論文 - 土川　覚

Calibration of SilviScan data of <i>Cryptomeria japonica</i> wood concerning density and microfibril angles with NIR hyperspectral imaging with high spatial resolution 査読有り

Ma, T; Inagaki, T; Tsuchikawa, S

HOLZFORSCHUNG   71 巻 ( 4 ) 頁： 341 - 347   2017年4月

　詳細を見る

担当区分：責任著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Holzforschung  

Wood density and microfibril angle (MFA) are strongly correlated with wood stiffness, swelling/shrinkage, and its anisotropy. Understanding the spatial distribution of these data is critical for solid timber applications. In this study, near-infrared (NIR) hyperspectral imaging has been calibrated for evaluation of wood density and MFA in an effective manner. Briefly, five wood samples collected from both normal wood (NW) and compression wood (CW) moieties of two different Cryptomeria japonica trees were analyzed. Partial least squares (PLS) regression analysis was performed to determine the relationship between X-ray densitometry data obtained by SilviScan and NIR spectra, and cross-validation (leave-one-out) approach served for prediction performances. The validation coefficient of determination (r²) between the predicted densities by the NIR technique and the X-ray data was 0.83 with a root mean squared error of cross-validation (RMSECV) of 105.2 kg m^-3. Regarding MFA, the r² was 0.77 and RMSECV 5.36°. Wood density was successfully maped as well as the MFA at a high spatial resolution. As a result, the detection of annual growth ring features and evaluation of aspects of heterogeneous wood quality has been facilitated. The mapping results were visually checked by looking at the difference between earlywood (EW) and latewood (LW) for density and by means of the Mäule color reaction indicating high lignin contents in CW in terms of MFA validation as CWs have high MFA values.

DOI： 10.1515/hf-2016-0153

Web of Science

Scopus

Temperature dependence of wood photodegradation monitored by infrared spectroscopy

Varga, D, Tolvaj, L, Tsuchikawa, S, Bejoc, L, Prekleta, E

Journal of Photochemistry and Photobiology A: Chemistry   348 巻   頁： 219-225   2017年

Dynamic behavior of wood chemical components under drying process measured by near-infrared spectroscopy 査読有り

Sugii, S.; Fujimoto, T.; Tsutsumi, H.; Inagaki, T.; Tsuchikawa, S.

Journal of Near Infrared Spectroscopy   25 巻 ( 6 ) 頁： 400-406   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

Temperature dependence of wood photodegradation monitored by infrared spectroscopy 査読有り

Varga, D., Tolvaj, L.; Tsuchikawa, S.; Bejoc, L.; Prekleta, E.

Journal of Photochemistry and Photobiology A: Chemistry   348 巻   頁： 219-225   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

Segregating wood wastes by repetitive principal component analysis of near infrared spectra 査読有り

Kobori, H.; Higa, S.; Tsuchikawa, S., Kojima, Y.; Suzuki, S.

Journal of Near Infrared Spectroscopy   25 巻 ( 3 ) 頁： 180-187   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

The effect of path length, light intensity and co-added time on the detection limit associated with NIR spectroscopy of potassium hydrogen phthalate in aqueous solution 査読有り

Inagaki, T.; Watanabe, T.; Tsuchikawa S.

PLOS ONE     頁： https://doi.org/10.1371/journal.pone.0176920   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： https://doi.org/10.1371/journal.pone.0176920

Classification of mung bean seeds for sprout production using near-infrared spectroscopy and hyperspectral imaging 査読有り

Phuangsombut, K.; Terdwongworakul, A.; Suttiwijitpukdee, N.; Phuangsombut A.; Tsuchikawa S.; Inagaki T.; Ma T.

Thai Society of Agricultural Engineering Journal   23 巻 ( 1 ) 頁： 23-29   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

The effect of path length, light intensity and co-added time on the detection limit associated with NIR spectroscopy of potassium hydrogen phthalate in aqueous solution. 査読有り

Inagaki T, Watanabe T, Tsuchikawa S

PloS one   12 巻 ( 5 ) 頁： e0176920   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：PLoS ONE  

Near infrared (NIR) spectroscopy is a common means of non-invasively determining the concentrations of organic compounds in relatively transparent aqueous solutions. Rigorous determination for limit of detection (LOD) is of importance for the application use of NIR spectroscopy. The work reported herein determined the LOD with the analysis of potassium hydrogen phthalate (KHP) in water with partial least square (PLS) calibration in the range of 6300±5800 cm-1 between the two strong absorption bands of water, in which the C-H overtone bands of KHP are located. A comparison of the LOD estimated when using various condition (path length, aperture and co-Added scan times) showed that the lowest LOD for KHP obtained with a fiber optic cable attachment equipped NIR spectrometer is approximately 150 ppm.

DOI： 10.1371/journal.pone.0176920

Web of Science

Scopus

PubMed

Classification of mung bean seeds for sprout production using near-infrared spectroscopy and hyperspectral imaging 査読有り

Phuangsombut, K., Terdwongworakul, A., Suttiwijitpukdee, N., Phuangsombut A., Tsuchikawa S., Inagaki T., Ma T.

Thai Society of Agricultural Engineering Journal   23 巻 ( 1 ) 頁： 23-29   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）  

Dynamic behavior of wood chemical components under drying process measured by near-infrared spectroscopy

Sugii, S, Fujimoto, T, Tsutsumi, H, Inagaki, T, Tsuchikawa, S

Journal of Near Infrared Spectroscopy   25 巻 ( 6 ) 頁： 400-406   2017年

Development of Multiple Evaluation Method of Wood Pulp in Paper by Near Infrared Spectroscopy

Kawabe Chika, Fukasawa Hiroyuki, Inagaki Tetsuya, Tsuchikawa Satoru

紙パ技協誌   71 巻 ( 3 ) 頁： 326 - 334   2017年

　詳細を見る

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：紙パルプ技術協会  

<p>Near infrared spectroscopy （NIRS） has been applied in some fields such as medicines, chemicals and ag ricultural products. In this report, NIRS was applied to paper sheets to analyze the contained pulp qualita tively and quantitatively. LBKP, NBKP, CTMP and others could be classified by principal component analysis （PCA） for NIR spectra. The blend ratio of LBKP, NBKP and CTMP in the both mixtures of LBKP and CTMP, and NBKP and CTMP could be determined respectively by partial least squares regression （PLSR）for NIR spectra within the coefficient of determination （R² value） of 0.98. Furthermore, the ratio of mixture of KP and another pulp on the paper could be determined somewhat correctly even if we do not know what kinds of pulp were contained. NIRS could also be used to estimate the drainability of LBKP; that is, the pre dicted value was very close to the measured value. NIRS was also applied to evaluate the degree of degrada tion of pulp. PCA for NIR spectra of LBKP has revealed the linear relationships between recycled times and score.</p><p>The NIR technique is faster than staining techniques, and does not require special training. If we could have tested a wider variety of samples, if we had more time, and if we could have optimized the analysis con dition, it would be possible to estimate more precisely.</p>

DOI： 10.2524/jtappij.71.326

CiNii Research

Segregating wood wastes by repetitive principal component analysis of near infrared spectra

Kobori, H, Higa, S, Tsuchikawa, S, Kojima, Y, Suzuki, S

Journal of Near Infrared Spectroscopy   25 巻 ( 3 ) 頁： 180-187   2017年

近赤外分光法を用いた紙中の木材パルプの複合的評価手法の開発

河部 千香, 深沢 博之, 稲垣 哲也, 土川 覚

紙パ技協誌   71 巻 ( 3 ) 頁： 318 - 325   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：紙パルプ技術協会  

<p>近赤外分光法は食品や薬品などの多くの分野で実用化されている。製紙分野でも古くからオンライン水分計として多くの工場で利用されているが，水分計以外の用途について，まだ広くは利用されていない。</p><p>そこで本研究では，近赤外分光法を用いて木材パルプを中心に，紙に含まれるパルプ繊維を複合的に評価する手法の開発を目指すこととした。試験法として，①産地の異なる広葉樹漂白クラフトパルプ（LBKP）（計8種）と針葉樹漂白クラフトパルプ（NBKP）（計3種），ケミサーモメカニカルパルプ（CTMP）を始めとする様々な種類のパルプ繊維から作製した試料の繊維組成試験，②LBKPのろ水度評価，③LBKPのリサイクル回数の異なる試料のリサイクル回数評価試験を検討した。</p><p>①について，それぞれのパルプ繊維は主成分分析によりはっきりと分離でき，繊維の種類を判別することが可能であることが分かった。検討に用いたパルプ繊維のうち任意の2種を混合した紙の近赤外分光スペクトルをPLS回帰分析すると，含まれているパルプ繊維が分かっていない試料についても定量分析可能であることが分かった。②，③についても，近赤外分光法を適用すれば，今回検討に用いたLBKPに関して，評価可能であることが示された。</p><p>近赤外分光法による定性・定量分析は従来から行われている染色法と比較して，測定時間が短縮でき，経験を積まなくても非破壊で簡便に測定ができる。</p><p>今回，3つの項目をそれぞれ検討したが，これらの手法は解析に用いる水準や測定回数の増加，説明変数に用いる波数帯の最適化，異なる回帰手法の適用などにより，さらに精度が向上し，1度の測定でいくつかの項目が瞬時に評価可能となることも考えられる。より実用化が進めば，近赤外分光法が使用する原料を評価する有効な解析法の一つになりうると期待される。</p>

DOI： 10.2524/jtappij.1603

CiNii Research

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T., Kashima M., Tsuchikawa S.

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Scopus

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T, Kashima M, Tsuchikawa S

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T, Kashima M, Tsuchikawa S

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T, Kashima M, Tsuchikawa S

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T, Kashima M, Tsuchikawa S

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T, Kashima M, Tsuchikawa S

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.

Estimation of wood density, moisture content and fiber orientation by THz time domain spectroscopy 査読有り

Inagaki T., Kashima M., Tsuchikawa S.

28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector     頁： 3 - 6   2017年

　詳細を見る

記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：28th International Conference on Wood Science and Technology, ICWST 2017: Implementation of Wood Science in Woodworking Sector  

Terahertz (THz) radiation has the potential to be a useful tool for sensing and imaging of wood because wood is relatively transparent at these frequencies (below about 1 THz). In this study, demonstration of simultaneous prediction of solid wood density, moisture content and fiber orientation, all of which are critical in manufacturing operations, of 14 species including softwood and hard wood was accomplished using terahertz time-domain spectroscopy (THz-TDS). THz measurements of wood at various moisture contents were taken for 19 orientations of the THz field (0-180o with 10o step) with respect to the visible grain. The real part of refractive index value and absorption cosfficient had strong correlation with density and moisture content of the wood. A strong correlation between measured and predicted values for density and moisture content were observed. The possibility for the estimation of fiber orientation using the birefringence property of wood were shown.