Faculty Profiles - SHINOKUBO, Hiroshi

Papers - SHINOKUBO, Hiroshi

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Acid-Mediated Migration of Bromide in an Antiaromatic Porphyrinoid: Preparation of Two Regioisomeric Ni(II) Bromonorcorroles Reviewed

Kawashima Hiroyuki, Hiroto Satoru, Shinokubo Hiroshi

JOURNAL OF ORGANIC CHEMISTRY Vol. 82 ( 19 ) page： 10425 - 10432 2017.10

Shaping Antiaromatic -Systems by Metalation: Synthesis of a Bowl-Shaped Antiaromatic Palladium Norcorrole Reviewed

Yonezawa Tsubasa, Shafie Siham A., Hiroto Satoru, Shinokubo Hiroshi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 56 ( 39 ) page： 11822 - 11825 2017.9

Synthesis and Properties of meso-Arylated Corrphycenes. Reviewed

Nozawa R, Shinokubo H

Organic letters Vol. 19 ( 18 ) page： 4928 - 4931 2017.9

Design and Synthesis of Tunable Ligands with 4,4'-Bipyridyl as an Electron-Accepting Unit and Their Rhenium Complexes Reviewed

Kamatsuka Takuto, Shinokubo Hiroshi, Miyake Yoshihiro

ORGANOMETALLICS Vol. 36 ( 17 ) page： 3429 - 3434 2017.9

A synthesis of novel expanded porphyrinoids: Ni-II-induced nitrile cyclization of dicyanovinylene-bis (meso-aryl)dipyrrin Reviewed

Faialaga Nathan H., Ito Satoru, Shinokubo Hiroshi, Kim Younghoon, Kim Kimoon, Shin Ji-Young

DALTON TRANSACTIONS Vol. 46 ( 33 ) page： 10802 - 10808 2017.9

pi-Extended Dihydrophenazines with Three-State NIR Electrochromism Involving Large Conformational Changes Reviewed

Nagasaki Juri, Hiroto Satoru, Shinokubo Hiroshi

CHEMISTRY-AN ASIAN JOURNAL Vol. 12 ( 17 ) page： 2311 - 2317 2017.9

Direct amination of the antiaromatic Ni-II norcorrole Reviewed

Yoshida Takuya, Shinokubo Hiroshi

MATERIALS CHEMISTRY FRONTIERS Vol. 1 ( 9 ) page： 1853 - 1857 2017.9

Selective alpha-arylation of alpha,beta-unsaturated imides mediated by a visible light photoredox catalyst

Ando Yuki, Kamatsuka Takuto, Shinokubo Hiroshi, Miyake Yoshihiro

CHEMICAL COMMUNICATIONS Vol. 53 ( 65 ) page： 9136-9138 2017.8

Highly-conducting molecular circuits based on antiaromaticity Reviewed

Fujii Shintaro, Marques-Gonzalez Santiago, Shin Ji-Young, Shinokubo Hiroshi, Masuda Takuya, Nishino Tomoaki, Arasu Narendra P., Vazquez Hector, Kiguchi Manabu

NATURE COMMUNICATIONS Vol. 8 2017.7

Synthesis, Properties, and Reactivities of Ruthenium(II) Carbonyl 5,15-Diazaporphyrins Reviewed

Nishimura Tsubasa, Miyake Yoshihiro, Shinokubo Hiroshi

CHEMISTRY LETTERS Vol. 46 ( 7 ) page： 995 - 997 2017.7

NIR mechanochromic behaviours of a tetracyanoethylene-bridged hexa-peri-hexabenzocoronene dimer and trimer through dissociation of C-C bonds Reviewed

Oda Kazuma, Hiroto Satoru, Shinokubo Hiroshi

JOURNAL OF MATERIALS CHEMISTRY C Vol. 5 ( 22 ) page： 5310 - 5315 2017.6

NIR mechanochromic behaviours of a tetracyanoethylene-bridged hexa-peri-hexabenzocoronene dimer and trimer through dissociation of C–C bonds Reviewed International journal

Oda Kazuma, Hiroto Satoru, Shinokubo Hiroshi

Journal of Materials Chemistry C Vol. 5 ( 22 ) page： 5310 - 5315 2017.6

Authorship：Corresponding author Language：English Publishing type：Research paper (scientific journal)

Oxidation of dicyanomethyl-substituted hexa-peri-hexabenzocoronenes (HBCs) furnished a tetracyanoethylene-bridged HBC dimer and trimer. The solid state structures of the oligomers were elucidated using single crystal X-ray diffraction analysis. In the solution state, these HBC oligomers exhibited conformational isomerism, depending on solvents and temperatures. Moreover, solid samples of the HBC dimer and trimer exhibited mechanochromism, showing near IR absorption upon grinding through generation of radical species. The formed radical was stable for 4 months, indicating the persistent nature of the radical species. These NIR mechanochromic behaviours of the HBC oligomers were originated from the reversible C–C bond dissociation and formation of a tetracyanoethylene linkage between the HBC units.

CiNii Research

10-Silacorroles Exhibiting Near-Infrared Absorption and Emission

Omori Hiroto, Hiroto Satoru, Shinokubo Hiroshi

CHEMISTRY-A EUROPEAN JOURNAL Vol. 23 ( 33 ) page： 7866-7870 2017.6

10-Silacorroles Exhibiting NIR Absorption and Emission Reviewed International journal

Omori Hiroto, Hiroto Satoru, Shinokubo Hiroshi

CHEMISTRY-A EUROPEAN JOURNAL Vol. 22 ( 33 ) page： 7866 - 7870 2017.6

Authorship：Corresponding author Language：English Publishing type：Research paper (scientific journal)

10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(α,α′-dibromodipyrrin) Ni^II precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and Zn^II 10-silacorroles exhibit emissions in the NIR region. Theoretical calculations on these 10-silacorroles revealed the presence of σ*–π* conjugation between the silyl group and the tetrapyrrole π system, which significantly lowers their LUMO energy levels.

DOI： 10.1002/chem.201783363

CiNii Research

Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds Reviewed

Serizawa Yuma, Akahori Shuhei, Kato Shohei, Sakai Hayato, Hasobe Taku, Miyake Yoshihiro, Shinokubo Hiroshi

CHEMISTRY-A EUROPEAN JOURNAL Vol. 23 ( 29 ) page： 6948 - 6952 2017.5

Synthesis of Tetraaza[8]circulenes from Tetrathia[8]circulenes through an SNAr-Based Process Reviewed

Nagata Yuya, Kato Shohei, Miyake Yoshihiro, Shinokubo Hiroshi

ORGANIC LETTERS Vol. 19 ( 10 ) page： 2718 - 2721 2017.5

Synthesis of a figure-eight azahelicene dimer with high emission and CPL properties

Ushiyama Ayako, Hiroto Satoru, Yuasa Junpei, Kawai Tsuyoshi, Shinokubo Hiroshi

ORGANIC CHEMISTRY FRONTIERS Vol. 4 ( 5 ) page： 664-667 2017.5

Synthesis and Functionalization of Porphyrins through Organometallic Methodologies Invited Reviewed

Hiroto Satoru, Miyake Yoshihiro, Shinokubo Hiroshi

CHEMICAL REVIEWS Vol. 117 ( 4 ) page： 2910 - 3043 2017.2

Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers Reviewed

Oda Kazuma, Hiroto Satoru, Hisaki Ichiro, Shinokubo Hiroshi

ORGANIC & BIOMOLECULAR CHEMISTRY Vol. 15 ( 6 ) page： 1426 - 1434 2017.2

Enhancing the low-energy absorption band and charge mobility of antiaromatic Ni-II norcorroles by their substituent effects Reviewed

Yoshida Takuya, Sakamaki Daisuke, Seki Shu, Shinokubo Hiroshi

CHEMICAL COMMUNICATIONS Vol. 53 ( 6 ) page： 1112 - 1115 2017.1

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Papers - SHINOKUBO, Hiroshi