Updated on 2022/03/24

写真a

 
SHINOKUBO, Hiroshi
 
Organization
Graduate School of Engineering Molecular and Macromolecular Chemistry 1 Professor
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Chemistry and Biotechnology
Title
Professor
Contact information
メールアドレス

Degree 1

  1. 博士(工学) ( 1998.3   京都大学 ) 

Research Interests 2

  1. antiaromatic molecule

  2. pi-conjugated molecule

Research Areas 3

  1. Others / Others  / Organic Chemistry

  2. Others / Others  / Synthetic Chemistry

  3. Others / Others  / Functional Material Chemistry

Current Research Project and SDGs 3

  1. 遷移金属触媒反応を活用した新規機能性分子の創製

  2. π共役系有機分子の効率的変換反応の開発と応用

  3. 機能性有機金属錯体の合成と物性探求

Research History 7

  1. Nagoya University   Professor

    2017.4

  2. Nagoya University   Professor

    2008.9 - 2017.3

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    Country:Japan

  3. 京都大学大学院理学研究科化学専攻   准教授

    2007.4 - 2008.8

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    Country:Japan

  4. 京都大学大学院理学研究科化学専攻助教授

    2003.10 - 2007.3

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    Country:Japan

  5. 独立行政法人科学技術振興機構戦略的創造研究さきがけ研究21研究者

    2003.10 - 2007.3

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    Country:Japan

  6. 文部省在外研究員(米国マサチューセッツ工科大学客員研究員)

    1999.9 - 2000.8

  7. 京都大学大学院工学研究科材料化学専攻助手

    1995.10 - 2003.10

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    Country:Japan

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Education 3

  1. Kyoto University   Graduate School, Division of Engineering

    1994.4 - 1995.10

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    Country: Japan

  2. Kyoto University   Graduate School, Division of Engineering

    1992.4 - 1994.3

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    Country: Japan

  3. Kyoto University   Faculty of Engineering

    1988.4 - 1992.3

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    Country: Japan

Professional Memberships 11

  1. 東海化学工業会   幹事

    2019.4

  2. 基礎有機化学会   理事

    2019.3

  3. 有機合成化学協会東海支部   幹事

    2014.4 - 2020.3

  4. 日本化学会東海支部   庶務幹事

    2013.4 - 2014.3

  5. 日本化学会東海支部   幹事

    2010.4 - 2013.3

  6. The Chemical Society of Japan

    2008.4 - 2011.3

  7. American Chemical Society

  8. 有機合成化学協会

  9. 近畿化学協会

  10. Society of Porphyrins and Phthalocyanines

  11. Society of Porphyrins and Phthalocyanines

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Committee Memberships 1

  1. 分子科学研究   分子科学研究所運営会議委員  

    2020.4   

Awards 13

  1. Ambassadeurs INC

    2019.9   Centre national de la recherche scientifique (CNRS)  

    Hiroshi Shinokubo

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    Award type:International academic award (Japan or overseas)  Country:France

  2. Les Ambassadeurs de l'INC

    2019.9   Centre national de la recherche scientifique (CNRS)  

    SHINOKUBO, Hiroshi

  3. 矢崎学術賞

    2018.3   矢崎科学技術振興記念財団  

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    Award type:International academic award (Japan or overseas)  Country:Japan

  4. 井上学術賞

    2018.2   井上科学振興財団  

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    Award type:International academic award (Japan or overseas)  Country:Japan

  5. 有機合成化学協会機能性材料賞

    2013.2   有機合成化学協会  

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    Country:Japan

  6. 日本学術振興会賞

    2012.2   日本学術振興会  

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    Country:Japan

  7. 科学技術分野の文部科学大臣表彰 若手科学者賞

    2009.4   文部科学省  

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    Country:Japan

  8. Banyu Young Chemist Award 2008

    2008.11  

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    Country:Japan

  9. 日本化学会進歩賞

    2004.3   日本化学会  

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    Country:Japan

  10. 日本化学会 化学と工業誌「化学のフロンティア」

    2002.4   日本化学会  

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    Country:Japan

  11. 日本化学会「若い世代の特別講演」

    2001.9   日本化学会  

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    Country:Japan

  12. Bulletin of the Chemical Society of Japan賞

    2001.9   日本化学会  

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    Country:Japan

  13. 有機合成化学協会研究企画賞(萬有製薬)

    1999.2   有機合成化学協会  

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    Country:Japan

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Papers 341

  1. Diverse Crystal Structures of Ion Pairs Consisting of Oxaporphyrinium Cations and Pentacyanocyclopentadienide Reviewed

    Asahi Takiguchi, Hiroki Tanaka, Hiromitsu Maeda, Hiroshi Shinokubo

    Bulletin of the Chemical Society of Japan   Vol. 95   2022.3

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/bcsj.20220026

  2. A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa Reviewed International journal

    Takiguchi Asahi, Sakakibara Erika, Sugimoto Hiroshi, Shoji Osami, Shinokubo Hiroshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 61 ( 7 ) page: e202112456   2022.2

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.202112456

    Web of Science

  3. Isolation and Structure Analysis of a Ni(II) Norcorrole Radical Anion Reviewed International journal

    Ukai Shusaku, Fukui Norihito, Ikeue Takahisa, Shinokubo Hiroshi

    Chemistry Letters   Vol. 51 ( 2 ) page: 182 - 184   2022.2

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    <p>A radical anion of Ni(II) <i>meso</i>-dimesitylnorcorrole was prepared and isolated upon chemical reduction of the corresponding neutral species with cobaltocene (Co<sup>II</sup>Cp<sub>2</sub>). The radical anion was substantially stable under degassed solution conditions. X-ray crystal analysis of the radical anion revealed that the structural change by one-electron reduction is marginal. DFT calculations demonstrated that the reorganization energy of Ni(II) norcorrole upon one-electron reduction is smaller than those of Zn(II) porphyrin and C<sub>60</sub> fullerenes.</p>

    DOI: 10.1246/cl.210715

    CiNii Research

  4. Indeno[1,2,3,4‐ pqra ]Perylene: A Medium‐Sized Aromatic Hydrocarbon Exhibiting Full‐Range Visible‐Light Absorption Reviewed International journal

    Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    Chemistry – A European Journal   Vol. 28 ( 2 ) page: e202103647   2022.1

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/chem.202103647

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  5. A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles Reviewed International journal

    Shusaku Ukai, Aiko Takamatsu, Masaki Nobuoka, Yusuke Tsutsui, Norihito Fukui, Soichiro Ogi, Shu Seki, Shigehiro Yamaguchi, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 61   page: e202114230   2021.12

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202114230

  6. Dual-Ion NiNc Battery: A Sustainable Revolution for Sodium Organic Batteries Reviewed International journal

    Jinkwang Hwang, Kazuhiko Matsumoto, Rika Hagiwara, Shusaku Ukai, Hiroshi Shinokubo, Ji-Young Shin

    Batteries & Supercaps   Vol. 4 ( 10 ) page: 1605 - 1610   2021.10

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/batt.202100193

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  7. Manganese(III) 5,15-diazaporphyrins: Synthesis, properties, and catalytic use for benzylic C–H fluorination Reviewed International journal

    Shiho Mori, Tsubasa Nishimura, Hiroshi Shinokubo, Yoshihiro Miyake

    Journal of Porphyrins and Phthalocyanines   Vol. 25 ( 10N12 ) page: 991 - 996   2021.10

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:World Scientific Pub Co Pte Lt  

    <jats:p> Fluorination of sp<jats:sup>3</jats:sup> C–H bonds has attracted considerable attention as a promising method for the synthesis of organofluorine compounds. Manganese porphyrins have been extensively investigated as catalysts in the fluorination of saturated sp<jats:sup>3</jats:sup> C–H bonds. Recently, we have found that iron(III) 5,15-diazaporphyrins, which are porphyrin analogues with imine-type sp<jats:sup>2</jats:sup>-hybridized nitrogen atoms at the meso-positions, showed high catalytic performance in the oxidation of sp<jats:sup>3</jats:sup> C–H bonds. Here we disclose the synthesis, structure, and electronic properties of manganese(III) 5,15-diazaporphyrins. We also demonstrate the catalysis of chloromanganese(III) 5,15-diazaporphyrins for benzylic fluorination. </jats:p>

    DOI: 10.1142/S1088424621500887

    Web of Science

  8. Antiaromatic 1,5‐Diaza‐ s ‐indacenes Reviewed International coauthorship International journal

    Kensuke Hanida, Jinseok Kim, Norihito Fukui, Yusuke Tsutsui, Shu Seki, Dongho Kim, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 60 ( 38 ) page: 20765 - 20770   2021.9

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202109003

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  9. Synthesis of Tetrasilatetrathia[8]circulenes through C-I and C-H Silylation Invited Reviewed International journal

    Akahori Shuhei, Fujihara Tetsuaki, Tsuji Yasushi, Shinokubo Hiroshi, Miyake Yoshihiro

      Vol. 53 ( 17 ) page: 2995 - 3000   2021.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/a-1437-9917

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  10. Determinant Factors of Three-Dimensional Aromaticity in Antiaromatic Cyclophanes Reviewed International coauthorship International journal

    Hiroyuki Kawashima, Shusaku Ukai, Ryo Nozawa, Norihito Fukui, Garrett Fitzsimmons, Tim Kowalczyk, Heike Fliegl, Hiroshi Shinokubo

    Journal of the American Chemical Society   Vol. 143 ( 28 ) page: 10676 - 10685   2021.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.1c04348

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  11. Non‐Planar Perylene Bisimide Analogues with Inserted Carbonyl and Methylene Subunits Reviewed International journal

    Mai Odajima, Keita Tajima, Norihito Fukui, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 60 ( 29 ) page: 15838 - 15843   2021.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    The synthesis and properties of dinaphthotropone bisimide (DNTrBI) and dinaphthocycloheptatriene bisimide (DNCHepBI) are described. Their molecular design is conceptually based on the insertion of a carbon atom into a perylene bisimide (PBI) core. These molecules adopt non-planar structures due to the presence of a seven-membered ring. The PBI derivative into which a carbonyl group was inserted (DNTrBI) immediately underwent nonradiative decay and/or intersystem crossing in its excited state. The PBI derivative into which a methylene group was inserted (DNCHepBI) was susceptible to deprotonation on account of the two electron-withdrawing naphthalene monoimide units. Subsequent aerobic oxidation resulted in the formation of a C-C bond at the central methylene unit, thus affording a sigma-dimer. The formation of this C-C bond is dynamically redox-active, i.e., electron injection into the sigma-dimer almost quantitatively regenerated the deprotonated DNCHepBI.

    DOI: 10.1002/anie.202104882

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  12. Acridino[2,1,9,8‐ klmna ]acridine Bisimides: An Electron‐Deficient π‐System for Robust Radical Anions and n‐Type Organic Semiconductors Reviewed International journal

    Keita Tajima, Kyohei Matsuo, Hiroko Yamada, Shu Seki, Norihito Fukui, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 60 ( 25 ) page: 14060 - 14067   2021.6

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    We report the synthesis and properties of acridino[2,1,9,8-klmna]acridine bisimide (AABI), a nitrogen-doped anthanthrene with two imide functionalities. AABI exhibits excellent electron affinity as evident by its low-lying LUMO level (-4.1 eV vs. vacuum). Single-electron reduction of one AABI derivative afforded the corresponding radical anion, which was stable under ambient conditions. Photoconductivity measurements suggest that the intrinsic electron mobility of an N-phenethyl AABI derivative obeys a band-transport model. Accordingly, an electron mobility of 0.90 cm(2) V-1 s(-1) was attained with the corresponding single-crystal organic field-effect transistor (OFET) device. The vacuum-deposited OFET device consisting of a polycrystalline sample exhibited high electron mobility of up to 0.27 cm(2) V-1 s(-1) even in air. This study demonstrates that dual incorporation of both imide substituents and imine-type nitrogen atoms is an effective strategy to create novel electron-deficient pi-systems.

    DOI: 10.1002/anie.202102708

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  13. Synthesis and Characterization of 16 pi Antiaromatic 2,7-Dihydrodiazapyrenes: Antiaromatic Polycyclic Hydrocarbons with Embedded Nitrogen Reviewed International journal

    Nakazato, Takumi, Takekoshi, Haruka, Sakurai, Takahiro, Shinokubo, Hiroshi, Miyake, Yoshihiro

    Angewandte Chemie International Edition   Vol. 60 ( 25 ) page: 13877 - 13881   2021.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/anie.202103667

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  14. Quadruply BN‐Fused Tetrathia[8]circulenes with Flexible Frameworks: Synthesis, Structures and Properties Reviewed International journal

    Shuhei Akahori, Takahiro Sasamori, Hiroshi Shinokubo, Yoshihiro Miyake

    Chemistry – A European Journal   Vol. 27 ( 31 ) page: 8178 - 8184   2021.6

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/chem.202100454

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/chem.202100454

  15. Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp(3) C-H bonds Reviewed International journal

      Vol. 50 ( 18 ) page: 6343 - 6348   2021.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1dt00893e

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  16. Cationic Nickel(II) Pyridinophane Complexes: Synthesis, Structures and Catalytic Activities for C–H Oxidation Reviewed International journal

    Nishimura Tsubasa, Ando Yuki, Shinokubo Hiroshi, Miyake Yoshihiro

    Chemistry Letters   Vol. 50 ( 5 ) page: 1049 - 1052   2021.5

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    <p>A series of nickel(II) pyridinophane complexes were synthesized and characterized by X-ray crystallographic analysis. Their IR spectra supported the existence of mononuclear nickel(II) complexes in solution. Furthermore, we conducted catalytic C–H oxidation of cyclooctane with nickel(II) pyridinophanes as the catalysts. The activity of nickel(II) pyridinophanes was affected by steric hindrance around the nitrogen atoms.</p>

    DOI: 10.1246/cl.210074

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  17. Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin Reviewed International journal

    Kazuya Miyagawa, Ichiro Hisaki, Norihito Fukui, Hiroshi Shinokubo

    Chemical Science   Vol. 12 ( 14 ) page: 5224 - 5229   2021.4

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    3,5-Ethenoporphyrin is a pi -extended porphyrin containing a fused ethene unit between the meso- and beta -positions, exhibiting unique contribution of macrocyclic antiaromaticity. We have recently reported that its analogue, etheno-fused diporphyrin, underwent thermal [2 + 2] cycloaddition to furnish X-shaped cyclobutane-linked tetraporphyrins. Here we demonstrate that the cyclobutane-ring formation is dynamically redox-active. Namely, the tetraporphyrin underwent two-step four-electron oxidation to afford two etheno-fused diporphyrin dications. The reduction of the resulting dication regenerated the cyclobutane-linked tetraporphyrin. The dication was sufficiently stable to allow its isolation under ambient conditions. The structure of the dication has been confirmed by H-1 NMR spectroscopy and X-ray diffraction analysis. Importantly, the simultaneous double C-C bond cleavage in the cyclopropane ring in the tetraporphyrin is exceptional among dynamic redox (dyrex) systems to achieve large structural changes, thus offering new insights for the design of novel redox-active functional organic materials for electrochromic dyes, organic batteries, and organic memories.

    DOI: 10.1039/d1sc00438g

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  18. Synthesis and Properties of an 18π Aromatic Norcorrole P(V) Complex Reviewed International journal

    Takuya Yoshida, Siham Asyiqin Shafie, Hiroyuki Kawashima, Norihito Fukui, Hiroshi Shinokubo

    Organic Letters   Vol. 23 ( 7 ) page: 2826 - 2830   2021.4

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    [16]Norcorrole is an antiaromatic ring-contracted porphyrinoid. Here, we show that the phosphorus insertion of the free-base [16]norcorrole switches its antiaromaticity to aromaticity. The treatment of a free-base meso-dimesityl[16]norcorrole with phosphorus tribromide in pyridine afforded an [18]norcorrole P(V) complex, which exhibited porphyrin-like absorption and fluorescence spectra. The phosphorus center adopted a distorted tetragonal pyramidal coordination geometry. The distinct aromatic nature of the [18]-norcorrole P(V) complex was corroborated both experimentally and theoretically.

    DOI: 10.1021/acs.orglett.1c00823

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  19. Enthalpically and Entropically Favorable Self-Assembly: Synthesis of C-4h-Symmetric Tetraazatetrathia[8]circulenes by Regioselective Introduction of Pyridine Rings Reviewed

    Akahori Shuhei, Sasamori Takahiro, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 27   page: 5675 - 5682   2021.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202005077

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  20. Peripherally Arylated 2,8-Diazaperylenes from Anthracene Diimide: Synthesis and Oxidative Annulation Reviewed

    Takahiro Sakurai, Takumi Nakazato, Hiroshi Shinokubo, and Yoshihiro Miyake

    Organic Letters   Vol. 23 ( 6 ) page: 2099 - 2103   2021.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.1c00253

  21. Dinaphtho[1,8-bc:1 ',8 '-fg][1,5]dithiocine Bisimide Invited Reviewed

    Tanaka Yuki, Tajima Keita, Fukui Norihito, Shinokubo Hiroshi

    ASIAN JOURNAL OF ORGANIC CHEMISTRY   Vol. 10 ( 3 ) page: 541 - 544   2021.2

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    DOI: 10.1002/ajoc.202000722

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  22. Dual Emission of a Free-Base 5-Oxaporphyrinium Cation from its cis- and trans-NH Tautomers Reviewed International coauthorship

    Takiguchi Asahi, Kang Seongsoo, Fukui Norihito, Kim Dongho, Shinokubo Hiroshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 60 ( 6 ) page: 2915 - 2919   2021.2

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.202013542

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  23. Complexation of 2,7-diazapyrene with boron for structural and electronic tuning Reviewed

    Nakazato Takumi, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMICAL COMMUNICATIONS   Vol. 57 ( 3 ) page: 327 - 330   2021.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0cc07804b

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  24. Dual-ion charge–discharge behaviors of Na–NiNc and NiNc–NiNc batteries Reviewed International journal

    Jinkwang Hwang, Rika Hagiwara, Hiroshi Shinokubo, Ji-Young Shin

    Materials Advances   Vol. 2 ( 7 ) page: 2263 - 2266   2021

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry ({RSC})  

    <p>Dual-ion Na–organic batteries were provided with anti-aromatic NiNc, exposing inherent charge–discharge behavior with high discharge capacity, high durability, and high Coulombic efficiency with high-density currents.</p>

    DOI: 10.1039/D1MA00007A

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  25. Hetero[8]circulenes: synthetic progress and intrinsic properties Invited Reviewed

    Miyake Yoshihiro, Shinokubo Hiroshi

    CHEMICAL COMMUNICATIONS   Vol. 56 ( 100 )   2020.12

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0cc06495e

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  26. Aggregation-Induced Emission in Tetrathia[8]circulene Octaoxides via Restriction of the Dynamic Motion of their Negatively Curved pi-Frameworks Reviewed

    Murase Hiroyasu, Nagata Yuya, Akahori Shuhei, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMISTRY-AN ASIAN JOURNAL   Vol. 15 ( 22 ) page: 3873 - 3877   2020.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/asia.202001129

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  27. Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination Reviewed

    Longevial Jean-Francois, Miyagawa Kazuya, Shinokubo Hiroshi

    DALTON TRANSACTIONS   Vol. 49 ( 42 ) page: 14786 - 14789   2020.11

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0dt02727h

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  28. Synthesis and electron-transport properties of a stable antiaromatic Ni-II norcorrole with the smallest meso-substituent Reviewed

    Ukai Shusaku, Koo Yun Hee, Fukui Norihito, Seki Shu, Shinokubo Hiroshi

    DALTON TRANSACTIONS   Vol. 49 ( 41 ) page: 14383 - 14387   2020.11

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0dt03143g

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  29. Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp(3))-H Bonds Reviewed

    Nishimura Tsubasa, Ikeue Takahisa, Shoji Osami, Shinokubo Hiroshi, Miyake Yoshihiro

    INORGANIC CHEMISTRY   Vol. 59 ( 21 ) page: 15751 - 15756   2020.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.0c02166

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  30. as-Indaceno[3,2,1,8,7,6-ghijklm]terrylene as a near-infrared absorbing C-70-fragment Reviewed

    NATURE COMMUNICATIONS   Vol. 11 ( 1 )   2020.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-020-17684-6

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  31. Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide Reviewed

    Hayakawa Sakiho, Matsuo Kyohei, Yamada Hiroko, Fukui Norihito, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 142 ( 27 ) page: 11663 - 11668   2020.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.0c04096

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  32. meso-Diazacorrphycenes: Neighboring Effect of Two Nitrogen Atoms Reviewed

    Yagi Atsumi, Shinokubo Hiroshi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 26 ( 37 ) page: 8210 - 8213   2020.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202002053

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  33. A 2-to-2 ' 18-to-18 ' doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad Reviewed

    Liu Si-Yu, Kawashima Hiroyuki, Fukui Norihito, Shinokubo Hiroshi

    CHEMICAL COMMUNICATIONS   Vol. 56 ( 50 ) page: 6846 - 6849   2020.6

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    DOI: 10.1039/d0cc02543g

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  34. 新形式の芳香族化合物の合成を目指して Reviewed International journal

    忍久保 洋

    化学と教育   Vol. 68 ( 6 ) page: 268 - 269   2020.6

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    Authorship:Corresponding author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:公益社団法人 日本化学会  

    <p>反芳香族化合物は不安定な化合物であるが,それを上下に接近させて重ねると芳香族化合物になり,安定化することが分かってきた。これまで,芳香族性の起源は二次元的なπ電子の広がりであると考えられてきた。しかし最新の研究により,2つの分子の間の三次元的なπ電子の広がりによっても芳香族性が生じることが示された。また,反芳香族化合物が芳香族化合物よりも互いに接近しやすいことも分かってきた。分子が近づいて電荷が移動しやすくなるため,有機半導体などへの応用が期待される。</p>

    DOI: 10.20665/kakyoshi.68.6_268

    CiNii Research

  35. Reactions of Antiaromatic Norcorrole Ni(II) Complex with Carbenes Reviewed

    Liu Si-Yu, Fukuoka Takaki, Fukui Norihito, Shin Ji-Young, Shinokubo Hiroshi

    ORGANIC LETTERS   Vol. 22 ( 11 ) page: 4400 - 4403   2020.6

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    DOI: 10.1021/acs.orglett.0c01402

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  36. Synthesis and Crystal Packing Structures of 2,7-Diazapyrenes with Various Alkyl Groups at 1,3,6,8-Positions Reviewed

    Nakazato Takumi, Matsuda Wakana, Sakurai Tsuneaki, Seki Shu, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMISTRY LETTERS   Vol. 49 ( 5 ) page: 465 - 468   2020.5

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    DOI: 10.1246/cl.200083

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  37. Synthesis and properties of 5-aza-15-thiaporphyrins Invited Reviewed

    Yamashita Daisuke, Omori Hiroto, Fukui Norihito, Shinokubo Hiroshi

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   Vol. 24 ( 1-3 ) page: 84 - 89   2020.3

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    DOI: 10.1142/S108842461950069X

    Web of Science

  38. Site-Selective N-Methylation of 5,15-Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues Reviewed International coauthorship

    Chia Wen Xi, Nishijo Mayu, Kang Seongsoo, Oh Juwon, Nishimura Tsubasa, Omori Hiroto, Longevial Jean-Francois, Miyake Yoshihiro, Kim Dongho, Shinokubo Hiroshi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 26 ( 12 ) page: 2754 - 2760   2020.2

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    DOI: 10.1002/chem.201905402

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  39. Systematic Synthesis of Tetrathia[8]circulenes: The Influence of Peripheral Substituents on the Structures and Properties in Solution and Solid States Reviewed

    Kato Shohei, Akahori Shuhei, Serizawa Yuma, Lin Xu, Yamauchi Mitsuaki, Yagai Shiki, Sakurai Tsuneaki, Matsuda Wakana, Seki Shu, Shinokubo Hiroshi, Miyake Yoshihiro

    JOURNAL OF ORGANIC CHEMISTRY   Vol. 85 ( 1 ) page: 62 - 69   2020.1

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    DOI: 10.1021/acs.joc.9b01655

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  40. Inserting Nitrogen: An Effective Concept To Create Nonplanar and Stimuli-Responsive Perylene Bisimide Analogues Reviewed International coauthorship

    Hayakawa Sakiho, Kawasaki Ayumi, Hong Yongseok, Uraguchi Daisuke, Ooi Takashi, Kim Dongho, Akutagawa Tomoyuki, Fukui Norihito, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 141 ( 50 ) page: 19807 - 19816   2019.12

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    DOI: 10.1021/jacs.9b09556

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  41. Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers Reviewed

    Tajima Keita, Fukui Norihito, Shinokubo Hiroshi

    ORGANIC LETTERS   Vol. 21 ( 23 ) page: 9516 - 9520   2019.12

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    DOI: 10.1021/acs.orglett.9b03699

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  42. 5,5,15,15‐Tetraoxo‐5,15‐Dithiaporphyrin as a Highly Electron‐Deficient Porphyrinic Ligand Reviewed

    Atsumi Yagi, Takeshi Kondo, Daisuke Yamashita, Naruhiko Wachi, Hiroto Omori, Norihito Fukui, Takahisa Ikeue, Hiroshi Shinokubo

    Chemistry – A European Journal   Vol. 25 ( 68 ) page: 15580 - 15585   2019.12

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    DOI: 10.1002/chem.201903639

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  43. Regioselective Desilylation of a pi-Extended Aza[5]helicene

    Ushiyama Ayako, Shinokubo Hiroshi, Hiroto Satoru

    CHEMISTRY LETTERS   Vol. 48 ( 9 ) page: 1069 - 1072   2019.9

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    DOI: 10.1246/cl.190369

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  44. Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position

    Omori Hiroto, Shinokubo Hiroshi

    ORGANOMETALLICS   Vol. 38 ( 15 ) page: 2878 - 2882   2019.8

  45. Soluble and Planar 2,9-Diazaperopyrenes through Reductive Aromatization of Perylene Diimides: Tunable Emission and Aggregation Behaviors

    Nakamura Yasutaka, Nakazato Takumi, Kamatsuka Takuto, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 25 ( 45 ) page: 10571 - 10574   2019.8

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    DOI: 10.1002/chem.201902123

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  46. Three-dimensional aromaticity in an antiaromatic cyclophane Reviewed International coauthorship

    Nozawa Ryo, Kim Jinseok, Oh Juwon, Lamping Anna, Wang Yemei, Shimizu Soji, Hisaki Ichiro, Kowalczyk Tim, Fliegl Heike, Kim Dongho, Shinokubo Hiroshi

    NATURE COMMUNICATIONS   Vol. 10   2019.8

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    DOI: 10.1038/s41467-019-11467-4

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  47. Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material

    Shin Ji-Young, Zhang Zhongyue, Awaga Kunio, Shinokubo Hiroshi

    MOLECULES   Vol. 24 ( 13 )   2019.7

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    DOI: 10.3390/molecules24132433

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  48. Synthesis of meso-Alkyl-Substituted Norcorrole-Ni-II Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)

    Liu Si-Yu, Tanaka Hiroko, Nozawa Ryo, Fukui Norihito, Shinokubo Hiroshi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 25 ( 32 ) page: 7618 - 7622   2019.6

  49. Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins

    Takiguchi Asahi, Fukui Norihito, Shinokubo Hiroshi

    ORGANIC LETTERS   Vol. 21 ( 11 ) page: 3950 - 3953   2019.6

  50. Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s

    Shafie Siham A., Kawashima Hiroyuki, Miyake Yoshihiro, Shinokubo Hiroshi

    CHEMPLUSCHEM   Vol. 84 ( 6 ) page: 623 - 626   2019.6

  51. Synthesis of Dihydropyrazine-fused Porphyrin Dimers

    Takiguchi Asahi, Wakita Mana, Hiroto Satoru, Shinokubo Hiroshi

    CHEMISTRY LETTERS   Vol. 48 ( 4 ) page: 371 - 373   2019.4

  52. Ni(II) 10-Phosphacorrole: A Porphyrin Analogue Containing Phosphorus at the Meso Position

    Omori Hiroto, Hiroto Satoru, Takeda Youhei, Fliegl Heike, Minakata Satoshi, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 141 ( 12 ) page: 4800 - 4805   2019.3

  53. Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy. Reviewed

    Longevial Jean-Francois, Yamaji Ayaka, Aggad Dina, Kim Gakhyun, Chia Wen Xi, Nishimura Tsubasa, Miyake Yoshihiro, Clement Sebastien, Oh Juwon, Daurat Morgane, Nguyen Christophe, Kim Dongho, Gary-Bobo Magali, Richeter Sebastien, Shinokubo Hiroshi

    Chemical communications (Cambridge, England)   Vol. 54 ( 98 ) page: 13829 - 13832   2018.12

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    DOI: 10.1039/c8cc07489e

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  54. Theoretical Study on Open-Shell Singlet Character and Second Hyperpolarizabilities in Cofacial π-Stacked Dimers Composed of Weak Open-Shell Antiaromatic Porphyrins Reviewed

    Fujiyoshi Jun-ya, Tonami Takayoshi, Yamane Masaki, Okada Kenji, Kishi Ryohei, Muhammad Shabbir, Al-Sehemi Abdullah G, Nozawa Ryo, Shinokubo Hiroshi, Nakano Masayoshi

    ChemPhysChem   Vol. 19 ( 21 ) page: 2863 - 2871   2018.11

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    DOI: 10.1002/cphc.201800745

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  55. X-Shaped Cyclobutane-Linked Tetraporphyrins through a Thermal [2+2] Cycloaddition of Etheno-Fused Diporphyrins Reviewed

    Nagai Tomohiro, Takiguchi Asahi, Ueda Masayuki, Oda Kazuma, Hiroto Satoru, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 140 ( 27 ) page: 8392-8395   2018.7

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    DOI: 10.1021/jacs.8b04673

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  56. Azabuckybowl-Based Molecular Tweezers as C-60 and C-70 Receptors Reviewed

    Takeda Motoki, Hiroto Satoru, Yokoi Hiroki, Lee Sangsu, Kim Dongho, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 140 ( 20 ) page: 6336-6342   2018.5

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    DOI: 10.1021/jacs.8b02327

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  57. The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes Reviewed

    Nakazato Takumi, Kamatsuka Takuto, Inoue Junichi, Sakurai Tsuneaki, Seki Shu, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMICAL COMMUNICATIONS   Vol. 54 ( 41 ) page: 5177-5180   2018.5

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    DOI: 10.1039/c8cc01937a

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  58. Reversible sigma-Bond Formation in Bowl-Shaped pi-Radical Cations: The Effects of Curved and Planar Structures Reviewed

    Yokoi Hiroki, Hiroto Satoru, Shinokubo Hiroshi

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 140 ( 13 ) page: 4649-4655   2018.4

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    DOI: 10.1021/jacs.8b00798

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  59. Figuration of bowl-shaped pi-conjugated molecules: properties and functions Invited Reviewed

    Saito Masaichi, Shinokubo Hiroshi, Sakurai Hidehiro

    MATERIALS CHEMISTRY FRONTIERS   Vol. 2 ( 4 ) page: 635 - 661   2018.4

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    DOI: 10.1039/c7qm00593h

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  60. Benzonorcorrole Ni-II Complexes: Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion Reviewed

    Yoshida Takuya, Takahashi Kohtaro, Ide Yuki, Kishi Ryohei, Fujiyoshi Jun-ya, Lee Sangsu, Hiraoka Yuya, Kim Dongho, Nakano Masayoshi, Ikeue Takahisa, Yamada Hiroko, Shinokubo Hiroshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 57 ( 8 ) page: 2209-2213   2018.2

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    DOI: 10.1002/anie.201712961

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  61. Supramolecular assemblies of a nitrogen-embedded buckybowl dimer with C-60 Reviewed

    Yokoi Hiroki, Hiroto Satoru, Sakamaki Daisuke, Seki Shu, Shinokubo Hiroshi

    CHEMICAL SCIENCE   Vol. 9 ( 4 ) page: 819-824   2018.1

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    DOI: 10.1039/c7sc04453d

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  62. Synthesis and Photodynamics of Tetragermatetrathia[8]circulene Reviewed

    Akahori Shuhei, Sakai Hayato, Hasobe Taku, Shinokubo Hiroshi, Miyake Yoshihiro

    ORGANIC LETTERS   Vol. 20 ( 1 ) page: 304-307   2018.1

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    DOI: 10.1021/acs.orglett.7b03764

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  63. Nickel (II) pyrrocorphin: Enhanced binding ability in a highly reduced porphyrin complex. Reviewed

    Ide Y, Kuwahara T, Takeshita S, Fujishiro R, Suzuki M, Mori S, Shinokubo H, Nakamura M, Yoshino K, Ikeue T

    Journal of inorganic biochemistry   Vol. 178   page: 115 - 124   2018.1

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    DOI: 10.1016/j.jinorgbio.2017.10.012

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  64. Synthesis of Heteroatom-Containing Curved pi-Conjugated Molecules Reviewed

    Hiroto Satoru, Shinokubo Hiroshi

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   Vol. 76 ( 1 ) page: 37-44   2018.1

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  65. Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group. Reviewed

    Uehara H, Shisaka Y, Nishimura T, Sugimoto H, Shiro Y, Miyake Y, Shinokubo H, Watanabe Y, Shoji O

    Angewandte Chemie (International ed. in English)   Vol. 56 ( 48 ) page: 15279 - 15283   2017.11

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    DOI: 10.1002/anie.201707212

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  66. Acid-Mediated Migration of Bromide in an Antiaromatic Porphyrinoid: Preparation of Two Regioisomeric Ni(II) Bromonorcorroles Reviewed

    Kawashima Hiroyuki, Hiroto Satoru, Shinokubo Hiroshi

    JOURNAL OF ORGANIC CHEMISTRY   Vol. 82 ( 19 ) page: 10425 - 10432   2017.10

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    DOI: 10.1021/acs.joc.7b01899

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  67. Shaping Antiaromatic -Systems by Metalation: Synthesis of a Bowl-Shaped Antiaromatic Palladium Norcorrole Reviewed

    Yonezawa Tsubasa, Shafie Siham A., Hiroto Satoru, Shinokubo Hiroshi

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 56 ( 39 ) page: 11822 - 11825   2017.9

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    DOI: 10.1002/anie.201706134

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  68. Synthesis and Properties of meso-Arylated Corrphycenes. Reviewed

    Nozawa R, Shinokubo H

    Organic letters   Vol. 19 ( 18 ) page: 4928 - 4931   2017.9

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    DOI: 10.1021/acs.orglett.7b02390

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  69. Design and Synthesis of Tunable Ligands with 4,4'-Bipyridyl as an Electron-Accepting Unit and Their Rhenium Complexes Reviewed

    Kamatsuka Takuto, Shinokubo Hiroshi, Miyake Yoshihiro

    ORGANOMETALLICS   Vol. 36 ( 17 ) page: 3429 - 3434   2017.9

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    DOI: 10.1021/acs.organomet.7b00611

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  70. A synthesis of novel expanded porphyrinoids: Ni-II-induced nitrile cyclization of dicyanovinylene-bis (meso-aryl)dipyrrin Reviewed

    Faialaga Nathan H., Ito Satoru, Shinokubo Hiroshi, Kim Younghoon, Kim Kimoon, Shin Ji-Young

    DALTON TRANSACTIONS   Vol. 46 ( 33 ) page: 10802 - 10808   2017.9

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    DOI: 10.1039/c7dt01838j

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  71. pi-Extended Dihydrophenazines with Three-State NIR Electrochromism Involving Large Conformational Changes Reviewed

    Nagasaki Juri, Hiroto Satoru, Shinokubo Hiroshi

    CHEMISTRY-AN ASIAN JOURNAL   Vol. 12 ( 17 ) page: 2311 - 2317   2017.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/asia.201700840

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  72. Direct amination of the antiaromatic Ni-II norcorrole Reviewed

    Yoshida Takuya, Shinokubo Hiroshi

    MATERIALS CHEMISTRY FRONTIERS   Vol. 1 ( 9 ) page: 1853 - 1857   2017.9

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    DOI: 10.1039/c7qm00176b

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  73. Selective alpha-arylation of alpha,beta-unsaturated imides mediated by a visible light photoredox catalyst

    Ando Yuki, Kamatsuka Takuto, Shinokubo Hiroshi, Miyake Yoshihiro

    CHEMICAL COMMUNICATIONS   Vol. 53 ( 65 ) page: 9136-9138   2017.8

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    DOI: 10.1039/c7cc04776b

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  74. Highly-conducting molecular circuits based on antiaromaticity Reviewed

    Fujii Shintaro, Marques-Gonzalez Santiago, Shin Ji-Young, Shinokubo Hiroshi, Masuda Takuya, Nishino Tomoaki, Arasu Narendra P., Vazquez Hector, Kiguchi Manabu

    NATURE COMMUNICATIONS   Vol. 8   2017.7

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    DOI: 10.1038/ncomms15984

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  75. Synthesis, Properties, and Reactivities of Ruthenium(II) Carbonyl 5,15-Diazaporphyrins Reviewed

    Nishimura Tsubasa, Miyake Yoshihiro, Shinokubo Hiroshi

    CHEMISTRY LETTERS   Vol. 46 ( 7 ) page: 995 - 997   2017.7

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    DOI: 10.1246/cl.170363

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  76. NIR mechanochromic behaviours of a tetracyanoethylene-bridged hexa-peri-hexabenzocoronene dimer and trimer through dissociation of C-C bonds Reviewed

    Oda Kazuma, Hiroto Satoru, Shinokubo Hiroshi

    JOURNAL OF MATERIALS CHEMISTRY C   Vol. 5 ( 22 ) page: 5310 - 5315   2017.6

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    DOI: 10.1039/c7tc01270e

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  77. 10-Silacorroles Exhibiting Near-Infrared Absorption and Emission

    Omori Hiroto, Hiroto Satoru, Shinokubo Hiroshi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 23 ( 33 ) page: 7866-7870   2017.6

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    DOI: 10.1002/chem.201701474

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  78. Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds Reviewed

    Serizawa Yuma, Akahori Shuhei, Kato Shohei, Sakai Hayato, Hasobe Taku, Miyake Yoshihiro, Shinokubo Hiroshi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 23 ( 29 ) page: 6948 - 6952   2017.5

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    DOI: 10.1002/chem.201700729

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  79. Synthesis of Tetraaza[8]circulenes from Tetrathia[8]circulenes through an SNAr-Based Process Reviewed

    Nagata Yuya, Kato Shohei, Miyake Yoshihiro, Shinokubo Hiroshi

    ORGANIC LETTERS   Vol. 19 ( 10 ) page: 2718 - 2721   2017.5

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    DOI: 10.1021/acs.orglett.7b01074

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  80. Synthesis of a figure-eight azahelicene dimer with high emission and CPL properties

    Ushiyama Ayako, Hiroto Satoru, Yuasa Junpei, Kawai Tsuyoshi, Shinokubo Hiroshi

    ORGANIC CHEMISTRY FRONTIERS   Vol. 4 ( 5 ) page: 664-667   2017.5

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    DOI: 10.1039/c6qo00629a

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  81. Synthesis and Functionalization of Porphyrins through Organometallic Methodologies Invited Reviewed

    Hiroto Satoru, Miyake Yoshihiro, Shinokubo Hiroshi

    CHEMICAL REVIEWS   Vol. 117 ( 4 ) page: 2910 - 3043   2017.2

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    DOI: 10.1021/acs.chemrev.6b00427

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  82. Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers Reviewed

    Oda Kazuma, Hiroto Satoru, Hisaki Ichiro, Shinokubo Hiroshi

    ORGANIC & BIOMOLECULAR CHEMISTRY   Vol. 15 ( 6 ) page: 1426 - 1434   2017.2

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    DOI: 10.1039/c6ob02775j

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  83. Enhancing the low-energy absorption band and charge mobility of antiaromatic Ni-II norcorroles by their substituent effects Reviewed

    Yoshida Takuya, Sakamaki Daisuke, Seki Shu, Shinokubo Hiroshi

    CHEMICAL COMMUNICATIONS   Vol. 53 ( 6 ) page: 1112 - 1115   2017.1

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    DOI: 10.1039/c6cc09444a

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  84. Stacked antiaromatic porphyrins Reviewed International journal

    Nozawa, R., Tanaka, H., Cha, W.-Y., Hong, Y., Hisaki, I., Shimizu, S., Shin, J.-Y., Kowalczyk, T., Irle, S., Kim, D., Shinokubo, H.

    Nature Communications   Vol. 7   page: 13620   2016.11

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    DOI: 10.1038/ncomms13620

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  85. Reversible Carbon–Carbon Bond Breaking and Spin Equilibria in Bis(pyrimidinenorcorrole) Reviewed International journal

    Liu, B., Yoshida, T., Li, X., Stępień, M., Shinokubo, H., Chmielewski, P.J.

    Angewandte Chemie - International Edition   Vol. 55 ( 42 ) page: 13142 - 13146   2016.10

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    DOI: 10.1002/anie.201607237

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    CiNii Research

  86. β-to-β 2,5-Pyrrolylene-Linked Cyclic Porphyrin Oligomers Reviewed International journal

    Rao, Y., Kim, J.O., Kim, W., Zhong, G., Yin, B., Zhou, M., Shinokubo, H., Aratani, N., Tanaka, T., Liu, S., Osuka, A., Kim, D., Song, J.

    Chemistry - A European Journal   Vol. 22 ( 26 ) page: 8801 - 8804   2016.6

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    DOI: 10.1002/chem.201601306

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    CiNii Research

  87. Synthesis of Free-Base 10-Azacorroles Reviewed International journal

    Omori, H., Hiroto, S., Shinokubo, H.

    Organic Letters   Vol. 18 ( 12 ) page: 2978 - 2981   2016.6

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    DOI: 10.1021/acs.orglett.6b01323

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  88. Fully-substituted 1,3-butadienes as π-conjugated linkers between pyrenes Reviewed International journal

    Oda, K., Hiroto, S., Sakamaki, D., Seki, S., Shinokubo, H.

    Chemistry Letters   Vol. 45 ( 4 ) page: 403 - 405   2016.4

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    Pyrenyl-substituted 1,3-butadienes bearing alkyl and aryl groups have been synthesized by palladium-catalyzed addition of 2-borylpyrene to internal alkynes. On UV irradiation, 1-pyrenylbutadienes undergo photochromism in solution. In the solid state, 1-pyrenyl-1,2,3,4-tetraaryl-1,3-butadiene exhibits red-shifted and broad emission as compared with the alkylated butadiene. The charge-carrier mobility of 1-pyrenyl-1,2,3,4-tetraalkyl-1,3-butadiene is higher than that of the arylated butadiene.

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  89. Control of Conformation and Chirality of Nonplanar π-Conjugated Diporphyrins Using Substituents and Axial Ligands Reviewed International journal

    Ito, S., Hiroto, S., Ousaka, N., Yashima, E., Shinokubo, H.

    Chemistry - An Asian Journal   Vol. 11 ( 6 ) page: 936 - 942   2016.3

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    DOI: 10.1002/asia.201600105

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  90. Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids Reviewed International journal

    Yamaji, A., Tsurugi, H., Miyake, Y., Mashima, K., Shinokubo, H.

    Chemistry - A European Journal   Vol. 22 ( 12 ) page: 3956 - 3961   2016.3

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    DOI: 10.1002/chem.201600066

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  91. The synthesis of Ni<sup>II</sup> and Al<sup>III</sup> 10-azacorroles through coordination-induced cyclisation involving 1,2-migration Reviewed International journal

    Omori, H., Hiroto, S., Shinokubo, H.

    Chemical Communications   Vol. 52 ( 17 ) page: 3540 - 3543   2016

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    DOI: 10.1039/c5cc10247b

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  92. Ni<sup>II</sup> tetrahydronorcorroles: Antiaromatic porphyrinoids with saturated pyrrole units Reviewed International journal

    Nozawa, R., Yamamoto, K., Hisaki, I., Shin, J.-Y., Shinokubo, H.

    Chemical Communications   Vol. 52 ( 44 ) page: 7106 - 7109   2016

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    DOI: 10.1039/c6cc02918c

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  93. Indolylindolinone: Easily accessible, tunable, and wide-range absorbing dyes Reviewed International journal

    Shigeno, A., Matsuno, T., Hiroto, S., Shinokubo, H.

    Chemistry Letters   Vol. 44 ( 12 ) page: 1703 - 1705   2015.12

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    Dehydrative coupling between indoles and isatins provided indolylindolinones in good yields as novel dyes with wide-range absorption due to intramolecular charge-transfer interactions. The HOMO and LUMO levels of indolylindolinones could be manipulated individually by the introduction of substituents on the indole and isatin units, respectively. Indolylindolinones served as a bidentate ligand to Ni(II) and Cu(II) ions to provide stable metal complexes. Metal coordination induced large bathochromic shift of the lowest-energy absorption band to the near-infrared region.

    DOI: 10.1246/cl.150815

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  94. Twisting of π-conjugated plane to one rotation Reviewed International journal

    Hiroto S., Shinokubo H.

    Kobunshi   Vol. 64 ( 11 ) page: 713 - 714   2015.11

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    We have established the facile and efficient protocol to synthesize distorted 71-conjugated molecules. Oxidation of amino-substituted porphyrins proceeded with high regioselectivity to produce pyrazine fused dimers. X-ray diffraction analysis revealed its highly twisted structure. Electrochemical and optical measurements indicated the twisting mostly influences on HOMO. The sequential use of our protocol has achieved the synthesis of unidirectionally twisted porphyrin tetramers efficiently. NMR analysis suggested that the racemization barrier of twisting increases on oligomerization. To the best of our knowledge, this is the first observation of a similar phenomenon observed in polymer science for twisted, jt-conjugated molecules. The present findings represent an important advance towards the long-term goal of preparing -conjugated molecular wires, whose properties can be fine-tuned through molecular twisting.

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  95. A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin Reviewed International journal

    Tanaka, Y., Yoneda, T., Furukawa, K., Koide, T., Mori, H., Tanaka, T., Shinokubo, H., Osuka, A.

    Angewandte Chemie - International Edition   Vol. 54 ( 37 ) page: 10908 - 10911   2015.9

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    DOI: 10.1002/anie.201505130

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  96. Nitrogen-embedded buckybowl and its assembly with C<inf>60</inf> Reviewed International journal

    Yokoi, H., Hiraoka, Y., Hiroto, S., Sakamaki, D., Seki, S., Shinokubo, H.

    Nature Communications   Vol. 6   page: 8215   2015.9

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    DOI: 10.1038/ncomms9215

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  97. Regioselective Nucleophilic Functionalization of Antiaromatic Nickel(II) Norcorroles Reviewed International journal

    Nozawa, R., Yamamoto, K., Shin, J.-Y., Hiroto, S., Shinokubo, H.

    Angewandte Chemie - International Edition   Vol. 54 ( 29 ) page: 8454 - 8457   2015.7

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    DOI: 10.1002/anie.201502666

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  98. Synthesis of highly twisted and fully π-conjugated porphyrinic oligomers Reviewed International journal

    Ito, S., Hiroto, S., Lee, S., Son, M., Hisaki, I., Yoshida, T., Kim, D., Kobayashi, N., Shinokubo, H.

    Journal of the American Chemical Society   Vol. 137 ( 1 ) page: 142 - 145   2015.1

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    DOI: 10.1021/ja511905f

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  99. Palladium-catalyzed [3+2] annulation of meso-bromoporphyrins with silylacetylenes and desilylation of 8&lt;sup&gt;a&lt;/sup&gt;-silyl-7,8-dehydropurpurin Reviewed International journal

    Fukui, N., Arai, S., Shinokubo, H., Yorimitsu, H., Osuka, A.

    Heterocycles   Vol. 90 ( 1 ) page: 252 - 260   2015.1

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    DOI: 10.3987/COM-14-S(K)15

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  100. Synthesis of Novel Porphyrinoids from Dipyrrins Invited Reviewed International journal

    Hiroshi Shinokubo

    Chemical Science of Electron Systems     page: 243 - 255   2015.1

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    Most syntheses of meso-substituted porphyrinoid rely on acid-catalyzed condensation of pyrrole segments with aldehyde units followed by oxidation. This standard procedure is convenient but generally is low yielding. However, modern synthetic methodologies would offer an expeditious route to several intriguing porphyrinoids. In particular, the metal template strategy using dipyrrin metal complexes is effective to construct porphyrin-like cyclic π-conjugated systems, which are otherwise difficult to access by the conventional methodology.

    DOI: 10.1007/978-4-431-55357-1_14

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  101. Isolation of a 1,4-diketone intermediate in oxidative dimerization of 2-hydroxyanthracene and its conversion to oxahelicene Reviewed International journal

    Matsuno, T., Koyama, Y., Hiroto, S., Kumar, J., Kawai, T., Shinokubo, H.

    Chemical Communications   Vol. 51 ( 22 ) page: 4607 - 4610   2015

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    DOI: 10.1039/c5cc00764j

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  102. Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C-H borylation and annulation Reviewed International journal

    Kato, S., Serizawa, Y., Sakamaki, D., Seki, S., Miyake, Y., Shinokubo, H.

    Chemical Communications   Vol. 51 ( 95 ) page: 16944 - 16947   2015

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    DOI: 10.1039/c5cc06921a

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  103. Macrocyclic dipyrrin dimer bridged by ethylene and dioxyphenylene linkers Reviewed International journal

    Ji-Young Shin, Satoru Hiroto, Hiroshi Shinokubo

    Journal of Porphyrins and Phthalocyanines   Vol. 19 ( 1-3 ) page: 135 - 139   2015

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    DOI: 10.1142/S108842461450093X

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  104. A 3-pyridyl-5,15-diazaporphyrin nickel(II) complex as a bidentate metalloligand for transition metals Reviewed International journal

    Yamaji, A., Shin, J.-Y., Miyake, Y., Shinokubo, H.

    Angewandte Chemie - International Edition   Vol. 53 ( 50 ) page: 13924 - 13927   2014.12

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    DOI: 10.1002/anie.201408852

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  105. Synthesis of curved hexa-peri-hexabenzocoronenes Reviewed International journal

    Yamaguchi, R., Hiroto, S., Shinokubo, H.

    Chemistry Letters   Vol. 43 ( 10 ) page: 1637 - 1639   2014.10

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    Halogenation and phenylthiolation of hexabenzocoronenetetraone were performed. We found that introduction of substituents at the fjord regions induced substantial curvature of the hexabenzocoronene (HBC) plane through steric repulsion between the substituents and proximal hydrogen atoms. This method allows construction of curved HBC derivatives, which would allow formation of novel supramolecular structures.

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  106. Regioselective double cyclization of 5,15-bis(trimethylsilylethynyl)porphyrin to produce di(oxoethano)porphyrin Reviewed International journal

    Oda, K., Hiroto, S., Shinokubo, H.

    Chemistry Letters   Vol. 43 ( 9 ) page: 1444 - 1446   2014.9

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    Treatment of bis(trimethylsilylethynyl)porphyrin with strong acids afforded doubly oxoethano-fused porphyrin with perfect regioselectivity. The oxoethano-fused porphyrin was more electron deficient than <i>meso</i>-acetylporphyrin because of the coplanar orientation of the carbonyl groups to the porphyrin π system.

    DOI: 10.1246/cl.140470

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  107. Facile synthesis of nitrogen-containing polycyclic aromatic hydrocarbons from perylene bisimides Reviewed International journal

    Ito, S., Hiroto, S., Shinokubo, H.

    Chemistry Letters   Vol. 43 ( 8 ) page: 1309 - 1311   2014.8

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    We have developed a facile procedure for the synthesis of π-extended fluorubins from perylene bisimides. Iridium-catalyzed direct borylation, the Suzuki–Miyaura cross-coupling, and an acid-condensation sequence afforded π-extended fluorubins <b>1</b> in moderate yields. X-ray diffraction analysis revealed a planar structure of <b>1</b>. In addition, optical analysis and DFT calculations indicated the presence of intramolecular charge-transfer interactions in <b>1c</b>.

    DOI: 10.1246/cl.140330

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  108. Synthesis of diazo-bridged bodipy dimer and tetramer by oxidative coupling of β-amino-substituted BODIPYs Reviewed International journal

    Yokoi, H., Hiroto, S., Shinokubo, H.

    Organic Letters   Vol. 16 ( 11 ) page: 3004 - 3007   2014.6

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    DOI: 10.1021/ol501131j

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  109. Photodynamics of [26]- and [28]Hexaphyrin-Bodipy Hybrids Reviewed International journal

    Ji-Young Shin, Kilsuk Kim, Jong Min Lim, Takayuki Tanaka, Dongho Kim, Kimoon Kim, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 20 ( 16 ) page: 4574 - 4582   2014.4

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    A set of hybrids having gradual variation in distances between hexaphyrin and bodipy moieties, given by uses of phenylene, biphenylene, and triphenyelene bridges was prepared. Efficient PET processes from bodipy (donor) to [26]- or [28]hexaphyrin (acceptor) were successfully observed, where the PET speed was controlled by intramolecular distances between the donor and the acceptor. UV irradiation at 515nm raised a band corresponding to the bodipy absorption. As the time delayed, the bodipy bands decreased and new absorption bands at 615 and 580nm corresponding to respective absorption bands of [28]- and [26]-hybrids gradually appeared. Whereas the femtosecond transient absorption spectra of [28]/[26]-hybrids having terphenylene bridges completely showed energy transfers from bodipy to hexaphyrin, irradiation of the hybrids using 615 and 580nm pulses did not induce opposite ways of the PET process. On the basis of enlarged center-to-center-distances of [26]-hybrids than those of [28]-hybrids, the set of [26]-hybrids resulted in slow decay/rise processes. PET parameters obtained with the experiments were fairly consistent with the PET parameters calculated.

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  110. Silylethynyl substituents as porphyrin protecting groups for solubilization and selectivity control Reviewed International journal

    Oda, K., Akita, M., Hiroto, S., Shinokubo, H.

    Organic Letters   Vol. 16 ( 6 ) page: 1818 - 1821   2014.3

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    DOI: 10.1021/ol500569b

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  111. An antiaromatic electrode-active material enabling high capacity and stable performance of rechargeable batteries Reviewed International journal

    Shin, J.-Y., Yamada, T., Yoshikawa, H., Awaga, K., Shinokubo, H.

    Angewandte Chemie - International Edition   Vol. 53 ( 12 ) page: 3096 - 3101   2014.3

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    DOI: 10.1002/anie.201310374

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  112. Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole Reviewed International journal

    Fukuoka, T., Uchida, K., Sung, Y.M., Shin, J.-Y., Ishida, S., Lim, J.M., Hiroto, S., Furukawa, K., Kim, D., Iwamoto, T., Shinokubo, H.

    Angewandte Chemie - International Edition   Vol. 53 ( 6 ) page: 1506 - 1509   2014.2

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    DOI: 10.1002/anie.201309921

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  113. Synthesis of Novel Porphyrinoids through Organometallic Means Invited Reviewed International journal

    Shinokubo Hiroshi

    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN   Vol. 72 ( 2 ) page: 149 - 157   2014.2

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  114. Transition metal catalyzed borylation of functional π-systems Reviewed International journal

    Shinokubo, H.

    Proceedings of the Japan Academy Series B: Physical and Biological Sciences   Vol. 90 ( 1 ) page: 1 - 11   2014.1

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    Borylated functional π-systems are useful building blocks to enable efficient synthesis of novel molecular architectures with beautiful structures, intriguing properties and unique functions. Introduction of boronic ester substituents to a variety of extended π-systems can be achieved through either iridium-catalyzed direct C–H borylation or the two-step procedure via electrophilic halogenation followed by palladium-catalyzed borylation. This review article focuses on our recent progress on borylation of large π-conjugated systems such as porphyrins, perylene bisimides, hexabenzocoronenes and dipyrrins.

    DOI: 10.2183/pjab.90.1

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  115. Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimers Reviewed International journal

    Yokoi, H., Wachi, N., Hiroto, S., Shinokubo, H.

    Chemical Communications   Vol. 50 ( 21 ) page: 2715 - 2717   2014

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    DOI: 10.1039/c3cc48738e

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  116. Synthesis, reactivity and property of 5,15-dithiaporphyrin copper(II) complex Reviewed International journal

    Wachi, N., Kondo, T., Ito, S., Hiroto, S., Shin, J.-Y., Shinokubo, H.

    Journal of Porphyrins and Phthalocyanines   Vol. 18 ( 8-9 ) page: 675 - 678   2014

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    DOI: 10.1142/S1088424614500412

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  117. Selective Synthesis of a [32]Octaphyrin(1.0.1.0.1.0.1.0) Bis(palladium) Complex by a Metal-Templated Strategy Reviewed International journal

    Hiromitsu Kido, Ji-Young Shin, Hiroshi Shinokubo

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 52 ( 51 ) page: 13727 - 13730   2013.12

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    DOI: 10.1002/anie.201306905

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  118. Synthesis of Pyridine-Fused Perylene Imides with an Amidine Moiety for Hydrogen Bonding Reviewed International journal

    Satoru Ito, Satoru Hiroto, Hiroshi Shinokubo

    ORGANIC LETTERS   Vol. 15 ( 12 ) page: 3110 - 3113   2013.6

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    Pyridine-fused perylene tetracarboxylic acid bisimides (PBIs) were synthesized via Suzuki-Miyaura coupling and acid condensation. The fused PBIs with electron-donating substituents exhibited an intramolecular charge transfer Interaction. One of the N-alkyl substituents was selectively removed with BBr3 to create an amidine guest binding site. A hydrogen bonding Interaction with pentafluorobenzoic acid changed the absorption spectra and enhanced fluorescence.

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  119. Porphyrin Analogues That Consist of Indole, Benzofuran, and Benzothiophene Subunits Reviewed International journal

    Shoichi Nakamura, Takeshi Kondo, Satoru Hiroto, Hiroshi Shinokubo

    ASIAN JOURNAL OF ORGANIC CHEMISTRY   Vol. 2 ( 4 ) page: 312 - 319   2013.4

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    DOI: 10.1002/ajoc.201300033

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  120. Functionalization of Hexa-peri-hexabenzocoronenes: Investigation of the Substituent Effects on a Superbenzene Reviewed International journal

    Ryuichi Yamaguchi, Satoru Ito, Byung Sun Lee, Satoru Hiroto, Dongho Kim, Hiroshi Shinokubo

    CHEMISTRY-AN ASIAN JOURNAL   Vol. 8 ( 1 ) page: 178 - 190   2013.1

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    We have demonstrated that the iridium-catalyzed direct borylation of hexa-peri-hexabenzocoronene (HBC) enables regioselective introduction of boryl groups to the para-, ortho-, and meta-substituted HBCs in high yields. The boryl groups have been transformed into various functionalities such as hydroxy, cyano, ethynyl, and amino groups. We have elucidated that the substituents significantly influence the photophysical properties of HBCs to enhance fluorescence quantum yields. DFT calculations revealed that the origin of the substituent effect is the lift in degeneracy in the frontier orbitals by an interaction with electron-donating and electron-withdrawing substituents at the para- and ortho-positions. The change in molecular orbitals results in an increase of the transition probability from the S-0 -&gt; S-1 states. In addition, the two-photon absorption cross-section values of para-substituted HBCs are significantly larger than those of ortho-and meta-substituted HBCs.

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  121. Synthesis of highly distorted π-extended [2.2]metacyclophanes by intermolecular double oxidative coupling Reviewed International journal

    Yutaro Koyama, Satoru Hiroto, Hiroshi Shinokubo

    Angewandte Chemie - International Edition   Vol. 52 ( 22 ) page: 5740 - 5743   2013

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    A strained relationship: Oxidation of dihydroxy-substituted acenes provides face-to-face [2.2]metacyclophane-like dimers (see scheme
    Ored, Si of iPr 3Si groupsblue). The products exhibited highly distorted structures caused by steric repulsion. UV/Vis and electrochemical analysis revealed that the HOMO-LUMO gap was decreased upon dimerization. Copyright © 2013 WILEY-VCH Verlag GmbH &amp
    Co. KGaA, Weinheim.

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  122. Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins Reviewed International journal

    Ayaka Yamaji, Satoru Hiroto, Ji-Young Shin, Hiroshi Shinokubo

    Chemical Communications   Vol. 49 ( 44 ) page: 5064 - 5066   2013

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    Treatment of meso-mesityl 5,15-diazaporphyrin with alkyllithiums in toluene at low temperature provided monoalkylated diazachlorins through highly regioselective nucleophilic addition at the β-position near the meso-nitrogen atom. © The Royal Society of Chemistry 2013.

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  123. Assembled structures of dipyrrins and their oligomers bridged by dioxy-boron moieties Reviewed International journal

    Hiromitsu Maeda, Yuki Nishimura, Satoru Hiroto, Hiroshi Shinokubo

    DALTON TRANSACTIONS   Vol. 42 ( 45 ) page: 15885 - 15888   2013

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    A linear arrangement of BODIPY dimers and trimers was transformed into boron-bridged box, ladder and cage structures on treatment with spacer units possessing multiple diol moieties.

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  124. meso-Thiaporphyrinoids Revisited: Missing of Sulfur by Small Metals Reviewed International journal

    Hiroki Kamiya, Takeshi Kondo, Takafumi Sakida, Shigeru Yamaguchi, Hiroshi Shinokubo

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 18 ( 50 ) page: 16129 - 16135   2012.12

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    Facile synthesis of meso-aryl-substituted 5,15-dithiaporphyrins and 10-thiacorroles has been achieved by sulfidation of a,a'-dichlorodipyrrin metal complexes with sodium sulfide in DMF. Thiacorrole metal complexes exhibit distinct aromaticity due to 18?p-conjugation including the lone pair on sulfur, whereas dithiaporphyrins are nonaromatic judging from 1H NMR spectra, X-ray analysis, and absorption spectra. We have found that NiII and AlIII dithiaporphyrin complexes undergo smooth thermal sulfur extrusion reaction to give the corresponding thiacorrole complexes, whereas free base, ZnII, PdII, and PtII dithiaporphyrin complexes did not exhibit the similar reactivity. The DFT calculations have elucidated a reaction pathway involving an episulfide intermediate, which can explain the markedly different reactivity among dithiaporphyrin metal complexes.

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  125. Synthesis of Oxygen-Substituted Hexa-peri-hexabenzocoronenes through Ir-Catalyzed Direct Borylation Reviewed International journal

    Ryuichi Yamaguchi, Satoru Hiroto, Hiroshi Shinokubo

    ORGANIC LETTERS   Vol. 14 ( 10 ) page: 2472 - 2475   2012.5

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    Direct C-H borylation of hexa-peri-hexabenzocoronenes (HBCs) has been achieved under iridium catalysis, which allows efficient synthesis of hydroxy-substituted HBCs by oxidation of the boryl groups. Further oxidation of dihydroxy HBC with phenyliodine bis(trifluoroacetate) (PIFA) afforded tetraoxo-substituted HBC without any regioisomers, which can be considered as a pi-extended quinone.

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  126. Synthesis of Nickel(II) Azacorroles by Pd-Catalyzed Amination of a,a'-Dichlorodipyrrin NiII Complex and Their Properties Reviewed International journal

    Miki Horie, Yosuke Hayashi, Shigeru Yamaguchi, Hiroshi Shinokubo

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 18 ( 19 ) page: 5919 - 5923   2012.5

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    Synthesis of nickel(II) complexes of meso-aryl-substituted azacorroles was performed by BuchwaldHartwig amination of a dipyrrin NiII complex with benzylamine through C?N and C?C coupling. The highly planar structure of NiII azacorroles was elucidated by X-ray diffraction analysis. 1H NMR analysis and nucleus independent chemical shift (NICS) calculation on NiII azacorrole revealed its distinct aromaticity with [17]triaza-annulene 18p conjugation. In addition, acylation of azacorrole selectively afforded N- and C-acylated azacorroles depending on the reaction conditions, showing the dual reactivity of azacorroles.

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  127. Energy and Electron Transfer from Fluorescent Mesostructured Organosilica Framework to Guest Dyes Reviewed International journal

    Norihiro Mizoshita, Ken-ichi Yamanaka, Satoru Hiroto, Hiroshi Shinokubo, Takao Tani, Shinji Inagaki

    LANGMUIR   Vol. 28 ( 8 ) page: 3987 - 3994   2012.2

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    Energy and electron transfer from frameworks of nanoporous or mesostructured materials to guest species in the nanochannels have been attracting much attention because of their increasing availability for the design and construction of solid photofunctional systems, such as luminescent materials, photovoltaic devices, and photocatalysts. In the present study, energy and electron-transfer behavior of dye-doped periodic mesostructured organosilica films with different host-guest arrangements were systematically examined. Fluorescent tetraphenylpyrene (TPPy)-silica mesostructured films were used as a host donor. The location of guest perylene bisimide (PBI) dye molecules, acting as an acceptor, could be controlled on the basis of the molecular design of the PBI substituent groups. PBI dyes with bulky substituents and polar anchoring groups were located at the pore surface with low self-aggregation, which induced efficient energy or electron transfer because of the close host-guest arrangement. However, PBI dye with bulky and hydrophobic substituents was located in the center of template surfactant micelles; the fluorescence emission from the host TPPy groups was hardly quenched when the host-guest distance was longer than the critical Forster radius (ca. 4.5 nm). The relationship between the energy or electron-transfer efficiency and the location of guest species in the channels of mesostructured organosilica was first revealed by molecular design of the PBI substituents.

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  128. Facile Synthesis of Biphenyl-Fused BODIPY and Its Property Reviewed International journal

    Yosuke Hayashi, Naoki Obata, Masatomo Tamaru, Shigeru Yamaguchi, Yutaka Matsuo, Akinori Saeki, Shu Seki, Yuka Kureishi, Shohei Saito, Shigehiro Yamaguchi, Hiroshi Shinokubo

    ORGANIC LETTERS   Vol. 14 ( 3 ) page: 866 - 869   2012.2

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    A biphenyl-fused BODIPY was synthesized through a facile oxidative cyclization of peripheral aryl-substituents at the beta-position of the BODIPY unit. The extended pi-system of the fused BODIPY induces near-infrared (NIR) absorption and strong pi-pi interactions in the solid state. These features are beneficial for the application of the dye as a functional material. The biphenyl-fused BODIPY dye was demonstrated to exhibit photocurrent conversion ability on the basis of its n-type semiconducting property.

    DOI: 10.1021/ol2033916

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  129. Ensemble and Single-Molecule Spectroscopic Study on Excitation Energy Transfer Processes in 1,3-Phenylene-Linked Perylenebisimide Oligomers Reviewed International journal

    Hee Won Bahng, Min-Chul Yoon, Ji-Eun Lee, Yuichi Murase, Tomoki Yoneda, Hiroshi Shinokubo, Atsuhiro Osuka, Dongho Kim

    JOURNAL OF PHYSICAL CHEMISTRY B   Vol. 116 ( 4 ) page: 1244 - 1255   2012.2

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    1,3-Phenylene-bridged perylenebisimide dimer (PBI2) and trimer (PBI3) were prepared along with monomer reference (PBI1) using perylene imide-anhydride 5 as a key precursor. 3,3-Dimethylbut-1-ylsubstituents were introduced at the 2,5-positions of perylenebisimide (PBI) to improve the solubilities of PBI oligomers. Actually, no serious aggregation of PBI2 and PBI3 was detected in their dilute CH2Cl2 solutions. Under these conditions, intramolecular electronic interactions among PBI chromophores have been revealed by measuring the photophysical properties at their ensemble and single-molecule levels. The excitation energy transfer times of PBI2 (0.16 ps) and PBI3 (0.60 ps) were determined from the two different observables, anisotropy depolarization, and singlet-singlet annihilation, respectively, which are considered as the incoherent Forster-type energy hopping (EEH) times as compared with the EEH time constant (1.97 ps) calculated on the basis of the Forster mechanism. The relatively short EEH times compared to similar PBI oligomers can be attributed to 1,3-phenylene linker, which assures a short distance between the chromophores and, as a consequence, makes it hard to treat the PBI unit as a point dipole. The limitation of point-dipole approximation to describe the PBI oligomers and additional through-bond type interactions can be attributed as the causes of the discrepancies in excitation energy transfer times. Considering these photophysical properties, we can suggest that 1,3-phenylene-linked PBI oligomers have potentials as molecular photonic devices including the artificial light-harvesting system.

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  130. Synthesis and oxidation of cyclic tetraindole Reviewed International journal

    Shoichi Nakamura, Satoru Hiroto, Hiroshi Shinokubo

    CHEMICAL SCIENCE   Vol. 3 ( 2 ) page: 524 - 527   2012

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    A cyclic indole tetramer has been synthesized via an iridium-catalysed C-H borylation-cross coupling sequence. The tetraindole has a highly distorted structure, but can be oxidized with bromine and water into a highly planar macrocycle. The oxidized macrocycle can capture metal ions in its inner cavity as a novel porphyrin analogue, accompanied by a significant colour change from purple to blue or black.

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  131. Mesoporous Organosilica Hybrids Consisting of Silica-Wrapped p-p Stacking Columns Reviewed International journal

    Norihiro Mizoshita, Takao Tani, Hiroshi Shinokubo, Shinji Inagaki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51 ( 5 ) page: 1156 - 1160   2012

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    DOI: 10.1002/anie.201105394

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  132. A meso-Spiro[Cyclopentadiene-Isoporphyrin] from a Phenylethynyl Porphyrin Platinum(II) Pincer Complex Reviewed International journal

    Shoma Anabuki, Hiroshi Shinokubo, Naoki Aratani, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51 ( 13 ) page: 3174 - 3177   2012

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    DOI: 10.1002/anie.201109091

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  133. Oxidative Annulation of ss-Aminoporphyrins into Pyrazine-Fused Diporphyrins Reviewed International journal

    Masanari Akita, Satoru Hiroto, Hiroshi Shinokubo

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51 ( 12 ) page: 2894 - 2897   2012

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    DOI: 10.1002/anie.201108037

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  134. Gram-Scale Synthesis of Nickel(II) Norcorrole: The Smallest Antiaromatic Porphyrinoid Reviewed International journal

    Tomohiro Ito, Yosuke Hayashi, Soji Shimizu, Ji-Young Shin, Nagao Kobayashi, Hiroshi Shinokubo

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51 ( 34 ) page: 8542 - 8545   2012

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    DOI: 10.1002/anie.201204395

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  135. Intermolecular Oxidative Annulation of 2-Aminoanthracenes to Diazaacenes and Aza[7]helicenes Reviewed International journal

    Kiyohiko Goto, Ryuichi Yamaguchi, Satoru Hiroto, Hiroshi Ueno, Tsuyoshi Kawai, Hiroshi Shinokubo

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51 ( 41 ) page: 10333 - 10336   2012

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    DOI: 10.1002/anie.201204863

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  136. Functionalization of a Simple Dithienylethene via Palladium-Catalyzed Regioselective Direct Arylation Reviewed International journal

    Hiroki Kamiya, Shuichi Yanagisawa, Satoru Hiroto, Kenichiro Itami, Hiroshi Shinokubo

    ORGANIC LETTERS   Vol. 13 ( 24 ) page: 6394 - 6397   2011.12

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    The direct arylation on the thienyl groups of a diarylethene with various aryl iodides efficiently provided arylated dithienylethenes under palladium catalysis. Unsymmetrically substituted dithienylethenes were also synthesized by this protocol. This procedure allows a rapid access to a variety of aryl-substituted dithienylethenes from a single substrate of a simple dithienylethene.

    DOI: 10.1021/ol2026069

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  137. A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction Reviewed International journal

    Jianxin Song, Shoma Anabuki, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY LETTERS   Vol. 40 ( 9 ) page: 902 - 903   2011.9

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    A meso-to-beta directly linked hexameric porphyrin triangle was synthesized by the Suzuki-Miyaura cross-coupling reaction via either one-pot or a stepwise route. Hexakis-zine(II) complex of the porphyrin triangle exhibits a split Soret band in the absorption spectrum, reflecting the effective exciton coupling over the whole molecule.

    DOI: 10.1246/cl.2011.902

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  138. Synthetic Protocol for Diarylethenes through Suzuki-Miyaura Coupling Reviewed

    Satoru Hiroto, Katsuya Suzuki, Hiroki Kamiya, and Hiroshi Shinokubo

    Chem. Commun.   Vol. 47 ( 25 ) page: 7149-7151   2011.5

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  139. Synthesis of Directly Connected BODIPY Oligomers through Suzuki-Miyaura Coupling Reviewed

    Yosuke Hayashi, Shigeru Yamaguchi, Won Young Cha, Dongho Kim, and Hiroshi Shinokubo

    Org. Lett.   Vol. 13 ( 12 ) page: 2992-2995   2011.5

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  140. Iridium-Catalyzed Direct Tetraborylation of Perylene Bisimides Reviewed

    Takuro Teraoka, Satoru Hiroto, and Hiroshi Shinokubo

    Org. Lett.   Vol. 13 ( 10 ) page: 2532-2535   2011.4

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  141. Metal-Mediated Synthesis of Antiaromatic Porphyrinoids from a BODIPY Precursor Reviewed

    Takafumi Sakida, Shigeru Yamaguchi, and Hiroshi Shinokubo

    Angew. Chem., Int. Ed.   Vol. 50 ( 10 ) page: 2280-2283   2011.2

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  142. A beta-to-beta 2,5-Thienylene-Bridged Cyclic Porphyrin Tetramer: Its Rational Synthesis and 1:2 Binding Mode with C60 Reviewed

    Jianxin Song, Naoki Aratani, Hiroshi Shinokubo, and Atsuhiro Osuka

    Chem. Sci.   Vol. 2 ( 4 ) page: 748-751   2011.1

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  143. Peripherally Cyclometalated Iridium Complexes of Dipyridylporphyrin Reviewed

    Keita Yoshida, Takumi Nakashima, Shigeru Yamaguchi, Atsuhiro Osuka and Hiroshi Shinokubo

    Dalton Trans.     page: in press   2011

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  144. Synthesis of a Diimidazolylporphyrin Pincer Palladium Complex Reviewed

    Jun Yamamoto, Tomohiro Shimizu, Shigeru Yamaguchi, Naoki Aratani, Hiroshi Shinokubo and Atsuhiro Osuka

    J. Porphyrins Phthalocyanines     page: in press   2011

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  145. Pyrrole-Bridged Porphyrin Nanorings Reviewed

    Jianxin Song, Naoki Aratani, and Hiroshi Shinokubo, Atsuhiro Osuka

    Chem. Eur. J.   Vol. 16 ( 45 ) page: 13320-13324   2010.11

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  146. A Porphyrin Nanobarrel that Encapsulates C60 Reviewed

    Jianxin Song, Naoki Aratani, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 132 ( 46 ) page: 16356-16357   2010.10

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  147. Platinum(II) and Platinum(IV) Porphyrin Pincer Complexes: Synthesis, Structures, and Reactivity Reviewed International journal

    Keita Yoshida, Shigeru Yamaguchi, Atsuhiro Osuka, Hiroshi Shinokubo

    ORGANOMETALLICS   Vol. 29 ( 17 ) page: 3997 - 4000   2010.9

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    Pt(II)and Pt(IV)porphyrin pincer complexes were synthesized and characterized. Their structures and electronic properties were influenced by the valence state of platinum at the outer coordination site. The considerable distortion in the porphyrin core of the Pt(II) complex was relieved in the Pt(IV) complex, due to the change of the coordination geometry of platinum. Oxidation of the phenylplatinum(II) pincer complex with iodine induced a facile carbon carbon bond formation reaction at the meso position via reductive elimination.

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  148. Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures Reviewed

    Jianxin Song, Naoki Aratani, Ji Haeng Heo, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 132 ( 34 ) page: 11868-11869   2010.9

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  149. eta(2)-Porphyrin Ru(II) pi Complexes Reviewed International journal

    Shigeru Yamaguchi, Hiroshi Shinokubo, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 132 ( 29 ) page: 9992 - 9993   2010.7

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    Highly stable eta(2)-porphyrin Ru(II) pi complexes have been synthesized. The formation of the eta(2) pi it bond has been facilitated through pi-pi stacking interactions between the porphyrin and the planar ligand on Ru. pi coordination of ruthenium to porphyrin results in dramatic changes in the aromaticity and electronic properties. These properties are controllable via fine-tuning of the ligand on ruthenium.

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  150. A Stable Non-Kekule Singlet Biradicaloid from meso-Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1) Reviewed International journal

    Taro Koide, Ko Furukawa, Hiroshi Shinokubo, Jae-Yoon Shin, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 132 ( 21 ) page: 7246 - +   2010.6

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    A meso,meso-diketohexaphyrin was isolated and characterized as a chemically stable non-Kekule singlet biradicaloid. Two unpaired electrons are seemingly delocalized on two tripyrrolic units separated by C=O bonds. These results underscore the potential of expanded porphyrins to achieve unique electronic states.

    DOI: 10.1021/ja101040s

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  151. Synthesis of meso,meso'-Pyrrole-Bridged Diporphyrins by Cu(I)-Mediated Annulation Reviewed

    Chihiro Maeda, Hiroshi Shinokubo, and Atsuhiro Osuka

    Org. Lett.   Vol. 12 ( 8 ) page: 1820-1823   2010.4

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  152. Porphyrin "Lego Block" Strategy To Construct Directly meso-beta Doubly Linked Porphyrin Rings Reviewed

    Jianxin Song, Naoki Aratani, Pyosang Kim, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 49 ( 21 ) page: 3617-3620   2010.4

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  153. Large Porphyrin Squares from the Self-Assembly of meso-Triazole-Appended L-Shaped meso-meso-Linked ZnII-Triporphyrins: Synthesis and Efficient Energy Transfer Reviewed

    Chihiro Maeda, Pyosang Kim, Sung Cho, Jong Kang Park, Jong Min Lim, Dongho Kim, Josh Vura-Weis, Michael R. Wasielewski, and Hiroshi Shinokubo, Atsuhiro Osuka

    Chem. Eur. J.   Vol. 16 ( 17 ) page: 5052-5061   2010.3

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  154. Excess Polarizability Reveals Exciton Localization/Delocalization Controlled by Linking Positions on Porphyrin Rings in Butadiyne-Bridged Porphyrin Dimers Reviewed

    Chunxing She, Shanmugam Easwaramoorthi, Pyosang Kim, Satoru Hiroto, Ichiro Hisaki, Hiroshi Shinokubo, Atsuhiro Osuka, Dongho Kim and Joseph T. Hupp

    J. Phys. Chem. A   Vol. 114 ( 10 ) page: 3384-3390   2010.3

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  155. Strategic Synthesis of 2,6-Pyridylene-Bridged β-to-β Porphyrin Nanorings through Cross-Coupling Reviewed

    Jianxin Song, Pyosang Kim, Naoki Aratani, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Chem. Eur. J.   Vol. 16 ( 10 ) page: 3009-3012   2010.2

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  156. Bithiophene-Porphyrin Hybrid Nanorings Reviewed

    Kenta Osawa, Jianxin Song, Ko Furukawa, Hiroshi Shinokubo, Naoki Aratani, and Atsuhiro Osuka

    Chem. Asian J.   Vol. 5 ( 4 ) page: 764-767   2010.1

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  157. A Stable Organic Radical Delocalized on a Highly Twisted pi System Formed Upon Palladium Metalation of a Mobius Aromatic Hexaphyrin Reviewed International journal

    Harapriya Rath, Sumito Tokuji, Naoki Aratani, Ko Furukawa, Jong Min Lim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 49 ( 8 ) page: 1489 - 1491   2010

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    DOI: 10.1002/anie.200906017

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  158. Doubly beta-Functionalized Meso-Meso Directly Linked Porphyrin Dimer Sensitizers for Photovoltaics Reviewed International journal

    Jong Kang Park, Jinping Chen, Hye Ryun Lee, Sun Woo Park, Hiroshi Shinokubo, Atsuhiro Osuka, Dongho Kim

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 113 ( 52 ) page: 21956 - 21963   2009.12

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    Novel meso-meso directly linked porphyrin dinners tethered at beta-pyrrolic positions of the porphyrin ring with 2-propenoic acids or 2,4-pentadienoic acids were prepared for sensitization of nanocrystalline titanium dioxide solar cells. Most importantly, the absorption spectra of dimeric porphyrins were notably extended into the midvisible region in the solar spectrum while the LUMO levels are sufficiently high to inject electrons to the conduction band of TiO2. Among these dimers, PEG-2b-bd-Zn2 dimer, bearing a poly(ethylene glycol) end group at one meso position, showed the highest incident photon-to-photocurrent generation with 47% efficiency at the Soret region as well as the power conversion efficiency of 4.2% under standard AM 1.5 solar condition. To elucidate electronic structures and excited-state properties, UV-vis absorption and emission, cyclic voltammetry measurements, and density functional theory Calculations were performed. To Our best knowledge, the obtained conversion efficiency of 4.2% from PEG-2b-bd-Zn2-sensitized DSSC is the highest photovoltaic performance among DSSCs based on oligomeric porphyrins. Thus, this work suggests that the wide spectral response of directly linked porphyrin dimers due to the excitonic coupling is an intriguing aspect of directly linked pophyrin dimers to be utilized for DSSCs and gives an insight into the design of more efficient light-harvesting molecules.

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  159. Synthesis of Arylated Perylene Bisimides through C-H Bond Cleavage under Ruthenium Catalysis Reviewed

    Satomi Nakazono, Shanmugam Easwaramoorthi, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Org. Lett.   Vol. 11 ( 23 ) page: 5426-5429   2009.12

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  160. meso,meso '-Bis(5-azaindol-2-yl)-Appended meso-meso-Linked Zn(II) Diporphyrin: A Discrete Fluorescent Assembly Reviewed International journal

    Chihiro Maeda, Hiroshi Shinokubo, Atsuhiro Osuka

    ORGANIC LETTERS   Vol. 11 ( 22 ) page: 5322 - 5325   2009.11

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    Cu(II)-catalyzed intramolecular cyclization of meso-(4-aminopyrid-3-yl)ethynyl Zn(II) porphyrin provided meso-(5-azaindol-2-yl)-substituted Zn(II) porphyrin. meso,meso'-Bis(5-azaindol-2-yl)-substituted diporphyrin 7 was similarly prepared and was found to form a fluorescent trimeric prismatic assembly consisting of single atropisomer 7(in-in).

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  161. Palladium-Catalyzed Dimerization of meso-Bromoporphyrins: Highly Regioselective meso-beta Coupling through Unprecedented Remote C-H Bond Cleavage Reviewed International journal

    Sumito Tokuji, Taiga Yurino, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 15 ( 45 ) page: 12208 - 12211   2009.10

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    DOI: 10.1002/chem.200902143

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  162. Regioselective Ru-Catalyzed Direct 2,5,8,11-Alkylation of Perylene Bisimides Reviewed

    Satomi Nakazono, Yusuke Imazaki, Hyejin Yoo, Jaesung Yang, Takahiro Sasamori, Norihiro Tokitoh, Tassel Cédric, Hiroshi Kageyama, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Chem. Eur. J.   Vol. 15 ( 31 ) page: 7530-7533   2009.7

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  163. Porphyrin Derivatives with Carbon-Metal Bonds Reviewed

    Satoru Hiroto, Shigeru Yamaguchi, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Synth. Org. Chem. Jpn.   Vol. 67 ( 7 ) page: 688-700   2009.7

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  164. Unusual Interchromophoric Interactions in beta,beta ' Directly and Doubly Linked Corrole Dimers: Prohibited Electronic Communication and Abnormal Singlet Ground States Reviewed International journal

    Sung Cho, Jong Min Lim, Satoru Hiroto, Pyosang Kim, Hiroshi Shinokubo, Atsuhiro Osuka, Dongho Kim

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 131 ( 18 ) page: 6412 - 6420   2009.5

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    Directly and doubly beta,beta'-linked corrole dimers (DH3CD, DH2CD, and DZnCD) are excellent platforms for the investigation of intercorrole interactions because of their enforced coplanar geometries and short edge-to-edge distances. Through the use of these molecules along with the reference monomer H3CM and the singly beta,beta'-linked corrole dimer SH3CD, the intercorrole interactions have been systematically studied by density functional theory calculations, ultrafast photophysical measurements, and two-photon absorption measurements. A particular focus was placed on revealing factors that are important for the induced photophysical properties of the doubly linked corrole dimers compared with corrole monomer. In the doubly linked corrole dinners, strong molecular orbital interactions caused by the coplanar geometry and the short interchromophoric distance give rise to perturbations of the electronic states that are responsible for the red-shifted and intensified Q-like band in DH3CD and the broad NIR absorption bands and fast excitation-energy relaxation processes in DH2CD and DZnCD. On the other hand, electronic communication between corrole units is prohibited by the structurally constrained octagonal core in the center, so each constituent corrole unit in the doubly linked corrole dimers maintains an intrinsic pi-conjugation system. Consequently, the overall aromaticity of the directly linked corrole dimers can be explained in terms of a linear sum of two constituent corrole monomers, and the singlet biradical character of DH2CD and DZnCD can be understood in terms of two unpaired electrons (one from each constituent oxidized corrole monomer) and their appropriate interaction. In addition, the nonlinear optical properties of DH2CD and DZnCD with singlet biradical character have been confirmed to be significantly enhanced compared with those of closed-shell DH3CD. Collectively, double beta,beta'-linkages of corroles provide the coplanar geometry with a short interchromophoric distance and the strained octagonal core that play key roles in allowing the strong molecular orbital interactions and restricting the electronic communication between the two corroles, respectively.

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  165. Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Huckel aromatic-antiaromatic interconversion Reviewed International journal

    Harapriya Rath, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMICAL COMMUNICATIONS   ( 25 ) page: 3762 - 3764   2009.5

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    Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)(2)](2) resulted in the formation of an antiaromatic bis-Rh(I) complex, which can be oxidized to an aromatic bis-Rh(I) complex with retention of its rectangular structure.

    DOI: 10.1039/b905859a

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  166. Functionalization of Boron Dipyrrin (BODIPY) Dyes through Iridium and Rhodium Catalysis: A Complementary Approach to alpha- and beta-Substituted BODIPYs Reviewed International journal

    Jinping Chen, Masatoshi Mizumura, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 15 ( 24 ) page: 5942 - 5949   2009.5

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    Iridium-catalyzed direct borylation has been applied to meso-substituted dipyrromethane and boron dipyrrin (BODIPY) dyes. Borylation is highly regioselective and complementary: it occurs exclusively at the alpha position for meso-mesityldipyrromethane and at the beta positions for meso-mesityl BODIPY dye. This regioselective borylation enables a variety of alpha- and beta-substituted BODIPY dyes to be synthesized. Introduction of alpha,beta-enoate and alpha,beta,gamma,delta-dienoate functions into BODIPY dyes at the alpha or beta positions was achieved by rhodium-catalyzed Heck-type addition of the borylated compounds to acrylate and 2,4-pentadienoate esters. This functionalization has a significant effect on the electronic properties of BODIPY dyes, as seen in substantial redshift of the absorption and emission spectra. Comparative studies showed that the alpha- and beta-substituted series of BODIPY dyes show substantially different photophysical properties, and thus the importance of the position to be functionalized is highlighted.

    DOI: 10.1002/chem.200802541

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  167. Metathesis-like Splitting Reactions of Metallated [36]Octaphyrins(1.1.1.1.1.1.1.1): Experimental and Computational Investigations Reviewed International journal

    Yasuo Tanaka, Hiroshi Shinokubo, Yosuke Yoshimura, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 15 ( 23 ) page: 5674 - 5685   2009.4

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    meso-Octakis(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) (1) is a figure-of-eight nonaromatic macrocycle that serves its a unique platform to induce a metathesis-like splitting reaction upon bis-Cu(II) metalation. To get a better understanding of this splitting reaction, we examined the metalation of 1 with several metal ions. In contrast with the smooth and quantitative splitting reaction of bis-Cu(II) complex 1-CuCu, free-base 1, mono-Cu(II) complex 1-Cu, and bis-Zi(II) complex 1-ZnZn do not undergo the splitting reaction. Mono-Con complex 1-Co was selectively produced from metalation with the Co(II) ion, from which hybrid complex 1-CoCu was synthesized. The hybrid complex 1-CoCu undergoes the splitting reaction to give 2-Co and 2-Cu quantitatively. Activation parameters of the splitting reactions were determined: E(a) = 104 kJ mol(-1), Delta H double dagger 101 kJ mol(-1), Delta S double dagger = -25.0 J mol(-1) K(-1), and Delta V double dagger = 18 cm(3)mol(-1) for 1-CuCu and E(a) = 105 kJ mol(-1), Delta H double dagger = 102 kJ mol(-1), and Delta S double dagger = -29.9 J mol(-1) K(-1) for 1-CoCu. A marked difference between the splitting reaction reactivity of 1-CuCu and 1-ZnZn has been examined by DFT calculations at the B3LYP/631SDD// B3LYP/LANL2DZ level, which revealed that the reaction proceeds through it stepwise route involving initial C1-C20 bond formation to give INT1 as the rate-determining step and subsequent C21-C40 bond formation to give a spirocyclobutane intermediate (INT2), followed by a radical reverse cycloaddition reaction to give two metalloporphyrins. Inherent instability of 1-CuCu, which may arise from its strongly distorted structure, was indicated to be a main factor in the smooth splitting reaction. Finally, a new bis-Pd(II) complex (5-PdPd) was isolated in the metalation of 1 with Pd(OAc)(2) in a 9:1 mixture of 2,2,2-trifluoroethanol and methanol as a manifestation of the transannular electronic interaction in metalated octaphyrin complexes. Collectively, these results underscore the importance of the transannular electronic interactions that are enhanced by metalation, depending upon the coordinated metal ions.

    DOI: 10.1002/chem.200900454

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  168. Conformational Changes of meso-Aryl Substituted Expanded Porphyrins upon Protonation: Effects on Photophysical Properties and Aromaticity Reviewed

    Jae-Yoon Shin, Jong Min Lim, Zin Seok Yoon, Kil Suk Kim, Min-Chul Yoon, Satoru Hiroto, Hiroshi Shinokubo, Soji Shimizu, Atsuhiro Osuka, and Dongho Kim

    J. Phys. Chem. B,   Vol. 113 ( 17 ) page: 5794–5802   2009.4

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  169. Post-Modification of meso-meso-Linked Porphyrin Arrays by Iridium and Rhodium Catalyses for Tuning of Energy Gap Reviewed International journal

    Jinping Chen, Naoki Aratani, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY-AN ASIAN JOURNAL   Vol. 4 ( 7 ) page: 1126 - 1133   2009.3

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    meso-meso-Linked diporphyrins fabricated with multiple unsaturated carboxylic acid groups are efficiently synthesized by the use of transition-metal catalysis. Iridium-catalyzed direct borylation of meso-meso-linked diporphyrins furnish multi-borylated diporphyrins with high regioselectivity. Then, the introduction of alpha,beta- or alpha,beta,gamma,delta-unsaturated ester functions to the diporphyrins is achieved through rhodium-catalyzed Heck-type addition of the borylated diporphyrins to acrylate or 2,4-pentadienoate esters. Saponification of the esters to the corresponding acids is accomplished in high yields. The post-modification of diporphyrin 6 smoothly provides a water-soluble multiporphyrin array 1 in 84% total yield in 3 steps. This functionalization significantly affects the electronic properties of the porphyrins, resulting in different energy levels of each porphyrin unit. The absorption and fluorescence spectra indicate efficient energy transfer in the porphyrin dimers.

    DOI: 10.1002/asia.200900053

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  170. First self-assembly study of large pi-conjugated corrole dimers on solid substrates Reviewed International journal

    Xinrui Miao, Aimei Gao, Zhuomin Li, Satoru Hiroto, Hiroshi Shinokubo, Atsuhiro Osuka, Wenli Deng

    APPLIED SURFACE SCIENCE   Vol. 255 ( 11 ) page: 5885 - 5890   2009.3

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    Our study focus on beta, beta'-doubly linked corrole dimers (CDs) on mica and Au(1 1 1) surface using samples prepared by the synthetic method described by Osuka group appeared on recent publication [S. Hiroto, K. Furukawa, H. Shinokubo, A. Osuka, J. Am. Chem. Soc. 128 (2006) 12380]. Atomic force microscopy (AFM) and scanning tunneling microscopy (STM) were used to investigate the self-assembled structure of corrole dimers adsorbed on mica and Au(1 1 1) surfaces respectively at room temperature in air. The CDs adopt a dissimilar adsorption modality due to the different surface free energy of the different substrates. These types of molecular layers provide a useful platform for the study of surface and interface phenomena outside a vacuum system. It is potentially useful for practical fabrication of molecular devices because of the simplicity of the sample preparation and the stability of the interface in ambient conditions. (C) 2009 Elsevier B. V. All rights reserved.

    DOI: 10.1016/j.apsusc.2009.01.026

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  171. Zwitterionic Corroles: Regioselective Nucleophilic Pyridination of a Doubly Linked Biscorrole Reviewed International journal

    Satoru Hiroto, Naoki Aratani, Naoki Shibata, Yoshiki Higuchi, Takahiro Sasamori, Norihiro Tokitoh, Hiroshi Shinokubo, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 48 ( 13 ) page: 2388 - 2390   2009.2

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    DOI: 10.1002/anie.200805674

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  172. Double Cleavage of sp(2) C-H and sp(3) C-H Bonds on One Metal Center: DMF-Appended Cyclometalated Platinum(II) and -(IV) Porphyrins Reviewed International journal

    Shigeru Yamaguchi, Hiroshi Shinokubo, Atsuhiro Osuka

    INORGANIC CHEMISTRY   Vol. 48 ( 3 ) page: 795 - 797   2009.2

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    DMF-appended cyclometalated platinum(II) and -(IV) porphyrins were synthesized via the double cleavage of sp(2) C-H and sp(3) C-H bonds on one platinum center.

    DOI: 10.1021/ic8019149

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  173. Adsorption Characteristic of Self-Assembled Corrole Dimers on HOPG Reviewed

    Xinrui Miao, Aimei Gao, Satoru Hiroto, Hiroshi Shinokubo, Atsuhiro Osuka, Hongliang Xina, and Wenli Deng

    Surf. Interface Anal.   Vol. 41   page: 225–230   2009.1

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  174. Synthesis of Norbornane-Bridged Diporphyrins via Palladium-Catalyzed [3+2] Annulation Strategy Reviewed International journal

    Masatoshi Mizumura, Hiroshi Shinokubo, Atsuhiro Osuka

    SYNTHESIS-STUTTGART   ( 1 ) page: 59 - 61   2009.1

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    The reaction of meso-bromoporphyrins with norbornene-fused porphyrins afforded novel norbornane-bridged diporphyrins in excellent yields via palladium-catalyzed [3+2] annulation reaction.

    DOI: 10.1055/s-0028-1083267

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  175. Marriage of porphyrin chemistry with metal-catalysed reactions Reviewed International journal

    Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMICAL COMMUNICATIONS   ( 9 ) page: 1011 - 1021   2009

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    The development of porphyrin synthesis by means of transition metal-catalyzed reactions is explored in this feature article. Porphyrins have been receiving much attention in a wide area of chemistry as functional dyes, non-linear optical materials, ligands for a variety of metals, structural motifs in supramolecules, and so forth. However, they have been merely recognized as a reaction substrate in transition metal-catalyzed transformations. Recently, application of such new methodologies to porphyrin synthesis has proven to be very powerful to create new types of porphyrinic compounds, which have their own intriguing structures and properties. New transformations on porphyrins via transition metal catalysis offer us prospects of new designs of architectures, thus facilitating further development of this important class of functional molecules.

    DOI: 10.1039/b817941g

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  176. Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin Reviewed International journal

    Sumito Tokuji, Yuji Takahashi, Hideyuki Shinmori, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMICAL COMMUNICATIONS   ( 9 ) page: 1028 - 1030   2009

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    The treatment of 3,5-dibenzoylporphyrins with ammonium acetate provided novel oxopyridochlorins as the first examples of pyridine-fused porphyrinoids, which displayed absorption bands reaching into the near IR region and an ability to sensitize singlet oxygen effectively.

    DOI: 10.1039/b819284g

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  177. Synthesis of Directly and Doubly Linked Dioxoisobacteriochlorin Dimers Reviewed International journal

    Satoru Hiroto, Ichiro Hisaki, Hiroshi Shinokubo, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 130 ( 48 ) page: 16172 - 16173   2008.12

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    Oxidation of 2,18-diborylporphyrin provided 2,18-dihydroxyporphyrin, which shows solvent-dependent keto-enol tautomerism and dimerization through hydrogen bonding interaction in solution. Further oxidation of 2,18-dihydroxyporphyrins afforded doubly and directly linked dioxoisobacteriochlorin face-to-face dimers.

    DOI: 10.1021/ja807659h

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  178. Pt(II)- and Pt(IV)-Bridged Cofacial Diporphyrins via Carbon-Transition Metal sigma-Bonds Reviewed International journal

    Shigeru Yamaguchi, Taisuke Katoh, Hiroshi Shinokubo, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 130 ( 44 ) page: 14440 - +   2008.11

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    A directly Pt(IV)-bridged cofacial diporphyrin has been synthesized by the cyclometalation reaction of beta-pyridylporphyrin with a Pt(IV) salt. Upon treatment with methylhydrazine, the Pt(IV) bridge is reduced to the Pt(II) center, resulting in a Pt(II)-bridged cofacial dimer with a helicity inversion of the complex as well as change in eletronic communication through the metal bridge.

    DOI: 10.1021/ja8066385

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  179. Unambiguous identification of Mobius aromaticity for meso-Aryl-substituted [28]hexaphyrins(1.1.1.1.1.1) Reviewed International journal

    Jeyaraman Sankar, Shigeki Mori, Shohei Saito, Harapriya Rath, Masaaki Suzuki, Yasuhide Inokuma, Hiroshi Shinokubo, Kil Suk Kim, Zin Seok Yoon, Jae-Yoon Shin, Jong Min Lim, Yoichi Matsuzaki, Osamu Matsushita, Atsuya Muranaka, Nagao Kobayashi, Dongho Kim, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 130 ( 41 ) page: 13568 - 13579   2008.10

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    meso-Aryl-substituted [28]hexaphyrins(1.1.1.1.1.1) have been examined by (1)H, (13)C, and (19)F NMR spectroscopies, UV-vis absorption spectroscopy, magnetic circular dichroism spectroscopy, and single-crystal X-ray diffraction analysis. All of these data consistently indicate that [28]hexaphyrins(1.1.1.1.1.1) in solution at 25 degrees C exist largely as an equilibrium among several rapidly interconverting twisted Mobius conformations with distinct aromaticities, with a small contribution from a planar rectangular conformation with antiaromatic character at slightly higher energy. In the solid state, [28]hexaphyrins(1.1.1.1.1.1) take either planar or Mobius-twisted conformations, depending upon the meso-aryl substituents and crystallization conditions, indicating a small energy difference between the two conformers. Importantly, when the temperature is decreased to -100 degrees C in THF, these rapid interconversions among Mobius conformations are frozen, allowing the detection of a single [28]hexaphyrin(1.1.1.1.1.1) species having a Mobius conformation. Detailed analyses of the solid-state Mobius structures of compounds 2b, 2c, and 2f showed that singly twisted structures are achieved without serious strain and that cyclic pi-conjugation is well-preserved, as needed for exhibiting strong diatropic ring currents. Actually, the harmonic-oscillator model for aromaticity (HOMA) values of these structures are significantly large (0.85, 0.69, and 0.71, respectively), confirming the first demonstration of stable Mobius aromatic systems consisting of free-base expanded porphyrins without the assistance of metal coordination.

    DOI: 10.1021/ja801983d

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  180. Photoelectrochemical Properties of Doubly beta-Functionalized Porphyrin Sensitizers for Dye-Sensitized Nanocrystalline-TiO2 Solar Cells Reviewed International journal

    Jong Kang Park, Hye Ryun Lee, Jinping Chen, Hiroshi Shinokubo, Atsuhiro Osuka, Dongho Kim

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 112 ( 42 ) page: 16691 - 16699   2008.10

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    Functionalized porphyrins at meso- and beta-positions with different carboxylic acid groups were prepared to investigate electronic and photovoltaic properties as dye-sensitized nanocrystalline-TiO2 solar cells. The electronic structures of the porphyrin macrocyclic core are strongly coupled with olefinic side chains so that the absorption spectrum exhibits largely broad and red-shifted Soret and Q-bands, especially up to 475 nm at the Soret band in a porphyrin doubly functionalized with malonic diacid groups. Among porphyrin derivatives prepared in this study, 2b-bdta-Zn exhibits the maximum overall conversion efficiency of 3.03% and the maximum incident photon to current efficiency of 60. 1% in the Soret band region, superior to the others. From such photovoltaic performances, we can suggest that multiple pathways through olefinic side chains at two beta-positions enhance the overall electron injection efficiency and the moderate distance between the porphyrin sensitizer and the TiO2 semiconductor layer is important, retarding the charge recombination processes. As a consequence, these combined effects give rise to higher photovoltaic efficiency in photovoltaic regenerative solar cells.

    DOI: 10.1021/jp804258q

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  181. 2,5-Thienylene-Bridged Triangular and Linear Porphyrin Trimers Reviewed

    Jianxin Song, So Young Jang, Shigeru Yamaguchi, Jeyaraman Sankar, Satoru Hiroto, Naoki Aratani, Jae-Yoon Shin, Shanmugam Easwaramoorthi, Kil Suk Kim, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 47   page: 6004-6007   2008.7

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  182. Synthesis of Novel Chiral Porphyrins through Pd-Catalyzed [3 + 2] Annulation and Heterochiral Self-Assembling to Form Heterodimers Reviewed

    Masatoshi Mizumura, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 47   page: 5387-5381   2008.6

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  183. Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1) Reviewed International journal

    Goro Mori, Hiroshi Shinokubo, Atsuhiro Osuka

    TETRAHEDRON LETTERS   Vol. 49 ( 13 ) page: 2170 - 2172   2008.3

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    Direct functionalization of aromatic substituents on [28]hexaphyrin was achieved by Ir-catalyzed borylation with the Smith-Miyaura-Hartwig protocol. High para. selectivity was observed in the reaction on 2,6-dichlorophenyl and 2,6-dimethoxyphenyl substituents of [28]hexaphyrin. The reaction with [26]hexaphyrin resulted only in reduction of the substrate to provide [28]hexaphyrin without borylation, thus highlighting the importance of the oxidation state of substrates in this catalytic transformation. The borylated hexaphyrin can be used for Suzuki-Miyaura cross-coupling reaction. (c) 2008 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.tetlet.2008.01.069

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  184. Dimeric assemblies from 1 2,3-triazole-appended Zn(II) porphyrins with control of NH-tautomerism in 1 2,3-triazole Reviewed International journal

    Chihiro Maeda, Shigeru Yamaguchi, Chusaku Ikeda, Hiroshi Shinokubo, Atsuhiro Osuka

    ORGANIC LETTERS   Vol. 10 ( 4 ) page: 549 - 552   2008.2

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    Cu(I)-catalyzed 1,3-dipolar cycloaddition of meso-ethynyl Zn(II) porphyrin with benzyl azide efficiently provides meso-1-benzyl-1H-1,2,3-triazolyl Zn(II) porphyrin, which assembles to form a slipped cofacial dimer by the complementary coordination of the triazole nitrogen atom at the 3-position to the zinc center of a second porphyrin moiety both in the solid and solution states. Removal of the benzyl protection and introduction of a 2-ethoxycarbonylphenyl moiety greatly stabilize the dimeric assembly through an additional hydrogen bonding interaction between the NH proton of 2H-1,2,3-triazole and the carbonyl oxygen.

    DOI: 10.1021/ol7028299

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  185. meso-Aryl Substituted Rubyrin and Its Higher Homologues: Structural Characterization and Chemical Properties Reviewed

    Soji Shimizu, Shohei Saito, Won-Seob Cho, Jonathan L. Sessler, Hiroshi Shinokubo, and Atsuhiro Osuka

    Chem. Eur. J.   Vol. 14 ( 9 ) page: 2668-2678   2008.2

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  186. Efficient Rhodium-Catalyzed installation of unsaturated ester functions onto porphyirins: Site-specific heck-type addition versus conjugate addition Reviewed International journal

    Hiromi Baba, Jinping Chen, Hiroshi Shinokubo, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 14 ( 14 ) page: 4256 - 4262   2008

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    A facile introduction of alpha,beta-or alpha,beta,gamma,delta-unsaturated ester functions onto porphyrins was achieved through rhodium-catalyzed addition of beta-borylporphyrins to acrylate or 2,4-pentadienoate esters. The reaction of meso-borylporphyrins with acrylates exclusively afforded saturated esters by 1,4-conjugate addition under the same re-mode (Heck-type versus conjugate addition) is highly dependent on the reaction site (beta versus meso). This functionalization has a significant impact on the electronic properties of the pi system of porphyrins, which induces a substantial redshift and broadening in the absorption spectra by effective conjugation through the beta positions. The coplanar structure of the unsaturated ester moieties with respect to the porphyrin core has been unambiguously elucidated by X-ray crystallographic analysis.

    DOI: 10.1002/chem.200701943

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  187. Metalation of expanded porphyrins: A chemical trigger used to produce molecular twisting and Mobius aromaticity Reviewed International journal

    Yasuo Tanaka, Shohei Saito, Shigeki Mori, Naoki Aratani, Hiroshi Shinokubo, Naoki Shibata, Yoshiki Higuchi, Zin Seok Yoon, Kil Suk Kim, Su Bum Noh, Jong Kang Park, Dongho Kim, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 47 ( 4 ) page: 681 - 684   2008

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    DOI: 10.1002/anie.200704407

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  188. Synthesis of meso-5-Azaindolyl Appended Zn(II) Porphyrins via Pd-Catalyzed Annulation Reviewed

    Chihiro Maeda, Hiroshi Shinokubo, and Atsuhiro Osuka

    Org. Lett.   Vol. 9 ( 13 ) page: 2493-2496   2007.6

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  189. Synthesis of Doubly β-to-β 1,3-Butadiyne-Bridged Diporphyrins: Enforced Planar Structures and Large Two-photon Absorption Cross Sections Reviewed

    Ichiro Hisaki, Satoru Hiroto, Kil Suk Kim, Su Bum Noh, Dongho Kim, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 46 ( 27 ) page: 5125-5128   2007.6

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  190. Regioselective Borylation of Porphyrins via C-H Bond Activation under Iridium Catalysis That Affords Useful Building Blocks for Porphyrin Assemblies Reviewed

    Hiroshi Hata, Shigeru Yamaguchi, Goro Mori, Satomi Nakazono, Taisuke Katoh, Keishi Takatsu, Satoru Hiroto, Hiroshi Shinokubo, and Atsuhiro Osuka

    Chem. Asian J.   Vol. 2 ( 7 ) page: 849-859   2007.5

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  191. Porphyrin Pincer Complexes: Peripherally Cyclometallated Porphyrins and Their Catalytic Activities Controlled by Central Metals Reviewed

    Shigeru Yamaguchi, Taisuke Katoh, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 129 ( 20 ) page: 6392-6393   2007.5

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  192. Facile Peripheral Functionalization of Porphyrins via Pd-Catalyzed [3 + 2] Annulation with Alkynes Reviewed

    Akhila K. Sahoo, Shigeki Mori, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 45 ( 47 ) page: 7972-7975   2006.11

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  193. Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers Reviewed

    Satoru Hiroto, Ko Furukawa, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 128 ( 38 ) page: 12380-12381   2006.9

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  194. Intermolecular Rhodium-Catalyzed Carbometallation-Heck-Type Reaction in Water Reviewed

    Takuya Kurahashi, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 45 ( 38 ) page: 6336-6338   2006.8

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  195. Synthesis of Brominated Directly Fused Diporphyrins through Gold(III)-Mediated Oxidation Reviewed

    Akhila K. Sahoo, Yasuyuki Nakamura, Naoki Aratani, Kil Suk Kim, Su Bum Noh, Hiroshi Shinokubo, Dongho Kim, and Atsuhiro Osuka

    Org. Lett.   Vol. 8 ( 18 ) page: 4141-4144   2006.8

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  196. Porphyrin Synthesis in Water Provides New Expanded Porphyrins with Direct Bipyrrole Linkages: Isolation and Characterization of Two Heptaphyrins Reviewed

    Satoru Hiroto, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 128 ( 20 ) page: 6568-6569   2006.5

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  197. A Directly Fused Tetrameric Porphyrin Sheet and Its Anomalous Electronic Properties That Arise from the Planar Cyclooctatetraene Core Reviewed

    Yasuyuki Nakamura, Naoki Aratani, Hiroshi Shinokubo, Akihiko Takagi, Tomoji Kawai, Takuya Matsumoto, Zin Seok Yoon, Deok Yun Kim, Tae Kyu Ahn, Dongho Kim, Atsuya Muranaka, Nagao Kobayashi, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 129 ( 12 ) page: 4119-4127   2006.3

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  198. Oxidation of gem-Borylsilylalkylcoppers to Acylsilanes with Air Reviewed

    Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 8 ( 6 ) page: 1185-1187   2006.3

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  199. Synthesis of Pyrrolidine-Fused [34]- and [36]Octaphyrins via 1,3-Dipolar Cycloaddition Reviewed

    Hiroshi Hata, Yiho Kamimura, Hiroshi Shinokubo, and Atsuhiro Osuka

    Org. Lett.   Vol. 8 ( 6 ) page: 1169-1172   2006.3

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  200. Oxidation of Hydroquinones with meso-Hexakispentafluorophenyl [26]hexaphyrin(1.1.1.1.1.1) Reviewed

    Chihiro Maeda, Hiroshi Shinokubo, and Atsuhiro Osuka

    Org. Biomol. Chem.   Vol. 4 ( 2 ) page: 200-202   2006.1

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  201. 1,2-Migration of Phosphorus-centered Anions on Ate-type Copper Carbenoids and Its Application for the Synthesis of New Potent Phosphine Ligands Reviewed

    Junichi Kondo, Hidenori Someya, Hidenori Kinoshita, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 7 ( 25 ) page: 5713-5715   2005.12

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  202. Importance of β-β Bond for Long-range Antiferromagnetic Coupling in Directly Linked Cu(II)- and Ag(II)-Diporphyrins Reviewed

    Takahisa Ikeue, Ko Furukawa, Hiroshi Hata, Naoki Aratani, Hiroshi Shinokubo, Tatsuhisa Kato and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 44 ( 42 ) page: 6899-6901   2005.10

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  203. Synthesis of Corrole Derivatives through Regioselective Ir-Catalyzed Direct Borylation Reviewed

    Satoru Hiroto, Ichiro Hisaki, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 44 ( 41 ) page: 6763-6766   2005.9

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  204. Intramolecular [4 + 2] Cycloadditions of Benzynes with Conjugated Enynes, Arenynes, and Dienes Reviewed

    Martin E. Hayes, Hiroshi Shinokubo, and Rick L. Danheiser

    Org. Lett.   Vol. 7 ( 18 ) page: 3917-3920   2005.9

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  205. Highly Regioselective Ir-Catalyzed beta-Borylation of Porphyrins via C-H Bond Activation and Construction of beta-beta Linked Diporphyrin Reviewed

    Hiroshi Hata, Hiroshi Shinokubo, and Atsuhiro Osuka

    J. Am. Chem. Soc.   Vol. 127 ( 23 ) page: 8264-8265   2005.6

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  206. A new method for the synthesis of acyltitanium complexes and their application to copper-mediated acylmetallation of carbon-carbon multiple bonds in aqueous media Reviewed

    Zhenfu Han, Takuma Fujioka, Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, andKoichiro Oshima

    Org. Biomol. Chem.   Vol. 3 ( 9 ) page: 1622-1623   2005.4

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  207. Preparation of α-silyl- or α,α-bis(silyl)-substituted alkylcopper reagents and their synthetic use Reviewed

    Junichi Kondo, Atsushi Inoue, Yuki Ito, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 61 ( 13 ) page: 3361-3369   2005.3

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  208. Synthesis of Medium- and Large-Sized Lactones in an Aqueous-Organic Biphasic System Reviewed

    Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 44 ( 16 ) page: 2397-2400   2005.3

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  209. Anthracene-Bridged Z-Shape [26]Hexaphyrin(1.1.1.1.1.1.1) Dimer from Regioselective Diels-Alder Reaction of Hexaphyrin with Bis-o-xylylene Equivalent Reviewed

    Hiroshi Hata, Hiroshi Shinokubo, and Atsuhiro Osuka

    Angew. Chem., Int. Ed.   Vol. 44 ( 6 ) page: 932-935   2004.12

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  210. Cobalt-Mediated Mizoroki-Heck-Type Reaction of Epoxide with Styrene Reviewed

    Yousuke Ikeda, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Adv. Synth. Catal.   Vol. 346 ( 13-15 ) page: 1631-1634   2004.12

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  211. Synthesis of Silyl Aziridines and α-Amino Acylsilanes with Silyldibromomethyllithium Reviewed

    Kazunari Yagi, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 6 ( 23 ) page: 4339-4341   2004.11

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  212. Water Enables Direct Use of Allyl Alcohol for Tsuji-Trost Reaction without Activators Reviewed

    Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 6 ( 22 ) page: 4085-4088   2004.10

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  213. Reaction of Silyldihalomethyllithiums with Nitriles. Formation of α-Keto Acylsilanes via Azirines and 1,3-Rearrangement of Silyl Group from C to N Reviewed

    Kazunari Yagi, Takayuki Tsuritani, Kazuaki Takami, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 126 ( 28 ) page: 8618-8619   2004.7

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  214. Hydrosilylation of Alkynes with a Cationic Rhodium Species Formed in Anionic Micellar System Reviewed

    Akinori Sato, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 6 ( 13 ) page: 2217-2220   2004.6

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  215. Transformation of Zirconocene-Olefin Complexes into Zirconocene Allyl Hydride and Their Use as Dual Nucleophilic Reagents: Reactions with Acid Chloride and 1,4-Diketone Reviewed

    Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 126 ( 21 ) page: 6776-6783   2004.6

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  216. Direct Preparation of Allylic Zirconium Reagents from Zirconocene-Olefin Complexes and Alkenes Reviewed

    Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 69 ( 10 ) page: 3302-3307   2004.5

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  217. Phosphane-Free Rhodium Catalyst in an Anionic Micellar System for [4+2] Annulation of Dienynes Reviewed

    Dai Motoda, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 43 ( 14 ) page: 1860-1862   2004.3

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  218. Boron Trifluoride-Catalyzed Reaction of Alkyl Fluoride with Silyl Enolate, Allylsilane, and Hydrosilane Reviewed

    Koji Hirano, Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo and Koichiro Oshima

    Tetrahedron Lett.   Vol. 45 ( 12 ) page: 2255-2257   2004.3

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  219. Transition Metal-Catalyzed Carbon-Carbon Bond Formation with Grignard Reagents - Novel Reactions with a Classic Reagent Invited Reviewed

    Hiroshi Shinokubo, and Koichiro Oshima

    Eur. J. Org. Chem.   ( 10 ) page: 2081-2091   2004.2

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  220. Disulfidation of Alkynes and Alkenes with Gallium Trichloride Reviewed

    Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 6 ( 4 ) page: 601-603   2004.2

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  221. Triethylborane-Induced Radical Allylation Reaction with Zirconocene-Olefin Complex Reviewed

    Koji Hirano, Kazuya Fujita, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 6 ( 4 ) page: 593-595   2004.2

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  222. Synthesis of Pyrimidines via Base-induced Condensation of α-Chloro Oxime Derivatives Reviewed

    Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   Vol. 33 ( 2 ) page: 122-123   2004.2

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  223. Synthesis of Cyclopropanes via Iodine-Magnesium Exchange between 3-Iodomethyl-1-oxacyclopentanes and Organomagnesium Reagents Invited Reviewed

    Takashi Tsuji, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 60 ( 4 ) page: 973-978   2004.1

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  224. Consecutive Double 1,2-Migration of Two Different Groups in Silyldichloromethylcuprates Reviewed

    Junichi Kondo, Yuki Ito, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 43 ( 1 ) page: 106-108   2003.12

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  225. Regioselective Allylmetallation of Allenes with Tetraallylmanganate or Allylmagnesium Chloride under MnCl2 Catalysis Reviewed

    Toshihiro Nishikawa, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 5 ( 24 ) page: 4623-4626   2003.11

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  226. Formation of Manganese-Alkyne Complexes Mediated by Trialkylmanganates and Their Application Reviewed

    Toshihiro Nishikawa, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 59 ( 48 ) page: 9661-9668   2003.11

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  227. Highly Diastereoselective Addition of Silyldihalomethyllithiums to Chiral Alkyl Esters Reviewed

    Hiroshi Shinokubo, Junichi Kondo, Atsushi Inoue and Koichiro Oshima

    Chirality   Vol. 15 ( 1 ) page: 31-37   2003.11

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  228. Base-Induced Condensation of α-Chloro Oxime Derivatives Furnishes Alkynes Reviewed

    Takayuki Tsuritani, Kazunari Yagi, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 42 ( 45 ) page: 5613-5615   2003.11

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  229. Cobalt Catalyzed Three-Component Coupling Reaction of Alkyl Halides, 1,3-Dienes, and Trimethylsilylmethylmagnesium Chloride Reviewed

    Keiya Mizutani, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 5 ( 21 ) page: 3959-3961   2003.10

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  230. Triethylborane-Mediated Hydrogallation and Hydroindation: Novel Access to Organogalliums and Organoindiums Reviewed

    Kazuaki Takami, Satoshi Mikami, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 68 ( 17 ) page: 6627-6631   2003.8

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  231. Triethylborane-Induced Radical Reactions with Gallium- and Indium Hydrides Reviewed

    Kazuaki Takami, Satoshi Mikami, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 59 ( 34 ) page: 6627-6635   2003.8

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  232. Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition in an Aqueous-Organic Biphasic System Reviewed

    Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 125 ( 26 ) page: 7784-7785   2003.7

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  233. Highly Diastereoselective Tandem Reduction-Allylation Reaction of 1,4-Diketones with Zirconocene-Olefin Complexes Reviewed

    Kazuya Fujita, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 42 ( 22 ) page: 2550-2552   2003.6

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  234. Et3B-Induced Radical Addition of N,N-Dichlorosulfonamide to Alkenes and Pyrrolidine Formation via Radical Annulation Reviewed

    Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 68 ( 8 ) page: 3246-3250   2003.4

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  235. Manganese-Catalyzed Carbomagnesation of Alkynes Invited Reviewed

    Hiroshi Shinokubo and Koichiro Oshima

    Catalysis Surveys from Asia   Vol. 7 ( 1 ) page: 39-46   2003.4

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  236. Development of Novel Synthetic Reactions with Organomagnesium Reagents Invited Reviewed

    Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    J. Synth. Org. Chem. Jpn.   Vol. 61 ( 4 ) page: 331-342   2003.4

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  237. From Alkenylsilanes to Ketones with Air as the Oxidant Reviewed

    Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed.   Vol. 42 ( 7 ) page: 825-827   2003.2

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  238. Oxidative Heck-Type Reaction involving Cleavage of a Carbon-Phosphorus Bond of Arylphosphonic Acids Reviewed

    Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 125 ( 6 ) page: 1484-1485   2003.2

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  239. Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo Carbonyl Compounds Reviewed

    Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 75 ( 12 ) page: 2687-2690   2002.12

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  240. Preparation of Allylic Germanes with Tri(2-furyl)germane via π-Allylpalladium Species Reviewed

    Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 11 ) page: 1916-1918   2002.11

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  241. Biaryl Synthesis from Two Different Aryl Halides with Tri(2-furyl)germane Reviewed

    Tomoaki Nakamura, Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 4 ( 18 ) page: 3165-3167   2002.9

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  242. Intramolecular Tandem Michael-Type Addition/Aldol Cyclization Induced by TiCl4-R4NX Combinations Reviewed

    Kazunari Yagi, Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 4 ( 18 ) page: 3111-3114   2002.9

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  243. Triethylborane Induced Radical Reaction of Gallium Enolates with α-Halo Esters Reviewed

    Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 75 ( 9 ) page: 2049-2052   2002.9

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  244. Efficient Pd(0)-Catalyzed Hydrosilylation of Alkynes with Triorganosilanes Reviewed

    Dai Motoda, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 9 ) page: 1529-1531   2002.9

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  245. Cyclization of 1,6-Enynes with Allylic Chromate Species Reviewed

    Toshihiro Nishikawa, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 4 ( 16 ) page: 2795-2797   2002.8

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  246. Reaction of α,α-Dibromo Oxime Ethers with Grignard Reagents: Alkylative Annulation Providing a Pyrimidine Core Reviewed

    Hirotada Kakiya, Kazunari Yagi, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 124 ( 31 ) page: 9032-9033   2002.8

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  247. A Room Temperature Kharasch Reaction Catalyzed by Pd(0) in a Heterogeneous Aqueous System Reviewed

    Dai Motoda, Hidenori Kinoshita, Hiroshi Shinokubo, Koichiro Oshima

    Advanced Synthesis and Catalysis   Vol. 344 ( 3, 4 ) page: 261-265   2002.6

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  248. Coupling of Vinylcyclopropanes with Aldehydes Induced by a TiCl4/n-Bu4NI Combination: Synthesis of Conjugated Dienols Reviewed

    Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 6 ) page: 978-980   2002.6

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  249. Synthetic Radical Reactions in Aqueous Media Invited Reviewed

    Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 5 ) page: 674-686   2002.5

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  250. Pd(0)-Catalyzed Reaction of Alkynes with Trifurylgermane and CO Providing Acylgermanes: Hydrometalcarbonylation of Alkynes Reviewed

    Hidenori Kinoshita, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 124 ( 16 ) page: 4220-4221   2002.4

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  251. Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species: Formation of Cyclopropane Derivatives Reviewed

    Shin-ichi Usugi, Takayuki Tsuritani, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 75 ( 4 ) page: 841-845   2002.4

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  252. Reactions of gem-Dibromo Compounds with Trialkylmagnesate Reagents Providing Alkylated Organomagnesium Compound Reviewed

    Atsushi Inoue, Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Eur. J.   Vol. 8 ( 7 ) page: 1730-1740   2002.3

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  253. Generation and Regioselective Reactions of alpha,alpha-Bis(silyl)-Substituted Allylcopper Reagents-Synthesis of 1,1-Disilylalkenes Reviewed

    Junichi Kondo, Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 43 ( 13 ) page: 2402   2002.3

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  254. Facile Synthesis of Ketones from 1,1-Disilylethenes via Oxidation of gem-Disilylalkanes Reviewed

    Atsushi Inoue, Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Commun.   ( 2 ) page: 114-115   2002.1

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  255. Allylation of Carbonyl Compounds with Allylic Gallium Reagents Reviewed

    Takashi Tsuji, Shin-ichi Usugi, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Chem. Lett.   ( 1 ) page: 2-3   2002.1

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  256. Synthesis of Trisubstituted and Tetrasubstituted Alkenes via a Manganate-Induced Migration-Elimination Process Reviewed

    Hirotada Kakiya, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 57 ( 51 ) page: 10063-10069   2001.12

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  257. Conversion of Acid Chloride into Homoallylic Alcohol via Allylic C-H Bond Activation of Alkene with a Zirconocene Complex Reviewed

    Kazuya Fujita, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 123 ( 48 ) page: 12115-12116   2001.12

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  258. Nucleophilic Addition of Tri-2-furylgermane to Aldehydes and α,β-Unsaturated Carbonyl Compounds in the Presence of a Catalytic Amount of Base Reviewed

    Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 57 ( 49 ) page: 9827-9836   2001.12

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  259. TiCl4-n-Bu4NX (X = I, Br, and Cl) Combination-Induced Coupling of alpha,beta-Unsaturated Ketones with Aldehydes Reviewed

    Zhenfu Han, Shigeki Uehira, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 66 ( 23 ) page: 7854-7857   2001.11

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  260. Triethylborane-Induced Bromine Atom-Transfer Radical Addition in Aqueous Media: Study of the Solvent Effect on Radical Addition Reaction Reviewed

    Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, Koichiro Oshima, Kiyoyuki Omoto, and Hiroshi Fujimoto

    J. Org. Chem.   Vol. 66 ( 23 ) page: 7776-7785   2001.11

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  261. Facile Synthesis of Acylsilanes via Aerobic Oxidation of gem-Disilylalkylcopper Compounds Reviewed

    Atsushi Inoue, Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 123 ( 44 ) page: 11109-11110   2001.11

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  262. Preparation of Organomanganese Reagents from Organic Halides with Activated Manganese Reviewed

    Hirotada Kakiya, Shinji Nishimae, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 57 ( 42 ) page: 8807-8815   2001.10

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  263. A Facile Synthesis of 1,1-Disilylethenes via Me3MgLi-Induced Monomethylation of Dibromodisilylmethanes Reviewed

    Atsushi Inoue, Junichi Kondo, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   ( 10 ) page: 956-957   2001.10

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  264. Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator in Aqueous Media: Facile Synthesis of γ-Lactones Reviewed

    Hideki Yorimitsu, Katsuyu Wakabayashi, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 74 ( 10 ) page: 1963-1970   2001.10

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  265. Selective Oxidation of Propargylic Alcohols into α,β-Acetylenic Aldehydes with TiCl4/Et3N System Reviewed

    Zhenfu Han, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 9 ) page: 1421-1422   2001.9

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  266. Radical [3 + 2] Annulation of N-Allyl-N-Chlorotosylamide with Alkenes via Atom-transfer Process Reviewed

    Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 3 ( 17 ) page: 2709-2711   2001.8

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  267. Remarkable Rate Acceleration of Pd(0)-Catalyzed Hydrogermylation of Alkynes and Dienes in Water Reviewed

    Hidenori Kinoshita, Tomoaki Nakamura, Hirotada Kakiya, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Org. Lett.   Vol. 3 ( 16 ) page: 2521-2524   2001.8

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  268. Radical Addition of Triphenylgermane to Vinyloxiranes: Its Application to Synthesis of 4-Vinyltetrahydro-2-furanones Reviewed

    Shinobu Tanaka, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Synlett   ( 8 ) page: 1278-1280   2001.8

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  269. Triethylborane-Induced Hydrogermylation of Alkenes with Tri-2-furylgermane Reviewed

    Tomoaki Nakamura, Shinobu Tanaka, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Computes Rendus Acad. Sci. Paris, Chimie   Vol. 4 ( 6 ) page: 461-470   2001.7

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  270. Palladium-Catalyzed Cross-Coupling Reaction of Organoindiums with Aryl Halides in Aqueous Media Reviewed

    Kazuaki Takami, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Org. Lett.   Vol. 3 ( 13 ) page: 1997-1999   2001.6

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  271. Selective Halogen-Magnesium Exchange Reaction via Organomagnesium Ate Complex Reviewed

    Atsushi Inoue, Kazuya Kitagawa, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 66 ( 12 ) page: 4333-4339   2001.6

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  272. Triethylborane-Induced Radical Reactions with Gallium Hydride Reagent HGaCl2Satoshi Mikami, Kazuya Fujita, Tomoaki Nakamura, Hideki Reviewed

    Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Org. Lett.   Vol. 3 ( 12 ) page: 1853-1855   2001.6

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  273. Alkylative Preparation of α-Silylalkylmagnesium from R3SiCHBr2 Using a Magnesate Reagent Reviewed

    Junichi Kondo, Atsushi Inoue, Hiroshi Shinokubo and Koichiro Oshima

    Angew. Chem., Int. Ed. Engl.   Vol. 40 ( 11 ) page: 2085-2087   2001.5

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  274. Novel [2 + 2 + 2]Annulation of 1,6-Diynes Mediated by Methallylchromate or Methallylmagnesium Chloride under CrCl3 Catalysis Reviewed

    Toshihiro Nishikawa, Hirotada Kakiya, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 123 ( 19 ) page: 4629-4630   2001.5

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  275. Reduction of Organic Halides with Tri-2-furylgermane: Stoichiometric and Catalytic Reduction Reviewed

    Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 74 ( 4 ) page: 747-752   2001.4

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  276. Stereospecific or Stereoselective Elimination of Vicinal-Alkoxyiodoalkanes by Means of Organometallic Reagents Reviewed

    Hiroshi Shinokubo and Koichiro Oshima

    Synlett   ( 3 ) page: 322-328   2001.3

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  277. Enolate Formation from Cyclopropyl Ketones via Iodide-Induced Ring Opening and Its Use for Stereoselective Aldol Reaction Reviewed

    Zhenfu Han, Shigeki Uehira, Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 57 ( 6 ) page: 987-995   2001.2

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  278. Iodotrimethylsilane-Induced Cyclization of 6-Alkynal Acetals Reviewed

    Kazuaki Takami, Hideki Yorimitsu, Hiroshi Shinokubo, Seijiro Matsubara, and Koichiro Oshima

    Synlett   ( 2 ) page: 293-295   2001.2

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  279. Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous Media Reviewed

    Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 74 ( 2 ) page: 225-235   2001.2

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  280. Simple and Efficient TiCl4-Mediated Synthesis of Biaryls via Arylmagnesium Compounds Reviewed

    Atsushi Inoue, Kazuya Kitagawa, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 56 ( 49 ) page: 9601-9605   2000.12

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  281. Powerful Solvent Effect of Water in Radical Reaction: Triethylborane-Induced Atom-Transfer Radical Cyclization in Water. Reviewed

    Hideki Yorimitsu, Tomoaki Nakamura, Hiroshi Shinokubo, Koichiro Oshima, Kiyoyuki Omoto, and Hiroshi Fujimoto

    J. Am. Chem. Soc.   Vol. 122 ( 45 ) page: 11041-11047   2000.11

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  282. Radical Cyclization of N-Allyl-2-halo Amide in Water Reviewed

    Katsuyu Wakabayashi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 73 ( 10 ) page: 2377-2378   2000.10

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  283. Reaction of Trialkyl(dibromomethyl)silanes or 1,2-Bis(dibromomethyl)benzene with Triorganomanganates. A Facile an Selective Synthesis of Alkenylsilanes and 1,2-Diaryl-1,2-dihydrobenzocyclobutenes Reviewed

    Hirotada Kakiya, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 73 ( 9 ) page: 2139-2147   2000.9

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  284. TiCl4-n-Bu4NI as a Reducing Reagent: Pinacol Coupling and Enolate Formation from alpha-Haloketones Reviewed

    Takayuki Tsuritani, Saeko Ito, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 65 ( 16 ) page: 5066-5068   2000.8

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  285. Tributylmanganate(II)-Mediated Cyclization of Enynes Reviewed

    Shinichi Usugi, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 73 ( 8 ) page: 1903-1904   2000.8

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  286. Halogen-Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium Reagents Reviewed

    Kazuya Kitagawa, Atsushi Inoue, Hiroshi Shinokubo and Koichiro Oshima

    Angew. Chem., Int. Ed. Engl.   Vol. 39 ( 14 ) page: 2481-2483   2000.7

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  287. Et3B-Induced Hydrogermylation of Alkenes and Silyl Enol Ethers Reviewed

    Shinobu Tanaka, Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 2 ( 13 ) page: 1911-1914   2000.6

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  288. Intramolecular Aryl Migration from Tin to Carbon via a Radical Atom-Transfer Process Reviewed

    Katsuyu Wakabayashi, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 2 ( 13 ) page: 1899-1901   2000.6

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  289. A Highly Effective Aldol Reaction Mediated by Ti(O-n-Bu)4/t-BuOK Combined Reagent Reviewed

    Zhenfu Han, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 41 ( 22 ) page: 4415-4418   2000.6

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  290. Reaction of gem-Dibromocyclopropanes or Iodobenzofuran with Trialkylmanganate Reviewed

    Hirotada Kakiya, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 56 ( 15 ) page: 2131-2137   2000.4

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  291. Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals Reviewed

    Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 2 ( 5 ) page: 651-653   2000.3

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  292. Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol Reviewed

    Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   ( 2 ) page: 104-105   2000.2

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  293. Highly Selective Cleavage of Prenyl Ethers by Means of a TiCl4-n-Bu4NI Mixed Reagent Reviewed

    Takayuki Tsuritani, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 40 ( 46 ) page: 8121-8124   1999.11

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  294. Highly Stereoselective Coupling Reaction of Acrolein or Vinyl Ketone with Aldehyde Reviewed

    Shigeki Uehira, Zenfu Han, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 1 ( 9 ) page: 1383-1385   1999.11

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  295. Reaction of Titanate-Type Aldehyde Enolate with Ketones to Provide 3-Hydroxyaldehydes Reviewed

    Kentaro Yachi, Hiroshi Shinokubo, and Koichiro Oshima

    J. Am. Chem. Soc.   Vol. 121 ( 40 ) page: 9465-9466   1999.10

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  296. An Unprecedented Coupling Reaction of Arylmagnesium Compounds with Tetrahydrofuran Providing 2-Aryltetrahydrofuran Mediated by an Iodoalkane-EtMgBr System Reviewed

    Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 10 ) page: 1582-1584   1999.10

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  297. Stereoselective Allylation of Acetals through Intramolecular Transfer of an Allylsilane Reviewed

    Kazuya Fujita, Atsushi Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Org. Lett.   Vol. 1 ( 6 ) page: 917-919   1999.9

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  298. Transformation of Tetrahydropyranyl Ether of Allylic Alcohol into 7-Octene-1,5-diol by Means of Trialkylmanganate Reviewed

    Toshihiro Nishikawa, Tomoaki Nakamura, Hirotada Kakiya, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 40 ( 36 ) page: 6613-6616   1999.9

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  299. Preparation of Tributylstannylmanganate and its Addition to Propargylic Alcohols with High Regio- and Stereoselectivities Reviewed

    Shinichi Usugi, Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 9 ) page: 1417-1419   1999.9

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  300. Reduction of Organic Halides with Tri-2-furanylgermane: Stoichiometric and Catalytic Reaction Reviewed

    Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 9 ) page: 1415-1416   1999.9

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  301. A New Strategy for the Preparation of an Active Mn(0) and its Use for Radical Cyclization Reactions Reviewed

    Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 55 ( 7 ) page: 1893-1904   1999.2

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  302. Stereoselective Transformation of 1-Alkenyl Ether (R1CH=CHOMe) into Alkene (R1CH=CHR2) Based on Stereospecific Elimination of the Vicinal Iodo(methoxy)alkane Reviewed

    Atsushi Inoue, Katsuya Maeda, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 55 ( 3 ) page: 665-674   1999.1

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  303. Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenols Using a Water-Soluble Radical Initiator in Water. A Facile Synthesis of γ-Lactones Reviewed

    Hideki Yorimitsu, Katsuyu Wakabayashi, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 40 ( 3 ) page: 519-522   1999.1

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  304. Organic Synthesis Using Organomanganese Compounds Reviewed

    Hiroshi Shinokubo and Koichiro Oshima

    J. Synth. Org. Chem. Jpn.   Vol. 57 ( 1 ) page: 27-37   1999.1

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  305. A Facile Generation of a Cyclopropylzinc Compound from an Alkenylzinc Derivative and Its Reaction with Electrophiles Reviewed

    Kentaro Yachi, Hiroshi Shinokubo, and Koichiro Oshima

    Angew. Chem., Int. Ed. Engl.   Vol. 37 ( 18 ) page: 2515-2517   1998.12

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  306. Triethylborane-Induced Radical Addition of Halogenated Compounds to Alkenes and Alkynes in Water Reviewed

    Tomoaki Nakamura, Hideki Yorimitsu, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 12 ) page: 1351-1352   1998.12

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  307. Triethylborane-Mediated Atom Transfer Radical Cyclization Reaction in Water Reviewed

    Hideki Yorimitsu, Tomoaki Nakamura, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 63 ( 23 ) page: 8604-8605   1998.11

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  308. Regioselective Reaction of Dilithiated 1-Alkynylsilanol with Electrophiles Reviewed

    Shigeki Uehira, Koji Takaku, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 10 ) page: 1096-1098   1998.10

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  309. New Method for the Preparation of an Active Manganese Species and its Use for Radical Cyclization Reactions Reviewed

    Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Synlett   ( 10 ) page: 1075-1076   1998.10

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  310. Manganese(II) Chloride-Catalyzed Alkylmagnesation of 2-Alkynylphenol Reviewed

    Shinji Nishimae, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   ( 8 ) page: 785-786   1998.8

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  311. Synthesis of Cyclopropanols via Cyclopropanation of Zinc Enolates Reviewed

    Saeko Ito, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 39 ( 29 ) page: 5253-5256   1998.7

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  312. Enolate Formation from α-Iodoaldehydes and α-Iodoketones Compounds by Means of Allylsilane-Titanium Tetrachloride and Its Application to an Aldol Reaction Reviewed

    Katsuya Maeda, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 63 ( 13 ) page: 4558-4560   1998.6

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  313. Sequential Carbon-Carbon Bond Formation Reaction Using 1-Silyl-2-propenyllithium Reviewed

    Koji Takaku, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 39 ( 17 ) page: 2575-2578   1998.4

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  314. Reaction of tert-Butyl Dibromoacetate or N,N-Diethyldibromoacetamide with Trialkylmanganate Providing an Alkylated Manganese Enolate Reviewed

    Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 63 ( 4 ) page: 910-911   1998.2

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  315. Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons Reviewed

    Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Organometallics   Vol. 17 ( 3 ) page: 290-292   1998.2

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  316. Intramolecular Radical Cyclization of 2-Haloethanal Allyl Acetal and Allyl 2-Halophenyl Ether with a Grignard Reagent in the Presence of Iron(II) Chloride Reviewed

    Yasuhiro Hayashi, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 39 ( 1 ) page: 63-66   1998.1

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  317. Reaction of 1,3-Dihalopropene with Trialkylmanganate Reviewed

    Hirotada Kakiya, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   ( 1 ) page: 73-74   1998.1

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  318. Manganese-Catalyzed Phenylation of Acetylenic Compounds with a Phenyl Grignard Reagent Reviewed

    Hideki Yorimitsu, Jun Tang, Kenji Okada, Hiroshi Shinokubo, and Koichiro Oshima

    Chem. Lett.   ( 1 ) page: 11-12   1998.1

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  319. Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides Reviewed

    Jun Tang, Hideki Yorimitsu, Hirotada Kakiya, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 38 ( 52 ) page: 9019-9022   1997.12

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  320. Lewis Acid-Induced Chemo- and Stereoselective Allylation of alpha-Iodo Mixed Acetal with Allylsilane Reviewed

    Katsuya Maeda, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 62 ( 18 ) page: 6429-6431   1997.9

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  321. Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one or Cyclohexanecarbaldehyde Reviewed

    Hideki Yorimitsu, Yasuhiro Hayashi, Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 70 ( 9 ) page: 2297-2300   1997.9

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  322. Facile Preparation of Vicinal Allylsiloxy- and Vinylsiloxyhaloalkanes and Their Radical Cyclization Reaction Reviewed

    Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Bull. Chem. Soc. Jpn.   Vol. 70 ( 9 ) page: 2255-2263   1997.9

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  323. Radical Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and 2-Iodoethanal Acetal by Means of Trialkylmanganate(II) Reviewed

    Rie Inoue, Junko Nakao, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 70 ( 9 ) page: 2039-2049   1997.9

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  324. gamma-Regioselective Reaction of Metaloxysilyl-substituted Allyllithium Derived from Allyldiphenylsilanol Reviewed

    Koji Takaku, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 38 ( 29 ) page: 5189-5192   1997.7

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  325. Stereospecific Conversion of Iodohydrin Derivatives into Alkenes by Means of an Allylsilane-Titanium Tetrachloride System and its Application to Stereoretentive Deoxygenation of Epoxides Reviewed

    Kentaro Yachi, Katsuya Maeda, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 38 ( 29 ) page: 5161-5164   1997.7

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  326. Manganese-Catalyzed Reaction of gem-Dibromoalkanes with Grignard Reagents. Selective Synthesis of Alkenylsilanes Reviewed

    Hirotada Kakiya, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 38 ( 18 ) page: 3275-3278   1997.5

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  327. Allylmanganation and Diallylation of Acetylenic Compounds Reviewed

    Jun Tang, Kenji Okada, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron   Vol. 53 ( 14 ) page: 5061-5072   1997.4

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  328. Trialkylmanganate-Induced Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and alpha-Iodo Acetal Reviewed

    Junko Nakao, Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 62 ( 7 ) page: 1910-1911   1997.4

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  329. Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes Reviewed

    Jun Tang, Hiroshi Shinokubo, and Koichiro Oshima

    Bull. Chem. Soc. Jpn.   Vol. 70 ( 1 ) page: 245-251   1997.1

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  330. Facile Syntheses of alpha-Bromo-alpha-Silyl Ketones and alpha-Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds Reviewed

    Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron   Vol. 52 ( 46 ) page: 14533-14542   1996.11

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  331. Olefin Inversion: Stereospecific Olefin Synthesis from Vicinal Alkoxyiodoalkanes with Butyllithium by an E2 Syn Mechanism Reviewed

    Katsuya Maeda, Hiroshi Shinokubo, and Koichiro Oshima

    J. Org. Chem.   Vol. 61 ( 20 ) page: 6770-6771   1996.10

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  332. Intramolecular Iodosilyletherization of Alkenylsilanols with Bis(2,4,6-trimethylpyridine)iodine(I) Hexafluorophosphate Reviewed

    Koji Takaku, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 37 ( 37 ) page: 6781-6784   1996.9

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  333. Dialkylation of gem-Dibromocyclopropanes with Trialkylmanganate and Manganese(II) Chloride-Catalyzed Reaction with Alkylmagnesium Bromide Reviewed

    Rie Inoue, Hiroshi Shinokubo, and Koichiro Oshima

    Tetrahedron Lett.   Vol. 37 ( 30 ) page: 5377-5380   1996.7

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  334. Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers Reviewed

    Katsuya Maeda, Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    J. Org. Chem.   Vol. 61 ( 7 ) page: 2262-2263   1996.4

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  335. tert-Butyldimethylsilyldihalomethyllithium as a Dihalomethylene Dianion Synthon. 1,3-Rearrangement and 1,4-Rearrangement of Silyl Group from Carbon to Oxide Reviewed

    Hiroshi Shinokubo, Katsukiyo Miura, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron   Vol. 52 ( 2 ) page: 503-514   1996.1

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  336. A Facile Preparation of Alkenyl- and Allenylmetallic Compounds by Means of Iodine-Metal Exchange and Their Use in Organic Synthesis Reviewed

    Hiroshi Shinokubo, Katsukiyo Miura, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron   Vol. 51 ( 43 ) page: 11681-11692   1995.10

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  337. Preparation of Alkyl Silyl Acetals from Carboxylic Esters with tert-Butyldimethylsilyldihalomethyllithium. 1,3-Rearrangement of Silyl Group from Carbon to Oxigen Reviewed

    Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Chem. Lett.   Vol. 1995 ( 6 ) page: 461-462   1995.6

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  338. A Room Temperature Preparation of Alkenyllithiums by Lithium-Halogen Exchange between Alkenyl Iodides and n-BuLi in Hydrocarbon Solvents Reviewed

    Toshiaki Yokoo, Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Synlett   Vol. 1994 ( 8 ) page: 645-646   1994.8

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  339. One-Pot Synthesis of alpha,beta-Unsaturated Ketones from tert-Butyldimethylsilyldibromomethane and Two Different Aldehydes Reviewed

    Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron Lett.   Vol. 35 ( 22 ) page: 3741-3744   1994.5

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  340. Rearrangement of tert-Butyldimethylsiloxy Carbenoids.  Regio- and Stereoselective Synthesis of (Z)-1-Halo-2-tert-Butyldimethylsiloxy-1-alkenes Reviewed

    Hiroshi Shinokubo, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron Lett.   Vol. 34 ( 31 ) page: 4985-4988   1993.7

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  341. tert-Butyldimethylsilyldihalomethyllithium as a Dichloromethylene Dianion Synthon. 1,3-Rearrangement of Silyl Group from Carbon to Oxide Reviewed

    Hiroshi Shinokubo, Katsukiyo Miura, Koichiro Oshima, and Kiitiro Utimoto

    Tetrahedron Lett.   Vol. 34 ( 12 ) page: 1951-1954   1993.3

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Books 12

  1. ウォーレン有機化学

    野依良治,奥山格,柴崎正勝,檜山爲次郎,石橋正己,岩澤伸治,大嶋孝志,金井求,木越英夫,忍久保洋,白川英二,橋本俊一,吉田潤一( Role: Joint author)

    東京化学同人  2015.3  ( ISBN:9784807908714

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    Language:Japanese

  2. ブラウン有機化学

    村上正浩,井上将行,王子田彰夫,大井貴史,桑野良一,忍久保洋,浜地格,松田健児,山口茂弘,山子茂( Role: Joint author)

    東京化学同人  2014.1  ( ISBN:9784807907793

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    Language:Japanese

  3. スミス基礎有機化学

    大嶌幸一郎, 高井和彦, 忍久保洋, 依光英樹( Role: Joint author)

    化学同人  2012.9  ( ISBN:9784759815276

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    Language:Japanese

  4. 有機合成化学

    檜山爲次郎, 大嶌幸一郎, 丸岡啓二, 高井和彦, 松原誠二郎, 野崎京子, 白川英二, 忍久保洋( Role: Joint author)

    東京化学同人  2012.3 

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    Language:Japanese

  5. Bromotrichloromethane, in Encyclopedia of Reagents for Organic Synthesis, Vol. 3

    Hiroshi Shinokubo and Koichiro Oshima( Role: Joint author)

    2009 

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    Language:English

  6. 電子共役系有機材料の創製・機能開発・応用(檜山 爲次郎監修)ポルフィリンの周辺官能基化

    忍久保 洋( Role: Sole author)

    シーエムシー出版  2008 

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    Language:Japanese

  7. 有機合成における触媒反応(檜山爲次郎・野崎京子編)炭素ー炭素不飽和結合生成

    忍久保 洋( Role: Sole author)

    東京化学同人  2004 

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    Language:Japanese

  8. 有機合成における触媒反応(檜山爲次郎・野崎京子編)シリル基の転位

    忍久保 洋( Role: Sole author)

    東京化学同人  2004 

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    Language:Japanese

  9. 有機合成における触媒反応(檜山爲次郎・野崎京子編)[2+2+2]環化付加

    忍久保 洋( Role: Sole author)

    東京化学同人  2004 

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    Language:Japanese

  10. 有機金属反応剤ハンドブック(玉尾皓平編著)マグネシウム(Mg)

    大嶌幸一郎・忍久保 洋( Role: Joint author)

    化学同人  2003 

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    Language:Japanese

  11. 有機金属反応剤ハンドブック(玉尾皓平編著)酸化剤:クロム(Cr)、ルテニウム(Ru)、オスミウム(Os)、タリウム(Tl)

    大嶌幸一郎・忍久保 洋( Role: Joint author)

    化学同人  2003 

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    Language:Japanese

  12. 有機金属反応剤ハンドブック(玉尾皓平編著)マンガン(Mn)

    大嶌幸一郎・忍久保 洋( Role: Joint author)

    化学同人  2003 

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    Language:Japanese

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MISC 1

  1. Synthesis of octaaza[8]circulenes containing azaindole units

    赤堀周平, 加賀敦志, 依光英樹, 忍久保洋, 三宅由寛

    日本化学会春季年会講演予稿集(CD-ROM)   Vol. 100th   2020

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Presentations 590

  1. Synthesis and properties of Ni(II) norcorrole with pentafluorophenyl groups

    Shota Kino, Shusaku Ukai, Norihito Fukui, Hiroshi Shinokubo

    2022.3.25 

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    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  2. Synthesis and long-wavelength-absorption of indenoperylene and its π-extended derivatives

    Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2022.3.23 

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    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  3. Synthesis and properties of diazazethrene bisimide and its dimer

    Keita Tajima, Norihito Fukui, Hiroshi Shinokubo

    2022.3.23 

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    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  4. Synthesis and properties of outer-palladated tetrapyridyldiazaporphyrin complexes

    Takahiro Sakurai, Yoshihiro Miyake, Hiroshi Shinokubo

    2022.3.25 

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    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  5. Encapsulation of Stacked Antiaromatic Norcorrole Ni(II) Complexes in a Water-Soluble Micellar Capsule

    Si-Yu Liu, Norihito Fukui, Hiroshi Shinokubo

    2022.3.23 

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    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  6. Three-dimensional aromaticity of closely stacked antiaromatic porphyrins Invited International conference

    Hiroshi Shinokubo

    The International Chemical Congress of Pacific Basin Societies 2021  2021.12.18 

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    Event date: 2021.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:online   Country:United States  

  7. Sulfur extrusion reactions of sulfur inserted naphthalene dimers

    Yuki Tanaka, Norihito Fukui, Hiroshi Shinokubo

    2021.11.19 

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    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  8. Effect of inner substituents in bowl-shaped aromatic hydrocarbons

    Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.11.19 

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    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  9. ジメチルシロキサンで架橋されたノルコロール二量体の合成と物性

    木野 翔太・鵜飼 修作・福井 識人・忍久保 洋

    第52回中部化学関係学協会支部連合秋季大会  2021.10.30 

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    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  10. Sulfur extrusion reactions of sulfur inserted perylene derivatives

    Yuki Tanaka, Norihito Fukui, Hiroshi Shinokubo

    2021.10.30 

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    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  11. Recognition of fullerenes with internally functionalized bowl-shaped aromatic hydrocarbons

    Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.10.30 

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    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  12. 反芳香族分子の近接積層による高密度共役 Invited

    Hiroshi Shinokubo

    2021.10.19 

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    Event date: 2021.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  13. Encapsulation of Antiaromatic Norcorrole Ni(II) Complexes in a Water-Soluble Micellar Capsule

    Si-Yu Liu, Norihito Fukui, Hiroshi Shinokubo

    2021.9.22 

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    Event date: 2021.9

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  14. Synthesis and properties of indeno[1,2,3,4-pqra]perylene

    Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.9.21 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  15. Formation and properties of 1D stacked antiaromatic norcorrole supramolecular polymer

    Shusaku Ukai, Aiko Takamatsu, Masaki Nobuoka, Yusuke Tsutsui, Soichiro Ogi, Norihito Fukui, Shu Seki, Shigehiro Yamaguchi, Hiroshi Shinokubo

    2021.9.22 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  16. Synthesis of β-functionalized diazaporphyrins from tetrabromodipyrrins

    Takahiro Sakurai,Tsubasa Nishimura , Yoshihiro Miyake, Hiroshi Shinokubo,

    2021.9.21 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  17. Synthesis and properties of diazazethrene bisimides

    Keita Tajima, Norihito Fukui, Hiroshi Shinokubo

    2021.9.21 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  18. Structure, Property, and Biological Activity of Oxaporphyrinium Cations

    Asahi Takiguchi, Erika Sakakibara, Hiroshi Sugimoto, Osami Shoji, Hiroshi Shinokubo

    2021.9.21 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

  19. Synthesis and Properties of Carbon-Inserted Perylene Bisimide

    Mai Odajima, Keita Tajima, Norihito Fukui, Hiroshi Shinokubo

    2021.9.22 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  20. Recognition of fullerenes with internally functionalized bowl-shaped aromatic hydrocarbons

    Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.9.22 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  21. Sulfur extrusion reactions of sulfur inserted perylene derivatives

    Yuki Tanaka, Norihito Fukui, Hiroshi Shinokubo

    2021.9.21 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

  22. Redox-Induced Reversible [2+2] Cycloaddition of Etheno-Fused Diporphyrin International conference

    Kazuya Miyagawa, Norihito Fukui, Hiroshi Shinokubo

    11th International Conference on Porphyrins and Phthalocyanines (ICPP-11) 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

    Venue:online   Country:United States  

  23. Synthesis of Covalently Linked Norcorrole Dimers and Their Association Behavior International conference

    Si-Yu Liu, Shusaku Ukai, Norihito Fukui, Hiroshi Shinokubo

    11th International Conference on Porphyrins and Phthalocyanines (ICPP-11) 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

    Venue:online   Country:United States  

  24. Facile Synthesis of Bilindione and Optical Property of 5-Oxaporphyrinium Cation International coauthorship International conference

    Asahi Takiguchi, Seongsoo Kang, Norihito Fukui, Dongho Kim, Hiroshi Shinokubo

    11th International Conference on Porphyrins and Phthalocyanines (ICPP-11)  2021.6.28 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

  25. Three-Dimensional Aromaticity of Closely Stacked Norcorrole Dimers Invited International conference

    Hiroshi Shinokubo

    11th International Conference on Porphyrins and Phthalocyanines (ICPP-11)  2021.6.28 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  26. Synthesis and Property of 14,15-Diazacorrphycene Palladium Complex International conference

    Atsumi Yagi, Hiroshi Shinokubo

    11th International Conference on Porphyrins and Phthalocyanines (ICPP-11)  2021.6.28 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

  27. Investigation of Kinetic Stabilization Effect at meso-Positions of Norcorrole Ni(II) Complexes International conference

    Shusaku Ukaia, Yun Hee Koob, Norihito Fukuia, Shu Sekib, Hiroshi Shinokuboa

    11th International Conference on  2021.6.28 

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

  28. 反芳香族ポルフィリン:ノルコロールの化学 Invited

    Hiroshi Shinokubo

    2021.5.17 

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    Event date: 2021.5

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  29. Synthesis of Covalently Linked Norcorrole Dimers and Their Association Behavior

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    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  30. インデノペリレンの合成と物性

    Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  31. ビリンジオンの簡易合成法と5-オキサポルフィリニウムカチオンの光学特性

    Asahi Takiguchi, Seongsoo Kang, Norihito Fukui, Dongho Kim, Hiroshi Shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  32. ジナフトジチオシンビスイミドの合成と物性

    Yuki Tanaka, Keita Tajima, Norihito Fukui, Hiroshi shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  33. 骨格内部が官能基化されたお椀型芳香族炭化水素によるフラーレン認識

    Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  34. 超分子的アプローチによる反芳香族ノルコロールの一次元積層体形

    Shusaku Ukai, Aiko Takamatsu, Soichiro Ogi, Norihito Fukui, Shu Seki, Shigehiro Yamaguchi, Hiroshi Shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  35. N,N’-ジメチル-2,7-ジアザピレニウムジカチオンの還元と還元体の性質

    Takumi Nakazato , Haruka Takekoshi, Hiroshi Shinokubo, Yoshihiro Miyake

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  36. アザインドール骨格をもつオクタアザ[8]サーキュレンの合成とそのプロトン化挙動

    Shuhei Akahori, Hiroshi Shinokubo, Yoshihiro Miyake

    日本化学会第101春季年会  2021.3.20 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  37. インデノペリレンの合成と物性

    Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.3.21 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

  38. ジナフトジチオシンビスイミドの合成と物性

    Yuki Tanaka, Keita Tajima, Norihito Fukui, Hiroshi shinokubo

    2021.3.20 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

  39. Synthesis of Covalently Linked Norcorrole Dimers and Their Association Behavior

    Si-Yu Liu, Shusaku Ukai, Norihito Fukui, Hiroshi Shinokubo

    2021.3.22 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

  40. カルボニル基を挿入したペリレンビスイミド類縁体の合成と物性

    Mai Odajima, Keita Tajima, Norihito Fukui, Hiroshi shinokubo

    日本化学会第101春季年会  2021.3.20 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  41. 超分子的アプローチによる反芳香族ノルコロールの一次元積層体形

    Shusaku Ukai, Aiko Takamatsu, Soichiro Ogi, Norihito Fukui, Shu Seki, Shigehiro Yamaguchi, Hiroshi Shinokubo

    2021.3.20 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

  42. 骨格内部が官能基化されたお椀型芳香族炭化水素によるフラーレン認識

    Yoshihiro Takeo, Masaki Kato, Norihito Fukui, Hiroshi Shinokubo

    2021.3.20 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

  43. 2,7-ジアザピレン骨格を基盤とする水素結合性有機構造体の構築

    Masahiro Odawara, Masanori Shichino, Ryotaro Matsuda, Hiroshi Shinokubo, Yoshihiro Miyake

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  44. アクリジノアクリジンビスイミドの合成と物性

    Keita Tajima, Kyohei Matsuo, Hiroko Yamada, Shu Seki, Norihito Fukui, Hiroshi shinokubo

    日本化学会第101春季年会 

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  45. 高密度共役のための分子創製と新しい共役概念の提唱 Invited

    忍久保 洋

    学術領域研究(A)「高密度共役の科学:電子共役概念の変革と電子物性をつなぐ」第一回公開シンポジウム  2021.1.23 

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    Event date: 2021.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン  

  46. アクリジノアクリジンビスイミドの合成と物性

    Keita Tajima, Kyohei Matsuo, Hiroko Yamada, Shu Seki, Norihito Fukui, Hiroshi shinokubo

    第47回有機典型元素化学討論会 

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    Event date: 2020.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  47. 2,8-ジアザペリレンの合成と物性

    Takahiro Sakurai,Takumi Nakazato , Hiroshi Shinokubo, Yoshihiro Miyake

    第47回有機典型元素化学討論会 

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    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  48. 2,8-ジアザペリレンの合成と物性

    Takahiro Sakurai,Takumi Nakazato, Hiroshi Shinokubo, Yoshihiro Miyake

    若手オンラインシンポジウム 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  49. ジアザ-s-インダセンの合成と物性

    Kensuke Hanida, Norihito Fukui, Hiroshi Shinokubo

    若手オンラインシンポジウム 

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    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  50. A 2-to-2' 18-to-18' Doubly Linked Ni(II) Norcorrole Dimer: An Effectively Conjugated Antiaromatic Dyad

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    Event date: 2020.10

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  51. ビリンジオンの簡易合成法の開発と反応性の検証

    瀧口 あさひ, 福井 識人, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  52. ニッケルピリジノファン錯体を用いたアルカンの直接的酸化反応

    西村翼, 安藤祐樹, 忍久保洋, 三宅由寛

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  53. 14,15-ジアザコルフィセンパラジウム錯体の合成と物性

    八木 篤実, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  54. Synthesis, Structure, and Properties of Doubly Linked Norcorrole Dimer

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    Event date: 2020.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  55. ノルコロールNi錯体におけるメゾ位置換基の速度論的安定化効果の検証

    鵜飼 修作, 野澤 遼, 福井 識人, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  56. 大環状ノルコロール二量体の合成

    川島 寛之,野澤 遼,福井 識人,忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  57. 硫黄挿入型ペリレンビスイミドの合成と物性

    早川 咲穂, 福井 識人, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  58. 近赤外吸収を示すC70部分骨格の合成と物性

    田中 佑宜, 福井 識人, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  59. アントラセンジイミドの還元的芳香族化によるジアザペリレンの合成

    櫻井貴浩,仲里巧, 忍久保洋, 三宅由寛

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  60. ジアザ-s-インダセンの合成と物性

    埴田 健介, 福井 識人, 忍久保 洋

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  61. アザインドール骨格を有するオクタアザ[8]サーキュレンの合成

    赤堀 周平, 加賀 敦志, 依光英樹, 忍久保 洋, 三宅 由寛

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  62. ジアザピレンホウ素錯体の合成

    仲里巧, 忍久保洋, 三宅由寛

    日本化学会第100春季年会 

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    Event date: 2020.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学   Country:Japan  

  63. Fusion of Porphyrin Chemistry and Organic Chemistry Invited

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    Event date: 2020.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  64. 三次元芳香族性の発現を目指して Invited

    忍久保 洋

    第4回有機化学シンポジウム 

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    Event date: 2020.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:金沢大学   Country:Japan  

  65. Synthesis and Properties of 5-Oxaporphyrinium Cation and Its Application

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    Event date: 2020.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  66. Supramolecular assembly of antiaromatic norcorrole

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    Event date: 2020.1

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  67. Supramolecular assembly of antiaromatic norcorrole

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    Event date: 2020.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  68. Synthesis and Property of 14,15-Diazacorrphycene Metal Complex

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    Event date: 2020.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  69. Encapsulation of Antiaromatic Norcorrole Ni (II) Complexes Within a Micellar Capsule in Water

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    Event date: 2020.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  70. ノルコロール化学の最近の進展 Invited

    忍久保 洋

    京都大学理学研究科化学専攻講演会 

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    Event date: 2019.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:京都大学   Country:Japan  

  71. 硫黄挿入型ペリレンビスイミドの合成と物性

    早川咲穂, 福井 識人, 忍久保 洋

    第46回有機典型元素化学討論会 

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    Event date: 2019.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:松山大学   Country:Japan  

  72. ジアザコルフィセンの合成と物性

    八木 篤実, 忍久保 洋

    第46回有機典型元素化学討論会 

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    Event date: 2019.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:松山大学   Country:Japan  

  73. ジアザポルフィリンマンガン錯体を用いたアルカンの直接的フッ素化反応

    森 しほ, 西村 翼, 忍久保 洋, 三宅 由寛

    第52回酸化反応討論会 

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    Event date: 2019.11

    Language:Japanese   Presentation type:Poster presentation  

    Venue:奈良女子大学   Country:Japan  

  74. 遷移金属ピリジノファン錯体によるアルカンの選択的水酸化反応

    西村 翼, 安藤 祐樹, 忍久保 洋, 三宅 由寛

    第52回酸化反応討論会 

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    Event date: 2019.11

    Language:Japanese   Presentation type:Poster presentation  

    Venue:奈良女子大学   Country:Japan  

  75. 新規ポルフィリンの合成と機能探索 Invited

    忍久保 洋

    豊田工業大学研究談話会 

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    Event date: 2019.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:豊田工業大学   Country:Japan  

  76. New heterocorroles and norcorroles from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New heterocorroles and norcorroles from dipyrrin metal complexes 

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    Event date: 2019.10

    Language:English  

    Venue:Lyon   Country:Japan  

  77. New porphyrins from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New porphyrins from dipyrrin metal complexes 

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    Event date: 2019.10

    Language:English  

    Venue:Nice   Country:Japan  

  78. New heterocorroles and norcorroles from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New heterocorroles and norcorroles from dipyrrin metal complexes 

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    Event date: 2019.10

    Language:English  

    Venue:Paris   Country:Japan  

  79. New heterocorroles and norcorroles from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New heterocorroles and norcorroles from dipyrrin metal complexes 

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    Event date: 2019.10

    Language:English  

    Venue:Montpellier   Country:Japan  

  80. New heterocorroles and norcorroles from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New heterocorroles and norcorroles from dipyrrin metal complexes 

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    Event date: 2019.9

    Language:English  

    Venue:Rennes   Country:Japan  

  81. New heterocorroles and norcorroles from dipyrrin metal complexes Invited

    Hiroshi Shinokubo

    New heterocorroles and norcorroles from dipyrrin metal complexes 

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    Event date: 2019.9

    Language:English  

    Venue:Strasbourg   Country:Japan  

  82. [2+2] Cycloaddition of etheno-fused diporphyrins International conference

    Kazuya Miyagawa, Norihito Fukui, Hiroshi shinokubo

    [2+2] Cycloaddition of etheno-fused diporphyrins 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Osaka   Country:Japan  

  83. Chromic Behaviors of Tetrathia[8]circulene Octaoxides Having Peripheral Aryl Groups International conference

    Hiroyasu Murase, Yuya Nagata, Ichiro Hisaki, Hiroshi Shinokubo, Yoshihiro Miyake

    Chromic Behaviors of Tetrathia[8]circulene Octaoxides Having Peripheral Aryl Groups 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Osaka   Country:Japan  

  84. 5,15-ジアザポルフィリン金属錯体のN-メチル化反応

    西條真由, Chia WenXi, 西村翼, 三宅由寛, 忍久保洋

    第30回基礎有機化学討論会 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:大阪交流国際センター   Country:Japan  

  85. Synthesis of a cyclic norcorrole dimer International conference

    Hiroyuki Kawashima, Ryo Nozawa, Hiroshi Shinokubo

    Synthesis of a cyclic norcorrole dimer 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Osaka   Country:Japan  

  86. Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues International conference

    Sakiho Hayakawa, Norihito Fukui, Hiroshi Shinokubo

    Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:Osaka   Country:Japan  

  87. Synthesis and Properties of C70-fragment showing NIR absorption International conference

    Yuki Tanaka, Norihito Fukui, Hiroshi Shinokubo

    Synthesis and Properties of C70-fragment showing NIR absorption 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Osaka   Country:Japan  

  88. Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers International conference

    Keita Tajima, Norihito Fukui, Hiroshi shinokubo

    Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Osaka   Country:Japan  

  89. Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues International conference

    Sakiho Hayakawa, Norihito Fukui, Hiroshi Shinokubo

    Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  90. Synthesis and properties of N,N'-dimethyl-2,7-diazapyrenes International conference

    Haruka Takekoshi, Takumi Nakazato, Hiroshi Shinokubo, Yoshihiro Miyake

    Synthesis and properties of N,N'-dimethyl-2,7-diazapyrenes 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  91. Optical properties of N,N'-dimethyl-2,7-diazapyrenes International conference

    Haruka Takekoshi, Takumi Nakazato, Hiroshi Shinokubo, Yoshihiro Miyake

    Optical properties of N,N'-dimethyl-2,7-diazapyrenes 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  92. Synthesis and chromic behavior of tetrathia[8]circulene octoxides having peripheral aryl groups International conference

    Hiroyasu Murase, Yuya Nagata, Ichiro Hisaki, Hiroshi Shinokubo, Yoshihiro Miyake

    Synthesis and chromic behavior of tetrathia[8]circulene octoxides having peripheral aryl groups 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  93. N-メチル5,15-ジアザポルフィリン金属錯体の合成とその光物性

    西條真由, Chia WenXi, 西村翼, 三宅由寛, 忍久保洋

    2019光化学討論会 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学   Country:Japan  

  94. Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers International conference

    Keita Tajima, Norihito Fukui, Hiroshi shinokubo

    Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  95. Synthesis of a cyclic norcorrole dimer International conference

    Hiroyuki Kawashima, Ryo Nozawa, Hiroshi Shinokubo

    Synthesis of a cyclic norcorrole dimer 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  96. Synthesis of 2,9-diazadibenzocoronene by reductive aromatization International conference

    Takahiro Sakurai, Hiroshi Shinokubo, Yoshihiro Miyake

    Synthesis of 2,9-diazadibenzocoronene by reductive aromatization 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  97. Direct C_H Fluorination of Alkanes with Manganese Diazaporphyrin Complexes International conference

    Shiho Mori, Tsubasa Nishimura, Hiroshi Shinokubo, Yoshihiro Miyake

    Direct C_H Fluorination of Alkanes with Manganese Diazaporphyrin Complexes 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  98. ヘテロコルフィセンの合成

    八木篤実,忍久保洋

    第51回構造有機化学若手の会 夏の学校 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:京都竹の郷温泉 ホテル京都エミナース   Country:Japan  

  99. Synthesis of meso-Alkyl Norcorroles and Conversion to 5-Oxaporphyrins(2.0.1.0)

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    Event date: 2019.8

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  100. 遷移金属ピリジノファン錯体によるアルカンの選択的水酸化反応

    西村翼, 安藤祐樹, 忍久保洋, 三宅由寛

    第51回構造有機化学若手の会 夏の学校 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:京都竹の郷温泉 ホテル京都エミナース   Country:Japan  

  101. Stability and association behavior of a norcorrole Ni(II) complex with 3,5-di-tert-butylphenyl groups at meso positions International conference

    Shusaku Ukai, Ryo Nozawa, Norihito Fukui, Hiroshi Shinokubo

    Stability and association behavior of a norcorrole Ni(II) complex with 3,5-di-tert-butylphenyl groups at meso positions 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  102. Synthesis, Structure, and Properties of Tetraazatetrathia[8]circulenes International conference

    Shuhei Akahori, Hiroshi Shinokubo, Yoshihiro Miyake

    Synthesis, Structure, and Properties of Tetraazatetrathia[8]circulenes 

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    Event date: 2019.8

    Language:Japanese   Presentation type:Poster presentation  

    Venue:Kyoto   Country:Japan  

  103. Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins

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    Event date: 2019.8

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  104. Towards Three-Dimensional Aromaticity from an Antiaromatic Porphyrinoid Invited

    Hiroshi Shinokubo

    The 18th International Symposium on Novel Aromatic Compounds (ISNA-18) 

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    Event date: 2019.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Sapporo   Country:Japan  

  105. Synthesis and Properties of Peripherally Functionalized 2,7-Diazapyrene Derivatives

    Takumi Nakazato, Takuto Kamatsuka, Junichi Inoue, Tsuneaki Sakurai, Shu Seki, Hiroshi Shinokubo, and Yoshihiro Miyake

    The 18th International Symposium on Novel Aromatic Compounds (ISNA-18) 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Sapporo   Country:Japan  

  106. Synthesis of meso-Alkyl-Substituted Norcorrole Ni Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)

    Si-Yu Liu, Norihito Fukui, Hiroshi Shinokubo

    The 18th International Symposium on Novel Aromatic Compounds (ISNA-18) 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Sapporo   Country:Japan  

  107. Synthesis, Structure, and Properties of Tetraazatetrathia[8]circulenes

    Shuhei Akahori, Hiroshi Shinokubo, Yoshihiro Miyake

    The 18th International Symposium on Novel Aromatic Compounds (ISNA-18) 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Sapporo   Country:Japan  

  108. Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins

    Asahi Takiguchi, Norihito Fukui, Hiroshi Shinokubo

    The 18th International Symposium on Novel Aromatic Compounds (ISNA-18) 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Sapporo   Country:Japan  

  109. [2+2] Cycloaddition of etheno-fused diporphyrins

    Kazuya Miyagawa, Norihito Fukui, Hiroshi shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  110. Synthesis of meso-Alkyl-Substituted Norcorrole Ni Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0)

    Si-Yu Liu, Norihito Fukui, Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  111. Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins

    Asahi Takiguchi, Norihito Fukui, Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  112. Direct C-H Fluorination of Alkanes with Manganese Diazaporphyrin Complexes

    Shiho Mori, Tsubasa Nishimura, Hiroshi Shinokubo, Yoshihiro Miyake

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  113. Synthesis and Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers

    Keita Tajima, Norihito Fukui, Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  114. 5,15-Dithiaporphyrin S,S-Tetraoxide as a Highly Electron-Deficient Porphyrinic Ligand

    Atsumi Yagi, Daisuke Yamashita, Norihito Fukui, Takahisa Ikeue, and Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  115. Synthesis of a cyclic norcorrole dimer

    Hiroyuki Kawashima, Ryo Nozawa, Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  116. Stability and association behavior of a norcorrole Ni(II) complex with 3,5-di-tert-butylphenyl groups at meso positions

    Shusaku Ukai, Ryo Nozawa, Norihito Fukui, Hiroshi Shinokubo

    ITbM-GTR Pre-ISNA Symposium "Toward Advanced Functions from New pi-Skeletons" 

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    Event date: 2019.7

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya   Country:Japan  

  117. 反芳香族ポルフィリンから探る新たな芳香族性 Invited International conference

    忍久保 洋

    大阪大学工学研究科応用化学専攻講演会 

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    Event date: 2019.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:大阪   Country:Japan  

  118. Synthesis, reactivity, and property of antiaromatic porphyrins Invited

    Hiroshi Shinokubo

    The 47th Naito Conference "C-H Bond Activation and Transformation" 

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    Event date: 2019.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Sapporo   Country:Japan  

  119. Towards Three-Dimensional Aromaticity from Antiaromatic Porphyrinoid Invited

    Hiroshi Shinokubo

    10th International Conference on Materials for Advanced Technologies (ICMAT 2019) 

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    Event date: 2019.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Singapore   Country:Japan  

  120. Exploration of Synthesis and Property of Novel Porphyrinoids Invited

    Hiroshi Shinokubo

    CBC SEMINAR 

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    Event date: 2019.6

    Language:English  

    Venue:Singapore   Country:Japan  

  121. Synthesis and Properties of Heteroatom-inserted Perylene Bisimide Analogues

    Sakiho Hayakawa, Norihito Fukui, Hiroshi Shinokubo

    The 80th Okazaki Conference, Chirality-induced spin selectivity and its related phenomena 

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    Event date: 2019.5

    Language:English   Presentation type:Poster presentation  

    Venue:Okazaki   Country:Japan  

  122. 3D Aromaticity Based on Antiaromatic Porphyrins Invited International conference

    SHINOKUBO, Hiroshi

    Let’s leap! Challenges in Organic Chemistry 

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    Event date: 2019.4

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  123. 窒素架橋されたナフタレンモノイミド二量体の合成とその凝集誘起発光 International conference

    田島 慶太・福井 識人・忍久保 洋

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  124. ヘテロ原子挿入型ペリレンビスイミド類縁体の合成と物性 International conference

    早川 咲穂・福井 識人・忍久保 洋

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  125. Synthesis and properties of peripherally functionalized 2,7-diazapyrene derivatives International conference

    NAKAZATO, Takumi; KAMATSUKA, Takuto; INOUE, Junichi; SAKURAI, Tsuneaki; SEKI, Syu; SHINOKUBO, Hiroshi; MIYAKE, Yoshihiro

    Synthesis and properties of peripherally functionalized 2,7-diazapyrene derivatives 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  126. 5,15-ジアザポルフィリン金属錯体のN-メチル化反応 International conference

    西條 真由・西村 翼・CHIA Wen Xi・三宅 由寛・忍久保 洋

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  127. 5,15-ジアザポルフィリン鉄錯体のsp3 C-H酸化触媒としての利用 International conference

    西村 翼・渡辺 芳人・荘司 長三・忍久保 洋・三宅 由寛

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  128. ジアザポルフィリンマンガン錯体を用いたアルカンの直接的フッ素化反応 International conference

    森 しほ・西村 翼・忍久保 洋・三宅 由寛

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  129. Synthesis and Properties of Dialkoxybis(dipyrrin)s through Oxidative Cleavage of Norcorrole International conference

    SHAFIE, Siham Asyiqin; KAWASHIMA, Hiroyuki; MIYAKE, Yoshihiro; SHINOKUBO, Hiroshi

    Synthesis and Properties of Dialkoxybis(dipyrrin)s through Oxidative Cleavage of Norcorrole 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  130. Synthesis and Properties of Covalently Linked Norcorrole Dimers International conference

    LIU, Siyu; KAWASHIMA, Hiroyuki; FUKUI, Norihito; SHINOKUBO, Hiroshi

    Synthesis and Properties of Covalently Linked Norcorrole Dimers 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  131. 外周部にアリール基をもつテトラチア[8]サーキュレン酸化体の合成とクロミズム特性 International conference

    村瀬 浩康・永田 裕也・久木 一朗・忍久保 洋・三宅 由寛

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  132. B-NおよびC=N置換テトラチア[8]サーキュレンの合成と物性 International conference

    赤堀 周平・忍久保 洋・三宅 由寛

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  133. ヒドロキシオキソフロリン誘導体の合成と物性 International conference

    瀧口 あさひ・忍久保 洋

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  134. 外周部にアルキル基をもつテトラチア[8]サーキュレン酸化体の合成とAIE特性 International conference

    村瀬 浩康・永田 裕也・忍久保 洋・三宅 由寛

    日本化学会第99春季年会 

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    Event date: 2019.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:甲南大学   Country:Japan  

  135. Exploration of Antiaromatic Porphyrins Invited

    H. Shinokubo

    Core-to-Core and GTR Symposiumon Elements Function for Transformative Catalysis and Materials 

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    Event date: 2019.2

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Nagoya University   Country:Japan  

  136. ジヘテロポルフィリンの合成と物性 Invited International conference

    忍久保洋

    ジヘテロポルフィリンの合成と物性 

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    Event date: 2018.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:京都大学   Country:Japan  

  137. 四重BN置換テトラチア[8]サーキュレンの合成と物性 International conference

    赤堀 周平・忍久保 洋・三宅 由寛

    第45回有機典型元素化学討論会 

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    Event date: 2018.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:朱鷺メッセ新潟   Country:Japan  

  138. ヘテロ原子挿入型ペリレンビスイミド類縁体の合成と物性 International conference

    早川 咲穂・福井 識人・忍久保 洋

    第45回有機典型元素化学討論会 

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    Event date: 2018.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:朱鷺メッセ新潟   Country:Japan  

  139. メゾ位にリンを含む新規ポルフィリノイドの合成 International conference

    大森 裕土・忍久保 洋

    第45回有機典型元素化学討論会 

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    Event date: 2018.12

    Language:Japanese   Presentation type:Poster presentation  

    Venue:朱鷺メッセ新潟   Country:Japan  

  140. Reductive Aromatization of Arylene Diimides to 2,7-Diazapyrenes and 2,9-Diazaperopyrenes

    Takumi Nakazato, Yasutaka Nakamura, Takuto Kamatsuka, Junichi Inoue, Tsuneaki Sakurai, Shu Seki, Hiroshi Shinokubo, Yoshihiro Miyake

    14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14) 

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    Event date: 2018.11

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Rihga Royal Hotel   Country:Japan  

  141. Synthesis and Properties of Diethoxybis(dipyrrin) through Oxidation of Norcorrole International conference

    Siham Asyiqin Shafie・川島弘之・忍久保洋

    第49回 中部化学関係学協会支部連合秋季大会 

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    Event date: 2018.11

    Presentation type:Poster presentation  

    Country:Japan  

  142. ジアザポルフィリン鉄錯体を用いたアルカンの直接的酸化反応 International conference

    西 村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛

    第49回 中部化学関係学協会支部連合秋季大会 

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    Event date: 2018.11

    Presentation type:Oral presentation (general)  

    Country:Japan  

  143. 2,9-ジアザペロピレンの合成と物性 International conference

    中村泰崇・鎌塚拓人・忍久保洋・三宅由寛

    第49回 中部化学関係学協会支部連合秋季大会 

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    Event date: 2018.11

    Country:Japan  

  144. テトラチア[8]サーキュレン酸化体の合成と物性 International conference

    村瀬浩康、永田裕也、久木一朗、三宅由寛、忍久保洋

    第113回有機合成シンポジウム 

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    Event date: 2018.11

    Presentation type:Poster presentation  

    Venue:名古屋大学   Country:Japan  

  145. 5,15-ジアザポルフィリン鉄錯体触媒を用いたアルカンの直接的酸化反応 International conference

    西 村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛

    第51回酸化反応討論会 

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    Event date: 2018.11

    Presentation type:Oral presentation (general)  

    Country:Japan  

  146. N--メチル-5,15-ジアザポルフィリン白金およびパラジウム錯体の合成と反応性 International conference

    西條真由・西村 翼・三宅由寛・忍久保洋

    CSJ化学フェスタ 

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    Event date: 2018.10

    Country:Japan  

  147. フラーレンの選択的包接を目指したアザバッキ―ボウル金属錯体の合成 International conference

    横田智也、廣戸聡、忍久保洋

    第113回有機合成シンポジウム 

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    Event date: 2018.10

    Venue:名古屋大学   Country:Japan  

  148. 積み重ねて生みだす芳香族の新次元 Invited International conference

    忍久保洋

    CSJ化学フェスタ 

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    Event date: 2018.10

    Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  149. お椀型分子を用いたDonorーAcceptor型分子の合成と物性 International conference

    田中佑宜・廣戸 聡・忍久保 洋

    CSJ化学フェスタ 

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    Event date: 2018.10

    Country:Japan  

  150. 金属錯体の有機反応による新規ポルフィリン類縁体の合成と物性探求 Invited International conference

    忍久保洋

    第4回材料相模セミナー 

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    Event date: 2018.10

    Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  151. 流れに任せて Invited International conference

    忍久保洋

    2018年π造形若手会 

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    Event date: 2018.10

    Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  152. Synthesis and properties of novel porphyrins from dipyrrins Invited International conference

    H. Shinokubo

    Hunan Normal University 

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    Event date: 2018.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  153. ニッケルピリジノファン錯体を用いたアルカンの選択的水酸化反応 International conference

    西村 翼・安藤 祐樹・忍久保 洋・三宅 由寛

    第65回有機金属化学討論会 

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    Event date: 2018.9

    Country:Japan  

  154. 遷移金属ジアザポルフィリン錯体触媒による sp3 C-H 結合の直接的酸化反応 International conference

    西 村 翼・荘司 長三・渡辺 芳人・忍久保 洋・三宅 由寛

    第65回有機金属化学討論会 

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    Event date: 2018.9

    Country:Japan  

  155. ポルフィリンにおける有機化学と無機化学の接点 Invited International conference

    忍久保洋

    第31回生物無機化学夏季セミナー 

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    Event date: 2018.9

    Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  156. 反芳香族ポルフィリンとその積層体のπ造形科学 Invited International conference

    忍久保洋

    日本物理学会共催シンポジウム「π造形科学による材料と物性の開拓」 

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    Event date: 2018.9

    Presentation type:Oral presentation (invited, special)  

    Venue:同志社大学   Country:Japan  

  157. N,N‘-ジメチル-2,7-ジアザピレンの合成と物性 International conference

    竹腰遥、仲里巧、三宅由寛、忍久保洋

    第113回有機合成シンポジウム 

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    Event date: 2018.9

    Venue:名古屋大学   Country:Japan  

  158. 内部に窒素原子による架橋を有するペリレンビスイミド類縁体の合成と物性 International conference

    早川咲穂・福井識人・忍久保洋

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  159. 積層した反芳香族ノル コロールにおける三次元芳香族性の発現 International conference

    野澤遼・久木一朗・清水宗 治・Won-Young Cha・Jinseok Kim・Dongho Kim・忍久保洋

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Language:Japanese  

    Country:Japan  

  160. Diazachlorin and Diazabacteriochlorin for In Vivo Two Photon Photodynamic Therapy International conference

    Ayaka Yamaji・Jean Franc_ois Longevial・Dina Aggad・Gakhyun Kim・Wen Xi Chia・Tsubasa Nishimura・Yoshihiro Miyake・Se_bastien Cle_ment・Dongho Kim・Magali Gary-Bobo・Se_bastien Richeter・ Hiroshi Shinokubo

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  161. Synthesis and Properties of meso-Alkyl Norcorroles International conference

    Siyu Liu・Norihito Fukui・Hiroshi Shinokubo

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  162. Synthesis and Properties of Phosphorus(V) Norcorrole International conference

    Siham Asyiqin Shafie・Takuya Yoshida・ Yoshihiro Miyake・Hiroshi Shinokubo

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  163. 1,3,6,8-テトラアルキル 2,7-ジアザピレンの系統的合成法の開発 International conference

    仲里巧・三宅由寛・忍久保洋

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  164. ビススピロ骨格をもつポルフィリン二量体の合成 International conference

    瀧口あさひ・坪井秀夫・伊藤覚・廣戸聡・忍久保洋

    第29回基礎有機化学討論会 

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    Event date: 2018.9

    Country:Japan  

  165. Diversity-Oriented Synthesis of Hetero[8]circulenes through Direct C-H Borylation of Tetrathienylene

    Yoshihiro Miyake, Yuma, Serizawa, Shohei Kato, Yuya Nagata, Shuhei Akahori, Hiroshi Shinokubo

    4th International Symposium on C-H Activation 

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    Event date: 2018.9

    Language:English  

    Venue:Keio University   Country:Japan  

  166. 反芳香族ポルフィリンから探る新たな芳香族性 Invited International conference

    忍久保洋

    有機合成夏期セミナー「明日の有機合成化学」 

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    Event date: 2018.8

    Presentation type:Oral presentation (invited, special)  

    Venue:大阪科学技術センター   Country:Japan  

  167. Synthesis and Properties of Tetrasilatetrathia[8]circulene and Tetragermatetrathia[8]circulene

    S. Akahori, Y. Serizawa, S. Kato, H. Sakai, T. Hasobe, Y. Miyake, and H. Shinokubo

    28th International Symposium on the Organic Chemistry of Sulfur 

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    Event date: 2018.8

    Language:English  

    Venue:Tokyo Institute of Technology   Country:Japan  

  168. Functionalization and Properties of Norcorroles Invited

    H. Shinokubo

    10th International Conference on Porphyrins and Phthalocyanines 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Munich   Country:Japan  

  169. Synthesis of novel porphyrins from dipyrrins Invited International conference

    H. Shinokubo

    Supramolecular Chemistry of Nitrogen Ligands 

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    Event date: 2018.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Strasbourg   Country:Japan  

  170. 新規ポルフィリン類縁体の合成と物性の探求 Invited International conference

    忍久保洋

    新潟大学大学院講演会 

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    Event date: 2018.6

    Presentation type:Oral presentation (invited, special)  

    Venue:新潟大学   Country:Japan  

  171. アザバッキーボウルを基盤とするドナー・アクセプター型分子の合成とその物性 International conference

    田中佑宜、廣戸聡、忍久保洋

    第113回有機合成シンポジウム 

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    Event date: 2018.6

    Venue:名古屋大学   Country:Japan  

  172. 可逆的に構造変化するポルフィリン二量体の合成とフラーレンとの包接挙動 International conference

    瀧口あさひ、廣戸聡、忍久保洋

    第113回有機合成シンポジウム 

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    Event date: 2018.6

    Venue:名古屋大学   Country:Japan  

  173. Synthesis of N-methyl-5,15-diazaporphyrin exhibiting high electron accepting ability International conference

    Chia Wen Xi, T. Nishimura, H. Omori, H. Shinokubo

    第113回有機合成シンポジウム 

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    Event date: 2018.6

    Venue:名古屋大学   Country:Japan  

  174. Exploration of Novel Porphyrins from Dipyrrin Precursors Invited

    H. Shinokubo

    Japanese-Spanish Post-Symposium in Organic Synthesis in Nagoya 

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    Event date: 2018.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Nagoya University   Country:Japan  

  175. Strongly Antiaromatic Porphyrins with Singlet Biradical Character Invited International conference

    H. Shinokubo

    233rd ECS Meeting 

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    Event date: 2018.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Seattle   Country:Japan  

  176. meso位にスルホニル基を有する新規ポルフィリノイドの合成と物性

    山下大輔・大森裕土・近藤剛資・和智成彦・忍久保洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  177. Substituent Effect on Oxidative Dimerization of beta-aminoporphyrins

    廣戸聡、伊藤覚、坪井秀夫、忍久保洋

    日本大学 

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    Event date: 2018.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  178. ノルコロールシクロファンの合成と物性

    野澤 遼、久木 一朗、忍久保 洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  179. 1,3,6,8-テトラアルキル-2,7-ジアザピレンの合成および物性

    仲里 巧・鎌塚 拓人・井上 純一・櫻井 庸明・関 修平・三宅 由寛・忍久保 洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  180. 強い反芳香族性とジラジカル性を示すベンゾノルコロールの合成

    吉田 拓矢, 高橋 功太郎, 井手 雄紀, 岸 亮平, 藤吉 純也, Lee Sangsu, 平岡 勇哉, Kim Dongho, 中野 雅由, 池上 崇久, 山田 容子, 忍久保 洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  181. 5,15-ジアザポルフィリン鉄錯体を用いたアルカンの触媒的酸化反応

    西村翼、三宅由寛、忍久保洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  182. Synthesis and properties of N-methyl-5,15-diazaporphyrin

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    Event date: 2018.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  183. N,N'-ジメチル-2,7-ジアザピレンの合成と物性

    竹腰遥,仲里巧,三宅由寛,忍久保洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  184. 可逆的に構造変化するポルフィリン二量体の合成とC60 との包接挙動

    瀧口あさひ・廣戸聡・忍久保洋

    日本大学 

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    Event date: 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  185. Organic Batteries Using Multiple-Oxidation-State Hexaphyrin as an Active Electrode Material International conference

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    Event date: 2018.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  186. 有機金属化学で挑むπ電子化合物の合成 Invited

    忍久保洋

    島根大学 

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    Event date: 2018.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  187. 新しいポルフィリンの合成と物性・機能の探求 Invited

    忍久保洋

    島根大学 

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    Event date: 2018.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  188. 新規縮環ポルフィリノイドの合成と物性 Invited

    忍久保洋

    京都大学 

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    Event date: 2017.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  189. ジピリン金属錯体を前駆体とするポルフィリン類縁体の合成と物性・機能の探求 Invited

    忍久保洋

    筑波大学 

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    Event date: 2017.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  190. ナフタレンジイミドの還元的芳香族化による2,7-ジアザピレン誘導体の合成

    仲里 巧・鎌塚 拓人・井上 純一・櫻井 庸明・関 修平・三宅 由寛・忍久保 洋

    東京工業大学 

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    Event date: 2017.12 - 2018.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  191. meso 位にスルホニル基を有する新規ポルフィリノイドの合成と物性

    山下大輔・大森裕土・近藤剛資・和智成彦・池上崇久・忍久保洋

    東京工業大学 

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    Event date: 2017.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  192. アザバッキーボウル-フラーレン共有結合体の合成と物性

    落合 達也・廣戸 聡・忍久保 洋

    岐阜大学 

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    Event date: 2017.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  193. 還元的芳香族化によるピリジン縮環多環芳香族炭化水素の合成と物性

    仲里 巧・鎌塚 拓人・井上 純一・櫻井 庸明・関 修平・三宅 由寛・忍久保 洋

    岐阜大学 

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    Event date: 2017.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  194. 可逆的に構造変化する縮環ポルフィリンの合成

    瀧口あさひ・廣戸聡・忍久保洋

    岐阜大学 

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    Event date: 2017.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  195. 可逆的に構造変化する縮環ポルフィリンの合成

    瀧口あさひ・廣戸聡・忍久保洋

    名古屋大学 

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    Event date: 2017.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  196. テトラシラテトラチア[8]サーキュレンおよびテトラゲルマテトラチア[8]サーキュレンの合成と物性

    赤堀周平・芹澤祐真・加藤祥平・酒井隼人・羽曾部卓・三宅由寛・忍久保洋

    名古屋大学 

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    Event date: 2017.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  197. ナフタレンジイミドの還元的芳香族化による2,7-ジアザピレン誘導体の合成

    仲里 巧・鎌塚 拓人・井上 純一・櫻井 庸明・関 修平・三宅 由寛・忍久保 洋

    タワーホール船堀 

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    Event date: 2017.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  198. 縮環ポルフィリンの可逆的構造変化への試み

    瀧口あさひ・廣戸聡・忍久保洋

    タワーホール船堀 

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    Event date: 2017.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  199. Exploration of antiaromatic porphyrins Invited International conference

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    Event date: 2017.10 - 2018.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:China  

  200. ジピリン元素ブロックを用いた新規ポルフィリン類縁体の合成 Invited

    忍久保洋

    愛媛大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  201. 酸化還元活性な新規ポルフィリン類縁体の創成と機能 Invited

    忍久保洋

    長崎大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  202. Catalytic Oxidation of Alkanes Using Diazaporphyrin Metal Complexes

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  203. メゾ位にヘテロ原子を含む新規ポルフィリノイドの合成

    大森 裕土、廣戸 聡、武田 洋平、南方 聖司、忍久保 洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  204. ぺりレンジイミドの還元的芳香族化による2,9-ジアザペロピレンの合成

    中村泰崇、三宅由寛、忍久保洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  205. 反芳香族ノルコロールの簡便なC–Hアミノ化反応

    吉田 拓矢, 忍久保 洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  206. アルキンの環化反応を利用した縮環ポルフィリン二量体の合成

    永井 智大・上田 真之・小田 一磨・廣戸 聡・忍久保 洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  207. π拡張アザコラニュレンラジカルカチオンの二量化反応

    横井寛生, 廣戸 聡, 忍久保洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  208. 5-アザ-15-チアポルフィリンおよびその酸化体の合成と物性

    山下大輔・大森裕土・忍久保洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  209. ナフタレンジイミドの還元的芳香族化による2,7-ジアザピレン誘導体の合成

    仲里 巧・鎌塚 拓人・井上 純一・櫻井 庸明・関 修平・三宅 由寛・忍久保 洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  210. π拡張ジヒドロフェナジンの合成とエレクトロクロミック特性

    廣戸 聡, 長崎 樹梨, 忍久保 洋

    九州大学 

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    Event date: 2017.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  211. Supramolecular Polymerization of a Nitrogen-Embedded Buckybowl Dimer with C60 International conference

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  212. Strong Antiaromaticity and Biradicaloid Characters of Benzonorcorroles International conference

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  213. The emergence of 3D aromaticity in stacked norcorrole dimers International conference

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  214. 10-Silacorroles Exhibiting Near-IR Absorption and Emission International conference

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  215. Synthesis and properties of tetrasilatetrathia[8]circulene and tetragermatetrathia[8]circulene International conference

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  216. The emergence of 3D aromaticity in stacked norcorrole dimers

    2017.7.25 

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    Event date: 2017.7

    Language:English   Presentation type:Poster presentation  

  217. 反芳香族化合物の創成 Invited

    忍久保洋

    東京大学 

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    Event date: 2017.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  218. ジアザポルフィリン鉄錯体の合成とアルカンの触媒的酸化反応への応用

    西村翼、三宅由寛、忍久保洋

    岡山大学 

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    Event date: 2017.6

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  219. Synthesis and Properties of 10-Heterocorroles Invited International conference

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    Event date: 2017.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  220. Synthesis, Structures, and Properties of Stacked Antiaromatic Porphyrins Invited International conference

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    Event date: 2017.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  221. Synthesis, Structures and Properties of Norcorrole Metal Complexes Invited International conference

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    Event date: 2017.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Canada  

  222. ジアザポルフィリン鉄錯体の合成とアルカンの触媒的酸化反応への応用

    西村翼・ 三宅由寛・忍久保洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  223. メゾ位にヘテロ原子を含む新規ポルフィリノイドの合成

    大森裕土・廣戸聡・忍久保洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  224. 光線力学療法への応用を指向した新規ジアザポルフィリノイドの開発

    山路文香・Jean-François Longevial・三宅由寛・ Sébastien Richeter・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  225. 5-アザ-15-チアポルフィリンの合成と物性

    山下 大輔・大森 裕土・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  226. A facile synthesis of novel expanded porphyrinoids: BisNi(II) complexes of dicyanovinylene-di(meso-aryl)dipyrromethene

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    Event date: 2017.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  227. ペリレンシジイミドの還元的芳香族化による 2,9-ジアザペロピレン誘導体の合成

    中村 泰崇・鎌塚 拓人・三宅 由寛・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  228. ナフタレンジイミドの還元的芳香族化による 2,7-ジアザピレン誘導体の合成

    仲里 巧・鎌塚 拓人・三宅 由寛・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  229. ジシアノメチル基をもつヘキサベンゾコロネンの物性と反応性

    小田 一磨・廣戸 聡・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  230. 銅(I)塩を用いた新規スピロ環化合物の一段階合成

    落合 達也・廣戸 聡・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  231. アザバッキーボウルの物性と反応性

    横井 寛生・廣戸 聡・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  232. アザバッキーボウル二量体の合成とその C60 包接挙動

    武田 基希、横井 寛生、廣戸 聡、忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  233. ノルコロール銅錯体およびフリーベース体の合成と物性

    米澤 翼・廣戸 聡・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  234. 反芳香族ノルコロールの置換基効果およひπ拡張による多彩な物性変化

    吉田 拓矢・高橋功太郎・酒巻大輔・関修平・山田 容子・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  235. ノルコロールポルフィリン三重縮環二量体の合成

    伊藤 覚・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  236. メゾ位にヘテロ原子を含む新規ポルフィリノイドの合成

    板淵 史栞・吉田 拓矢・野澤 遼・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  237. 積層型反芳香族ノルコロール二量体による三次元芳香族性の発現

    野澤 遼 ・清水 宗治 ・久木 一朗・Won Young Cha・Dongho Kim・忍久保 洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  238. テトラシラテトラチア[8]サーキュレンおよびテトラゲルマテトラ チア[8]サーキュレンの合成と物性

    赤堀 周平・芹澤 祐真・加藤 祥平・酒井 隼人・羽曾部 卓・三宅 由寛・忍久保洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  239. 架橋アルキン部位の環化反応を利用した新規ポルフィリン二量体の合成

    永井 智大・上田 真之・小田 一磨・廣戸聡・忍久保洋

    日本化学会第97春季年会 

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    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  240. 有機金属化学とポルフィリン Invited

    忍久保洋

    京都大学大学院理学研究科 

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    Event date: 2017.2

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  241. 反芳香族ポルフィリンの合成と物性 Invited

    忍久保洋

    京都大学大学院理学研究科 

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    Event date: 2016.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  242. テトラシラテトラチア[8]サーキュレン及びテトラゲルマテトラチア[8]サーキ ュレンの合成と物性

    赤堀周平, 芹澤 祐真, 加藤祥平, 酒井隼人, 羽曾部卓, 三宅由寛, 忍久保 洋

    第43回有機典型元素化学討論会 

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    Event date: 2016.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  243. テトラチア[8]サーキュレン酸化体の合成と光物性

    永田裕也, 加藤祥平, 三宅由寛, 忍久保洋,

    第43回有機典型元素化学討論会, 

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    Event date: 2016.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  244. ケイ素およびホウ素を含む新規ポルフィリノイドの合成

    大森裕土, 廣戸聡, 忍久保洋,

    第43回有機典型元素化学討論会, 

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    Event date: 2016.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  245. 合成化学から生活を豊かにする機能性マテリアル創出へ! Invited

    忍久保洋

    タワーホール船堀 

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    Event date: 2016.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  246. Synthesis of Exotic π-Conjugated Systems with Unique Properties Invited

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    Event date: 2016.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  247. 有機金属化学で挑むπ電子化合物の合成 Invited

    忍久保洋

    京都大学化学研究所 

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    Event date: 2016.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  248. 光誘起電子移動によるアニリン誘導体の酸化を鍵段階とするα,β-不飽和カルボニル化合物のα位選択的アリール化反応

    安藤祐樹, 鎌塚拓人, 三宅 由寛, 忍久保洋,

    第63回有機金属化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  249. ベンゾノルコロールの合成とその反芳香族性

    吉田拓矢, 平岡勇哉, 高橋功太郎, 山田 容子, 忍久保 洋

    第27回基礎有機化学討論会  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  250. 芳香族求核置換反応を基盤とするアザ[8]サーキュレン類の合成

    永田裕也, 加藤祥平, 三宅由寛, 忍久保洋

    第27回基礎有機化学討論会,  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  251. ノルコロール銅錯体の合成と物性

    米澤翼, 平岡勇哉, 忍久保洋,

    第27回基礎有機化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  252. アザコラヌレン二量体の合成とその性質

    横井寛生, 廣戸聡, 酒巻大輔, 関修平, 忍久保洋,

    第27回基礎有機化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  253. メゾ位にケイ素およびリンを含む新規ポルフィリノイドの合成

    大森裕土, 廣戸聡, 武田洋平, 南方聖司, 忍久保洋,

    第27回基礎有機化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  254. 積層型反芳香族ノルコロール二量体による三次元芳香族性の発現

    野澤遼, Won Young Cha, 久木一朗, 清水宗治, Dongho Kim, 忍久保洋,

    第27回基礎有機化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  255. 転位反応を用いた反芳香族ノルコロールの位置選択的臭素化

    川島弘之, 廣戸聡, 忍久保洋

    第27回基礎有機化学討論会, 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  256. ヘテロ芳香環置換基を有するノルコロールの合成および物性

    板淵史栞, 吉田拓矢, 野澤 遼, 忍久保洋,

    第27回基礎有機化学討論会,  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  257. 芳香環架橋アザバッキーボウル二量体の合成

    武田基希, 横井寛生, 廣戸 聡, 忍久保 洋

    第27回基礎有機化学討論会,  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  258. テトラピリジルジアザポルフィリン金属三核錯体の合成と性質

    平岡勇哉, 三宅由寛, 忍久保 洋

    第27回基礎有機化学討論会,  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  259. テトラゲルマテトラチア[8]サーキュレンの合成と物性

    赤堀周平, 酒井隼人, 羽曾部 卓, 三宅由寛, 忍久保洋

    第27回基礎有機化学討論会,  

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    Event date: 2016.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  260. Synthesis and properties of azacorannulenes International conference

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    Event date: 2016.8

    Language:English   Presentation type:Poster presentation  

    Country:Indonesia  

  261. Diversity-Oriented Synthesis of Tetrathia[8]circulenes by C-H Borylation and Annulation International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  262. Azacorroles from Nitrogen Bridged Bisdipyrrins International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:China  

  263. Functionalization of an Antiaromatic Porphyrinoid Norcorrole Ni(II) Complex Invited International conference

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    Event date: 2016.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:China  

  264. Highly-twisted porphyrin oligomers: Synthesis, characterization and applications Invited International conference

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    Event date: 2016.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:China  

  265. Tetrabenzonorcorrole: a benzo-fused 16π antiaromatic porphyrinoid International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:China  

  266. Chemo- and Regioselective Reduction of Diazaporphyrins International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:China  

  267. Synthesis and Properties of Stacked Antiaromatic Norcorrole Dimer International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:China  

  268. Synthesis and Properties of Tetrapyridyldiazaporphyrin International conference

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    Event date: 2016.7

    Language:English   Presentation type:Poster presentation  

    Country:China  

  269. 平面および曲面含窒素π電子系の合成 Invited

    忍久保洋

    関西学院大学 

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    Event date: 2016.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  270. Synthesis and Properties of Antiaromatic Porphyrins Invited International conference

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    Event date: 2016.5 - 2016.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  271. Synthesis of Nitrogen-Embedded Buckybowl and Its Strong Association Behavior with C60 Invited International conference

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    Event date: 2016.5 - 2016.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  272. Synthesis of Tetrathia[8]circulenes with Diverse Substituents snd Their Properties in Solid State

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    Event date: 2016.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  273. アザヘリセンを基盤とした8の字型キラル発光分子の合成

    牛山 綾子,河合 壯,廣戸 聡,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  274. 置換基効果を利用した反芳香族ノルコロールの物性発現

    吉田 拓矢,廣戸 聡,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  275. 多様な置換基をもつテトラチア[8]サーキュレンの合成と固体物性

    加藤 祥平,芹澤 祐真,酒巻 大輔,関 修平,三宅 由寛,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  276. 芳香族求核置換反応によるアザ[8]サーキュレン類の合成

    永田 裕也,加藤 祥平,三宅 由寛,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  277. 反芳香族ノルコロールの新規周辺官能基化反応の開発

    川島 弘之,野澤 遼,廣戸 聡,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  278. メゾ位にケイ素およびリンを含む新規ポルフィリノイドの合成

    大森 裕土,廣戸 聡,武田 洋平,南方 聖司,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  279. 脱炭酸的アリール化によるグラフェン量子ドットの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    第63回応用物理学会春季学術講演会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  280. 反芳香族ノルコロールの積層型二量体の合成と物性

    野澤 遼,廣戸 聡,清水 宗治,Young, Cha Won ,Kim, Dongho,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  281. 脱炭酸的アリール化によるグラフェン量子ドットの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  282. ジアザポルフィリンの選択的還元による新規ポルフィリノイドの構築

    山路 文香,三宅 由寛,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  283. 中心に窒素原子をもつバッキーボウルの物性と フラーレン包接挙動

    横井 寛生,平岡 勇哉,廣戸 聡,酒巻 大輔,関 修平,忍久保 洋

    日本化学会第96春季年会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  284. 金属錯体上での有機反応による新規ポルフィリンの合成

    忍久保 洋

    Chemistry in Paradise 2016 ~合成化学が創る未来~ 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  285. Studies of Substituent Effects on Antiaromatic Norcorroles

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  286. 中心に窒素原子をもつバッキーボウルの合成と物性の解明

    横井 寛生,平岡 勇哉,廣戸 聡,忍久保 洋

    IGER 2015年度年次報告会 

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  287. アリール基の導入によるグラフェンの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    IGER 2015年度年次報告会 

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  288. Conformation control of nonplanar π-conjugated diporphyrins using substitents and axial ligands

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  289. 位置選択的な直接官能基化を利用したノルコロール2量体の合成

    野澤 遼,廣戸 聡,忍久保 洋

    IGER 2015年度年次報告会 

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  290. Synthesis of Novel Porphyrinoids Containing Silicon and Phosphorus Atoms

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    Event date: 2016.1

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  291. 平面および曲面含窒素π電子系の合成

    忍久保 洋

    京都大学理学研究科化学専攻特別セミナー 

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    Event date: 2015.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  292. Synthesis of distorted compounds by oxidation of aminophenanthrene International conference

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    Event date: 2015.12

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  293. Straightforward synthesis of highly twisted porphyrin oligomers International conference

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:United States  

  294. Antiaromatic Norcorrol Batteries International conference

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    Event date: 2015.12

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  295. 脱炭酸的アリール化によるグラフェン量子ドットの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    第5回酸化グラフェンシンポジウム 

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    Event date: 2015.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  296. ケイ素およびリンを含む新規ポルフィリノイドの合成

    大森 裕土,廣戸 聡,武田 洋平,南方 聖司,忍久保 洋

    第42回有機典型元素化学討論会 

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    Event date: 2015.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  297. 脱水素環化を鍵とするテトラシラテトラチア[8]サーキュレンの合成と物性

    芹澤 祐真,赤堀 周平,加藤 祥平,三宅 由寛,忍久保 洋

    第42回有機典型元素化学討論会 

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    Event date: 2015.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  298. テトラチア[8]サーキュレンの多様性指向合成と固体物性

    加藤 祥平,芹澤 祐真,酒巻 大輔,関 修平,三宅 由寛,忍久保 洋

    第42回有機典型元素化学討論会 

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    Event date: 2015.12

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  299. 位置選択的な直接官能基化を利用したノルコロール2量体の合成

    野澤 遼,廣戸 聡,忍久保 洋

    ITbM/IGER Chemistry Workshop 2015 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  300. 反芳香族性ノルコロールの置換基効果の研究

    吉田 拓矢,辛 知映,廣戸 聡,忍久保 洋

    第2回π造形科学若手研究会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  301. 中心に窒素原子をもつバッキーボウルの合成と物性の解明

    横井 寛生,平岡 勇哉,廣戸 聡,忍久保 洋

    第2回π造形科学若手研究会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  302. アリール基の導入によるグラフェンの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    第2回π造形科学若手研究会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  303. 位置選択的な直接官能基化を利用したノルコロール2量体の合成

    野澤 遼,廣戸 聡,忍久保 洋

    第2回π造形科学若手研究会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  304. ケイ素およびリンを含む新規ポルフィリノイドの合成

    大森 裕土,廣戸 聡,武田 洋平,南方 聖司,忍久保 洋

    第2回π造形科学若手研究会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  305. 新規10-ヘテロコロールの合成

    大森 裕土,廣戸 聡,武田 洋平,南方 聖司,忍久保 洋

    分子科学研究所リトリート研修 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  306. 中心に窒素原子をもつバッキーボウルの合成と物性の解明

    横井 寛生,平岡 勇哉,廣戸 聡,忍久保 洋

    名大・分子研リトリート研修 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  307. 脱炭酸的アリール化によるグラフェン量子ドットの可溶化と発光色の制御

    小田 一磨,廣戸 聡,忍久保 洋

    名大・分子研リトリート研修 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  308. Diversity-Oriented Synthesis of Tetrathia[8]circulenes by C-H Borylation and Annulation

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    Event date: 2015.11

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  309. 反芳香族ノルコロールの新規周辺官能基化反応の開発

    川島 弘之,野澤 遼,福岡 嵩規,廣戸 聡,忍久保 洋

    第46回中部化学関係学協会支部連合秋期大会 

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    Event date: 2015.11

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  310. Oxidation of tetrathia[8]circulenes International conference

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    Event date: 2015.11

    Language:English   Presentation type:Poster presentation  

    Country:Japan  

  311. 10-アザコロールの汎用的合成法の開発

    大森 裕土,廣戸 聡,忍久保 洋

    ITbM/IGER Chemistry Workshop 

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    Event date: 2015.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  312. 中心に窒素原子をもつバッキーボウルの合成と物性の解明

    横井 寛生,平岡 勇哉,廣戸 聡,忍久保 洋

    ITbM/IGER Chemistry Workshop 

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    Event date: 2015.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  313. 還元反応による反芳香族ジヒドロジアザポルフィリンの合成

    山路 文香,三宅 由寛,忍