Faculty Profiles - KAMIGAITO, Masami

Papers - KAMIGAITO, Masami

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Proton Transfer Anionic Polymerization with C–H Bond as the Dormant Species Reviewed

M. Uchiyama, N. Ohira, K. Yamashita, K. Sagawa, and M. Kamigaito

Nature Chemistry Vol. 16 ( 10 ) page： 1630 - 1637 2024.10

’Living’ Anionic Polymerization through Reversible Activation of C–H Bonds with a Base Catalyst Invited Reviewed

M. Uchiyama and M. Kamigaito

Nature Chemistry Vol. 16 ( 10 ) page： 1582 - 1583 2024.10

Step-Growth Irreversible Deactivation Radical Polymerization: Synergistic Developments with Chain-Growth Reversible Deactivation Radical Polymerization Invited Reviewed

M. Kamigaito

Bull. Chem. Soc. Jpn Vol. 97 ( 7 ) page： uoae069 2024.7

Radical-Promoted Single-Unit Monomer Insertion (SUMI) [aka. Reversible-Deactivation Radical Addition (RDRA)] Invited Reviewed International coauthorship

C. Boyer, M. Kamigaito, K. Satoh, and G. Moad

Prog. Polym. Sci. Vol. 138 page： 101648 2023.3

Cationic RAFT and DT polymerization Invited Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito,

Prog. Polym. Sci. Vol. 124 page： 101485 2022.1

Degenerative Chain-Transfer Process: Controlling All Chain-Growth Polymerizations and Enabling Novel Monomer Sequences Invited Reviewed

M. Kamigaito, K. Satoh, M. Uchiyama

J. Polym. Sci., Part A, Polym. Chem. Vol. 57 ( 3 ) page： 243 - 254 2019.2

Proton Transfer Anionic Polymerization of Methyl Methacrylate with Ligands for Dual Control of Molecular Weight and Tacticity Invited Reviewed

K. Sagawa, M. Uchiyama, H. Watanabe, C. Homma, and M. Kamigaito

Precis. Chem. Vol. 2 ( 12 ) page： 628 - 633 2024.12

Synthesis of Degradable Polymers through 1,5-Shift Radical Isomerization Polymerizations of Vinyl Ether Derivatives with a Cleavable Bond Invited Reviewed

M. Uchiyama, M. Imai, and M. Kamigaito

Polym. J. Vol. in press 2024.4

Evolutions of Precision Radical Polymerizations from Metal-Catalyzed Radical Addition: Living Polymerization, Step-Growth Polymerization, and Monomer Sequence Control Invited Reviewed

M. Kamigaito

Polym. J. Vol. 54 ( 12 ) page： 1391 - 1405 2022.12

Synergistic Advances in Living Cationic and Radical Polymerizations Invited Reviewed

M. Kamigaito, M. Sawamoto

Macromolecules Vol. 53 ( 16 ) page： 6749 - 6753 2020.8

Cationic β-Scission of C–H and C–C Bonds for Selective Dimerization and Subsequent Sulfur-Free RAFT Polymerization of α-Methylstyrene and Isobutylene Reviewed

T. Tanimoto, M. Uchiyama, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 62 ( 43 ) page： e202307791 2023.10

Direct Radical Copolymerizations of Thioamides to Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbone Reviewed

H. Watanabe and M. Kamigaito

J. Am. Chem. Soc. Vol. 145 ( 20 ) page： 10948 - 10953 2023.5

Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals Reviewed

M. Uchiyama, Y. Murakami, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 62 ( 4 ) page： e202215021 2023.1

Sulfur-Free Radical RAFT Polymerization of Methacrylates in Homogeneous Solution: Design of exo-Olefin Chain-Transfer Agents (R-CH2C(=CH2)Z) Reviewed

M. Amano, M. Uchiyama, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 61 ( 52 ) page： e202212633 2022.12

Asymmetric Cationic Polymerization of Benzofuran through a Reversible Chain-Transfer Mechanism: Optically Active Polybenzofuran with Controlled Molecular Weights Reviewed

J. Am. Chem. Soc. Vol. 144 ( 23 ) page： 10429 - 10437 2022.6

Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions Reviewed

M. Miyajima, K. Satoh, T. Horibe, K. Ishihara, M. Kamigaito

J. Am. Chem. Soc. Vol. 142 ( 44 ) page： 18955 - 18962 2020.11

Metal-Catalyzed Living Radical Polymerization Invited Reviewed

M. Kamigaito, T. Ando, M. Sawamoto

Chem. Rev. Vol. 101 ( 12 ) page： 3689 2001.12

Stereospecific Living Radical Polymerization: Dual Control of Chain Length and Tacticity for Precision Polymer Synthesis Invited Reviewed

K. Satoh, M. Kamigaito

Chem. Rev. Vol. 109 ( 11 ) page： 5120-5156 2009.11

Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris-(triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization Reviewed

M. Kato, M. Kamigaito, M. Sawamoto, and T. Higashimura

Macromolecules Vol. 28 page： 1721 1995

Structures and Properties of Temperature-Responsive Gels with Homogeneous Networks Prepared by Photogelation of Four-Armed Star-Shaped Poly(N-isopropylacrylamide) Invited Reviewed

N. Itaya, C. Norioka, K. Satoh, M. Kamigaito, A. Kawamura, and T. Miyata

Vol. in press 2025.1

Nature Communications from the point of view of our very fast authors Invited Reviewed

M. Kamigaito

Nat. Commun. Vol. 15 page： 306 2024.1

Biocompatible Thermoresponsive N-Isopropyl-N-(3-(isopropylamino)-3-oxopropyl)acrylamide-Based Random Copolymer: Synthesis and Studies of Its Composition Dependent Properties and Anticancer Drug Delivery Efficiency Reviewed International coauthorship

Vol. 10 ( 41 ) page： 8462 - 8477 2022.11

植物由来ビニル化合物の特徴を活かしたバイオベースポリマー開発 Invited Reviewed

佐藤浩太郎, 上垣外正己

milsil 自然と科学の情報誌［ミルシル］ Vol. 15 ( 6 ) page： 15 - 17 2022.11

Hydrophilic Bio-Based Polymers by Radical Copolymerization of Cyclic Vinyl Ethers Derived from Glycerol Reviewed

R. Kashima, A. Kajita, T. Kubo, M. Kamigaito, and K. Satoh

Chem. Commun. Vol. 58 ( 63 ) page： 8766 - 8769 2022.8

One-Pot Synthesis of Structure-Controlled Temperature-Responsive Polymer Gels Invited Reviewed

T. Sakai, N. Ito, M. Hara, T. Seki, M. Uchiyama, M. Kamigaito, K. Satoh, T. Hoshino, and Y. Takeoka

Vol. 13 ( 29 ) page： 4230 - 4240 2022.8

Periodically Functionalized Sequence-Regulated Vinyl Polymers via Iterative Atom Transfer Radical Additions and Acyclic Diene Metathesis Polymerization Invited Reviewed

M. Miyajima, K. Satoh, and M. Kamigaito

Macromol. Chem. Phys. Vol. 223 ( 12 ) page： 2100426 2022.6

Model and Terpenoid-Derived exo-Methylene 6-Membered Conjugated Dienes: Comprehensive Studies on Cationic and Radical Polymerizations of Substituted 3-Methylenecyclohexenes Invited Reviewed International coauthorship

T. Nishida, K. Satoh, M. Tamura, Y. Li, K. Tomishige, M. Kamigaito

Macromolecules Vol. 55 ( 6 ) page： 2300 - 2309 2022.3

Acridinium salts as photoredox organocatalysts for photomediated cationic RAFT and DT polymerizations of vinyl ethers Invited Reviewed

Matsuda Marina, Uchiyama Mineto, Itabashi Yuki, Ohkubo Kei, Kamigaito Masami

Polym. Chem. Vol. 13 ( 8 ) page： 1031 - 1039 2022.2

Mechanical Properties of Homogeneous Polymer Networks Prepared by Star Polymer Synthesis Methods Reviewed

Y. Baba, G. Gao, M. Hara, T. Seki, K. Satoh, M. Kamigaito, T. Hoshino, K. Urayama, Y. Takaoka

Macromolecules Vol. 54 ( 22 ) page： 10468 - 10476 2021.11

植物由来原料に基づく新規ビニルポリマーの精密合成と材料設計 Invited Reviewed

佐藤浩太郎, 上垣外正己

日本接着学会誌 Vol. 57 ( 10 ) page： 418-425 2021.10

Hybridization of Step-/Chain-Growth and Radical/Cationic Polymerizations Using Thioacetals as Key Components for Triblock, Periodic and Random Multiblock Copolymers with Thermoresponsiveness Invited Reviewed

M. Uchiyama, M. Osumi, K. Satoh, M. Kamigaito

Macromol. Rapid Commun. Vol. 42 ( 18 ) page： 2100192 2021.9

Nonturbid Fast Temperature-Responsive Hydrogels with Homogeneous Three-Dimensional Networks by Two Types of Star Polymer Synthesis Methods Reviewed

D. W. Kwon, Y. Jochi, Y. Okaya, T. Seki, K. Satoh, M. Kamigaito, T. Hoshino, K. Urayama, Y. Takeoka

Macromolecules Vol. 54 ( 12 ) page： 5750 - 5764 2021.6

Terpenoid-Derived Conjugated Dienes with exo-Methylene and a 6-Membered Ring: High Cationic Reactivity, Regioselective Living Cationic Polymerization, and Random and Block Copolymerization with Vinyl Ethers Invited Reviewed International coauthorship

T. Nishida, K. Satoh, M. Tamura, Y. Li, K. Tomishige, S. Caillol, V. Ladmiral, M. Vayer, F. Mahut, C. Sinturel, M. Kamigaito

Polym. Chem. Vol. 12 ( 9 ) page： 1186 - 1198 2021.3

Stereospecific Cationic RAFT Polymerization of Bulky Vinyl Ethers and Stereoblock Poly(vinyl Alcohol) via Mechanistic Transformation to Radical RAFT Polymerization of Vinyl Acetate Invited Reviewed

M. Uchiyama, K. Satoh, M. Kamigaito

Giant Vol. 5 page： 100047 2021.3

Sequence-Regulated Vinyl Polymers via Iterative Atom Transfer Radical Additions and Acyclic Diene Metathesis Polymerization Invited Reviewed

M. Miyajima, K. Satoh, M. Kamigaito

Polym. Chem. Vol. 12 ( 3 ) page： 423 - 431 2021.1

Biobased Polymers via Radical Homopolymerization and Copolymerization of a Series of Terpenoid-Derived Conjugated Dienes with exo-Methylene and 6-Membered Ring Invited Reviewed

T. Nishida, K. Satoh, M. Kamigaito

Molecules Vol. 25 ( 24 ) page： 5890 2020.12

ポリマーの立体構造制御で物性アップ—キラル触媒を用いた立体選択重合・立体特異性重合 Invited

内山峰人, 上垣外正己

化学 Vol. 75 ( 11 ) page： 70 - 71 2020.11

Epoxy-Functionalised 4-Vinylguaiacol for the Synthesis of Bio-Based, Degradable Star Polymers via a RAFT/ROCOP Strategy Reviewed International coauthorship

T. M. McGuire, M. Miyajima, M. Uchiyama, A. Buchard, M. Kamigaito

Polym. Chem. Vol. 11 ( 36 ) page： 5844 - 5850 2020.9

Progress and Perspectives beyond Traditional RAFT Polymerization Reviewed International coauthorship

M. D. Nothling, Q. Fu, A. Reyhani, S. Allison-Logan, K. Jung, J. Zhu, M. Kamigaito, C. Boyer, G. G. Qiao

Adv. Sci. Vol. 7 ( 20 ) page： 2001656 2020.8

Bio-Based Cycloolefin Polymers: Carvone-Derived Cyclic Conjugated Diene with Reactive exo-Methylene Group for Regioselective and Stereospecific Living Cationic Polymerization Reviewed

T. Nishida, K. Satoh, S. Nagano, T. Seki, M. Tamura, Y. Li, K. Tomishige, M. Kamigaito

ACS Macro Lett. Vol. 9 ( 9 ) page： 1178 - 1183 2020.8

Thiol-Ene Cationic and Radical Reactions: Cyclization, Step-Growth, and Concurrent Polymerizations for Thioacetal and Thioether Units Reviewed

M. Uchiyama, M. Osumi, K. Satoh, M. Kamigaito

Angew. Chem. Int. Ed. Vol. 59 ( 17 ) page： 6832 - 6838 2020.4

Precise Synthesis of a Homogeneous Thermoresponsive Polymer Network Composed of Four-Branched Star Polymers with a Narrow Molecular Weight Distribution Reviewed

Y, Okaya, Y. Jochi, T. Seki, K. Satoh, M. Kamigaito, T. Hoshino, T. Nakatani, S. Fujinami, M. Takata, and Y. Takeoka,

Macromolecules Vol. 53 ( 1 ) page： 374-386 2020.1

Interconvertible and Switchable Cationic/PET-RAFT Copolymerization Triggered by Visible Light Invited

K. Satoh, Z. Sun, M. Uchiyama, M. Kamigaito, J. Xu, and C. Boyer

Polym. J. Vol. 52 ( 1 ) page： 65-73 2020.1

Bio-Based Vinylphenol Family: Synthesis via Decarboxylation of Naturally Occurring Cinnamic Acids and Living Radical Polymerization for Functionalized Polystyrenes Invited Reviewed

H. Takeshima, K. Satoh, and M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 58 ( 1 ) page： 91-100 2020.1

1:3 ABAA Sequence-Regulated Substituted Polymethylenes via Alternating Radical Copolymerization of Methyl Cinnamate and Maleic Anhydride Followed by Post-Polymerization Reactions Invited Reviewed

Y. Terao, S. Sugihara, K. Satoh, and M. Kamigaito

Eur. Polym. J. Vol. 120 page： 109225 2019.11

Cationic Polymerization via Activation of Alkoxyamines Using Photoredox Catalysts Invited Reviewed

M. Konya, M. Uchiyama, K. Satoh, and M. Kamigaito

ChemPhotoChem Vol. 3 ( 11 ) page： 1100-1108 2019.11

Fully Bio-Based Polymer Blend of Polyamide 11 and Poly(vinylcatechol) Showing Thermodynamic Miscibility and Excellent Engineering Properties Reviewed

T. Hirai, J. Kawada, M. Narita, T. Ikawa, H. Takeshima, K. Satoh, and M. Kamigaito

Polymer Vol. 181 page： 121667 2019.10

A User-Friendly Living Cationic Polymerization: Degenerative Chain-Transfer Polymerization of Vinyl Ethers by Simply Using Mixtures of Weak and Superstrong Protonic Acids Invited Reviewed

M. Uchiyama, M. Sakaguchi, K. Satoh, and M. Kamigaito

Chinese J. Polym. Sci. Vol. 37 ( 9 ) page： 851-857 2019.9

可逆的連鎖移動機構に基づくリビングカチオン重合による精密高分子合成 Invited Reviewed

内山峰人, 佐藤浩太郎, 上垣外正己

材料の科学と工学 Vol. 56 ( 4 ) page： 14-17 2019.8

Editorial on special issue for MoDeSt2018

Nishida Haruo, Kamigaito Masami, Abe Hideki

POLYMER DEGRADATION AND STABILITY Vol. 166 page： 237 - 237 2019.8

Ferulic Acid-Based Reactive Core-Shell Latex by Seeded Emulsion Polymerization Reviewed

W.-S. J. Li, V. Ladmiral, H. Takeshima, K. Satoh, M. Kamigaito, M. Semsarilar, C. Negrell, P. Lacoix-Desmazes, and S. Caillol

Polym. Chem. Vol. 10 ( 23 ) page： 3116-3126 2019.6

交換連鎖移動機構による精密高分子合成 Invited Reviewed

上垣外正己, 佐藤浩太郎, 内山峰人

触媒 Vol. 61 ( 3 ) page： 118-123 2019.6

Halogenation of Propagating Terminal in Anionic Polymerization of Isoprene for the Synthesis of Block Copolymers Reviewed

K. Satoh, Y.Mori, and M. Kamigaito

Kobunshi Ronbunshu Vol. 76 ( 3 ) page： 234-240 2019.5

Construction of Sequence-Regulated Vinyl Copolymers via Iterative Single Vinyl Monomer Additions and Subsequent Metal-Catalyzed Step-Growth Radical Polymerization Reviewed

K Satoh, K. Ishizuka, T. Hamada, M. Handa, T. Abe, S. Ozawa, M. Miyajima, and M. Kamigaito

Macromolecules Vol. 52 ( 9 ) page： 3327-3341 2019.5

Cooperative Reduction of Various RAFT Polymer Terminals using Hydrosilane and Thiol via Polarity Reversal Catalysis Invited Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito

Chem. Commun. Vol. 55 ( 37 ) page： 5327-5330 2019.5

R-Cl/SnCl4/n-Bu4NCl-Induced Direct Living Cationic Polymerization of Naturally-Derived Unprotected 4-Vinylphenol, 4-VInylguiacol, and 4-Vinylcatechol in CH3CN Reviewed

H. Takeshima, K. Satoh, and M. Kamigaito

Polym. Chem. Vol. 10 ( 10 ) page： 1192-1201 2019.3

Valencene as a Naturally Occurring Sesquiterpene Monomer for Radical Copolymerization with Maleimide to Induce Concurrent 1:1 and 1:2 Propagation Reviewed

H. Hashimoto, H. Takeshima, T. Nagai, M. Uchiyama, K. Satoh, and M. Kamigaito

Polym. Degrad. Stab Vol. 161 page： 183-190 2019.3

Direct through Anionic, Cationic, and Radical Active Species: Terminal Carbon-Halogen Bond for "Controlled"/Living Polymerizations of Styrene Invited Reviewed

K. Satoh, Y.Mori, and M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 57 ( 3 ) page： 465–473 2019.2

Helix-Sense-Selective Copolymerization of Triphenylmethyl Methacrylate with Chiral 2-Isopropenyl-4-phenyl-2-oxazoline Invited Reviewed

J. Shen, N. Ikeda, W. Bi, K. Satoh, M. Kamigaito, and Y. Okamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 57 ( 3 ) page： 441–447 2019.2

Professor Mitsuo Sawamoto-sensei and innovator in polymer synthesis

Ouchi Makoto, Terashima Takaya, Kamigaito Masami, Satoh Kotaro

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY Vol. 57 ( 3 ) page： 197 - 198 2019.2

Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions Invited Reviewed

Y. Terao, K. Satoh, and M. Kamigaito

Biomacromolecules Vol. 20 ( 1 ) page： 192-203 2019.1

Naturally-Derived Amphiphilic Polystyrenes Prepared by Aqueous Controlled/Living Cationic Polymerization and Copolymerization of Vinylguaiacol with R-OH/BF3OEt2 Reviewed

H. Takeshima, K. Satoh, and M. Kamigaito

Polymers Vol. 10 ( 12 ) page： 1404 2018.12

Scalable Synthesis of Bio-Based Functional Styrene: Protected Vinyl Catechol from Caffeic Acid and Controlled Radical and Anionic Polymerizations Thereof Reviewed

H. Takeshima, K. Satoh, and M. Kamigaito

ACS Sustainable Chem. Eng. Vol. 6 ( 11 ) page： 13681-13686 2018.11

Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion Reviewed

Z. Huang, B. B. Noble, N. Corrigan, Y. Chu, K. Satoh, D. S. Thomas, C. J. Hawker, G. Moad, M. Kamigaito, M. L. Coote, C. Boyer, and J. Xu

J. Am. Chem. Soc. Vol. 140 ( 41 ) page： 13392–13406 2018.10

Spontaneous Synthesis of a Homogeneous Thermoresponsive Polymer Network Composed of Polymers with a Narrow Molecular Weight Distribution Reviewed

Y. Jochi, T. Seki, T. Soejima, K. Satoh, M. Kamigaito, and Y. Takeoka

NPG Asia Materials Vol. 10 page： 840–848 2018.8

Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical Interconvertible Simultaneous Polymerization Invited Reviewed

K. Satoh, Y. Fujiki, M. Uchiyama, and M. Kamigaito

ACS Symp. Ser. Vol. 1284 page： 323–334 2018.8

Synthesis and Stereocomplexation of PMMA-Based Star Polymers Prepared by a Combination of Stereospecific Anionic Polymerization and Crosslinking Radical Polymerization Reviewed

N. Usuki, K. Satoh, and M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 56 ( 11 ) page： 1123+1127 2018.6

Synthesis of PEVE-b-P(CTFE-alt-EVE) Block Copolymers by Sequential Cationic and Radical RAFT Polymerization Reviewed

M. Guerre, M. Uchiyama, G. Lopez, B. Améduri, K. Satoh, M. Kamigaito, and V. Ladmiral

Polym. Chem. Vol. 9 ( 3 ) page： 352-361 2018.1

交換連鎖移動機構に基づく精密重合 Invited Reviewed

上垣外正己, 佐藤浩太郎, 内山峰人

高分子 Vol. 67 ( 1 ) page： 30-33 2018.1

Synthesis of Isotactic-block-Syndiotactic Poly(methyl Methacrylate) via Stereospecific Living Anionic Polymerizations in Combination with Metal-Halogen Exchange, Halogenation, and Click Reactions Reviewed

N. Usuki, K. Satoh, and M. Kamigaito

Polymers Vol. 9 ( 12 ) page： 723 (14 pages) 2017.12

Diverse Approaches to Star Polymers via Cationic and Radical RAFT Cross-Linking Reactions Using Mechanistic Transformation Reviewed

M. Uchiyama, K. Satoh, T. G. McKenzie, Q. Fu, G. G. Qiao, and M. Kamigaito

Polym. Chem. Vol. 8 ( 38 ) page： 5972–5981 2017.10

Diverse approaches to star polymers <i>via</i> cationic and radical RAFT cross-linking reactions using mechanistic transformation

Uchiyama, M; Satoh, K; McKenzie, TG; Fu, Q; Qiao, GG; Kamigaito, M

POLYMER CHEMISTRY Vol. 8 ( 38 ) page： 5972 - 5981 2017.10

One-Shot Controlled/Living Radical Copolymerization for Various Comonomer Sequence Distributions via Dual Radical and Cationic Active Species from RAFT Terminals Reviewed

K. Satoh, H. Hashimoto, S. Kumagai, H. Aoshima, M. Uchiyama, R. Ishibashi, T. Fujiki, and M. Kamigaito

Polym. Chem. Vol. 8 ( 34 ) page： 5002-5011 2017.9

Bio-Based Functional Styrene Monomers Derived from Naturally Occurring Ferulic Acid for Poly(vinylcatechol) and Poly(vinylguaiacol) via Controlled Radical Polymerization Reviewed

H. Takeshima, K. Satoh, and M. Kamigaito

Macromolecules Vol. 50 ( 11 ) page： 4206-4216 2017.6

Synthesis of Syndiotactic Macrocyclic Poly(methyl Methacrylate) via Transformation of the Growing Terminal in Stereospecific Anionic Polymerization Reviewed

N. Usuki, K. Satoh, and M. Kamigaito

Macromol. Chem. Phys Vol. 218 ( 12 ) page： 1700041 (10 pages) 2017.6

可逆的連鎖移動機構によるメタルフリーのリビングカチオン重合 Invited Reviewed

内山峰人, 佐藤浩太郎, 上垣外正己

日本接着学会誌 Vol. 53 ( 5 ) page： 179-187 2017.5

Combination of Cationic and Radical Polymerizations: A Versatile Route to Well-Defined Poly(ethyl Vinyl Ether)-block-Poly(vinylidene Fluoride) Block Copolymers Reviewed

M. Guerre, M. Uchiyama, E. Folagado, M. Semsarilar, B. Améduri, K. Satoh, M. Kamigaito, and V. Ladmiral

ACS Macro Lett Vol. 6 ( 4 ) page： 393-398 2017.4

Combination of Cationic and Radical RAFT Polymerizations: A Versatile Route to Well-Defined Poly(ethyl vinyl ether)-<i>block</i>-poly(vinylidene fluoride) Block Copolymers

Guerre, M; Uchiyama, M; Folgado, E; Semsarilar, M; Améduri, B; Satoh, K; Kamigaito, M; Ladmiral, V

ACS MACRO LETTERS Vol. 6 ( 4 ) page： 393 - 398 2017.4

BAB-random-C Monomer Sequence via Radical Terpolymerization of Limonene (A), Maleimide (B), and Methacrylate (C): Terpene Polymers with Randomly Distributed Periodic Sequences Reviewed

M. Ojika, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 56 ( 7 ) page： 1789-1793 2017.2

Light Leads to Ultra-Long Polymer Chains in Water Invited Reviewed

M. Kamigaito and K. Satoh

Chem. Vol. 2 ( 1 ) page： 13-15 2017.1

Control of Stereochemistry in Atom Transfer Radical Addition and Step-Growth Radical Polymerization by Chiral Transition Metal Catalysts Invited Reviewed

T. Soejima, K. Satoh, and M. Kamigaito

Tetrahedron Vol. 72 ( 48 ) page： 7657-7664 2016.12

Enantioseparation Using Cellulose Tris(3,5-dimehtylphenylcarbamate) as Chiral Stationary Phase for HPLC: Influence of Molecular Weight of Cellulose Reviewed

Y. Okada, C. Yamamoto, M. Kamigaito, Y. Gao, J. Shen, and Y. Okamoto

Molecules Vol. 21 ( 11 ) page： 1484 2016.11

Diversifying Cationic RAFT Polymerization with Various Counteranions: Generation of Cationic Species from Organic Halides and Various Metal Salts Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito

ACS Macro Lett. Vol. 5 ( 10 ) page： 1157-1161 2016.10

Sequence-regulated vinyl copolymers with acid and base monomer units by atom transfer radical addition and alternating radical copolymerization Reviewed

T. Soejima, K. Satoh, and M. Kamigaito

Polym. Chem. Vol. 7 ( 29 ) page： 4833-4841 2016.8

Beyond Traditional RAFT: Alternative Activation of Thiocarbonylthio Compounds for Controlled Polymerization Reviewed

T. G. McKenzie, Q. Fu, M. Uchiyama, K. Satoh, J. Xu, C. Boyer, M. Kamigaito, and G. G. Qiao

Adv. Sci. Vol. 3 page： 1500394 2016.5

Crosslinked Nanocellular Polymer Films: Water and Oil Repellent Anti-Reflection Coating Reviewed

H. Yokoyama, C. Dutriez, K. Satoh, and M. Kamigaito

Polym. J. Vol. 48 ( 4 ) page： 497-501 2016.4

Fullerene Peapod Nanoparticles as Organic Semiconductor-Electrode Interface Layer Reviewed

J. M. Ren, J. Subbiah, B. Zhang, K. Ishitake, K. Satoh, M. Kamigaito, G. G. Qiao, E. H. H. Wong, and W. W. H. Wong

Chem. Commun. Vol. 52 ( 16 ) page： 3356-3359 2016.2

A Phosphonium Intermediate for Cationic RAFT Polymerization Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito

Polym. Chem. Vol. 7 ( 7 ) page： 1387-1396 2016.2

Stereoregular High-Density Bottlebrush Polymer and Its Organic Nanocrystal Stereocomplex through Triple-Helix Formation Reviewed

J. M. Ren, K. Ishitake, K. Satoh, A. Blencowe, Q. Fu, E. H. H. Wong, M. Kamigaito, and G. G. Qiao

Macromolecules Vol. 49 ( 3 ) page： 788-795 2016.2

Main- and Side-Chain Sequence-Regulated Vinyl Copolymers by Iterative Atom Transfer Radical Additions and 1:1 or 2:1 Alternating Radical Copolymerization Reviewed

T. Soejima, K. Satoh, and M. Kamigaito

J. Am. Chem. Soc. Vol. 138 ( 3 ) page： 944-954 2016.1

Bio-Based Polyketones by Selective Ring-Opening Radical Polymerization of α-Pinene-Derived Pinocarvone Reviewed

H. Miyaji, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 55 ( 4 ) page： 1372-1376 2016.1

炭素—硫黄結合を介する金属触媒フリーの新しいリビングカチオン重合（２）チオエーテルを用いたDT機構によるカチオン重合 Invited Reviewed

内山峰人, 佐藤浩太郎, 上垣外正己

日本ゴム協会誌 Vol. 88 ( 12 ) page： 461-465 2015.12

炭素—硫黄結合を介する金属触媒フリーの新しいリビングカチオン重合（１）チオエステルを用いたRAFT機構によるカチオン重合 Invited Reviewed

内山峰人, 佐藤浩太郎, 上垣外正己

日本ゴム協会誌 Vol. 88 ( 10 ) page： 391-396 2015.10

Thioether-Mediated Degenerative Chain-Transfer Cationic Polymerization: A Simple Metal-Free System for Living Cationic Polymerization Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito

Macromolecules Vol. 48 ( 16 ) page： 5533-5542 2015.8

Monomer Sequence Regulation in Main- and Side-Chains of Vinyl Copolymers: Synthesis of Vinyl Oligomonomers via Sequential Atom Transfer Radical Addition and Their Alternating Radical Copolymerization Invited Reviewed

T. Soejima, K. Satoh, and M. Kamigaito

ACS Macro Lett. Vol. 4 ( 7 ) page： 745-749 2015.7

植物由来のビニルモノマーから新規高分子を合成 Invited Reviewed

上垣外正己, 佐藤浩太郎

現代化学 Vol. 532 page： 24-29 2015.7

植物由来テルペンの精密重合系の開発 Invited Reviewed

佐藤浩太郎, 上垣外正己

高分子論文集 Vol. 72 ( 7 ) page： 421-432 2015.7

Controlled Radical Polymerization of Styrene with Magnetic Iron Oxides Prepared through Hydrothermal, Bioinspired, and Bacterial Processes Reviewed

A. Kanazawa, K. Satoh, S. Kanaoka, M. Kakihana, M. Kobayashi, J. Sato, H. Imai, Y. Oaki, A. Arakaki, K. Katagiri, M. Kamigaito, and S. Aoshima

RSC Adv. Vol. 5 ( 63 ) page： 51122-51129 2015.6

Study of the Effect of Isotacticity on Some Physical Properties of Poly(N-isopropylacrylamide) Reviewed

C. S. Biswas, K. Mitra, A. Singh, K. Ramesh, N. Misra, B. Maiti, A. K. Panda, P. Maiti, M. Kamigaito, Y. Okamoto, and B. Ray

Colloid Polym. Sci, Vol. 293 ( 6 ) page： 1749-1757 2015.6

Periodic Introduction of Water-Tolerant Titanatrane Complex to Poly(NIPAM) Prepared by Simultaneous Step-Growth and Living Radical Polymerization Invited Reviewed

K. Satoh, D. Ito, and M. Kamigaito

ACS Symp. Ser Vol. 1188 page： 1-14 2015.5

Molecular Mapping of Poly(methyl Methacrylate) Super-Helix Stereocomplexes Reviewed

A. J. Christofferson, G. Yiapanis, J. M. Ren, G. G. Qiao, K. Satoh, M. Kamigaito, and I. Yarovsky

Chem. Sci. Vol. 6 ( 2 ) page： 1370-1378 2015.3

Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 54 ( 6 ) page： 1924-1928 2015.2

Interconvertible Living Radical and Cationic Polymerization through Reversible Activation of Dormant Species with Dual Activity Reviewed

H. Aoshima, M. Uchiyama, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 53 ( 41 ) page： 10932-10936 2014.10

ビニルポリマーにおけるモノマー配列制御 Invited Reviewed

佐藤浩太郎, 上垣外正己

高分子 Vol. 63 ( 10 ) page： 715-717 2014.10

Synthesis of Side-Chain-Sequenced Copolymers Using Vinyl Oligomonomers via Sequential Single-Monomer ATRA Invited Reviewed

T. Soejima, K. Satoh, and M. Kamigaito

ACS Symp. Ser Vol. 1170 page： 189-200 2014.9

Renewable β-Methylstyrenes for Bio-Based Heat-Resistant Styrenic Copolymers: Radical Copolymerization Enhanced by Fluoroalcohol and Controlled/Living Copolymerization by RAFT Reviewed

Y. Nonoyama, K. Satoh, and M. Kamigaito

Polym. Chem Vol. 5 ( 9 ) page： 3182-3189 2014.5

Sustainable Cycloolefin Polymer from Pine Tree Oil for Optoelectronics Material: Living Cationic Polymerization of β-Pinene and Catalytic Hydrogenation for High-Molecular-Weight Hydrogenated Poly(β-pinene) Reviewed

K. Satoh, A. Nakahara, K. Mukunoki, H. Sugiyama, H. Saito, and M. Kamigaito

Polym. Chem Vol. 5 ( 9 ) page： 3222-3230 2014.5

Construction of Vinyl Polymer and Polyester or Polyamide Units in a Single Polymer Chain via Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization of Various Monomers Invited Reviewed

M. Mizutani, K. Satoh, and M. Kamigaito

Aust. J. Chem. Vol. 67 ( 4 ) page： 544-554 2014.4

Synthesis of Titanium-Containing Block, Random, End- and Junction-Functionalized Polymers via Ruthenium-Catalyzed Living Radical Polymerization and Direct Observation of Titanium Domains by Electron Microscopy Reviewed

Y. Tsujimoto, K. Satoh, H. Sugimori, H. Jinnai, and M. Kamigaito

Macromolecules Vol. 47 ( 3 ) page： 944-953 2014.2

Stereospecific Cyclic Poly(methyl Methacrylate) and Its Topology-Guided Hierarchically-Controlled Supramolecular Assemblies Reviewed

J. M. Ren, K. Satoh, T. K. Goh, A. Blencowe, K. Nagai, K. Ishitake, A. J. Christofferson, G. Yiapanis, I. Yarovsky, M. Kamigaito, and G. G. Qiao

Angew. Chem. Int. Ed. Vol. 53 ( 1 ) page： 459-464 2014.1

Precision Synthesis of Bio-Based Acrylic Thermoplastic Elastomer by RAFT Polymerization of Itaconic Acid Derivatives Invited Reviewed

K. Satoh, D.-H. Lee, K. Nagai, and M. Kamigaito

Macromol. Rapid Commun. Vol. 35 ( 2 ) page： 161-167 2014.1

植物由来のビニルモノマーを精密に重合して機能性バイオベースポリマーをつくる Invited Reviewed

佐藤浩太郎, 上垣外正己

バイオプラジャーナル ( 51 ) page： 12-17 2013.11

さまざまな植物由来ビニルモノマーの制御重合 Invited Reviewed

佐藤浩太郎, 上垣外正己

接着の技術 Vol. 33 ( 2 ) page： 6-10 2013.10

Periodically Functionalized and Grafted Copolymers via 1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Functional Limonene and Maleimide Derivatives Reviewed

M. Matsuda, K. Satoh, and M. Kamigaito

Macromolecules Vol. 46 ( 14 ) page： 5473-5482 2013.7

A Simple Combination of Higher-Oxidation-State FeX3 and Phosphine or Amine Ligand for Living Radical Polymerization of Styrene, Methacrylate, and Acrylate Reviewed

H. Aoshima, K. Satoh, and M. Kamigaito

Polym. Chem. Vol. 4 ( 12 ) page： 3554-3562 2013.6

Asymmetric Anionic Polymerization of Tris(trimethylsilyl)silyl Methacrylate: A Highly Isotacitc Helical Chiral Polymer Reviewed

K. Ishitake, K. Satoh, M. Kamigaito, and Y. Okamoto

Polym. J. Vol. 45 ( 6 ) page： 676-680 2013.6

Controlled Radical Copolymerization of Naturally-Occurring Terpenes with Acrylic Monomers in Fluorinated Alcohol Invited Reviewed

M. Matsuda, K. Satoh, and M. Kamigaito

KGK-Kautschuk Gummi Kunststoffe Vol. 66 ( 5 ) page： 51-56 2013.5

1:2-Sequence-Regulated Radical Copolymerization of Naturally Occurring Terpenes with Maleimide Derivatives in Fluorinated Alcohol Reviewed

M. Matsuda, K. Satoh, and M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 51 ( 8 ) page： 1774-1785 2013.4

遷移金属触媒による逐次ラジカル重合を用いた精密構造制御ポリマー Invited Reviewed

佐藤浩太郎, 上垣外正己

触媒 Vol. 55 ( 2 ) page： 78-85 2013.4

研究室紹介—北から南から Invited Reviewed

上垣外正己, 佐藤浩太郎, 永井寛嗣

Organometallic News ( 1 ) page： 40-41 2013.3

植物由来ビニルモノマーの精密重合による新規バイオベースポリマーの構築 Invited Reviewed

上垣外正己, 佐藤浩太郎

材料の科学と工学 Vol. 50 ( 1 ) page： 20-25 2013.2

Direct Mechanistic Transformations from Isotactic or Syndiotactic Living Anionic Polymerizations of Methyl Methacrylate into Metal-Catalyzed Living Radical Polymerizations Reviewed

H. Aoshima, K. Satoh, and M. Kamigaito

ACS Macro Lett. Vol. 2 ( 1 ) page： 72-76 2013.1

In-Situ Direct Mechanistic Transformation from FeCl3-Catalyzed Living Cationic to Radical Polymerizations Invited Reviewed

H. Aoshima, K. Satoh, and M. Kamigaito

Macromol. Symp. Vol. 323 page： 64-74 2013.1

Metal-Catalyzed Step-Growth Radical Polymerization of AA and BB Monomers for Monomer Sequence Regulation Invited Reviewed

K. Satoh, A. Abe, and M. Kamigaito

ACS Symp. Ser. Vol. 1100 page： 134-144 2012.12

From-Syndiotactic-to-Isotactic Stereogradient Methacrylic Polymers by RAFT Copolymerization of Methacrylic Acid and Its Bulky Esters Invited Reviewed

K. Ishitake, K. Satoh, M. Kamigaito, and Y. Okamoto

Polym. Chem. Vol. 3 ( 7 ) page： 1750-1757 2012.7

Kinetic Hydrate Inhibition of Poly(N-isopropylmethacrylamide)s with Different Tacticities Reviewed

P. C. Cheng, M. Kelland, K. Ishitake, K. Satoh, M. Kamigaito, and Y. Okamoto

Energy Fuels Vol. 26 ( 6 ) page： 3577-3585 2012.6

Design and Synthesis of Self-Degradable Antibacterial Polymers by Simultaneous Chain- and Step-Growth Radical Copolymerization Reviewed

M. Mizutani, E. Palermo, L. Thoma, K. Satoh, M. Kamigaito, and K. Kuroda

Biomacromolecules Vol. 13 ( 5 ) page： 1554-1563 2012.5

Nanocellular Foaming of Fluorine Containing Block Copolymers in Carbon Dioxide: The Role of Glass Transition in Carbon Dioxide Reviewed

D. Dutriez, K. Satoh, M. Kamigaito, and H. Yokoyama

RSC Adv. Vol. 2 ( 7 ) page： 2821-2827 2012.4

Intramolecular Friedel-Crafts Cyclization and Subsequent Hydrogenation of Styrene-Isoprene Random Copolymers Prepared by Anionic Polymerization for Thermally-Resistant and Optical Applications Reviewed

A. Nakahara, K. Satoh, H. Saito, and M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 50 ( 7 ) page： 1298-1307 2012.4

Random Copolymer of Styrene and Diene Derivatives via Anionic Living Polymerization Followed by Intramolecular Friedel-Crafts Cyclization for High-Performance Thermoplastics Reviewed

A. Nakahara, K. Satoh, and M. Kamigaito

Polym. Chem. Vol. 3 ( 1 ) page： 190-197 2012.1

Stereospecific Free Radical and RAFT Polymerization of Bulky Silyl Methacrylates for Stereo- and Molecular Weight-Controlled Poly(methacrylic Acid) Reviewed

K. Ishitake, K. Satoh, M. Kamigaito, and Y. Okamoto

Macromolecules Vol. 44 page： 10.1021/ma202155b 2011.12

Effects of Tacticity and Molecular Weight of Poly(N-isopropylacrylamide) on Its Glass Transition Temperature Reviewed

C. S. Biswas, V. K. Patel, N. K. Vishwakarma, V. K. Tiwari, B. Maiti, P. Maiti, M. Kamigaito, Y. Okamoto, and B. Ray

Macromolecules Vol. 44 ( 14 ) page： 5822-5824 2011.7

Iron Oxides as Heterogeneous Catalysts for Controlled/Living Radical Polymerization of Styrene and Methyl Methacrylate Reviewed

A. Kanazawa, K. Satoh, and M. Kamigaito

Macromolecules Vol. 44 ( 18 ) page： 1927-1933 2011.4

Degradable Poly(N-isopropylacrylamide) with Tunable Thermosensitivity by Simultaneous Chain- and Step-Growth Radical Polymerization Reviewed

M. Mizutani, K. Satoh, and M. Kamigaito

Macromolecules Vol. 44 ( 18 ) page： 2382-2386 2011.4

Immobilization of Amphiphilic Polycations by Catechol Functionality for Antimicrobial Coatings Reviewed

H. Han, J. Wu, C. Avery, M. Mizutani, X. Jiang, M. Kamigaito, Z. Chen, C. Xi, K. Kuroda

Langmuir Vol. 27 ( 7 ) page： 4010-4019 2011.4

Highly-Efficient Synthesis of Low Polydispersity Core Cross-Linked Star Polymers by Ru-Catalyzed Living Radical Polymerization Invited Reviewed

T. K. Goh, S. Yamashita, K. Satoh, A. Blencowe, M. Kamigaito, G. G. Qiao

Macromol. Rapid Commun. Vol. 32 ( 5 ) page： 456-461 2011.3

Recent Developments in Metal-Catalyzed Living Radical Polymerization Invited Reviewed

M. Kamigaito

Polym. J. Vol. 43 ( 2 ) page： 105-120 2011.2

Nucleobase-Mediated Stereospecific Radical Polymerization and Combination with RAFT Polymerization for Simultaneous Control of Molecular Weight and Tacticity Invited Reviewed

Y. Tao, K. Satoh, M. Kamigaito

Macromol. Rapid Commun. Vol. 32 ( 2 ) page： 226-232 2011.1

Chiral Recognition Ability of Cellulose Derivatives Bearing Pyridyl and Bipyridyl Residues as Chiral Stationary Phases for High-Performance Liquid Chromatography Reviewed

Y. Katoh, Y. Tsujimoto, C. Yamamoto, T. Ikai, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 43 ( 1 ) page： 84-90 2011.1

遷移金属触媒による逐次ラジカル重合 Invited Reviewed

佐藤浩太郎, 水谷将人, 上垣外正己

高分子論文集 Vol. 68 page： 433-456 2011

Effects of Tacticity and Molecular Weight of Poly(N-isopropylacrylamide) on Its Glass Transition Temperature Reviewed

C. S. Biswas, V. K. Patel, N. K. Vishwakarma, V. K. Tiwari, B. Maiti, P. Maiti, M. Kamigaito, Y. Okamoto, and B. Ray

Macromolecules Vol. 44 page： in press 2011

In Situ and Time-Resolved Small-Angle Neutron Scattering Observation of Star Polymer Formation via Arm-Linking Reaction in Ruthenium-Catalyzed Living Radical Polymerization Reviewed

T. Terashima, R. Motokawa, S. Koizumi, M. Sawamoto, M. Kamigaito, T. Ando, T. Hashimoto

Macromolecules Vol. 43 ( 19 ) page： 8218-8232 2010.10

ラジカル重合における配列制御 Invited

上垣外正己、佐藤浩太郎

高分子 Vol. 59 ( 10 ) page： 781-784 2010.10

Helical Structure of Liquid Crystalline Poly(N-((4-n-butylphenyl)diphenylmethyl) methacrylamide) Reviewed

K. Nagai, K. Okoshi, S. Sakurai, M. Bannno, A. K. M. F. Azam, M. Kamigaito, Y. Okamoto, E. Yashima

Macromolecules Vol. 43 ( 17 ) page： 7386-7390 2010.9

In-Situ Direct Mechanistic Transformation from RAFT to Living Cationic Polymerization for (Meth)acrylate-Vinyl Ether Block Copolymers Reviewed

S. Kumagai, K. Nagai, K. Satoh, and M. Kamigaito

Macromolecules Vol. 43 ( 18 ) page： 7523-7531 2010.9

AAB-Sequence Living Radical Chain Copolymerization of Naturally-Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer Reviewed

K. Satoh, M. Matsuda, K. Nagai, M. Kamigaito

J. Am. Chem. Soc. Vol. 132 ( 29 ) page： 10003-10005 2010.7

Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization: Marriage of Vinyl Polymers and Polyesters Reviewed

M. Mizutani, K. Satoh, M. Kamigaito

J. Am. Chem. Soc. Vol. 132 ( 21 ) page： 7498-7507 2010.6

精密に構造制御しながら高分子を合成する―ラジカル重合での挑戦― Invited

上垣外正己、佐藤浩太郎、永井寛嗣

現代化学 Vol. 471 page： 32-37 2010.6

Sequence-Regulated Vinyl Copolymers by Metal-Catalysed Step-Growth Radical Polymerization Reviewed

K. Satoh, S. Ozawa, M. Mizutani, K. Nagai, M. Kamigaito

Nature Commun. Vol. 1 page： 6 2010.4

植物由来モノマーの精密重合に基づく機能性高分子の合成 Invited Reviewed

佐藤浩太郎、上垣外正己

日本接着学会誌 Vol. 46 ( 1 ) page： 29-36 2010.1

Enantioseparation Using Amylose Esters as Chiral Stationary Phases for High-Performance Liquid Chromatography Invited Reviewed

Y. Sugiura, C. Yamamoto, T. Ikai, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 42 ( 1 ) page： 31-36 2010.1

ラジカル重合 Invited Reviewed

上垣外正己、佐藤浩太郎

ネットワークポリマー Vol. 30 ( 5 ) page： 234-249 2009.9

合成高分子の構造精密制御：ラジカル重合の制御と精密高分子合成 Invited Reviewed

上垣外正己

化学と工業 Vol. 62 ( 1 ) page： 25-27 2009.1

Metal-Catalyzed Radical Polyaddition for Aliphatic Polyesters via Evolution of Atom Transfer Radical Addition into Step-Growth Polymerization Reviewed

M. Mizutani, K. Satoh, M. Kamigaito

Macromolecules Vol. 42 ( 2 ) page： 472-480 2009.1

Metal-Catalyzed Living Radical Polymerization and Radical Polyaddition for Precision Polymer Synthesis Reviewed

M. Mizutani, K. Satoh, M. Kamigaito

J. Phys. Conf. Ser. Vol. 184 page： 012025 2009

有機金属触媒によるリビングラジカル重合の実用化に向けた展開 Invited

上垣外正己

Organometallic News page： 66 2009

Nano-to-Macroscale Poly(methyl methacrylate) Stereocomplex Assemblies Reviewed

T. K. Goh, J. F. Tan, S. N. Guantari, K. Satoh, A. Blencowe, M. Kamigaito, G. G. Qiao

Angew. Chem. Int. Ed. Vol. 48 ( 46 ) page： 8707-8711 2009

Mn2(CO)10-Induced RAFT Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene Reviewed

K. Koumura, K. Satoh, M. Kamigaito

Polym. J. Vol. 41 ( 8 ) page： 595-603 2009

Stereogradient Polymers Formed by Controlled/Living Radical Polymerization of Bulky Methacrylate Monomers Reviewed

K. Ishitake, K. Satoh, M. Kamigaito, Y. Okamoto

Angew. Chem. Int. Ed. Vol. 48 ( 11 ) page： 1991-1994 2009

Mn2(CO)10-Induced Controlled/Living Radical Copolymerization of Methyl Acrylate and 1-Hexene in Fluoroalcohol: High α-Olefin Content Copolymers with Controlled Molecular Weights Reviewed

K. Koumura, K. Satoh, M. Kamigaito

Macromolecules Vol. 42 ( 7 ) page： 2497-2504 2009

Cycloolefin Copolymer Analogues from Styrene and Isoprene: Cationic Cyclization of the Random Copolymers Prepared by Living Anionic Polymerization Reviewed

A. Nakahara, K. Satoh, M. Kamigaito

Macromolecules Vol. 42 ( 3 ) page： 620-625 2009

Mn2(CO)10-Induced Controlled/Living Radical Copolymerization of Vinyl Acetate and Methyl Acrylate: Spontaneous Formation of Block Copolymers Consisting of Gradient and Homopolymer Segments Reviewed

K. Koumura, K. Satoh, M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 47 ( 5 ) page： 1343-1353 2009

Thiourea-Mediated Stereospecific Radical Polymerization of Acrylamides and Combination with RAFT for Simultaneous Control of Molecular Weight and Tacticity Invited Reviewed

H. Murayama, K. Satoh, M. Kamigaito

ACS Symp. Ser. Vol. 1024 page： 49-63 2009

低環境負荷型重合系の開発―極性モノマーの重合反応制御から実用化まで Invited

佐藤浩太郎, 上垣外正己

化学 Vol. 63 ( 11 ) page： 70-71 2008.11

リビングラジカル重合の基礎と展開 Invited Reviewed

上垣外正己, 佐藤浩太郎

色材協会誌 Vol. 81 ( 11 ) page： 45-470 2008.11

遷移金属錯体を用いたリビングラジカル重合による多重制御グラフト共重合体 Invited Reviewed

佐藤浩太郎, 上垣外正己

日本ゴム協会誌 Vol. 81 ( 10 ) page： 424-430 2008.10

Organic-Inorganic Hybrid Materials for Efficient Enantioseparation Using Cellulose 3,5-Dimethylphenylcarbamate and Tetraethyl Orthosilicate Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

Chem. Asian J. Vol. 3 ( 8 ) page： 1494-1499 2008.8

ラジカル重合における精密制御ー分子量、立体構造、モノマー配列の制御 Invited Reviewed

上垣外正己、佐藤浩太郎

有機合成化学協会誌 Vol. 66 ( 6 ) page： 578-589 2008.6

Synthesis and Chiral Recognition of Novel Regioselectively Substituted Amylose Derivatives Reviewed

S. Kondo, C. Yamamoto, M. Kamigaito, and Y. Okamoto

Chem. Lett. Vol. 37 ( 5 ) page： 558-559 2008.5

Stereoregulation in Living Radical Polymerization Invited Reviewed

M. Kamigaito, K. Satoh

Macromolecules Vol. 41 ( 2 ) page： 269-276 2008.1

精密重合による機能性高分子材料の開発ーリビングカチオン重合による新規脂環式ポリオレフィンの合成ー Invited

上垣外正己, 佐藤浩太郎

化学工業 Vol. 59 ( 1 ) page： 1-9 2008.1

Regiospecific Radical Polymerization of Vinyl Methacrylate in the Presence of Lewis Acids into Soluble Polymers with Pendent Vinyl Ester Substituents Reviewed

F. Sugiyama, K. Satoh, M. Kamigaito

Macromolecules Vol. 41 ( 9 ) page： 3042-3048 2008

Immobilized-Type Chiral Packing Materials for HPLC Based on Polysaccharide Derivatives Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

J. Chromatogr. B. Vol. 875 ( 1 ) page： 2-11 2008

Evolution of Iron Catalysts for Effective Living Radical Polymerization: P–N Chelate Ligand for Enhancement of Catalytic Performances Reviewed

C. Uchiike, M. Ouchi, T. Ando, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 46 ( 20 ) page： 6819-6827 2008

Enantioseparation Using Urea- and Imide-Bearing Chitosan Phenylcarbamate Derivatives as Chiral Stationary Phases for High-Performance Liquid Chromatography Reviewed

C. Yamamoto, M. Fujisawa, M. Kamigaito, Y. Okamoto

Chirality Vol. 20 ( 3-4 ) page： 288-294 2008

Manganese-Based Controlled/Living Radical Polymerization of Vinyl Acetate, Methyl Acrylate, and Styrene: Highly Active, Versatile, and Photoresponsive Systems Reviewed

K. Koumura, K. Satoh, M. Kamigaito

Macromolecules Vol. 41 ( 20 ) page： 7359-7367 2008

Iron(III) Chloride/R–Cl/Tributylphosphine for Metal-Catalyzed Living Radical Polymerization: A Unique System with a Higher Oxidation State Iron Complex Reviewed

K. Satoh, H. Aoshima, M. Kamigaito

J. Polym. Sci., Part A, Polym. Chem. Vol. 46 ( 18 ) page： 6358-6363 2008

A Neutron Reflectivity Study on a Terraced Lamellar Morphology in a Block Copolymer Thin Film Reviewed

K. Niihara, U. Matsuwaki, N. Torikai, K. Satoh, M. Kamigaito, H. Jinnai

Polym. J. Vol. 39 ( 11 ) page： 1105-1111 2007.11

AxBAx-Type Block-Graft Polymers with Soft Methacrylate Middle Segments and Hard Styrene Outer Grafts: Synthesis, Morphology, and Mechanical Properties Reviewed

Y. Miura, T. Kaneko, Satoh, M. Kamigaito, H. Jinnai, Y. Okamoto

Chem. Asian J. Vol. 2 ( 3 ) page： 662-672 2007

Chiral (–)-DIOP Ruthenium Complexes for Asymmetric Radical Addition and Living Radical Polymerization Reviewed

Y. Iizuka, Z. Li, K. Satoh, M. Kamigaito, Y. Okamoto, J. Itoh, H. Nishiyama

Eur. J. Org. Chem. ( 5 ) page： 782-791 2007

Evolution of Iron Catalysts for Effective Living Radical Polymerization: Design of Phosphine/Halogen Ligands in FeX2(PR3)2 Reviewed

C. Uchiike, T. Terashima, M. Ouchi, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 40 ( 24 ) page： 8658-8662 2007

AxBAx-Type Block-Graft Polymers with Middle Soft Segments and Outer Hard Graft Chains by Ruthenium-Catalyzed Living Radical Polymerization: Synthesis and Characterization Reviewed

Y. Miura, Satoh, M. Kamigaito, Y. Okamoto, T. Kaneko, H. Jinnai, S. Kobukata

Macromolecules Vol. 40 ( 3 ) page： 465-473 2007

Preparation and Chiral Recognition Ability of Cross-linked Beads of Polysacchride Derivatives Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

J. Sep. Sci. Vol. 30 ( 17 ) page： 971-978 2007

Immobilized Polysaccharide Derivatives: Chiral Packing Materials for Efficient HPLC Resolution Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

Chem. Rec. Vol. 7 ( 2 ) page： 91-103 2007

Nanometer Voids Prevent Crack Growth in Polymeric Materials Reviewed

C. Dutriez, K. Satoh, M. Kamigaito, H. Yokoyama

Macromolecules Vol. 40 ( 21 ) page： 7433-7436 2007

Immobilization of Polysaccharide Derivatives onto Silica Gel. Facile Synthesis of Chiral Packing Materials by Means of Intermolecular Polycondensation of Triethoxysilyl Groups Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

J. Chromatogr. A. Vol. 1117 ( 1-2 ) page： 151-158 2007

Helix-Sense-Selective Anionic Polymerization of a Bulky Methacrylamide Using Organozincates Having Sugar Residues Reviewed

M. Tsuji, A. K. M. F. Azam, M. Kamigaito, Y. Okamoto

Macromolecules Vol. 40 ( 10 ) page： 3518-3520 2007

A Linear Lignin Analogue: Phenolic Alternating Copolymers from Naturally-Occurring β-Methylstyrene via Aqueous Controlled Cationic Copolymerization Reviewed

K. Satoh, S. Saitoh, M. Kamigaito

J. Am. Chem. Soc. Vol. 129 ( 31 ) page： 9586-9587 2007

Asymmetric Radical Polymerization and Copolymerization of N-(1-Phenyldibenzosuberyl)methacrylamide and Its Derivative Leading to Optically Active Helical Polymers Reviewed

A. K. M. F. Azam, M. Kamigaito, Y. Okamoto

J. Polym. Sci. Part A, Polym. Chem. Vol. 45 ( 7 ) page： 1304-1315 2007

Metal-Catalyzed Radical Polyaddition as a Novel Polymer Synthetic Route Reviewed

K. Satoh, M. Mizutani, M. Kamigaito

Chem. Commun. ( 12 ) page： 1260-1262 2007

Amphiphilic, Thermosensitive Ruthenium(II)-Bearing Star Polymer Catalysts: One-Pot Synthesis of PEG Armed Star Polymers with Ruthenium(II)-Enclosed Microgel Cores via Metal-Catalyzed Living Radical Polymerization Reviewed

T. Terashima, M. Ouchi, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 40 ( 10 ) page： 3581-3588 2007

Iron-Catalyzed Radical Polymerization of Acrylamides in the Presence of Lewis Acid for Simultaneous Control of Molecular Weight and Tacticity Reviewed

Y. Sugiyama, K. Satoh, M. Kamigaito, Y. Okamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 44 ( 6 ) page： 2086 2006

A "Ladder" Morphology in an ABC Triblock Copolymer Reviewed

T. Kaneko, K. Suda, K. Satoh, M. Kamigaito, T. Kato, T. Ono, E. Nakamura, T. Nishi, and H. Jinnai

Macromol. Symp. Vol. 242 page： 80 2006

Helicity Induction in N-[(4-Butyl)triphenylmethyl]methacrylamide Sequence via Radical Copolymerization of Chiral Monomers Reviewed

A. K. M. F. Azam, M. Kamigaito, M. Tsuji, Y. Okamoto

Polym. J. Vol. 38 ( 11 ) page： 1173 2006

Helix-Sense-Selective Free Radical Polymerization of N-(Triphenylmethyl)-methacrylamide Derivatives Reviewed

A. K. M. F. Azam, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 38 ( 10 ) page： 1035 2006

Biomass-Derived Heat-Resistant Alicyclic Hydrocarbon Polymers: Poly(terpenes) and their Hydrogenated Derivatives Reviewed

K. Satoh, H. Sugiyama, M. Kamigaito

Green Chem. Vol. 8 ( 10 ) page： 878 2006

Triple Hydrogen Bonding for Stereospecific Radical Polymerization of a DAD Monomer and Simultaneous Control of Tacticity and Molecular Weight Reviewed

D. Wan, K. Satoh, M. Kamigaito

Macromolecules Vol. 39 ( 20 ) page： 6882 2006

A Bicyclic Conjugated Diene Monomer, Tetrahydroindene, for Cationic Polymerization and a Novel Alicyclic Hydrocarbon Polymer with Heat Resistance Reviewed

N. Mizuno, K. Satoh, M. Kamigaito, Y. Okamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 44 ( 21 ) page： 6124 2006

Well-Defined Graft Copolymers of Methacrylate, Acrylate, and Styrene via Ruthenium-Catalyzed Living Radical Polymerization Reviewed

Y. Miura, K. Satoh, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 38 ( 9 ) page： 930 2006

Living Cationic Polymerization of a Novel Bicyclic Conjugated Diene Monomer, Tetrahydroindene, and Its Block Copolymers with Vinyl Ether Reviewed

N. Mizuno, K. Satoh, M. Kamigaito, Y. Okamoto

Macromolecules Vol. 39 ( 16 ) page： 5280 2006

Iodine Transfer Radical Polymerization of Vinyl Acetate in Fluoroalcohols for Simultaneous Control of Molecular Weight, Stereospecificity, and Regiospecificity Reviewed

K. Koumura, K. Satoh, M. Kamigaito, Y. Okamoto

Macromolecules Vol. 39 ( 12 ) page： 4054 2006

立体特異性リビングラジカル重合 Invited

上垣外正己、佐藤浩太郎

高分子 Vol. 55 ( 4 ) page： 250 2006

Stereospecific Living Radical Polymerization Reviewed

M. Kamigaito, K. Satoh, D. Wan, K. Koumura, T, Shibata, Y. Okamoto

ACS Symposium Series Vol. 944 page： 26 2006

Simultaneous Control of the Stereospecificity and Molecular Weight in the Ruthenium-Catalyzed Living Radical Polymerization of Methyl and 2-Hydroxyethyl Methacrylates and Sequential Synthesis of Stereoblock Polymers Reviewed

T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 44 ( 11 ) page： 3609 2006

Stereogradient Polymers by Ruthenium-Catalyzed Stereospecific Living Radical Copolymerization of Two Monomers with Different Stereospecificities and Reactivities Reviewed

Y. Miura, T. Shibata, K. Satoh, M. Kamigaito, Y. Okamoto

J. Am. Chem. Soc. Vol. 128 ( 50 ) page： 16026-16027 2006

Stereospecific Living Radical Polymerization for Simultaneous Control of Molecular Weight and Tacticity Invited Reviewed

M. Kamigaito, K. Satoh

J. Polym. Sci., Part A, Polym. Chem. Vol. 44 ( 21 ) page： 6147 2006

Immobilized Polysaccharide-Based Chiral Stationary Phases for HPLC Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 38 ( 2 ) page： 91-108 2006

High-Performance Liquid Chromatographic Enantioseparations on Capillary Columns Containing Monolithic Silica Modified with Amylose Tris(3,5-dimethylphenylcarbamate) Reviewed

B. Chankvetadze, C. Yamamoto, M. Kamigaito, N. Tanaka, K. Nakanishi, Y. Okamoto

J. Chromatogr. A. Vol. 1110 ( 1-2 ) page： 46-52 2006

High-Performance Liquid Chromatographic Enantioseparations on Capillary Columns Containing Crosslinked Polysaccharide Phenylcarbamate Dericvatives Attached to Monolithic Silica Reviewed

B. Chankvetadze, T. Kubota, T. Ikai, C. Yamamoto, M. Kamigaito, N. Tanaka, K. Nakanishi, Y. Okamoto

J. Sep. Sci. Vol. 29 ( 13 ) page： 1988-1995 2006

Efficient Immobilization of Cellulose Phenylcarbamate Bearing Alkoxysilyl Group onto Silica Gel by Intermolecular Polycondensation and Its Chiral Recognition Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

Chem. Lett. Vol. 35 ( 11 ) page： 1250-1251 2006

Metal-Complex-Bearing Star Polymers by Metal-Catalyzed Living Radical Polymerization: Synthesis and Characterization of Poly(methyl Methacrylate) Star Polymers with Ru(II)-Embedded Microgel Cores Reviewed

T. Terashima, M. Ouchi, T. Ando, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 44 ( 17 ) page： 4966 2006

Xanthate-Mediated Radical Polymerization of N-Vinylpyrrolidone in Fluoroalcohols for Simultaneous Control of Molecular Weight and Tacticity: Possibility of Living Radical Polymerization Reviewed

D. Wan, K. Satoh, M. Kamigaito, Y. Okamoto

Macromolecules Vol. 38 ( 26 ) page： 10397 2005

Effects of Tacticity of Poly(N-Isopropylacrylamide) on the Phase Separation Temperature of Its Aqueous Solutions Reviewed

B. Ray, Y. Okamoto, M. Kamigaito, M. Sawamoto, K. Seno, S. Kanaoka, S. Aoshima

Polym. J. Vol. 37 ( 3 ) page： 234 2005

Enantioseparation by HPLC Using Phenylcarbamate, Benzoylformate, p-Toluenesulfonylcarbamate, and Benzoylcarbmates of Cellulose and Amylose as Chiral Stationary Phases Reviewed

T. Ikai, C. Yamamoto, M. Kamigaito, Y. Okamoto

Chirality Vol. 17 ( 6 ) page： 299-304 2005

Metal-Catalyzed Living Radical Polymerization: Discovery and Developments Invited Reviewed

M. Kamigaito, T. Ando, M. Sawamoto

Chem. Rec. Vol. 4 ( 3 ) page： 159 2004.7

ルテニウム錯体によるメタクリル酸メチルのリビングラジカル重合―チタンアルコキシドによる重合の加速 Reviewed

浜崎真也、安藤剛、上垣外正己、澤本光男

高分子論文集 Vol. 61 ( 4 ) page： 256 2004.4

遷移金属錯体によるリビングラジカル重合－重合と有機化学の相互のフィードバック Invited

安藤剛、上垣外正己、澤本光男

化学 Vol. 58 ( 2 ) page： 58 2004.2

RAFT Polymerization of N-Isopropylacrylamide in the Absence and Presence of Y(OTf)3: Simultaneous Control of Molecular Weight and Tacticity Reviewed

B. Ray, Y. Isobe, K. Matsumoto, S. Habaue, Y. Okamoto, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 37 ( 5 ) page： 1702 2004

Novel Initiating Systems for the Stereocontrolled Radical Polymerization of Acrylamides: Alkyl Bromide/Rare Earth Metal Triflate System Reviewed

B. Ray, Y. Isobe, S. Habaue, M. Kamigaito, Y. Okamoto

Polym. J. Vol. 36 ( 9 ) page： 728 2004

精密制御ラジカル重合における最近の展開 Invited

上垣外正己

日本接着学会誌 Vol. 40 ( 8 ) page： 358 2004

Cellulose Derivative-Based Beads as Chiral Stationary Phase for HPLC Reviewed

T. Ikai, R. Muraki, C. Yamamoto, M. Kamigaito, Y. Okamoto

Chem. Lett. Vol. 33 ( 9 ) page： 1188-1189 2004

水中におけるリビング重合 Invited

上垣外正己、安藤剛、澤本光男

高分子 Vol. 52 ( 4 ) page： 246 2003.4

Polymer Catalysts from Polymerization Catalysts: Direct Encapsulation of Metal Catalysts into Star Polymer Core during Metal-Catalyzed Living Radical Polymerization Reviewed

T. Terashima, M. Kamigaito, K.-Y. Baek, T. Ando, M. Sawamoto

J. Am. Chem. Soc. Vol. 125 ( 18 ) page： 5288 2003

Living Radical Polymerization with Designed Metal Complexes Reviewed

M. Kamigaito, T. Ando, M. Sawamoto

ACS Symposium Series Vol. 854 ( 18 ) page： 102 2003

Synthesis of Isotactic Poly(N-isopropylacrylamide) by RAFT Polymerization in the Presence of Lewis Acid Reviewed

B. Ray, Y. Isobe, K. Morioka, S. Habaue, Y. Okamoto, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 36 ( 5 ) page： 543 2003

Controlled Cationic Polymerization of p-(Chloromethyl)styrene: BF3-Catalyzed Selective Activation of a C–O Terminal from Alcohol Reviewed

M. Kamigaito, J. Nakashima, K. Satoh, M. Sawamoto

Macromolecules Vol. 36 page： 3540 2003

Synthesis and Characterization of [TiF2(NMe2)2]4 and its Use for Olefin Polymerizations Reviewed

D. A. Straus, M. Kamigaito, A. P. Cole, R. M. Waymouth

Inorg. Chim. Acta Vol. 349 page： 65 2003

Amino Alcohol Additives for the Fast Living Radical Polymerization of Methyl Methacrylate with RuCl2(PPh3)3 Reviewed

T. Ando, C. Sawauchi, M. Ouchi, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 41 page： 3597 2003

カチオン重合系ブロックポリマーと熱可塑性エラストマー Invited

澤本光男, 上垣外正己, 安藤剛

日本ゴム協会誌 Vol. 76 ( 8 ) page： 285 2003

水中での精密重合 Invited

上垣外正己

化学 Vol. 57 ( 3 ) page： 58 2002.3

A New Ruthenium Complex with an Electron-Donating Aminoindenyl Ligand for Fast Metal-Mediated Living Radical Polymerizations Reviewed

M. Kamigaito, Y. Watanabe, T. Ando, M. Sawamoto

J. Am. Chem. Soc. Vol. 124 ( 34 ) page： 9994 2002

A Highly Active Fe(I) Catalyst for Radical Polymerisation and Taming the Polymerisation with Iodine Reviewed

M. Kamigaito, I. Onishi, S. Kimura, Y. Kotani, M. Sawamoto

Chem. Commun. ( 22 ) page： 2694 2002

Possibility of Living Radical Polymerization of Vinyl Acetate Catalyzed by Iron(I) Complex Reviewed

M. Wakioka, K.-Y. Baek, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 35 page： 330 2002

Ruthenium-Catalyzed Fast Living Radical Polymerization of Methyl Methacrylate: The R–Cl/Ru(Ind)Cl(PPh3)2/n-Bu2NH Initiating System Reviewed

S. Hamasaki, C. Sawauchi, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 617 2002

Iron-Catalyzed Suspension Living Radical Polymerizations of Acrylates and Styrene in Water Reviewed

Y. Fuji, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 35 page： 2249 2002

Amine-Additives for Fast Living Radical Polymerization of Methyl Methacrylate with RuCl2(PPh3)3 Reviewed

S. Hamasaki, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 35 page： 2934 2002

Core-Functionalized Star Polymers by Transition Metal-Catalyzed Living Radical Polymerization. 2. Selective Interaction with Protic Guests via Core Functionalities Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 35 page： 1493 2002

Synthesis of Star-Shaped Polymers with Methyl Methacrylate and n-Butyl Methacrylate by Metal-Catalyzed Living Radical Polymerization: Block- and Random-Copolymer Arms, and Microgel Cores Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 633 2002

遷移金属錯体によるリビングラジカル重合の新展開：－金属触媒の設計と精密重合系の開発 Invited Reviewed

安藤剛, 上垣外正己, 澤本光男

高分子論文集 Vol. 59 page： 199 2002

Living Radical and Cationic Polymerization in Water and Organic Media Reviewed

M. Sawamoto, M. Kamigaito

Macromol. Symp. Vol. 177 page： 17 2002

Star-Shaped Polymers by Metal-Catalyzed Living Radical Polymerization. 2. Effect of Reaction Conditions and Characterization by MALLS/SEC and SAXS Reviewed

K.-Y. Baek, M. Kamigaito, and M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 2245 2002

Controlled Radical Polymerization of 2-Hydroxyethyl Methacrylate with a Hydrophilic Ruthenium Complex and the Synthesis of Amphiphilic Random and Block Copolymers with MMA Reviewed

Y. Fuji, K. Watanabe, K.-Y. Baek, T. Ando, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 2055 2002

Iron-Catalyzed Living Radical Polymerization of Acrylates: Iodide-Based Initiating Systems and Block and Random Copolymerizations Reviewed

I. Onishi, K.-Y. Baek, Y. Kotani, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 2033 2002

Star Poly(methyl Methacrylate) with End-Functionalized Arm Chains by Ruthenium-Catalyzed Living Radical Polymerization Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 1972 2002

Synthesis of End-Functionalized PMMA by Ruthenium-Catalyzed Living Radical Polymerization with Functionalized Initiators Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 40 page： 1937 2002

Metal-Catalyzed Living Radical Polymerization Invited Reviewed

M. Kamigaito, T. Ando, M. Sawamoto

Chem. Rev. Vol. 101 ( 12 ) page： 3689 2001.12

Cationic Polymerization of Cyclopentadiene with SnCl4: Control of Molecular Weights and Narrow Molecular Weight Distributions Reviewed

M. Ouchi, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 3176 2001

リビングラジカル重合－生長種を休ませることによる反応制御－ Invited

上垣外正己、澤本光男

現代化学 Vol. 363 page： 34 2001

Control of Regioselectivity and Main-Chain Microstructure in Cationic Polymerization of Cyclopentadiene Reviewed

M. Ouchi, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 6586 2001

Star-Shaped Polymers by Metal-Catalyzed Living Radical Polymerization. 1. Design of Ru(II)-Based Systems and Divinyl Linking Agents Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 215 2001

Core-Functionalized Star Polymers by Transition Metal-Catalyzed Living Radical Polymerization. 1. Synthesis and Characterization of Star Polymers with PMMA Arms and Amide Cores Reviewed

K.-Y. Baek, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 7629 2001

Ru(Cp*)Cl(PPh3)2: A Versatile Catalyst for Living Radical Polymerization of Methacrylate, Acrylate, and Styrene Reviewed

Y. Watanabe, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 4370 2001

MALDI-TOF-MS Analysis of Ru(II)-Mediated Living Radical Polymerization of Methyl Methacrylate, Methyl Acrylate, and Styrene Reviewed

H. Nonaka, M. Ouchi, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 2083 2001

シクロペンタジエンの精密制御カチオン重合 Invited

大内誠, 上垣外正己, 澤本光男

高分子加工 Vol. 50 page： 386 2001

Local Chain Dynamics of Poly(N-vinylcarbazole) Studied by the Fluorescence Depolarization Method Reviewed

H. Aoki, J. Horinaka, S. Ito, M. Yamamoto, H. Katayama, M. Kamigaito, M. Sawamoto

Polym. J. Vol. 33 page： 464 2001

MALDI-TOF-MS Analysis of Living Cationic Polymerization of Vinyl Ethers. III. Polymerization with SnCl4 and TiCl4 in the Absence of Additives Reviewed

H. Katayama, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 39 page： 1258 2001

MALDI-TOF-MS Analysis of Living Cationic Polymerization of Vinyl Ethers. II. Living Nature of Growing End and Side Reactions Reviewed

H. Katayama, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 39 page： 1249 2001

Stereoregulation in Cationic Polymerization. III. High Isospecificity with the Bulky Phosphoric Acid [(RO)2PO2H]/SnCl4 Initiating Systems: Design of Counteranions via Initiators Reviewed

M. Ouchi, M. Sueoka, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 39 page： 1067 2001

Stereoregulation in Cationic Polymerization by Designed Lewis Acids. II. Effects of Alkyl Vinyl Ether Structure Reviewed

M. Ouchi, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 39 page： 1060 2001

Synthesis of End-Functionalized Polymers and Copolymers of Cyclopentadiene with Vinyl Ethers by Cationic Polymerization Reviewed

M. Ouchi, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 39 page： 398 2001

Novel BF3OEt2/R-OH Initiating Systems for Controlled Cationic Polymerization of Styrene in the Presence of Water Reviewed

K. Satoh, J. Nakashima, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 34 page： 396 2001

Reversible Activation of Carbon–Halogen Bonds by RuCl2(PPh3)3: Halogen Exchange Reactions in Living Radical Polymerization Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 2819 2000

Olefin Polymerization with Me4Cp–Amido Complexes with Electron-Withdrawing Groups Reviewed

M. Kamigaito, T. K. Lal, R. M. Waymouth

J. Polym. Sci., Part A, Polym. Chem. Vol. 38 ( 9 ) page： 4649 2000

Lanthanide Triflates-Mediated Emulsion Cationic Polymerization of p-Alkoxystyrenes in Aqueous Media Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 4660 2000

Direct Living Cationic Polymerization of p-Hydroxystyrene with Boron Trifluoride Etherate in the Presence of Water Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 5405 2000

Ru(II)-Mediated Living Radical Polymerization: Block and Random Copolymerizations of N,N-Dimethylacrylamide and Methyl Methacrylate Reviewed

M. Senoo, Y. Kotani, M. Kamigaito, M. Sawamoto

Macromol. Symp. Vol. 157 page： 193 2000

Living Radical Polymerization of Styrene: RuCl2(PPh3)3 and Alkyl Iodide-Based Initiating Systems Reviewed

Y. Kotani, M. Kamigaito, M. Sawamoto

ACS Symposium Series Vol. 768 page： 168 2000

Living Radical Polymerization of Acrylates with Rhenium(V)-Based Initiating Systems: ReO2I(PPh3)2/Alkyl Iodide Reviewed

H. Uegaki, Y. Kotani, M. Kamigaito, M. Sawamoto

ACS Symposium Series Vol. 760 page： 196 2000

Quenching of Metal-Catalyzed Living Radical Polymerization with Silyl Enol Ethers Reviewed

K. Tokuchi, T. Ando, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 38 page： 4735 2000

Living Radical Polymerization of Para-Substituted Styrenes and Synthesis of Styrene-Based Copolymers with Rhenium and Iron Complex Catalysts Reviewed

Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 6746 2000

Metal Alkoxides as Additives for Ruthenium(II)-Mediated Living Radical Polymerization Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 6732 2000

Catalytic Activities of Ruthenium(II) Complexes in Transition Metal-Mediated Living Radical Polymerization: Polymerization, Model Reaction, and Cyclic Voltammetry Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 5825 2000

Living Radical Polymerization of Styrene by Half-Metallocene Iron Carbonyl Complexes Reviewed

Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 3543 2000

Controlled Synthesis of Functionalized Polymers by Transition-Metal-Mediated Living Radical Polymerization Reviewed

M. Sawamoto, M. Kamigaito

Macromol. Symp. Vol. 161 page： 11 2000

Transition Metal-Catalyzed Living Radical Polymerization: Recent Development in Catalysis and Precision Polymer Synthesis Invited

M. Sawamoto, M. Kamigaito

Polymer News Vol. 25 page： 149 2000

MALDI-TOF-MS Analysis of Living Cationic Polymerization of Vinyl Ethers. I. Optimization of Measurement Conditions for Poly(isobutyl Vinyl Ether) Reviewed

H. Katayama, H. Kitaguchi, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 38 page： 4023 2000

Sulfonic Acids as Water-Soluble Initiators for Cationic Polymerization in Aqueous Media with Yb(OTf)3 Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 38 page： 2728 2000

Metal Triflates and Tetrafluoroborates as Water-Tolerant Lewis Acids for Cationic Polymerization in Aqueous Media Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 5836 2000

Direct Synthesis of Amphiphilic Block or Random Copolymers of p-Hydroxystyrene and p-Methoxystyrene via Living Cationic Polymerization with BF3OEt2/ROH Systems Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 5830 2000

Aromatic Acetals as New Initiators for Cationic Polymerization of Isobutyl Vinyl Ether Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 33 page： 748 2000

Transition Metal-Catalyzed Living Radical Polymerization: System Design and Precision Polymer Synthesis Reviewed

M. Sawamoto, M. Kamigaito

CHEMTECH Vol. 29 ( 6 ) page： 30 1999

Half-Metallocene-Type Ruthenium Complexes as Active Catalysts for Living Radical Polymerization of Methyl Methacrylate and Styrene Reviewed

H. Takahashi, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 3820 1999

Controlled Cationic Polymerization of p-Methoxystyrene in Aqueous Media with Yb(OTf)3 Reviewed

K. Satoh, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 3827 1999

Stereoregulation in Cationic Polymerization by Designed Lewis Acids. 1. Highly Isotactic Poly(Isobutyl Vinyl Ether) with Titanium-Based Lewis Acids Reviewed

M. Ouchi, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 6407 1999

Living Radical Polymerization of N,N-Dimethylacrylamide with RuCl2(PPh3)3-Based Initiating Systems Reviewed

M. Senoo, Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 8005 1999

RuH2(PPh3)4: An Active Catalyst for Living Radical Polymerization of Methyl Methacrylate at or above Room Temperature Reviewed

H. Takahashi, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 6461 1999

Living Radical Polymerization of Methyl Methacrylate with a Zerovalent Nickel Complex, Ni(PPh3)4 Reviewed

H. Uegaki, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 37 page： 3003 1999

Living Radical Polymerization in Water and Alcohols: Suspension Polymerization of Methyl Methacrylate with RuCl2(PPh3)3 Complex Reviewed

T. Nishikawa, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 32 page： 2204 1999

Re(V)-Mediated Living Radical Polymerization of Styrene Reviewed

Y. Kotani, M. Kamigaito, and M. Sawamoto

Macromolecules Vol. 32 page： 2420 1999

水中での重合の制御 Invited

上垣外正己, 澤本光男

高分子加工 Vol. 48 page： 453 1999

Amphiphilic 3-Arm Star Block Polymers by Living Cationic Polymerization Reviewed

R. Takahashi, M. Ouchi, K. Satoh, M. Kamigaito, M. Sawamoto

Polym. J. Vol. 31 page： 995 1999

Calixarene-Core Multifunctional Initiators for the Ruthenium-Mediated Living Radical Polymerization of Methacrylates Reviewed

J. Udea, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 31 page： 6762 1998

NiBr2(PnBu3)2-Mediated Living Radical Polymerization of Methacrylates and Acrylates and their Block and Random Copolymerizations Reviewed

H. Uegaki, Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 31 page： 6756 1998

Multifunctional Initiators for the Ruthenium-Mediated Living Radical Polymerization of Methyl Methacrylate: Di- and Trifunctional Dichloroacetates for Synthesis of Multiarmed Polymers Reviewed

J. Ueda, M. Matsuyama, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 31 page： 557 1998

Living Random Copolymerization of Styrene and MMA with a Ru(II) Complex and Synthesis of ABC-Type "Block-Random" Copolymers Reviewed

Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 31 page： 5582 1998

Living Radical Polymerization Mediated by Transition Metals: Recent Advances Reviewed

M. Sawamoto, M. Kamigaito

ACS Symposium Series Vol. 685 page： 296 1998

リビングラジカル重合の新展開－金属錯体による精密制御重合－

澤本光男, 上垣外正己

高分子加工 Vol. 47 page： 537 1998

In-Situ Direct Analysis of the Growing Species by 119Sn NMR Spectroscopy: Living Cationic Polymerization of Isobutyl Vinyl Ether with HCl/SnCl4/nBu4NCl Reviewed

H. Katayama, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 31 page： 4703 1998

Design of Initiators for Living Radical Polymerization of Methyl Methacrylate Mediated by Ruthenium(II) Complex Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Tetrahedron Vol. 53 page： 15445 1997

Evidence for Living Radical Polymerization of MMA with Ruthenium Complex: Effects of Protic Compounds and Reinitiation from the Recovered Polymers Reviewed

T. Nishikawa, T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 30 page： 2244 1997

Iron(II) Chloride Complex for Living Radical Polymerization of Methyl Methacrylate Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 30 page： 4507 1997

Nickel-Mediated Living Radical Polymerization of Methyl Methacrylate Reviewed

H. Uegaki, Y. Kotani, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 30 page： 2249 1997

Living Cationic Isomerization Polymerization of b-Pinene. 1. Initiation with HCl–2-Chloroethyl Vinyl Ether Adduct/TiCl3(OiPr) in Conjunction with nBu4NCl Reviewed

TJ. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura, Y.-X. Deng

Macromolecules Vol. 30 page： 22 1997

Metal Complex-Mediated Living Radical Polymerization: Features, Scope, and Precision Polymer Synthesis Invited Reviewed

M. Sawamoto M. Kamigaito

J. Macromol. Sci.-Pure Appl. Chem. Vol. A34 page： 1803 1997

遷移金属錯体によるリビングラジカル重合 Invited Reviewed

澤本光男, 上垣外正己

高分子論文集 Vol. 54 page： 875 1997

Living Cationic Polymerization with Yb(OSO2CF3)3 as a Water-Resistant, Recoverable Lewis Acid Reviewed

K. Satoh, H. Katayama, M. Kamigaito, M. Sawamoto

ACS Symposium Series Vol. 665 page： 106 1997

Synthesis and SANS Characterization of Poly(vinyl methyl ether)-block-Polystyrene Reviewed

T. Hashimoto, H. Hasegawa, T. Hashimoto, H. Katayama, M. Kamigaito, M. Sawamoto, M. Imai

Macromolecules Vol. 30 page： 6819 1997

Living Cationic Isomerization Polymerization of b-Pinene. 3. Synthesis of End-Functionalized Polymers and Graft Copolymers Reviewed

J. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura, Y.-X. Deng

J. Polym. Sci., Part A, Polym. Chem. Vol. 35 page： 1423 1997

Living Cationic Isomerization Polymerization of b-Pinene. 2. Synthesis of Block and Random Copolymers with Styrene or p-Methylstyrene Reviewed

J. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura, Y.-X. Deng

Macromolecules Vol. 30 page： 27 1997

Living Cationic Isomerization Polymerization of b-Pinene. 1. Initiation with HCl–2-Chloroethyl Vinyl Ether Adduct/TiCl3(OiPr) in Conjunction with nBu4NCl Reviewed

J. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura, Y.-X. Deng

Macromolecules Vol. 30 page： 22 1997

Living Radical Polymerization of Alkyl Methacrylates with Ruthenium Complex and Synthesis of Their Block Copolymers Reviewed

Y. Kotani, M. Kato, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 29 page： 6979 1996

Living Radical Polymerization of Methyl Methacrylate with Ruthenium Complex: Formation of Nearly Monodisperse Polymers with Controlled Molecular Weights Reviewed

T. Ando, M. Kamigaito, M. Sawamoto

Macromolecules Vol. 29 page： 1070 1996

Living Radical Polymerizations Based on Transition Metal Complexes Invited Reviewed

M. Sawamoto, M. Kamigaito

Trends Polym. Sci. Vol. 4 page： 371 1996

Sulfonyl Chlorides as Initiators for the Ruthenium-Mediated Living Radical Polymerization of Methyl Methacrylate Reviewed

M. Matsuyama, M. Kamigaito, M. Sawamoto

J. Polym. Sci., Part A, Polym. Chem. Vol. 34 page： 3585 1996

Living Cationic Polymerization of Styrene with TiCl3(OiPr) as a Lewis Acid Activator Reviewed

T. Hasebe, M. Kamigaito, M Sawamoto

Macromolecules Vol. 29 page： 6100 1996

Cationic Polymerization of b-Pinene with the AlCl3/SbCl3 Binary Catalyst: Comparison with a-Pinene Polymerization Reviewed

J. Lu, M. Kamigaito, M. Sawamoto, T. Higashimura, Y.-X. Deng

J. Appl. Polym. Sci. Vol. 61 page： 1011 1996

Cationic Polymerization with Titanium(IV) Compounds: Living Polymerization and Possibility of Stereoregulation Reviewed

M. Sawamoto, M. Kamigaito

Macromol. Symp. Vol. 107 page： 43 1996

ラジカルリビング重合－最近の展開－ Invited

上垣外正己

海外高分子研究 Vol. 41 page： 203 1995

Titanium-Based Lewis Acids for Living Cationic Polymerizations of Vinyl Ethers and Styrene: Control of Lewis Acidity in Design of Initiating Systems Reviewed

M. Sawamoto, M. Kamigaito

Macromol. Symp. Vol. 98 page： 153 1995

Alkoxy-Substituted Titanium(IV) Chlorides as Lewis Acid Activators for Living Cationic Polymerization of Isobutyl Vinyl Ether: Control of Lewis Acidity in the Design of Initiating Systems Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 28 page： 5671 1995

Living Cationic Polymerization of Isobutyl Vinyl Ether by the CF3CO2H/SnCl4/nBu4NCl system: In-situ Direct Analysis of the Growing Species by 1H, 13C, and 19F NMR Spectroscopy Reviewed

H. Katayama, M. Kamigaito, M. Sawamoto, T. Higashimura

J. Phys. Org. Chem. Vol. 8 page： 282 1995

In-situ 13C and 1H NMR Analysis of Growing Species in Living Cationic Polymerization: Isobutyl Vinyl Ether by HCl/SnCl4 Initiating Systems in the Presence of nBu4NCl Salt Reviewed

H. Katayama, M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 28 page： 3747 1995

Living Cationic Polymerization of a-Methylstyrene. 2. Synthesis of Block and Random Copolymers with 2-Chloroethyl Vinyl Ether and End-Functionalized Polymers Reviewed

M. Sawamoto, T. Hasebe, M. Kamigaito, T. Higashimura

J. Macromol. Sci.–Pure Appl. Chem. Vol. A31 page： 937 1994

Synthesis of End-Functionalized Polystyrenes with Organosilicon End-Capping Reagents via Living Cationic Polymerization Reviewed

K. Miyashita, M. Kamigaito, M. Sawamoto, T. Higashimura

J. Polym. Sci., Part A, Polym. Chem. Vol. 32 page： 2531 1994

End-Functionalized Polymers of Styrene and p-Methylstyrene by Living Cationic Polymerization with Functionalized Initiators Reviewed

K. Miyashita, M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 27 page： 1093 1994

Cationic Polymerization of a-Pinene with Aluminum-Based Catalysts. 2. Survey of Catalyst Systems Reviewed

T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto, Y.-X. Deng

Makromol. Chem. Vol. 194 page： 3441 1993

Living Cationic Polymerization of a-Methylstyrene Initiated with a Vinyl Ether–Hydrogen Chloride Adduct in Conjunction with Tin Tetrabromide Reviewed

T. Higashimura, M. Kamigaito, M. Kato, T. Hasebe, M. Sawamoto

Macromolecules Vol. 26 page： 2670 1993

Living Cationic Polymerization of Isobutyl Vinyl Ether by Trimethylsilyl Halide/Zinc Halide Initiating Systems: Effects of Carbonyl Compounds Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

Makromol. Chem. Vol. 194 page： 727 1993

Phosphoric and Phosphinic Acids/Zinc Chloride Initiating Systems for Isobutyl Vinyl Ether Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

J. Polym. Sci., Part A, Polym. Chem. Vol. 31 page： 2987 1993

Living Cationic Polymerization of Isobutyl Vinyl Ether by Hydrogen Chloride/Lewis Acid Initiating Systems in the Presence of Salts: In-situ Direct NMR Analysis of the Growing Species Reviewed

M. Kamigaito, Y. Maeda, M. Sawamoto, T. Higashimura

Macromolecules Vol. 26 page： 1643 1993

Cationic Polymerization of a-Pinene with Aluminum-Based Catalysts. 3. Effects of Added Base Reviewed

T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto, Y.-X. Deng

Makromol. Chem. Vol. 194 page： 3455 1993

Living Cationic Polymerization of Isobutyl Vinyl Ether by Protonic Acid/Zinc Halide Initiating Systems: Evidence for the Halogen Exchange with Zinc Halide in the Growing Species Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 25 page： 2587 1992

Cationic Polymerization of a-Pinene with AlCl3/SbCl3 Binary Catalyst Reviewed

T. Higashimura, J. Lu, M. Kamigaito, M. Sawamoto, Y.-X. Deng

Makromol. Chem. Vol. 193 page： 2311 1992

Living Cationic Polymerization of Isobutyl Vinyl Ether by Benzoic Acid Derivatives/Zinc Chloride Initiating Systems: Slow Interconversion between Dormant and Activated Growing Species Reviewed

M. Kamigaito, K. Yamaoka, M. Sawamoto, T. Higashimura

Macromolecules Vol. 25 page： 6400 1992

Living Cationic Polymerization of Isobutyl Vinyl Ether by Trimethylsilyl Halide/Zinc Halide Initiating Systems in the Presence of p-Methoxybenzaldehyde: Effects of Halide Anions and Zinc Halides Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

J. Polym. Sci., Part A, Polym. Chem. Vol. 29 page： 1909 1991

Living Cationic Polymerization of Isobutyl Vinyl Ether by RCOOH/Lewis Acid Initiating Systems: Effects of Carboxylate Ions and Lewis Acid Activators Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 24 page： 3988 1991

Living Cationic Polymerization of Isobutyl Vinyl Ether by Me3SiI/Lewis Acid Systems in the Presence of Acetone: Initiation via a Silyloxycarbocation Reviewed

M. Kamigaito, M. Sawamoto, T. Higashimura

Macromolecules Vol. 23 page： 4896 1990

Living Cationic Polymerization of Isobutyl Vinyl Ether Initiated by the Trimethylsilyl Iodide/Zinc Iodide System Reviewed

M. Sawamoto, M. Kamigaito, K. Kojima, T. Higashimura

Polym. Bull. Vol. 19 page： 359 1988

Living Cationic Polymerization of Isobutyl Vinyl Ether Initiated by the Diphenyl Phosphate/Zinc Iodide Initiating System Reviewed

M. Sawamoto, M. Kamigaito, T. Higashimura

Polym. Bull. Vol. 20 page： 407 1988

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