研究者詳細 - 齋藤　永宏

論文 - 齋藤　永宏

分割表示 367 件中 101 - 120 件目／全件表示 >>

Generation of non-equilibrium condition in solution plasma discharge using low-pass filter circuit

Heo Y., Lee S., Bratescu M., Kim S., Lee G., Saito N.

Plasma Processes and Polymers 14 巻 ( 8 ) 2017年8月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Plasma Processes and Polymers

Solution plasma process has been researched as one of the synthetic methods of nano- and functional materials using plasma discharge in liquids. In this study, a low-pass filter circuit was introduced to increase the density and temperature of electrons involved in a non-equilibrium condition. The discharge properties of the solution plasma generated by conventional and low-pass filter circuits were characterized and comparatively analyzed. Filtration of the MHz range current oscillations, an increase in the maximum discharge current, and a higher stability of solution plasma were obtained by simply inserting a resistor-capacitor (RC) component in the circuit, which leads to the increases in the density and temperature of electrons.

DOI： 10.1002/ppap.201600163

Simple Solution Plasma Synthesis of Hierarchical Nanoporous MnO<inf>2</inf> for Organic Dye Removal

Kim H., Watthanaphanit A., Saito N.

ACS Sustainable Chemistry and Engineering 5 巻 ( 7 ) 頁： 5842 - 5851 2017年7月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：ACS Sustainable Chemistry and Engineering

We have demonstrated a simple and green approach to synthesize hierarchical nanoporous MnO2 by applying plasma in a liquid precursor; the approach is named the "solution plasma process (SPP)." Three types of sugar, i.e., glucose, fructose, and sucrose, were used as inducers for the nanoporous MnO2 formation (hereafter called G-MnO2, F-MnO2, and S-MnO2). These were successfully synthesized within a few minutes (7-19 min) under ambient conditions. It was confirmed that the generated numerous reactive species (e.g., electrons, radicals, and ions) accelerated the reduction of MnO4-. The reaction rate as well as the physical and chemical features of resulting products were found to be related to the type of sugars. Their high surface areas (F-MnO2 (169.1 m2·g-1) > G-MnO2 (141.0 m2·g-1) > S-MnO2 (85.5 m2·g-1)) provided efficient capability for the adsorption of cationic dye molecules, i.e., methylene blue. The dye removal efficiencies of all samples were >99% for an initial dye concentration (C0) of 10 mg·L-1 within 2 min and >82% for C0 = 50 mg·L-1 within 30 min. We expect that the synthesis route presented in this study can be extended to the large-scale production of effective adsorbents and to find practical applications for the industrial and green infrastructure.

DOI： 10.1021/acssuschemeng.7b00560

Enhanced degradation of chitosan by applying plasma treatment in combination with oxidizing agents for potential use as an anticancer agent

Chokradjaroen C., Rujiravanit R., Watthanaphanit A., Theeramunkong S., Saito N., Yamashita K., Arakawa R.

Carbohydrate Polymers 167 巻頁： 1 - 11 2017年7月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Carbohydrate Polymers

Solution plasma (SP) treatment in combination with oxidizing agents, i.e., hydrogen peroxide (H2O2), potassium persulfate (K2S2O8) and sodium nitrite (NaNO2) were adopted to chitosan degradation in order to achieve fast degradation rate, low chemicals used and high yield of low-molecular-weight chitosan and chitooligosaccharide (COS). Among the studied oxidizing agents, H2O2 was found to be the best choice in terms of appreciable molecular weight reduction without major change in chemical structure of the degraded products of chitosan. By the combination with SP treatment, dilute solution of H2O2 (4–60 mM) was required for effective degradation of chitosan. The combination of SP treatment and dilute solution of H2O2 (60 mM) resulted in the great reduction of molecular weight of chitosan and water-soluble chitosan was obtained as a major product. The resulting water-soluble chitosan was precipitated to obtain COS. An inhibitory effect against cervical cancer cell line (HeLa cells) of COS was also examined.

DOI： 10.1016/j.carbpol.2017.03.006

Crystallinity and surface state of cellulose in wet ball-milling process

Nemoto S., Ueno T., Watthanaphanit A., Hieda J., Saito N.

Journal of Applied Polymer Science 134 巻 ( 22 ) 2017年6月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Applied Polymer Science

We report the effect of wet ball-milling process under mild neutral salt conditions on the alteration of crystallinity and surface state of microcrystalline cellulose (MC). The ball-milling experiments were performed when the MC was immersed in H2O, NaCl aqueous solution, and KCl aqueous solution. Two collation groups, i.e., MC immersed in H2O2 and nonimmersed MC were additionally investigated for comparison. Except when H2O2 was present, the highest decrease in the cellulose crystallinity index (CI) was observed in dilute KCl. On the other hand, the CI of wet-milled MC/NaCl was greater than that of the wet-milled MC/H2O, however, still lower than that of the non-immersed MC. XPS results showed that the carbonization progressed in dry-milled MC and wet-milled MC/NaCl surfaces. Though, the surface oxidization progressed in wet-milled MC/H2O and wet-milled MC/KCl. Lastly, the ball-milling processes in different solutions led to various decreases of the crystallinity and the surface degradation due to carbonization and/or oxidization. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44903.

DOI： 10.1002/app.44903

The plasma-assisted formation of Ag@Co<inf>3</inf>O<inf>4</inf> core-shell hybrid nanocrystals for oxygen reduction reaction

Kim S.M., Jo Y.G., Lee M.H., Saito N., Kim J.W., Lee S.Y.

Electrochimica Acta 233 巻頁： 123 - 133 2017年4月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Electrochimica Acta

In this study, Ag@Co3O4 core-shell hybrid nanocrystals are synthesized using a plasma discharge in water for oxygen reduction reaction in alkaline solutions. A detailed analysis via electron microscopy in combination with EDS elemental mapping conclusively verifies that the reactive oxygen species generated from the plasma-assisted decomposition of water molecules govern the phase structure of the nanocrystals. Under oxidizing conditions, the Co oxide, which is more stable than the Ag oxide, provides the driving force for the segregation and preferential oxidation of Co at the surface. This leads to the formation of the core-shell architecture. The electrochemical measurements for the oxygen reduction reaction reveal that the specific activities of the Ag@Co3O4 core-shell nanocrystals are ca. 5.2 and 2.6 times higher than those of the pure Ag and Ag-Co alloy nanocrystals. The enhanced catalytic performance is attributed to the combination of electronic and geometric effects, which facilitates the O[sbnd]O bond breaking and desorption for the oxygen reduction. The insights gain through this study may serve as a foundation to design better electrochemical oxygen reduction electrocatalysts.

DOI： 10.1016/j.electacta.2017.03.049

Enhanced ferromagnetism in graphite-like carbon layer-coated ZnO crystals

Tu N., Dung N.H., Lan N.T., Nguyen K.T., Dung N.D., Viet D.X., Tuan N.T., Bui H.V., Nam D.V., Huy P.T., Saito N.

Journal of Alloys and Compounds 695 巻頁： 233 - 237 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Alloys and Compounds

We report on the preparation of graphite-like carbon-coated ZnO nanoparticles by ball milling a powder mixture of ZnO and C. Magnetic measurements indicated that carbon coating can strongly enhance the room-temperature ferromagnetism of ZnO nanoparticles, depending on preparation conditions. This enhancement may stem from robust ferromagnetism at the ZnO/C interface. The origin of interfacial ferromagnetism is attributed to crystallographic defects at the surface of ZnO crystals which are stabilized by the carbon shell layer.

DOI： 10.1016/j.jallcom.2016.10.200

Facile preparation of defective black TiO<inf>2</inf> through the solution plasma process: Effect of parametric changes for plasma discharge on its structural and optical properties

Jedsukontorn T., Ueno T., Saito N., Hunsom M.

Journal of Alloys and Compounds 726 巻頁： 567 - 577 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Alloys and Compounds

Defective TiO2 or black TiO2 nanoparticles (NPs) are remarkably attractive for photocatalytic applications, since the defect-disordered structure crucially affects the optical properties. In this work, high visible light-active black TiO2 NPs were synthesized by an innovative solution plasma process (SPP) with a titanium (Ti) electrode in HNO3 solution. The effects of the plasma operating parameters, in terms of the pulse frequency (20–80 kHz) and pulse width (0.5–2.0 μs) under two different HNO3 concentrations (0.3 mM and 3.0 mM) on the morphology, structural and optical properties of the obtained black TiO2 NPs were explored. Increasing the pulse frequency, pulse width and concentration of HNO3 all increased the input energy per pulse and energy per second, which induced an increased volume-based particle size, synthesis rate and Ti3+/Ti4+ ratio, but decreased the rutile mass fraction, the Ti-OH/TiO ratio and the band gap energy of the obtained black TiO2 NPs. Among all the prepared black TiO2 NP samples, those prepared at a pulse frequency of 20 kHz, pulse width of 2 μs (energy input per second of 17.3 J) in 3.0 mM HNO3 exhibited the highest visible-light absorption capability (the lowest band gap energy of ∼2.44 eV). The variation in the band gap energy was more strongly dependent on the Ti3+/Ti4+ ratio than the Ti-OH/TiO ratio in the structure of black TiO2 NPs.

DOI： 10.1016/j.jallcom.2017.08.028

New insights into vegetable oil pyrolysis by cold plasma technique

Meeprasertsagool P., Watthanaphanit A., Ueno T., Saito N., Reubroycharoen P.

Energy Procedia 138 巻頁： 1153 - 1158 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Energy Procedia

Green liquid fuels are alternatively produced by pyrolysis of vegetable oil. Still, this process requires high processing temperature and high energy consumption per unit cost. Recently, solution/liquid-phase plasma (cold plasma) is the novel method to provide the direct energy at highly excited energy state. In this study, the investigation of the green fuel synthesis from vegetables oils using cold plasma was examined. The cold plasma reactor was connected to a bipolar pulsed power supply under 200 ml of palm oil, the pulse frequency adjusted from 15-45 kHz and the voltage adjusted in ranges of 1.2-1.5 kV with 40 minutes of discharge times, pulse width 2 μs, electrode distance 0.5 mm. Properties of generated plasma were investigated by optical emission spectroscopy (OES) methods. The liquid products were analysed by GC-MS. In order to identify components of the liquid product, a GC-MS chromatogram was carried out; the main peaks were oleic acid and palmitic acid. Therefore, the other peak showed which products were cracked to short-chain hydrocarbon and hexadecane was one of the compounds which were cracked in palm oil. In conclusion, the results showed that plasma has potential and enough energy to convert vegetable oils in liquid fuels at room temperature which can also provide the direct energy better than pyrolysis.

DOI： 10.1016/j.egypro.2017.10.224

Photocatalytic behavior of metal-decorated TiO<inf>2</inf> and their catalytic activity for transformation of glycerol to value added compounds

Jedsukontorn T., Saito N., Hunsom M.

Molecular Catalysis 432 巻頁： 160 - 171 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Molecular Catalysis

In this work, TiO2 was decorated with one of four different metals (Bi, Pd, Pt and Au) by sol immobilization at ambient condition. The individual addition of each metals on the TiO2 did not affect the crystallite size or band gap energy of TiO2, but increased its visible light absorption ability due to the localized surface plasmon resonance effect of the doped metals, except for Bi, as well as the mechanism of the charge transfer. Among all the prepared metal-decorated TiO2 photocatalysts, Au/TiO2 exhibited the highest visible light absorption ability and an appropriate mechanism of charge transfer, which consequently alleviated the e−–h+ recombination. It also provided the highest photocatalytic activity for glycerol conversion (92.8% at 14 h) and yield of dihydroxyacetone, glyceraldehyde, glycolic acid, hydroxypyruvic acid and formaldehyde of 12.0, 23.1, 10.7, 13.6 and 15.3%, respectively.

DOI： 10.1016/j.mcat.2017.02.022

Novel synthesis of PtPd nanoparticles with good electrocatalytic activity and durability

Zhang J., Hu X., Yang B., Su N., Huang H., Cheng J., Yang H., Saito N.

Journal of Alloys and Compounds 709 巻頁： 588 - 595 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Alloys and Compounds

PtPd nanoparticles in the size range of 2–5 nm have been directly synthesized from their metal wire electrodes via a one-step plasma sputtering technique in a solution of water and methanol under atmospheric pressure. PtPd nanoparticles produced in the water/methanol solution have good dispersibility compared with those produced in water because methanol successfully reduces the aggregation of the nanoparticles during the plasma sputtering process. Further, the solution plasma technique provides a novel reaction field with a highly energetic state for the PtPd nanoparticle synthesis. KB-supported PtPd nanoparticles (PtPd/KB, 12 wt% Pt) exhibit excellent electrocatalytic activity (over 4 times mass activity compared with commercial Pt/C) and stability (maintaining 43% mass activity after 300 cycles) towards methanol electrooxidation because of their large electrochemical surface area (ECSA, that is 2.5 times greater than that of commercial Pt/C) and synergistic effect of the binary alloy. Thus, as-synthesized PtPd/KB catalysts may have potential applications in direct methanol fuel cells (DMFCs) to lower their cost and improve their cycle efficiency.

DOI： 10.1016/j.jallcom.2017.03.202

Simple introduction of carboxyl head group with alkyl spacer onto multiwalled carbon nanotubes by solution plasma process

Nemoto S., Ueno T., Watthanaphanit A., Hieda J., Bratescu M.A., Saito N.

Japanese Journal of Applied Physics 56 巻 ( 9 ) 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Japanese Journal of Applied Physics

A simple method of fabricating carboxyl-terminated multiwalled carbon nanotubes (MWCNTs) with alkyl spacers was developed to improve the dispersion quality of MWCNTs in aqueous solutions using solution plasma (SP) in a 6-aminocaproic acid solution. The formation of SP in the solution led to better dispersion of MWCNTs in aqueous solutions. Fourier transform infrared spectroscopy (FT-IR) results indicate that a carboxyl group with an alkyl spacer can be introduced by SP treatment in the 6-aminocaproic acid solution. Sedimentation tests show that the SP-treated MWCNTs in the 6-aminocaproic acid solution retained their good dispersion quality in aqueous solutions of pHs 5 6 and 9. The alkyl spacer plays an important role in the preservation of dispersion states particularly at pH 6.

DOI： 10.7567/JJAP.56.096202

Solution plasma synthesis of Pt/ZnO/KB for photo-assisted electro-oxidation of methanol

Hu X., Ge C., Su N., Huang H., Xu Y., Zhang J., Shi J., Shen X., Saito N.

Journal of Alloys and Compounds 692 巻頁： 848 - 854 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Alloys and Compounds

A high electrocatalytic performance Pt/ZnO/KB is well fabricated by a solution plasma technique in water at atmospheric pressure. Their electrocatalytic performance toward methanol oxidation is evaluated in alkaline with light irradiation or in dark. The electrocatalytic activity of Pt is improved in dark because the distribution and reactive sites of Pt nanoparticles are improved by coupling ZnO. And higher electrocatalytic activity is detected under light irradiation because of synergistic effect of photo- (ZnO) and electro-catalyst (Pt). Compared with several morphologies ZnO, ZnO nanowires give better catalytic activity for methanol oxidation than porous ZnO nanosheets because ZnO nanowires possess better electron transport property and smaller resistance. Under light irradiation, Pt/ZnO/KB coupled with ZnO nanowires shows over 3 times higher catalytic activity (ca. 964 mA mgPt−1) than Pt/KB (ca. 306 mA mgPt−1). And the tolerance to CO-poisoning and stability of Pt/ZnO/KB are also improved. Therefore, Pt/ZnO/KB nanocomposite will be a highly efficient potential anode catalyst in DMFCs with light irradiation.

DOI： 10.1016/j.jallcom.2016.09.032

Solution plasma synthesis of a boron-carbon-nitrogen catalyst with a controllable bond structure

Lee S., Heo Y., Bratescu M.A., Ueno T., Saito N.

Physical Chemistry Chemical Physics 19 巻 ( 23 ) 頁： 15264 - 15272 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Physical Chemistry Chemical Physics

Synthesis of boron-carbon-nitrogen (BCN) nanocarbon with a controllable bond structure for enhanced oxygen reduction reaction (ORR) activity and durability was performed using a new method of discharge in organic solution mixtures named the 'Solution Plasma Process'. Using selected precursors a new strategy for the simultaneous synthesis of nanocarbon co-doped with heteroatoms was found. The synergistic effect of N and B in an uncoupling bond state improved the formation of new active sites for the ORR performance by changing the electronic structure of the base carbon. Meanwhile, when B and N are bonded together, the BCN catalyst contributes to a reduced ORR activity by forming a balanced electronic structure in carbon. The BCN nanocarbon with an uncoupling bond state exhibits an enhanced ORR activity under alkaline conditions, with an onset potential of -0.25 V versus -0.31 V for B/N coupling and 3.43 transferred electrons during the ORR. Although the ORR activity of the B/N uncoupling nanocarbon was not as good as the typical Pt/C, the durability of this synthesized material (15.1% current decrease after 20000 s of operation) was significantly better than that of the Pt/C catalyst (61.5% current drop under the same conditions). After the durability test, the increase of the chemical states containing oxygen was higher for Pt/C than B/N uncoupling.

DOI： 10.1039/c6cp06063c

Synthesis of carbon nanoparticles from used motor oil and benzene via solution plasma process

Seangarunthong N., Khongthong P., Panomsuwan G., Ueno T., Saito N., Eiad-Ua A.

Key Engineering Materials 751 KEM 巻頁： 773 - 778 2017年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Key Engineering Materials

Carbon nanoparticles (CNPs) were successfully synthesized from the mixture of used motor oil and benzene via a solution plasma process (SPP). The synthesis was achieved within a single step at room temperature and atmospheric pressure. The effects of mixing ratio between used motor oil and benzene on the physical and chemical properties of CNPs were investigated by means of field-emission scanning electron microscopy (FESEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and Raman spectroscopy. The results revealed that there were no significant changes in morphological feature and chemical functional groups on CNPs at different mixing ratios. The CNPs exhibited the aggregates of fine particles with the diameter of about 20-30 nm. The crystallinity of CNPs was found to be slightly increased when synthesized under the presence of used motor oil, possibly due to the effect of aliphatic hydrocarbons and polycyclic aromatic hydrocarbons in used motor oil. We expect that the conversion of used motor oil into CNPs by SPP could be another attractive way to add the value to used motor oil prior to disposing.

DOI： 10.4028/www.scientific.net/KEM.751.773

In-situ one-step synthesis of carbon-encapsulated naked magnetic metal nanoparticles conducted without additional reductants and agents

Kang J., Kim Y., Kim H., Hu X., Saito N., Choi J., Lee M.

Scientific Reports 6 巻 2016年12月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Scientific Reports

C-encapsulated highly pure Ni, Co, and Fe magnetic nanoparticles (MNPs/C) were synthesized by an innovative one-step in-situ plasma in liquid method (solution plasma processing, SPP) without any additional reductants, agents, or treatment. Successful encapsulation of MNPs was demonstrated by using inductively coupled plasma-atomic emission spectrometry and cyclic voltammetry techniques. The obtained X-ray diffraction patterns and transmission electron microscopy images corresponded to MNPs with average diameters of 5 nm and good crystalline structure. The C capsules with spherical shapes (containing onion-like layers) were characterized by uniform sizes (ranging from 20 nm to 30 nm) and chain-like morphologies. The synthesized MNPs/C exhibited superparamagnetic properties at room temperature and might be utilized in data storage, biomedical, and energy applications since various NPs (including bimetallic ones) could be easily prepared by changing working electrodes. This study shows the potential of SPP to be a candidate for the next-generation synthesis method of NPs/C.

DOI： 10.1038/srep38652

Fastest Formation Routes of Nanocarbons in Solution Plasma Processes

Morishita T., Ueno T., Panomsuwan G., Hieda J., Yoshida A., Bratescu M., Saito N.

Scientific Reports 6 巻 2016年11月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Scientific Reports

Although solution-plasma processing enables room-temperature synthesis of nanocarbons, the underlying mechanisms are not well understood. We investigated the routes of solution-plasma-induced nanocarbon formation from hexane, hexadecane, cyclohexane, and benzene. The synthesis rate from benzene was the highest. However, the nanocarbons from linear molecules were more crystalline than those from ring molecules. Linear molecules decomposed into shorter olefins, whereas ring molecules were reconstructed in the plasma. In the saturated ring molecules, C-H dissociation proceeded, followed by conversion into unsaturated ring molecules. However, unsaturated ring molecules were directly polymerized through cation radicals, such as benzene radical cation, and were converted into two- and three-ring molecules at the plasma-solution interface. The nanocarbons from linear molecules were synthesized in plasma from small molecules such as C2 under heat; the obtained products were the same as those obtained via pyrolysis synthesis. Conversely, the nanocarbons obtained from ring molecules were directly synthesized through an intermediate, such as benzene radical cation, at the interface between plasma and solution, resulting in the same products as those obtained via polymerization. These two different reaction fields provide a reasonable explanation for the fastest synthesis rate observed in the case of benzene.

DOI： 10.1038/srep36880

Effect of electron acceptors H<inf>2</inf>O<inf>2</inf> and O<inf>2</inf> on the generated reactive oxygen species <sup>1</sup>O<inf>2</inf> and OH<sup>·</sup> in TiO<inf>2</inf>-catalyzed photocatalytic oxidation of glycerol

Jedsukontorn T., Meeyoo V., Saito N., Hunsom M.

Cuihua Xuebao/Chinese Journal of Catalysis 37 巻 ( 11 ) 頁： 1975 - 1981 2016年11月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Cuihua Xuebao/Chinese Journal of Catalysis

The effect of the electron acceptors H2O2 and O2 on the type of generated reactive oxygen species (ROS), and glycerol conversion and product distribution in the TiO2-catalyzed photocatalytic oxidation of glycerol was studied at ambient conditions. In the absence of an electron acceptor, only HO· radicals were generated by irradiated UV light and TiO2. However, in the presence of the two electron acceptors, both HO· radical and 1O2 were produced by irradiated UV light and TiO2 in different concentrations that depended on the concentration of the electron acceptor. The use of H2O2 as an electron acceptor enhanced glycerol conversion more than O2. The type of generated value-added compounds depended on the concentration of the generated ROS.

DOI： 10.1016/S1872-2067(16)62519-6

Differences in intermediate structures and electronic states associated with oxygen adsorption onto Pt, Cu, and Au clusters as oxygen reduction catalysts

Morishita T., Ueno T., Panomsuwan G., Hieda J., Bratescu M., Saito N.

Journal of Physics D: Applied Physics 49 巻 ( 41 ) 2016年9月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Physics D: Applied Physics

We used ab initio molecular orbital (MO) calculations to study the differences in the intermediate structures and the electronic states involved in the adsorption of O2 onto 13-atom metal clusters of Pt, Cu, and Au. Additionally, the conditions required for the electrocatalytic oxygen reduction reaction (ORR) on the Pt, Cu, and Au clusters were investigated and discussed. The intermediates involved in O2 adsorption onto Pt, Cu, and Au were found to be (Pt-O)-(Pt-O), Cu-O, and Au-O2, respectively. The differences in the O2 adsorption intermediates is explained on the basis of our analysis of the projected density of state (PDOS) area of the new MOs produced from a mixture of the 2pπ ∗ orbitals of O2 and the d orbitals of the metal clusters. The formation of the (Pt-O)-(Pt-O) intermediate after the adsorption of O2 onto the Pt cluster is attributed to the emergence of an antibonding orbital above the Fermi level. Thus, this electronic state can lead to the decomposition and desorption of O2 molecules, thereby promoting the high-activity level of ORR. For the Cu cluster, a new antibonding orbital was observed below the Fermi level. Moreover, the Cu cluster surface can only promote O2 decomposition and not O2 desorption due to the formation of copper oxides. For the Au cluster, no new MOs related to 2pπ ∗ orbitals of O2 appeared because O2 was molecularly adsorbed, implying that the Au cluster is an inefficient ORR catalyst.

DOI： 10.1088/0022-3727/49/41/415305

Fabrication of bacterial cellulose-ZnO composite via solution plasma process for antibacterial applications

Janpetch N., Saito N., Rujiravanit R.

Carbohydrate Polymers 148 巻頁： 335 - 344 2016年9月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Carbohydrate Polymers

Zinc oxide (ZnO) was successfully synthesized by applying a solution plasma, a plasma discharge in a liquid phase, without the addition of a reducing agent and simultaneously deposited into a bacterial cellulose pellicle that functioned as a template. By the reasons of its nano-sized structure as well as favorable porous configuration, the BC pellicle has been proved to be a splendid upholding template for the coordination of ZnO. In addition, the ZnO-deposited BC composites demonstrated strong antibacterial activity without a photocatalytic reaction against both Staphylococcus aureus and Escherichia coli. Hence, the ZnO-deposited BC composites can be used as an antibacterial material in wound dressing and water disinfection applications.

DOI： 10.1016/j.carbpol.2016.04.066

Heterocarbon nanosheets incorporating iron phthalocyanine for oxygen reduction reaction in both alkaline and acidic media

Hyun K., Ueno T., Panomsuwan G., Li O., Saito N.

Physical Chemistry Chemical Physics 18 巻 ( 16 ) 頁： 10856 - 10863 2016年4月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Physical Chemistry Chemical Physics

Heterocarbon nanosheets incorporating iron phthalocyanine (FP-NCNs-SP) have been successfully synthesized by a facile one-pot solution plasma process at high repetition frequency. It was found that the Fe-N4 catalytic active sites could be preserved on the FP-NCNs-SP without degradation. The FP-NCNs-SP also possessed large surface area, good conductivity and high degree of graphitization. Electrochemical evaluations demonstrated that NCNs-SP had excellent electrocatalytic activity and selectivity toward oxygen reduction reaction (ORR) in alkaline medium through a direct four-electron pathway. Although the significant improvement in ORR activity was clearly observed in acidic medium, it was much poorer than in alkaline medium. We believe that the results presented in this work will shed light on the advanced synthesis and design of ORR electrocatalysts at room temperature with an abundance of catalytically active sites and high ORR performance.

DOI： 10.1039/c5cp07739g

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