Organization
Research Center for Materials Science Associate professor
Graduate School
Graduate School of Science
Title
Associate professor
Contact information
YAMADA, Yasuyuki
Degree 1
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Doctor （ 2003.3 The University of Tokyo ）
Research Interests 5
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metal complex
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Porphyrin
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Phthalocyanine
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supramolecular chemistry
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Catalyst
Research Areas 4
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Others / Others / Nano Materials/Nano Bioscience
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Others / Others / Functional Material Chemistry
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Nanotechnology/Materials / Inorganic/coordination chemistry
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Nanotechnology/Materials / Organic functional materials
Current Research Project and SDGs 3
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Synthesis of Supramolecular Metallo-Nanowires
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Synthesis of Stacked Nanoarrays of Porphyrins and Phtalocyanines
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新奇な超分子型遷移金属オキソ種を酸化活性種とするメタン直接変換触媒の創製
Research History 5
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Japan Science and Technology Agency PRESTO "Science and Creation of Innovative Catalysts" Researcher
2017.10 - 2021.9
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Nagoya University Research Center for Materials Science Associate professor
2014.8
Country：Japan
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Assistant Professor, Department of Chemistry, Nagoya University
2007.4
Country：Japan
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Assistant Professor, Faculty of Pharmaceutical Sciences, Tokyo University of Science
2004.4 - 2007.3
Country：Japan
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Postdoctral Fellow, Purdue University, Department of Chemistry
2003.4 - 2004.3
Education 2
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The University of Tokyo Graduate School, Division of Science Department of Chemistry
2000.4 - 2003.3
Country： Japan
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The University of Tokyo Faculty of Science Department of Chemistry
1994.4 - 1998.3
Country： Japan
Professional Memberships 5
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The Chemical Society of Japan
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錯体化学会
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ホストーゲスト・超分子化学研究会
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The Electrochemical Society of Japan
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Catalysis Society of Japan
Committee Memberships 1
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Green Synthesis & Catalysis Editorial Board
2022.3
Committee type：Other
Awards 6
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・ Symposium of Host-Guest and Supramolecular Chemistry (SHGSC) Japan Award of Excellence
2019.5
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Symposium Award
2018.3 International Congress on Pure & Applied Chemistry 2018 (ICPAC 2018)
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Excellent Oral Presentation Award
2016.8 International Symposium on Pure & Applied Chemistry 2016 (ISPAC 2016)
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第28回若い世代の特別講演会証
2014.3 日本化学会
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バイオ関連合同シンポジウム講演賞
2006.9 日本化学会生体機能関連化学部会、バイオテクノロジー部会、生命化学研究会
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第83春季年会 学生講演賞
2003.3 日本化学会
Papers 79
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Inorganic–Organic Framework Constructed by the Intercalation of a Double–Decker Porphyrin Metal Complex into Clay Nanosheets and Its Efficient Dye Adsorption Ability Invited Reviewed
Yamada, Y. *; Nishino, T.; Hashimoto, A.; Toyoda, Y.; Yoshikawa, H.; Tanaka, K.*
ACS Applied Optical Materials Vol. 2 page： 405 - 413 2024
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Stacking of Cofacially Stacked Iron Phthalocyanine Dimer on Graphite Achieved High Catalytic CH4 Oxidation Activity Comparable to that of pMMO Invited Reviewed
Yamada, Y.*; Morita, K.; Sugiura, T.; Toyoda, Y.; Mihara, N.; Nagasaka, M.; Takaya, H.; Tanaka, K.; Koitaya, T.; Nakatani, N.; Ariga-Miwa, H.; Takakusagi, S.; Hitomi, Y.; Kudo, T.; Tsuji, Y.; Yoshizawa, K.; Tanaka, K.*
JACS Au Vol. 3 ( 3 ) page： 823 - 833 2023.3
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Evaluation of CH4 Oxidation Activity of High-Valent Iron-Oxo Species of A µ-Nitrido-Bridged Heterodimer of Iron Porphycene and Iron Phthalocyanine Invited Reviewed
Yamada, Y.*; Miwa, Y.; Toyoda, Y.; Phung, Q. M.; Oyama, K.-i.; Tanaka, K.*
Catalysis Science & Technology 2023.1
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Optical Resolution of Carboxylic Acid Derivatives of Homoleptic Cyclometalated Iridium(III) Complex via Diastereomers Formed with Chiral Auxiliaries Reviewed
Kanbe, A.; Yokoi, K.; Yamada, Y.; Tsurui, M.; Kitagawa, Y.; Hasegawa, Y.; Ogata, D.; Yuasa, J.; Aoki, S.*
Inorganic Chemistry Vol. 62 page： 11325 - 11341 2023
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Design and Synthesis of Poly(2,2’-bipyridyl) Ligands for Use in Cancer Chelation Therapy: Control of Anticancer Activity and Cytotoxicity by Complexation/Decomplexation with Biorelevant Metal Cations Invited Reviewed
Balachandran, C.; Hirose, M.; Tanaka, T.; Jie, Z. J.; Yokoi, K.; Hisamatsu, Y.; Yamada, Y.; Aoki, S.*
Inorganic Chemistry Vol. 62 page： 14615 - 14631 2023
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Synthesis of Isomeric Tb3+–Phthalocyanine Double–Decker Complexes Depending on the Difference in the Direction of Coordination Plane and Their Magnetic Properties Reviewed
Yamada, Y.; Nakajima, H.; Kobayashi, C.; Shuku, Y.; Awaga, K.; Akine, S.; Tanaka, K.*
Chemistry, A European Journal Vol. 29 ( 1 ) page： e202203272 - e202203272 2022.12
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Significant Effect of Flexibility of Bridging Alkyl Chains on the Proximity of Stacked Porphyrin and Phthalocyanine Conjugated with Fourfold Rotaxane Linkage Reviewed
Yamada, Y.; Iida, H.; Shibano, S.; Mihara, N.; Kato, T.; Tanaka, K.*
Chemistry, A European Journal Vol. 28 ( 37 ) page： e202200819 - e202200819 2022.4
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Design, Synthesis, and Anticancer Activity of Triptycene–Peptide Hybrids that Induce Paraptoic Cell Death in Cancer Cell Reviewed
Yamaguchi, K.; Yokoi, K.; Umezawa, K.; Tsuchiya, K.; Yamada, Y.; Aoki, S.*
Bioconjugate Chemistry Vol. 33 page： 691 - 717 2022.4
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Yamada, Y; Miwa, Y; Toyoda, Y; Phung, QM; Oyama, KI; Tanaka, K
CATALYSIS SCIENCE & TECHNOLOGY Vol. 13 ( 6 ) page： 1725 - 1734 2023.3
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Significant Effect of the Flexibility of Bridging Alkyl Chains on the Proximity of Stacked Porphyrin and Phthalocyanine Conjugated with a Fourfold Rotaxane Linkage
Yamada Yasuyuki, Iida Hayato, Shibano Shinya, Mihara Nozomi, Kato Tatsuhisa, Tanaka Kentaro
CHEMISTRY-A EUROPEAN JOURNAL Vol. 28 ( 37 ) 2022.7
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Significant Effect of the Flexibility of Bridging Alkyl Chains on the Proximity of Stacked Porphyrin and Phthalocyanine Conjugated with a Fourfold Rotaxane Linkage
Yamada Yasuyuki, Iida Hayato, Shibano Shinya, Mihara Nozomi, Kato Tatsuhisa, Tanaka Kentaro
CHEMISTRY-A EUROPEAN JOURNAL Vol. 28 ( 37 ) 2022.7
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Yamada, Y; Teoh, CM; Toyoda, Y; Tanaka, K
NEW JOURNAL OF CHEMISTRY Vol. 46 ( 3 ) page： 955 - 958 2022.1
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Synthesis of a Monocationic μ-Nitrido-Bridged Iron Porphycene Dimer and Its Methane Oxidation Activity Reviewed
Yamada, Y.*; Miwa, Y; Toyoda, Y.; Yamaguchi, T.; Akine, S.; Tanaka, K.*
Dalton Trans. Vol. 50 ( 45 ) page： 16775 - 16781 2021.11
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Shimizu, T.; Wakamatsu, K.; Yamada, Y.*; Toyoda, Y.; Akine, S.; Yoza, K.; Yoshikawa, H.*
ACS Appl. Mater. Interfaces Vol. 13 ( 34 ) page： 40612 - 40617 2021.9
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Yamada, Y.*; Kura, J.; Toyoda, Y.; Tanaka, K.*
Dalton Trans. Vol. 50 ( 19 ) page： 6718 - 6724 2021.5
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Design, Synthesis, and Anticancer Properties of Bis and Mono(cationic peptide) Hybrids of Cyclometalated Ir(III) Complexes: Effect of the Number of Peptide Units on Anticancer Activity Reviewed
Haribabu, J.; Tamura, Y.; Yokoi, K.; Balachandran, C.; Umezawa, M.; Tsuchiya, K.; Yamada, Y.; Karvembu, R.; Aoki, S.*
Eur. J. Inorg. Chem. Vol. 2021 ( 18 ) page： 1796 - 1814 2021.5
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Synthesis of Bis{meso-Tetrakis(4-N-alkylpyridiniumyl)porphyrinato}cerium and Its Redox Switching Behavior
Nishino Toshio, Yamada Yasuyuki, Yamamoto Ayumi, Tanaka Kentaro
MOLECULES Vol. 26 ( 4 ) 2021.2
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Synthesis of bis{meso-tetrakis(4-N-alkylpyridinium)porphyrinato}cerium and its redox switching behavior Reviewed
Nishino, T.; Yamada, Y.; Yamamoto, A.; Tanaka, K.
Molecules Vol. 26 page： 790 2021
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Kazama, A; Imai, Y; Okayasu, Y; Yamada, Y; Yuasa, J; Aoki, S
INORGANIC CHEMISTRY Vol. 59 ( 10 ) page： 6905 - 6922 2020.5
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Yamada, Y; Tanaka, K
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY Vol. 96 ( 3-4 ) page： 197 - 213 2020.4
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One-pot synthesis of cyclic oligosaccharides by the polyglycosylation of monothioglycosides
Someya Hidehisa, Seki Takehito, Ishigami Gota, Itoh Taiki, Saga Yutaka, Yamada Yasuyuki, Aoki Shin
CARBOHYDRATE RESEARCH Vol. 487 2020.1
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Development of Functional Molecular Assemblies Based on Programmable Construction of Face-to-Face Assemblies of Metallo-Porphyrinoids Invited Reviewed
Yamada, Y., Tanaka, K.
Journal of Inclusion Phenomena and Macrocycle Chemistry Vol. 96 page： 197 - 213 2020
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mu-Nitrido-Bridged Iron Phthalocyanine Dimer Bearing Eight Peripheral 12-Crown-4 Units and Its Methane Oxidation Activity Reviewed
Yamada, Y.*; Kura, J.; Toyoda, Y.; Tanaka, K.
New Journal of Chemistry Vol. 44 page： 19179 - 19183 2020
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Design and Synthesis of Cyclometalated Iridium(III) Complex-Chromophore Hybrids that Exhibit Long Emission Lifetime Based on a REET (Reversible Electronic Energy Transfer ) Mechanism Reviewed
Kazama, A.; Imai, Y.; Okayasu, Y.; Yamada, Y.; Yuasa, J.; Aoki, S.
Inorganic Chemistry Vol. 59 page： 6905 - 6922 2020
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One-pot Synthesis of Cyclic Oligosaccharides by the Polyglycosylation of Monothioglycosides Reviewed
Someya, H.; Seki, T.; Ishigami, G.; Itoh, T.; Saga, Y.; Yamada, Y.; Aoki, S.
Carbohydrate Research Vol. 487 page： 10788 2020
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Yamada, Y; Morita, K; Mihara, N; Igawa, K; Tomooka, K; Tanaka, K
NEW JOURNAL OF CHEMISTRY Vol. 43 ( 29 ) page： 11477 - 11482 2019.8
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Yamada, Y; Sugiura, T; Morita, K; Ariga-Miwa, H; Tanaka, K
INORGANICA CHIMICA ACTA Vol. 489 page： 160 - 163 2019.4
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Site-Selective Supramolecular Complexation Activates Catalytic Ethane Oxidation by a Nitrido-Bridged Iron Porphyrinoid Dimer
Mihara Nozomi, Yamada Yasuyuki, Takaya Hikaru, Kitagawa Yasutaka, Igawa Kazunobu, Tomooka Katsuhiko, Fujii Hiroshi, Tanaka Kentaro
CHEMISTRY-A EUROPEAN JOURNAL Vol. 25 ( 13 ) page： 3369 - 3375 2019.3
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超分子型ポルフィリン・フタロシアニンface-to-face分子組織のプログラム構築とその機能化 Invited
山田 泰之
化学工業 Vol. 70 page： 208 - 218 2019
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Catalytic Methane Oxidation by Supramolecular Conjugate Based on mu-Nitrido-Bridged Iron Porphyrinoid Dimer Reviewed
Yamada, Y.*; Morita, K.; Mihara, N.; Igawa, K.; Tomooka, K.; Tanaka, K.
New Journal of Chemistry Vol. 43 page： 11477 - 11482 2019
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Improved Synthesis of Monocationic -Nitrido-Bridged Iron Phthalocyanine Dimer with No Peripheral Substituents Reviewed
Yamada, Y.*; Sugiura, T.; Morita, K.; Ariga-Miwa, H.; Tanaka, K.
Inorganica Chimica Acta Vol. 489 page： 160 - 163 2019
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Site-Selective Supramolecular Complexation Activates Catalytic Ethane-Oxidation of -Nitrido-Bridged Iron Porphyrinoid Dimer Reviewed
Mihara, N.; Yamada, Y.*; Takaya, H.; Kitagawa, Y.; Igawa, K.; Tomooka, K.; Fujii, H.; Tanaka, K.*
Chemistry, A European Journal Vol. 25 page： 3369 - 3375 2019
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Kawano, S; Yamada, Y; Shu, RF; Ishihara, Y; Tanaka, K
CHEMISTRY LETTERS Vol. 47 ( 10 ) page： 1262 - 1264 2018.10
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Yamada, Y; Nawate, K; Maeno, T; Tanaka, K
CHEMICAL COMMUNICATIONS Vol. 54 ( 59 ) page： 8226 - 8228 2018.7
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Programmable arrangement of metal ions in a cofacially stacked assembly of porphyrinoids toward molecular tags
Mihara Nozomi, Yamada Yasuyuki, Furukawa Ko, Kato Tatsuhisa, Tanaka Kentaro
DALTON TRANSACTIONS Vol. 47 ( 20 ) page： 7044 - 7049 2018.5
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Liquid-Crystalline Phthalocyanine with Short Intercolumnar Distance and Variation of the Liquid Crystallinity Induced by Square-Planar Metal Ions Reviewed
Kawano, S.; Yamada, Y.; Shu, R.; Ishihara, Y.; Tanaka, K.
Chemistry Letters Vol. 47 page： 1262 - 1264 2018
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Intramolecular Strong Electronic Coupling in a Discretely H-Aggregated Phthalocyanine Dimer Connected with a Rigid Linker Reviewed
Yamada, Y.; Nawate, K.; Maeno, T.; Tanaka, K.
Chemical Communications Vol. 54 page： 8226 - 8228 2018
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Programmable Arrangement of Metal Ions in a Cofacially Stacked Assembly of Porphyrinoids Reviewed
Mihara, N.; Yamada, Y.; Furukawa, K.; Kato, T.; Tanaka, K.
Dalton Transactions Vol. 47 page： 7044 - 7049 2018
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Dynamic Molecular Invasion into Multiply Interlocked Catenane Reviewed
Yamada, Y.; Itoh, R.; Ogino, S.; Kato, T.; Tanaka, K.
Angew. Chem. Int. Ed. Vol. 56 page： 14124–14129 2017.12
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Dynamic Molecular Invasion into a Multiply Interlocked Catenane
Yamada, Y; Itoh, R; Ogino, S; Kato, T; Tanaka, K
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 56 ( 45 ) page： 14124 - 14129 2017.11
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Oxygen Reduction to Water by Cofacial Dimer of Fe(III)porphyrin and Fe(III)phthalocyanine Linked via Highly Flexible Four-fold Rotaxane Reviewed
Mihara, N.; Yamada, Y.; Takaya. H.; Kitagawa, Y.; Aoyama, S.; Igawa, K.; Tomooka, K.; Tanaka, K.
Chem. Eur. J. Vol. 23 page： 7508-7514 2017.7
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Oxygen Reduction to Water by a Cofacial Dimer of Iron(III)-Porphyrin and Iron(III)- Phthalocyanine Linked through a Highly Flexible Fourfold Rotaxane
Mihara Nozomi, Yamada Yasuyuki, Takaya Hikaru, Kitagawa Yasutaka, Aoyama Shin, Igawa Kazunobu, Tomooka Katsuhiko, Tanaka Kentaro
CHEMISTRY-A EUROPEAN JOURNAL Vol. 23 ( 31 ) page： 7508 - 7514 2017.6
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Electronic Perturbation of Supramolecular Conjugates of Porphyrins and Phthalocyanine Reviewed
Mihara, N.; Yamada, Y.; Akine, S.; Sugimoto, K.; Tanaka, K.
Chem. Commun. Vol. 53 page： 2230-2232 2017.4
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Programmable Arrangement of Heterometal Ions in a Supramolecular Array of Porphyrin and Phthalocyanine
Mihara Nozomi, Yamada Yasuyuki, Tanaka Kentaro
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN Vol. 90 ( 4 ) page： 427 - 435 2017.4
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Programmable Arrangement of Heterometal Ions in a Supramolecular Array of Porphyrin and Phthalocyanine Reviewed
Mihara, N.; Yamada, Y.; Tanaka, K.
Bull. Chem. Soc. Jpn. Vol. 90 page： 427-435 2017.3
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Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines
Mihara, N; Yamada, Y; Akine, S; Sugimoto, K; Tanaka, K
CHEMICAL COMMUNICATIONS Vol. 53 ( 14 ) page： 2230 - 2232 2017.2
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Yamashita, K; Kohashi, K; Yamada, Y; Oda, Y; Toyokuni, S
MODERN PATHOLOGY Vol. 30 page： 27A - 27A 2017.2
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Yamashita, K; Kohashi, K; Yamada, Y; Oda, Y; Toyokuni, S
LABORATORY INVESTIGATION Vol. 97 page： 27A - 27A 2017.2
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Assembly of Multi-Phthalocyanines on a Porphyrin Template via Fourfold Rotaxane Formation Reviewed
Yamada, Y.; Kato, T.; Tanaka, K.
Chem. Eur. J. Vol. 22 page： 12371-12380 2016
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Crystalline Two-dimensional Nanosheet Composed of Tetraanionic Porphyrins and Tetracationic Metallomacrocycles Reviewed
Nishino, T.; Yamada, Y.; Tanaka, K.
J. Porphyr. Phthalocya. Vol. 20 page： 694-699 2016
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Stacked Pairing of Anionic Porphyrins on a Tetracationic Macrocyclic Template Reviewed
Nishino, T.; Yamada, Y.; Tanaka, K.
Chem. Lett. Vol. 45 page： 356-358 2016
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Kinetically Locked Metallomacrocycle Reviewed
Nishino, T.; Yamada, Y.; Sugimoto, K.; Akine, S.; Tanaka, K.
Dalton Trans. Vol. 45 page： 3831-3837 2016
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Metal-induced dynamic conformational and fluorescence switch of quinone-appended Zn-porphyri Reviewed
Yamada, Y.; Hiraga, K.; Tanaka, K.
Journal of Porphyrins and Phthalocyanines Vol. 19 page： 344-351 2015.4
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Crystal Structures of Stacked Ionic Assemblies of Tetracationic and Tetraanionic Porphyrins Invited Reviewed
Yamada, Y.; Matsumoto, S.; Yamada, K.; Nishino, T.; Mihara, N.; Sugimoto, K.; Tanaka, K.
Chemistry Letters Vol. 43 page： 1377-1379 2014
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Sequential and Spatial Organization of Metal Complexes Inside a Peptide Duplex Reviewed
Yamada, Y.; Kubota, T.; Nishio, M.; Tanaka, K.
Journal of the American Chemical Society Vol. 136 page： 6505-6509 2014
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ポルフィリン・フタロシアニンスタッキング会合体のプログラム構築 Invited Reviewed
山田 泰之
化学と工業 Vol. 67 page： 1074 - 1075 2014
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Repetitive Stepwise Rotaxane Formation toward programmable Molecular Arraying Reviewed
Yasuyuki Yamada, Masaaki Okada, Kentaro Tanaka
Chemical Communications Vol. 49 ( 94 ) page： 11053-11055 2013.11
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Metal-Induced Structural Switching of a Folded Quinone-Sandwiched Porphyrin Invited Reviewed
Yasuyuki Yamada, Kentaro Tanaka
Journal of Inorganic and Organometallic Polymers and Materials Vol. 23 page： 180-185 2013.1
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Synthesis of a Hetero-Dinuclear Metal Complex in a Porphyrin/Phthalocyanine Four-Fold Rotaxane Invited Reviewed
Yasuyuki Yamada, Nozomi Mihara, Kentaro Tanaka
Dalton Transactions Vol. 42 ( 45 ) page： 15873-15876 2013
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Triply Stacked Heterogeneous Array of Porphyrins and Phthalocyanine through Stepwise Formation of a Fourfold Rotaxane and an Ionic Complex Reviewed
Yasuyuki Yamada, Nozomi MIhara, Shinya Shibano, Kunihisa Sugimoto, Kentaro Tanaka
Journal of the American Chemical Society Vol. 135 ( 31 ) page： 11505-11508 2013
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pi-pi スタッキング相互作用と金属錯体形成が織りなす分子機能のハーモニー Invited Reviewed
山田 泰之、田中 健太郎
錯体化学会誌 Vol. 62 page： 12 - 28 2013
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Programmed arraying of metal complexes in a supramolecular system: Stacked assembly of porphyrin and phthalocyanine Invited
Tanaka, K.; Yamada, Y.
Spring-8 Research Frontiers page： 68 - 69 2013
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Room-Temperature Single Molecular Memory Reviewed
Shinya Kano, Yasuyuki Yamada, Kentaro Tanaka, Yutaka Majima
Applied Physics Letters Vol. 100 ( 5 ) page： 053101 2012.1
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Switchable Intermolecular Communication in a Four-Fold Rotaxane Reviewed
Yasuyuki Yamada, Mitsuhiro Okamoto, Ko Furukawa, Tatsuhisa Kato, Kentaro Tanaka
Angew. Chem. Int. Ed. Vol. 51 ( 3 ) page： 709–713 2012
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Design and Synthesis of a Fluorescent Probe for Zn2þ,5,7-Bis(N,N-dimethylaminosulfonyl)-8-hydroxyquinoline-Pendant1,4,7,10-Tetraazacyclododecane and Zn2þ-Dependent Hydrolytic andZn2þ-Independent Photochemical Reactivation of Its Benzenesulfonyl-CagedDerivative Reviewed
Ryosuke Ohshima, Masanori Kitamura, Akinori Morita, Motoo Shiro,Yasuyuki Yamada, Masahiko Ikekita,Eiichi Kimura, and Shin Aoki
Inorganic Chemistry Vol. 49 page： 888-899 2010.2
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Photochemical Cleavage Reactions of 8-Quinolinyl Sulfonates in AqueousSolution Reviewed
Yoshiyuki KAGEYAMA, Ryosuke OHSHIMA, Kazusa SAKURAMA, Yoshihisa FUJIWARA, Yoshifumi TANIMOTO, Yasuyuki YAMADA, and Shin AOKI
Chemical and Pharmaceutical Bulletin Vol. 57 ( 11 ) page： 1257-1266 2009.11
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Chiral Catalysts Dually Functionalized with Amino Acid and Zn2+ ComplexComponents for Enantioselective Direct Aldol Reactions Inspired by NaturalAldolases: Design, Synthesis, Complexation Properties, Catalytic Activities,and Mechanistic Study Reviewed
Susumu Itoh, Masanori Kitamura, Yasuyuki Yamada, and Shin Aoki
Chemistry, A European Journal Vol. 15 ( 40 ) page： 10570-10584 2009.9
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Design and synthesis of a photocleavable biotin-linker for the photoisolation of ligand–receptor complexes based on the photolysis of 8-quinolinyl sulfonates in aqueous solution Reviewed
Shin Aoki, Nanako Matsuoa, Kengo Hanayaa, Yasuyuki Yamada, Yoshiyuki Kageyama
Bioorganic and Medicinal Chemistry Vol. 17 ( 9 ) page： 3405–3413 2009.5
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*Photolysis of the Sulfonamide Bond of Metal Complexes of N-Dansyl-1,4,7,10-Tetraazacyclododecane in Aqueous Solution: A Mechanistic Studyand Application to the Photorepair of cis,syn-Cyclobutane ThyminePhotodimer Reviewed
Shin Aoki, Yumiko Tomiyama, Yoshiyuki Kageyama, Yasuyuki Yamada, Motoo Shiro, Eiichi Kimura
Chemistry-An Asian Journal Vol. 9 ( 4 ) page： 561-573 2009.4
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*BODIPY-Based Fluorescent Redox Potential Sensors that Utilize Reversible Redox Properties of Flavin Reviewed
Yasuyuki Yamada, Yumiko Tomiyama, Akinori Morita, Masahiko Ikekita, and Shin Aoki
ChemBioChem Vol. 9 page： 853–856 2008.4
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Design and Synthesis of A Caged Zn2+ Probe, 8-Benzenesulfonyloxy-5-N,N-dimethylaminosulfonylquinolin-2-ylmethyl-pendant 1,4,7,10-Tetraazacyclododecane, and Its Hydrolytic Uncaging upon Complexation with Zn2+ Reviewed
Shin Aoki, Kazusa Sakurama, Ryosuke Ohshima, Nanako Matsuo, Yasuyuki Yamada, Ryoko Takasawa, Sei-ishi Tanuma, and Eiichi Kimura
Inorganic Chemistry Vol. 47 page： 2747–2754 2008.4
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光照射によって進行する二重結合化合物の化学反応
山田 泰之、青木 伸
化学と教育 Vol. 55 ( 2 ) page： 84-87 2007.2
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光照射によって進行する二重結合化合物の化学反応 Invited Reviewed
山田 泰之、青木 伸
化学と教育 Vol. 55 page： 84 - 87 2007
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A New Fluorescent Probe for Zinc(II): An 8-Hydroxy-5-N, N'-dimethylaminosulfonylquinoline-Pentdant 1,4,7,10-Tetraazacyclododecane Reviewed
Shin Aoki, Kazusa Sakurama, Nanako Matsuo, Yasuyuki Yamada, Ryoko Takasawa, Sei-ichi Tanuma, Motoo Shiro, Kei Takeda, Eiichi Kimura
Chemistry - A European Journal Vol. 12 ( 35 ) page： 9066-9080 2006.12
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*Programmable self-assembly of metal ions inside artificial DNA duplexes Reviewed
Kentaro Tanaka, Guido H. Clever, Yusuke Takezawa, Yasuyuki Yamada, Corinna Kaul, Mitsuhiko Shionoya, Thomas Carell
Nature Nanotechnology Vol. 1 ( 3 ) page： 190-194 2006.12
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*Efficient cycloreversion of cis,syn-thymine photodimer by a Zn2+-1,4,7,10-tetraazacyclododecane complex bearing a lumiflavin and tryptophan by chemical reduction and photoreduction of a lumiflavin unit Reviewed
Yasuyuki Yamada, Shin Aoki
Journal of Biological Inorganic Chemistry Vol. 11 ( 8 ) page： 1007-1023 2006.11
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Artificial metallo-DNA: structural control and discrete metal assembly Reviewed
Tanaka, K.; Yamada, Y.; Tengeiji, A.; Kato, T.; Toyama, N.; Takezawa, Y.; Yori, M.; Shiro, M.; Shionoya, M.
Nucleic Acids Research Supplement Vol. 3 page： 121-122 2003
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*Formation of Silver(I)-Mediated DNA Duplex and Triplex through an Alternative Base Pair of Pyridine Nucleobases Reviewed
Tanaka, K.; Yamada, Y.; Shionoya, M.
Journal of the American Chemical Society Vol. 124 page： 8802-8803 2002
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Synthesis of a new bis(ferrocenyl)ruthenacyclopentatriene compound with a significant intermetal electronic communication Reviewed
Yamada, Y.; Mizutani, J.; Kurihara, M.; Nishihara, H.
Journal of Organometallic Chemistry Vol. 637-639 page： 80-83 2001
Books 1
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メタンと二酸化炭素〜その触媒的科学変換技術の現状と展望〜
山田 泰之（ Role： Contributor , 担持型金属錯体触媒によるメタン過酸化水素酸化）
シーエムシー・リサーチ 2023
Presentations 24
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高活性メタン酸化触媒創製に超分子化学の発想で挑む Invited
山田 泰之
第56回酸化反応討論会 2023.11.11
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Direct Observation of Elecrtrochemically Generated High-Valent Iron-Oxo Species That can be Utilized for CH4 Oxidation Reaction Invited International conference
Yamada, Y. and Nagasaka. M.
UVSOR–III+MAX IV International Workshop “Frontier of Soft X-ray Spectroscopy for Chemical Processes in Solutions” 2023.10.3
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How to Utilize Supramolecular Methodology for Achieving Highly Potent Artificial Oxygenase Invited
Yasuyuki Yamada
錯体化学会第73回討論会シンポジウム”Designer Metalloenzyme and Beyond” 2023.9.21
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担持型鉄錯体触媒によるメタン酸化〜超分子化学の発想に基づいて人工メタン酸化分子触媒の活性を天然酵素のレベルにまで高める〜 Invited
山田 泰之
2022年度高難度選択酸化反応研究会シンポジウム 2023.1.20 触媒学会
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Development of Highly Potent Methane Oxidation Catalyst Based on Double-Decker-Type Iron Porphyrinoids Invited International conference
Yamada, Y.
10th Asian Biological Inorganic Chemistry Conference (ASBIC10) 2022.12.2
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Highly Potent Methane Oxidation Catalyst Achieved by Close Stacking of Double-Decker-Type Iron Phthalocyanine Complex on Graphite Surface Invited
Yamada, Y.
International Congress on Pure & Applied Chemistry Kota Kinabalu 2022 (ICPAC KK 2022) 2022.11.24
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Potent Methane Oxidation Catalyst Achieved by Close Stacking of Double-Decker-Type Iron Phthalocyanine Complex on Graphite Surface Invited
Yamada, Y.
8th Asian Conference on Coordination Chemistry (ACCC8) 2022.8.8
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Supramolecular Approach to Achieve Highly Reactive Catalyst for Direct C–H Activation of Methane Invited International conference
Yamada, Y.; Sugiura, T.; Morita, K.; Mihara, N.; Tanaka, K.
Pacifichem 2021 2021.12.19 Pacifichem 2021
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Supramolecular Approach towards potent molecule-based methane oxidation catalyst Invited International conference
Yasuyuki Yamada
The 4th Workshop of the Reaction Infography (R–ing) Unit 2021.11.5 the Reaction Infography (R–ing) Unit, Nagoya University
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分子組織化学の発想でつくる超強力酸化触媒 Invited
山田 泰之
第17回アカデミックナイト 2021.10.14 ナゴヤイノベーターズガレージ
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ダブルデッカー型フタロシアニン錯体メタン酸化触媒のグラファイト上へのスタッキングによる高活性化
山田 泰之、森田 健太郎、杉浦 琢哉、豊田 結香、長坂 将成、辻 雄太、吉澤 一成、田中 健太郎
錯体化学会第71回討論会 2021.9.17 錯体化学会
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Supramolecular Approach to Increase the Catalytic Light Alkane Oxidation Activities of μ-Nitrido Bridged Iron Porphyrinoid Dimer Invited International conference
Yamada, Y.; Mihara, N.; Morita, K.; Tanaka, K.
11th International Conference on Porphyrins & Phthalocyanines (ICPP-11) 2021.6.29 Society of Porphyrins and Phthalocyanines
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ダブルデッカー型フタロシアニン錯体のグラファイト表面へのスタッキングに基づく高活性メタン酸化触媒の合成
山田 泰之、豊田 結香、杉浦 琢哉、森田 健太郎、杉浦 琢哉、長坂 将成、田中 健太郎
第18回ホストーゲスト・超分子化学シンポジウム 2021.6.27 ホストーゲスト・超分子化学研究会
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一次元金属錯体アレイの分子プログラミング法の開発
山田 泰之
生体機能関連化学部会 第２５回 若手フォーラム
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Supramolecular Photochemistry Based on the Photophysical Properties of Flavins International conference
JSPS-DFG Japanese-German Graduate Externship Lecture
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My academic career
1st. Global COE International Symposium
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Inhibition of complexation of DNA with transcription factor, NF-kappaB by a heteromultinuclear complex
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Design and synthesis of a fluorescent probe for the redox potential invivo by using the redox property of flavin
Asian international symposium in 87th national meeting of the chemical society of Japan
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人工DNA光修復酵素の設計と合成
山田 泰之、青木 伸
平成18年度若手研究者のためのセミナー
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白金ー亜鉛複核錯体による配列特異的核酸塩基修飾を利用した転写因子NF-kappaB-DNA複合体の形成阻害
山田 泰之、鈴木 友紀子、岡谷 理恵子、中村 幹彦、青木 伸
バイオ関連化学合同シンポジウム
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Photorepair of a cis-syn cyclobutane thymine photodimer by a flavin-tryptophan-appended Zn2+-cyclen complex
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Zn2+－Cyclenを利用した人工DNAフォトリアーゼの開発
第55回錯体化学討論会
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シクロブタン型チミンダイマーを光修復するペプチド型人工DNAフォトリアーゼの開発
山田 泰之、青木 伸
第3回次世代を担う有機化学シンポジウム
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Zn2+-cyclenを利用した人工フラビン酵素の開発
山田 泰之、青木 伸
日本薬学会第125年会
Research Project for Joint Research, Competitive Funding, etc. 2
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超強力酸化触媒による有機系環境汚染物質分解技術の開発
2023.9 - 2024.8
指定共同研究
Authorship：Principal investigator Grant type：Collaborative (industry/university)
Grant amount：\20000000
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新奇な超分子型遷移金属オキソ種を酸化活性種とするメタン直接変換触媒の創製
2017.10 - 2021.9
さきがけ
Authorship：Principal investigator Grant type：Competitive
（ Direct Cost: \46020000 、 Indirect Cost：\13816000 ）
KAKENHI (Grants-in-Aid for Scientific Research) 6
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超分子型ポルフィリノイド分子組織をベースにした新奇高反応性cPCET活性種の探索
Grant number：22K19045 2022.6 - 2024.3
日本学術振興会 科学研究費助成事業 挑戦的研究(萌芽)
山田 泰之
Authorship：Principal investigator Grant type：Competitive
Grant amount：\6370000 （ Direct Cost: \4900000 、 Indirect Cost：\1470000 ）
応募者らは最近、４重ロタキサン結合により連結されたポルフィリンとフタロシアニンのface-to-face会合体内に構築した窒素架橋鉄二核錯体とテトラアニオン性ポルフィリンとのイオン性会合体 T が過剰量のH2O2を含む100°C以下の酸性水溶液中、メタンを触媒的にメタノール、ホルムアルデヒド、ギ酸へと変換可能であり、数あるメタン酸化分子触媒の中でも最高クラスの触媒活性を示すことを見出した。
本研究ではTの超分子骨格を利用しつつ、Tの中心金属および架橋配位子を変化させた新奇な構造を持つ超分子型cPCET活性種を構築して、高活性なメタン資源化反応活性種を探索する。 -
難分解性有機物資源化を可能にするグラファイト担持型超強力酸化触媒活性種の開発
Grant number：22H02156 2022.4 - 2025.3
科学研究費助成事業 基盤研究(B)
山田 泰之, 長坂 将成
Authorship：Principal investigator
Grant amount：\17550000 （ Direct Cost: \13500000 、 Indirect Cost：\4050000 ）
下記(A), (B)2つの課題を、超分子化学・錯体化学・電気化学・軟X線分光の技術を駆使してクリアすることで、水溶液中において難分解性有機物を酸化的に分解して有用有機物を与える「難分解性有機物資源化触媒反応活性種」を開発する。
(A) 疎水性反応場を持つ「二階建て型鉄二核錯体触媒」を方向選択的にグラファイト電極上に吸着させる技術の開発。
(B) グラファイト電極上に吸着させた触媒分子を水溶液中で電解酸化することで酸化反応活性種を生成させ、分解反応に用いる。 -
Grant number：19H02787 2019.4 - 2022.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B)
Yamada Yasuyuki
Authorship：Principal investigator
Grant amount：\17680000 （ Direct Cost: \13600000 、 Indirect Cost：\4080000 ）
We attempted to fabricate molecular machines based on the porphyrin/phthalocyanine face-to-face molecular conjugates connected through fourfold rotaxane structures. As a result of this research, the following finding which is considered to be useful for the future design of molecular machines were obtained. "Generally, an alkyl chain is considered to be a flexible molecular linker. Although a sufficiently long alkyl chain behaves flexibly like a molecular string, a short alkyl chain sometimes behaves like a molecule-sized scale because of the intrinsic rigidity."
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Development of innovative molecular devices based on molecular inclusion reaction
Grant number：16K13961 2016.4 - 2019.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Challenging Exploratory Research
Yamada Yasuyuki, Itoh Ryosuke, Ogino Sayaka, Mihara Nozomi, Nawate Katsuhiko, Maeno Tomoaki, Furukawa Ko, Kato Tatsuhisa, Akine Shigehisa, Sugimoto Kunihisa, Shimokawa Koya, Igawa Kazunobu, Tomooka Katsuhiko, Tanaka Kentaro
Authorship：Principal investigator
Grant amount：\3770000 （ Direct Cost: \2900000 、 Indirect Cost：\870000 ）
We synthesized a multiply interlocked molecular assembly (M) with a novel topological structure in which a cofacial porphyrin dimer connected with four alkylammonium chains is quadruply interlocked by a phthalocyanine bearing four peripheral crown ethers. Since M has such a flexible structure that an alternative addition of an appropriate acid and a base resulted in its dynamic conformational change. It was demonstrated that M incorporates π-planer anions in its two isolated nanospaces in between a porphyrin and a phthalocyanine. It was also found that M showed unique molecular inclusion behavior in which a central phthalocyanine moves like a “slide door” to capture a guest molecule. This behavior is quite similar to the “induced fit” found in natural enzymes.
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Molecular architecture of molecular spaces through self-assembly
Grant number：15H02167 2015.4 - 2018.3
Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A)
Tanaka Kentaro, Yamada Yasuyuki, Kawano Shin-ichiro
Authorship：Collaborating Investigator(s) (not designated on Grant-in-Aid)
The aim of this study was generation of emerging flexible molecular functions through formation of dimentionally-controled discrete or consecutive molecular spaces in molecular assemblies constructed via self-assembly. We have obtained the research findings listed below. 1) Invention of stimuli-responsive spin arrays and molecular reaction fields which were formed by reversible self-assembly reactions. 2) Invention of novel liquid crystals of macrocyclic mesogens. 3) Two-dimensional molecular assemblies to form novel electronic materials and molecular recognition sites. 4) Invention of discrete three-dimensional molecular spaces surrounded by pai-conjugated walls as molecular recognition sites.
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ロタキサン型ポルフィリンーフタロシアニンスタッキングアレイの構築と機能化
2013.4 - 2016.3
科学研究費補助金 基盤研究(C)
Industrial property rights 1
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Redox-sensitive fluorescent compounds and isoalloxazine derivatives as one of them
Teaching Experience (On-campus) 1
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化学基礎II
2015