Faculty Profiles - SHINOKUBO, Hiroshi

Papers - SHINOKUBO, Hiroshi

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Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material

Shin Ji-Young, Zhang Zhongyue, Awaga Kunio, Shinokubo Hiroshi

MOLECULES Vol. 24 ( 13 ) 2019.7

Synthesis of meso-Alkyl-Substituted Norcorrole-Ni-II Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)

Liu Si-Yu, Tanaka Hiroko, Nozawa Ryo, Fukui Norihito, Shinokubo Hiroshi

CHEMISTRY-A EUROPEAN JOURNAL Vol. 25 ( 32 ) page： 7618 - 7622 2019.6

Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins

Takiguchi Asahi, Fukui Norihito, Shinokubo Hiroshi

ORGANIC LETTERS Vol. 21 ( 11 ) page： 3950 - 3953 2019.6

Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

Shafie Siham A., Kawashima Hiroyuki, Miyake Yoshihiro, Shinokubo Hiroshi

CHEMPLUSCHEM Vol. 84 ( 6 ) page： 623 - 626 2019.6

Synthesis of Dihydropyrazine-fused Porphyrin Dimers

Takiguchi Asahi, Wakita Mana, Hiroto Satoru, Shinokubo Hiroshi

CHEMISTRY LETTERS Vol. 48 ( 4 ) page： 371 - 373 2019.4

Ni(II) 10-Phosphacorrole: A Porphyrin Analogue Containing Phosphorus at the Meso Position

Omori Hiroto, Hiroto Satoru, Takeda Youhei, Fliegl Heike, Minakata Satoshi, Shinokubo Hiroshi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Vol. 141 ( 12 ) page： 4800 - 4805 2019.3

Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy. Reviewed

Longevial Jean-Francois, Yamaji Ayaka, Aggad Dina, Kim Gakhyun, Chia Wen Xi, Nishimura Tsubasa, Miyake Yoshihiro, Clement Sebastien, Oh Juwon, Daurat Morgane, Nguyen Christophe, Kim Dongho, Gary-Bobo Magali, Richeter Sebastien, Shinokubo Hiroshi

Chemical communications (Cambridge, England) Vol. 54 ( 98 ) page： 13829 - 13832 2018.12

Theoretical Study on Open-Shell Singlet Character and Second Hyperpolarizabilities in Cofacial π-Stacked Dimers Composed of Weak Open-Shell Antiaromatic Porphyrins Reviewed

Fujiyoshi Jun-ya, Tonami Takayoshi, Yamane Masaki, Okada Kenji, Kishi Ryohei, Muhammad Shabbir, Al-Sehemi Abdullah G, Nozawa Ryo, Shinokubo Hiroshi, Nakano Masayoshi

ChemPhysChem Vol. 19 ( 21 ) page： 2863 - 2871 2018.11

X-Shaped Cyclobutane-Linked Tetraporphyrins through a Thermal [2+2] Cycloaddition of Etheno-Fused Diporphyrins Reviewed

Nagai Tomohiro, Takiguchi Asahi, Ueda Masayuki, Oda Kazuma, Hiroto Satoru, Shinokubo Hiroshi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Vol. 140 ( 27 ) page： 8392-8395 2018.7

Azabuckybowl-Based Molecular Tweezers as C-60 and C-70 Receptors Reviewed

Takeda Motoki, Hiroto Satoru, Yokoi Hiroki, Lee Sangsu, Kim Dongho, Shinokubo Hiroshi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Vol. 140 ( 20 ) page： 6336-6342 2018.5

The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes Reviewed

Nakazato Takumi, Kamatsuka Takuto, Inoue Junichi, Sakurai Tsuneaki, Seki Shu, Shinokubo Hiroshi, Miyake Yoshihiro

CHEMICAL COMMUNICATIONS Vol. 54 ( 41 ) page： 5177-5180 2018.5

Reversible sigma-Bond Formation in Bowl-Shaped pi-Radical Cations: The Effects of Curved and Planar Structures Reviewed

Yokoi Hiroki, Hiroto Satoru, Shinokubo Hiroshi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Vol. 140 ( 13 ) page： 4649-4655 2018.4

Figuration of bowl-shaped pi-conjugated molecules: properties and functions Invited Reviewed

Saito Masaichi, Shinokubo Hiroshi, Sakurai Hidehiro

MATERIALS CHEMISTRY FRONTIERS Vol. 2 ( 4 ) page： 635 - 661 2018.4

Benzonorcorrole Ni-II Complexes: Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion Reviewed

Yoshida Takuya, Takahashi Kohtaro, Ide Yuki, Kishi Ryohei, Fujiyoshi Jun-ya, Lee Sangsu, Hiraoka Yuya, Kim Dongho, Nakano Masayoshi, Ikeue Takahisa, Yamada Hiroko, Shinokubo Hiroshi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 57 ( 8 ) page： 2209-2213 2018.2

Supramolecular assemblies of a nitrogen-embedded buckybowl dimer with C-60 Reviewed

Yokoi Hiroki, Hiroto Satoru, Sakamaki Daisuke, Seki Shu, Shinokubo Hiroshi

CHEMICAL SCIENCE Vol. 9 ( 4 ) page： 819-824 2018.1

Synthesis and Photodynamics of Tetragermatetrathia[8]circulene Reviewed

Akahori Shuhei, Sakai Hayato, Hasobe Taku, Shinokubo Hiroshi, Miyake Yoshihiro

ORGANIC LETTERS Vol. 20 ( 1 ) page： 304-307 2018.1

Nickel (II) pyrrocorphin: Enhanced binding ability in a highly reduced porphyrin complex. Reviewed

Ide Y, Kuwahara T, Takeshita S, Fujishiro R, Suzuki M, Mori S, Shinokubo H, Nakamura M, Yoshino K, Ikeue T

Journal of inorganic biochemistry Vol. 178 page： 115 - 124 2018.1

Synthesis of Heteroatom-Containing Curved pi-Conjugated Molecules Reviewed

Hiroto Satoru, Shinokubo Hiroshi

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN Vol. 76 ( 1 ) page： 37-44 2018.1

Synthesis of Heteroatom-Containing Curved pi-Conjugated Molecules Reviewed International journal

Hiroto, Satoru, Shinokubo, Hiroshi

Journal of Synthetic Organic Chemistry Japan Vol. 76 ( 1 ) page： 37 - 44 2018

Authorship：Last author,　Corresponding author Language：Japanese Publishing type：Research paper (scientific journal) Publisher：The Society of Synthetic Organic Chemistry, Japan

<p>Recently, π-conjugated molecules with curved-π surface have attracted considerable interest for their unique properties originating from their curved structures. However, most of them consist of only carbon and hydrogen atoms. In these situations, we have developed novel synthetic protocols for construction of distorted structures directly from 2D π-conjugated molecules under mild reaction conditions. By applying phenol and aniline oxidation methods, we have succeeded in the synthesis of highly distorted cyclophanes, π-extended heterohelicenes, and highly twisted porphyrin oligomers. Furthermore, we have succeeded in the synthesis of a nitrogen-embedded buckybowl as a novel bowl-shaped π-conjugated molecule with a pyrrolic nitrogen in its skeleton. These heteroatom containing curved-π conjugated molecules exhibit unique characteristics due to the combination of the curved structure with heteroatoms such as circularly polarized luminescence, strong C<sub>60</sub> binding, and near IR electrochromism. We believe that the chemistry of heteroatom containing curved-π conjugated molecules would enhance the potential of three-dimensional π-conjugated molecules for molecular materials.</p>

DOI： 10.5059/YUKIGOSEIKYOKAISHI.76.37

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Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group. Reviewed

Uehara H, Shisaka Y, Nishimura T, Sugimoto H, Shiro Y, Miyake Y, Shinokubo H, Watanabe Y, Shoji O

Angewandte Chemie (International ed. in English) Vol. 56 ( 48 ) page： 15279 - 15283 2017.11

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Papers - SHINOKUBO, Hiroshi