Faculty Profiles - KAMIGAITO, Masami

Papers - KAMIGAITO, Masami

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Proton Transfer Anionic Polymerization with C–H Bond as the Dormant Species Reviewed

M. Uchiyama, N. Ohira, K. Yamashita, K. Sagawa, and M. Kamigaito

Nature Chemistry Vol. 16 ( 10 ) page： 1630 - 1637 2024.10

’Living’ Anionic Polymerization through Reversible Activation of C–H Bonds with a Base Catalyst Invited Reviewed

M. Uchiyama and M. Kamigaito

Nature Chemistry Vol. 16 ( 10 ) page： 1582 - 1583 2024.10

Step-Growth Irreversible Deactivation Radical Polymerization: Synergistic Developments with Chain-Growth Reversible Deactivation Radical Polymerization Invited Reviewed

M. Kamigaito

Bull. Chem. Soc. Jpn Vol. 97 ( 7 ) page： uoae069 2024.7

Radical-Promoted Single-Unit Monomer Insertion (SUMI) [aka. Reversible-Deactivation Radical Addition (RDRA)] Invited Reviewed International coauthorship

C. Boyer, M. Kamigaito, K. Satoh, and G. Moad

Prog. Polym. Sci. Vol. 138 page： 101648 2023.3

Cationic RAFT and DT polymerization Invited Reviewed

M. Uchiyama, K. Satoh, and M. Kamigaito,

Prog. Polym. Sci. Vol. 124 page： 101485 2022.1

Degenerative Chain-Transfer Process: Controlling All Chain-Growth Polymerizations and Enabling Novel Monomer Sequences Invited Reviewed

M. Kamigaito, K. Satoh, M. Uchiyama

J. Polym. Sci., Part A, Polym. Chem. Vol. 57 ( 3 ) page： 243 - 254 2019.2

Proton Transfer Anionic Polymerization of Methyl Methacrylate with Ligands for Dual Control of Molecular Weight and Tacticity Invited Reviewed

K. Sagawa, M. Uchiyama, H. Watanabe, C. Homma, and M. Kamigaito

Precis. Chem. Vol. 2 ( 12 ) page： 628 - 633 2024.12

Synthesis of Degradable Polymers through 1,5-Shift Radical Isomerization Polymerizations of Vinyl Ether Derivatives with a Cleavable Bond Invited Reviewed

M. Uchiyama, M. Imai, and M. Kamigaito

Polym. J. Vol. in press 2024.4

Evolutions of Precision Radical Polymerizations from Metal-Catalyzed Radical Addition: Living Polymerization, Step-Growth Polymerization, and Monomer Sequence Control Invited Reviewed

M. Kamigaito

Polym. J. Vol. 54 ( 12 ) page： 1391 - 1405 2022.12

Synergistic Advances in Living Cationic and Radical Polymerizations Invited Reviewed

M. Kamigaito, M. Sawamoto

Macromolecules Vol. 53 ( 16 ) page： 6749 - 6753 2020.8

Cationic β-Scission of C–H and C–C Bonds for Selective Dimerization and Subsequent Sulfur-Free RAFT Polymerization of α-Methylstyrene and Isobutylene Reviewed

T. Tanimoto, M. Uchiyama, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 62 ( 43 ) page： e202307791 2023.10

Direct Radical Copolymerizations of Thioamides to Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbone Reviewed

H. Watanabe and M. Kamigaito

J. Am. Chem. Soc. Vol. 145 ( 20 ) page： 10948 - 10953 2023.5

Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals Reviewed

M. Uchiyama, Y. Murakami, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 62 ( 4 ) page： e202215021 2023.1

Sulfur-Free Radical RAFT Polymerization of Methacrylates in Homogeneous Solution: Design of exo-Olefin Chain-Transfer Agents (R-CH2C(=CH2)Z) Reviewed

M. Amano, M. Uchiyama, K. Satoh, and M. Kamigaito

Angew. Chem. Int. Ed. Vol. 61 ( 52 ) page： e202212633 2022.12

Asymmetric Cationic Polymerization of Benzofuran through a Reversible Chain-Transfer Mechanism: Optically Active Polybenzofuran with Controlled Molecular Weights Reviewed

J. Am. Chem. Soc. Vol. 144 ( 23 ) page： 10429 - 10437 2022.6

Multifactor Control of Vinyl Monomer Sequence, Molecular Weight, and Tacticity via Iterative Radical Additions and Olefin Metathesis Reactions Reviewed

M. Miyajima, K. Satoh, T. Horibe, K. Ishihara, M. Kamigaito

J. Am. Chem. Soc. Vol. 142 ( 44 ) page： 18955 - 18962 2020.11

Metal-Catalyzed Living Radical Polymerization Invited Reviewed

M. Kamigaito, T. Ando, M. Sawamoto

Chem. Rev. Vol. 101 ( 12 ) page： 3689 2001.12

Stereospecific Living Radical Polymerization: Dual Control of Chain Length and Tacticity for Precision Polymer Synthesis Invited Reviewed

K. Satoh, M. Kamigaito

Chem. Rev. Vol. 109 ( 11 ) page： 5120-5156 2009.11

Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris-(triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization Reviewed

M. Kato, M. Kamigaito, M. Sawamoto, and T. Higashimura

Macromolecules Vol. 28 page： 1721 1995

Structures and Properties of Temperature-Responsive Gels with Homogeneous Networks Prepared by Photogelation of Four-Armed Star-Shaped Poly(N-isopropylacrylamide) Invited Reviewed

N. Itaya, C. Norioka, K. Satoh, M. Kamigaito, A. Kawamura, and T. Miyata

Vol. in press 2025.1

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Papers - KAMIGAITO, Masami