Updated on 2024/04/06
博士（工学） （ 2014.3 東京大学 ）
Nanotechnology/Materials / Synthetic organic chemistry / radical
Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry
Nanotechnology/Materials / Organic functional materials
Life Science / Bioorganic chemistry
新規光触媒分子の開発と有機合成化学への展開
Nagoya University Institute of Transformative Bio-Molecules JSPS research fellow(PD)
2016.2 - 2016.3
Country：Japan
Kyoto University
2014.4 - 2016.1
Country：Japan
The University of Tokyo Graduate School, Division of Engineering
2011.4 - 2014.3
Country： Japan
The University of Tokyo Faculty of Engineering
2005.4 - 2009.3
Country： Japan
有機合成化学協会
日本化学会
Exploiting Single-Electron Transfer in Lewis Pairs for Catalytic Bond-Forming Reactions Reviewed
Yoshitaka Aramaki, Naoki Imaizumi, Mao Hotta, Jun Kumagai, Takashi Ooi
Chemical Science Vol. 11 ( 17 ) page： 4305 - 4311 2020.5
Excited-state tris(pentafluorophenyl)borane as a strong single-electron oxidant: Photophysical properties and catalysis Invited Reviewed
Yoshitaka Aramaki, Yuki Uchida, Ryo Ishikawa, Takashi Ooi
Journal of Photochemisty and Photobiology 2023.8
Synthesis and enantioseparation of chiral Au-13 nanoclusters protected by bis-N-heterocyclic carbene ligands Reviewed International coauthorship
Yi Hong, Osten Kimberly M., Levchenko Tetyana I, Veinot Alex J., Aramaki Yoshitaka, Ooi Takashi, Nambo Masakazu, Crudden Cathleen M.
CHEMICAL SCIENCE Vol. 12 ( 31 ) page： 10436 - 10440 2021.8
アニオンーπ触媒 Reviewed
荒巻 吉孝
有機合成化学協会誌 Vol. 75 ( 9 ) page： 965-966 2017.9
Anion-pi Catalyst
Aramaki Yoshitaka
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN Vol. 75 ( 9 ) page： 73 - + 2017.9
H. Shimogawa, O. Yoshikawa, Y. Aramaki, M. Murata, A. Wakamiya, Y. Murata
Chemistry -A European Journal Vol. 23 ( 15 ) page： 3784 - 3791 2017.3
Near-Infrared Emissive Donor-Acceptor-Type Molecules Containing Thiazole-Fused Benzothiadiazole as an Electron-Acceptor Moiety Reviewed
Motoi Satou, Tomoya Nakamura, Yoshitaka Aramaki, Shuhei Okazaki, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata
Chem. Lett. Vol. 45 ( 8 ) page： 892-894 2016.6
Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen Reviewed
Nicole Dettenrieder, Yoshitaka Aramaki, Benjamin M. Wolf, Cäcilia Maichle-Mössmer, Xiaoxi Zhao, Makoto Yamashita, Kyoko Nozaki, Reiner Anwander
Angew. Chem. Int. Ed. Vol. 53 ( 24 ) page： 6259-6262 2014.6
Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical Reviewed
Yoshitaka Aramaki, Hideki Omiya, Makoto Yamashita, Koji Nakabayashi, Shin-ichi Ohkoshi, Kyoko Nozaki
J. Am. Chem. Soc. Vol. 134 ( 49 ) page： 19989-19992 2012.12
Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions Reviewed
Kyoko Nozaki, Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Malacria, Emmanuel Lacôte, Dennis P. Curran
J. Am. Chem. Soc. Vol. 132 ( 33 ) page： 11449-11451 2010.8
Reduction of base-stabilized difluoroboranes to induce rearrangement reactions Reviewed
Makoto Yamashita, Yoshitaka Aramaki, Kyoko Nozaki
New J. Chem. Vol. 34 ( 8 ) page： 1774-1782 2010.7
Regio-divergent [3+2] Cycloaddition of gem-Difluorocyclopropane Derivatives Based on the Control of Bidirectional Bond Cleavage
2024.3.18
キラルブレンステッド塩基と光増感剤の協奏的触媒作用による立体選択的[3+2]環化付加反応の開発
西 健伸, 神作 八起, 山野本 健, 荒巻 吉孝, 浦口 大輔, 大井 貴史
日本化学会 第104春季年会 2024.3.19
gem-ジフルオロシクロプロパンの双方向性均等開裂の制御による位置異性体分岐型[3+2]環化付加反応の開発
内田 裕貴, 荒巻 吉孝, 大井 貴史
IRCCS成果報告会 2024.1.30
ルイス酸-塩基間での一電子移動の触媒化学 Invited
荒巻 吉孝
IRCCS成果報告会 2024.1.31
Development of 4-borylthiophenols as Multifunctional Photocatalyst
2024.1.12
Synthesis, Characterization and Reactivity of NHC stabilized Au8Pt Nanocluster
2023.9.13
多機能光触媒としてのボリルチオフェノールの創製：1,2-ジオール及び1,2-アミノアルコール誘導体合成への応用
木倉 健翔, 田浦 悠也, 荒巻 吉孝, 大井 貴史
日本化学会 第103春季年会 2023.3.24
Development and Catalytic Use of 4-Borylthiophenols as Multifunctional Donor-Acceptor-Type Molecules
木倉 健翔, 田浦 悠也, 荒巻 吉孝, 大井 貴史
2023.2.27
Development of 4-borylthiophenols as multifunctiona photocatalysts: Brønsted acid, single-electron reductant, and hydrogen atom transfer(HAT) reagent
2023.1.16
ブレンステッド酸・光一電子還元剤・水素原子引き抜き(HAT)の三機能を有するボリルチオフェノールの分子設計と触媒的応用
木倉 健翔, 田浦 悠也, 荒巻 吉孝, 大井 貴史
第53回中部化学関係学協会支部連合秋季大会 2022.11.5
電子不足トリアリールボランの光励起一電子酸化触媒としての機能開拓
内田 裕貴, 石川 稜, 荒巻 吉孝, 大井 貴史
日本化学会 第102春季年会 2022.3.25 日本化学会
内在的なルイス酸への一電子移動反応と炭素－炭素結合形成反応への触媒的展開
荒巻吉孝, 今泉直樹, 堀田真央, 大井貴史
2019年光化学討論会
Lewis酸への一電子移動を駆動力とした触媒システムの開発 International conference
石川稜, 今泉直樹, 荒巻吉孝, 大井貴史
ITbM/IGER Chemistry Workshop 2018
ルイス酸、ルイス塩基間での一電子移動によるラジカルイオンペア形成と光酸化還元反応触媒への展開
今泉直樹, 荒巻吉孝, 大井貴史
第113回有機合成シンポジウム2018
光照射下でのラジカルイオンペアの形成と触媒的結合形成反応への展開
今泉 直樹, 荒巻 吉孝, 大井 貴史
日本化学会第98春季年会
Grant number：21K14625 2021.4 - 2024.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Early-Career Scientists
Authorship：Principal investigator
Grant amount：\4680000 （ Direct Cost: \3600000 、 Indirect Cost：\1080000 ）
Grant number：19K15538 2019.4 - 2021.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Early-Career Scientists
Aramaki Yoshitaka
Authorship：Principal investigator
Grant amount：\4160000 （ Direct Cost: \3200000 、 Indirect Cost：\960000 ）
A self-activating hydrogen transfer catalyst has been developed as described in the title of this project. With the original molecular structure described in the research plan, but, by improving the molecular design of the radical active site, the catalyst as a photo-excited self-activating hydrogen catalyst was achieved. Using this catalyst, it became possible to proceed with the reaction of hydrogen atom transfer catalyst and single-electron reduction catalyst using only one catalyst, whereas the conventional method required two types of catalysts of photocatalyst and hydrogen atom transfer catalyst. In addition, the discovery of the single-electron transfer reaction between boron compounds and aniline derivatives, the analysis of the mechanism of the one-electron transfer reaction, and its application to catalytic carbon-carbon coupling reactions were reported in a paper.
Grant number：16H06862 2016.8 - 2018.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Research Activity Start-up
Aramaki Yoshitaka
Authorship：Principal investigator
Grant amount：\2990000 （ Direct Cost: \2300000 、 Indirect Cost：\690000 ）
In order to verify the transformation of radical reactivity depending on the coordination number of a boron center, some radical compounds with a boryl group were synthesized.In this process, we found the generation of Lewis radical-ion pairs via the single electron transfer between a Lewis acid and a base under photoirradiation. Although an additional condition, photoirradiation, is essential, the result indicates that the generation of boron-centered radical can be controlled by the presence and absence of a Lewis base. The finding will remove the barrier of structural limitation of Lewis pairs inducing single electron transfer and have a potential to accelerate the application to organic transformation and catalysis. In fact, we revealed the photocatalytic ability of electron-deficient borane, which could be a mile stone for catalysis of Lewis radical-ion pairs.
環状π共役系ホウ素化合物の合成とその芳香族性の実証
2014.4 - 2016.3
科学研究費補助金
Authorship：Principal investigator
低酸化数ホウ素化合物の合成と応用
2012.4 - 2014.3
科学研究費補助金
Chemistry and Biotechnology Laboratory 2
2023
有機化学実験I
2022
有機化学特別実験及び演習Ⅰ
2019
有機化学特別実験及び演習Ⅱ
2019
有機化学１及び演習
2019
有機化学実験第２
2018
有機化学実験第１
2018
有機化学セミナー１D
2018
有機化学セミナー１C
2018
有機化学セミナー1B
2018
有機化学セミナー1A
2018
有機化学１及び演習
2018
有機化学演習第１
2018
有機化学特別実験及び演習Ⅰ
2018
有機化学特別実験及び演習Ⅱ
2018
有機化学特別実験及び演習Ⅱ
2017
有機化学特別実験及び演習Ⅰ
2017
有機化学セミナー１D
2017
有機化学セミナー１C
2017
有機化学セミナー１B
2017
有機化学セミナー１A
2017
有機化学１及び演習
2017
有機化学演習第２
2017
有機化学実験第２
2017
有機化学実験第１
2017
有機化学特別実験及び演習Ⅱ
2016
有機化学特別実験及び演習Ⅰ
2016
有機化学セミナー１D
2016
有機化学セミナー１C
2016
有機化学セミナー１B
2016
有機化学セミナー１A
2016
