研究者詳細 - 日比野　高士

論文 - 日比野　高士

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Detection of propylene under oxidizing conditions using zirconia-based potentiometric sensor 査読有り

Hibino T, Wang SQ, Kakimoto S, Sano M

SENSORS AND ACTUATORS B-CHEMICAL 50 巻 ( 2 ) 頁： 149 - 155 1998年7月

NOx detection using the electrolysis of water vapor in a YSZ cell Part II. Electrochemical oxygen pump 査読有り

Hibino T., Kuwahara Y., Otsuka T., Ishida N., Oshima T.

Solid State Ionics 107 巻 ( 3-4 ) 頁： 217 - 220 1998年4月

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Solid State Ionics

The detection of NO in the presence of excess oxygen has been carried out using four electrochemical cells, Pt|YSZ|Pt, which serve as an electrochemical pumping cell, an electrolysis cell and two oxygen sensors, respectively. Their operation temperature was 800°C. A mixture of 0-2500 ppm NO, 1-7% oxygen, 3-10% water vapor and 0-10% carbon dioxide in argon was used as a sample gas. At the electrochemical pumping cell, oxygen in the sample gas was removed down to a constant concentration of 1800 ppm, which was monitored by the oxygen sensor. At the electrolysis cell, water vapor in the sample gas was electrolyzed, and the resulting hydrogen reacted with NO in the sample gas. Finally, the sample gas was fed into another oxygen sensor. Two potentiometric and amperometric methods were adopted to detect NO. In the potentiometric method, the EMF value of the oxygen sensor decreased with increasing NO concentration. In the amperometric method, the current applied to the electrolysis cell was proportional to the concentration of NO. Additionally, the influences of the coexisting oxygen, water vapor and carbon dioxide in the sample gas on the detection of NO were investigated in detail. © 1998 Elsevier Science B.V. All rights reserved.

DOI： 10.1016/s0167-2738(97)00539-0

Scopus

NOx detection using the electrolysis of water vapour in a YSZ cell Part I. NOx detection 査読有り

Hibino T., Kuwahara Y., Otsuka T., Ishida N., Oshima T.

Solid State Ionics 107 巻 ( 3-4 ) 頁： 213 - 216 1998年4月

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Solid State Ionics

The reaction of NO with the hydrogen formed by electrolyzing water vapour in a YSZ cell has been applied to detect NO with output signal of magnitude in millivolt or milliampere. The experimental apparatus consisted of two YSZ cells, Pt|YSZ|Pt, which served as an electrolysis cell and an oxygen sensor, respectively. A mixture of 0-3000 ppm NO and 3% H2O in argon was successively fed to the two cells at 800°C. In the upstream cell, the hydrogen formed by electrolyzing water vapour in the sample gas reacted with NO in the sample gas. In the downstream cell, the electromotive force (EMF) value was measured using air as a reference gas. The EMF value of the oxygen sensor was used as a sensor signal, when a current of 6.7 mA was applied to the electrolysis cell. The EMF signal decreased with increasing NO concentration in the sample gas. Furthermore, the current applied to the electrolysis cell was used as another sensor signal, when the EMF value of the oxygen sensor was held at 700 mV. The current signal increased with increasing NO concentration in the sample gas. © 1998 Elsevier Science B.V. All rights reserved.

DOI： 10.1016/s0167-2738(97)00538-9

Scopus

Nonideal electromotive force of zirconia sensors for unsaturated hydrocarbon gases 査読有り

Takashi Hibino, Yoshitaka Kuwahara, Shuqiang Wang, Shiro Kakimoto, Mitsuru Sano

Electrochemical and Solid-State Letters 1 巻頁： 197-199 1998年4月

NOx detection using the electrolysis of water vapor in a YSZ cell - Part II. Electrochemical oxygen pump 査読有り

Hibino T, Kuwahara Y, Otsuka T, Ishida N, Oshima T

SOLID STATE IONICS 107 巻 ( 3-4 ) 頁： 217 - 220 1998年4月

NOx detection using the electrolysis of water vapour in a YSZ cell - Part I. NOx detection 査読有り

Hibino T, Kuwahara Y, Otsuka T, Ishida N, Oshima T

SOLID STATE IONICS 107 巻 ( 3-4 ) 頁： 213 - 216 1998年4月

NOx detection using the electrolysis of water vapor in a YSZ cell Part Ⅰ. NOx detection 査読有り

Takashi Hibino, Yoshitaka Kuwahara, T. Otsuka, N. Ishida, T. Oshima

Solid State Ionics 107 巻頁： 213-216 1998年

Detection of propylene under oxidizing conditions using zirconia-based potentiometric sensor 査読有り

Takashi Hibino, Shuqiang Wang, Shiro Kakimoto, Mitsuru Sano

Sensors and Actuators B 50 巻頁： 149-155 1998年

NOx detection using the electrolysis of water vapor in a YSZ cell. Part Ⅱ. electrochemical oxygen pump 査読有り

Takashi Hibino, Yoshitaka Kuwahara, T. Otsuka, N. Ishida, T. Oshima

Solid State Ionics 107 巻頁： 217-220 1998年

Detection of propylene under oxidizing conditions using zirconia-based potentiometric sensor 査読有り

Hibino T., Wang S., Kakimoto S., Sano M.

Sensors and Actuators, B: Chemical 50 巻 ( 2 ) 頁： 149 - 155 1998年

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Sensors and Actuators, B: Chemical

A sensor device detecting propylene under oxidizing conditions at high temperatures has been fabricated using a yttria-stabilized zirconia (YSZ) as the solid electrolyte. When the sample gas containing 0-500 ppm propylene and 10 vol.% O2 was fed to various metal electrodes at 600°C, the Pt, Pd and Ni electrodes had a small or negligible EMF response, but the Au electrode had a large EMF response, which was based on a mixed potential. The mixed potentials of the Au electrode for H2, CO and CH4 were very small and that for propylene was independent of the presence of water vapor and CO2. However, since this sensor was an oxygen concentration cell, the mixed potential for propylene was affected by changing the O2 concentration. This problem was appreciably solved using a one-compartment cell attached with the Au and Pt electrodes, where their sensitivities to O2 were compensated by each other. In addition, the mechanism of the mixed potential for propylene was discussed by measuring the polarization curve of the Au electrode and its catalytic activity. © 1998 Elsevier Science S.A. All rights reserved.

DOI： 10.1016/S0925-4005(98)00217-2

Scopus

Solid electrolyte HC sensor on gasoline engines 査読有り

Hibino T., Kuwahara Y., Kuroki Y., Oshima T., Inoue R., Kitanoya S., Fuma T.

Solid State Ionics 104 巻 ( 1-2 ) 頁： 163 - 166 1997年12月

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Solid State Ionics

A sensor for detecting CH4 in exhaust gases from gasoline engines has been constructed from two Pd|YSZ| Au cells, which are attached to each other with their Pd electrodes in the interior side of the assembly. When the sample gases consisting of CH4, O2 and H2O were fed to the sensor element at 750°C, EMF values were generated from the one cell and then compensated by pumping O2 electrochemically from the other cell. Currents applied to the latter cell linearly increased with CH4 concentration, but were not influenced by changing O2 concentration.

DOI： 10.1016/s0167-2738(97)00405-0

Scopus

Solid electrolyte HC sensor on gasoline engines 査読有り

Hibino T, Kuwahara Y, Kuroki Y, Oshima T, Inoue R, Kitanoya S, Fuma T

SOLID STATE IONICS 104 巻 ( 1-2 ) 頁： 163 - 166 1997年12月

Mechanism of NO decomposition in a solid electrolyte reactor by SEP method 査読有り

Hibino T., Ushiki K., Kuwahara Y.

Solid State Ionics 98 巻 ( 3-4 ) 頁： 185 - 190 1997年6月

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Solid State Ionics

The mechanism of the NO decomposition in the presence of excess O2, H2O and CO2 using a ceria-based oxide ionic conductor with a Pd electrode has been studied by solid electrolyte potentiometry (SEP) method. A single compartment cell for measuring PO2 , Pt|YSZ|Pt, are attached to another single compartment cell for decomposing NO, Pd|Ce0.8Sm0.2O1.9|Pd, where their working electrodes come into contact with each other. Experiments were carried out with a mixture of 2611 ppm NO, 0.1-4% O2, 0-5% H2O and 0-5% CO2 in argon at 800°C. A PO2 measurement in the neighborhood of the Pd electrode during NO decomposition confirms that the NO decomposition is initiated after the electrochemical oxygen pump is completed. A comparison of the Pd electrodes heated at 850°C with that heated at 1300°C shows that the poorer the oxygen pumping property, the better the NO decomposition. On the basis of these results, the mechanism of the NO decomposition is discussed in detail. In addition, the SEP method also gives information about the influences of the coexistent O2, H2O and CO2 on the NO decomposition.

DOI： 10.1016/s0167-2738(97)00116-1

Scopus

Mechanism of NO decomposition in a solid electrolyte reactor by SEP method 査読有り

Hibino T, Ushiki K, Kuwahara Y

SOLID STATE IONICS 98 巻 ( 3-4 ) 頁： 185 - 190 1997年6月

Electrochemical oxygen pump using CeO2-based solid electrolyte for NOx detection independent of O-2 concentration 査読有り

Hibino T, Ushiki K, Kuwahara Y

SOLID STATE IONICS 93 巻 ( 3-4 ) 頁： 309 - 314 1997年1月

Electrochemical oxygen pump using CeO<inf>2</inf>-based solid electrolyte for NOx detection independent of O<inf>2</inf> concentration 査読有り

Hibino T., Ushiki K., Kuwahara Y.

Solid State Ionics 93 巻 ( 3-4 ) 頁： 309 - 314 1997年1月

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Solid State Ionics

The electrochemical oxygen pump has been studied using Ceo0.8Sm0.2O1.9 as a solid electrolyte and gold metal as an electrode. The O2 concentration in the flow of a mixture of 1000 ppm NO, 1-10% O2, 5% H2O and 5% CO2 at a flow-rate of 20 ml min-1 was electrochemically controlled to a constant value of 5% by applying anodic or cathodic currents to the cell at 900°C. During oxygen pumping, NO was not electrolyzed at all and the pumping amount of oxygen obeyed Faraday's law. A potentiometic-or amperometric-type sensor for NOx when introduced into the resulting gas stream, exhibited an output signal without influence of the O2 concentration.

DOI： 10.1016/s0167-2738(96)00541-3

Scopus

Electrochemical oxygen pump using CeO2-based solid electrolyte for NOx detection independent of O2 concentration 査読有り

Takashi Hibino, Ken-ichi Ushiki, Yoshitaka Kuwahara

Solid State Ionics 93 巻頁： 309-314 1997年

Solid electrolyte HC sensor on gasoline engines 査読有り

Takashi Hibino, Yoshitaka Kuwahara, Y. Kuroki, T. Oshima, R. Inoue, S. Kitanoya, T. Fuma

Solid state Ionics 104 巻頁： 163-166 1997年

Mechanism of NO decomposition in a solid electrolyte reactor by SEP method 査読有り

Takashi Hibino, Ken-ichi Ushiki, Yositaka Kuwahara

Solid State Ionics 98 巻頁： 185-190 1997年

総説：固体電解質を使用した排ガスセンサ

日比野高士

触媒 39 巻頁： 660-663 1997年

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