Updated on 2021/04/01

写真a

 
UCHIYAMA Mineto
 
Organization
Graduate School of Engineering Molecular and Macromolecular Chemistry 2 Lecturer
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Chemistry and Biotechnology
Title
Lecturer
Contact information
メールアドレス
External link

Degree 1

  1. 博士(工学) ( 2016.3   名古屋大学 ) 

Research Interests 2

  1. Polymer Synthesis

  2. Polymer Science

Research Areas 2

  1. Nanotechnology/Materials / Polymer chemistry

  2. Nanotechnology/Materials / Polymer materials

Current Research Project and SDGs 3

  1. 精密重合反応の開発と高分子の精密合成

  2. 分解性高分子材料の開発

  3. 新規リビング重合、立体特異性重合の開発

Education 3

  1. Nagoya University   Graduate School, Division of Engineering

    2013.4 - 2016.3

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    Country: Japan

  2. Nagoya University   Graduate School, Division of Engineering

    2011.4 - 2013.3

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    Country: Japan

  3. Nagoya University   Faculty of Engineering

    2007.4 - 2011.3

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    Country: Japan

Professional Memberships 3

  1. 高分子学会

  2. 日本化学会

  3. アメリカ化学会

Committee Memberships 3

  1. 東海高分子研究会 夏期合宿   幹事  

    2019.8   

  2. 東海高分子研究会   6月講演会 幹事  

    2018.6   

  3. 東海高分子研究会   12月講演会幹事  

    2017.12   

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    Committee type:Academic society

Awards 1

  1. GSCポスター賞

    2017.7   公益社団法人新化学技術推進協会 グリーン・サステイナブルケミストリーネットワーク会議   可逆的連鎖移動機構によるメタルフリーのリビングカチオン重合系の開発

    内山峰人

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

 

Papers 26

  1. Stereospecific cationic RAFT polymerization of bulky vinyl ethers and stereoblock poly(vinyl alcohol) via mechanistic transformation to radical RAFT polymerization of vinyl acetate Reviewed

    M. Uchiyama, K. Satoh, M. Kamigaito

    Giant   Vol. 5   page: 100047   2021.1

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.giant.2021.100047

  2. ポリマーの立体構造制御で物性アップ—キラル触媒を用いた立体選択重合・立体特異性重合

    内山峰人, 上垣外正己

    化学   Vol. 75 ( (11) ) page: 70-71.   2020.10

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    Language:Japanese  

  3. Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymersviaa RAFT/ROCOP strategy Reviewed

    T. M. McGuire, M. Miyajima, M. Uchiyama, A. Buchard, and M. Kamigaito

    POLYMER CHEMISTRY   Vol. 11 ( 36 ) page: 5844-5850   2020.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0py00878h

    Web of Science

  4. Thiol-Ene Cationic and Radical Reactions: Cyclization, Step-Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units Reviewed

    Uchiyama Mineto, Osumi Masahiro, Satoh Kotaro, Kamigaito Masami

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 59 ( 17 ) page: 6832-6838   2020.4

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201915132

    Web of Science

  5. Interconvertible and switchable cationic/PET-RAFT copolymerization triggered by visible light

    Satoh Kotaro, Sun Zhihong, Uchiyama Mineto, Kamigaito Masami, Xu Jiangtao, Boyer Cyrille

    POLYMER JOURNAL   Vol. 52 ( 1 ) page: 65-73   2020.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41428-019-0257-5

    Web of Science

  6. 可逆的連鎖移動機構に基づくリビングカチオン重合による精密高分子合

    内山峰人, 佐藤浩太郎, 上垣外正己

    材料の科学と工学   Vol. 56 ( 4 ) page: 14-17   2019.8

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

  7. Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts

    Konya Masato, Uchiyama Mineto, Satoh Kotaro, Kamigaito Masami

    CHEMPHOTOCHEM     2019.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cptc.201900148

    Web of Science

  8. Cooperative reduction of various RAFT polymer terminals using hydrosilane and thiol via polarity reversal catalysis

    Uchiyama Mineto, Satoh Kotaro, Kamigaito Masami

    CHEMICAL COMMUNICATIONS   Vol. 55 ( 37 ) page: 5327-5330   2019.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cc00900k

    Web of Science

  9. A User-friendly Living Cationic Polymerization: Degenerative Chaintransfer Polymerization of Vinyl Ethers by Simply Using Mixtures of Weak and Superstrong Protonic Acids Reviewed

    M. Uchiyama, M. Sakaguchi, K. Satoh, and M. Kamigaito,

    Chinese J. Polym. Sci.     page: in press.   2019.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s10118-019-2233-0

  10. Degenerative chain-transfer process: Controlling all chain-growth polymerizations and enabling novel monomer sequences

    M. Kamigaito, K. Satoh, and M. Uchiyama

    J. Polym. Sci., Part A, Polym. Chem.   Vol. 57 ( 3 ) page: 243-254   2019.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/pola.29257

    Web of Science

  11. Valencene as a Naturally Occurring Sesquiterpene Monomer for Radical Copolymerization with Meimide to Induce Concurrent 1:1 and 1:2 Propagation Reviewed

    H. Hashimoto, H. Takeshima, T. Nagai, M. Uchiyama, K. Satoh, and M. Kamigaito

    Polym. Degrad. Stab.   Vol. 161   page: 183-190   2019.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.polymdegradstab.2019.01.025

  12. Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical Interconvertible Simultaneous Polymerization

    K. Satoh, Y. Fujiki, M. Uchiyama, and M. Kamigaito

    ACS Symp. Ser.   ( 1284 ) page: 323-334   2018.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/bk-2018-1284.ch015

  13. Synthesis of PEVE-b-P(CTFE-alt-EVE) block copolymers by sequential cationic and radical RAFT polymerization

    M. Guerre, M. Uchiyama, G. Lopez, B. Améduri, K. Satoh, M. Kamigaito, and V. Ladmiral

    Polym. Chem.   Vol. 9 ( 3 ) page: 352-361   2018.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7py01924f

    Web of Science

  14. 交換連鎖移動機構に基づく精密重合 Reviewed

    上垣外正己、佐藤浩太郎、内山峰人

    高分子   Vol. 67 ( 1 ) page: 30-33   2018.1

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

  15. Diverse approaches to star polymers via cationic and radical RAFT cross-linking reactions using mechanistic transformation

    Uchiyama Mineto, Satoh Kotaro, McKenzie Thomas G., Fu Qiang, Qiao Greg. G., Kamigaito Masami

    POLYMER CHEMISTRY   Vol. 8 ( 38 ) page: 5972-5981   2017.10

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7py01401e

    Web of Science

  16. One-shot controlled/living copolymerization for various comonomer sequence distributions via dual radical and cationic active species from RAFT terminals

    K. Satoh, H. Hashimoto, S. Kumagai, H. Aoshima, M. Uchiyama. R. Ishibashi, Y. Fujiki, and M. Kamigaito,

    Polym. Chem.   Vol. 8 ( 34 ) page: 5002-5011   2017.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7py00324b

    Web of Science

  17. Metal-Free Living Cationic Polymerization via Degenerative Chain-Transfer Mechanism Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito,

    Journal of The Adhesion Society of Japan   Vol. 53 ( 5 ) page: 179-187   2017.5

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.11618/adhesion.53.179

  18. Combination of Cationic and Radical RAFT Polymerizations: A Versatile Route to Well-Defined Poly(ethyl vinyl ether)-block-poly(vinylidene fluoride) Block Copolymers

    Guerre Marc, Uchiyama Mineto, Folgado Enrique, Semsarilar Mona, Ameduri Bruno, Satoh Kotaro, Kamigaito Masami, Ladmiral Vincent

    ACS MACRO LETTERS   Vol. 6 ( 4 ) page: 393-398   2017.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsmacrolett.7b00150

    Web of Science

  19. Diversifying Cationic RAFT Polymerization with Various Counteranions: Generation of Cationic Species from Organic Halides and Various Metal Salts Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito

    ACS Macro Lett.   Vol. 5   page: 1157-1161   2016.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsmacrolett.6b00541

  20. Beyond Traditional RAFT: Alternative Activation of Thiocarbonylthio Compounds for Controlled Polymerization Reviewed

    T. G. McKenzie, Q. Fu, M. Uchiyama, K. Satoh, J. Xu, C. Boyer, M. Kamigaito, and G. G. Qiao

    Adv. Sci   Vol. 3   page: 1500394   2016.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/advs.201500394

  21. Phosphonium Intermediate for Cationic RAFT Polymerization Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito

    Polym. Chem.   ( 7 ) page: 1387-1396   2015.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5py01879j

  22. Thioether-Mediated Degenerative Chain-Transfer Cationic Polymerization: A Simple Metal-Free System for Living Cationic Polymerization Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito

    Macromolecules   Vol. 48   page: 5533-5542   2015.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.macromol.5b01341

  23. Metal-Free Living Cationic Polymerization via Carbon-Sulfur Bonds (2) Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito,

    NIPPON GOMU KYOKAISHI   Vol. 88   page: 461–465   2015

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.2324/gomu.88.461

  24. Metal-Free Living Cationic Polymerization via Carbon-Sulfur Bonds (1) Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito,

    NIPPON GOMU KYOKAISHI   Vol. 88   page: 391–396   2015

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.2324/gomu.88.391

  25. Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid Reviewed

    M. Uchiyama, K. Satoh, and M. Kamigaito

    Angew. Chem. Int. Ed.   Vol. 54   page: 1924-1928   2014.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201410858

  26. Interconvertible Living Radical and Cationic Polymerization through Reversible Activation of Dormant Species with Dual Activity Reviewed

    H. Aoshima, M. Uchiyama, K. Satoh, and M. Kamigaito

    Angew. Chem. Int. Ed.   Vol. 53   page: 10932-10936   2014.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201406590

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Books 1

  1. RAFT機構によるリビングカチオン重合 リビングラジカル重合―機能性高分子の合成と応用展開―, 松本章一 監修 , シーエムシー出版

    内山峰人( Role: Sole author)

    シーエムシー出版  2018 

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    Language:Japanese

Presentations 14

  1. チオアセタールへの可逆的連鎖移動に基づくメタルフリーカチオン重合を用いた周期構造制御

    内山峰人, 村上幸大, 大角昌弘, 佐藤浩太郎, 上垣外正己

    第69回高分子討論会  2020.9.17 

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    Event date: 2020.9

  2. カチオン重合における交換連鎖移動機構を生かした精密高分子設計

    内山峰人・坂口将隆・渡辺大智・佐藤浩太郎・上垣外正己

    第68回高分子討論会 

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    Event date: 2019.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  3. Metal-free living cationic polymerization based on degenerative chain-transfer mechanism Invited International conference

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    ACS Fall 2019 National Meeting & Exposition  

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    Event date: 2019.8

    Language:English   Presentation type:Oral presentation (general)  

    Country:United States  

  4. Simultaneous Control of Molecular Weights and Stereo-Structures Using Cationic RAFT Polymerization

    Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito

    The 12th SPSJ International Polymer Conference (IPC2018) 

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    Event date: 2018.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  5. メタルフリーカチオンRAFT重合を用いた分子量と立 体構造の同時制御

    内山 峰人・佐藤 浩太郎・上垣外 正己

    高分子学会討論会 

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    Event date: 2018.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  6. Development of New Living Cationic Polymerization via Reversible Chain-Transfer Mechansim Invited International conference

    The 2nd International Meeting of M&M SYNTECH Unit, Dec 17, 2016 

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    Event date: 2017.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  7. メタルフリーカチオンRAFT重合に基づく多重構造制御されたポリマーの設計

    内山峰人、佐藤浩太郎、上垣外正己

    第66回高分子討論会 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:愛媛大学   Country:Japan  

  8. Metal-Free Cooperative Hydrogenation of RAFT Chain End Using Hydrosilane and Thiol International conference

    M. Uchiyama, K. Satoh, H. Ida, and M. Kamigaito

    254nd American Chemical Society National Meeting and Exposition 

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    Event date: 2017.8

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  9. 可逆的連鎖移動機構によるメタルフリーのリビングカチオン重合系の開発

    内山峰人 、佐藤浩太郎、 上垣外 正己

    第6回JACI/GSCシンポジウム 

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    Event date: 2017.7

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  10. Novel Living Cationic Polymerization via Reversible Chain-Transfer Mechanism

    M. Uchiyama, K. Satoh, and M. Kamigaito

    The 11th SPSJ International Polymer Conference 

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    Event date: 2016.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  11. シラン化合物とチオールを用いたRAFT末端の水素化

    内山峰人, 佐藤浩太郎, 上垣外正己、井田大嗣

    第25回ポリマー材料フォーラム 

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    Event date: 2016.11

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  12. 可逆的連鎖移動機構によるメタルフリーリビングカチオン重合

    内山峰人, 佐藤浩太郎, 上垣外正己

    第65回高分子学会討論会 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  13. Novel Living Cationic Polymerization via Reversible Chain-Transfer Mechanism International conference

    M. Uchiyama, K. Satoh, and M. Kamigaito

    252nd American Chemical Society National Meeting and Exposition 

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    Event date: 2016.8

    Language:English   Presentation type:Poster presentation  

    Venue:Philadelphia, PA, USA   Country:United States  

  14. カチオンおよびラジカルRAFT重合を用いた星型ポリマーの合成

    内山峰人, 佐藤浩太郎, 上垣外正己

    第65回高分子学会年次大会 

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    Event date: 2016.5

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

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Research Project for Joint Research, Competitive Funding, etc. 6

  1. 可逆的連鎖移動に基づくリビングカチオン重合を鍵とする光学活性高分子の精密合成

    2020.4 - 2022.3

    公益財団法人 旭硝子財団  研究助成 

    内山峰人

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\2000000

  2. 主鎖に硫黄を含む新規分解性高分子材料の開発

    2020.4 - 2021.3

    研究助成 

    内山峰人

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000

  3. 可逆的的連鎖移動に基づくリビングカチオン重合による主鎖に周期的に分解性ユニットを有するビニルポリマーの合成

    2020.4 - 2021.3

    研究助成 

    内山 峰人

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\1000000

  4. 可逆的連鎖移動機構に基づくメタルフリーリビングカチオン重合

    2019.8

    海外調査研究助成 

    内山峰人

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    Grant type:Competitive

  5. 可逆的連鎖移動機構に基づくメタルフリーリビングカチオン重合系の開発

    2019.8

    国際交流援助 

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    Grant type:Competitive

  6. 分解性を有する新規含硫黄高分子材料の開発

    2019

    研究助成 

    内山峰人

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\300000

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KAKENHI (Grants-in-Aid for Scientific Research) 4

  1. Development of Novel Precision Polymerization Systems by Reversible Activation of C-H Bond

    Grant number:20K15332  2020.4 - 2022.3

    Grant-in-Aid for Early-Career Scientists

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4160000 ( Direct Cost: \3200000 、 Indirect Cost:\960000 )

  2. Innovative precision polymerization via photo-induced multi active species

    Grant number:18KK0158  2018.10 - 2022.3

    Fund for the Promotion of Joint International Research (Fostering Joint International Research (B))

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    Authorship:Coinvestigator(s) 

  3. Precision Synthesis of Polymers with Special Architectures by Reversible Activation of C-S Bonds

    Grant number:18K14274  2018.4 - 2020.3

    Grant-in-Aid for Early-Career Scientists

    Mineto Uchiyama

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    Authorship:Principal investigator 

    Grant amount:\4160000 ( Direct Cost: \3200000 、 Indirect Cost:\960000 )

    This study was directed to the precision synthesis of polymers with special architectures by reversible activation and formation of C-S bonds. The cationic and radical step-growth polymerizations of divinyl ethers and dithiols were achieved using organic acids and radical catalysts respectively, which were based on the selective formation of thioacetal and thioether bonds. In addition, the various polymers with controlled periodic structures were synthesized by the combination of step-growth or ring-opening polymerization with cationic degenerative chain-transfer (DT) polymerization using C-S bonds as dormant species. Furthermore, DT cationic polymerization was used in asymmetric cationic polymerization to attain the dual control of molecular weight and enantioselectivity.

  4. Design of Multiple Controlled Polymers Based on Reversible Chain Transfer Cationic Polymerization

    Grant number:16H06863  2016.8 - 2018.3

    UCHIYAMA Mineto

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    Authorship:Principal investigator 

    Grant amount:\2990000 ( Direct Cost: \2300000 、 Indirect Cost:\690000 )

    This study was directed to the control of multiple precise structures based on cationic polymerization via reversible chain transfer mechanism. The reversible chain transfer cationic polymerization was combined with stereospecific cationic polymerization to achieve stereospecific living cationic polymerization, in which both molecular weight and stereoregularity were controlled simultaneously. The control of molecular weight based on reversible chain transfer reaction was also efficient for asymmetric cationic polymerization of benzofuran. In addition, the synthesis of star polymer via cross-linking reactions was achieved by combination cationic and radical RAFT polymerization.

Industrial property rights 1

  1. ビニルエステルとビニルエーテルの共重合体、およびその製造方法

    上垣外正己, 佐藤浩太郎, 内山峰人, 井田大嗣

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    Applicant:国立大学法人名古屋大学、株式会社クラレ

    Application no:特願2012-110600  Date applied:2012.5

    Announcement no:特開2013-237748  Date announced:2013.11

    Country of applicant:Domestic  

 

Teaching Experience (On-campus) 29

  1. Chemistry and Biotechnology Laboratory 4

    2020

  2. Organic Chemistry 2 with Exercises

    2020

  3. Chemistry and Biotechnology Laboratory 4

    2020

  4. 有機・高分子化学基礎論

    2020

  5. 化学生命工学実験2

    2020

  6. 化学生命工学演習2

    2020

  7. 化学生命工学演習1

    2020

  8. 卒業研究B

    2020

  9. 卒業研究A

    2020

  10. 高分子化学特別実験及び演習Ⅱ

    2020

  11. 高分子化学特別実験及び演習Ⅰ

    2020

  12. 高分子化学セミナー1D

    2020

  13. 高分子化学セミナー1C

    2020

  14. 高分子化学セミナー1B

    2020

  15. 高分子化学セミナー1A

    2020

  16. 化学生命工学実験4

    2019

  17. 化学生命工学実験2

    2019

  18. 有機化学2及び演習

    2019

  19. 有機化学演習第2

    2018

  20. 有機化学実験第2

    2018

  21. 有機化学実験第1

    2018

  22. 有機化学2および演習

    2018

  23. 有機化学演習第1

    2017

  24. 有機化学実験第1

    2017

  25. 有機化学2および演習

    2017

  26. 有機化学実験第2

    2017

  27. 有機化学演習第2

    2016

  28. 有機化学実験第2

    2016

  29. 有機化学実験第1

    2016

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Social Contribution 1

  1. 平成28年度名古屋大学オープンキャンパス

    2016.8

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    Audience: High school students

    Type:University open house