Updated on 2023/12/19

写真a

 
NOMURA Nobuyoshi
 
Organization
Graduate School of Bioagricultural Sciences Department of Applied Biosciences Associate professor
Graduate School
Graduate School of Bioagricultural Sciences
Undergraduate School
School of Agricultural Sciences
Title
Associate professor
Contact information
メールアドレス

Degree 1

  1. Ph.D ( 1994.3   Nagoya University ) 

Research Interests 5

  1. polymer synthesis

  2. precision polymerization

  3. ring-opening polymerization

  4. catalyst

  5. condensation polymerization

Research Areas 3

  1. Others / Others  / Polymer Chemistry

  2. Others / Others  / Polymer/Textile Materials

  3. Others / Others  / Engineering@Industrial Chemistry@Synthetic Chemistry

 

Papers 14

  1. Random Copolymerization of epsilon-Caprolactone with Lactide Using a Homosalen-Al Complex Reviewed

    Nomura, N.; Akita, A.; Ishii, R.; Mizuno, M.

    Journal of the American Chemical Society   Vol. 132 ( 6 ) page: 1750 - 1751   2010.2

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja9089395

  2. An Efficient Protocol of Iridium-Catalyzed Allylic Substitution Reaction and its Application to Polymer Synthesis: Complementary Regio- and Stereoselective Allylation Polycondensation via Ir- and Pd-catalyses Reviewed

    Nomura, N.; Komiyama, S.; Kasugai, H.; Saba, M.

    Journal of the American Chemical Society   Vol. 130 ( 3 ) page: 812 - 814   2008.1

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja076019k

  3. Homogeneous Two-Component Polycondensation without Strict Stoichiometric Balance via the Tsuji-Trost Reaction: Remote Control of Two Reaction Sites by Catalysis Reviewed International coauthorship

    Nomura, N.; Tsurugi, K.; Kondo, T.; RajanBabu, T. V.

    Journal of the American Chemical Society   Vol. 126 ( 17 ) page: 5354 - 5355   2004.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja0492743

  4. A Direct Function Relationship between Isotacticity and Melting Temperature of Multiblock Stereocopolymer Poly(rac-lactide) Reviewed

    Nomura, N.; Hasegawa, J.; Ishii, R.

    Macromolecules   Vol. 42 ( 13 ) page: 4907 - 4909   2009.7

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ma900760z

  5. Stereoselective Ring-Opening Deacetonation Polymerization of Racemic 2,2,5-Trimethyl-1,3-dioxolan-4-one by Using Homosalen-Aluminum Complexes: A Novel Approach to Isotactic -Poly( rac-lactic acid)

    Sakai, K; Yagi, Y; Nomura, N

    SYNLETT   Vol. 34 ( 20 ) page: 2520 - 2524   2023.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-0042-1751472

    Web of Science

  6. Ring-Opening Polymerization of epsilon-Caprolactone Initiated by Multinuclear Aluminum Methanetris(aryloxido) Complexes

    Oishi Masataka, Ichinose Yuri, Iwata Naomi, Nomura Nobuyoshi

    ORGANOMETALLICS   Vol. 38 ( 21 ) page: 4233-4243   2019.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.organomet.9b00540

    Web of Science

  7. Dinuclear Pentacoordinated Organoyttrium Biphenolates as Initiators for the Synthesis of High-Molecular Weight Isotactic Poly(2-vinylpyridine)

    Oishi Masataka, Yoshimura Reiji, Nomura Nobuyoshi

    INORGANIC CHEMISTRY   Vol. 58 ( 20 ) page: 13755-13760   2019.10

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.9b02385

    Web of Science

    PubMed

  8. A synergic catalysis of (salicylaldiminate)2AlEt and (BnO)2AlEt in the ring-opening polymerization of ε-caprolactone Reviewed

    Nomura, N.; Yamakawa, D.; Marutani, T.; Aoyama, T.; Oishi, M.

    Polymer Journal   Vol. 51 ( 8 ) page: 791 - 794   2019.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41428-019-0187-2

    Web of Science

  9. A practical ortho-rearrangement of silyl group of ortho-bromophenyl silyl ethers using magnesium(0) Reviewed

    Hasegawa, T.; Kishida, H.; Nomura,* N.

    Tetrahedron Letters   Vol. 58 ( 5 ) page: 455 - 457   2017.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.tetlet.2016.12.052

    Web of Science

  10. Structural Diversity of Tris(2-hydroxyaryl)methane-derived Aluminum Complexes Reviewed

    Oishi, M.; Ichinose, Y.; Nomura, N.

    European Journal of Inorganic Chemistry     page: 1596-1603   2016.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ejic.201501438

  11. Synthesis of Crystalline Poly(lactic acid) from Glycerol By-product via Hydrothermal Reaction and Stereoselective Polymerization Reviewed

    Hasegawa, T.; Kishida, H.; Nomura, N.; Moriya, T.

    Chemistry Letters   Vol. 44 ( 3 ) page: 375-377   2015.3

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.141059

  12. Ring-opening polymerization of lactones by rare-earth metal triflates and by their reusable system in ionic liquids Invited Reviewed

    Nomura, N.; Taira, A.; Nakase, A.; Tomioka, T.; Okada, M.

    Tetrahedron   Vol. 63 ( 35 ) page: 8478-8484   2007.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    有機合成で研究が活発な希土類金属錯体を用いて、ε-カプロラクトンの開環重合について検討し、水やアルコールなどが存在していてもスカンジウムトリフラート錯体が分子量および分子量分布を制御したポリマーを与えることを見出した。さらに、イオン液体を触媒担持体として利用し、触媒を何度も利用できる重合系を報告した。

  13. Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Achiral Salen- and Homosalen-Aluminum Complexes Reviewed

    Nomura, N.; Ishii, R.; Yamamoto, Y.; Kondo, T.

    Chemistry-A European Journal   Vol. 13 ( 16 ) page: 4433-4451   2007.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  14. Salicylaldimine-Aluminum Complexes for the Facile and Efficient Ring-Opening Polymerization of ε-Caprolactone Reviewed

    Nomura, N.: Aoyama, T.; Ishii, R.; Kondo, T.

    Macromolecules   Vol. 38 ( 13 ) page: 5363-5366   2005.6

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

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Books 1

  1. Hydrovinylation in Organic Synthesis (Comprehensive Organic Synthesis) Reviewed International journal

    RajanBabu, T. V.; Cox, G. A.; Lim, H. J.; Nomura, N.; Sharma, R. K.; Smith, C. R.; Zhang, A.( Role: Joint author)

    Elsevier  2014.4 

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    Total pages:39   Language:English Book type:Scholarly book

MISC 3

  1. Synthesis of Stereocomplex Poly(lactic acid) from Racemic Lactide Using Polymer-Supported Al Catalysts Invited

    高分子   Vol. 59 ( 12 ) page: 902 - 902   2010.12

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Article, review, commentary, editorial, etc. (other)  

  2. Ideal Copolymerization of Lactide with epsilon-Caprolactone Invited

    Akita, A.; Ishii, R.; Nomura, N.

      Vol. 59 ( 10 ) page: 773 - 773   2010.10

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    Authorship:Corresponding author   Language:English   Publishing type:Article, review, commentary, editorial, etc. (other)  

  3. 非等モル下の重縮合 Invited

    野村信嘉

    高分子   Vol. 53 ( 8 ) page: 587 - 590   2004.8

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    Authorship:Lead author, Corresponding author   Language:Japanese  

Presentations 2

  1. Selective Polymerization of 1:1:1 Mixture of D-, L-, meso-Lactides for Synthesis of Semicrystalline Poly(lactic acid)

    Nobuyoshi Nomura

    The 1st Nagoya Symposium on Green Synthesis & Catalysis 

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    Event date: 2012.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  2. Ring-opening homo- and copolymerizations of racemic lactide and/or epsilon-caprolactoneusing homosalen-Al complexes International conference

    Nomura, N.; Akita, A.; Ishii, R.; Mizuno, M.

    Pacifichem 2010 

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    Event date: 2010.12

    Language:English   Presentation type:Poster presentation  

Research Project for Joint Research, Competitive Funding, etc. 9

  1. ステレオコンプレックス型ポリ乳酸重合触媒の実用化研究

    2007.7 - 2015.3

    国内企業との共同研究 

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    Grant type:Collaborative (industry/university)

    Grant amount:\9750000

  2. ラセミラクチドの開環重合触媒の実用化検討

    2006.12 - 2007.3

    企業からの受託研究 

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    Grant type:Collaborative (industry/university)

    Grant amount:\470000

  3. バイオポリマーに関する研究

    2009.4 - 2012.3

    国内企業との共同研究 

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    Authorship:Coinvestigator(s)  Grant type:Collaborative (industry/university)

    Grant amount:\2000000

  4. モノマーの化学量論比が重合度に影響しない均一系二成分重縮合

    2004.6 - 2006.3

    旭硝子財団 

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    Grant type:Competitive

    委任経理金

  5. ラセミラクチドの立体選択的リビング重合触媒の開発とその活用法

    2002.11 - 2004.4

    住友財団 

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    Grant type:Competitive

    委任経理金

  6. 後期遷移金属触媒によるアリル化反応を利用した光学活性ポリマーの合成

    2012.4 - 2016.3

    国内共同研究 

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    Grant type:Other

    Grant amount:\460000

  7. 研究助成

    2012.4 - 2013.3

    研究寄附金 

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    Grant type:Collaborative (industry/university)

    Grant amount:\300000

  8. 環境調和型生医学材料合成反応の開発

    2001.5 - 2002.5

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    委任経理金

  9. 低原子価チタン触媒を用いた新規精密重合反応の開発

    1997.5 - 1998.5

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    委任経理金

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KAKENHI (Grants-in-Aid for Scientific Research) 1

  1. Designing racemic monomer consisting of one molecule of lactic acid and synthesis of crystalline poly(racemic lactic acid) by its stereoselective polymerization

    Grant number:19K05579  2019.4 - 2022.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

    Nomura Nobuyoshi

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4290000 ( Direct Cost: \3300000 、 Indirect Cost:\990000 )

    The stereoselective polymerization of racemic lactide which is a cyclic dimer of racemic lactic acid is one of the effective methods for synthesis of crystalline poly(lactic acid) from racemic lactic acid. However, in the process of racemic lactide synthesis, undesired isomer, meso-lactide, is also produced about 35-50% yield, and purification of racemic lactide is required.
    In this research, a new monomer consisting of one molecule of racemic lactic acid was designed. In this case, diastereomers do not exist, and racemic lactic acid is effectively utilized without formation of undesired compound. The designed monomer was iso-selectively polymerized to form crystalline poly(lactic acid).

Industrial property rights 1

  1. 半結晶ポリラクチドの製造方法(PCT)

    岸田央範・長谷川剛史・野村信嘉・高橋誠・SCHROEDER, Joeseph・NATAL, Manuel

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    Application no:PCT/JP2012/074308  Date applied:2012.9

    Country of applicant:Domestic  

 

Media Coverage 3

  1. 新素材で裾野広がる Newspaper, magazine

    日刊工業新聞  2013.10

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    Author:Other 

  2. 結晶性ポリ乳酸量産へ Newspaper, magazine

    日刊工業新聞  2013.2

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    Author:Other 

  3. BDF副産物からPLA Newspaper, magazine

    化学工業日報  2011.9

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    Author:Other