a self-aligned process. The fabricated MOSFET has demonstrated a high breakdown voltage of 1380 V and a low on resistance of 66 mΩ · cm2 (including a drift resistance of 24 mΩ · cm2). The drift resistance of the fabricated double RESURF MOSFETs is only 50% or even lower than that of the single RESURF MOSFETs. © 2007 IEEE.

    DOI: 10.1109/TED.2007.894249

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  235. A comparative study of nonpolar a-plane and m-plane AlN grown on 4H-SiC by plasma-assisted molecular-beam epitaxy

    Suda J., Horita M., Armitage R., Kimoto T.

    JOURNAL OF CRYSTAL GROWTH   Vol. 301 ( SPEC. ISS. ) page: 410 - 413   2007.4

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    AlN has been grown on 4H-SiC m-plane (1 over(1, -) 0 0) and a-plane (1 1 over(2, -) 0) substrates by RF-plasma-assisted molecular-beam epitaxy. Similarities and differences between the two growth orientations are discussed. High-quality AlN can be obtained in both orientations when grown in the metastable 4H-crystal structure. For both epilayer orientations Al-rich conditions were necessary to stabilize the 4H-polytype. 4H-AlN for both growth directions shows very narrow X-ray rocking curves widths less than 100 arcsec. a-plane 4H-AlN exhibited a much smoother morphology than m-plane 4H-AlN. On the other hand, reflection high-energy diffraction intensity oscillations in the initial growth stage were observed only for m-plane AlN. © 2007 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jcrysgro.2006.11.287

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  236. Reduction in potential barrier height of AlGaN/GaN heterostructures by SiN passivation

    Onojima N., Higashiwaki M., Suda J., Kimoto T., Mimura T., Matsui T.

    JOURNAL OF APPLIED PHYSICS   Vol. 101 ( 4 )   2007.2

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    SiN passivation on AlGaNGaN heterostructures was carried out using catalytic or plasma-enhanced chemical vapor deposition (Cat-CVD or PECVD), which has been found to increase two-dimensional electron gas (2DEG) density. The 2DEG density can be closely related to AlGaN surface properties via polarization effects. AlGaN potential barrier heights of AlGaNGaN heterostructures with and without SiN passivation were systematically investigated using x-ray photoelectron spectroscopy (XPS) and capacitance-voltage (C-V) measurements. The results for the XPS and C-V measurements were consistent and demonstrated that a reduction in the AlGaN potential barrier height was actually induced by SiN passivation. Furthermore, Cat-CVD SiN passivation lowered the AlGaN potential barrier height more significantly than PECVD SiN passivation did, suggesting that the passivation method can influence the AlGaN potential barrier height. © 2007 American Institute of Physics.

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  237. m-plane GaN layers grown by rf-plasma assisted molecular beam epitaxy with varying Ga/N flux ratios on m-plane 4H-SiC substrates

    Armitage R., Horita M., Suda J., Kimoto T.

    JOURNAL OF APPLIED PHYSICS   Vol. 101 ( 3 )   2007.2

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    A series of m -plane GaN layers with the Ga beam-equivalent pressure (BEP) as the only varied parameter was grown by rf-plasma assisted molecular beam epitaxy on m -plane 4H-SiC substrates using AlN buffer layers. The smoothest growth surfaces and most complete film coalescence were found for the highest Ga BEP corresponding to the Ga droplet accumulation regime. However, better structural quality as assessed by x-ray rocking curves was observed for growth at a lower Ga BEP value below the droplet limit. The variation of rocking curve widths for planes inclined with respect to the epilayer c axis followed a different trend with Ga BEP than those of reflections parallel to the c axis. The GaN layers were found to exhibit a large residual compressive strain along the a axis. © 2007 American Institute of Physics.

    DOI: 10.1063/1.2435806

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  238. Accurate determination of nonlinear optical coefficients of hexagonal silicon carbide of polytype 6H

    Abe M., Maruyama K., Sato H., Tanaka H., Suda J., Shoji I., Kondo T.

    Optics InfoBase Conference Papers     2007

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    Nonlinear optical coefficients of 6H-SiC have been measured with much improved accuracy using high quality single crystalline plane-parallel plates by the Maker-fringe technique combined with theoretical analysis taking into account of the multiple-reflection effect. © 2007 Optical Society of America.

    DOI: 10.1364/nlo.2007.we25

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  239. Impact of acceptor concentration on electronic properties of n<sup>+</sup>-GaN/p<sup>+</sup>-SiC heterojunction for gan/sic heterojunction bipolar transistor

    Amari K., Suda J., Kimoto T.

    Materials Science Forum   Vol. 556-557   page: 1039 - 1042   2007

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    The electrical properties of n+-GaN/p+-SiC heterojunction diodes have been investigated by varying the acceptor concentration of p+-SiC epilayers (Na) and polytype of SiC (4H- and 6H-SiC). The current-voltage (I-V) characteristics of diodes with Na ~ 1x1019 cm-3 were dominated by tunneling-assisted current. The diodes with Na ~ 1x1018 cm-3 exhibit excellent characteristics and 6H-SiC may be a better choice from a view point of electron injection into p-SiC base. Compared to previous investigations (Na<1016cm-3), we could obtain good rectification with p-SiC doped to two-order-of-magnitude higher acceptor concentration.

    DOI: 10.4028/www.scientific.net/MSF.556-557.1039

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  240. Impact of acceptor concentration on electronic properties of n <sup>+</sup>-GaN/p<sup>+</sup>-SiC heterojunction for GaN/SiC heterojunction bipolar transistor

    Amari K., Suda J., Kimoto T.

    Materials Science Forum   Vol. 556-557   page: 1039 - 1042   2007

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    The electrical properties of n+-GaN/p+-SiC heterojunction diodes have been investigated by varying the acceptor concentration of P+-SiC epilayers (Na) and polytype of SiC (4H- and 6H-SiC). The current-voltage (I-V) characteristics of diodes with Na ∼1×1019 cm-3 were dominated by tunneling-assisted current. The diodes with Na ∼ 1×10 18 cm-3 exhibit excellent characteristics and 6H-SiC may be a better choice from a view point of electron injection into p-SiC base. Compared to previous investigations (Na<1016cm -3), we could obtain good rectification with p-SiC doped to two-order-of-magnitude higher acceptor concentration.

    DOI: 10.4028/0-87849-442-1.1039

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  241. Lateral 4H-SiC MOSFETs with low on-resistance by using two-zone double RESURF structure

    Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 556-557   page: 815 - 818   2007

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    4H-SiC lateral MOSFETs with a double reduced surface field (RESURF) structure have been fabricated in order to reduce drift resistance. A two-zone RESURF structure was also employed in addition to double RESURF structure for achieving both high breakdown voltage and low on-resistance. After device simulation for dose optimization, 4H-SiC two-zone double RESURF MOSFETs have been fabricated. The fabricated MOSFETs block 1380 V and exhibit a low on-resistance of 66 Ωcm2 (including a drift resistance of 24 mΩcm2) at a gate oxide field of 3 MV/cm. The figure-of-merit of present device is about 29 MW/cm2, which is the best performance among any lateral MOSFETs. The drift resistance of the fabricated double RESURF MOSFETs is only 50 % or even lower than that of single RESURF MOSFETs. Temperature dependence of device characteristics is also discussed.

    DOI: 10.4028/0-87849-442-1.815

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  242. Lateral 4H-SiC MOSFETs with low on-resistance by using two-zone double RESURF structure

    Noborio M., Suda J., Kimoto T.

    Materials Science Forum   Vol. 556-557   page: 815 - 818   2007

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    4H-SiC lateral MOSFETs with a double reduced surface field (RESURF) structure have been fabricated in order to reduce drift resistance. A two-zone RESURF structure was also employed in addition to double RESURF structure for achieving both high breakdown voltage and low on-resistance. After device simulation for dose optimization, 4H-SiC two-zone double RESURF MOSFETs have been fabricated. The fabricated MOSFETs block 1380 V and exhibit a low on-resistance of 66 mΩcm2 (including a drift resistance of 24 mΩcm2) at a gate oxide field of 3 MV/cm. The figure-of-merit of present device is about 29 MW/cm2, which is the best performance among any lateral MOSFETs. The drift resistance of the fabricated double RESURF MOSFETs is only 50% or even lower than that of single RESURF MOSFETs. Temperature dependence of device characteristics is also discussed.

    DOI: 10.4028/www.scientific.net/MSF.556-557.815

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  243. Dose designing and fabrication of 4H-SiC double RESURF MOSFETs

    Noborio M., Suda J., Kimoto T.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs   Vol. 2006   2006.12

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    Designing and fabrication of 4H-SiC (0001) lateral MOSFETs with a double reduced surface field (RESURF) structure have been investigated to reduce a drift resistance. In order to achieve high breakdown voltage, a two-zone RESURF structure was also employed In addition to the double RESURF structure. After device simulation for dose optimization, 4H-SiC two-zone double RESURF MOSFETs have been fabricated by using an original self-aligned process proposed in this paper. The fabricated MOSFETs with optimum doses exhibit a high breakdown voltage of 1380 V and a low on-resistance of 66 mΩcm2 (including a drift resistance of 13 mΩcm2). The drift resistance in the fabricated MOSFETs with double RESURF structure is only 50 % or even lower than that in the MOSFETs with a normal RESURF structure. The figure-of-merit (VB2/RON) of the present device reaches 29 MW/cm2, which is the best performance among any lateral MOSFETs ever reported. ©2006 IEEE.

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  244. High-quality nonpolar 4H-AlN grown on 4H-SiC (11(2)over-bar20) substrate by molecular-beam epitaxy

    Horita Masahiro, Suda Jun, Kimoto Tsunenobu

    APPLIED PHYSICS LETTERS   Vol. 89 ( 11 )   2006.9

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    Growth of very high-quality nonpolar (112̄0) a-plane face 4H-AlN on 4H-SiC (112̄0) substrate was investigated. Nonpolar 4H-AlN (112̄0) was isopolytypically grown on 4H-SiC (112̄0) substrate by molecular-beam epitaxy. A reduction of defects such as stacking faults and threading dislocations was achieved by keeping the growing surface flat. To this end, the SiC substrate was HCl gas etched and the V/III ratio was optimized for AlN growth. A full width at half maximum of symmetrical x-ray diffraction ω scan of the 4H-AlN layer was 40 arc sec. Transmission electron microscopy revealed the stacking fault density to be 2 × 105 cm -1, and the partial and perfect threading dislocation densities to be 7 × 107 and 1 × 107 cm-2, respectively. © 2006 American Institute of Physics.

    DOI: 10.1063/1.2352713

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  245. Growth of nonpolar AlN and AlGaN on 4H-SiC (1-100) by molecular beam epitaxy

    Armitage R., Horita M., Suda J., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 892   page: 705 - 710   2006.5

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    AlN and AlGaN have been grown on 4H-SiC (1-100) substrates by rf-plasma molecular beam epitaxy. AlN assumes a metastable 4H structure to match the in-plane stacking arrangement of the substrate. Initial 2D nucleation of 4H-AlN is revealed by reflection high-energy electron diffraction. The epitaxial quality is evidenced by narrow x-ray diffraction co-scan line widths less than 100 arcsec for symmetric and asymmetric reflections. Structural characterization results for AlGaN/AlN multiple quantum wells are also presented. © 2006 Materials Research Society.

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  246. Extremely high quantum efficiency of donor-acceptor-pair emission in N-and-B-doped 6H-SiC

    Kamiyama S., Maeda T., Nakamura Y., Iwaya M., Amano H., Akasaki I., Kinoshita H., Furusho T., Yoshimoto M., Kimoto T., Suda J., Henry A., Ivanov I. G., Bergman J. P., Monemar B., Onuma T., Chichibu S. F.

    JOURNAL OF APPLIED PHYSICS   Vol. 99 ( 9 )   2006.5

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    High-efficiency visible light emission in N-and-B-doped 6H-SiC epilayers was observed in photoluminescence measurements at room temperature. The orange-yellow light emission due to the recombination of donor-acceptor pairs (DAPs) has a broad spectrum with a peak wavelength of 576 nm and a full width at half maximum of 110 nm at 250 K. The high B concentration of more than 1018 cm-3 improves the emission efficiency of the DAP recombination at a high temperature. Compared with the photoluminescence spectrum of GaN at 10 K, a high quantum efficiency of 95% was estimated for the highly B-doped sample. From time-resolved photoluminescence measurements, a DAP recombination time of 5.0 ms was obtained, which is in good agreement with the calculated value by the rate equation with the assumption of a 95% internal quantum efficiency. This is quite promising as a light-emitting medium by optical pumping, as well as monolithic light sources combined with nitride-based light-emitting diodes grown on the DA-doped SiC epilayer. © 2006 American Institute of Physics.

    DOI: 10.1063/1.2195883

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  247. Structure analysis of ZrB2(0001) surface prepared by ex situ HF treatment

    Suto Hirofumi, Fujii Shunjiro, Miyamae Nobuhiko, Armitage Robert D., Suda Jun, Kimoto Tsunenobu, Honda Shin-ichi, Katayama Mitsuhiro

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS   Vol. 45 ( 17-19 ) page: L497 - L500   2006.5

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics, Part 2: Letters  

    The surface structure of ZrB2(0001) was investigated using coaxial impact-collision ion scattering spectroscopy (CAICISS). The ZrB 2(0001) 1 × 1 surface was prepared by HF solution treatment and annealing in vacuum. It was directly evidenced that the ZrB2(0001) surface is terminated with a Zr layer. Moreover, we found that the interlayer spacing between the first Zr layer and the second B layer is expanded by 20% with regard to c-axis lattice constant. Since small amount of O atoms were detected after the cleaning, the incorporation of the residual O atoms into the subsurface region of the ZrB2(0001) surface is likely to be the origin of the large expansion. © 2006 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.45.L497

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  248. Characterization of ZrB2(0001) surface prepared by ex situ HF solution treatment toward applications as a substrate for GaN growth

    Armitage R, Suda J, Kimoto T

    SURFACE SCIENCE   Vol. 600 ( 7 ) page: 1439 - 1449   2006.4

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    ZrB2(0 0 0 1) crystals grown by the rf-floating zone technique were characterized by X-ray photoelectron spectroscopy, reflection high-energy electron diffraction, and atomic force microscopy. These characteristics were investigated as a function of thermal cleaning temperature up to 1000 °C in vacuum for as-received substrates as well as substrates treated ex situ in HF aqueous solution. The HF treatment process removed the ZrO2 native oxide layer present on as-received substrates and resulted in ZrB2(0 0 0 1) surfaces exhibiting long-range order. Upon annealing the HF-treated surface in high vacuum, two types of reconstructions were observed: an incommensurate reconstruction from 650 to 900°C related to residual H 2 gas, and n × n reconstructions at 1000°C, possibly related to oxygen. © 2006 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.susc.2006.01.032

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  249. Epitaxy of nonpolar AlN on 4H-SiC (1-100) substrates

    Armitage R, Suda J, Kimoto T

    APPLIED PHYSICS LETTERS   Vol. 88 ( 1 )   2006.1

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    AlN has been grown on 4H-SiC (1-100) substrates by rf-plasma molecular beam epitaxy. The epilayers assume a metastable 4H structure to match the in-plane stacking arrangement of the substrate. Initial two-dimensional nucleation of 4H-AlN is revealed by reflection high-energy electron diffraction. The epitaxial quality is evidenced by narrow x-ray diffraction ω-scan linewidths less than 70 arcsec for both symmetric and asymmetric reflections. The AlN growth surface exhibits a smooth and anisotropic morphology similar to that of GaN (1-100). Large residual stress is present in the epilayers, consistent with incomplete relaxation of misfit strain during growth. © 2006 American Institute of Physics.

    DOI: 10.1063/1.2161809

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  250. Anisotropic etching of single crystalline SiC using molten KOH for SiC bulk micromachining

    Fukunaga Katsuhiko, Suda Jun, Kimoto Tsunenobu

    MICROMACHINING AND MICROFABRICATION PROCESS TECHNOLOGY XI   Vol. 6109   2006

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Proceedings of SPIE - The International Society for Optical Engineering  

    Microelectromechanical systems (MEMS) devices made of single crystalline silicon carbide (SiC) are attractive for applications in harsh environment, because SiC is chemically inert and semiconductor devices made of SiC can be operated at very high temperature. On the other hand, due to its chemical inertness, controllable etching of SiC has been difficult. Molten KOH etching has been widely used to detect crystalline defects in SiC as etch pit in crystal growth researchers. Some etch pits have hexagonal shape, indicating anisotropic etching nature. Therefore, molten KOH etching may have potential as a SiC MEMS fabrication process. In this study we have developed the anisotropic wet chemical etching of single crystalline hexagonal SiC using molten KOH for SiC bulk micromachining, 6H-SiC (0001)Si face and (000-1)C face substrates are used. Etching rates of (0001)Si and (000-1)C faces at 490°C are evaluated to be 37 nm/min and 3.1 μm/min, respectively, indicating that the (0001)Si face is etched almost 100 times slower than the (000-1)C face is. Cross sectional analysis of etched structure of (000-1)C face revealed that inclined crystal plane was formed as a sidewall with some undercut. To assess in-plane etching anisotropy, ring shape mesa structures are formed on SiC (0001)Si face by R1E and then etched by molten KOH, Ring shape changed into hexagonal shape, clearly indicating etching rate along 〈11-20〉 direction is larger than 〈1-100〉 direction in (0001)Si face.

    DOI: 10.1117/12.647116

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  251. Electron injection from GaN to SiC and fabrication of GaN/SiC heterojunction bipolar transistors

    Suda J., Nakano Y., Shimada S., Amari K., Kimoto T.

    Materials Science Forum   Vol. 527-529 ( PART 2 ) page: 1545 - 1548   2006

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    Characterization of n+-GaN/p--SiC and n +-GaN/p+-SiC heterojunctions as well as fabrication of GaN/SiC heterojunction bipolar transistors (HBTs) using these heterojunctions is presented. The electroluminescence spectrum from n+-GaN/p +-SiC heterojunction diodes under forward bias clearly indicates electron injection from n+-GaN into P+-SiC. HBTs consisting of n+-GaN emitter /p+-SiC base/n --SiC collector/n+-SiC substrate have been fabricated. Although clear common-base properties were obtained, the current gain was very low (10-4). SiC homojunction bipolar junction transistors (BJT) using the same base-collector junction exhibited a current gain value of 0.5, suggesting the low current gain of GaN/SiC HBTs originates from low emitter efficiency.

    DOI: 10.4028/0-87849-425-1.1545

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  252. Improved dielectric and interface properties of 4H-SiC MOS structures processed by oxide deposition and N<inf>2</inf>O annealing

    Kimoto T., Kawano H., Noborio M., Suda J., Matsunami H.

    Materials Science Forum   Vol. 527-529 ( PART 2 ) page: 987 - 990   2006

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    Oxide deposition followed by high-temperature annealing in N2O has been investigated to improve the quality of 4H-SiC MOS structures. Annealing of deposited oxides in N2O at 1300°C significantly enhances the breakdown strength and decreases the interface state density to 3×10" cm-2 eV-1 at Ec- 0.2 eV. As a result, high channel mobility of 34 cm2/Vs and 52 cm2/Vs has been attained for inversion-type MOSFETs fabricated on 4H-SiC(0001)Si and (000-1)C faces, respectively. The channel mobility shows a maximum when the increase of oxide thickness during N2O annealing is approximately 5 nm. A lateral RESURF MOSFET with gate oxides formed by the proposed process has blocked 1450 V and showed a low on-resistance of 75 mΩcm2, which is one of the best performances among lateral SiC MOSFETs reported.

    DOI: 10.4028/0-87849-425-1.987

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  253. Low-dislocation-density nonpolar AlN grown on 4H-SiC (11-20) substrates

    Suda J., Horita M., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 955   page: 61 - 62   2006

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    Growth of AlN on 4H-SiC (11-20) substrates by plasma-assisted molecular-beam epitaxy is presented. Very high-quality AlN can be grown under a slightly Al-rich condition. Transmission electron microscopy revealed that the AlN layer has 4H crystalline structure with high-phase purity (stacking-fault density of 2×105cm-1) and the density of threading dislocations is as small as 8×107cm-2. © 2007 Materials Research Society.

    DOI: 10.1557/proc-0955-i06-03

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  254. Reduction of on-resistance in 4H-SiC multi-RESURF MOSFETs

    Noborio M., Negoro Y., Suda J., Kimoto T.

    Materials Science Forum   Vol. 527-529 ( PART 2 ) page: 1305 - 1308   2006

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    SiC lateral MOSFETs with multi-RESURF structures have been fabricated by a self-aligned process. The "multi-RESURF" means "double RESURF" and "buried-p RESURF" structures, which have the buried-p region at the top and at the middle of RESURF region, respectively. The increase of net RESURF dose and the decrease of channel length lead to the reduced on-resistance. The "buried-p RESURF" MOSFETs have higher on-resistances than the "double RESURF" MOSFETs, due to the resistance of parasitic JFET inside the RESURF region. The dose designing for double RESURF MOSFETs has been optimized by using device simulation. A double RESURF MOSFET exhibits a breakdown voltage of 750 V and an on-resistance of 52 mΩcm2.

    DOI: 10.4028/0-87849-425-1.1305

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  255. 1200 V-Class 4H-SiC RESURF MOSFETs with low on-resistances

    Kimoto T., Kawano H., Suda J.

    Proceedings of the International Symposium on Power Semiconductor Devices and ICs     page: 279 - 282   2005.11

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    4H-SiC{0001} RESURF MOSFETs with a two-zone structure have been simulated and fabricated. The dose dependencies of experimental breakdown voltage show good agreement with simulation. Through the optimization of implant dose, high-temperature (1700°C) annealing after ion implantation, and reduction of channel length, a high breakdown voltage of 1330 V and a low on-resistance of 69 mΩcm2 have been obtained. The 4H-SiC(000-1) face is promising for MOS-based devices owing to superior quality of MOS interface, and a performance of 1260 V - 62 mΩcm2 has been achieved. The figure-of-merit (VB2/Ron) of the present devices reaches 26 MW/cm2, being the best performance among lateral SiC MOSFETs reported. ©2005 IEEE.

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  256. Molecular-beam epitaxy of AlN on off-oriented SiC and demonstration of MISFET using AlN/SiC interface

    Onojima N., Kaido J., Suda J., Kimoto T.

    Physica Status Solidi C: Conferences   Vol. 2 ( 7 ) page: 2643 - 2646   2005.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Physica Status Solidi C: Conferences  

    Molecular-beam epitaxy (MBE) of AlN on 4H-SiC epilayers with the off-cut angle of 8° was performed using elemental Al and rf-plasma excited active nitrogen (N*) toward the goal of MISFETs using the AlN/4H-SiC hetero-interface. AlN films grown at 600 °C had a very flat surface with monolayer-height steps. Control of atomic arrangement at the AlN/4H-SiC interface was attempted by pre-irradiation of active nitrogen to achieve MIS structures with excellent electrical characteristics. The electronic properties of AlN/4H-SiC interface were characterized by C-V measurements of Al/AlN/n-type 4H-SiC MIS capacitors. The interface states at the AlN/4H-SiC interface were revealed to be strongly influenced by preirradiation of active nitrogen. Planar-type n-channel AlN/4H-SiC MISFETs were fabricated using a gate-stacked structure with SiO2. Owing to the novel device structure as well as an optimized AlN growth condition, we could first demonstrate the good transistor operation of MISFETs using the AlN/4H-SiC interface. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssc.200461526

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  257. Role of initial nucleation in molecular-beam epitaxy of GaN on lattice-matched ZrB<inf>2</inf> substrates

    Armitage R., Suda J., Kimoto T.

    Physica Status Solidi C: Conferences   Vol. 2 ( 7 ) page: 2191 - 2194   2005.11

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    Nitrogen-polar GaN was grown on lattice-matched ZrB2 substrates by a two-step rf-MBE process with conventional low-temperature GaN (LT-GaN) used as the nucleation layer. For nucleation in slightly Ga-rich conditions, a streaky RHEED pattern was maintained from the very beginning and persisted through-out subsequent high-temperature growth. However, despite the streaky RHEED pattern the initial nucleation was evidently not 2D as inferred from AFM and x-ray results. For nucleation in slightly N-rich conditions, spots appeared in the RHEED in the early stages of growth but a streak pattern was restored with high-temperature GaN growth. Tradeoffs were identified in optimizing the LT-GaN nucleation process. Slightly Ga-rich nucleation conditions offered the best x-ray characteristics with ω-scan FWHM values of 400-500 and 720-800 arcsec for the (0002) and (11̄04) reflections, respectively. Short-length atomic steps (up to ∼200 nm) were present on the surfaces of such layers, but the morphology showed a sub-grain structure. Slightly N-rich nucleation conditions yielded remarkably smooth films surfaces (rms 0.5 nm over 10 μm2) with uninterrupted atomic steps up to several urn long, but inferior x-ray ω-scans (∼50% larger FWHM values). © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssc.200461539

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  258. Direct growth of GaN on off-oriented SiC (0001) by molecular-beam epitaxy for GaN/SiC heterojunction bipolar transistor

    Nakano Y., Suda J., Kimoto T.

    Physica Status Solidi C: Conferences   Vol. 2 ( 7 ) page: 2208 - 2211   2005.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Physica Status Solidi C: Conferences  

    Direct growth of GaN on misoriented 4H- and 6H-SiC (0001) Si-face substrates and electrical characteristics of n-GaN/p-SiC heterojunction mesa diodes are presented. GaN was grown by molecular-beam epitaxy (MBE) using elemental Ga and rf plasma-excited active nitrogen. SiC substrates misoriented 8° toward the [11-20] direction were used in this study. The surfaces of MBE-grown GaN layers have wavy features with peak-to-valley height of 30 nm. These features originated from the substrate misorientation. It was found that step bunching and large faceting along [01-10] and [10-10] directions occurred during the growth of GaN. Lowering the growth temperature suppresses large faceting, and results in reduction of the peak-to-valley height to 3 nm. However, the surface still has the same undulating features (on a smaller length scale). Mesa diodes were fabricated from the grown GaN layers. The correlation between the diode electrical characteristics and GaN growth conditions is discussed. © 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

    DOI: 10.1002/pssc.200461549

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  259. Mechanism of stabilization of zincblende GaN on hexagonal substrates: Insight gained from growth on ZrB2(0001)

    Armitage R, Nishizono K, Suda J, Kimoto T

    JOURNAL OF CRYSTAL GROWTH   Vol. 284 ( 3-4 ) page: 369 - 378   2005.11

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of Crystal Growth  

    Thin (∼25 nm) zincblende GaN (1 1 1) epilayers have been grown on hexagonal ZrB2 (0 0 0 1) substrates by plasma-assisted molecular-beam epitaxy at temperatures near 600 °C. Layers grown in near-stoichiometric conditions exhibit high phase purity; no wurtzite inclusions are detected by high-resolution X-ray diffraction or photoluminescence. For growth in the presence of excess Ga the layers are predominantly zincblende phase, but contain some wurtzite inclusions. Reducing the growth temperature to 400 °C results in a much-increased fraction of wurtzite inclusions. The growth of zincblende GaN with high phase purity on hexagonal ZrB2 implies the existence of an underlying physical mechanism rather than simply a result of "growth mistakes." A possible surface energy-related mechanism by which zincblende GaN (1 1 1) can be preferentially nucleated on hexagonal substrates is discussed. © 2005 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jcrysgro.2005.07.037

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  260. 1330 V, 67 m Omega center dot cm(2) 4H-SiC(0001) RESURF MOSFET

    Kimoto T, Kawano H, Suda J

    IEEE ELECTRON DEVICE LETTERS   Vol. 26 ( 9 ) page: 649 - 651   2005.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:IEEE Electron Device Letters  

    Design and fabrication of 4H-SiC(0001) lateral MOSFETs with a two-zone reduced surface field structure have been investigated. The dose dependencies of experimental breakdown voltage show good agreement with simulation. Through the optimization of implant dose, high-temperature (1700 °C) annealing after ion implantation, and reduction of channel length, a breakdown voltage of 1330 V and a low on-resistance of 67 mΩ · cm2 have been obtained. The figure-of-merit (VB2/Ron) of the present device reaches 26 MW/cm2, being the best performance among lateral MOSFETs reported. The temperature dependence of static characteristics is also presented. © 2005 IEEE.

    DOI: 10.1109/LED.2005.854371

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  261. Experimental and theoretical investigations on short-channel effects in 4H-SiC MOSFETs

    Noborio M, Kanzaki Y, Suda J, Kimoto T

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 52 ( 9 ) page: 1954 - 1962   2005.9

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    In this paper, a fundamental investigation on short-channel effects (SCEs) in 4H-SiC MOSFETs is given. Planar MOSFETs with various channel lengths have been fabricated on p-type 4H-SiC (0001), (0001̄) and (112̄0) faces. In the fabricated MOSFETs, SCEs such as punchthrough behavior, decrease of threshold voltage, deterioration of subthreshold characteristics, and saturation of transconductance occur by reducing channel length. The critical channel lengths below which SCEs occur are analyzed as a function of p-body doping and oxide thickness by using device simulation. The critical channel lengths obtained from the device simulation is in good agreement with the empirical relationship for Si MOSFETs. The critical channel lengths in the fabricated SiC MOSFETs are slightly longer than simulation results. The dependence of crystal face orientations on SCEs is hardly observed. Impacts of interface charge on the appearance of SCEs are discussed. © 2005 IEEE.

    DOI: 10.1109/TED.2005.854269

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  262. Influence of substrate misorientation angle and direction in growth of GaN on off-axis SiC (0001)

    Suda J., Nakano Y., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 831   page: 471 - 476   2005.8

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    Growth of GaN on 4H- or 6H-SiC (0001) Si-face substrates with various misorientation angles and directions is presented. GaN layers were directly grown on the SiC substrates by molecular-beam epitaxy using elemental Ga and rf plasma-excited active nitrogen. First, 4H-SiC (0001) 8o-off toward the [11-20] direction was investigated. Before the growth of GaN, ex-situ high-temperature gas etching was carried out, resulting in a smooth SiC initial surface. However, the surface of the subsequently grown GaN layer has wavy features with peak-to-valley height of 30 nm. Since the direction of the undulations is parallel to the misorientation direction, this feature must originate from the substrate misorientation. Step bunching and large faceting along 〈01-10〉 and 〈10-10〉 directions occurred during the growth of GaN. Lowering the growth temperature suppresses large faceting, and results in reduction of the peak-to-valley height to 3 nm. However, the surface still has the same undulating features on a smaller length scale. On the other hand such morphology was not observed for GaN grown on (0001) on-axis SiC substrates (misorientation < 0.3o). The influence of the polytype of the SiC substrate and the misorientation angle and direction are also discussed. © 2005 Materials Research Society.

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  263. Molecular beam epitaxy of GaN on lattice-matched ZrB<inf>2</inf> substrates using low-temperature GaN and AlN nucleation layers

    Armitage R., Nishizono K., Suda J., Kimoto T.

    Materials Research Society Symposium Proceedings   Vol. 831   page: 477 - 482   2005.8

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    GaN epilayers have been grown by plasma-assisted molecular-beam epitaxy on ZrB2 substrates with close in-plane lattice match. Growth processes utilizing both low-temperature GaN (LT-GaN) and AlN nucleation layers were investigated. The x-ray ω-scan widths for the optimized LT-GaN nucleation process were 400 and 750 arcsec for symmetric and asymmetric reflections, respectively. When using LT-GaN nucleation layers, the chemical incompatibility of ZrB2 results in a high dislocation density despite the in-plane lattice match. The epilayer polarity was N-polar for LT-GaN nucleation layers under all conditions investigated. For AlN nucleation layers, Gapolar epilayers were obtained under suitable conditions (Al-rich, lower nucleation temperatures) for nominal AlN thickness as low as 1 nm. From RHEED analysis it appears that a psuedomorphic Al wetting layer forms on the ZrB2 surface, and that using AlN as the nucleation layer may offer promise for reducing the epilayer defect density. © 2005 Materials Research Society.

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  264. Design and Fabrication of RESURF MOSFETs on 4H-SiC(0001), (1120), and 6H-SiC(0001)

    Kimoto T, Kosugi H, Suda J, Kanzaki Y, Matsunami H

    IEEE TRANSACTIONS ON ELECTRON DEVICES   Vol. 52 ( 1 ) page: 112 - 117   2005.1

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    Design and fabrication of lateral SiC reduced surface field (RESURF) MOSFETs have been investigated. The doping concentration (dose) of the RESURF and lightly doped drain regions has been optimized to reduce the electric field crowding at the drain edge or in the gate oxide by using device simulation. The optimum oxidation condition depends on the polytype: N2O oxidation at 1300 °C seems to be suitable for 4H-SiC, and dry O2 oxidation at 1250 °C for 6H-SiC. The average inversion-channel mobility is 22, 78, and 68 cm2 /Vs for 4H-SiC(0001), (112̄0), and 6H-SiC(0001) MOSFETs, respectively. RESURF MOSFETs have been fabricated on 10-μm-thick p-type 4H-SiC(0001), (112̄0), and 6H-SiC(0001) epilayers with an acceptor concentration of 1 × 1016 cm-3. A 6H-SiC(0001) RESURF MOSFET with a 3-μm channel length exhibits a high breakdown voltage of 1620 V and an on-resistance of 234 mΩ · cm2. A 4H-SiC(112̄0) RESURF MOSFET shows the characteristics of 1230 V-138 mΩ · cm2. © 2005 IEEE.

    DOI: 10.1109/TED.2004.841358

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  265. 1200 V-class 4H-SiC RIESURF MOSFETs with low on-resistances

    Kimoto T, Kawano H, Suda J

    PROCEEDINGS OF THE 17TH INTERNATIONAL SYMPOSIUM ON POWER SEMICONDUCTOR DEVICES & ICS     page: 279 - 282   2005

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  266. Molecular beam epitaxy of GaN on lattice-matched ZrB2 substrates using low-temperature GaN and AlN nucleation layers

    Armitage R, Nishizono K, Suda J, Kimoto T

    GaN, AIN, InN and Their Alloys   Vol. 831   page: 477 - 482   2005

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  267. Short-Channel Effects in 4H-SiC MOSFETs

    Noborio M, Kanzaki Y, Suda J, Kimoto T, Matsunami H

    SILICON CARBIDE AND RELATED MATERIALS 2004   Vol. 483   page: 821 - 824   2005

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  268. Dose designing for high-voltage 4H-SiC RESURF MOSFETs - device simulation and fabrication

    Kawano H, Kimoto T, Suda J, Matsunami H

    SILICON CARBIDE AND RELATED MATERIALS 2004   Vol. 483   page: 809 - 812   2005

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  269. Dose designing for high-voltage 4H-SiC RESURF MOSFETs - Device simulation and fabrication

    Kawano H., Kimoto T., Suda J., Matsunami H.

    Materials Science Forum   Vol. 483-485   page: 809 - 812   2005

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    Optimum dose designing for 4H-SiC (0001) two-zone RESURF MOSFETs is investigated by device simulation and fabrication. Simulated results suggest that negative charge at the SiC/SiO2 interface significantly influences breakdown voltage. Simulation has also showed that breakdown voltage strongly depends on LDD (Lightly-Doped Drain) dose. The dose dependencies of the breakdown voltage experimentally obtained are in good agreement with the device simulation. A RESURF MOSFET, processed by N2O oxidation, with an optimized dose blocks 1080V and has a low on-resistance of 79 mΩcm 2 at a gate oxide field of 3.0 MV/cm, which is the best 4H-SiC RESURF MOSFET ever reported.

    DOI: 10.4028/0-87849-963-6.809

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  270. Short-channel effects in 4H-SiC MOSFETs

    Noborio M., Kanzaki Y., Suda J., Kimoto T., Matsunami H.

    Materials Science Forum   Vol. 483-485   page: 821 - 824   2005

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Materials Science Forum  

    Short-channel effects in SiC MOSFETs have been investigated. Planar MOSFETs with various channel lengths have been fabricated on p-type 4H-SiC (0001), (000-1) and (11-20) faces. Short-channel effects such as punchthrough behavior, decrease of threshold voltage and deterioration of subthreshold characteristics are observed. Furthermore, the critical channel lengths below which short-channel effects occur are analyzed as a function of p-body doping and oxide thickness by using device simulation. The critical channel lengths in the fabricated SiC MOSFETs are in agreement with those obtained from the device simulation. The results are also in agreement with the empirical relationship for Si MOSFETs.

    DOI: 10.4028/0-87849-963-6.821

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  271. Molecular beam epitaxy of GaN on lattice-matched zirconium diboride substrates using low-temperature GaN and ALN nucleation layers

    Armitage R., Suda J., Kimoto T.

    Proceedings - Electrochemical Society   Vol. 6   page: 484 - 495   2004.12

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    GaN epilayers have been grown on lattice-matched ZrB2 substrates by rf-molecular beam epitaxy using a two-step method with low-temperature GaN or AlN employed as the nucleation layer. N-polarity was always obtained for GaN nucleation layers, while Ga-polarity could be obtained with AlN nucleation layers under certain conditions. The characteristics of N-polar GaN epilayers were found to strongly depend on the Ga/N ratio during initial nucleation. Remarkably smooth morphologies (rms <0.5 nm over 10 μm2) with atomic steps up to several μm long were obtained for layers with N-excess nucleation conditions. Ga-excess nucleation conditions resulted in better x-ray diffraction characteristics, but the morphology showed a subgrain structure and increased roughness (rms 1-2 nm). Typical ω-scan values for Ga-excess nucleation were in the range 400-500 arcsec and 750-860 arcsec for the (002) and (104) reflections, respectively. Possible reasons for the high dislocation density despite the good lattice match of ZrB2 are discussed.

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  272. Molecular-beam epitaxy of III-N on novel ZrB<inf>2</inf> substrates

    Suda J.

    Proceedings of SPIE - The International Society for Optical Engineering   Vol. 5349   page: 397 - 407   2004.8

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    Electrically conductive zirconium diboride (ZrB2) is a promising lattice-matched substrate for GaN-based nitride semiconductors. In this paper, important properties of ZrB2 as a substrate for nitrides, such as, thermal expansion coefficient, thermal conductivity, optical reflectivity and cleavage, are reviewed. Then, heteroepitaxial growth of GaN and AlN on the substrate by molecular-beam epitaxy (MBE) are discussed. Direct growth and two-step growth using low-temperature GaN nucleation layers as well as characterization of the surface condition of ZrB2 substrates by X-ray photoelectron spectroscopy (XPS) and the effect of surface treatment on grown layers are presented.

    DOI: 10.1117/12.540326

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  273. Molecular-beam epitaxy of III-N on novel ZrB2 substrates

    Suda J

    PHYSICS AND SIMULATION OF OPTOELECTRONIC DEVICES XII   Vol. 5349   page: 397 - 407   2004

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  274. High channel mobilities of MOSFETs on highly-doped 4H-SiC (11-20) face by oxidation in N<inf>2</inf>O ambient

    Kanzaki Y., Kinbara H., Kosugi H., Suda J., Kimoto T., Matsunami H.

    Materials Science Forum   Vol. 457-460 ( II ) page: 1429 - 1432   2004

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    Planar n-channel MOSFETs have been fabricated on 4H-SiC (11-20), (0001) and (000-1) faces by using oxidation in N2O ambient. The relationship between the MOSFET performance and the acceptor concentration (7×10 15-2×1017 cm-3) of epilayers has been investigated. 4H-SiC (11-20) MOSFETs have shown a high effective channel mobility of 70 cm2/Vs at a 2×1016 cm-3 doping, and 54 cm2/Vs at 2×1017 cm-3. Short-channel effects have been also investigated.

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  275. Towards high-quality AlN/SiC hetero-interface by controlling initial processes in molecular-beam epitaxy

    Onojima N., Kaido J., Suda J., Kimoto T., Matsunami H.

    Materials Science Forum   Vol. 457-460 ( II ) page: 1569 - 1572   2004

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    The electronic properties of AlN/SiC hetero-interface were investigated by using Al/AlN/4H-SiC MIS capacitors. Single crystalline AlN was grown on n-type 8° off-axis 4H-SiC (0001) epilayers via plasma-assisted molecular-beam epitaxy (PA-MBE). The C-V characteristics revealed that the initial pre-irradiation of atomic nitrogen (N*) before AlN growth strongly affected the electronic properties of AlN/SiC interface, which probably attributed to the atomic arrangement of Al, N, Si and C at the interface. A noticeably small value of interface state density (Dit), such as 3×1011 cm-2eV-1 at Ec-0.2 eV, was obtained for the N* pre-irradiated interface.

    DOI: 10.4028/www.scientific.net/msf.457-460.1569

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  276. 4H-polytype AlN grown on 4H-SiC(11(2)over-bar0) substrate by polytype replication

    Onojima N, Suda J, Kimoto T, Matsunami H

    APPLIED PHYSICS LETTERS   Vol. 83 ( 25 ) page: 5208 - 5210   2003.12

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    The growth of aluminum nitride (AlN) on a 4H-SiC(112̄0) substrate, which has a different stacking structure compared to 6H-SiC was studied. 4H-AlN was grown on the 4H-SoC(112̄0) substrate owing to the atomic-template effect, i.e., polytype reduction. The FWHM of XRC (112̄0) diffraction for the 4H-AlN epilayer was as small as 90 arc sec. The results show that the excellent crystalline quality is probably owing to the polytype matching between the 4H-AlN epilayer and the 4H-SiC substrate.

    DOI: 10.1063/1.1636533

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  277. High-quality AlN by initial layer-by-layer growth on surface-controlled 4H-SiC(0001) substrate

    Onojima N, Suda J, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 42 ( 5A ) page: L445 - L447   2003.5

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    The initial layer-by-layer growth of AlN was realized on a surface-controlled 4H-SiC(0001) substrate using plasma-assisted molecular-beam epitaxy (PA-MBE). To achieve initial two-dimensional (2D) growth, the control of SiC surface chemistry is very important as well as that of surface flatness. The effect of SiC preparation on the surface structure and chemical composition was investigated by using reflection high-energy electron diffraction (RHEED) and in situ X-ray photoelectron spectroscopy (XPS). The initial growth mode of AlN was strongly influenced by the removal of residual oxygen atoms from the SiC surface. Symmetrical and asymmetrical X-ray rocking curve (XRC) measurements revealed that initial 2D growth was essential to obtain the excellent crystalline quality of AlN layer.

    DOI: 10.1143/JJAP.42.L445

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  278. Fabrication of SiC lateral super junction diodes with multiple stacking p- and n-layers

    Miura M, Nakamura S, Suda J, Kimoto T, Matsunami H

    IEEE ELECTRON DEVICE LETTERS   Vol. 24 ( 5 ) page: 321 - 323   2003.5

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    Using epitaxial multiple p-n junction structures of 4H-SiC, lateral super junction diodes were fabricated for the first time. The breakdown voltage of the device was 400 V, which is more than 3 × higher than the theoretical value calculated for a device with uniformly-doped drift layer (130 V), indicating the effective operation of super junction structure.

    DOI: 10.1109/LED.2003.812561

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  279. ZrB2 substrate for nitride semiconductors

    Kinoshita H, Otani S, Kamiyama S, Amano H, Akasaki I, Suda J, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS   Vol. 42 ( 4B ) page: 2260 - 2264   2003.4

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers  

    Zirconium diboride (ZrB2) has excellent properties as an electrically conductive substrate for nitride semiconductors. In this paper, the bulk growth of ZrB2 by a floating-zone method and some properties of ZrB2, together with a brief summary of heteroepitaxial growth of gallium nitride (GaN) by molecular beam epitaxy (MBE) and metalorganic vapor phase epitaxy (MOVPE), are presented. By optimizing the bulk growth conditions, a 20-mm-diameter ZrB2 single crystal was obtained. The cleavage direction of the ZrB2 (0001) substrate was confirmed to be parallel to [112̄0], which is parallel to that of GaN (0001). Epitaxial growth by both MBE and MOVPE was demonstrated. The grown n-type GaN/ZrB2 structure exhibited ohmic-like current-voltage behavior. These results indicate that ZrB2 has potential for application to the substrate for nitride semiconductors.

    DOI: 10.1143/JJAP.42.2260

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  280. Epitaxial growth of AlN on 6H-SiC (11(2)over-bar0) by molecular-beam epitaxy and effect of low-temperature buffer layer

    Onojima N, Suda J, Matsunami H

    GAN AND RELATED ALLOYS-2002   Vol. 743   page: 139 - 144   2003

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  281. Growth of high-quality non-polar AlN on 4H-SiC(11-20) substrate by molecular-beam epitaxy

    Onojima N, Suda J, Kimoto T, Matsunami H

    5TH INTERNATIONAL CONFERENCE ON NITRIDE SEMICONDUCTORS (ICNS-5), PROCEEDINGS   Vol. 0 ( 7 ) page: 2502 - 2505   2003

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    Non-polar AlN epitaxial growth on SiC substrates with the (11-20) face, which is parallel to the 〈0001〉 direction, has been investigated. AlN(11-20) epilayers were grown on 6H- and 4H-SiC(11-20) substrates by molecular-beam epitaxy (MBE) using elemental Al and rf plasma-excited nitrogen. The crystalline structure of the AlN layer was strongly influenced by the stacking structure of the SiC substrate. A considerably smooth AlN(11-20) layer with an rms roughness of 0.3 nm was obtained on the 4H-SiC(11-20) substrate. From the results of X-ray diffraction (XRD), the superior crystalline quality of the AlN(11-20) layer on the 4H-SiC(11-20) substrate was clearly shown. © 2003 WILEY-VCH Verlag GmbH & Co. KGaA.

    DOI: 10.1002/pssc.200303396

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  282. Lattice relaxation of AlN buffer on surface-treated SiC in molecular-beam epitaxy for growth of high-quality GaN

    Suda J, Miura K, Honaga M, Onojima N, Nishi Y, Matsunami H

    GAN AND RELATED ALLOYS-2002   Vol. 743   page: 311 - 316   2003

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  283. Impact of SiC surface control on initial growth mode and crystalline quality of AlN grown by molecular-beam epitaxy

    Onojima N, Suda J, Kimoto T, Matsunami H

    5TH INTERNATIONAL CONFERENCE ON NITRIDE SEMICONDUCTORS (ICNS-5), PROCEEDINGS   Vol. 0 ( 7 ) page: 2529 - 2532   2003

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    The surface pretreatment of SiC substrate for AlN heteroepitaxial growth was investigated to realize initial two-dimensional (2D) layer-by-layer growth. AlN layers were grown on atomically flat SiC (0001) substrates by plasma-assisted molecular-beam epitaxy (PA-MBE). To achieve initial 2D growth, the control of SiC surface chemistry was very important as well as that of surface flatness. Owing to Ga deposition on the SiC surface and subsequent flash-off, an oxygen-free (V3 × V3) R30° surface structure was achieved, and initial 2D growth with an evident RHEED intensity oscillation was demonstrated. The initial growth mode of AlN closely correlated with the crystalline quality of AlN layer. © 2003 WILEY-VCH Verlag GmbH & Co. KGaA.

    DOI: 10.1002/pssc.200303358

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  284. Surface control of ZrB2 (0001) substrate for molecular-beam epitaxy of GaN

    Suda J, Yamashita H, Armitage R, Kimoto T, Matsunami H

    GAN AND RELATED ALLOYS - 2003   Vol. 798   page: 369 - 374   2003

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  285. Either step-flow or layer-by-layer growth for AlN on SiC (0001) substrates

    Suda J., Onojima N., Kimoto T., Matsunami H.

    Materials Research Society Symposium - Proceedings   Vol. 798   page: 311 - 316   2003

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    AlN was grown on 4H- or 6H-SiC (0001) on-axis substrates by plasma-assisted molecular beam epitaxy. By utilizing optimized SiC surface pretreatment, RHEED oscillations just after the growth of AlN were obtained with high reproducibility. This study focused on the growth kinetics of AlN and the correlation between kinetics and the crystalline quality of the grown layers. It was found that the growth mode changed from layer-by-layer to step-flow for high growth temperatures, while for lower temperatures the layer-by-layer growth mode persisted. The mechanism responsible for the change in growth mode is discussed. Symmetrical (0002) and asymmetrical (01-14) x-ray rocking curve measurements were carried out to evaluate the crystalline quality. For the (0002) peak, both high-temperature and low-temperature grown layers showed almost the same FWHM values. On the other hand, for the (01-14) peak, the FWHM of low-temperature grown AlN was much smaller (180 arcsec) than that of the high-temperature grown AlN (450 arcsec).

    DOI: 10.1557/proc-798-y3.4

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  286. SiC Lateral Super-Junction Diodes Fabricated by Epitaxial Growth

    Miura M., Nakamura S.I., Suda J., Kimoto T., Matsunami H.

    Materials Science Forum   Vol. 433-436   page: 859 - 862   2003

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    Lateral super junction diodes were fabricated using epitaxial multiple pn junction structures of 4H-SiC. The diodes showed very high on-state current densities of 500 A/cm2 at 3.9V and 1000 A/cm2 at 5.0V were obtained, and the corresponding specific on-state resistance of 2.1 mΩcm2. Even without the aid of conductivity modulation, a specific on-state resistance of 4.2 mΩcm2 was obtained, showing an extremely low value as lateral devices. The maximum breakdown voltage of the diodes was 400V, which is more than three times higher than the theoretical value calculated for a lateral p+n diode with a uniformly-doped drift region (130 V), indicating the effective operation of super junction structure made of SiC.

    DOI: 10.4028/www.scientific.net/msf.433-436.859

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  287. Surface control of ZrB<inf>2</inf> (0001) substrate for molecular-beam epitaxy of GaN

    Suda J., Yamashita H., Armitage R., Kimoto T., Matsunami H.

    Materials Research Society Symposium - Proceedings   Vol. 798   page: 369 - 374   2003

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    Zirconium diboride (ZrB2) is a promising lattice-matched substrate for GaN-based materials. A key issue to realize high-quality heteroepitaxial growth is preparation of the substrate surface. The ZrB 2 surface was studied by x-ray photoemission spectroscopy (XPS) and reflection high-energy electron diffraction (RHEED). XPS results indicated the presence of both ZrO2 and ZrB2 on the as-received substrate surface. Thermal cleaning at 1000°C in ultra-high vacuum, Ar + ion sputtering, and wet chemical treatments were examined as surface preparation methods. After treatment with HF acid, the O peak intensity was much reduced. The combination of HF treatment and thermal cleaning resulted in sharp and intense RHEED from the ZrB2 surface. GaN grown on the surface by molecular-beam epitaxy exhibited intense photoluminescence, suggesting that this treatment is effective to obtain high-quality GaN on ZrB2 substrates.

    DOI: 10.1557/proc-798-y10.65

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  288. Effects of 6H-SiC surface reconstruction on lattice relaxation of AlN buffer layers in molecular-beam epitaxial growth of GaN

    Suda J, Miura K, Honaga M, Nishi Y, Onojima N, Matsunami H

    APPLIED PHYSICS LETTERS   Vol. 81 ( 27 ) page: 5141 - 5143   2002.12

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    A high-temperature HCl-gas etching technique followed by chemical treatment as a SiC substrate pretreatment, which resulted in 1 × 1 reconstruction with an atomically flat surface was proposed. The effects of SiC surface reconstruction on the lattice relaxation of AlN buffer layers and the crystalline quality of GaN layers were investigated. The GaN layers grown on the AlN buffer layer demonstrated the narrowest x-ray rocking curve (XRC) (0002) diffraction of 70 arcsec and 107 cm-2 screw-type dislocation density, which is two orders of magnitude smaller than that of GaN grown on as-received substrates.

    DOI: 10.1063/1.1533855

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  289. Growth of AlN (11(2)over-bar0) on 6H-SiC (11(2)over-bar0) by molecular-beam epitaxy

    Onojima N, Suda J, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 41 ( 12A ) page: L1348 - L1350   2002.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Japanese Journal of Applied Physics, Part 2: Letters  

    AlN epitaxial growth on 6H-SiC substrates with the (112̄0) face, which is parallel to the <0001> direction, has been investigated. AlN epitaxial layers were grown by molecular-beam epitaxy (MBE) using elemental Al and rf plasma-excited nitrogen (N*). The surface roughness of the AlN layers was relatively small (rms roughness of 0.98 nm). From the results of reflection high-energy electron diffraction (RHEED), AlN layers on 6H-SiC (112̄0) substrates were revealed to be grown toward the [112̄0] direction, not toward the [0001] direction. AlN and 6H-SiC (112̄0) had an exact epitaxial relationship, i.e., [112̄0]AlN ∥ [112̄0]SiC and [0001]AlN ∥ [0001]SiC. The polytype of the AlN layer was also discussed based on the results of microscopic Raman scattering spectroscopy.

    DOI: 10.1143/JJAP.41.L1348

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  290. Heteroepitaxial growth of group-III nitrides on lattice-matched metal boride ZrB2 (0001) by molecular beam epitaxy

    Suda J, Matsunami H

    JOURNAL OF CRYSTAL GROWTH   Vol. 237   page: 1114 - 1117   2002.4

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  291. Lattice relaxation process of AlN growth on atomically flat 6H-SiC substrate in molecular beam epitaxy

    Onojima N, Suda J, Matsunami H

    JOURNAL OF CRYSTAL GROWTH   Vol. 237   page: 1012 - 1016   2002.4

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  292. Heteroepitaxial growth of group-III nitrides on lattice-matched metal boride ZrB<inf>2</inf> (0 0 0 1) by molecular beam epitaxy

    Suda J., Matsunami H.

    Journal of Crystal Growth   Vol. 237-239 ( 1-4 II ) page: 1114 - 1117   2002.4

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    Growth of group-III nitrides was carried out on zirconium diboride (ZrB2) (0 0 0 1) substrates for the first time. ZrB2 is a semi-metal compound and have a hexagonal crystal structure. The a-axis lattice constant of ZrB2 is 3.169Å, which is almost lattice-matched to GaN and AlN. GaN and AlN were grown on mirror-polished ZrB2 (0 0 0 1) substrate directly by molecular beam epitaxy using elemental Al and Ga, and radio frequency plasma-excited active nitrogen. Epitaxial growth was confirmed by in situ reflection high-energy electron diffraction observation and X-ray diffraction pole-figure measurement. The surface morphology of 1.4μm-thick GaN layer was rough. On the other hand, that of 0.9μm-thick AlN layer was specular. © 2002 Elsevier Science B.V. All rights reserved.

    DOI: 10.1016/S0022-0248(01)02065-6

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  293. Lattice relaxation process of AlN growth on atomically flat 6H-SiC substrate in molecular beam epitaxy

    Onojima N., Suda J., Matsunami H.

    Journal of Crystal Growth   Vol. 237-239 ( 1-4 II ) page: 1012 - 1016   2002.4

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    The lattice relaxation process of AlN growth on an atomically flat 6H-SiC (0 0 0 1)Si substrate was investigated by using high-resolution X-ray diffraction. The atomically flat 6H-SiC substrates were prepared by HCl gas etching at 1300°C. AlN layers were grown by molecular beam epitaxy using elemental Al and radio frequency plasma-excited active nitrogen. Owing to 1% in-plane lattice mismatch between AlN and 6H-SiC, lattice relaxation occurs at a certain thickness, which strongly affects the structural property of AlN layer. The layer thickness dependence of AlN c-axis lattice constant was examined. The structural property of these AlN layers is also discussed based on the linewidth of XRD ω-scan measurements. © 2002 Elsevier Science B.V. All rights reserved.

    DOI: 10.1016/S0022-0248(01)02118-2

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  294. Scanning capacitance and spreading resistance microscopy of SiC multiple-pn-junction structure

    Suda J, Nakamura S, Miura M, Kimoto T, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 41 ( 1AB ) page: L40 - L42   2002.1

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    Scanning capacitance microscopy (SCM) and scanning spreading resistance microscopy (SSRM) of a SiC multiple-pn-junction structure are presented. The structure was grown by atmospheric-pressure chemical vapor deposition using silane, propane and hydrogen. Nitrogen and diborane were used for n- and p-type doping gases, respectively. The SCM and SSRM results are compared with those of secondary ion mass spectrometry (SIMS). The 0.2-μm-thick n-type layer and 0.3-μm-thick p-type layer with a doping level of 1.5 × 1017 cm-3 in the multiple pn-junction were clearly resolved by both SCM and SSRM as well as SIMS.

    DOI: 10.1143/JJAP.41.L40

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  295. Molecular-beam epitaxial growth of insulating AlN on surface-controlled 6H-SiC substrate by HCl gas etching

    Onojima N, Suda J, Matsunami H

    APPLIED PHYSICS LETTERS   Vol. 80 ( 1 ) page: 76 - 78   2002.1

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  296. Molecular-beam epitaxial growth of insulating AlN on surface-controlled 6H-SiC substrate by HCl gas etching

    Onojima N., Suda J., Matsunami H.

    Applied Physics Letters   Vol. 80 ( 1 ) page: 76 - 78   2002.1

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    Insulating AlN layers were grown on surface-controlled 6H-SiC subtrates by molecular-beam epitaxy (MBE) using elemental Al and rf plasma-excited nitrogen (N*). HCl gas etching was introduced as an effective pretreatment method of substrate for MBE growth of AlN. 6H-SiC substrates pretreated by HCl gas etching had no surface polishing scratches and an atomically flat surface. In addition, evident (×)R30° surface reconstruction was observed even before thermal cleaning. AlN layers grown on this substrate had no defects related to surface polishing scratches and excellent insulating characteristics. © 2002 American Institute of Physics.

    DOI: 10.1063/1.1428620

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  297. Scanning capacitance microscopy of SiC multiple PN junction structure grown by cold-wall chemical vapor deposition

    Suda J, Nakamura S, Miura M, Kimoto T, Matsunami H

    SILICON CARBIDE AND RELATED MATERIALS 2001, PTS 1 AND 2, PROCEEDINGS   Vol. 389-3   page: 659 - 662   2002

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  298. Epitaxial growth of AlN on 6H-SiC (1120) by molecular-beam epitaxy and effect of low-temperature buffer layer

    Onojima N., Suda J., Matsunami H.

    Materials Research Society Symposium - Proceedings   Vol. 743   page: 139 - 144   2002

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    Aluminum nitride (AlN) has been grown on 6H-silicon carbide (SiC) substrates with the non-polar (112̄0) face using rf plasma-assisted molecular-beam epitaxy (rf-MBE). Reflection high-energy electron diffraction (RHEED) revealed that AlN and 6H-SiC (112̄0) had an exact epitaxial relationship, i.e., [112̄0]AlN∥[112̄0]SiC and [0001]AlN∥[0001]SiC. From the result of microscopic Raman scattering spectroscopy, the stacking structure of the AlN epitaxial layer was suggested to be a 2H structure, not a 6H structure. A directly grown AlN layer and layer with AlN low-temperature (LT) buffer layer were investigated based on atomic force microscopy (AFM) and X-ray diffraction (XRD).

    DOI: 10.1557/proc-743-l3.21

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  299. Heteroepitaxial growth of insulating AlN on 6H-SiC by MBE

    Onojima N, Suda J, Matsunami H

    SILICON CARBIDE AND RELATED MATERIALS 2001, PTS 1 AND 2, PROCEEDINGS   Vol. 389-3   page: 1457 - 1460   2002

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  300. Heteroepitaxial growth of insulating AIN on 6H-SiC by MBE

    Onojima N., Suda J., Matsunami H.

    Materials Science Forum   Vol. 389-393   page: 1457 - 1460   2002

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    Insulating AIN single crystals were grown on 6H-SiC substrates by molecular beam epitaxy (MBE). The insulating properties of AIN were investigated by a current-voltage (I-V) measurement of Al/AIN/6H-SiC metal-insulator-semiconductor (MIS) diode structures. 6H-SiC substrates pretreated by HCI gas etching had no surface polishing scratches and an atomically flat surface. The AIN layer grown on the atomically flat substrate was very smooth and exhibited excellent insulating properties. The resistivity of this layer was around 7×1013 Ωcm. Thinner AIN layers had superior insulating properties. From the result of X-ray diffraction (XRD) measurements, thinner AIN layers had superior structural quality. These results indicate strong correlations between insulating properties and structural quality of AIN layer.

    DOI: 10.4028/www.scientific.net/MSF.389-393.1457

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  301. Lattice relaxation of AlN buffer on surface-treated SiC in molecular-beam epitaxy for growth of high-quality GaN

    Suda J., Miura K., Honaga M., Onojima N., Nishi Y., Matsunami H.

    Materials Research Society Symposium - Proceedings   Vol. 743   page: 311 - 316   2002

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    The effects of SiC surface treatment on the lattice relaxation of AlN buffer layers and the crystalline quality of GaN layers grown on the buffer layers were studied. AlN buffer layers and GaN main layers were grown by plasma-assisted molecular-beam epitaxy on on-axis 6H-SiC (0001)Si substrates. High-temperature HCl-gas etching resulted in an atomically flat SiC surface with (√3×√3)R30° surface reconstruction, while HCl-gas etching followed by HF chemical treatment resulted in an atomically flat surface with (1×1) structure. The AlN layer grown on the (1×1) surface showed slower lattice relaxation. GaN grown on the AlN buffer layer exhibited a (0002) X-ray rocking curve of 70 arcsec and 107 cm-2 of screw-type dislocation density, which was superior than that of GaN grown on (√3×√3)R30° surface.

    DOI: 10.1557/proc-743-l4.6

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  302. Scanning capacitance microscopy of SiC multiple PN junction structure grown by cold-wall chemical vapor deposition

    Suda J., Nakamura S., Miura M., Kimoto T., Matsunami H.

    Materials Science Forum   Vol. 389-393 ( 1 ) page: 659 - 662   2002

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    Scanning capacitance microscopy (SCM) of a SiC multiple pn junction structure is presented. The structure was grown by cold-wall atmospheric-pressure chemical vapor deposition using silane, propane and hydrogen. Nitrogen and diborane were used for n- and p-type doping gases, respectively. From secondary ion mass spectrometry (SIMS), it was confirmed that a multiple pn junction consists of 0.2 μm-thick n-type layer and 0.3 μm-thick p-type layer with a doping level of 1.5×1017 cm-3 was successfully grown. The multiple pn junction structure was clearly resolved by SCM and scanning electron microscopy (SEM). © 2002 Trans Tech Publications.

    DOI: 10.4028/www.scientific.net/msf.389-393.659

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  303. Zirconium diboride (0001) as an electrically conductive lattice-matched substrate for gallium nitride

    Kinoshita H, Otani S, Kamiyama S, Amano H, Akasaki I, Suda J, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 40 ( 12A ) page: L1280 - L1282   2001.12

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  304. Zirconium diboride (0001) as an electrically conductive lattice-matched substrate for gallium nitride

    Kinoshita H., Otani S., Kamiyama S., Amano H., Akasaki I., Suda J., Matsunami H.

    Japanese Journal of Applied Physics, Part 2: Letters   Vol. 40 ( 12 A )   2001.12

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    Zirconium diboride (ZrB2) has a hexagonal crystal structure with an in-plane lattice constant of 3.168 Å, very close to that of GaN (3.189 Å). It is a metalloid compound and a very good electrical conductor, with a resistivity of 4.6μΩ·cm. We propose ZrB2 (0001) as an electrically conductive lattice-matched substrate for GaN. Firstly, bulk crystal growth of ZrB2 using a radio frequency (rf)-heated floating zone (FZ) method is presented. Relatively large crystals (φ 10 mm × 60 mm) were obtained using this method. The thermal expansion coefficient and thermal conductivity of ZrB2 were evaluated using this crystal. Characterization of ZrB2 (0001) mirror-polished substrate was carried out by optical microscopic examination and X-ray diffraction. Finally, the results of heteroepitaxial growth are briefly mentioned.

    DOI: 10.1143/jjap.40.l1280

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  305. Selective area growth of cubic GaN on 3C-SiC (001) by metalorganic molecular beam epitaxy

    Suda J, Kurobe T, Nakamura S, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 39 ( 11A ) page: L1081 - L1083   2000.11

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  306. Selective area growth of cubic GaN on 3C-SiC (001) by metalorganic molecular beam epitaxy

    Suda J., Kurobe T., Nakamura S., Matsunami H.

    Japanese journal of applied physics   Vol. 39 ( 11 A )   2000.11

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    Selective area growth (SAG) of cubic GaN (c-GaN) was performed by metalorganic molecular beam epitaxy (MOMBE). The substrates used in this study were vapor phase epitaxy (VPE)-grown 3C-SiC on Si (001) 4°-off substrates. As a mask, 70-nm-thick SiO2 was formed by thermal oxidation of 3C-SiC and patterned by photolithography or focused ion beam (FIB) etching. GaN was grown on these patterned 3C-SiC substrates without a low-temperature-grown (LT) buffer layer. At a high growth temperature (850 °C), growth of GaN did not occur even on a 3C-SiC surface. At a low temperature (800 °C), c-GaN was epitaxially grown on a 3C-SiC surface, while polycrystalline GaN (poly-GaN) was grown on the SiO2-masked region. Growth of poly-GaN on the mask was suppressed by optimizing the growth temperature and V/III supply ratio. The possibility of positioning control for c-GaN microcrystals is also presented.

    DOI: 10.1143/jjap.39.l1081

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  307. GaP/Si heterojunction with ohmic conduction fabricated by wafer fusion technique

    Soeno A, Kajita D, Suda J, Matsunami H

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 39 ( 9AB ) page: L905 - L907   2000.9

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  308. GaP/Si heterojunction with ohmic conduction fabricated by wafer fusion technique

    Soeno A., Kajita D., Suda J., Matsunami H.

    Japanese Journal of Applied Physics, Part 2: Letters   Vol. 39 ( 9 A/B )   2000.9

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    In this letter, we report the fabrication of a GaP/Si heterojunction with ohmic conduction by a wafer fusion technique. After a hydrophilic pretreatment, GaP and Si wafers were brought in contact and annealed at 500 °C in a flowing forming gas for 30 min. The electrical properties of n-GaP/n+-Si and p+-GaP/n+-Si junctions fabricated by this procedure were investigated. The n-GaP/n+-Si junction exhibited potential barriers for both directions, indicating Fermi-level pinning due to high-density interface states at the fused interface. For the p+-GaP/n+-Si junction, ohmic conduction (10-20 Ω·cm2) was observed. This may be due to carrier transport by a tunneling process. The wafer fusion technique of GaP/Si is applicable to optoelectronic integrated circuits (OEICs) and high-efficiency tandem-type solar cells.

    DOI: 10.1143/jjap.39.l905

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  309. Morphological diversity in the crystal growth of potassium and rubidium dichromates in gelatin gel

    Suda J., Matsushita M., Izumi K.

    Journal of the Physical Society of Japan   Vol. 69 ( 1 ) page: 124 - 129   2000.1

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    We have found that the crystals of rubidium dichromate (Rb2Cr2O7) grown in gelatin gel have a rich variety of morphologies such as platelike, spherulitic and diffusion-limited aggregation (DLA)-like shapes. The morphological diagram has been determined in the range of solute and gelatin concentrations from 1.0 to 4.0%, 0.1 to 7.0%, respectively. The diagram corresponds to that of potassium dichromate (K2Cr2O7) which is similar to Rb2Cr2O7 in the crystal structure and physico-chemical properties. However, featherlike crystals have grown in the region of the diagram where the unique helical K2Cr2O7 crystals grow. We discuss the morphological changes of two kinds of dichromate crystals grown in gelatin gel.

    DOI: 10.1143/JPSJ.69.124

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  310. Morphological diversity in the crystal growth of potassium. and rubidium dichromates in gelatin gel

    Suda J, Matsushita M, Izumi K

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   Vol. 69 ( 1 ) page: 124 - 129   2000.1

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  311. Growth of cubic GaN by metal organic molecular beam epitaxy

    Suda J., Kurobe T., Matsunami H.

    Shinku/Journal of the Vacuum Society of Japan   Vol. 43 ( 4 ) page: 512 - 517   2000

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    Growth of GaN on sapphire (0001) substrates by metalorganic molecular beam epitaxy (MOMBE) was studied using triethyl gallium (TEGa) and rf plasma excited active nitrogen. A series of samples were grown under various TEGa flow rates while growth temperature (800 °C) and nitrogen supply were fixed. With increasing TEGa flow rate, the dominant polytype of grown layer changed from hexagonal GaN (h-GaN) to cubic GaN (c-GaN). From the dependence of growth rate on TEGa flow rates, it was revealed that a Ga-stabilized growth condition results in the growth of c-GaN. This preferential growth mode was applied to the growth of c-GaN on cubic 3C-SiC (001) substrates.

    DOI: 10.3131/jvsj.43.512

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  312. Preferential growth mode of cubic GaN by metalorganic molecular beam epitaxy on sapphire (0001) substrates

    Suda J, Kurobe T, Masuda T, Matsunami H

    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE   Vol. 176 ( 1 ) page: 503 - 507   1999.11

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  313. Preferential growth mode of cubic GaN by metalorganic molecular beam epitaxy on sapphire (0001) substrates

    Suda J., Kurobe T., Masuda T., Matsunami H.

    Physica Status Solidi (A) Applied Research   Vol. 176 ( 1 ) page: 503 - 507   1999.11

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    Growth of GaN on sapphire (0001) substrates by metalorganic molecular beam epitaxy (MOMBE) was studied using triethyl gallium (TEGa) and rf-plasma excited active nitrogen. A series of samples were grown under various TEGa flow rates while growth temperature (800 °C) and nitrogen supply were fixed. At a very low TEGa flow rate, the grown layer was polycrystalline. With increasing TEGa flow rate, the dominant polytype of the grown layer changed from hexagonal GaN (h-GaN) to cubic GaN (c-GaN). From the dependence of growth rate on TEGa flow rates, it was revealed that a Ga-stabilized growth condition results in the growth of c-GaN. By increasing growth time, the c-GaN composition became larger, indicating preferential growth of c-GaN.

    DOI: 10.1002/(SICI)1521-396X(199911)176:1<503::AID-PSSA503>3.0.CO;2-1

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  314. Growth evolution of cubic-GaN on sapphire (0001) substrate by metalorganic molecular beam epitaxy

    Suda J, Kurobe T, Matsunami H

    JOURNAL OF CRYSTAL GROWTH   Vol. 201   page: 437 - 440   1999.5

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  315. Growth evolution of cubic-GaN on sapphire (0 0 0 1) substrate by metalorganic molecular beam epitaxy

    Suda J., Kurobe T., Matsunami H.

    Journal of Crystal Growth   Vol. 201   page: 437 - 440   1999.5

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    Cubic GaN (c-GaN) could be grown on sapphire (0 0 0 1) substrates by metalorganic molecular beam epitaxy (MOMBE) under a Ga-rich condition at a relatively high growth temperature (800 °C). The growth was carried out with two different substrate treatments, either nitridation or deposition of a GaN buffer layer at a low temperature (400 °C). In both case, the grown layer contains not only c-GaN but also hexagonal GaN (h-GaN). The ratio of h-GaN to c-GaN is greatly reduced by using the buffer layer. Based on the experimental results, a growth model of c-GaN is proposed.

    DOI: 10.1016/S0022-0248(98)01370-0

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  316. Preferential growth of cubic GaN on sapphire (0001) substrates by metal organic molecular beam epitaxy

    Kurobe T., Sekiguchi Y., Suda J., Yoshimoto M., Matsunami H.

    Applied Physics Letters   Vol. 73 ( 16 ) page: 2305 - 2307   1998.12

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    Preferential growth of high-quality cubic GaN on sapphire (0001) substrates was realized at 800°C under a Ga-rich condition by metal organic molecular beam epitaxy. Hexagonal GaN was grown under a N-rich condition. On the contrary, under the Ga-rich condition, the growing layer changed from a hexagonal phase to a cubic phase as the growth proceeds, which was verified by in situ reflection high-energy electron diffraction. The low-temperature photoluminescence (PL) of this layer was dominated by a sharp and intense excitonic emission of cubic GaN, indicating high crystal quality. The results of PL and x-ray diffraction indicate that the polytype of GaN can be intentionally controlled by changing V/III ratios without serious degradation of crystal quality. In addition, enhancement of cubic phase growth by using a low-temperature grown buffer layer is also discussed. © 1998 American Institute of Physics.

    DOI: 10.1063/1.121805

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  317. Preferential growth of cubic GaN on sapphire (0001) substrates by metal organic molecular beam epitaxy

    Kurobe T, Sekiguchi Y, Suda J, Yoshimoto M, Matsunami H

    APPLIED PHYSICS LETTERS   Vol. 73 ( 16 ) page: 2305 - 2307   1998.10

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  318. Optical properties of light-hole excitons in ZnSSe/ZnMgSSe tensile-strained quantum wells

    Suda J, Ogawa M, Sakurai K, Kawakami Y, Fujita S, Fujita S

    JOURNAL OF CRYSTAL GROWTH   Vol. 184   page: 863 - 866   1998.2

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  319. Optical properties of light-hole excitons in ZnSSe/ZnMgSSe tensile-strained quantum wells

    Suda J., Ogawa M., Sakurai K., Kawakami Y., Fujita S., Fujita S.

    Journal of Crystal Growth   Vol. 184-185   page: 863 - 866   1998

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    Optical properties are assessed in the ZnSSe/ZnMgSSe tensile-strained multiple quantum wells (MQWs) which were grown on GaAs (0 0 1) substrates by gas-source molecular-beam epitaxy (GSMBE). Optically pumped lasing was performed at 23 K in the transverse magnetic (TM) mode with the threshold excitation intensity of 80 kW/cm2, indicating that optical gain is contributed from the recombination process of light-hole excitons in the ZnSSe wells. Time-resolved photoluminescence (TRPL) spectroscopy revealed the dynamical behavior of localized excitons. © 1998 Elsevier Science B.V. All rights reserved.

    DOI: 10.1016/s0022-0248(98)80180-2

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  320. Hydrogen sulfide treatment of GaAs substrate and its effects on initial stage of ZnSe growth

    Suda J, Tokutome R, Kawakami Y, Fujita S, Fujita S

    JOURNAL OF CRYSTAL GROWTH   Vol. 175   page: 593 - 597   1997.5

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  321. Hydrogen sulfide treatment of GaAs substrate and its effects on initial stage of ZnSe growth

    Suda J., Tokutome R., Kawakami Y., Fujita S., Fujita S.

    Journal of Crystal Growth   Vol. 175-176 ( PART 1 ) page: 593 - 597   1997.5

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    Hydrogen sulfide (H2S) treatment of GaAs substrates was examined by means of in situ reflection high energy electron diffraction (RHEED) and ex situ atomic force microscope (AFM) observations. Its effects on initial stage of molecular beam epitaxy (MBE) of ZnSe were also investigated. According to the H2S treatment conditions, an atomically flat surface with (4 × 3) reconstruction or a faceted surface with (2 × 6) reconstruction was obtained. Clear RHEED intensity oscillations over 40 cycles were observed just after starting the growth on the (4 × 3) surface, showing two-dimensional (2D) nucleation, i.e., layer-by-layer growth of ZnSe. Etch pit density (EPD) of the epilayer was about 2.5 × 106 cm-2, which was much lower than that obtained by the ever applied ammonium-sulfide ((NH4)2Sx) treatment.

    DOI: 10.1016/S0022-0248(96)00997-9

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  322. Surface reconstruction and morphology of hydrogen sulfide treated GaAs (001) substrate

    Suda J, Kawakami Y, Fujita S, Fujita S

    CONTROL OF SEMICONDUCTOR SURFACES AND INTERFACES   Vol. 448   page: 15 - 20   1997

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  323. (2x6) surface reconstruction of GaAs (001) obtained by hydrogen sulfide irradiation

    Suda J, Kawakami Y, Fujita S, Fujita S

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS   Vol. 35 ( 11B ) page: L1498 - L1500   1996.11

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  324. (2 × 6) surface reconstruction of GaAs (001) obtained by hydrogen sulfide irradiation

    Suda J., Kawakami Y., Fujita S., Fujita S.

    Japanese Journal of Applied Physics, Part 2: Letters   Vol. 35 ( 11 SUPPL. B )   1996.11

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    Sulfur treatment of GaAs (001) using hydrogen sulfide to obtain a (2 × 6) S-terminated surface is presented. When a GaAs substrate with no epitaxial buffer layer is annealed at up to 580°C in a high vacuum (< 1 × 10-9 Torr) a mixture of (3 × 6) and (4 × 6) Ga-terminated reconstructions is observed. After cooling of the substrate to 300°C and irradiating it with hydrogen sulfide, a clear (2 × 6) S-terminated surface reconstruction appears in a few minutes.

    DOI: 10.1143/jjap.35.l1498

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  325. Growth of p-type ZnSe by metalorganic molecular beam epitaxy using metal Zn and dimethylselenide

    Suda J, Tsuka M, Honda D, Funato M, Kawakami Y, Fujita S, Fujita S

    JOURNAL OF ELECTRONIC MATERIALS   Vol. 25 ( 2 ) page: 223 - 227   1996.2

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  326. The role of defects on radiative transitions in nitrogen doped ZnSe

    Hauksson IS, Suda J, Tsuka M, Kawakami Y, Fujita S, Fujita S

    JOURNAL OF CRYSTAL GROWTH   Vol. 159 ( 1-4 ) page: 329 - 333   1996.2

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  327. Dynamics of dense excitonic systems in ZnSe-based single quantum wells

    Yamada Y, Mishina T, Masumoto Y, Kawakami Y, Suda J, Fujita S, Fujita S, Taguchi T

    JOURNAL OF CRYSTAL GROWTH   Vol. 159 ( 1-4 ) page: 814 - 817   1996.2

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  328. Growth of P-type ZnSe by metalorganic molecular beam epitaxy using metal Zn and dimethylselenide

    Suda J., Tsuka M., Honda D., Funato M., Kawakami Y., Fujita S., Fujita S.

    Journal of Electronic Materials   Vol. 25 ( 2 ) page: 223 - 227   1996.2

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    This paper describes metalorganic molecular beam epitaxy (MOMBE) of p-type ZnSe using metal zinc, pre-cracked metalorganic dimethylselenide, and microwave-excited nitrogen plasma as sources. Optical, structural, and electrical properties of the p-type ZnSe layers have been investigated. At present, maximum net acceptor concentration Na-Nd is 3 × 1017 cm-3 without any post-growth annealing. This is the highest acceptor concentration ever reported for MOMBE-grown p-type ZnSe doped with nitrogen plasma, but photoluminescence and deep level transient spectroscopy suggest that acceptors are highly compensated and the reduction of compensating defects is a key to further increase the acceptor concentration.

    DOI: 10.1007/BF02666248

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  329. Dynamics of dense excitonic systems in ZnSe-based single quantum wells

    Yamada Y., Mishina T., Masumoto Y., Kawakami Y., Suda J., Fujita S., Fujita S., Taguchi T.

    Journal of Crystal Growth   Vol. 159 ( 1-4 ) page: 814 - 817   1996.2

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    Time-resolved nonlinear luminescence of excitons and bi-excitons in ZnSe-based single quantum wells has been studied by means of a sub-picosecond excitation correlation technique. The enhancement in luminescence efficiency of bi-excitons was clearly observed in a time-correlation trace of nonlinear bi-exciton luminescence. The origin of the enhancement was attributed to the higher-order nonlinearity with respect to the density of bi-excitons, and was explained by considering the stimulation of bi-exciton luminescence.

    DOI: 10.1016/0022-0248(95)00700-8

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  330. The role of defects on radiative transitions in nitrogen doped ZnSe

    Hauksson I., Suda J., Tsuka M., Kawakami Y., Fujita S., Fujita S.

    Journal of Crystal Growth   Vol. 159 ( 1-4 ) page: 329 - 333   1996.2

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    The radiative emission in nitrogen doped ZnSe grown by molecular beam epitaxy (MBE) and metalorganic molecular beam epitaxy (MOMBE) has been studied by means of time-resolved spectroscopy at 18 K. The lifetime of the free exciton emission and the oscillator strength of the acceptor bound exciton transition decreases with increased nitrogen incorporation. ZnSe:N MOMBE grown samples show different or additional compensation mechanism compared with MBE grown ZnSe:N due to higher defect concentration. The characteristic lifetime of the donor-acceptor pair emission is found to increase with increased incorporation of nitrogen as longer radiative lifetime of more localized carriers is expected as the carriers are trapped in deeper potential wells.

    DOI: 10.1016/0022-0248(95)00585-4

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  331. TIME-RESOLVED NONLINEAR LUMINESCENCE OF BIEXCITONS IN ZNSE-ZNXMG1-XSYSE1-Y SINGLE QUANTUM-WELLS

    YAMADA Y, MISHINA T, MASUMOTO Y, KAWAKAMI Y, SUDA J, FUJITA S, FUJITA S

    PHYSICAL REVIEW B   Vol. 52 ( 4 ) page: R2289 - R2292   1995.7

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  332. GROWTH OF ZNSE/ZNMGSSE QUANTUM-WELL STRUCTURES BY METALORGANIC MOLECULAR-BEAM EPITAXY UNDER IN-SITU OBSERVATION OF REFLECTION HIGH-ENERGY ELECTRON-DIFFRACTION INTENSITY OSCILLATION

    SUDA J, KAWAKAMI Y, FUJITA S, FUJITA S

    JOURNAL OF CRYSTAL GROWTH   Vol. 150 ( 1-4 ) page: 738 - 742   1995.5

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  333. Growth of ZnSe/ZnMgSSe quantum well structures by metalorganic molecular beam epitaxy under in situ observation of reflection high energy electron diffraction intensity oscillation

    Suda J., Kawakami Y., Fujita S., Fujita S.

    Journal of Crystal Growth   Vol. 150   page: 738 - 742   1995

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    ZnSe/ZnMgSSe quantum well (QW) structures with an abrupt heterointerface have successfully been grown on [100]-oriented GaAs substrates by metalorganic molecular beam epitaxy (MOMBE) under in situ observation of reflection high energy electron diffraction (RHEED). Source materials used were elemental zinc (Zn), selenium (Se), the RHEED specular spot were observed over 10 cycles during the growth of ZnSe well and ZnMgSSe barrier layers. A series of single quantum wells (SQWs) with various well widths were grown and characterized by photoluminescence (PL) measurements at 4.2 K. SQWs with 24 and 33 Å well widths exhibited sharp intense emissions which originated from n=1 heavy-hole free excitons. © 1995, All rights reserved.

    DOI: 10.1016/0022-0248(95)80038-E

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  334. Time-resolved nonlinear luminescence of biexcitons in ZnSe-ZnxMg1-xSySe1-y single quantum wells

    Yamada Y., Mishina T., Masumoto Y., Kawakami Y., Suda J., Fujita S., Fujita S.

    Physical Review B   Vol. 52 ( 4 )   1995

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    Nonlinear optical properties of dense excitonic systems in ZnSe-ZnxMg1-xSySe1-y single quantum wells have been studied by means of time-resolved nonlinear luminescence spectroscopy, based on an excitation correlation technique. The enhancement in luminescence efficiency of biexcitons was clearly observed in a time-correlation trace of nonlinear biexciton luminescence. The origin of the enhancement was attributed to the stimulation of biexciton luminescence. © 1995 The American Physical Society.

    DOI: 10.1103/PhysRevB.52.R2289

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  335. OPTICAL-PROPERTIES OF ZNSE/ZNMGSSE SINGLE QUANTUM-WELLS GROWN BY METALORGANIC MOLECULAR-BEAM EPITAXY

    SUDA J, KAWAKAMI Y, FUJITA S, FUJITA S

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 33 ( 7B ) page: L986 - L989   1994.7

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  336. Optical properties of ZnSe/ZnMgSSe single quantum wells grown by metalorganic molecular beam epitaxy

    Suda J., Kawakami Y., Fujita S., Fujita S.

    Japanese Journal of Applied Physics   Vol. 33 ( 7 ) page: L986 - L989   1994.7

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    In this letter we report optical properties of ZnSe/ZnMgSSe single quantum wells (SQWs) grown by metalorganic molecular beam epitaxy (MOMBE). At 4.2 K, a 10.5 monolayer (30 Å) ZnSe SQW confined in Zn0.90Mg0.10-S0.18Se0.82 layers exhibited intense purplish blue photoluminescence (PL) peaking at 2.865 eV, whose linewidth was as small as 5 meV. This emission was assigned to the n=1 heavy-hole exciton (.Ex1hh)- Another peak appeared on the low-energy side of Ex1hh under high excitation and grew nonlinearly with increasing excitation intensity. We tentatively attribute this line to the recombination of biexcitons. The exciton-longitudinal-optical(LO)-phonon coupling constant was also assessed from the temperature dependence of PL measurements. © 1994 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.33.L986

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  337. GAS-SOURCE MOLECULAR-BEAM EPITAXIAL-GROWTH OF (ZN,MG)(S,SE) USING BIS-METHYLCYCLOPENTADIENYL-MAGNESIUM AND HYDROGEN-SULFIDE

    SUDA J, KAWAKAMI Y, FUJITA S, FUJITA S

    JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS   Vol. 33 ( 3A ) page: L290 - L293   1994.3

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  338. Gas-source molecular beam epitaxial growth of (zn, mg)(s, se) using bis-methylcyclopentadienyl-magnesium and hydrogen sulfide

    Suda J., Kawakami Y., Fujita S., Fujita S.

    Japanese Journal of Applied Physics   Vol. 33 ( 3 ) page: L290 - L293   1994.3

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    In this letter we report the first successful gas-source molecular beam epitaxy (GSMBE) of ZnMgSSe on (100) GaAs substrates. Source materials used were elemental zinc (Zn), elemental selenium (Se), hydrogen sulfide (H2S) and bis-methylcyclopentadienyl-magnesium ((MeCp)2Mg). It is revealed that the growth by this technique results in good controllability of solid compositions of this quaternary alloy system. Photoluminescence and X-ray diffraction measurements show that the layer coherently grown on GaAs exhibits high quality comparable to that grown by conventional molecular beam epitaxy (MBE). © 1994 The Japan Society of Applied Physics.

    DOI: 10.1143/JJAP.33.L290

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  339. GAS-SOURCE MBE OF ZNMGSSE LAYERS

    FUJITA S, SUDA J, KAWAKAMI Y, FUJITA S

    II-VI BLUE/GREEN LASER DIODES   Vol. 2346   page: 40 - 47   1994

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Books 2

  1. Lifetime-Killing Defects in 4H-SiC Epilayers and Lifetime Control by Low-Energy Electron Irradiation

    Kimoto T., Danno K., Suda J.( Role: Sole author)

    Silicon Carbide  2011.4  ( ISBN:9783527409532

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    Language:Japanese

    DOI: 10.1002/9783527629053.ch10

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  2. 4H-SiC MISFETs with Nitrogen-Containing Insulators

    Noborio M., Suda J., Beljakowa S., Krieger M., Kimoto T.( Role: Sole author)

    Silicon Carbide  2011.3  ( ISBN:9783527409976

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    Language:Japanese

    DOI: 10.1002/9783527629077.ch10

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KAKENHI (Grants-in-Aid for Scientific Research) 20

  1. 炭化珪素基板上へのⅢ族窒化物の超高品質コヒーレント成長の基礎とデバイス応用

    2012.4 - 2016.3

    科学研究費補助金  基盤研究(B)

    須田 淳

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    SiC基板上への高Al組成窒化物半導体のコヒーレント成長の基礎を築き、デバイス応用への展開を目指して研究を行った。高Al組成AlGaNの成長として、組成や構造のデジタル的な制御が可能な、AlN/GaN短周期超格子に着目した。さまざまな構造・成長条件のAlN/GaN短周期超格子の臨界膜厚の解明、緩和メカニズムの解明を行い、GaNモル分率20%の規則混晶のコヒーレント成長に成功した。また、3BLのGaNを成長すると格子緩和がはじまることを明らかにした。極薄GaNの格子緩和はゆっくりと生じることを利用して、SiC基板上に圧縮、引っ張り歪みを持つAlNを成長する方法も提案した。

  2. 炭化珪素半導体の欠陥制御と超高耐圧ロバスト素子への応用

    2009.4 - 2014.3

    科学研究費補助金  基盤研究(S)

    木本 恒暢

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    電力系統や高圧電源に用いられる高効率電力変換用パワーデバイスの実現を目指し、炭化珪素(SiC)半導体に関する材料科学と超高耐圧デバイスの基礎研究を遂行した。主な成果として、高純度結晶の作製、拡張欠陥の構造および物性の解明、拡張欠陥の非破壊高速検出、深い準位の物性解明、キャリア寿命キラー欠陥の大幅な低減とキャリア寿命の増大、キャリア寿命制御、超高耐圧を可能とする接合終端構造および設計指針の提示、絶縁破壊機構に関する考察、固体素子として最高の超高耐圧(20kV以上) SiC PiNダイオードおよびバイポーラトランジスタの作製、特性解析と高温動作(300℃)の実証を達成した。

  3. 超高耐圧ロバスト素子を目指した炭化珪素半導体の欠陥制御に関する研究

    2009.4 - 2010.3

    科学研究費補助金  基盤研究(A)

    木本 恒暢

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  4. 新しい結晶構造を持つ窒化アルミニウムの物性制御と深紫外発光デバイスへの展開

    2008.4 - 2011.3

    科学研究費補助金  基盤研究(B)

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  5. イオン注入および埋め込み再成長を利用したSiC超接合パワーMOSFETの研究

    2006.4 - 2009.3

    科学研究費補助金  基盤研究(A)

    木本 恒暢

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  6. ヘテロバレント・ヘテロポリタイプSiC上III族窒化物結晶成長の総合的理解と制御

    2004.4 - 2007.3

    科学研究費補助金  若手研究(A)

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  7. Dislocation passivation in InGaN by intentinally using immiscible nature during MBE growth by DERI method

    Grant number:26600090  2014.4 - 2017.3

    NANISHI YASUSHI

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    InGaN alloys are currently widely used as active layers of blue LEDs. Optical and electronic characteristics are degraded dramatically, however, when we increase In composition to fabricate green, red and infra-red LEDs due to generation of dislocations. In this study, we tried to suppress this dislocation effect by using DERI method, newly developed RF-MBE growth method by us, for high quality InN growth. Intentionally utilizing immiscible nature of InGaN alloys, we grew Ga-rich InGaN surrounding dislocations with wider bandgap. It was found that leakage current due to dislocation was suppressed as expected by conductive AFM measurements.

  8. Coherent growth of high-quality group-III nitirides on SiC substrates and its device applications

    Grant number:24360009  2012.4 - 2016.3

    Suda Jun

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    Grant amount:\18590000 ( Direct Cost: \14300000 、 Indirect Cost:\4290000 )

    Coherent Growth of high-Al-content AlGaN on SiC substrates aiming at device applications were investigated. As high-Al-content AlGaN, AlN/GaN short-period superlattices were grown. Various kinds of AlN/GaN Superlattices were grown to assess critical composition as well as critical thickness for coherent growth on SiC substrates. Superlattices with GaN mole fraction of 20% were successfully growth coherently. On the other hand, it was found that growth of 3-bilayer-thick GaN results in lattice relaxation. The relaxation was gradual. By using this nature, strain-controlled AlN were grown on SiC substrates via ultra-thin GaN/AlN multilayer structures.

  9. Temperature independent SiC photodetector operating up to 500 degreeC

    Grant number:24656230  2012.4 - 2014.3

    SUDA Jun

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    Grant amount:\4030000 ( Direct Cost: \3100000 、 Indirect Cost:\930000 )

    Ultra-violet photo detectors which can be operated up to 500 degreeC are needed for monitoring system of power plant and chemical plant. Such photo detectors are also expected to be used in engine combustion monitoring for automotive or aerospace field. Silicon (Si) which is mainly used in nowadays electronics cannot be operated at over 200 degreeC due to its small energy bandgap of 1.12 eV. Wide-bandgap semiconductor, silicon carbide (4H-SiC) is promising candidate for such photo detectors. In this study, we investigated optical properties of SiC, which are required for device design. We also found effective suppression method of leakage current which degrades sensitivity of photo detector. Based on these results, we successfully demonstrated operation of SiC photo detectors at 500 degree C.

  10. Defect Engineering in SiC and Application to Robust Devices with Ultrahigh Blocking Voltage

    Grant number:21226008  2009.5 - 2014.3

    KIMOTO Tsunenobu

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    Defect electronics in SiC and ultrahigh-voltage SiC power devices have been studied toward efficient electric power conversion employed for future smart grids. Fast epitaxy of high-purity SiC was developed, and extended defects in SiC epitaxial layers were systematically characterized. Physical properties of the major deep levels were elucidated. The carrier-lifetime killer defects could be eliminated, leading to remarkably enhanced carrier lifetimes. Control of carrier lifetimes was also achieved. Original junction-termination structures were proposed to achieve ultrahigh blocking voltage with SiC, and breakdown mechanism of SiC devices was discussed. By utilizing thick, lightly-doped SiC epitaxial layers and the original device structures, ultrahigh-voltage (> 20 kV) PiN diodes and npn bipolar transistors were realized. The performance was significantly improved by enhancement of carrier lifetimes, and high-temperature operation of SiC devices was demonstrated.

  11. 超高耐圧ロバスト素子を目指した炭化珪素半導体の欠陥制御に関する研究

    Grant number:21246051  2009

    木本 恒暢

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    超高耐圧素子の作製に必要な高純度・厚膜SiCエピタキシャル成長層の形成と欠陥評価について研究を行った。得られた成果は以下のとおりである。
    (1)独自の化学気相堆積法により、70-90μm/hの高速で70-160μmの厚膜SiCエピタキシャル成長層を形成することに成功した。成長層の表面は原子レベルで平坦であり、残留不純物密度が約1E13/cm3という高純度結晶を得た。また、SiCパワーデバイスの信頼性に悪影響を及ぼす基底面転位(基板から伝播)の密度が、成長速度の上昇と共に減少することを見出した。
    (2)フォトルミネッセンス(PL)のマッピング測定により、SiC成長層中に存在するin-grown積層欠陥を高速・非破壊に検出できることを示した。SiC成長層中に存在する主要なin-grown積層欠陥には3種類あり、高分解能断面電子顕微鏡(TEM)観察により、各々の欠陥構造を原子レベルで明らかにした。さらに、成長初期プロセスの改良により、積層欠陥密度を大幅に低減することに成功した。
    (3)n型SiC成長層に存在する点欠陥(深い準位)をショットキー障壁容量の過渡特性解析(DLTS)により評価した。伝導帯底から約0.6eVおよび1.5eVのエネルギー位置に主要な電子トラップが存在すること、およびこれらの点欠陥は1700℃の高温熱処理を施すことにより、密度を大幅に低減できることを明らかにした。

  12. Accurate measurements of the second-order nonlinear-optical coefficients of SiC

    Grant number:20560038  2008 - 2010

    SHOJI Ichiro

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    We have accurately measured the second-order nonlinear-optical coefficients of SiC, which is expected to be a material for next-generation high-power frequency-conversion devices. We carried out the measurements with several combinations of different manufacturers, polytypes, surface orientations of the samples, and different measurement techniques at the fundamental wavelength of 1.064 μm. The same accurate values were obtained for the same polytype samples, and d33 of 4H-SiC was found to be 6 % smaller than that of 6H-SiC. The magnitudes of the nonlinear-optical coefficients determined in this research should be useful for precise design of high-power and highly efficient frequency-conversion devices using SiC.

  13. Growth of aluminum nitride with a new crystal structure for deep-ultraviolet light emitting devices

    Grant number:20360008  2008 - 2010

    SUDA Jun

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    Grant amount:\18590000 ( Direct Cost: \14300000 、 Indirect Cost:\4290000 )

    Aluminum nitride (AlN) has attracted much attention as a material for deep-ultraviolet light emitting devices. Thermally stable structure of AlN is known to be wurtzite structure. On the other hand, AlN studied in this project has 4H structure. 4H-AlN can be obtained by isopolytypic growth on 4H-SiC. Thanks to isopolytypic growth, 4H-AlN grown on 4H-SiC shows excellent crystalline quality. In this study, growth of AlGaN alloy and AlGaN/AlN quantum well structures were studied. 4H-AlGaN/AlN quantum well structures were successfully grown on 4H-SiC (1-100). We revealed that growth of high-quality 4H-AlGaN on 4H-SiC (11-20) is impossible. We proposed 4H-GaN/AlN short-period super lattice structures instead of 4H-AlGaN. The 4H-GaN/AlN short-period super lattice structures were successfully grown on 4H-SiC (11-20).

  14. 窒化物半導体の非線形光学定数の精密評価と内部電界による制御

    Grant number:19032003  2007 - 2008

    近藤 高志

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    バルク試料を用いた回転型メーカーフリンジ法とウェッジ法とを併用することでSiCとGaNのintrmsicな非線形光学定数(d=x^<(2)>/2)の精密測定をおこなった。また, MBE法によるGaN周期極性反転構造の作製と導波路作製に取り組んだ。
    1. SiCの非線形光学定数精密測定
    GaNエピタキシャル薄膜の非線形光学定数をはかる準備として, 基板材料となるSiCの非線形光学定数評価をおこなった。その結果は以下のとおり。6H-SiCの非線形光学定数は, d_<31>=6.7pm/V, d_<15>=6.5pm/V, d_<33>=-12.5pm/V。4H-SiCの非線形光学定数は, d_<31>=6.5pm/V, d_<15>=6.7pm/V, d_<33>=-11.7pm/V。両者は測定誤差の範囲内で一致しているが, 4H-SiCのd_<33>が若干小さく, 理想的四面体構造に対して予想されるd_<33>/d_<31>=-2からのずれが大きい。これは, 4H-SICが6H-SiCと比較して格子の歪みが大きいことを反映している。
    2. GaNの非線形光学定数精密測定
    液相成長のバルク試料とエピタキシャル成長自立基板を試料として用い, GaNのintrinsicな非線形光学定数の精密測定をおこない, 以下の結果が得られた。d_<31>=2.4pm/V, d_<15>=2.5pm/V, d_<33>=-3.8pm/V。GaNは理想的四面体構造からの歪みが大きく, その結果, d_<33>/d_<31>=-2の関係から大きくずれている。また, この結果は, エピタキシャル薄膜試料を用いて測定された既報の値と比較してかなり小さく, これまでの測定に内部電界と3次非線形光学効果の影響が混入していたことをうかがわせる。
    3. 周期極性反転GaN導波路の作製
    MBEによるGaNエピタキシャル膜の格子極性制御の再現性を確認した上で, 疑似位相整合波長変換デバイス作製に不可欠な周期極性反転GaNの作製をおこなった。また, 導波路デバイス作製プロセス開発の第一段階としてリフトオフによるリブ構造作製が可能であることを示した。

  15. Study on SiC Super-Junction Power MOSFETs Utilizing Ion Implantation and Embedded Epitaxial Growth

    Grant number:18206032  2006 - 2008

    TSUNENOBU Kimoto

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  16. ヘテロバレント・ヘテロポリタイプSiC上III族窒化物結晶成長の総合的理解と制御

    Grant number:16686002  2004 - 2006

    須田 淳

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    Grant amount:\28600000 ( Direct Cost: \22000000 、 Indirect Cost:\6600000 )

    ヘテロバレソト・ヘテロポリタイプな系である、AlN/SiCヘテロエピタキシャル成長についての系統的な研究を行った。無極性面方位に関しては、(1-100)面、(11-20)面を対象に研究を行った。4H-SiCを用いた場合に、SiCの4層周期の積層構造がAlNに転写され、AlNは4H構造を持つことが明らかになった。SiC表面の原子レベルの平坦化とAlN成長条件の最適化を行うことで、きわめて欠陥の少ない4H-AlNを成長することに成功した。無極性面方位に関しては、成長条件を適切に設定することで、本来ヘテロポリタイプであるAlN/SiC系をアイソポリタイプ化し、結晶欠陥を大幅に低減できることが明らかになった。このアイソポリタイプAlNをテンプレートとして、デバイス応用上重要なGaNの成長を行った。広範囲な成長条件の検討を行ったが、GaNのポリタイプは熱力学的に安定な2H構造になってしまうことが判明した。AlN/GaNの格子不整合がAlN/SiCの倍以上であることや、GaNそれ自体が4H構造となった場合エネルギー的に不安定になることが原因として考えられるが、現時点では不明である。2H構造GaNは4H構造AlNほどは高品質ではないが、他の無極性基板と同等の品質のものが得られることは確認している。極性面については、SiCのステツプェツジに起因する欠陥の極限までの低減を目指して研究を進めた。ウエハーレベルでのSiCのステップエッジの高さ制御技術をほぼ確立し、6H-SiCにおいてステップ高さ6層に制御した基板を作製し、この表面上にAlNを成長し、結晶欠陥の低減を確認した。

  17. Fundamental Study on Low-loss SiC Power Devices Using Multi pn Junctions

    Grant number:16360153  2004 - 2005

    KIMOTO Tsunenobu

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    In this research project, designing and fabrication of low-loss, high-voltage silicon carbide (SiC) power devices with multi pn junction structures have been investigated. In the multi pn junction structures, two- or three-dimensional extension of space charge regions enables the usage of highly doped semiconductors, by which on-state resistance can be significantly reduced. This is the first investigation on SiC power devices with such structures. As a typical device, lateral high-voltage MOSFETs have been investigated.
    Effects of doping concentration of each region on breakdown voltage and on-resistance of SiC RESURF (Reduced Surface Field) MOSFETs have been analyzed by using a two-dimensional device simulator. Effective charge at the MOS interface influences the space charge region and thereby breakdown voltage. Optimum dose designing and its guideline have been determined. Double RESURF structure with a pnp layer structure is effective to reduce on-resistance. The breakdown voltage can be increased because the electric field inside the oxide is reduced.
    SiC Lateral RESURF MOSFETs have been fabricated on 10 μm-thick p-type epilayers. Ion implantation was employed to form RESURF, top-p, source, and drain regions. The gate oxide was grown by direct oxidation in N_3O at 1300℃. The typical channel length, RESURF length were 2〜3μm and 20μm, respectively. An original self-aigned process has been developed to fabricate double RESURF MOSFETs. A single-zone double RESURF MOSFET fabricated in this study exhibited a breakdown voltage of 750 V and a low on-resistance of 52 mΩcm^2. The original two-zone double RESURF MOSFET showed characteristics of 1380 V - 66mΩcm^2, which is the pest performance among any lateral MOSFETs ever reported.

  18. High-Voltage, High-Efficiency, High-Speed Power MOSFET Using Wide Bandgap Semiconductor SiC

    Grant number:13555094  2001 - 2002

    KIMOTO Tsunenobu

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    Control of MOS interface, device processing, and fabrication of high-voltage MOSFETs have been investigated by using a wide bandgap semiconductor silicon carbide (SiC), which shows high breakdown field and other excellent physical properties. In control of MOS interface, thermal oxidation at high temperature resulted in the improvement of the MOS quality, and high channel mobilities of 78 cm^2/Vs and 22 cm^2/Vs were obtained for 6H-SiC(OOOl) and 4H-SiC(OOOl) MOSFETs, respectively. 4H-SiC(ll20) and (0338) MOSFETs exhibited a high channel mobility of 30-40 cm^2/Vs. In device processing, thick SiO_2 films deposited by plasma CVD could successfully used as an implantation mask. Short-channel MOSFETs with a channel length of 1 μm could be processed. The electrical activation of implanted dopants was significantly improved by increasing annealing temperature after implantation. The structure of lateral SiC MOSFETs with RESURF (Reduced Surface Field) structure was designed by using a 2D device simulation. The RESURF dose, depth, and the drift layer structure were optimized. SiC lateral RESURF MOSFETs were fabricated on 4H-SiC and 6H-SiC which were grown in our group. The MOSFET showed a very high breakdown voltage of 1 kV and a low on-resistance of 0.1 Ωcm^2. This characteristics outperforms the "Si limit" which is theoretically determined from the material properties, demonstrating the much potential of SiC power devices.

  19. ワイドギャップ半導体ヘテロ界面の電子物性制御とパワーデバイスの高性能化への展開

    Grant number:13750010  2001 - 2002

    須田 淳

      More details

    Authorship:Principal investigator 

    Grant amount:\2100000 ( Direct Cost: \2100000 )

    ワイドギャップ半導体六方晶シリコンカーバイド(SiC)は大きな絶縁破壊電界強度を持つため、既存のシリコン(Si)系半導体パワーデバイスでは理論的に実現不可能な超低損失デバイスを実現可能と期待されている。しかし、シリコン酸化膜(SiO_2)/SiC界面におけるチャネル電子移動度がバルクSiCの電子移動度に比べ極めて小さいため、チャネル抵抗がデバイスの抵抗の大半を占め、デバイスの高性能化を阻んでいる。本研究では、SiO_2に代わる新たな絶縁膜としてSiCと同じ六方晶で、しかも、格子定数がほぼ等しい窒化アルミニウム(AlN)を提案している。窒化アルミニウムとSiCの界面を制御することで、デバイスに利用可能なAlN/SiCヘテロ構造を実現することを目指して研究を進めてきた。今年度得られた結果は以下の通りである。
    1.SiC表面を、構造的観点および化学的観点で制御を行うことで、高品質AlN結晶成長を実現した。すなわちステップ高さの制御と、表面に存在する酸素の完全な除去および表面超構造の発現を行ったSiC上にAlNを成長することで、2次元レイヤーバイレイヤー成長を実現すると共に、結晶性の大幅な改善を実現した。この高品質AIN層の応用としてGaN成長層の為のバッファー層として使用したところ、GaN層の結晶性も大きく向上することを明らかにした。GaN系パワーデバイスへの応用が期待される。
    2.従来用いられてきたSiC(0001)面に加え、無極性面であるSiC(11-20)面上へのAlNの結晶成長を試みた。SiCの結晶方位情報をAlNは引き継いで成長する、すなわち、エピタキシャル成長を実現した。しかし、SiCのポリタイプはAlNに引き継がれず、SiCが6Hポリタイプであるのに対して、AlNは2Hポリタイプ(ウルツ鉱構造)であることが判明した。この現象は結成成長学的に新しい知見であると当時に、GaN系光デバイスで必要とされる、無極性面の実現の1方法を新たに提案するものとして意義がある。

  20. 有機金属分子線エピタキシー法による立方晶窒化ガリウムの結晶成長機構の解明と応用

    Grant number:11750014  1999 - 2000

    奨励研究(A)

    須田 淳

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    Grant amount:\1000000 ( Direct Cost: \1000000 )

    トリエチルガリウム(TEGa)とrfプラズマ励起活性窒素(N^*)を原料に用いた有機金属分子線エピタキシャル(MOMBE)成長における、窒化ガリウム(GaN)の結晶成長機構を活用して新規な構造を作製することをめざして研究を進めた。
    立方晶シリコンカーバイド(3C-SiC)の(001)面方位を基板として用いて結晶成長を行ったところ、基板による構造引き込み効果により、サファイア基板上の場合よりもより広い成長条件で立方晶GaNが得られることが分かった。また、3C-SiC基板上においてはGaNの核形成が抑制されることが分かり、連続膜を得るためには低温バッファ層が不可欠であることが判明した。そこで、成長初期の核形成を制御すれば、任意の場所に立方晶の結晶を得ることができると考え、選択成長を試みることにした。
    3C-SiC基板を酸素雰囲気中で1000℃以上に加熱し、表面に酸化膜を形成した後、集束イオンビーム描画装置を用いて、酸化膜の一部を極微細な領域に限って除去し、真空トンネルを通じて直ちに結晶成長装置に搬送、GaNの結晶成長を行った。最適化した成長条件で、酸化膜の除去された開口部のみにGaNの核形成、結晶成長を起こすことに成功した。ただし、有機金属化学気相堆積(MOCVD)法で報告されているような横方向成長は確認されず、微小結晶が密集して存在する結晶成長形態であることが分かった。また、微小結晶は立方晶であり、{111}ファセットを側面に有していることが確認された。成長時間や開口部のサイズ調整などを行うことで、幾何学的に対称性を持つ微小結晶を平面に規則的に並べることができると考えられる。このような構造は、電子エミッタやフォトニック結晶などに応用可能と考えられる。

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Teaching Experience (On-campus) 10

  1. 線形代数学I

    2018

  2. 固体電子工学及び演習

    2018

  3. パワーデバイス工学特論

    2018

  4. 線形代数学I

    2021

  5. 固体電子工学及び演習

    2021

  6. 量子理論

    2021

  7. パワーデバイス工学特論

    2021

  8. 固体電子工学及び演習

    2020

  9. 固体電子工学及び演習

    2020

  10. 線形代数学I

    2019

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