Updated on 2022/08/06

写真a

 
YAMAMOTO, Yoshihiko
 
Organization
Graduate School of Pharmaceutical Sciences Department of Basic Medicinal Sciences Organic Chemistry Professor
Cellular and Structural Physiology Institute Professor
Graduate School
Graduate School of Engineering
Graduate School of Pharmaceutical Sciences
Undergraduate School
School of Engineering
School of Engineering Chemistry and Biotechnology
Title
Professor
Contact information
メールアドレス

Degree 1

  1. Doctor of Engineering

Research Interests 1

  1. Synthetic Organic Chemistry, Organometallic Chemistry

Research Areas 2

  1. Others / Others  / Engineering@Industrial Chemistry@Synthetic Chemistry

  2. Others / Others  / 創薬科学

Current Research Project and SDGs 1

  1. Development of Molecular-Transforming Methods Using Transition-Metal Catalysts

Research History 6

  1. Nagoya University   Department of Basic Medicinal Sciences, Graduate School of Pharmaceutical Sciences   Professor

    2012.4

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    Country:Japan

  2. 名古屋大学大学院工学研究科准教授

    2009.4 - 2012.3

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    Country:Japan

  3. 東京工業大学大学院理工学研究科准教授

    2006.4 - 2009.3

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    Country:Japan

  4. 名古屋大学大学院工学研究科助教授

    2003.1 - 2006.3

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    Country:Japan

  5. 名古屋大学大学院工学研究科助手

    1996.4 - 2002.12

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    Country:Japan

  6. 日本学術振興会特別研究員

    1995.4 - 1996.3

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    Country:Japan

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Education 2

  1. Nagoya University   Graduate School, Division of Engineering

    - 1996

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    Country: Japan

  2. Nagoya University   Faculty of Engineering

    - 1991

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    Country: Japan

Professional Memberships 4

  1. 日本化学会

  2. The Pharmaceutical Society of Japan

  3. 有機合成化学協会

  4. 近畿化学協会

Awards 4

  1. Incentive Award in Synthetic Organic Chemistry, Japan, 2003

    2003   Synthetic Organic Chemistry, Japan  

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    Country:Japan

  2. Japan Combinatorial Chemistry Focus Group Award in Synthetic Organic Chemistry, Japan

    2004  

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    Country:Japan

  3. 第19回若い世代の特別講演

    2005.3   日本化学会   ルテニウム触媒環化三量化を基盤とする多成分カップリング

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  4. Tokyo Tech Award for Challenging Research

    2006.12   Tokyo Institute of Technology  

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    Country:Japan

 

Papers 145

  1. Combined Computational and Experimental Study on [5 + 2] Cycloaddition of 2-Trifluoromethylated Oxidopyrylium Species Leading to 1-(Trifluoromethyl)-8-oxabicyclo[3.2.1]oct-3-en-2-ones Reviewed

    Yoshihiko Yamamoto, Yuya Nakazato, Ryu Tadano, Takeshi Yasui

    The Journal of Organic Chemistry   Vol. 87 ( 15 ) page: 10216 - 10228   2022.8

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.2c01189

  2. Co-Catalyzed atom transfer radical addition of bromodifluoroacetamides, expanding the scope of radical difluoroalkylation Reviewed

    Yoshihiko Yamamoto, Harufumi Suzuki, Eisuke Kuroyanagi, Keiji Yamada and Takeshi Yasui

    Organic & Biomolecular Chemistry   Vol. 20 ( 14 ) page: 2867 - 2872   2022.4

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D2OB00437B

  3. Computational Study of the Rh/phanephos-Catalyzed Enantioselective [2+2+2] Cyclization of Enediyne, Affording Lactone-Fused Cyclohexadiene Bearing a Quaternary Bridgehead Carbon Reviewed

    Yoshihiko Yamamoto

    Bulletin of the Chemical Society of Japan   Vol. 95 ( 2 ) page: 221 - 229   2022.2

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/bcsj.20210402

  4. Computational Mechanistic Study of Fused Phenol Formations from 1,6-Heptadiyne Involving Carbyne Complexes Reviewed

    Yoshihiko Yamamoto

    ChemCatChem   Vol. 13 ( 23 ) page: 4912 - 4924   2021.12

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    Authorship:Lead author, Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cctc.202101218

  5. Catalyst-Free Csp−Csp3 Cross-Coupling of Bromodifluoroacetamides with 1-Iodoalkynes under Visible-Light Irradiation Invited Reviewed

    Yoshihiko Yamamoto, Eisuke Kuroyanagi, Harufumi Suzuki, Takeshi Yasui

    Advanced Synthesis & Catalysis   Vol. 363 ( 21 ) page: 4932 - 4940   2021.11

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.202100846

  6. Cobalt/Organophotoredox Dual-Catalysis-Enabled Cascade Cyclization of 1,6-Diynyl Esters via Formal 1,8-Acyloxy Migration Reviewed

    Takeshi Yasui, Keiji Yamada, Rine Tatsumi, and Yoshihiko Yamamoto

    ACS Catalysis   Vol. 11 ( 18 ) page: 11716 - 11722   2021.9

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.1c03704

  7. Enantioselective Construction of 5-6-5 Tricyclic Lactone Framework Bearing a Quaternary Bridgehead Carbon via Rh-Catalyzed Asymmetric [2+2+2] Cycloaddition of Enediynes Reviewed

    Takeshi Yasui, Yuya Nakazato, Koutarou Kurisaki, Yoshihiko Yamamoto

    Advanced Synthesis & Catalysis   Vol. 363 ( 17 ) page: 4182 - 4189   2021.9

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.202100513

  8. Highly Enantioselective [2+2+2] Cycloaddition of Enediynes Enabled by Cobalt/Organophotoredox Cooperative Catalysis Reviewed

    Takeshi Yasui, Rine Tatsumi, and Yoshihiko Yamamoto

    ACS Catalysis   Vol. 11 ( 15 ) page: 9479 - 9484   2021.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.1c02410

  9. Synthesis of Benzo-Fused Cyclic Ketones via Metal-Free Ring Expansion of Cyclopropanols Enabled by Proton-Coupled Electron Transfer Reviewed

    Tomohiro Kikuchi, Keiji Yamada, Takeshi Yasui, Yoshihiko Yamamoto

    Organic Letters   Vol. 23 ( 12 ) page: 4710 - 4714   2021.6

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.1c01436

  10. Synthesis of difluoromethylated diarylmethanes via Fe(OTf)3-catalyzed Friedel–Crafts reaction of 2,2-difluoro-1-arylethyl phosphates Reviewed

    Yoshihiko Yamamoto, Tomoya Takase, Eisuke Kuroyanagi, Takeshi Yasui

    Chemical Communications   Vol. 57 ( 32 ) page: 3877 - 3880   2021.4

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D1CC00765C

  11. A Combined Experimental and Computational Study on the Palladium-Catalyzed Sequential [2+2+1] Spirocyclization/Arene C–H Activation of 4-Iodo-2-quinolones with Diphenylacetylene Reviewed

    Yoshihiko Yamamoto, Naohiro Hirako, Takeshi Yasui

    Bulletin of the Chemical Society of Japan   Vol. 94 ( 2 ) page: 623 - 631   2021.2

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/bcsj.20200328

  12. Synthesis of 1-(Difluoromethyl)alk-1-enes via Palladium-Catalyzed SN2'-Type Substitution Reaction of Difluoromethylated Allylic Phosphates with 1,3-Dicarbonyl Compounds and Imides Reviewed

    Yoshihiko Yamamoto, Motoji Sakai, Yuki Ishida, and Takeshi Yasui

    The Journal of Organic Chemistry   Vol. 86 ( 1 ) page: 1053-1064   2021.1

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.0c02538

  13. Theoretical Study of the Mechanism of Palladium(0)-Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester-Substituted Alkynes Reviewed

    Yoshihiko Yamamoto

    European Journal of Organic Chemistry   Vol. 2020 ( 48 ) page: 7455-7465   2020.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/ejoc.202001349

  14. Rhodium-catalyzed cycloisomerization of ester-tethered 1,6-diynes with cyclopropanol moiety leading to tetralone/exocyclic diene hybrid molecules Reviewed

    Takeshi Yasui, Tomohiro Kikuchia, Yoshihiko Yamamoto

    Chemical Communications   Vol. 56 ( 84 ) page: 12865-12868   2020.10

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D0CC05429A

  15. Palladium-Catalyzed [3+2] and [2+2+2] Annulations of 4-Iodo-2-quinolones with Activated Alkynes through Selective C-H Activation Reviewed

    Yoshihiko Yamamoto, Jiyue Jiang, Takeshi Yasui

    Chemistry A European Journal   Vol. 26 ( 17 ) page: 3749-3757   2020.3

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201904558

  16. Recent Advances in Transition-Metal-Catalyzed Synthesis of 3- and/or 4-Aryl-2(1H)-Quinolones Invited Reviewed

    Yoshihiko Yamamoto

    Heterocycles   Vol. 98 ( 10 ) page: 1309-1344   2019.11

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3987/REV-19-914

  17. Diastereoselective Methylation at the Congested β-Position of a Butenolide Ring: Studies toward the Synthesis of seco-Prezizaane-Type Sesquiterpenes Reviewed

    Tomoyoshi Kawamura, Hirokazu Moriya, Masatoshi Shibuya, Yoshihiko Yamamoto

    The Journal of Organic Chemistry   Vol. 84 ( 19 ) page: 12508-12519   2019.10

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.9b02017

  18. Synthesis of (Difluoromethyl)cycloalkenes from 2-Cycloalkenones by Utilizing Phospha-Brook Rearrangement Reviewed

    Yoshihiko Yamamoto, Yuki Ishida, Yosuke Takamizu, Takeshi Yasui

    Advanced Synthesis & Catalysis   Vol. 361 ( 16 ) page: 3739-3743   2019.8

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    DOI: 10.1002/adsc.201900469

  19. Synthesis of γ-Difluoromethylated Tetronate Derivatives from Squarates Using Difluoromethylphosphonate Reviewed

    Yoshihiko Yamamoto, Yuki Ishida, Takashi Kurohara, Masatoshi Shibuya, and Takeshi Yasui

    Heterocycles   Vol. 99 ( 1 ) page: 363-378   2019.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3987/COM-18-S(F)29

  20. Theoretical Study on the Transition-Metal-Catalyzed Cycloadditions of 2H-Azirines with Alkynes: Implication of Carbenoid Intermediates Reviewed

    Yoshihiko Yamamoto

    Bulletin of the Chemical Society of Japan   Vol. 92 ( 3 ) page: 619-628   2019.3

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    DOI: 10.1246/bcsj.20180344

  21. Theoretical Study of the Copper-Catalyzed Hydroarylation of (Trifluoromethyl)alkyne with Phenylboronic Acid Reviewed

    Yoshihiko Yamamoto

    The Journal of Organic Chemistry   Vol. 83 ( 20 ) page: 12775-12783   2018.10

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.8b02215

  22. Discussion Addendum for: Stereoselective Synthesis of 3-Arylacrylates by Copper- Catalyzed Syn Hydroarylation [(E)-Methyl 3-phenyloct-2- enoate] Invited

    Yoshihiko Yamamoto

    Organic Synthesis   Vol. 95   page: 267-275   2018.9

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    DOI: 10.15227/orgsyn.095.0267

  23. Synthesis of pyroles via ruthenium-catalyzed nitrogen-transfer [2+2+1] cycloaddition of α,ω-diynes using sulfoximines as nitrene surrogates Reviewed

    Kazuma Matsui, Masatoshi Shibuya, Yoshihiko Yamamoto

    Communications Chemistry   Vol. 1   2018.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s42004-018-0022-2

  24. Synthesis of Alkoxycarbonyldifluoromethyl-Substituted Semisquarates and Their Transformations Reviewed

    Takashi Kurohara, Jiang Jiyue, Masatoshi Shibuya, Yoshihiko Yamamoto

    Synthesis   Vol. 50 ( 8 ) page: 1687-1698   2018.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1055/s-0036-1591887

  25. Combined Experimental and Computational Study on Catalytic Cyclocoupling of Epoxides and CO2 Using Porphyrin-Based Cu(II) Metal-Organic Frameworks with 2D Coordination Networks Reviewed

    Tsukasa Murayama, Masayuki Asano, Tetsushi Ohmura, Arimitsu Usuki, Takeshi Yasui, and Yoshihiko Yamamoto

    Bulletin of the Chemical Society of Japan   Vol. 91 ( 3 ) page: 383-390   2018.3

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    DOI: 10.1246/bcsj.20170371

  26. The vinylogous Catellani reaction: a combined computational and experimental study Reviewed

    Yoshihiko Yamamoto, Tsukasa Murayama, Jiang Jiyue, Takeshi Yasui, Masatoshi Shibuya

    Chemcal Science   Vol. 9 ( 5 ) page: 1191-1199   2018.2

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    DOI: 10.1039/C7SC04265E

  27. Transfer hydrogenation of nitrogen heterocycles using a recyclable rhodium catalyst immobilized on bipyridine-periodic mesoporous organosilica Reviewed

    Kazuma Matsui, Yoshifumi Maegawa, Minoru Waki, Shinji Inagaki, Yoshihiko Yamamoto

    Catalysis Science & Technology   Vol. 8 ( 2 ) page: 534-539   2018.1

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    DOI: 10.1039/C7CY02167D

  28. Recent topics of Cp*RuCl-catalyzed annulation reactions Reviewed

    Yoshihiko Yamamoto

    Tetrahedron Letters   Vol. 58 ( 40 ) page: 3787-3794   2017.10

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    DOI: doi.org/10.1016/j.tetlet.2017.08.040

  29. Combined Experimental and Computational Study on Ruthenium(II)-Catalyzed Reactions of Diynes with Aldehydes and N,N-Dimethylformamide Reviewed

    Yoshihiko Yamamoto, Yuta Okude, Shota Mori, and Masatoshi Shibuya

    The Journal of Organic Chemistry   Vol. 82 ( 15 ) page: 7964-7973   2017.8

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    DOI: 10.1021/acs.joc.7b01229

  30. Synthesis of Fused Furans and Thiophenes via Ruthenium-Catalyzed Atom-Transfer [2+2+1] Cycloadditions of α,ω-Diynes Invited Reviewed

    Yoshihiko Yamamoto

    Synlett   Vol. 28 ( 11 ) page: 1250-1257   2017.7

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    DOI: 10.1055/s-0036-1588767

  31. Synthesis of 3-Aryl-2-(trifluoromethyl)indoles via Copper-Catalyzed Hydroarylation and Subsequent Cadogan Cyclization Reviewed

    Yoshishiko Yamamoto, Erina Ohkubo, Masatoshi Shibuya

    Advanced Synthesis & Catalysis   Vol. 359 ( 10 ) page: 1747-1751   2017.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201700122

  32. Assembly of a Benzo-Fused Bridged Ketone Scaffold from 1,5,10-Enediynes through One-Pot Ruthenium-Catalyzed Cyclization/Iodine-Mediated Oxidative Ring Expansion Reviewed

    Yoshihiko Yamamoto, Kei-ichiro Nishimura, Shota Mori, Masatoshi Shibuya

    Angewandte Chemie International Edition   Vol. 56 ( 20 ) page: 5494-5497   2017.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201700493

  33. Electrophilic Derivatization of Trifluoromethyl-Substituted Semisquarate Using Unsaturated Organosilanes and Subsequent Ring Transformations Authors Reviewed

    Takashi Kurohara, Masatoshi Shibuya and Yoshihiko Yamamoto

    Advanced Synthesis & Catalysis   Vol. 359 ( 8 ) page: 1413-1419   2017.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/adsc.201601297

  34. Synthesis of γ-Trifluoromethyl Tetronate Derivatives from Squarates Reviewed

    Yoshihiko Yamamoto, Yosuke Takamizu, Takashi Kurohara, and Masatoshi Shibuya

    Heterocycles   Vol. 95 ( 1 ) page: 525-539   2017.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3987/COM-16-S(S)12

  35. Theoretical Study on Ruthenium-Catalyzed Hydrocarbamoylative Cyclization of 1,6-Diyne with Dimethylformamide Reviewed

    Yoshihiko Yamamoto

    Organometallics   Vol. 36 ( 6 ) page: 1154-1163   2017.3

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.organomet.7b00026

  36. Ruthenium-catalyzed Hydrocarbamoylative Cyclization of 1,6-Diynes with Formamides Reviewed

    Shota Mori, Masatoshi Shibuya, Yoshihiko Yamamoto

    Chemistry Letters   Vol. 46 ( 2 ) page: 207-210   2017.2

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.160961

  37. Ruthenium-Catalyzed Cycloisomerization of 1,6-Diynes with Styryl Terminals Leading to Indenylidene Cycloalkanes Reviewed

    Yoshihiko Yamamoto, Kei-ichiro Nishimura, and Masatoshi Shibuya

    ACS Catalysis   Vol. 7 ( 2 ) page: 1101-1107   2017.2

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.6b03322

  38. Catalytic [2+2+1] Synthesis of Fused Thiophenes Using Thiocarbonyls as Sulfur Donors Authors Reviewed

    Kazuma Matsui, Masatoshi Shibuya, Yoshihiko Yamamoto

    Angewandte Chemie International Edition   Vol. 55 ( 49 ) page: 15397-15400   2016.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201609545

  39. Divergent Synthesis of Polymethoxylated 4-Aryl-2-quinolones Reviewed

    Tsukasa Murayama, Masatoshi Shibuya, and Yoshihiko Yamamoto

    The Journal of Organic Chemistry   Vol. 81 ( 23 ) page: 11940-11949   2016.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.6b02626

  40. Selective synthesis of trisubstituted (trifluoromethyl)alkenes via ligand-free Cu-catalyzed syn hydroarylation, hydroalkenylation and hydroallylation of (trifluoromethyl)alkynes Reviewed

    Yoshihiko Yamamoto, Erina Ohkubo and Masatoshi Shibuya

    Green Chemistry   Vol. 18 ( 17 ) page: 4628-4632   2016.9

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C6GC01782G

  41. Synthesis of 4-Aryl-2-Quinolones via Copper-Catalyzed Hydroarylation of (o-Aminophenyl)propiolates with Arylboronates Reviewed

    Tsukasa Murayama, Masatoshi Shibuya, and Yoshihiko Yamamoto

    Advanced Synthesis & Catalysis   Vol. 358 ( 2 ) page: 166-171   2016.1

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    DOI: DOI: 10.1002/adsc.201500837

  42. CF3-Substituted semisquarate: a pluripotent building block for the divergent synthesis of trifluoromethylated functional molecules Reviewed

    Yoshihiko yamamoto, Takashi Kurohara, Masatoshi Shibuya

    Chemical Communications   Vol. 51 ( 91 ) page: 16357-16360   2015.11

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1039/C5CC06920C

  43. Ruthenium-Catalyzed Transfer Oxygenative [2 + 2 + 1] Cycloaddition of Silyldiynes Using Nitrones as Adjustable Oxygen Atom Donors. Synthesis of Bicyclic 2-Silylfurans Reviewed

    Kazuma Matsui, Masatoshi Shibuya, Yoshihiko Yamamoto

    ACS Catalysis   Vol. 5 ( 11 ) page: 6468-6472   2015.11

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1021/acscatal.5b01855

  44. A Combined Transition-Metal-Catalyzed and Photopromoted Process: Synthesis of 2,3-Fused 4-Phenylnaphthalen-1-yl Carboxylates from 1,7-Diaryl-1,6-diynes Reviewed

    Yoshihiko Yamamoto, Shota Mori, Masatoshi Shibuya

    Chemistry - A European Journal   Vol. 21 ( 25 ) page: 9093-9100   2015.6

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1002/chem.201500978

  45. A lactone-fused cyclohexadiene as a versatile platform for diversified synthesis of 5,6,5-tricyclic scaffolds Reviewed

    M. Shibuya, T. Sudoh, T. Kawamura and Y. Yamamoto

    Organic & Biomolecular Chemistry   Vol. 13 ( 21 ) page: 5862-5866   2015.6

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1039/C5OB00729A

  46. A Combined Experimental and Computational Study on the Cycloisomerization of 2-Ethynylbiaryls Catalyzed by Dicationic Arene Ruthenium Complexes Reviewed

    Yoshihiko Yamamoto, Kazuma Matsui, Masatoshi Shibuya

    Chemistry - A European Journal   Vol. 21 ( 19 ) page: 7245-7255   2015.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1002/chem.201500248

  47. Synthesis of 3,4-Fused 2-Quinolones from an (o-Aminophenyl) propiolate via Sequential Cycloaddition/Lactam Formation Reviewed

    Tsukasa Murayama, Masatoshi Shibuya, and Yoshihiko Yamamoto

    Advanced Synthesis & Catalysis   Vol. 357 ( 4 ) page: 690-694   2015.3

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  48. Synthesis of β-Allylbutenolides via One-Pot Copper-Catalyzed Hydroallylation/Cyclization of γ-Hydroxybutynoate Derivatives Reviewed

    Yoshihiko Yamamoto, Shinya Shibano, Takashi Kurohara, and Masatoshi Shibuya

    The Journal of Organic Chemistry   Vol. 79 ( 10 ) page: 4503-4511   2014.5

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: DOI: 10.1021/jo500536b

  49. Tandem Ruthenium-Catalyzed Transfer-Hydrognative Cyclization/Intramolecular Diels-Alder Reaction of Enediynes Affording Dihydrocoumarin-Fused Polycycles Reviewed

    Yoshihiko Yamamoto, Kazuma Matsui, and Masatoshi Shibuya

    Organic Letters   Vol. 16 ( 6 ) page: 1806-1809   2014.3

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ol500548x

  50. Synthesis of Heterocycles via Transition-metal-catalyzed Hydroarylations of Alkynes Reviewed

    Yoshihiko Yamamoto

    Chemical Society Reviews   Vol. 43 ( 5 ) page: 1575-1600   2014.3

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  51. Syntheses of Heterocycles via Alkyne Cycloadditions Catalyzed by Cyclopentadienylruthenium-Type Complexes Invited Reviewed

    Yoshihiko Yamaoto

    Heterocycles   Vol. 87 ( 12 ) page: 2459-2493   2013.12

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  52. Theoretical Study on Ruthenium-Catalyzed Hydrocarboxylative Dimerization of Phenylacetylene with Acetic Acid Leading to (1E,3E)-1,4-Diphenyl-1,3-butadienyl Acetate Reviewed

    Yoshihiko Yamamoto

    Organometallics   Vol. 32 ( 18 ) page: 5201-5211   2013.9

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/om4007517

  53. Ruthenium-Catalyzed Transfer-Hydrogenative Cyclization of 1,6-Diynes with Hantzsch 1,4-Dihydropyridine as a H2 Surrogate Reviewed

    Yoshihiko Yamamoto, Shota Mori, Masatoshi Shibuya

    Chemistry - A European Journal   Vol. 19 ( 36 ) page: 12034-12041   2013.9

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  54. Copper-Catalyzed Conjugate Addition of Organoboronic Acids and Esters to Electron-Deficient Alkynes Reviewed

    Yoshihiko Yamamoto

      Vol. 71 ( 4 ) page: 296-306   2013.4

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  55. Ruthenium-catalyzed hydrophosphinylative cyclization of 1,6-diynes. Stereoselective synthesis of exocyclic 1,3-dienylphosphine oxides Reviewed

    Yoshihiko Yamamoto, Kosuke Fukatsu, Hisao Nishiyama

    Chemical Communications   Vol. 48 ( 64 ) page: 7985-7987   2012.8

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  56. Transition-Metal-Catalyzed Cycloisomerizations of α,ω-Dienes Reviewed

    Yoshihiko Yamamoto

    Chemical Reviews   Vol. 112 ( 8 ) page: 4736-4769   2012.8

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  57. Ruthenium-Catalyzed Transfer Oxygenative Cyclization of α,ω-Diynes: Unprecedented [2 + 2 + 1] Route to Bicyclic Furans via Ruthenacyclopentatriene Reviewed

    Ken Yamashita, Yoshihiko Yamamoto, Nisao Nishiyama

    Journal of the American Chemical Society   Vol. 134 ( 18 ) page: 7660-7663   2012.5

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  58. Copper-Catalyzed Regio- and Stereoselective Conjugate Allylation of Electron-Deficient Alkynes with Allylboronates under Mild Conditions Reviewed

    Yoshihiko Yamamoto, Satoshi Yamada, Hisao Nishiyama

    Chemistry - A European Journal   Vol. 18 ( 11 ) page: 3153-3156   2012.3

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    DOI: 10.1002/chem.201103697

  59. Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activation via metallacyclopentatriene Reviewed

    Ken Yamashita, Yuki, Nagashima, Yoshihiko Yamamoto, Hisao Nishiyama

    Chemical Communications   Vol. 47 ( 41 ) page: 11552-11554   2011.11

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  60. Synthesis of 3-Arylindole-2-carboxylates via Copper-Catalyzed Hydroarylation of o-Nitrophenyl-Substituted Alkynoates and Subsequent Cadogan Cyclization Reviewed

    Yoshihiko Yamamoto, Satoshi Yamada, and Hisao Nishiyama

    Advanced Synthesis & Catalysis   Vol. 353 ( 5 ) page: 701–706   2011.3

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    DOI: 10.1002/adsc.201000858

  61. Activation of water molecule under mild conditions by ruthenacyclopentatriene: Mechanism of hydrative cyclization of diynes Reviewed

    Yoshihiko Yamamoto, Ken Yamashita, Hisao Nishiyama

    Chemical Communications   Vol. 47 ( 5 ) page: 1556–1558   2011.2

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  62. Systematic Evaluation of Substituted Cyclopentadienyl Ruthenium Complexes, [(η5-C5MenH5-n)RuCl(cod)], for Catalytic Cycloadditions of Diynes Reviewed

    Yoshihiko Yamamoto, Ken Yamashita, Yu Harada

    Chemistry - An Asian Journal   Vol. 5 ( 4 ) page: 946-952   2010.4

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  63. Synthesis of Organometallic Analogues of Spirocyclic C-Arylribosides Reviewed

    Yoshihiko Yamamoto, Ken Yamashita, Mitsutaka Nakamura

    Organometallics   Vol. 29 ( 6 ) page: 1472-1478   2010.3

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  64. The First General and Selective Palladium(II)-Catalyzed Alkoxycarbonylation of Arylboronates: Interplay among Benzoquinone-Ligated Palladium(0) Complex, Organoboron, and Alcohol Solvent Reviewed

    Yoshihiko Yamamoto

    Advanced Synthesis & Catalysis   Vol. 352 ( 2-3 ) page: 478-492   2010.2

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  65. SYNTHESIS OF 4-ARYL-SUBSTITUTED BUTENOLIDES AND PENTENOLIDES BY COPPER-CATALYZED HYDROARYLATION Reviewed

    Yoshihiko Yamamoto, Naohiro Kirai

    Heterocycles   Vol. 80 ( 1 ) page: 269-279   2010.1

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  66. STEREOSELECTIVE SYNTHESIS OF 3-ARYLACRYLATES BY COPPER-CATALYZED SYN HYDROARYLATION Reviewed

    Naohiro Kirai, Yoshihiko Yamamoto

    Organic Synthesis   Vol. 87   page: 53-58   2010

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  67. Synthesis of 2,5-Dihydrofuran-fused Quinones from Ether-Tethered Diiododiyne Reviewed

    Yoshihiko Yamamoto, Ryosuke Takuma, Tomitaka Hotta, and Ken Yamashita

    The Journal of Organic Chemistry   Vol. 74 ( 11 ) page: 4324-4328   2009.6

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  68. Copper-Catalyzed Stereoselective Hydroarylation of 3-Aryl-2-propynenitriles with Arylboronic Acids Reviewed

    Yoshihiko Yamamoto, Tsuyoshi Asatani, Naohiro Kirai

    Advanced Synthesis & Catalysis   Vol. 351 ( 9 ) page: 1243-1249   2009.6

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  69. Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air Reviewed

    Naohiro Kirai and Yoshihiko Yamamoto

    European Journal of Organic Chemistry   ( 12 ) page: 1864-1867   2009.4

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  70. Synthesis of Chromans via [3 + 3] Cyclocoupling of Phenols with Allylic Alcohols Using a Mo/o-Chloranil Catalyst System Reviewed

    Yoshihiko Yamamoto and Kouhei Itonaga

    Organic Letters   Vol. 11 ( 3 ) page: 717-720   2009.2

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  71. Synthesis of 4-Arylcoumarins via Cu-catalyzed Hydroarylation with Arylboronic Acids Reviewed

    Yoshihiko Yamamoto and Naohiro Kirai

    Organic Letters   Vol. 10 ( 24 ) page: 5513-5516   2008.12

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  72. Versatile Friedel-Crafts-Type Alkylation of Benzene Derivatives Using a Molybdenum Complex/ortho-Chloranil Catalytic System Reviewed

    Yoshihiko Yamamoto and Kouhei Itonaga

    Chemistry - A European Journal   Vol. 14 ( 34 ) page: 10705-10715   2008.11

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  73. Silver-Catalyzed Csp-H and Csp-Si Bond Transformations and Related Processes Invited Reviewed

    Yoshihiko Yamamoto

    Chemical Reviews   Vol. 108 ( 8 ) page: 3199-3222   2008.8

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  74. ルテニウム触媒環化三量化反応を用いるC-アリールグリコシドの合成 Reviewed

    山本芳彦

    有機合成化学協会誌   Vol. 66 ( 8 ) page: 795-805   2008.8

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  75. Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates Reviewed

    Yoshihiko Yamamoto, Naohiro Kirai, and Yu Harada

    Chemical Communications   ( 17 ) page: 2010-2012   2008.5

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  76. Synthesis of multiply functionalized benzenes via ruthenium-catalyzed cycloaddition of diiododiynes Reviewed

    Yoshihiko Yamamoto and Kozo Hattori

    Tetrahedron   Vol. 64 ( 5 ) page: 847-855   2008.1

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  77. Synthesis of Spirocyclic C-Arylglycosides and -Ribosides by Ruthenium-Catalyzed Cycloaddition Reviewed

    Yoshihiko Yamamoto, Ken Yamashita, Tomitaka Hotta, Toru Hashimoto, Makoto Kikuchi, Hisao Nishiyama

    Chemistry - An Asian Journal   Vol. 2 ( 11 ) page: 1388-1399   2007.11

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  78. Multi-component coupling synthesis of polycyclic pyrrole derivatives via Ir- and Rh-catalyzed cycloisomerizations with microwave heating Reviewed

    Yoshihiko Yamamoto, and Hiroki Hayashi

    Tetrahedron   Vol. 63 ( 41 ) page: 10149-10160   2007.10

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  79. Recent advances in Pyridine synthesis via catalytic intramolecular cyclocotrimerizations of alkynes and nitriles Invited Reviewed

    Yoshihiko Yamamoto

    Chimica Oggi - Chemistry Today   Vol. 25 ( 5 ) page: 108-110   2007.9

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  80. Homocoupling of Arylboronic Acids with a Catalyst System Consisting of a Palladium(II) N-Heterocyclic Carbene Complex and p-Benzoquinone Reviewed

    Yoshihiko Yamamoto

    Synlett   ( 12 ) page: 1913-1916   2007.7

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  81. Convergent Synthesis of Azabicycloalkenones Using Squaric Acid as Platform Reviewed

    Yoshihiko Yamamoto, Shoji Kuwabara, Hiroyuki Hayashi, and Hisao Nishiyama

    Advanced Synthesis & Catalysis   Vol. 348 ( 16-17 ) page: 2493-2500   2006.11

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  82. Synthesis of Spirocyclic C-Arylribosides via Cyclotrimerization Reviewed

    Yoshihiko Yamamoto, Toru Hashimoto, Kozo Hattori, Makoto Kikuchi, and Hisao Nishiyama

    Organic Letters   Vol. 8 ( 16 ) page: 3565-3568   2006.8

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  83. Ruthenium-Catalyzed Cycloaddition of 1,6-Diynes and Nitriles under Mild Conditions: Role of the Coordinating Group of Nitriles Reviewed

    Yoshihiko Yamamoto, Keisuke Kinpara, Ryuji Ogawa, Hisao Nishiyama, and Kenji Itoh

    Chemistry - A European Journal   Vol. 12 ( 21 ) page: 5618-5631   2006.7

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  84. Synthesis of Bicyclic p-Diiodobenzenes via Silver-Catalyzed Csp-H Iodination and Ruthenium-Catalyzed Cycloaddition Reviewed

    Yoshihiko Yamamoto, Kozo Hattori, and Hisao Nishiyama

    Journal of the American Chemical Society   Vol. 128 ( 25 ) page: 8336-8340   2006.6

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  85. Base- and Phosphine-free Palladium-Catalyzed Homocoupling of Arylboronic Acid Derivatives under Air Reviewed

    Yoshihiko Yamamoto, Ryo Suzuki, Kozo Hattori, and Hisao Nishiyama

    Synlett   ( 7 ) page: 1027-1030   2006.5

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  86. Synthesis of arylboronates via Cp*RuCl-catalyzed cycloaddition of alkynylboronates Reviewed

    Yoshihiko Yamamoto, Kozo Hattori, Jun-ichi Ishii and Hisao Nishiyama

    Tetrahedron   Vol. 62 ( 18 ) page: 4294-4305   2006.5

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  87. Synthesis of 2-Haloalkylpyridines via Cp*RuCl-Catalyzed Cycloaddition of 1,6-Diynes with α-Halonitriles. Unusual Halide Effect in Catalytic Cyclotrimerization Reviewed

    Yoshihiko Yamamoto, Keisuke Kinpara, Hisao Nishiyama, and Kenji Itoh

    Advanced Synthesis & Catalysis   Vol. 347 ( 15 ) page: 1913-1916   2005.12

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  88. One-Pot Sequential Four-Component Coupling via Cp*RuCl-Catalyzed Cyclotrimerization and Suzuki-Miyaura Coupling Reviewed

    Yoshihiko Yamamoto, Jun-ichi Ishii, and Hisao Nishiyama

    Tetrahedron   Vol. 61 ( 48 ) page: 11501-11510   2005.11

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  89. Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of α,ω-diynes with ethynylboronate Reviewed

    Yoshihiko Yamamoto, Kozo Hattori, Jun-ichi Ishii, Hisao Nishiyama, and Kenji Itoh

    Chemical Communications   ( 35 ) page: 4438-4440   2005.9

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  90. Domino Coupling Relay Approach to Polycyclic Pyrrole-2-carboxylates Reviewed

    Yoshihiko Yamamoto, Hiroki Hayashi, Tomoaki Saigoku, and Hisao Nishiyama

    Journal of the American Chemical Society   Vol. 127 ( 31 ) page: 10804-10805   2005.8

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  91. Cp*RuCl-Catalyzed Formal Intermolecular Cyclotrimerization of Three Unsymmetrical Alkynes through Boron Temporary Tether. Regioselective Four-Component Coupling Synthesis of Phthalides Reviewed

    Yoshihiko Yamamoto,* Jun-ichi Ishii, Hisao Nishiyama and Kenji Itoh

    Journal of the American Chemical Society   Vol. 127 ( 26 ) page: 9625-9631   2005.7

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  92. Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides Reviewed

    Yoshihiko Yamamoto, Tomoaki Saigoku, Hisao Nishiyama, Takashige Ohgai, and Kenji Itoh

    Organic and Biomolecular Chemistry   Vol. 3 ( 9 ) page: 1768-1775   2005.5

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  93. Synthesis of Ferrocenylbenzenes via Cp*RuCl-Catalyzed Partially Intramolecular Cyclotrimerization of Ferrocenylalkynes Reviewed

    Yoshihiko Yamamoto, Hisashi Kataoka, Keisuke Kinpara, Hisao Nishiyama, Kenji Itoh

    Letteres in Organic Chemistry   Vol. 2 ( 3 ) page: 219-221   2005.5

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  94. Recent Advances in Intramolecular Alkyne Cyclotrimerization and Its Applications Reviewed

    Yoshihiko Yamamoto

    Current Organic Chemistry   Vol. 9 ( 6 ) page: 503-519   2005.4

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  95. Ruthenium(II)-Catalyzed Alkyne Cyclotrimerizations Invited Reviewed

    Yoshihiko Yamamoto

    Journal of Synthetic Organic Chemistry Japan   Vol. 63 ( 2 ) page: 112-121   2005.2

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  96. Cp*RuCl-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Electron-Deficient Carbon-Heteroatom Multiple Bonds Leading to Heterocycles Reviewed

    Yoshihiko Yamamoto, Keisuke Kinpara, Tomoaki Saigoku, Hideyuki Takagishi, Satoshi Okuda, HisaoNishiyama, and Kenji Itoh

    Journal of the American Chemical Society   Vol. 127 ( 2 ) page: 605-613   2005.1

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  97. Synthesis of C-arylglycosides via Ru(II)-catalyzed [2 + 2 + 2] cycloaddition Reviewed

    Yoshihiko Yamamoto, Tomoaki Saigoku, Takashige Ohgai, Hisao Nishiyama, and Kenji Itoh

    Chemical Communications   ( 23 ) page: 2702-2703   2004.12

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  98. Palladium(0)-Catalyzed Cyclization of Electron-Deficient Enynes and Enediynes Reviewed

    Yoshihiko Yamamoto, Shoji Kuwabara, Yoji Ando, Hitomi Nagata, Hisao Nishiyama, and Kenji Itoh

    The Journal of Organic Chemistry   Vol. 69 ( 20 ) page: 6697-6705   2004.10

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  99. Synthesis of a Dinuclear Ruthenabicyclic Complex and Its Ligand-Substitution Reactions Reviewed

    Yoshihiko Yamamoto, Yumiko Miyabe, and Kenji Itoh

    European Journal of Inorganic Chemistry   ( 18 ) page: 3651-3661   2004.9

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  100. Synthesis and Decomposition Behavior of a C2-Symmetrical Palladoum(IV) Spirocyclic Complex Reviewed

    Yoshihiko Yamamoto, Shoji Kuwabara, Shigeo Matsuo, Takuya Ohno, Hisao Nishiyama, and Kenji Itoh, , Organometallics 2004, 23 (16), 3898-3906.

    Organometallics   Vol. 23 ( 16 ) page: 3898-3906   2004.8

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  101. Synthesis of Naphthoquinone-Fused Cyclobutadiene Ruthenium Complexes Reviewed

    Yoshihiko Yamamoto, Takayasu Arakawa, and Kenji Itoh

    Organometallics   Vol. 23 ( 15 ) page: 3610-3614   2004.7

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  102. Synthesis of benzo-fused lactams and lactones via Ru(II)-catalyzed cycloaddition of amide- and ester-tethered α,ω-diynes with terminal alkynes: electronic directing effect of internal conjugated carbonyl group Reviewed

    Yoshihiko Yamamoto, Keisuke Kinpara, Tomoaki Saigoku, Hisao Nishiyama, and Itoh Kenji

    Organic & Biomolecular Chemistry   Vol. 2 ( 9 ) page: 1287-1294   2004.5

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  103. Ru(II)-Catalyzed Chemo- and Regioselective Cyclotrimerization of Three Unsymmetrical Alkynes through Boron Temporary Tether. One-Pot Four-Component Coupling via Cyclotrimerization/Suzuki-Miyaura Coupling Reviewed

    Yoshihiko Yamamoto, Jun-ichi Ishii, Hisao Nishiyama, and Kenji Itoh

    Journal of the American Chemical Society   Vol. 126 ( 12 ) page: 3712-3713   2004.3

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  104. Ruthenium-Catalyzed One-Pot Double Allylation/Cycloisomerization of 1,3-Dicarbonyl Compounds Leading to exo-Methylenecyclopentanes Reviewed

    Yoshihiko Yamamoto, Yu-ichiro Nakagai, Kenji Itoh

    Chemistry - A European Journal   Vol. 10 ( 1 ) page: 231-236   2004.1

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  105. Ruthenium-Catalyzed Synthesis of Heterocyclic Compounds Invited Reviewed

    Yoshihiko Yamamoto and Kenji Itoh

    Ruthenium Catalysts and Fine Chemistry, Topics In Organometallic Chemistry, Vol. 11, Springer   Vol. 11   page: 249-276   2004

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  106. Carbon-Carbon Bond Formations via Ruthenacycle Intermediates Invited Reviewed

    Yoshihiko Yamamoto and Kenji Itoh

    Ruthenium in Organic Synthesis (ed. by Shun-Ichi Murahashi) Wiley-VCH     page: 95-124   2004

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  107. Ruthenium(II)-Catalyzed Selective Intramolecular [2 + 2 + 2] Alkyne Cyclotrimerizations Reviewed

    Yoshihiko Yamamoto, Takayasu Arakawa, Ryuji Ogawa, Kenji Itoh

    Journal of the American Chemical Society   Vol. 125 ( 40 ) page: 12143-12160   2003.10

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  108. Ru(II)-catalyzed [2+2+2] cycloaddition of 1,2-bis(propiolyl)benzenes with monoalkynes Reviewed

    Yoshihiko Yamamnoto, Koichi Hata, Takayasu arakawa, Kenji Itoh

    Chemical Communications   ( 11 ) page: 1290-1291   2003.6

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  109. Palladium(0)-Catalyzed Intramolecular [2+2+2] Alkyne Cyclotrimerizations with Electron-Deficient Diynes and Triynes Reviewed

    Yoshihiko Yamamoto, Asako Nagata, Hitomi Nagata, Yoji Ando, Yasuhiro Arikawa, Kazuyuki Tatsumi, Kenji Itoh

    Chemistry - A European Journal   Vol. 9 ( 11 ) page: 2469-2483   2003.6

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  110. Dinuclear Palladium(0) and Platinum(0) Complexes with p-Benzoquinone and Norbornene Ligands Reviewed

    Yoshihiko Yamamoto, Takuya Ohno, Kenji Itoh

    Organometallics   Vol. 22 ( 11 ) page: 2267-2272   2003.5

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  111. Single-Step Assembly of a C2-Symmetrical Palladium(IV) Spirocyclic Complex Reviewed

    Yoshihiko Yamamoto, Takuya Ohno, Kenji Itoh

    Avgewandte Chemie International Edition   Vol. 41 ( 19 ) page: 3662-3665   2002.10

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  112. Selective Synthesis of Fused Cyclooctatetraenes by [4+4] Coupling Between Two Different Diene Units Reviewed

    Yoshihiko Yamamoto, Tatsuya Ohno, Kenji Itoh

    Chemistry - A European Journal   Vol. 8 ( 20 ) page: 4734-4741   2002.10

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  113. Ruthenium(II)-Catalyzed [2+2+2] Cycloaddition of 1,6-Diynes with Tricarbonyl Compounds Reviewed

    Yoshihiko Yamamoto, Hideyuki Takagishi, Kenji Itoh

    Journal of the American Chemical Society   Vol. 124 ( 24 ) page: 6844-6845   2002.6

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  114. Ruthenium(II)-Catalyzed Cycloaddition of 1,6-Diynes with Isothiocyanates and Carbon Disulfide: First Transition-Metal Catalyzed [2+2+2] Cocyclotrimerization Involving C=S Double Bond Reviewed

    Yoshihiko Yamamoto, Hideyuki Takagishi, Kenji Itoh

    Journal of the American Chemical Society   Vol. 124 ( 1 ) page: 28-29   2002.1

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  115. Ruthenium(II)-Catalyzed Isomer-selective Cyclization of 1,6-Dienes Leading to exo-Methylenecyclopentanes. Unprecedented Cycloisomerization Mechanism Involving Ruthenacyclopentane(hydrido) Intermediate Reviewed

    Yoshihiko Yamamoto, Yu-ichiro Nakagai, Naoki Ohkoshi, and Kenji Itoh

    Journal of the American Chemical Society   Vol. 123 ( 26 ) page: 6372-6380   2001.7

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  116. Diastereoselective Inter- and Intramolecular Pinacol Coupling of Aldehydes Promoted by Monomeric Titanocene(III) Complex Cp2TiPh Reviewed

    Yoshihiko Yamamoto, Reiko Hattori, Takeyuki Miwa, Yu-ichiro Nakagai, Taketeru Kubota, Chiyo Yamamoto, Yoshio Okamoto, and Kenji Itoh

    The Journal of Organic Chemistry   Vol. 66 ( 11 ) page: 3865-3870   2001.6

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  117. Ruthenium(II)-Catalyzed Cycloaddition of 1,6-Diynes with Isocyanates Leading to Bicyclic Pyridones Reviewed

    Yoshihiko Yamamoto, Hideyuki Takagishi, and Kenji Itoh

    Organic Letters   Vol. 3 ( 13 ) page: 2117-2119   2001.6

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  118. Significant Chemo- and Regioselectivies in the Ru(II)-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Dicyanides Reviewed

    Yoshihiko Yamamoto, Ryuji Ogawa, and Kenji Itoh

    Journal of the American Chemical Society   Vol. 123 ( 25 ) page: 6189-6190   2001.6

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  119. Ruthenium(II)-catalyzed [2+2+2] cycloaddition of 1,6-diynes with electron-deficient nitriles Reviewed

    Yoshihiko Yamamoto, Satoshi Okuda, and Kenji Itoh

    Chemical Communications   ( 11 ) page: 1102-1103   2001.6

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  120. The First Palladium(0) Complex of a Linear 1,6,11-Triyne. A Reactive Intermediate in the Catalytic Cyclotrimerization of a Triyne Reviewed

    Yoshihiko Yamamoto, Asako Nagata, Yasuhiro Arikawa, Kazuyuki Tatsumi, and Kenji Itoh

    Organometallics   Vol. 19 ( 13 ) page: 2403-2405   2000.6

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  121. Ru(II)-Catalyzed Cycloadditions of 1,6-Heptadiynes with Alkenes: New Synthetic Potential of Ruthenacyclopentatrienes as Biscarbenoids in Tandem Cyclopropanation of Bicycloalkenes and Heteroatom-Assisted Cyclocotrimerization of 1,6-Heptadiynes with Heterocyclic Alkenes Reviewed

    Yoshihiko Yamamoto, Hideaki Kitahara, Ryuji Ogawa, Hiroyuki Kawaguchi, Kazuyuki Tatsumi, and Kenji Itoh

    Journal of the American Chemical Society   Vol. 122 ( 18 ) page: 4310-4319   2000.5

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  122. Highly chemo- and regio-selective [2+2+2] cycloaddition of unsymmetrical 1,6-diynes with terminal alkynes catalyzed by Cp*Ru(cod)Cl under mild conditions Reviewed

    Yoshihiko Yamamoto, Ryuji Ogawa, and Kenji Itoh

    Chemical Communications   ( 7 ) page: 549-550   2000.4

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  123. Fully substituted cyclooctatetraenes assembled by the [4+4] cross coupling of two different diene units: a shunting strategy of Wilke's metallacyclopentadiene coupling mechanism Reviewed

    Yoshihiko Yamamoto, Tatsuya Ohno, and Kenji Itoh

    Chemical Communications   ( 16 ) page: 1543-1544   1999.8

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  124. Pd(0)-Catalyzed Selective [2+2+2] Cycloaddition of Dimethyl Nona-2,7-diyne-1,9-dioate Derivatives with Dimethyl Acetylenedicarboxylate Reviewed

    Yoshihiko Yamamoto, Asako Nagata, and Kenji Itoh

    Tetrahedron Letters   Vol. 40 ( 27 ) page: 5035-5038   1999.7

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  125. Highly trans-selective intramolecular pinacol coupling of dials catalyzed by bulky Cp2TiPh Reviewed

    Yoshihiko Yamamoto, Reiko Hattori, and Kenji Itoh

    Chemical Communications   ( 9 ) page: 825-826   1999.5

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  126. The Cp2TiPh-Mediated Reductive Radical cyclization of Cyanoketones and Related Reactions. Efficient Trapping of Ketyl Radicals by Cp2TiPh-Coordinated Polar Multiple bonds Reviewed

    Yoshihiko Yamamoto, Daisuke Matsumi, Reiko Hattori, and Kenji Itoh

    the Journal of Organic Chemistry   Vol. 64 ( 9 ) page: 3224-3229   1999.4

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  127. Ruthenium-Catalyzed Highly Efficient Intramolecular Olefin Coupling of α,ω-Dienes. Facile and Regioselective Synthesis of exo-Methylenecyclopentanes

    Ruthenium-Catalyzed Highly Efficient Intramolecular Olefin Yoshihiko Yamamoto, Naoki Ohkoshi, Mitsutosi Kameda, and Kenji Itoh

    the Journal of Organic Chemistry   Vol. 64 ( 7 ) page: 2178-2179   1999.4

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  128. Cp*Ru(cod)Cl-Catalyzed [2+2+2] Cycloaddition of 1,6-Heptadiynes with Allylic Ethers. A Decisive Role of Coordination to the Ether Oxygen Atom Reviewed

    Yoshihiko Yamamoto, Hideaki Kitahara, Ryuji Ogawa, and Kenji Itoh

    the Journal of Organic Chemistry   Vol. 63 ( 26 ) page: 9610-9611   1998.12

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  129. Ruthenium-Catalyzed Tandem [2+2+2]/[4+2] Cycloaddition of 1,6-Heptadiyne with Norbornene Reviewed

    Yoshihiko Yamamoto, Hideaki Kitahara, Reiko Hattori, and Kenji Itoh

    Organometallics   Vol. 17 ( 10 ) page: 1910-1912   1998.5

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  130. Cp2TiPh-coordinated cyano and ester groups as efficient ketyl radical acceptors in the reductive radical cyclization of γ-and δ-cyano ketones and δ-keto esters Reviewed

    Yoshihiko Yamamoto, Daisuke Matsumi, and Kenji Itoh

    Chemical Communications   ( 8 ) page: 875-876   1998.4

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  131. Formation of 2-[1-(Trimethylsilyl)alkylidene]-4-cyclopentene-1,3-dione from Lewis Acid-Catalyzed Reaction of Cyclobutenedione Monoacetal with Alkynylsilane: Novel Cationic 1,2-Silyl Migrative Ring Opening and Subsequent 5-Exo-Trig Ring Closure Reviewed

    The Journal of Organic Chemistry   Vol. 62 ( 5 ) page: 1292-1298   1997.3

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  132. スクアリン酸を合成素子とする多官能型炭素および複素環化合物の高選択的合成

    有機合成化学協会誌   Vol. 55 ( 9 ) page: 785   1997

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  133. Study of 5-Endo Cyclization of 5-Oxapenta-2,4-dienoyl Radical and Related Radicals by ab Initio Calculations. Unusual Nonradical Cyclization Mechanism Reviewed

    The Journal of Organic Chemistry   Vol. 61 ( 26 ) page: 9264-9271   1996.12

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  134. Synthesis of Phenolic Biaryls and p-Terphenyls and Their Heteroaromatic Analogs via a Cycloaddition Route Using 4-Aryl-2-silyloxybuta-1,3-dienes and Electron Deficient Alkynes Reviewed

    Synthesis   ( 8 ) page: 949-953   1996.8

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  135. New Method for Derivatization of Squaric Acid to Highly Substituted Cyclobutenones: Lewis Acid-Catalyzed Reaction of Cyclobutene-1,2-dione Monoacetal and Its Vinylog with Unsaturated Organosilanes, and Subsequent Ring Transformation of the Adducts Reviewed

    Bulletin of the Chemical Society of Japan   Vol. 69 ( 5 ) page: 1353-1362   1996.5

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  136. Radical-Mediated Ring Enlargement of Cyclobutenones: New Synthetic Potential of Squaric Acid Reviewed

    Journal of the American Chemical Society   Vol. 117 ( 38 ) page: 9653-9661   1995.9

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  137. BF3-Catalyzed Reaction of Cyclobutene-1,2-dione Monoacetal and Its Vinylog with Allylsilanes. Regioselective Synthesis of 4-Allyl-4-ethoxy-cyclobutenones from Squaric Acid and Their Conversion to Bi- and Tricycloalkanones Reviewed

    Chemistry Letters   ( 7 ) page: 525-526   1995.7

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  138. Unexpected Ionic Rearragement of Hypoiodite. Ring-Expansion of 4-Alkynyl-4-hydroxycyclobutenone to Iodomethylenecyclopentene-1,3-dione Reviewed

    Tetrahedron Letters   Vol. 36 ( 31 ) page: 5539-5542   1995.7

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  139. Triethyloxonium Tetrafluoroborate Mediated Addition Reaction of Unsaturated Organosilanes to Squaric Acid Esters Reviewed

    Synthesis   ( 5 ) page: 571-576   1995.5

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  140. Oxidative Rearrangement of 4-Hydroxy-2-cyclobutenone. A New Route to Highly Substituted Furanones from Squaric Acid Reviewed

    The Journal of Organic Chemistry   Vol. 59 ( 17 ) page: 4707-4709   1994.8

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  141. Ring Transformation of 4-Acylmethyl-2-chloro-4-hydroxy-2-cyclobutenone to γ-Acylmethylenetetronate by Thermal Rearrangement: New Synthetic Aspect of Squaric Acid as a C_4 _-Synthon Reviewed

    Tetrahedron   Vol. 50 ( 26 ) page: 7783-7798   1994.6

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  142. Cyanohydrins from Squaric Acid Ester with Trimethylsilyl Cyanide and Their Ring Opening Reactions Reviewed

    Synlett   ( 10 ) page: 781-783   1993.10

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  143. Synthesis of γ-Acylmethylenetetronates from Squaric Acid Reviewed

    Tetrahedron Letters   Vol. 34 ( 30 ) page: 4807-4810   1993.7

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  144. Synthesis of Squaric Acid Derivatives by Lewis Acid-catalysed Reaction of its Dichloride, Methyl Ester Chloride, Diethylamide Chloride, and Ethyl Diester with Unsaturated Organosilanes: New Method for C-C Bond Formation on Cyclobutenedione Reviewed

    Journal of Chemical Society, Perkin Transactions 1   ( 2 ) page: 263-271   1993.1

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  145. Catalysed 1,2- vs 1,4-Addition of 3,4-Dichlorocyclobut-3-ene-1,2-dione with Unsaturated Organosilanes Reviewed

    Journal of Chemical Society, Perkin Transactions 1   ( 9 ) page: 2272-2273   1991.9

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Books 11

  1. Copper-Mediated Synthesis of Quinazolines and Related Benzodiazines (in Copper in N-Heterocyclic Chemistry)

    Yoshihiko Yamamoto( Role: Joint author)

    Elsevier  2020.11  ( ISBN:9780128212639

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    Language:English Book type:Scholarly book

  2. Transition-Metal-Catalyzed Alkyne Hydroarylation with Arylmetals and Aryl Halides (Organic Reactions)

    Yoshihiko Yamamoto( Role: Joint author)

    Wiley  2020  ( ISBN:978-1-119-65125-3

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    Language:English Book type:Scholarly book

    Other Link: https://www.amazon.com/Organic-Reactions-103-Andrew-Evans/dp/1119651255

  3. Spiroketal Phthalane C-Glycosides: Synthesis of Papulacandins and SGLT2 Inhibitors (in Carbohydrate-spiro-heterocycles; Topics in Heterocyclic Chemistry)

    Yoshihiko Yamamoto( Role: Contributor)

    Springer Nature  2019  ( ISBN:3030319415

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  4. Catalytic Alkyne Hydroarylation Using Arylboron Reagents, Aryl Halides, and Congeners (in Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds)

    Yoshihiko Yamamoto( Role: Contributor ,  8 Catalytic Alkyne Hydroarylation Using Arylboron Reagents, Aryl Halides, and Congeners)

    Wiley-VCH  2017.10  ( ISBN:978-3-527-34013-2

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  5. Cycloisomerizations of Substrates with Multiple Unsaturated Bonds, In Metal-Catalyzed Cyclization Reactions, Science of Synthesis reference library

    Yoshihiko Yamamoto( Role: Contributor)

    Thieme Chemistry  2015.11  ( ISBN:9783131998613

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    Cycloisomerizations of Substrates with Multiple Unsaturated Bonds

  6. Copper-Mediated Aryl-aryl Bond Formation Leading to Biaryls: A Century after the Ullmann Breakthrough (in Copper-Mediated Cross-Coupling Reactions)

    Yoshihiko Yamamoto( Role: Contributor)

    Wiley  2013.11  ( ISBN:978-1-118-06045-2

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  7. Ruthenium-Mediated [2+2+2] Cycloaddition, In Transition-Metal-Mediated Aromatic Ring Construction (in Transition-Metal-Mediated Aromatic Ring Construction)

    Yoshihiko Yamamoto( Role: Contributor)

    Wiley  2013.8  ( ISBN:978-1-118-14892-1

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    This chapter outlines advances in the ruthenium-mediated alkyne [2+2+2] cycloaddition reactions. These can be classified into two major categories in terms of the type of products: (1) syntheses of benzene derivatives via alkyne [2+2+2] cycloadditions and (2) syntheses of heteroaromatics via [2+2+2] co-cycloadditions of alkynes with nitriles or heterocumulenes. Benzene ring-forming reactions are essentially prototypes of the corresponding heteroaromatic annulations. Therefore, the first class of reactions will be reviewed in the next section and followed by a discussion of the second class of reactions. The mechanistic aspects and synthetic applications of ruthenium-catalyzed [2+2+2] cycloadditions are also described to exemplify the scientific and practical significance of ruthenium catalysis.

  8. 触媒調製ハンドブック, 第4編 均一系触媒、第11章

    山本芳彦( Role: Contributor)

    (株)エヌ・ティー・エス  2011.4 

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    遷移金属錯体触媒を用いる環化付加反応について簡潔にまとめると共に、代表的実験例として、ルテニウム錯体触媒を用いる[2+2+2]環化付加反応を上げて詳述した。

  9. Ruthenium in Organic Synthesis (Ed. S.-I. Murahashi), Chap 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates

    Yoshihiko Yamamoto, Kenji Itoh( Role: Contributor)

    Wiley-VCH  2004 

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  10. Ruthenium Catalysts and Fine Chemistry (Eds. C. Bruneau, P. H. Dixneuf), Topics in Organometallic Chemistry Series 11, Ruthenium-Catalyzed Synthesis of Heterocyclic Compound

    Yoshihiko Yamamoto, Kenji Itoh( Role: Contributor)

    Springer  2004 

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    Heterocyclic compounds have been synthesized by means of stoichiometric reagents under acidic or basic conditions. Recent progress of homogeneous transition-metal catalysis realizes a highly selective and atom-economical methodology for heterocycles synthesis under neutral and mild conditions. This review highlights the recent advances in the area of ruthenium-catalyzed syntheses of heterocyclic compounds.

  11. 1.2 芳香族炭化水素の合成1.2.1 芳香族炭化水素(環化)

    伊藤健兒、山本芳彦( Role: Contributor)

    日本化学会編第5版 実験化学講座13 有機化合物の合成I 炭化水素・ハロゲン化物丸善  2004 

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Presentations 19

  1. C-H活性化を鍵とする縮環キノロンの新規合成法 Invited

    山本芳彦

    第52回中部化学関係学協会支部連合秋季大会  2021.10.31  中部化学関係学協会支部連合

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    Event date: 2021.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:静岡(オンライン)   Country:Japan  

  2. トリス(ペンタフルオロフェニル)ボランによるフェニルアセチレンの求電子活性化を利用した三成分カップリング反応とその反応機構解析

    〇松田実季、澁谷正俊、山本芳彦

    日本薬学会第141年会  日本薬学会

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  3. コバルト/光レドックス触媒を利用するエステル含有1,6-ジインの環化異性化反応による1-ナフトール誘導体の合成

    ○山田啓士、安井猛、山本芳彦

    日本化学会第101春季年会  日本化学会

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    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  4. ロジウム触媒を用いるシクロプロパノール含有1,6-ジインの環化異性化反応によるらせん状エキソジエン骨格の構築

    ○菊池友宏、安井猛、山本芳彦

    日本化学会第101春季年会  日本化学会

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    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  5. DFT計算に導かれたルテニウム触媒反応開発 Invited

    山本芳彦

    化学反応経路探索のニューフロンティア2019 

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    Event date: 2019.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:名古屋大学   Country:Japan  

  6. 含フッ素化合物の効率的合成を可能とするビルディングブロックの開発 Invited

    山本芳彦

    第15回フッ素相模セミナー 

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    Event date: 2018.6

    Language:Japanese   Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:神奈川県綾瀬市 相模中央化学研究所   Country:Japan  

  7. Atom-transfer [2 + 2 + 1] Cycloaddition Enabled by Ruthenium Catalysis Invited International conference

    Yoshihiko Yamamoto

    International Symposium on Pure & Applied Chemistry (ISPAC) 2017 

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    Event date: 2017.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Ho Chi Minh, Vietnam   Country:Viet Nam  

  8. アルキンをカルベン源とする触媒反応

    山本芳彦

    近畿化学協会有機金属部会平成24年度第4回例会 

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    Event date: 2013.1

    Language:Japanese   Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:大阪科学技術センター   Country:Japan  

  9. 環状共役ビスカルベノイドの化学 ルテナサイクル錯体を鍵中間体とする新反応開発 Invited

    山本芳彦

    第47回天然物化学談話会 

     More details

    Event date: 2012.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:熊本県阿蘇市   Country:Japan  

  10. Cu-Catalyzed Selective Hydroarylation of Electron-Deficient Alkynes with Arylboronic Acids International conference

    International Symposium on Organic Synthesis 2009 

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    Event date: 2009.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    The Cu-catalyzed reaction of arylboronic acids with electron-deficient alkynes proceeded in MeOH at ambient temperature to yield trisubstituted alkenes stereoselectively. This Cu catalysis has been applied to the divergent synthesis of bioactive small molecules.

  11. Cu-Catalyzed Hydroarylation of Electron-Deficient Alkynes

    Chemistry of Organic & Polymer Materials for Ubiquitous ICTSession for Synthetic Organic Chemistry 

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    Event date: 2008.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

    After screening several non-precious transition-metal salts (Fe(OAc)2, Fe(acac)3, Co(OAc)2•4H2O, Ni(OAc)2•4H2O, and AgOAc), we gratifyingly identified CuOAc as an efficient catalyst. As shown below, arylboronic acids (3 equiv) were allowed to react with alkynoates (1 equiv) in the presene of 1–10 mol % CuOAc in MeOH at 28 ˚C to afford cinnamates in 60–97% isolated yields with excellent syn-selectivity. It should be noted that this method tolerates reactive functional

  12. ルテニウム触媒[2+2+2]環化付加によって統合された新しい多段階触媒プロセス

    平成19年度 化学系学協会東北大会 第29回有機化学コロキウム 

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    Event date: 2007.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

    遷移金属錯体触媒反応,とりわけ多成分カップリングプロセスは,簡便な操作により複数の小分子間に一挙に多数の結合を形成させ,より複雑で付加価値の高い分子骨格を構築する理想的分子変換プロセスとして注目を集めている。本講演では,ルテニウム触媒環化付加反応を核として,異なる複数の触媒反応が統合された新しい多成分カップリングプロセスについて紹介する。

  13. Sequential Multi-Component Coupling Based on Ruthenium-Catalyzed Cyclotrimerization

    23rd Conference on Combinatorial Chemistry, Japan 

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    Event date: 2006.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  14. Ruthenium-catalyzed cyclotrimerization of alkynylboronates and iodoalkynes International conference

    232nd American Chemical Society National Meeting: Modern Acetylene Chemistry 

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    Event date: 2006.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Syntheses of polysubstituted benzenes have often encountered difficulties in controlling regioselectivity and incompatibility to labile functionalities. Highly substituted benzeneboronic acid esters were synthesized by using ruthenium-catalyzed [2 + 2 + 2] cycloaddition of alkynylboronates under mild conditions. Multiply substituted iodobenzenes were also efficiently synthesized with defined substitution patterns via ruthenium-catalyzed [2 + 2 + 2] cycloaddition of iododiynes.

  15. Multicomponent Coupling Based on Ruthenium-Catalyzed Cyclotrimerization

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    Event date: 2005.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  16. ルテニウム触媒を用いるジインと炭素ーヘテロ元素多重結合の環化付加反応

    第15回北海道大学触媒化学研究センター研究討論会 「明日を創る有機化学」 

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    Event date: 2004.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

    遷移金属錯体を触媒とするアルキン類と炭素-ヘテロ元素多重結合の共環化三量化反応は,原子効率の高い複素環構築法である。1)しかしながら,非対称な反応基質間の共環化三量化反応においては,化学および位置選択性の制御が問題となる。最近になって,ジルコニウム錯体やチタン反応剤を化学量論量用いた手法が相次いで開発され大いに注目を集めたが,2)触媒反応における選択性の獲得が重要な課題として残されている。
     触媒反応において化学・位置選択性を制御する間接的な方法として,反応成分の一部あるいは全てを適当な連結鎖で繋

  17. ルテニウム錯体触媒を用いるジエンの環化異性化反応

    第35回中部化学関係学協会支部連合秋季大会 

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    Event date: 2004.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  18. ルテニウム触媒を用いる環化三量化反応

    第21回有機合成化学夏季大学 

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    Event date: 2004.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

    反応分子の接近方向を効果的に制御するペンタメチルシクロペンタジエニル(Cp*)配位子を装着した二価有機ルテニウム錯体、 Cp*RuCl(cod) を触媒前駆体として用いた, 1,6-ジイン類と,アルケン、アルキン、ニトリル、イソシアネートなどの不飽和分子との[2 + 2 + 2]環化付加反応の展開について紹介する。

  19. ルテニウム錯体を用いる触媒的アルキン分子内環化三量化反応

    第92回触媒討論会 

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    Event date: 2003.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

    二価有機ルテニウム錯体、クロロ(ペンタメチルシクロペンタジエニル)(1,5-シクロオクタジエン)ルテニウム、を前駆触媒として用いることにより、ジイン類とモノアルキンとの[2+2+2]環化付加反応および、トリイン類を用いる完全分子内[2+2+2]環化三量化反応が、いずれも室温で進行し、複環式ベンゼン誘導体を効率よく与えた。また、アルキン末端にフェニル基を導入したジインとルテニウム錯体の化学量論反応を行うことにより、本触媒反応の鍵中間体と考えられる双環式ルテナサイクル錯体を合成・単離した。

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Works 1

  1. Chloro[(1,2,5,6-η)-1,5-cyclooctadiene][(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]ruthenium

    2009

Research Project for Joint Research, Competitive Funding, etc. 5

  1. メソポーラス物質を利用した固定化分子触媒の研究

    2016.4 - 2018.3

    国内共同研究 

  2. 生理機能分子迅速構築触媒システムの開発

    2013.4 - 2014.3

    内藤記念科学奨励金 

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    Grant type:Competitive

    生理活性物質の複雑な分子骨格を、精密かつ迅速に構築可能な新規遷移金属触媒系を確立する。特に、地球上に偏在する小分子資源を有効活用し、環境負荷の小さな合成を達成する触媒を探索する。

  3. Synthesis of Highly Substituted Quinones via Sequential Catalytic Process

    2007.11 - 2009.3

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    Grant type:Competitive

  4. ルテニウム錯体触媒を用いる非天然型複合糖類の高効率精密合成

    2004.6 - 2005.5

    内藤科学技術振興財団研究助成 

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    Grant type:Competitive

  5. 多官能性分子の自発形成に基づく選択的多成分連結法の創製

    2004.6 - 2005.5

    徳山科学技術振興財団研究助成 

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    Grant type:Competitive

KAKENHI (Grants-in-Aid for Scientific Research) 10

  1. 触媒的酸素原子移動反応を活用する新規ケテン発生法の開拓

    2013.4 - 2014.3

    科学研究費補助金 

    山本芳彦

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    Authorship:Principal investigator 

    遷移金属カルベン錯体は、有機合成において極めて有用なツールとなっている。本計画では、末端アセチレンとカチオン性ルテニウム錯体から発生するビニリデンカルベン錯体への酸素原子移動反応によるケテンの発生と、同過程を組み込んだ新規触媒系の創成を目指す。旧来のカルベン錯体からのケテン発生法は、予め調製されたカルベン錯体を用いる非触媒的手法であったことに加え、有毒な一酸化炭素の挿入に頼らざるを得なかった。本計画の達成によって、入手容易な末端アセチレンよりビニリデンカルベン錯体を発生させ、その酸化により所望のケテンを触媒的に発生させる実用的な手法が確立される。本手法は学術的に興味深いことに加え、極めて応用範囲の広いものである。さらに、本研究を通して開発される触媒的分子変換プロセスを駆使して、生理活性物質の合成を展開する。

  2. 精密分子触媒を駆使する機能分子迅速合成プロセスの創成

    2008.4 - 2011.3

    科学研究費補助金  基盤研究(B), 20350045

    山本芳彦

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    Authorship:Principal investigator 

  3. 遷移金属錯体触媒を複合化した多成分連結プロセスの開発

    2008.4 - 2010.3

    科学研究費補助金  特定領域研究,課題番号:20037018

    山本芳彦

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    Authorship:Principal investigator 

  4. 遷移金属錯体触媒反応を駆使する生体機能分子の精密合成

    2006.4 - 2008.3

    科学研究費補助金  特定領域研究(公募,A02),課題番号:18032036

    山本 芳彦

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    Authorship:Principal investigator 

    2価ルテニウム錯体を触媒とする[2 + 2 + 2]環化付加反応を駆使して,生理機能が期待されるスピロ環状C-アリールグリコシドの多様性指向型合成法を確立した。また,銅触媒マンニッヒ型三成分カップリングとイリジウム触媒環化異性化/Diels-Alder環化付加タンデムプロセスを統合した環状アミノ酸の新規合成法を開発した。

  5. 遷移金属錯体触媒多成分連結法に基づく多様性指向型精密合成プロセスの開拓

    2005.4 - 2008.3

    科学研究費補助金  若手研究(A),課題番号:17685008

    山本 芳彦

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    Authorship:Principal investigator 

    本研究では,申請者がこれまで開発を進めてきた不飽和結合間の触媒的高次カップリングなどの遷移金属触媒反応を駆使して,複数の単純な出発原料から複雑な環状分子を効率良く合成し,エネルギー消費や廃棄物の発生を抑制することのできる新規多様性指向型精密合成プロセスの開発をおこなった。

  6. ルテニウム錯体触媒を用いる非天然型C-グリコシドの精密合成

    2005.4 - 2006.3

    科学研究費補助金  特定領域研究,課題番号:17035038

    山本 芳彦

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    Authorship:Principal investigator 

    面性配位子を持つ2価ルテニウム錯体 [Cp*RuCl(cod)] が,C-アルキニルグリコシドと1,6-ジインあるいは,C-ジイニルグリコシドとモノアルキンとの[2 + 2 + 2]環化付加反応に有効であることを確認し,新規なC-アリールサッカライドやアミノ酸糖複合分子の合成にも成功した。

  7. 不飽和有機分子の酸化的環化による高原子価有機金属錯体の合成

    2004.4 - 2005.3

    科学研究費補助金  特定領域研究,課題番号:15036228

    山本芳彦

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    Authorship:Principal investigator 

  8. 高機能メタラシクロペンタジエン錯体触媒の開発

    2002.4 - 2005.3

    科学研究費補助金  若手研究(B),課題番号:14750677

    山本 芳彦

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    Authorship:Principal investigator 

  9. 前・後周期遷移金属ハイブリッド錯体触媒の創製による精密触媒反応の開拓

    2000.4 - 2002.3

    科学研究費補助金  奨励研究A, 12750760

    山本芳彦

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    Authorship:Principal investigator 

  10. 低原子価チタン錯体を用いる新規還元的ラジカル環化反応の開発

    1997.4 - 1999.3

    科学研究費補助金  奨励研究A、,

    山本芳彦

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    Authorship:Principal investigator 

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Industrial property rights 1

  1. トリフルオロメチル置換セミスクアレートの製造方法、トリフルオロメチル置換セミスクアレートを起点とするトリフルオロメチル化合物の製造方法及びトリフルオロメチル基含有化合物

    山本芳彦、黒原崇、澁谷正俊

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    Applicant:国立大学法人名古屋大学

    Application no:特願2015-150175  Date applied:2015.7

    Country of applicant:Domestic  

    トリフルオロメチル置換セミスクアレートの製造方法、トリフルオロメチル置換セミスクアレートを起点とするトリフルオロメチル化合物の製造方法及びトリフルオロメチル基含有化合物

 

Teaching Experience (On-campus) 76

  1. Current Organic & Polymer Chemistry

    2020

  2. 先端有機化学

    2020

  3. 有機化学1及び演習

    2020

  4. 基盤創薬学概論

    2020

  5. 先端有機化学

    2019

  6. 創薬倫理特論

    2019

  7. 基盤創薬学概論

    2019

  8. 基礎セミナーA

    2019

  9. Current Organic Chemistry

    2019

  10. 有機化学1及び演習

    2019

  11. 化学生物工学序論

    2019

  12. 先端有機化学

    2018

  13. 創薬倫理特論

    2018

  14. 基盤創薬学概論

    2018

  15. 有機化学1及び演習

    2018

  16. 基礎セミナーA

    2018

  17. 先端有機化学

    2017

  18. Current Organic Chemistry

    2017

  19. 有機化学1及び演習

    2017

  20. 有機化学I

    2017

  21. 創薬倫理特論

    2017

  22. 基盤創薬学概論

    2017

  23. 化学生物工学序論

    2017

  24. 先端有機化学

    2016

  25. 創薬産業特論

    2016

  26. Current Organic Chemistry

    2016

  27. 有機化学I

    2016

  28. 基盤創薬学概論

    2016

  29. 先端有機化学

    2015

  30. Current Organic Chemistry

    2015

  31. 創薬産業特論

    2015

  32. 基盤創薬学概論

    2015

  33. 有機化学I

    2015

  34. Current Organic Chemistry

    2014

  35. 創薬産業特論

    2014

  36. 有機化学I

    2014

  37. 基盤創薬学概論

    2014

  38. 基盤創薬学概論

    2013

  39. 有機化学I

    2013

  40. 先端有機科学

    2013

  41. 創薬制御科学

    2013

  42. 化学生物工学概論

    2013

  43. 基礎セミナー

    2013

  44. 創薬有機化学セミナーIA

    2013

  45. 創薬有機化学セミナーIB

    2013

  46. 多分野融合実践実習

    2013

  47. 基盤創薬学概論

    2012

  48. 有機化学I

    2012

     詳細を見る

    有機化学の初歩:結合・構造・アルカンの立体配座・命名法等を教授する。

  49. 先端有機科学

    2012

  50. 創薬制御科学

    2012

  51. 創薬有機化学セミナーIA

    2012

  52. 応用有機化学基礎論

    2011

  53. 基礎化学実験

    2011

  54. 有機化学I

    2011

  55. 有機金属化学

    2011

  56. 有機化学実験第1

    2011

  57. 有機化学実験第2

    2011

  58. 有機化学演習第2

    2010

  59. 有機化学実験第2

    2010

  60. 有機化学演習第1

    2010

  61. 有機化学実験第1

    2010

  62. 応用有機化学基礎論

    2010

  63. 基礎化学実験

    2010

  64. 有機化学I

    2010

  65. 有機金属化学

    2009

  66. 有機化学I

    2009

  67. 応用有機化学基礎論

    2009

  68. 応用化学・物質化学特別講義第1

    2005

  69. 有機合成学

    2005

  70. 実験安全学

    2005

  71. 基礎セミナーA

    2005

  72. 応用化学・物質化学特別講義第2

    2005

  73. 有機化学I

  74. 有機合成化学

  75. 応用有機化学特論

  76. 有機合成化学

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Teaching Experience (Off-campus) 3

  1. 2008.4 - 2009.3 九州大学先導研)

  2. フロンティア研究者セミナー

    2007.4 - 2008.3 東京農工大)

  3. 2006.4 - 2007.3 福岡大学大学院理学研究科)