Updated on 2024/09/30

写真a

 
AWAGA, Kunio
 
Organization
Graduate School of Science Professor
Graduate School
Graduate School of Science
Undergraduate School
School of Science Department of Chemistry
Title
Professor
Profile
1988 D.S., Univ. of Tokyo
1988 Assistant Professor, Institute of Molecular Science
1992 Associate Professor, Department of Pure and Applied Science, University of Tokyo
2001 Professor, Department of Chemistry, Graduate School of Science, Nagoya University
2004 Professor, Research Center for Materials Science, Nagoya University
2013-17 Director, Professor, Research Center for Materials Science, Nagoya University
2014 Professor, Department of Chemistry, Graduate School of Science, Nagoya University
2019-22 Dean, Graduate School of Science, Nagoya University
2022 Director, Institute for Advanced Research, Nagoya University

Degree 1

  1. 理学博士 ( 1988.3 ) 

Research Areas 3

  1. Natural Science / Semiconductors, optical properties of condensed matter and atomic physics  / Solid state physics

  2. Nanotechnology/Materials / Fundamental physical chemistry  / Physical Chemistry

  3. Nanotechnology/Materials / Functional solid state chemistry  / Materials Chemistry

Current Research Project and SDGs 7

  1. 有機エレクトロニクス・スピントロニクス

  2. 強相関分子系の新しい有機エレクトロニクス

  3. ナノラジカル界面からの電子機能発現

  4. 固体電気化学プロセスから発現する新しいエネルギーおよび情報変換

  5. 分子性強等方性構造の化学構築と機能開拓

  6. K4分子結晶化学の構築

  7. Study on Molecular Magnetism

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Research History 8

  1. 名古屋大学大学院理学研究科   部長(学部長・研究科長)

    2019.4 - 2022.3

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    Country:Japan

  2. 名古屋大学大学院理学研究科物質理学専攻化学系   教授

    2014.12

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    Country:Japan

  3. 名古屋大学物質科学国際研究センター   所長(センター長)

    2013.4 - 2017.3

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    Country:Japan

  4. 名古屋大学物質科学国際研究センター   教授

    2005.10 - 2014.11

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    Country:Japan

  5. 名古屋大学大学院理学研究科物質理学専攻化学系   教授

    2001.4 - 2005.9

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    Country:Japan

  6. 東京大学大学院総合文化研究科広域科学専攻相関基礎科学系   助教授

    1995.4 - 2001.3

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    Country:Japan

  7. 東京大学教養学部基礎科学科第一   助教授

    1992.4 - 1995.3

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    Country:Japan

  8. 岡崎国立共同研究機構分子科学研究所   助手

    1988.3 - 1992.3

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    Country:Japan

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Education 2

  1. The University of Tokyo   Graduate School, Division of Science

    - 1988.2

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    Country: Japan

  2. The University of Tokyo   Faculty of Science

    - 1983.3

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    Country: Japan

Professional Memberships 7

  1. 日本化学会   物理化学ディビジョン監事

    2006.4

  2. 日本物理学会

  3. 電子スピンサイエンス学会   理事

    2005.4 - 2006.3

  4. 分子科学会   会長

    2012.9 - 2014.8

  5. 分子科学会   副会長

    2010.9 - 2012.8

  6. 有機スピントロニクス国際研究集会   国際アドバイザリーボード

    2009.4

  7. 日本化学会 物理化学ディビジョン   幹事

    2006.4 - 2008.3

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Committee Memberships 6

  1. 大学評価・学位授与機構   大学機関別認証評価委員会専門委員  

    2022.4 - 2023.3   

  2. 大学評価・学位授与機構   大学機関別認証評価委員会  

    2021.4 - 2022.3   

  3. 大学評価・学位授与機構   大学機関別認証評価各種委員  

    2019.4 - 2020.3   

  4. 大学評価・学位授与機構   国立大学教育研究評価委員会専門委員  

    2018.10 - 2019.9   

  5. 大学評価・学位授与機構   「理学系検討会」委員  

    2014.10 - 2016.9   

  6. 日本学術会議   連携会員  

    2012.4   

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Awards 6

  1. 日本化学会賞

    2024.1   日本化学会  

  2. 分子科学会賞

    2020   日本分子科学会  

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    Country:Japan

  3. 日本化学会学術賞

    2012   日本化学会  

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    Country:Japan

  4. 日本IBM科学賞

    2003  

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    Country:Japan

  5. 分子科学研究奨励森野基金

    2001  

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    Country:Japan

  6. 日本化学会進歩賞

    1994  

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    Country:Japan

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Papers 253

  1. Unveiling π-π interactions in triptycene-phenazine/SWCNT redox chemistry using ESR spectroscopy

    Qi Chen, Rie Suizu, Yoshiaki Shuku, Haruka Omachi, Michio M. Matsushita, Shuta Fukuura, Takashi Yumura, Shunji Bandow, Kunio Awaga

    Journal of Materials Chemistry A   Vol. 12 ( 36 )   2024.9

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Grasping the intricate π–π interactions between redox-active organic materials and conductive carbons is key to optimizing the performance of organic electrodes in energy storage devices. However, their precise role in...

    DOI: 10.1039/d4ta04176c

    Web of Science

  2. Chiral Honeycomb Lattices of Nonplanar π-Conjugated Supramolecules with Protected Dirac and Flat Bands

    Ryohei Nemoto, Ryuichi Arafune, Saya Nakano, Masahisa Tsuchiizu, Noriaki Takagi, Rie Suizu, Takashi Uchihashi, Kunio Awaga

    ACS Nano   Vol. 18 ( 30 ) page: 19663 - 19671   2024.7

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsnano.4c04496

    Web of Science

    PubMed

  3. Optoelectronic conversion and polarization hysteresis in organic MISM and MISIM devices with DA-type single-component molecules

    Akihiro Tomimatsu, Rie Suizu, Miyabi Nakazawa, Takashi Shirahata, Yohji Misaki, Naoya Kinoshita, Kunio Awaga

    Faraday Discussions   Vol. 250 ( 0 ) page: 96 - 109   2024.3

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    We fabricated MISM and MISIM devices using DA-type single-component molecules as the S layer and examined their photocurrent and polarization hysteresis.

    DOI: 10.1039/d3fd00125c

    Web of Science

    PubMed

  4. Optoelectronic conversion and polarization hysteresis in organic MISM and MISIM devices with DA-type single-component molecules Invited Reviewed

    Tomimatsu, A; Suizu, R; Nakazawa, M; Shirahata, T; Misaki, Y; Kinoshita, N; Awaga, K

    FARADAY DISCUSSIONS   Vol. 250   page: 96 - 109   2024.3

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    Authorship:Corresponding author   Language:English  

    DOI: https://doi.org/10.1039/d3fd00125c

  5. Critical transition to a highly conductive state through PEDOT oligomer percolation in redox-active COFs

    Cao, CQ; Chen, Q; Suizu, R; Awaga, K

    JOURNAL OF MATERIALS CHEMISTRY C   Vol. 12 ( 9 ) page: 3072 - 3076   2024.2

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    Authorship:Last author, Corresponding author  

    DOI: 10.1039/d3tc04794f

    Web of Science

  6. Synthesis of a novel triptycene-derived protected dithiolene ligand precursor for tri-nuclear mixed ligand metal dithiolene complexes

    Ali Wang, Yoshiaki Shuku, Rie Suizu, Neil Robertson, Kunio Awaga

    Chemistry Letters   Vol. 53 ( 2 )   2024.2

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    Publishing type:Research paper (scientific journal)   Publisher:Oxford University Press (OUP)  

    Abstract

    We synthesized a novel triptycene analogue, 3,3′,3″,3″′,3″″,3″″′-((triptycene-2,3,6,7,14,15-hexayl)hexakis(sulfanediyl))hexapropanenitrile (3), which served as a valuable precursor for the triptycene-derived tris-bidentate bridging dithiolene ligand, triptycene-2,3,6,7,14,15-hexakis(thiolate) (4), following the removal of the cyanoethyl moiety protection group. We determined the molecular and crystal structures of compound 3 and confirmed its capacity to yield compound 4. By reacting 3 with [NiCl2(BPY)] and [PtCl2(BPY)] (BPY: 2,2′-bipyridine) in methanol, we obtained crude samples of [Ni3(4)(BPY)3] and [Pt3(4)(BPY)3], respectively.

    DOI: 10.1093/chemle/upad051

    Web of Science

    Other Link: https://academic.oup.com/chemlett/article-pdf/53/2/upad051/56742344/upad051.pdf

  7. X-ray crystallographic analysis of the antiferromagnetic low-temperature phase of galvinoxyl: investigating magnetic duality in organic radicals

    Suizu, R; Shuku, Y; Robert, V; Roseiro, P; Ben Amor, N; Khawar, Z; Robertson, N; Awaga, K

    DALTON TRANSACTIONS   Vol. 53 ( 5 )   2024.1

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    DOI: 10.1039/d3dt03601d

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    PubMed

  8. Ideal trigonal prismatic coordination geometry of Co(<scp>ii</scp>) in a honeycomb MOF with a triptycene-based ligand

    Yoshiaki Shuku, Rie Suizu, Masahisa Tsuchiizu, Kunio Awaga

    Chemical Communications   Vol. 59 ( 67 ) page: 10105 - 10108   2023.8

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    Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    An ideal trigonal prismatic coordination geometry was achieved in the honeycomb metal–organic framework comprised of Co ions and triptycene-based bridging ligands.

    DOI: 10.1039/d3cc02986g

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    PubMed

  9. Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

    Chen, Q; Zhang, ZY; Awaga, K

    JOVE-JOURNAL OF VISUALIZED EXPERIMENTS   ( 196 )   2023.6

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    DOI: 10.3791/65335

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    PubMed

  10. Engineering Dirac cones and topological flat bands with organic molecules

    Yoshiaki Shuku, Rie Suizu, Saya Nakano, Masahisa Tsuchiizu, Kunio Awaga

    Physical Review B   Vol. 107 ( 15 )   2023.4

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    Publishing type:Research paper (scientific journal)   Publisher:American Physical Society (APS)  

    DOI: 10.1103/PhysRevB.107.155123

    Web of Science

    Other Link: http://harvest.aps.org/v2/journals/articles/10.1103/PhysRevB.107.155123/fulltext

  11. Enhanced Circularly Polarized Luminescence by a Homochiral Guest–Host Interaction in Gyroidal MOFs, [Ru(bpy)<sub>3</sub>] [M<sub>2</sub>(ox)<sub>3</sub>] (bpy = 2,2′-Bipyridyl, ox = Oxalate, M = Zn, Mn) Invited Reviewed

    Kazuya Nakashima, Rie Suizu, Shuhei Morishita, Noriaki Tsurumachi, Masahiro Funahashi, Hyuma Masu, Ryuki Ozawa, Kazuki Nakamura, Kunio Awaga

    ACS Materials Au   Vol. 3 ( 3 ) page: 201 - 205   2023.3

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsmaterialsau.2c00081

    DOI: 10.1021/acsmaterialsau.2c00081

    Web of Science

    PubMed

  12. Fabrication of MXene transparent conductive films via transfer process Invited Reviewed

    Yuki Shibata, Rie Suizu, Kunio Awaga, Jun Hirotani, Haruka Omachi

    Applied Physics Express   Vol. 16 ( 3 )   2023.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.35848/1882-0786/acbbb8

    Web of Science

  13. Isomeric Triptycene Triquinones as Universal Cathode Materials for High Energy Alkali Metal Batteries

    Park, H; Shuku, Y; Lee, J; Lee, K; Min, DJ; An, BK; Awaga, K; Park, SY; Kwon, JE

    BATTERIES & SUPERCAPS   Vol. 6 ( 3 )   2023.3

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    DOI: 10.1002/batt.202200497

    Web of Science

  14. Graphite-like Charge Storage Mechanism in a 2D π–d Conjugated Metal–Organic Framework Revealed by Stepwise Magnetic Monitoring

    Qi Chen, Olugbenga Adeniran, Zhen-Fei Liu, Zhongyue Zhang, Kunio Awaga

    Journal of the American Chemical Society   Vol. 145 ( 2 ) page: 1062 - 1071   2023.1

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.2c10650

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  15. Graphite-like Charge Storage Mechanism in a 2D?-d Conjugated Metal-Organic Framework Revealed by Stepwise Magnetic Monitoring

    Chen, Q; Adeniran, O; Liu, ZF; Zhang, ZY; Awaga, K

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY     2023.1

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    DOI: 10.1021/jacs.2c1065

    Web of Science

  16. Synthesis of Isomeric Tb3+-Phthalocyanine Double-Decker Complexes Depending on the Difference in the Direction of Coordination Plane and Their Magnetic Properties

    Yasuyuki Yamada, Hiroaki Nakajima, Chisa Kobayashi, Yoshiaki Shuku, Kunio Awaga, Shigehisa Akine, Kentaro Tanaka

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 29 ( 1 )   2023.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY-V C H VERLAG GMBH  

    A C-4h symmetrically substituted phthalocyanine, 1,8,15,22-tertrakis(2,4-dimethylpent-3-oxy)phthalocyanine (H(2)TdMPPc), was used to synthesize Tb3+-phthalocyanine double-decker complexes ([Tb(TdMPPc)(2)]s). Because H(2)TdMPPc has C-4h symmetry, S,S, R,R, and meso isomers of [Tb(TdMPPc)(2)] were obtained depending on the difference in the direction of the coordination plane of two C-4h-type phthalocyanines with respect to a central Tb3+ ion. We investigated the physical properties of these [Tb(TdMPPc)(2)] isomers, including their single-ion magnetic properties, and found that the spin-reversal energy barrier (U-eff) of the meso isomer was apparently higher than that of the enantiomers. Detailed crystal structural analyses indicated that the meso isomer has a more symmetrical structure than do the enantiomers, thereby suggesting that the higher U-eff of the meso isomer originated from the more highly symmetrical structure.

    DOI: 10.1002/chem.202203272

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    PubMed

  17. CNT Gels Formed by a Triptycene Analogue Enabling Coexistence of CNT-gelator and Intergelator Interactions

    Ryo Ushiroguchi, Rie Suizu, Yuki Matsunaga, Haruka Omachi, Yuya Doi, Yuichi Masubuchi, Shunji Bandow, Kunio Awaga

    Chemistry Letters   Vol. 51 ( 11 ) page: 1070 - 1073   2022.11

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    Publishing type:Research paper (scientific journal)   Publisher:The Chemical Society of Japan  

    DOI: 10.1246/cl.220319

    Web of Science

  18. Duty-cycle dependence of photo-induced displacement current in MISIM photocells Reviewed

    Akihiro Tomimatsu, Seiya Yokokura, Kunio Awaga

    Organic Electronics   Vol. 109   page: 106632 - 106632   2022.10

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier {BV}  

    DOI: 10.1016/j.orgel.2022.106632

    Web of Science

  19. N-doped nonalternant aromatic belt <i>via</i> a six-fold annulative double N-arylation

    Hiroki Sato, Rie Suizu, Tomoki Kato, Akiko Yagi, Yasutomo Segawa, Kunio Awaga, Kenichiro Itami

    Chemical Science   Vol. 13 ( 34 ) page: 9947 - 9951   2022.8

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    Nitrogen-doped nonalternant aromatic belt was synthesized via palladium-catalyzed six-fold annulative double N-arylation reaction. The highly symmetric structure and multistep oxidation behavior of the N-belt were confirmed.

    DOI: 10.1039/d2sc02647c

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    PubMed

  20. Improvement in Cycle Life of Organic Lithium-Ion Batteries by In-Cell Polymerization of Tetrathiafulvalene-Based Electrode Materials

    Aya Yoshimura, Keisuke Hemmi, Hayato Moriwaki, Ryo Sakakibara, Hitoshi Kimura, Yuto Aso, Naoya Kinoshita, Rie Suizu, Takashi Shirahata, Masaru Yao, Hideki Yorimitsu, Kunio Awaga, Yohji Misaki

    ACS Applied Materials & Interfaces   Vol. 14 ( 31 ) page: 35978 - 35984   2022.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acsami.2c09302

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    PubMed

  21. Salt-Assisted Pyrolysis of Covalent Organic Framework for Controlled Active Nitrogen Functionalities for Oxygen Reduction Reaction

    Charles-Blin, Y; Kondo, T; Wu, Y; Bandow, S; Awaga, K

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   Vol. 95 ( 6 ) page: 972 - 977   2022.6

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    Authorship:Last author, Corresponding author   Language:Japanese  

    DOI: 10.1246/bcsj.20220094

    Web of Science

  22. Exfoliation of Al-Residual Multilayer MXene Using Tetramethylammonium Bases for Conductive Film Applications. International journal

    Emi Saita, Masaki Iwata, Yuki Shibata, Yuki Matsunaga, Rie Suizu, Kunio Awaga, Jun Hirotani, Haruka Omachi

    Frontiers in chemistry   Vol. 10   page: 841313 - 841313   2022.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    This study describes the concise exfoliation of multilayer Ti3C2T x MXene containing residual aluminum atoms. Treatment with tetramethylammonium base in a co-solvent of tetrahydrofuran and H2O produced single-layer Ti3C2T x , which was confirmed via atomic force microscopy observations, with an electrical conductivity 100+ times that of Ti3C2T x prepared under previously reported conditions. The scanning electron microscopy and X-ray diffraction measurements showed that the exfoliated single-layer Ti3C2T x MXenes were reconstructed to assembled large-domain layered films, enabling excellent macroscale electric conductivity. X-ray photoelectron spectroscopy confirmed the complete removal of residual Al atoms and the replacement of surface fluorine atoms with hydroxy groups. Using the exfoliated dispersion, a flexible transparent conductive film was formed and demonstrated in an electrical application.

    DOI: 10.3389/fchem.2022.841313

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    PubMed

  23. Line graph theory reveals hidden spin frustration and bond frustration in molecular crystals with strong isotropy Reviewed

    Rie Suizu, Kunio Awaga

    Journal of Materials Chemistry C   Vol. 10 ( 4 ) page: 1196 - 1203   2022.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d1tc05161j

    Web of Science

  24. 3D supramolecular chiral crystal structures of radical anion salts of (−)-NDI-Δ and possible magnetic phase diagrams

    Asato Mizuno, Yoshiaki Shuku, Rie Suizu, Masahisa Tsuchiizu, Kunio Awaga

    CrystEngComm   Vol. 23 ( 29 ) page: 5053 - 5059   2021.8

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Supramolecular chiral crystals of radical anion salts of a triangular chiral electron acceptor, (−)-naphthalene diimide (NDI)-Δ, were electrochemically grown in propylene carbonate electrolyte solutions in the presence of cyclic multidentate ligands.</p>

    DOI: 10.1039/d1ce00628b

    Web of Science

  25. Stabilization of Interfacial Polarization and Induction of Polarization Hysteresis in Organic MISIM Devices Reviewed

    Seiya Yokokura, Akihiro Tomimatsu, Jun Ishiguro, Jun Harada, Haruka Takahashi, Yukihiro Takahashi, Yuto Nakamura, Hideo Kishida, Rie Suizu, Michio M. Matsushita, Kunio Awaga

    ACS Applied Materials & Interfaces   Vol. 13 ( 27 ) page: 31928 - 31933   2021.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society ({ACS})  

    DOI: 10.1021/acsami.1c08417

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  26. Evaluating the high-pressure structural response and crystal lattice interactions of the magnetically-bistable organic radical TTTA

    Jonathan G. Richardson, Asato Mizuno, Yoshiaki Shuku, Kunio Awaga, Neil Robertson, Carole A. Morrison, Mark R. Warren, David R. Allan, Stephen A. Moggach

    CrystEngComm   Vol. 23 ( 25 ) page: 4444 - +   2021.7

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    Magnetic bistability has previously been observed and evaluated in an organic thiazyl radical 1,3,5-triathia-2,4,6-triazapentalenyl (TTTA). Herein, the structure-pressure response of TTTA has been evaluated by X-ray diffraction, where a lack of a structural phase transition up to 4.6 GPa certifies that the paramagnetic suppression is caused by a steady decrease in the separation between the moieties containing the radical electron along the π-stacking chains. The intermolecular interactions throughout the crystal lattice have also been calculated using the PIXEL method, and highlight the relative strength of the inter-column interactions in the two known polymorphs of TTTA, which provides extra justification for the cause of the wide magnetic hysteresis and its response to pressure.

    DOI: 10.1039/d1ce00577d

    Web of Science

    Scopus

  27. Electrochemical Tuning-Induced Magnetic Transitions in Geometrically Frustrated Spinel Li<sub><i>x</i></sub>Mn<sub>2</sub>O<sub>4</sub> (0.07 ≤ <i>x</i> ≤ 0.93)

    Qi Chen, Zhongyue Zhang, Kunio Awaga

    The Journal of Physical Chemistry C   Vol. 125 ( 14 ) page: 7763 - 7771   2021.4

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.jpcc.1c00291

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  28. Enhanced proton conductivity in a flexible metal–organic framework promoted by single-crystal-to-single-crystal transformation Reviewed

    Xi Chen, Zhongyue Zhang, Jin Chen, Sergei Sapchenko, Xue Han, Ivan da-Silva, Ming Li, Inigo J. Vitorica-Yrezabal, George Whitehead, Chiu C. Tang, Kunio Awaga, Sihai Yang, Martin Schröder

    Chemical Communications   Vol. 57 ( 1 ) page: 65 - 68   2021.1

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    <p>Transformation of MFM-722(Pb)-DMA to MFM-722(Pb)-H<sub>2</sub>O leads to an increase in proton conductivity linked to a structural transition.</p>

    DOI: 10.1039/d0cc05270a

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    PubMed

  29. Variable Host–Guest Charge-Transfer Interactions in 1D Channels Formed in a Molecule-Based Honeycomb Lattice of Phenazine Analogue of Triptycene

    Ryo Ushiroguchi, Yoshiaki Shuku, Rie Suizu, Kunio Awaga

    Crystal Growth & Design   Vol. 20 ( 12 ) page: 7593 - 7597   2020.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.cgd.0c01176

    Web of Science

  30. Quantum Spin Liquid State in a Two-Dimensional Semiconductive Metal–Organic Framework Reviewed

    Yuki Misumi, Akira Yamaguchi, Zhongyue Zhang, Taku Matsushita, Nobuo Wada, Masahisa Tsuchiizu, Kunio Awaga

    Journal of the American Chemical Society   Vol. 142 ( 39 ) page: 16513 - 16517   2020.9

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.0c05472

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  31. Effect of fluorination on the crystal and electronic structure of organometallic cyclopentadienyl-phenylenediamino-cobalt complexes

    Pilia, L; Shuku, Y; Dalgleish, S; Hofmann, DWM; Melis, N; Awaga, K; Robertson, N

    JOURNAL OF ORGANOMETALLIC CHEMISTRY   Vol. 918   2020.7

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    Authorship:Last author, Corresponding author   Language:Japanese  

    Web of Science

  32. Electric and Thermosalient Properties of a Charge-Transfer Complex Exhibiting a Minor Valence Instability Transition

    Yukihiro Takahashi, Tsubasa Kondo, Seiya Yokokura, Mika Takehisa, Jun Harada, Tamotsu Inabe, Michio M. Matsushita, Kunio Awaga

    Crystal Growth & Design   Vol. 20 ( 7 ) page: 4758 - 4763   2020.7

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    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.cgd.0c00516

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  33. Effect of fluorination on the crystal and electronic structure of organometallic cyclopentadienyl-phenylenediamino-cobalt complexes

    Luca Pilia, Yoshiaki Shuku, Simon Dalgleish, Detlef W.M. Hofmann, Nicola Melis, Kunio Awaga, Neil Robertson

    Journal of Organometallic Chemistry   Vol. 918   2020.7

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier B.V.  

    The fluorinated half sandwich complex [CpCoLF] (Cp = cyclopentadiene
    LF = o-perfluoro-phenylenediimine
    2F) shows a T-shaped geometry with the LF ligand coplanar with the metallocycle. The molecules are dimerized in a head-to-tail fashion and arranged in a herringbone manner in the crystal packing. The crystal structure of 2F is different from that of the corresponding hydrocarbon compound (2H). Moreover, the differences due to the presence of fluorine atoms are also highlighted by the analysis of the intermolecular contacts, which show that 2F exhibits several F⋯F contacts, as well as aromatic intra-dimer π … π interactions in addition to C–H … π and C–H⋯F contacts. No relevant π … π interactions are observed in the case of 2H. Hirshfeld Surface (HS) analysis also depicted well the differences in the solid state interactions between the different crystal structures. In particular, HS has been useful in highlighting the differences observed between the crystal structure of 2H obtained from Rietveld refinement and that measured on single crystal (2HP and 2HSCH, respectively). The effect of the fluorination on the electronic structure has been investigated also by CV measurements and Density Functional Theory calculations. Both are consistent with a lowering in energy of the molecular orbitals. Data Mining Force Field calculations clearly indicate that the 2HSCH structure is more stable than the 2HP one. These findings can be explained in terms of the energy of the intermolecular interactions. The enhanced stability of the fluorine substitute can be easily explained by the large number of strong interactions involving fluorine atoms.

    DOI: 10.1016/j.jorganchem.2020.121277

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  34. Chemical potentials of electric double layers at metal–electrolyte interfaces: dependence on electrolyte concentration and electrode materials, and application to field-effect transistors Reviewed

    Chihiro Nanjo, Daisuke Yokogawa, Michio M. Matsushita, Kunio Awaga

    Physical Chemistry Chemical Physics   Vol. 22 ( 22 ) page: 12395 - 12402   2020.6

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    <p>We experimentally and theoretically reveal the chemical potentials of electric double layers at metal–electrolyte interfaces for carrier injections.</p>

    DOI: 10.1039/d0cp00423e

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  35. Structural, Electronic, and Magnetic Properties of Cobalt Tetrakis (Thiadiazole) Porphyrazine Molecule Films on Au(111) Reviewed

    Yu Wang, Jie Hou, Keitaro Eguchi, Chihiro Nanjo, Tsuyoshi Takaoka, Yasuyuki Sainoo, Kunio Awaga, Tadahiro Komeda

    ACS OMEGA   Vol. 5 ( 12 ) page: 6676 - 6683   2020.3

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    We investigated the structural and electronic/spin configurations of a film of the Co tetrakis(1,2,5-thiadiazole) porphyrazine (CoTTDPz) molecule adsorbed on the Au(111) surface by a scanning tunneling microscope (STM). CoTTDPz has a structure similar to that of the Co phthalocyanine molecule, but the benzene ring of the isoindole of the phthalocyanine molecule is replaced by the pentagon moiety of 1,2,5-thiadiazoles that has an S atom at the apex. We find an ordered molecular lattice with a threefold symmetry where a nearest-neighbor distance of 1.30 nm was measured, which is significantly smaller than that observed for the metal Pc molecule. The unit cell of the lattice contains two molecules that are rotated by 60 degrees relative to each other. With the configuration achieved by this rotation, the neighboring molecules can form a stronger interaction through bonding between the S atom at the apex of one molecule and the N atom of the other (the N atom that is bridging the thiadiazoles). The strong interaction between the molecule and the substrate appears in the spin state examined by the detection of the Kondo resonance, which is formed by the screening of an isolated spin by the conduction electron. Even though the existence of the spin was confirmed for the bulk and thick films of this molecule, no Kondo features are detected for the molecules in the first, second, and third layers of the films. However, the isolated molecule in the third layer showed an intriguing combination of the Kondo feature and an inelastic excitation feature caused by a spin-flip process.

    DOI: 10.1021/acsomega.9b04453

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  36. Enhanced magnetic spin-spin interactions observed between porphyrazine derivatives on Au(111) Reviewed

    Jie Hou, Yu Wang, Keitaro Eguchi, Chihiro Nanjo, Tsuyoshi Takaoka, Yasuyuki Sainoo, Ryuichi Arafune, Kunio Awaga, Tadahiro Komeda

    COMMUNICATIONS CHEMISTRY   Vol. 3 ( 1 )   2020.3

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    Magnetic molecules are of interest for application in spintronic and quantum-information processing devices. Therein, control of the interaction between the spins of neighboring molecules is the critical issue. Substitution of outer moieties of the molecule can tune the molecule-molecule interaction. Here we show a novel spin behavior for a magnetic molecule of vanadyl tetrakis (thiadiazole) porphyrazine (abbreviated as VOTTDPz) adsorbed on Au(111), which is modified from vanadyl phthalocyanine (VOPc) by replacing the inert phthalocyanine ligand with a reactive thiadiazole moiety. The magnetic properties of the molecules are examined by observing the Kondo resonance caused by the screening of an isolated spin by conduction electrons using scanning tunneling spectroscopy. The Kondo features are detected at the molecule whose shape and intensity show site-dependent variation, revealing complex spin-spin interactions due to the enhanced interaction between molecules, originating from the functionalization of the ligand with a more reactive moiety.Strong spin-spin interactions between surface-deposited magnetic molecules are desirable for quantum computing applications. Here the authors use scanning tunneling microscopy and spectroscopy to investigate the spin-spin interactions between neighbouring porphyrazine-derivatives on Au(111).

    DOI: 10.1038/s42004-020-0282-5

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  37. “Hidden Frustration” in Molecule-based <i>K</i><sub>4</sub> and Diamond Lattices Revealed by the Line Graph Transformation

    Rie Suizu, Kunio Awaga

    Molecular Science   Vol. 14 ( 1 ) page: A0113 - A0113   2020

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    DOI: 10.3175/molsci.14.a0113

  38. Salt-assisted pyrolysis of covalent organic frameworks to porous heteroatom-doped carbons for supercapacitive energy storage

    Dongwan Yan, Yang Wu, Ryo Kitaura, Kunio Awaga

    JOURNAL OF MATERIALS CHEMISTRY A   Vol. 7 ( 47 ) page: 26829 - 26837   2019.12

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    Supercapacitors have attracted intensive research interest due to their advantages including longer cycling ability and higher power density. Porous heteroatom-doped carbons (PHCs) have been regarded as a class of promising electrode materials for supercapacitors because of their unique porous, electronic and chemical properties. However, synthesis of PHCs with hierarchical mesoporous/microporous structures and ultra-high porosity and electrochemical performance remains a great research challenge. In this research, two oxygen and nitrogen co-doped PHCs (denoted as ONC-T1s) are prepared via a saltassisted pyrolysis method using covalent organic frameworks (COFs) as the precursor. ONC-T1s show a hierarchical porous structure with an ultra-high specific surface area (up to 3451 m(2) g(-1)). The ONC-T1-850-based supercapacitor exhibits a high specific capacitance of 1711 F g(-1) at 1 A g(1), an ultra-fast charge-discharge rate up to 500 A g(-1) with a specific capacitance of 856 F g(-1), and excellent stability. This work establishes a promising strategy for preparation of PHCs using COFs or other porous organic polymers as precursors and demonstrates the great potential of PHC-based supercapacitors.

    DOI: 10.1039/c9ta05150c

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  39. Potential modulations in flatland: near-infrared sensitization of MoS2 phototransistors by a solvatochromic dye directly tethered to sulfur vacancies

    Simon Dalgleish, Louisa Reissig, Yoshiaki Shuku, Giovanni Ligorio, Kunio Awaga, Emil J. W. List-Kratochvil

    Scientific Reports   Vol. 9 ( 1 )   2019.11

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    Near-infrared sensitization of monolayer MoS2 is here achieved via the covalent attachment of a novel heteroleptic nickel bis-dithiolene complex into sulfur vacancies in the MoS2 structure. Photocurrent action spectroscopy of the sensitized films reveals a discreet contribution from the sensitizer dye centred around 1300 nm (0.95 eV), well below the bandgap of MoS2 (2.1 eV), corresponding to the excitation of the monoanionic dithiolene complex. A mechanism of conductivity enhancement is proposed based on a photo-induced flattening of the corrugated energy landscape present at sulfur vacancy defect sites within the MoS2 due to a dipole change within the dye molecule upon photoexcitation. This method of sensitization might be readily extended to other functional molecules that can impart a change to the dielectric environment at the MoS2 surface under stimulation, thereby extending the breadth of detector applications for MoS2 and other transition metal dichalcogenides.

    DOI: 10.1038/s41598-019-53186-2

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  40. High Ambipolar Mobility in a Neutral Radical Gold Dithiolene Complex Reviewed

    Mizuno Asato, Benjamin Helen, Shimizu Yasuhiro, Shuku Yoshiaki, Matsushita Michio M, Robertson Neil, Awaga Kunio

    ADVANCED FUNCTIONAL MATERIALS   Vol. 29 ( 42 )   2019.10

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    DOI: 10.1002/adfm.201904181

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  41. Ionic liquid thin layer-induced memory effects in organic field-effect transistors Reviewed

    Keitaro Eguchi, Michio M. Matsushita, Kunio Awaga

    Physical Chemistry Chemical Physics   Vol. 21 ( 35 ) page: 18823 - 18829   2019.9

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    DOI: 10.1039/c9cp01647c

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  42. In situ formed [M(CN)(9)] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers Reviewed

    Qian Jun, Yoshikawa Hirofumi, Humphrey Mark G, Zhang Jinfang, Awaga Kunio, Zhang Chi

    CRYSTENGCOMM   Vol. 21 ( 29 ) page: 4363 - 4372   2019.8

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    DOI: 10.1039/c9ce00579j

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  43. Rate-determining process in MISIM photocells for optoelectronic conversion using photo-induced pure polarization current without carrier transfer across interfaces Reviewed

    Tomimatsu Akihiro, Yokokura Seiya, Reissig Louisa, Dalgleish Simon, Matsushita Michio M, Awaga Kunio

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 21 ( 25 ) page: 13440 - 13445   2019.7

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    DOI: 10.1039/c9cp01221d

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  44. Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material Reviewed

    Shinokubo, Hiroshi, Awaga, Kunio, Zhang, Zhongyue, Shin, Ji-Young

    Molecules   Vol. 24 ( 13 )   2019.7

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    DOI: 10.3390/molecules24132433

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  45. Auxiliary ligand-induced structural diversities of octacyanometalate-based heterobimetallic coordination polymers towards diverse magnetic properties Reviewed

    Qian Jun, Yoshikawa Hirofumi, Hu Jingchun, Humphrey Mark G, Zhang Jinfang, Awaga Kunio, Zhang Chi

    DALTON TRANSACTIONS   Vol. 48 ( 22 ) page: 7666 - 7676   2019.6

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    DOI: 10.1039/c9dt00654k

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  46. Recent Developments in Molecular Spin Gyroid Research Reviewed

    Mizuno Asato, Shuku Yoshiaki, Awaga Kunio

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   Vol. 92 ( 6 ) page: 1068 - 1093   2019.6

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    DOI: 10.1246/bcsj.20190033

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  47. Electron Highways into Nanochannels of Covalent Organic Frameworks for High Electrical Conductivity and Energy Storage Reviewed

    Wu Yang, Yan Dongwan, Zhang Zhongyue, Matsushita Michio M, Awaga Kunio

    ACS APPLIED MATERIALS & INTERFACES   Vol. 11 ( 8 ) page: 7661 - 7665   2019.2

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    DOI: 10.1021/acsami.8b21696

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  48. In Situ Real-Time Measurements for Ambipolar Channel Formation Processes in Organic Double-Layer Field-Effect Transistors of CuPc and F16CuPc Reviewed

    Eguchi, Keitaro, Matsushita, Michio M., Awaga, Kunio

    Journal of Physical Chemistry C   Vol. 122 ( 45 ) page: 26054 - 26060   2018.11

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    DOI: 10.1021/acs.jpcc.8b08744

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  49. Towards high-bandwidth organic photodetection based on pure active layer polarization Reviewed

    Reissig Louisa, Dalgleish Simon, Awaga Kunio

    SCIENTIFIC REPORTS   Vol. 8   2018.10

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    DOI: 10.1038/s41598-018-33822-z

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  50. 3D molecular network and magnetic ordering, formed by multi-dentate magnetic couplers, bis(benzene)chromium(I) and [1,2,5]thiadiazolo[3,4-c][1,2,5] thiadiazolidyl Reviewed

    Shuku Yoshiaki, Hirai Yuta, Semenov Nikolay A, Kadilenko Evgeny, Gritsan Nina P, Zibarev Andrey V, Rakitin Oleg A, Awaga Kunio

    DALTON TRANSACTIONS   Vol. 47 ( 29 ) page: 9897 - 9902   2018.8

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    DOI: 10.1039/c8dt02214c

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  51. Structural and Electronic Effects Due to Fluorine Atoms on Dibenzotetraaza-Annulenes Complexes Reviewed

    Pilia Luca, Shuku Yoshiaki, Dalgleish Simon, Awaga Kunio, Robertson Neil

    ACS OMEGA   Vol. 3 ( 8 ) page: 10074 - 10083   2018.8

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    DOI: 10.1021/acsomega.8b01442

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  52. Multifunctional Dithiadiazolyl Radicals: Fluorescence, Electroluminescence, and Photoconducting Behavior in Pyren-1 '-yl-dithiadiazolyl Reviewed

    Beldjoudi, Yassine, Nascimento, Mitchell A., Cho, Yong Joo, Yu, Hyeonghwa, Aziz, Hany, Tonouchi, Daiki, Eguchi, Keitaro, Matsushita, Michio M., Awaga, Kunio, Osorio-Roman, Igor, Constantinides, Christos P., Rawson, Jeremy M.

    Journal of the American Chemical Society   Vol. 140 ( 20 ) page: 6260 - 6270   2018.5

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    DOI: 10.1021/jacs.7b12592

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  53. Inter-molecule interaction for magnetic property of vanadyl tetrakis (thiadiazole) porphyrazine film on Au(111) Reviewed

    Hou, Jie, Wang, Yu, Eguchi, Keitaro, Nanjo, Chihiro, Takaoka, Tsuyoshi, Sainoo, Yasuyuki, Awaga, Kunio, Komeda, Tadahiro

    Applied Surface Science   Vol. 440   page: 16 - 19   2018.5

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    DOI: 10.1016/j.apsusc.2018.01.001

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  54. An exotic band structure of a supramolecular honeycomb lattice formed by a pancake π-π Interaction between triradical trianions of triptycene tribenzoquinone Reviewed

    Yoshiaki Shuku, Asato Mizuno, Ryo Ushiroguchi, Chang Seok Hyun, Young Jun Ryu, Byeong-Kwan An, Ji Eon Kwon, Soo Young Park, Masahisa Tsuchiizu, Kunio Awaga

    Chemical Communications   Vol. 54 ( 31 ) page: 3815 - 3818   2018.4

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    A supramolecular honeycomb lattice was successfully formed by using triradical trianion species of triptycene tribenzoquinone (TT) which forms strong intermolecular π-π pancake bonds toward three directions. The crystal structure of Rb3TT·2H2O belongs to the hexagonal P6/m space group, the tight-binding band calculation of which reveals Dirac cones and flat bands.

    DOI: 10.1039/c8cc00753e

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  55. Influence of Air Exposure on Photocarrier Generation in Amorphous and Phase II Thin Films of Titanyl Phthalocyanine Reviewed

    Eguchi, Keitaro, Imai, Yoshiaki, Matsushita, Michio M., Awaga, Kunio

    Journal of Physical Chemistry C   Vol. 122 ( 14 ) page: 7731 - 7736   2018.4

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    DOI: 10.1021/acs.jpcc.8b00290

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  56. Nanopore-induced host-guest charge transfer phenomena in a metal-organic framework Reviewed

    S. Yamamoto, J. Pirillo, Y. Hijikata, Z. Zhang, K. Awaga

    Chemical Science   Vol. 9 ( 13 ) page: 3282 - 3289   2018.4

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    A spontaneous entrapment of electron-donating small guest molecules, including tetrathiafulvalene (TTF) and N,N,N′,N′-tetramethyl-1,3-propanediamine (TMPDA), was realized in a structurally flexible metal-organic framework, {Mn7(2,7-AQDC)6(2,6-AQDC)(DMA)6}∞ (AQDC = anthraquinone dicarboxylates, DMA = N,N-dimethylacetamide), with electron-accepting anthraquinone groups, generating two MOF guest charge transfer complexes: {Mn7(2,7-AQDC)6(2,6-AQDC)(DMA)6(TTF)5} and {Mn7(2,7-AQDC)6(2,6-AQDC)(DMA)4(H2O)2(TMPDA)7}. Using a mild impregnation procedure, single crystals of the target complexes were obtained via a crystal-to-crystal conversion, and the crystals were suitable for structural analysis. Single crystal X-ray analysis demonstrated the different arrangements of these intercalated donor molecules: some donor molecules interacted with the anthraquinone groups and formed infinite D-A-A-D stacks, some appeared beside the anthraquinone groups but only formed donor-acceptor pairs, and the remainder of the molecules simply filled the space. The charge transfer between the guests and the framework was spectroscopically confirmed, and the radical densities on the organic species were estimated using magnetic susceptibility measurements. Compared with a solid-state mixture of anthraquinone and donor molecules, the evenly distributed donor molecules in the micropores of the MOF resulted in a "solid solution" state and significantly promoted the degree of charge transfer between donors and acceptors. Such an encapsulation process may be adopted as a new strategy for post-modification of the electronic and magnetic properties of MOFs, as well as for generating new semiconducting charge-transfer complexes.

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  57. Controlling the crystallinity and crystalline orientation of "shuttlecock" naphthalocyanine films for near-infrared optoelectronic applications Reviewed

    Simon Dalgleish, Louisa Reissig, Yoshiaki Shuku, Christophe Gourlaouen, Sergi Vela, Kunio Awaga

    Journal of Materials Chemistry C   Vol. 6 ( 8 ) page: 1959 - 1970   2018.2

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    The thin film properties of tin(ii) 2,3-naphthalocyanine (SnNPc) were interrogated and various strategies for controlling the crystallinity and crystalline orientation within the films were assessed. SnNPc is shown to crystallize in the space group P21/c (Z = 4), where the molecular arrangement consists of alternating layers of concave and convex overlap, induced by the out-of-plane Sn atoms, resulting in a 3D slipped-π-stack network structure analogous to that reported for Phase I of titanyl phthalocyanine. The thin films were studied by X-ray diffraction, atomic force microscopy and absorption spectroscopy and are highly sensitive not just to the conditions during growth, but also to substrate pre- and post-deposition treatment. While the films grown at room temperature were largely amorphous, the crystallinity was enhanced with substrate temperature, with the molecules orienting in a standing molecular geometry. A thin layer of 3,4:9,10-perlenetetracarboxylic dianhydride induces a lying molecular geometry of the same polymorph as that of the single crystal, while different polymorphs are accessible through solvent vapor annealing of amorphous films. Transient photocurrent measurements showed a dramatic improvement in photodetector device bandwidth for the lying molecular geometry, which was attributed to enhanced photoconductivity along the π-stacking axis, while solvent vapor annealing could be used to tune the photosensitivity across the near-infrared region.

    DOI: 10.1039/c7tc05521h

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  58. Giant negative magnetoresistance in Ni(quinoline-8-selenoate)2 Reviewed

    Nicholas Black, Tonouchi Daiki, Michio M. Matsushita, J. Derek Woollins, Kunio Awaga, Neil Robertson

    Physical Chemistry Chemical Physics   Vol. 20 ( 1 ) page: 514 - 519   2018.1

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    The magnetic, structural, conductivity and magnetoresistance properties of [Ni(quinoline-8-selenoate)2] ([Ni(qs)2]) have been studied. Despite the insolubility of the material necessitating its study as a powdered sample, a remarkably high conductivity has been measured. The conductivity is an order of magnitude greater than the thin-film processable thiol analogue previously reported and has been interpreted through the same space-charge limited conduction mechanism with charges injected from the electrodes. The introduction of selenium, results in a material with conductivity approaching metallic due to the enhanced interaction between adjacent molecules. Additionally, under an applied magnetic field, the material displays a negative magnetoresistance effect above 35% at 2 K. The effect can still be observed at 200 K and is interpreted in terms of a double-exchange mechanism.

    DOI: 10.1039/c7cp06273g

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  59. Electrochemical Synthesis and Doping for Nano-Porous Organic Magnetic Materials

    Shuku Yoshiaki, Awaga Kunio

    WORLD SCIENTIFIC REFERENCE ON SPIN IN ORGANICS, VOL 4 - SPIN IN ORGANICS   Vol. 10   page: 207 - 234   2018

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  60. Electrochemical synthesis and doping for nano-porous organic magnetic materials Reviewed

    Yoshiaki Shuku, Kunio Awaga

    World Scientific Reference On Spin In Organics   Vol. 4-4   page: 207 - 234   2017.12

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    In this chapter, we describe the solid-state electrochemical doping to nano-porous molecular crystals to control the conductive/magnetic properties, and the electrochemical crystal growth of unique 3D molecular crystals. (i) Electrochemical doping to the single crystals of lithium phthalocyanine (LiPc) in the x-form induces a crystal-to-crystal transformation to LiPc.Clx(0 &lt
    x &lt
    0.5), in which the x value is controlled by the electrochemical potential of the working electrode. X-ray crystal analyses for LiPc.Clx clearly demonstrates the presence of the Cl- ions in the 1D channels, and the shrinkage of the interplanar distance between the neighboring LiPc molecules. (ii) In-situ magnetic measurements for a mixed-valent Cr(II)-Cr(III) Prussian blue analog (PBA) in a solid-state electrochemical reduction, reveals a continuous change in magnetism, which can be well understood by a stepwise reduction of the Cr(III) ions in the A and B sites, respectively. (iii) The chiral 3D periodic structure in I4132 space group that is called K4 crystal or a number of different name, is successfully formed by the electrochemical crystallization of the radical anion salts of NDI(naphthalene diimide). This K4 crystal of NDI-? is found to correspond to the hyper-Kagome lattice of Mott dimers with spin frustration.

    DOI: 10.1142/9789813230200_0005

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  61. A Novel Strategy to Functionalize Covalent Organic Frameworks for High-Energy Rechargeable Lithium Organic Batteries via Graft Polymerization in Nano-Channels Reviewed

    Yang Wu, Zhongyue Zhang, Shunji Bandow, Kunio Awaga

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   Vol. 90 ( 12 ) page: 1382 - 1387   2017.12

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    By introducing catalyst- and solvent-free graft polymerization of low cost and environmentally benign sulfur to the nano-channels of an imine-linked covalent organic framework (COF), we demonstrated our strategy for functionalization of a conventional COF to yield a redox-active covalent organic framework-graft-polysulfide (COF-graft-PS), which can be utilized as a cathode active material in rechargeable lithium organic batteries. The COF-graft-PS-based batteries showed high capacity (425 mA h g(-1) at a rate of 250 mA g(-1)), excellent rate capability, and good cycling performance over 500 cycles. The design characteristics and synthetic strategy open new possibilities for the preparation of alternative, sustainable, high-performance rechargeable lithium batteries by using abundant and cost-effective materials.

    DOI: 10.1246/bcsj.20170247

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  62. 3D Spin-Liquid State in an Organic Hyperkagome Lattice of Mott Dimers Reviewed

    Asato Mizuno, Yoshiaki Shuku, Michio M. Matsushita, Masahisa Tsuchiizu, Yuuki Hara, Nobuo Wada, Yasuhiro Shimizu, Kunio Awaga

    PHYSICAL REVIEW LETTERS   Vol. 119 ( 5 ) page: 057201   2017.7

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    We report the first 3D spin liquid state of isotropic organic spins. Structural analysis, and magnetic and heat-capacity measurements were carried out for a chiral organic radical salt, (TBA)(1.5) [(-)-NDI-Delta] (TBA denotes tetrabutylammonium and NDI denotes naphthalene diimide), in which (-)-NDI-Delta forms a K-4 structure due to its triangular molecular structure and an intermolecular pi-pi overlap between the NDI moieties. This lattice was identical to the hyperkagome lattice of S = 1/2 Mott dimers, and should exhibit 3D spin frustration. In fact, even though the high-temperature magnetic susceptibility followed the Curie-Weiss law with a negative Weiss constant of theta = -15 K, the low-temperature magnetic measurements revealed no long-range magnetic ordering down to 70 mK, and suggested the presence of a spin liquid state with a large residual paramagnetism chi(0) of 8.5 x 10(-6) emu g(-1) at the absolute zero temperature. This was supported by the N-14 NMR measurements down to 0.38 K. Further, the low-temperature heat capacities c(p) down to 68 mK clearly indicated the presence of c(p) for the spin liquid state, which can be fitted to the power law of T-0.62 in the wide temperature range 0.07-4.5 K.

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  63. Negative differential resistance in the Peierls insulating phases of TTF-TCNQ Reviewed

    Daiki Tonouchi, Michio M. Matsushita, Kunio Awaga

    PHYSICAL REVIEW B   Vol. 96 ( 4 ) page: 045116   2017.7

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    Negative differential resistance (NDR) was observed in the most well known organic conductor, TTF-TCNQ, in its low-temperature Peierls insulator phase below 53 K. The voltage-current (V -I) characteristics below this temperature, measured by a four-probe method, exhibited unique NDR behavior, in which the dV/dI versus conductivity (sigma) plots had the inflection points at the three sigma values without depending on temperature. These sigma values were found to coincide with the conductivities at the three transition temperatures (53, 49, and 38 K) for the formation of the charge-density waves in TTF-TCNQ. This suggests that the electronic structure of the Peierls insulating phase of TTF-TCNQ is governed by the total carrier density, which is determined by not only thermal excitation but also carrier injection.

    DOI: 10.1103/PhysRevB.96.045116

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  64. Templating effects of tetrakis(thiadiazole) porphyrazine on the structure and optical properties of copper phthalocyanine thin films Reviewed

    Eguchi, Keitaro, Heutz, Sandrine, Awaga, Kunio

    Journal of Porphyrins and Phthalocyanines   Vol. 21 ( 4-6 ) page: 322 - 326   2017.4

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    DOI: 10.1142/S1088424617500171

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  65. Molecular and thin film properties of cobalt half-sandwich compounds for optoelectronic application Reviewed

    Maxwell Reinhardt, Simon Dalgleish, Yoshiaki Shuku, Louisa Reissig, Michio M. Matsushita, Jason Crain, Kunio Awaga, Neil Robertson

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 19 ( 9 ) page: 6768 - 6776   2017.3

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    The structure and electronic properties of a novel cobalt half sandwich complex of cyclopentadiene (Cp) and diaminonaphthalene (DAnap) [CpCo(DAnap)] are described and compared to the previously reported diaminobenzene derivative [CpCo(DAbnz)] in view of their potential for (opto) electronic device application. Both complexes show stable redox processes, tunable through the diaminoacene ligand, and show strong absorption in the visible region, with additional transitions stretching into the near infrared (NIR). CpCo(DAnap) crystallises with a particularly large unit cell (9301 angstrom 3), comprising 32 molecules, with a gradual rotation over 8 molecules along the long c-axis. In the solid state the balance of the optical transitions in both complexes is reversed, with a suppression of the visible band and an enhancement of the NIR band, attributed to extensive intermolecular electronic interaction. In the case of CpCo(DAnap), highly crystalline thin films could be formed under physical vapor deposition, which show a photocurrent response stretching into the NIR, and p-type semiconductor behavior in field effect transistors with mobility values of the order 1 x 10-(4) cm(2) V-1 s(-1). The device performance is understood through investigation of the morphology of the grown films.

    DOI: 10.1039/c6cp08685c

    Web of Science

    PubMed

  66. Fluorination induced electronic effects on a Pt(II) square-planar complex of the: O -phenylenedIImine ligand Reviewed

    L. Pilia, M. M. Matsushita, K. Awaga, N. Robertson

    New Journal of Chemistry   Vol. 41 ( 13 ) page: 5487 - 5492   2017

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    A novel complex [Pt(C6F4(NH)2)2] (2), formed by a Pt(ii) cation bound to two molecules of the tetrafluorinated 1,2-phenylenediimine ligand, has been synthesized and characterized by electrochemical and XRD measurements, UV-vis-NIR spectroscopy as well as by DFT and TD-DFT calculations. The effect induced by the fluorine atoms has been highlighted by comparison with the corresponding Ni (1H) and Pt (2H) hydrogenated complexes. The cyclic voltammetry data show that the reduction and the oxidation processes of 2 are easier and more difficult (by about 0.5 V), respectively, compared to those of 1H and 2H, suggesting that the electron withdrawing ability of the fluorine atoms lowers the energy level of both the HOMO and the LUMO. UV-vis-NIR measurements are similar for all the three complexes, indicating similar HOMO-LUMO gaps and that the effects of fluorination on the frontier orbitals are roughly the same. Moreover, polymorphism in the powder form of 2 has been highlighted by XRD measurements while the film presents only one phase. Furthermore, this complex shows a field-effect for n-type carriers. All the experimental results are also supported by the calculations, which show the role played by the fluorine atoms in the electronic structure of 2.

    DOI: 10.1039/c7nj00394c

    Scopus

  67. Highly-oriented molecular arrangements and enhanced magnetic interactions in thin films of CoTTDPz using PTCDA templates Reviewed

    K.. Eguchi, C. Nanjo, K. Awaga, H. H. Tseng, P. Robaschik and S. Heutz

    Phys. Chem. Chem. Phys.   Vol. 18 ( 26 ) page: 17360-17365   2016

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    DOI: 10.1039/C6CP01932C

  68. A perovskite based plug and play AC photovoltaic device with ionic liquid induced transient optoelectronic conversion Reviewed

    S. Karak, C. Nanjo, M. Odaka, K. Yuyama, G. Masuda, M. M. Matsushita, K. Awaga

    J. Mater. Chem. A.   Vol. 4   page: 9019-9028   2016

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    DOI: 10.1039/C6TA01427E

  69. Discovery of a "Bipolar Charging" Mechanism in the Solid-State Electrochemical Process of a Flexible Metal-Organic Framework Reviewed

    Z. Zhang, H. Yoshikawa and K. Awaga

    Chem. Mater.   Vol. 28 ( 5 ) page: 1298-1303   2016

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    DOI: 10.1021/acs.chemmater.5b04075

  70. Factors affecting the polarity and magnitude of photoresponse of transient photodetectors Reviewed

    L. Reissig, K. Mori, R. Treadwell, S. Dalgleish and K. Awaga

    Phys. Chem. Chem. Phys.   Vol. 18   page: 6821-6830   2016

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    DOI: 10.1039/c6cp00093b

  71. Synthesis of Vanadium-Incorporated, Polyoxometalate-Based Open Frameworks and Their Applications for Cathode-Active Material Reviewed

    Z. Zhang, H. Yoshikawa, Z. Zhang, T. Murayama, M. Sadakane, Y. Inoue, W. Ueda, K. Awaga and M. .Hara

    Eur. J. Inorg. Chem.   Vol. 8   page: 1242-1250   2016

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    DOI: 10.1002/ejic.201501396

  72. Integration of Paramagnetic Diruthenium Complexes into an Extended Chain by Heterometallic Metal-Metal Bonds with Diplatinum Complexes Reviewed

    K. Uemura, N. Uesugi, A. Matsuyama, M. Ebihara, H. Yoshikawa, K. Awaga

    Inorg. Chem.   ( 55 ) page: 7003-7011   2016

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    DOI: 10.1021/acs.inorgchem.6b00741

  73. Redox-active metal-organic frameworks as electrode materials for batteries Reviewed

    Z. Zhang, K. Awaga

    MRS Bulletin,   Vol. 41   page: 883-889   2016

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    DOI: 10.1557/mrs.2016.245

  74. Transport Characteristics of the Organic Field-Effect Transistors Based on Charge Transfer Complex as Semiconductors Reviewed

    S. Yokokura, Y. Takahashi, H. Hasegawa, J. Harada, T. Inabe, M. M. Matsushita, K. Awaga

    J. Nanosci. Nanotech.   ( 16 ) page: 3355-3359   2016

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    DOI: 10.1166/jnn.2016.12301

  75. Factors Affecting the Stability and Performance of Ionic Liquid-Based Planar Transient Photodetectors Reviewed

    S. Dalgleish, L. Reissig, L. Hu, M. M. Matsushita, Y. Sudo and K. Awaga

    Langmuir   Vol. 3 ( 18 ) page: 5235-5243   2015

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    DOI: 10.1021/la504972q

  76. Organic optoelectronic interfaces with anomalous transient photocurrent Reviewed

    L. Hu, X. Liu, S. Dalgleish, M. M. Matsushita,H. Yoshikawa and K. Awaga

    J. Mater. Chem. C   Vol. 3   page: 5122-5135   2015

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    DOI: 10.1039/c5tc00414d

  77. Photocurrent Generation in Organic Photodetectors with Tailor-Made Active Layers Fabricated by Layer-by-Layer Deposition Reviewed

    B. Vonhoeren, S. Dalgleish, L. Hu, M. M. Matsushita, K. Awaga, B.J. Ravoo

    ACS Applied Materials & Interfaces   Vol. 7 ( 13 ) page: 7049-7053   2015

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    DOI: 10.1021/am509031u

  78. Discovery of the K4 Structure Formed by a Triangular π Radical Anion Reviewed

    A. Mizuno, Y. Shuku, R.Suizu, M. M. Matsushita, M. Tsuchiizu, D. R. Maneru, F. Illas, V. Robert, and K. Awaga

    J. Am. Chem. Soc.   Vol. 137   page: 7612−7615   2015

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    DOI: 10.1021/jacs.5b04180

  79. External-Template-Assisted Formation of Octacyanometalate-Based MV-MnII (M = W, Mo) Bimetallic Coordination Polymers with Magnetic Properties Reviewed

    Q. Jun, Hu. Jingchun, H. Yoshikawa, Z. Jinfang, K. Awaga, Z. Chi

    European Journal of Inorganic Chemistry   Vol. 12   page: 2110-2119   2015

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    DOI: 10.1002/ejic.201403223

  80. Spatially inhomogeneous, stepwise phase transitions in a thiazyl diradical: a structural mismatch induced by lattice transformation Reviewed

    R. Suizu, A. Iwasaki, Y. Shuku, and K. Awaga

    J. Mater. Chem. C,   Vol. 3   page: 7968-7977   2015

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    DOI: 10.1039/c5tc01410g

  81. A differential photodetector: Detecting light modulations using transient photocurrents Reviewed

    L. Reissig, S. Dalgleish and K. Awaga

    AIP Advances   Vol. 6   page: 015306   2015

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    DOI: 10.1063/1.4939921

  82. Self-assembled honeycomb lattice in the monolayer of cyclic thiazyl diradical BDTDA (=4,4'-bis (1,2,3,5-dithiadiazolyl)) on Cu(111) with a zero-bias tunneling spectra anomaly Reviewed

    M. Yamamoto, R. Suizu, S. Dutta, P. Mishra, T. Nakayama, K. Sakamoto, K. Wakabayashi, T. Uchihashi, and K. Awaga

    Sci. Rep   Vol. 5   page: 18359   2015

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    DOI: 10.1038/srep18359

  83. Enhanced capacitor effects in polyoxometalate/graphene nanohybrid materials; a synergetic approach to high performance energy storages Reviewed

    K. Kume, N. Kawasaki, H. Wang, T. Yamada, H. Yoshikawa, K. Awaga

    J. Mater. Chem. A   Vol. 2   page: 3801-3807   2014

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  84. Giant Magnetoresistance in a Molecular Thin Film as an Intrinsic Property Reviewed

    L. Pilia, M. Serri, M. M. Matsushita, K. Awaga, S. Heutz, N. Robertson

    Adv. Funct. Mater.   Vol. 24 ( 16 ) page: 2383-2388   2014

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  85. Third-Order Nonlinear Optical Properties and Electroabsorption Spectra of an Organic Biradical, [Naphtho[2,1-d:6,5-d']bis([1,2,3]dithiazole)] Reviewed

    K. Takauji, R. Suizu, K. Awaga, H. Kishida, A. Nakamura

    J. Phys. Chem. C   Vol. 118   page: 4303-4308   2014

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  86. Cathode Composition Dependence of the Battery Performance of Polyoxometalate (POM)-Molecular Cluster Batteries Reviewed

    H. Wang, T. Yamada, S. Hamanaka, H. Yoshikawa, K. Awaga

    Chem. Lett.   Vol. 43   page: 1067-1069   2014

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  87. Theoretical investigation of molecular and electronic structure changes of the molecular magnet Mn12 cluster upon super-reduction Reviewed

    Y. Nishimoto, H. Yoshikawa, K. Awaga, M. Lundberg, and S. Irle

    Physica Status Solidi (RRL) - Rapid Research Letters   Vol. 8   page: 517-521   2014

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  88. A Three-Dimensional Hetero-Bimetallic Coordination Polymer with Unusual (4,5)-Connected Topology and Ferrimagnetic Property Based on Octacyanotungstate and Polydentate Ligand Reviewed

    J.Qian, J. Hu, H. Yoshikawa, J. Zhang, K. Awaga, and C. Zhang

    Cryst. Growth Des.   Vol. 14 ( 5 ) page: 2288-2295   2014

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  89. Crystal-to-Crystal Transformation in Solid-State Electrochemical Doping of Cl- Ions to a Nano-Porous Neutral Radical, Lithium Phthalocyanine; Revelation of Electron-Electron Correlations in a 1D Half-Filled System Reviewed

    Y. Miyoshi, H. Yoshikawa, K. Awaga

    CrystEngComm   Vol. 16   page: 9266-9272   2014

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  90. Ambipolar Transport in Phase-Separated Thin Films of p- and n-Type Vanadylporphyrazines with Two-Dimensional Percolation Reviewed

    C. Nanjo, T. Fujimoto, M. M. Matsushita, K. Awaga

    J. Phys. Chem. C   Vol. 118   page: 14142-14149   2014

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  91. Super-reduced polyoxometalates: Excellent molecular cluster battery components and semipermeable molecular capacitors Reviewed

    Y. Nishimoto, D. Yokogawa, H. Yoshikawa, K. Awaga, S. Irle

    J. Am. Chem. Soc.   Vol. 136   page: 6042-9052   2014

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  92. The solid-state electrochemical reduction process of magnetite in Li batteries: in-situ magnetic measurements toward electrochemical magnets Reviewed

    T. Yamada, K. Morita, K. Kume, H. Yoshikawa, and K. Awaga

    J. Mater. Chem. C   Vol. 2   page: 5183-5188   2014

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  93. The key role of vibrational entropy in the phase transitions of dithiazolyl-based bistable magnetic materials Reviewed

    S. Vela, F. Mota, M., Deumal, R. Suizu, Y. Shuku, A. Mizuno, K. Awaga, M. Shiga, J. J Novoa, J. Ribas-Arino

    Nat. Commun.   Vol. 5   page: 4411   2014

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  94. Storage of an electric field for photocurrent generation in ferroelectric-functionalized organic devices Reviewed

    L. Hu, S. Dalgleish, M. M. Matsushita, H. Yoshikawa, and K. Awaga

    Nat. Commun.   Vol. 5   page: 4279/1-4279/8   2014

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  95. Thiadiazole Dioxide-Fused Picene: Acceptor Ability, Anion Radical Formation, and n-Type Charge Transport Characteristics Reviewed

    Y. Xie, Y. Shuku, M. M. Matsushita, K. Awaga

    Chem. Commun.   Vol. 50 ( 32 ) page: 4178-4180   2014

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  96. Monitoring the Solid-state Electrochemistry of Cu(2,7-AQDC) (AQDC=anthraquinone dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal-Organic Framework Reviewed

    Z. Zhang, H. Yoshikawa, K. Awaga

    J. Am. Chem. Soc.   Vol. 136 ( 46 ) page: 16112-16115   2014

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    DOI: 10.1021/ja508197w

  97. Capacitance Effects Superimposed on Redox Processes in Molecular Cluster Batteries: A Synergic Route to High Capacity Energy Storage Reviewed

    H. Wang, Z. Zeng, N. Kawasaki, H. Eckert, H. Yoshikawa, K. Awaga

    Chem. Eur. J.   Vol. 19   page: 11235-11240   2013

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  98. In Situ Seamless Magnetic Measurements for Solid-State Electrochemical Processes in Prussian Blue Analogues Reviewed

    T. Yamada, K. Morita, H. Wang, K. Kume, H. Yoshikawa, K. Awaga

    Angew. Chem., Int. Ed   Vol. 52   page: 6238–6241   2013

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  99. Electronic structure of organic biradical molecular films Reviewed

    Kaname Kanai, Harunobu Koike, Rie Suizu, Kunio Awaga, Kazuhiko Mase, Takashi Kubo

    Journal of the Vacuum Society of Japan   Vol. 56 ( 1 ) page: 32-38   2013

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  100. Electric-double-layer field-effect transistors with ionic liquids Reviewed

    T. Fujimoto, K. Awaga

    Phys. Chem. Chem. Phys   Vol. 15   page: 8983-9006   2013

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  101. Synthesis, optical properties and charge transport characteristics of a series of novel thiophene-fused phenazine derivatives Reviewed

    Y. Xie, T. Fujimoto, S. Dalgleish, Y. Shuku, M.M. Matsushita, K. Awaga

    J. Mater. Chem. C   Vol. 1   page: 3467-3481   2013

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  102. Ambipolar Carrier Injections Governed by Electrochemical Potentials of Ionic Liquids in Electric-Double-Layer Thin-Film Transistors of Lead- and Titanyl-Phthalocyanine Reviewed

    T. Fujimoto, M. M. Matsushita, K. Awaga

    J. Phys. Chem. C   Vol. 117   page: 5552-5557   2013

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  103. Mn12 single molecule magnets deposited on μ-SQUID sensors the role of interphases and structural modifications Reviewed

    E. Bellido, P. Gonzalez-Monje, A. Repolles, M. Jenkins, J. Sese, D. Drung, T. Schurig, K. Awaga, F. Luis, D. Ruiz-Molina

    Nanoscale   Vol. 5   page: 12565-12573   2013

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  104. Solvent-Induced Assembly of Octacyanometalates-Based Coordination Polymers with Unique cjq Topology and Magnetic Properties Reviewed

    J. Qian, J. Hu, J. Zhang, H. Yoshikawa, K. Awaga, C. Zhang

    Crystal Growth & Design   Vol. 13   page: 5211-5219   2013

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  105. Multidimensional Network Structures and Versatile Magnetic Properties of Intermolecular Compounds of a Radical-Anion Ligand, [1,2,5]Thiadiazolo[3,4-f][1,10]phenanthroline-1,1-Dioxide Reviewed

    Y. Shuku, R. Suizu, A. Domingo, C. J. Calzado, V. Robert, K. Awaga

    Inorg. Chem   Vol. 52   page: 9921-9930   2013

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  106. Molecule-displacive ferroelectricity in organic supramolecular solids Reviewed

    H. Ye, Y. Zhang, S. Noro, K. Kubo, M. Yoshitake, Z. Liu, H. Cai, D. Fu, H. Yoshikawa, K. Awaga, R. Xiong, T. Nakamura

    Sci. Rep   Vol. 3   page: 2249   2013

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  107. Ferroelastic phase transition and dielectric anomalies in 2,4,6-trimethylanilinium perchlorate Reviewed

    Y. Zhang, K. Awaga, H. Yoshikawa, R.G. Xiong

    J. Mater. Chem   Vol. 22   page: 9841-9845   2012

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  108. Planar Ni(II), Cu(II) and Co(II) tetraaza[14]annulenes: structural, electronic and magnetic properties and application to field effect transistors Reviewed

    A.M. Whyte, Y. Shuku, G.S. Nichol, M.M. Matsushita, K. Awaga, N. Robertson

    J. Mater. Chem.   Vol. 22   page: 17967-17975   2012

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  109. Ionic-Liquid Component Dependence of Carrier Injection and Mobility for Electric-Double-Layer Organic Thin-Film Transistors Reviewed

    T. Fujimoto, M.M. Matsushita, K. Awaga

    J. Am. Chem. Soc   Vol. 116   page: 5241-5246   2012

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  110. Utilizing Photocurrent Transients for Dithiolene-Based Photodetection: Stepwise Improvements at Communications Relevant Wavelengths Reviewed

    S. Dalgleish, M. M. Matsushita, L. Hu, B. Li, H. Yoshikawa, and K. Awaga

    J. Am. Chem. Soc   Vol. 134   page: 12742-12750   2012

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  111. Molecular cluster batteries of nano-hybrid materials between Keggin POMs and SWNTs Reviewed

    H. Wang, N. Kawasaki, T. Yokoyama, H. Yoshikawa and K. Awaga

    Dalton Transactions   Vol. 41   page: 9863-9866   2012

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  112. Highly-efficient organic optoelectronic conversion induced by electric double layers in ionic liquids Reviewed

    B. Li, Y. Noda, L. Hu, H. Yoshikawa, M. M. Matsushita, and K. Awaga

    Appl. Phys. Lett   Vol. 100   page: 163304   2012

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  113. In operando XAFS Studies of Polyoxometalate Molecular Cluter Batteries: Polyoxometalates as Electron Sponges Reviewed

    H. Wang, S. Hamanaka, Y. Nishimoto, S. Irle, T, Yokoyama, H. Yoshikawa, and K. Awaga

    J. Am. Chem. Soc   Vol. 134   page: 4918–4924   2012

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  114. Crystal Structure, Spin Polarization, Solid-State Electrochemistry, and High n-Type Carrier Mobility of a Paramagnetic Semiconductor: Vanadyl Tetrakis(thiadiazole)porphyrazine Reviewed

    Y. Miyoshi, K. Takahashi, T. Fujimoto, H. Yoshikawa, M.M. Matsushita, Y. Ouchi, M. Kepenekian, V. Robert, M.P. Donzello, C. Ercolani, K. Awaga

    Inorg. Chem   Vol. 51   page: 456-462   2012

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  115. New indole trimers as precursors for molecular electronic materials Reviewed

    R.A. Valentine, A. Whyte, K. Awaga, N. Robertson

    Tetrahedron Lett   Vol. 53   page: 657-660   2012

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  116. Above-Room-Temperature Magnetodielectric Coupling in a Possible Molecule-Based Multiferroic: Triethylmethylammonium Tetrabromoferrate(III) Reviewed

    H-. L-. Cai, Y. Zhang, D-W. Fu, W. Zhang, T. Liu, H. Yoshikawa, K. Awaga, R-.G-. Xiong

    J. Am. Chem. Soc   Vol. 134   page: 18487-18490   2012

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  117. Formation of stable neutral copper bis-dithiolene thin films by potentiostatic electrodeposition Reviewed

    S. Dalgleish, K. Awaga and N. Robertson

    Chem. Commun.   Vol. 47   page: 7089-7091   2011

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  118. A complementary organic inverter of porphyrazine thin films: low-voltage operation using ionic liquid gate dielectrics Reviewed

    T. Fujimoto, Y. Miyoshi, M. M. Matsushita and K. Awaga

    Chem. Commun.   Vol. 47   page: 37-5839   2011

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  119. Two 3D Coordination Assemblies with Same Cluster Configuration Showing Different Magnetic Behaviors: A Ferromagnetic {[W(CN)8Co2(DMF)8][NO3]}n and A Paramagnetic {W(CN)8Cu2(py)8} Reviewed

    J. Qian, H Zhao, H. Wei, J. Li, J. Zhang, H. Yoshikawa, K. Awaga, C. Zhang

    CrystEngComm.   Vol. 13   page: 517-523   2011

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  120. Nanohybridization of Polyoxometalate Clusters and Single-Wall Carbon Nanotubes: Applications in Molecular Cluster Batteries Reviewed

    N. Kawasaki, H. Wang, R. Nakanishi, S. Hamanaka, R. Kitaura, H. Shinohara, T. Yokoyama, H. Yoshikawa, K. Awaga

    Angew. Chem Int. Ed.   Vol. 50   page: 3471-3474   2011

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  121. In-situ XAFS Studies of Mn12 Molecular-Cluster Batteries: Super-Reduced Mn12 Clusters in Solid-State Electrochemistry Reviewed

    H. Wang, S. Hamanaka, T. Yokoyama, H. Yoshikawa, K. Awaga

    Chem. Asian J.   Vol. 6   page: 1074-1079   2011

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  122. Photoconductivity and FET Performance of an n-Type Porphyrazine Semiconductor, Tetrakis(thiadiazole)porphyrazine Reviewed

    Y. Miyoshi, T. Fujimoto, H. Yoshikawa, M.M. Matsushita, K. Awaga, T. Yamada, H. Ito

    OrganicElectronics   Vol. 12   page: 239-243   2011

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  123. Electrodeposition as a superior route to a thin film molecular semiconductor Reviewed

    S. Dalgleish, H. Yoshikawa, M. M. Matsushita, K. Awaga, N. Robertson

    Chem. Sci.   Vol. 2   page: 316-320   2011

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  124. Highly efficient alternating photocurrent from interactive organic radical dimers. A novel light-harvesting mechanism for optoelectronic conversion Reviewed

    L. Hu, A. Iwasaki, R. Suizu, H. Yoshikawa, H. Ito, and K. Awaga

    Chem. Phys. Lett   Vol. 484   page: 177-180   2010

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  125. Exceptional Dielectric Phase Transitions in a Perovskite-Type Cage Compound Reviewed

    W. Zhang, Y. Cai, R-G. Xiong, H. Yoshikawa, K. Awaga

    Angew. Chem. Int. Ed   Vol. 49   page: 6608-6610   2010

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  126. Tetrakis(thiadiazole)porphyrazines. 7. Synthesis and structure of mu-oxo-bis[tetrakis(thiadiazole)porphyrazinato-aluminum(III)] Reviewed

    M. P. Donzello, M. Fujimori, Y. Miyoshi, H. Yoshikawa, E. Viola, K. Awaga, C. Ercolani

    J. Porphyrazines & Phthalocyanines   Vol. 14   page: 343-348   2010

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  127. Intermolecular band dispersion in a self-assembled phthalocyanine derivative film: The case of tetrakis(thiadiazole)porhyrazine Reviewed

    Y. Tanaka, K. Takahashi, T. Kuzumaki, Y. Yamamoto, K. Hotta, A. Harasawa, Y. Miyoshi, H. Yoshikawa, Y. Ouchi, N. Ueno, K. Seki, K. Awaga, K. Sakamoto

    Phys. Rev. B   Vol. 82   page: 073408   2010

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  128. A Novel Free Radical Probe Based on a Preluminescent Iridium Complex Bearing a Nitronyl Radical Moiety Reviewed

    H. Yoshikawa, M. Kobayashi, T. Takahashi, K. Awaga

    Bull. Chem. Soc. Japan   Vol. 83   page: 762-766   2010

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  129. Optoelectronic conversion by polarization current, triggered by space charges at organic-based interfaces Reviewed

    L. Hu, Y. Noda, H. Ito, H. Kishida, A. Nakamura, K. Awaga

    Appl. Phys. Lett   Vol. 96   page: 243303   2010

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  130. Magnetic and Optical Properties of Submicron-size Hollow Spheres Reviewed

    Q.-L. Ye, H. Yoshikawa and K. Awaga

    Materials   Vol. 3   page: 1244-1268   2010

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  131. Quantum Spin State and Magnetization Plateaus in an S=1 Kagome Heisenberg Antiferromagnet Reviewed

    T. Matsushita, N. Hamaguchi, K. Shimizu, N. Wada, W. Fujita, K. Awaga, A.

    J. Phys. Soc. Japan   Vol. 79   page: 093701   2010

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  132. Dual-gate field-effect transistors of octathio[8]circulene thin-films with ionic liquid and SiO2 gate dielectrics Reviewed

    T. Fujimoto, M. M. Matsushita, K. Awaga

    Appl. Phys. Lett   Vol. 97   page: 123303/1-123303/3   2010

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  133. Electrochemical Structural Transformation and Reversible Doping/Dedoping of Lithium Phthalocyanine Thin Films Reviewed

    Chem. Commun.     page: 3389-3391   2009

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  134. *Photoconductive Organic Radical Thin Films: Interactive Radical Dimers for Photofunctions Reviewed

    Angew. Chem. Int. Ed.   Vol. 48   page: 4022-4024.   2009

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  135. High-Yield Synthesis of Ultrathin Metal Nanowires in Carbon Nanotubes Reviewed

    Angew. Chem. Int. Ed.   Vol. 48   page: 8298-8302   2009

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  136. Rechargeable Batteries Driven by Redox Reactions of Mn12 Clusters with Structural Changes: XAFS Analyses of the Charging/Discharging Processes in Molecular Cluster Batteries Reviewed

    Inorg. Chem.   Vol. 48   page: 9057-9059   2009

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  137. Intercalation of stable organic radicals into layered saponite clay Reviewed

    Dalton Trans.   Vol. 38   page: 7995-8004   2009

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  138. Fe(II) spincrossover complex of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline Invited Reviewed

    CrystEngComm   Vol. 11   page: 2065-2068   2009

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  139. Ligands bonded to metal ion or through-metal interacting ligands? Analysis of unusual bonds formation in the (BDTA)2[Co(mnt)2] material Reviewed

    Phys. Chem. Chem. Phys.,   Vol. 11   page: 6066-6071   2009

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  140. *Green magnetite (Fe3O4): Unusual optical Mie scattering and magnetic isotropy of submicron-size hollow spheres Reviewed

    Appl. Phys. Lett.   Vol. 94   page: 063114   2009

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  141. Electrochemical and Electrochromic Properties of Octathio[8]circulene Thin Films in Ionic Liquids Reviewed

    J. Am. Chem. Soc.   Vol. 130   page: 15790–15791   2008

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  142. Structural Study of a Dimerization Process in an Organic Radical Magnet, BBDTA InBr4 Reviewed

      Vol. 47   page: 9480–9483   2008

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  143. Pressure-Induced Ferromagnetic to Nonmagnetic Transition and the Enhancement of Ferromagnetic Interaction in the Thiazyl-Based Organic Ferromagnet &#61543;-BBDTA&#903;GaCl4 Reviewed

      Vol. 77   page: 124713   2008

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  144. Diverse Magnetic and Electrical Properties of Molecular Solids containing the Thiazyl Radical BDTA Reviewed

      Vol. 361   page: 3761-3770   2008

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  145. High Yield Synthesis and Characterization of the Structural and Magnetic Properties of Crystalline ErCl3 Nanowires in Single-Walled Carbon Nanotube Templates Reviewed

    R. Kitaura, D. Ogawa, K. Kobayashi, T. Saito, S. Ohshima, T. Nakamura, H. Yoshikawa, K. Awaga, and H. Shinohara

    Nano Res   Vol. 1   page: 152-157   2008

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  146. Molecular, Crystal, and Thin-Film Structures of Octathio[8]circulene: Release of Anti-Aromatic Molecular Distortion and Lamellar Structure of Self-Assembling Thin Films Reviewed

    T. Fujimoto, R. Suizu, H. Yoshikawa, and K. Awaga

    Chem. Eur. J.   Vol. 14   page: 6053-6056   2008

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  147. Diverse magnetic and electrical properties of molecular solids containing the thiazyl radical BDTA Reviewed

    K. Awaga, Y. Umezono, W. Fujita, H. Yoshikawa, H.-B. Cui, H. Kobayashi, S. S. Staniland, N. Robertson

    Inorg. Chim. Acta   Vol. 361   page: 3761-3770   2008

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  148. *Preparation, photocatalytic activities and dye-sensitized solar-cell performance of submicron-scale TiO2 hollow spheres Reviewed

    Y. Kondo, H. Yoshikawa, K. Awaga, M. Murayama, T. Mori, K. Sunada, S. Bandow, S. Iijima

    Langmuir   Vol. 24   page: 547-550   2008

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  149. *Rechargeable Molecular Cluster Batteries Reviewed

    H. Yoshikawa, C. Kazama, K. Awaga, M. Satoh, J. Wada

    Chem. Commun,     page: 3169-3170   2007

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  150. *Electrochromism and Stable n-Type Doping of Highly Oriented Thin Films of Tetrakis(thiadiazole)porphyrazine Reviewed

    K. Okamoto, T. Tanaka, W. Fujita, K. Awaga, and T. InabeY. Miyoshi, M. Kubo, T. Fujinawa, Y. Suzuki, H. Yoshikawa, and K. Awaga

    Angew. Chem. Int. Ed.   Vol. 46   page: 5532-5536   2007

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  151. Impurity effect in ferromagnetic transition of β-BBDTA•GaBr4 Reviewed

    K. Shimizu, T. Gotohda, T. Matsushita, N. Wada, W. Fujita, K. Awaga, Y. Saiga, and D. S. Hirashima

    J. Magn. Magn. Mater.   Vol. 310   page: 1479-1481   2007

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  152. Pressure effect on spin-Peierls-like transition in quasi-1D spin systems [RBzPy][Ni(mnt)2] Reviewed

    X. M. Ren, S. Nishihara, T. Akutagawa, S. Noro, T. Nakamura, W. Fujita, and K. Awaga

    Chem. Phys. Lett.   Vol. 439   page: 318-322   2007

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  153. Spin, charge and lattice correlation in thiazyl radicals and their molecular compounds Invited Reviewed

    K. Awaga, T. Tanaka, T. Shirai, Y. Umezono, and W. Fujita

    Comp. Rend. Chim.   Vol. 10   page: 52-59   2007

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  154. Magnetic properties and crystal structure of solvent-free Sc@C82 metallofullerene microcrystals Reviewed

    Y. Ito, W. Fujita, T. Okazaki, T. Sugai, K. Awaga, E. Nishibori, M. Takata, M. Sakata, and H. Shinohara

    Chem. Phys. Chem   Vol. 8   page: 1019-1024   2007

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  155. Effects of the unique shape of submicron magnetite hollow spheres on magnetic properties and domain states

    Q.-L. Ye, Y. Kozuka, H. Yoshikawa, K. Awaga, S. Bandow, and S. Iijima

    Phys. Rev. B   Vol. 75   page: 224404/1-224404/5   2007

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  156. Magneto-structural correlation in the Jahn-Teller isomers of Mn12 Reviewed

    K. Awaga, Y. Suzuki, H. Hachisuka, and K. Takeda

    J. Mater. Chem.   Vol. 16   page: 2516-2521   2006

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  157. Single-line EPR spectra from radicals encapsulated in aggregates of amphiphilic block copolymers with hydrophobic dendritic pendants in water

    K. Tamano, T. Tanaka, K. Awaga, T. Imae, S. Yusa, and Y. Shimada

    Macromol. Rapid Commun.   Vol. 27   page: 764-1768   2006

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  158. Multi-dimensional crystal structures and unique solid-state properties of heterocyclic thiazyl radicals and related materials Invited Reviewed

    K.Awaga, T. Tanaka, T. Shirai, M. Fujimori, Y. Suzuki, H. Yoshikawa, and W. Fujita

    Bull. Chem. Soc. Jpn.   Vol. 79   page: 25-34   2006

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  159. Novel spin transition observed in two quasi-one-dimensional spin system based on [M(mnt)2]- monoanion compounds (M=Ni or Pt; mnt2- = maleonitriledithiolate) Reviewed

    X. M. Ren, S. Nishihara, T. Akutagawa, S. Noro, T. Nakamura, W. Fujita, and K. Awaga

    Chem. Phys. Lett.   Vol. 418   page: 423-427   2006

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  160. Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2] Reviewed

    Y. Umezono, W. Fujita, and K. Awaga

    J. Am. Chem. Soc.   Vol. 128   page: 1084-1085   2006

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  161. Quasi-one-dimensional molecular magnets based on derivatives of (fluorobenzyl)pyridinium with the [M(mnt)2] monoanion (M = Ni, Pd or Pt; mnt2- = maleonitriledithiolate): Syntheses, crystal structures andmagnetic properties Reviewed

    X. M. Ren, S. Nishihara, T. Akutagawa, S. Noro, T. Nakamura, W. Fujita, K. Awaga, Z. P. Ni, J. L. Xie, Q. J. Menge, and R. K. Kremer

    Dalton Trans.     page: 1988-1994   2006

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  162. A One-Dimensional Coordination Polymer, BBDTA•InCl4: Possible Spin-Peierls Transition with High Critical Temperature of 108 K

    W. Fujita, K. Awaga, R. Kondo, and S. Kagoshima

    J. Am. Chem. Soc.   Vol. 128   page: 6016-6017   2006

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  163. Low-Field Negative Resistance Effect in a Charge-Ordered State of Thiazyl Radical Crystals Reviewed

    K. Okamoto, T. Tanaka, W. Fujita, K. Awaga, and T. Inabe

    Angew. Chem. Int. Ed.   Vol. 45   page: 4516-4518   2006

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  164. Synthesis, Structure, and Magnetic Properties of [Dithiazolylium]x[M(tdas)2] Salts Reviewed

    S. Staniland, W. Fujita, Y. Umezono, K. Awaga, S. Crawford, S. Parsons, and N. Robertson

    Mol. Cryst. Liq. Cryst.   Vol. 452   page: 123-135   2006

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  165. Phase Selective Preparations and Surface Modifications of Spherical Hollow Nanomagnets Reviewed

    M. Ohnishi, Y. Kozuka, Q.-L. Ye, H. Yoshikawa, K. Awaga, R. Matsuno, M. Kobayashi, A. Takahara, T. Yokoyama, S. Bandow, and S. Iijima

    J. Mater. Chem.   Vol. 16   page: 3215-3220   2006

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  166. D helical polymeric chain with pseudo-53 screw axis formed by cuprophilicity; synthesis and crystal structure of copper(I) pivalate Reviewed

    T. Sugiura, H. Yoshikawa, and K. Awaga

    Inorg. Chem.   Vol. 45   page: 7584-7586   2006

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  167. Ferromagnetic ordering of S=1/2 Heisenberg ferromagnetic chains in organic magnet β-BBDTA•GaBr4 Reviewed

    K. Shimizu, T. Gotohda, T. Matsushita, N. Wada, W. Fujita, K. Awaga, Y. Saiga, and D. S. Hirashima

    Phys. Rev. B   Vol. 74   page: 172413/1-172413/4   2006

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  168. Investigation of structures of tetrakis(thiadiazole)porphyrazine on gold substrate using UHV-STM Reviewed

    T. Terui, S. Mashiko, Y. Suzuki, M. Fujimori, and K. Awaga

    International Journal of Nanoscience,   Vol. 5   page: 889-893   2006

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  169. [BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material

    S. S. Staniland, W. Fujita, Y. Umezono, K. Awaga, S. J. Clark, and N. Robertson

    Inorg. Chem.   Vol. 44   page: 546-551   2005

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  170. A unique new multiband molecular conductor: [BDTA][Ni(dmit)2]2 Reviewed

    S. S. Staniland, W. Fujita, Y. Umezono, K. Awaga, S. J. Clark, H. B. Cui, H. Kobayashi, and N. Robertson

    Chem. Commun.     page: 3204-3206   2005

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  171. Coexistence of ferromagnetic and antiferromagnetic interactions and magnetic ordering in the alternating stacking structure of (BDTA)[Ni(mnt)2]: Possible supramolecular superexchange mechanism Reviewed

    Y. Umezono, W. Fujita, and K. Awaga

    Chem. Phys. Lett.   Vol. 409   page: 139-143   2005

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  172. Structural Phase Transition Driven by Spin-Lattice Interaction in a Quasi-One-Dimensional Spin System of [1-(4'-Iodobenzyl)pyridinium][Ni(mnt)2] Reviewed

    X. M. Ren, T. Akutagawa, S. Nishihara, T. Nakamura, W. Fujita, and K. Awaga

    J. Phys. Chem. B   Vol. 109   page: 16610-16615   2005

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  173. Pressure effects on an organic radical ferromagnet γ-phase BBDTA•GaCl4 Reviewed

    M. Mito, M. Fujino, H. Deguchi, S. Takagi, W. Fujita, and K. Awaga

    Polyhedron   Vol. 24   page: 2501-2504   2005

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  174. A one-dimensional coordination polymer, BBDTA•InCl4; possible spin-Peierls transition with high critical temperature of 108 K Reviewed

    W. Fujita, R. Kondo, S. Kagoshima, and K. Awaga

    J. Am. Chem. Soc.   Vol. 128   page: 6016-6017   2005

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  175. Tetrakis(thiadiazolo)porphyrazines. 4. Direct Template Synthesis, Structure, General Physicochemical Behavior, and Redox Properties of AlIII, GaIII, and InIII Complexes Reviewed

    M. P. Donzello, R. Agostinetto, S. S. Ivanova, M. Fujimori, Y. Suzuki, H. Yoshikawa, J. Shen, K. Awaga, C. Ercolani, K. M. Kadish, and P. A. Stuzhin

    Inorg. Chem.   Vol. 44   page: 8539-8551   2005

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  176. Magnetic susceptibility and magnetization of slightly distorted Kagome magnet, m-EPYNN•BF4 Reviewed

    T. Gotohda, Y. Kugimiya, N. Hamaguchi, T. Matsushita, N. Wada, W. Fujita, and K. Awaga

    J. Phys. Chem. Solids   Vol. 66   page: 1446-1449   2005

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  177. Preparation of 1,3,5-trithia-2,4,6-triazapentalenyl films on gold surfaces

    K. Iketaki, K. Kanai, K. Tsuboi, W. Fujita, K. Awaga, M. Knupfer, Y. Ouchi, and K. Seki

    Synth. Met.   Vol. 153   page: 457-460   2005

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  178. Preparation and magnetic properties of hollow nano-spheres of cobalt and cobalt oxide: Drastic cooling-field effects on remnant magnetization of antiferromagnet Reviewed

    H. Yoshikawa, K. Hayashida, Y. Kozuka, A. Horiguchi, K. Awaga, S. Bandow, and S. Iijima

    Appl. Phys. Lett.   Vol. 85   page: 5287-5289   2004

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  179. Crystal structure and magnetic properties of a thiazyl organic ferromagnet, BBDTA•GaCl4 with Tc=7.0 K

    W. Fujita and K. Awaga

    Chem. Phys. Lett.   Vol. 388   page: 186-189   2004

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  180. Structural Phase Transition in Two-Dimensional kagome Antiferromagnet m-N-Methylpyridinium α-nitronyl nitroxide•BF4•1/3(Acetone)

    T. Kambe, Y. Nogami, K. Oshima, W. Fujita, and K. Awaga

    J. Phys. Soc. Japan.   Vol. 73   page: 796-799   2004

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  181. Pressure effects on magnetic bistability in a heterocyclic thiazyl radical TTTA

    T. Tanaka, W. Fujita, and K. Awaga

    Chem. Phys. Lett.   Vol. 393   page: 150-152   2004

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  182. Packing Motifs and Magneto-Structural Correlations in Crystal structures of Metallo-Tetrakis(1,2,5-thiadiazole)porphyrazine Series, TTDPzM (M = H2, Fe, Co, Ni, Cu, Zn)

    Y. Suzuki, M. Fujimori, H. Yoshikawa, and K. Awaga

    Chem. Euro. J.   Vol. 10   page: 5158-5164   2004

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  183. Comparison of 55Mn NMR between two kinds of Mn12 molecular magnets: Mn12Ac and Mn12Ph

    T. Kubo, A. Nagano, T. Goto, K. Takeda, and K. Awaga

    J. Magn. Magn. Mater.   Vol. 272-276   page: E727-E729   2004

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  184. ESR study on the distorted kagome antiferromagnet m-MPYNN•BF4•1/3 acetone

    T. Kambe, K. Oshima, W. Fujita, and K. Awaga

    J. Magn. Magn. Mater.   Vol. 272-276   page: E1041-E1043   2004

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  185. Structure and magnetic properties of single-molecule magnet [Mn11CrO12(O2CCH3)16(H2O)4] •2CH3COOH•4H2O: Magnetization manipulation and dipolar-biased tunneling in Mn11Cr/Mn12 mixed crystal Reviewed

    H. Hachisuka, K. Awaga, T. Yokoyama, T. Kubo, T. Goto, and H. Nojiri

    Phys. Rev. B.   Vol. 70   page: 104427   2004

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  186. Crystal structures and magnetic properties of (m- or p-MPYNN)2 NiII(tdas)2

    T. Okuno, K. Kuwamoto, W. Fujita, K. Awaga, and W. Nakanishi

    Polyhedron   Vol. 22   page: 2311-2315   2003

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  187. Transverse and longitudinal relaxations of 55Mn in the molecular cluster magnet Mn12O12(CH3COO)16(H2O)4

    T. Goto, T. Koshiba, T. Kubo, and K. Awaga

    Phys. Rev. B   Vol. 67   page: 104408   2003

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  188. Enhancement of Jahn-Teller isomerism in Mn12Ac under high quasi-hydrostatic pressure

    Y. Suzuki, K. Takeda, and K. Awaga

    Phys. Rev. B   Vol. 67   page: 132402   2003

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  189. Photoinduced Phase Transition in an Organic Radical Crystal with Room-Temperature Optical and Magnetic Bistability

    H. Matsuzaki, W. Fujita, K. Awaga, and H. Okamoto

    Phys. Rev. Lett.   Vol. 91   page: 017403   2003

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  190. Packing Motifs in Porphyrazine Macrocycles Carrying Peripherally Annulated Thiadiazole Rings: Crystal Growths of Metal-Free and Cobalt Tetrakis(1,2,5-thiadiazole)porphyrazines

    M. Fujimori, Y. Suzuki, H. Yoshikawa, and K. Awaga

    Angew. Chem. Int. Ed.   Vol. 42   page: 5863-5865   2003

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  191. μSR study on a metal complex having a ferromagnetic linear chain p-NPNN•Cu(hfac)2

    S. Ohira, K. Awaga, W. Fujita, I. Watanabe, and K. Nagamine

    Physica B   Vol. 326   page: 568-571   2003

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  192. μSR study of [Mn12O12(O2CC6H5)16(H2O)4]•2C6H5CO2H

    K. Takeda, K. Awaga, S. Ohira, and I. Watanabe

    Synth. Met.   Vol. 133-134   page: 609-610   2003

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  193. Paramagnetic-diamagnetic phase transition and magnetic ordering in thiazyl radicals

    W. Fujita and K. Awaga

    Synth. Met.   Vol. 137   page: 1263-1265   2003

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  194. 1H-NMR study of the 2D spin-gap system m-MPYNN•BF4

    Y. Fujii, T. Goto, W. Fujita, and K. Awaga

    Physica B   Vol. 329   page: 973-974   2003

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  195. 55Mn NMR in Mn12 acetate: quantum tunneling and magnetic relaxation of Mn12 cluster

    T. Kubo, H. Doi, B. Imanari, T. Goto, K. Takeda, and K. Awaga

    Physica B   Vol. 329   page: Physica B   2003

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  196. Unusual magnetization reversal of Mn12 cluster in ultra-fast sweeping fields

    T. Taniguchi, H. Nojiri, K. Takeda, and K. Awaga

    Physica B   Vol. 329   page: 1179-1180   2003

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  197. Observation of avalanche effect of the spin reversal in Mn12Ac by 55Mn NMR

    T. Goto, T. Koshiba, A. Oyamada, T. Kubo, Y. Suzuki, K. Awaga, B. Barbara, and J. P. Boucher

    Physica B   Vol. 329   page: 1185-1186   2003

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  198. Spin density distributions of p-N-alkylpyridinium nitronyl nitroxides studied by solid-state high-resolution NMR

    G. Maruta, S.Takeda, A. Yamaguchi, T. Okuno, and K. Awaga

    Polyhedron   Vol. 22   page: 1989-1994   2003

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  199. Room-temperature magnetic bistability in organic radical crystals: Paramagnetic-diamagnetic phase transition in 1,3,5-trithia-2,4,6-triazapentalenyl

    W. Fujita, K. Awaga, H. Matsuzaki, and H. Okamoto

    Phys. Rev. B   Vol. 65   page: 064434   2002

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  200. Observation of Magnetic Transition in Quantum Nanomagnet Mn4Br

    A. Yamaguchi, N. Kusumi, H. Ishimoto, H. Mitamura, T. Goto, N. Mori, M. Nakano, K. Awaga, J. Yoo, D. N. Hendrickson, and G. Christou

    J. Phys. Soc. Jpn.   Vol. 71   page: 414-417   2002

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  201. Complex phase transitions in stable thiazyl radicals: spin-gap, antiferromagnetic ordering and double melting

    W. Fujita, K. Awaga, Y. Nakazawa, K. Saito, and M. Sorai

    Chem. Phys. Lett.   Vol. 352   page: 348-352.   2002

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  202. Magnetic anisotropy, tunneling effects, high-frequency EPR, and molecular structure of fast-relaxation species of Mn12

    K. Takeda, K. Awaga, T. Inabe, A. Yamaguchi, H. Ishimoto, T. Tomita, H. Mitamura, T. Goto. N. Mori, and H. Nojiri

    Phys. Rev. B   Vol. 65   page: 094424   2002

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  203. Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent

    W. Fujita and K. Awaga

    Chem. Phys. Lett.   Vol. 357   page: 385-388   2002

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    Language:English   Publishing type:Research paper (scientific journal)  

  204. 55Mn NMR in Mn12 acetate: Hyperfine interaction and magnetic relaxation of the cluster

    T. Kubo, T. Goto, T. Koshiba, K. Takeda, and K. Awaga

    Phys. Rev. B   Vol. 65   page: 224425   2002

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  205. ynthesis, Structure and Magnetic Properties of the Antiferromagnetic Hexamanganese Cluster [Mn6(μ4-O)2(O2CC6HF4)10(HO2CCH3)4]•(C7H8)

    K. Nakata, H. Miyasaka, T. Ishii, M. Yamashita, and K. Awaga

    Mol. Cryst. Liq. Cryst.   Vol. 379   page: 211-216   2002

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  206. “Spontaneous magnetization below 44 K in (benzo[1,2-d:4,5-d']bis[1,3,2]dithiazole)•FeCl4 driven by evaporation of crystal solvent"

    W. Fujita, K. Awaga, M. Takahashi, M. Takeda, and T. Yamazaki

    Chem. Phys. Lett.   Vol. 362   page: 97-102   2002

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  207. Intercalation of stable organic radicals into layered copper hydroxides

    W. Fujita and K. Awaga

    Synth. Met.   Vol. 122   page: 569-572   2001

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  208. Ferromagnetic Coordination Polymer Composed of Heterocyclic Thiazyl Radical, 1,3,5-Trithia-2,4,6-triazapentalenyl (TTTA), and Bis(hexafluoroacetylacetonato)copper(II) (Cu(hfac)2)

    W. Fujita and K. Awaga

    J. Am. Chem. Soc.   Vol. 123   page: 3601-3602   2001

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  209. Diversity in the 1/2 spin arrangement of [Ni(dmit)2]- anions in divalent Ca2+(crown ether) supramolecular cation salts

    T. Akutagawa, N. Takamatsu, K. Shitagami, T. Hasegawa, T. Nakamura, T. Inabe, W. Fujita, and K. Awaga

    J. Mater. Chem.   Vol. 11   page: 2118-2124   2001

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  210. Inner- and outer-sphere magnetic moments in cobalt-quinone valence tautomeric system

    A. Yamaguchi and K. Awaga

    J. Mater. Chem.   Vol. 11   page: 2142-2145   2001

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  211. β"-(ET)3(MnCl4)(1,1,2-C2H3Cl3) (ET = bis(ethylenedithio)tetrathiafulvalene); a pressure-sensitive new molecular conductor with localized spins

    T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, and H. Tajima

    J. Mater. Chem.   Vol. 11   page: 2221-2227   2001

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  212. Magnetic Conversion Induced by Non-Magnetic Impurities in a Molecular Spin Ladder System, p-EPYNN•[Ni(dmit)2]

    T. Otsuka, M. Yoshimaru, K. Awaga, H. Imai, T. Inabe, N. Wada, and M. Ogata

    J. Phys. Soc. Jpn.   Vol. 70   page: 2711-2716   2001

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  213. Room-Temperature Magnetic Bistability in Organic Crystals: A Comparison with Spin Crossover Transitions

    W. Fujita and K. Awaga

    J. Solid State Chem.   Vol. 159   page: 451-454   2001

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  214. The observation of magnetization behavior of the nano-scale cluster magnet Mn12ac by 55Mn NMR

    T. Kubo, T. Koshiba, T. Goto, A. Oyamada, Y. Fujii, K. Takeda, and K. Awaga

    Physica B   Vol. 294-295   page: 310-313   2001

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  215. Peculiar physical properties of (ET)3(MnCl4)(TCE)

    T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, and H. Tajima

    Synth. Met.   Vol. 120   page: 877-878   2001

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  216. Physical and structural properties of the Ni(DMIT)2 ladder chain

    H. Imai, T. Naito, K. Awaga, and T. Inabe

    Synth. Met.   Vol. 120   page: 951-952   2001

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  217. Paramagnetic-diamagnetic phase transitions in organic radical crystals

    W. Fujita and K. Awaga

    Synth. Met.   Vol. 121   page: 1767-1769   2001

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  218. Novel magnetic properties of heterocyclic thiazyl radicals

    W. Fujita and K. Awaga

    Polyhedron   Vol. 20   page: 1517-1519   2001

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  219. Magnetic Behavior of the Layered Perovskite Ferromagnet(p-Cyanoanilinium+)2CuCl42- under Hydrostatic Pressure.

    Chem.Phys.Lett.   Vol. 249   page: 201   1996

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  220. Intermolecular Arrangements of p-Substituted Aniliniums in the Interlayer of Cupric Chloride

    Mol.Cryst.Liq.Cryst.   Vol. 279   page: 65   1996

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  221. Magnetic Properties of Cu2(OH)3(alkanecarboxylate) : Drastic Modification with Extension of the Alkyl Chain

    Inorg.Chem.   Vol. 35   page: 1915   1996

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  222. Intercalation of functional organic molecules into copper(II) magnetic materials

    Mol.Cryst.Liq.Cryst.   Vol. 286   page: 1   1996

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  223. Nuclear Magnetic Relaxation of 1H in Organic Cation Radical Salt m-MPYNN+X-(X=ClO4,BF4)

    Czecho.J.Phys.   Vol. 46   page: 2213   1996

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  224. M(]J1151[)ssbauer Spectroscopic Study of the Reentrant Phase Transitions in TBA[Fe(tdas)2]

    Mol.Cryst.Liq.Cryst.   Vol. 286   page: 77   1996

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  225. Molecular Complexes of Extended Sulphur Donor Ligands

    Mol.Cryst.Liq.Cryst.   Vol. 284   page: 39   1996

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  226. [NHN]+ Hydrogen Bond in Organic Radical Solid

    Mol.Cryst.Liq.Cryst.   Vol. 279   page: 57   1996

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  227. Molecular spin ladder in the Ni(dmit)2 (dmit=1,3-dithiol-2-thione-4,5-dithiolate) salt with a nitronyl nitroxide cation

    Phys.Rev.B   Vol. 54   page: 6838   1996

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  228. Crystal Structures and Magnetic Properties of MCl42-(M=Mn(II) and Co(II)) Salts of m- and p-N-Methylpyridinium Nitronyl Nitroxides

    Bull.Chem.Soc.Japan   Vol. 69   page: 875   1996

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  229. Crystal Structures and Magnetic Properties of (Pyridinium Nitronyl Nitroxide)・X : Possible Spin-1 <u>Kagome</u> Antiferromagnet

    <u>Synth. Metals</u>   Vol. 71   page: 1807   1995

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  230. Ferromagnetic Resonance and Nonlinear Absorption in <u>p</u>-NPNN

    <u>Synth. Metals</u>   Vol. 71   page: 1821   1995

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  231. EPR Studies of the 2-D Magnetic System in an Organic Cation Radical Salt, <u>m</u>-MPYNN+・X-

    <u>Synth. Metals</u>   Vol. 71   page: 1797   1995

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  232. Coexistence of Intermolecular Ferromagnetic Interaction and [NHN]+ Hydrogen Bond in <u>N</u>-Protonated <u>m</u>-Pyridyl Nitronyl Nitroxide

    <u>J. Chem. Soc. Chem. Commun. </u>     page: 827   1995

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  233. Preparation and Magnetic Property of Saponite Clay Intercalated with Stable Organic Radicals

    <u>J. Chem. Soc. Chem. Commun. </u>     page: 739   1995

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  234. Variable Magnetic Interactions in an Organic Radical System of (<u>m-N</u>-Methylpyridinium α-Nitronyl Nitroxide)・X- : A Possible <u>Kagome</u> Antiferromagnet

    Phys. Rev. B   Vol. 49   page: 3975-3981   1994

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  235. Ferromagnetic Intermolecular Interaction of the Cation Radical of <u>m-N</u>-Methylpyridinium Nitronyl Nitroxide, ACASSCF study

    Chem. Phys. Lett.   Vol. 228   page: 575-582   1994

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  236. Structure and Solid-State Properties of the Stable Ring-Oxidized Conductor CoPc(AsF6)0.5 : Interaction between Ring π-Electrons and Cobalt d-Electron

    Synth. Metals   Vol. 62   page: 169-178   1994

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  237. Possible 'Re-entrant' Behavior in Magnetic Properties of TBA[Fe(tdas)2] Complex

    <u>Inorg. Chem. </u>   Vol. 33   page: 5598   1994

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  238. Magneto-Structural Correlation in a Series of the Iodide Salts of <u>p-N</u>-Alkylpyridinium Nitronyl Nitroxides : Dependence of the Iodide-Pyridinium Ring Interaction of the Length of the <u>N</u>-Alkyl Chain

    J. Mater. Chem.   Vol. 4   page: 1377-1385   1994

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  239. Ferromagnetic Properties and Crystal Structures of Pyridyl and Pyridinium -Nitronyl Nitroxides

    Synth. Metals   ( 56 ) page: 3311   1993

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  240. Crystal Structures and Magnetic Properties of the p-N-Methylpyridinium Nitronyl Nitroxide Cation Radical Salts, p-MPYNN. I and p-MPYNN. C104

    Chem. Lett.     page: 1443   1993

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  241. Magnetic Properties and Crystal Structure of 1,5-Bis(4-nitrophenyl)-3-t-butyl-verdazyl Radicals

    Mol. Cryst. Liq. Cryst.   ( 232 ) page: 105   1993

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  242. Photoelectron Spectroscopic Studies of an -Nitronyl Nitroxide Radical : Mechanism of Ferromagnetic Intermolecular Interaction

    Mol. Cryst. Liq. Cryst.   ( 232 ) page: 27   1993

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  243. -Nitronyl Nitroxide Cation Radicals : Crystal Engineering for the Molecular Based Organic Ferromagnetism

    Mol. Cryst. Liq. Cryst.   ( 232 ) page: 69   1993

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  244. Crystal Structure and Electronic State of the Organic Ferromagnet, Nitrophenyl -Nitronyl Nitroxide Radical

    Mol. Cryst. Liq. Cryst.   ( 232 ) page: 79   1993

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  245. Ferromagnetic and Antiferromagnetic Intermolecular Interactions in the Two-Dimensional Triangular Lattice of an α-Nitronyl Nitroxide Cation Radical

    Chem. Phys. Lett.     page: 195   1992

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  246. Ferromagnetic Intermolecular Interaction and Crystal Structure of the p-pyridyl nitronyl nitroxide radical

    Chem. Phys. Lett.     page: 190   1992

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  247. Ferromagnetic Interaction in an α-Nitronyl Nitroxide under High Pressure

    Synth. Metals     page: 43   1991

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  248. An Organic Radical Ferromagnet

    Chem. Lett.     1991

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  249. α-Nitronyl Nitroxide Cation Radicals

    Chem. Lett.     1991

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  250. High-Pressure Effects on the Canted Ferromagnetism in Manganese(II) Phthalocyanine

    Phys. Rev. B     page: 44   1991

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  251. Ferromagnetic Coupling in a new Phase of the p-Nitrophenyl Nitronyl Nitroxide

    Chem. Phys. Lett.     page: 180   1991

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  252. Pressure-Induced Enhancement of the Ferromagnetic Intermolecular Interaction of an α-Nitronyl Nitroxide Organic Radical

    Chem. Mater.     page: 2   1990

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  253. Two-Dimensional Network of the Ferromagnetic Organic Radical

    J. Chem. Soc. Chem. Commun.     1989

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Books 31

  1. 物理化学入門

    阿波賀 邦夫( Role: Sole author)

    東京化学同人  2023.3  ( ISBN:978-4-8079-2044-0

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    Language:Japanese Book type:Textbook, survey, introduction

  2. 30. Transition metal complexes and radical anion salts of 1,10-phenanthroline derivatives annulated with a 1,2,5-tiadiazole and 1,2,5-tiadiazole 1,1-dioxide moiety: multidimensional crystal structures and various magnetic properties

    Yoshiaki Shuku, Kunio Awaga( Role: Joint author)

    Molecules  2014 

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    Language:English

  3. Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals

    K. Awaga, K. Nomura, H. Kishida, W. Fujita, H. Yoshikawa, M. M. Matsushita, L. Hu, Y. Shuku, and R. Suizu( Role: Joint author)

    Bull. Chem. Soc. Jpn  2014 

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    Language:English

  4. Electric-double-layer field-effect transistors with ionic liquids

    Takuya Fujimoto, Kunio Awaga( Role: Joint author)

    Phys. Chem. Chem. Phys  2013 

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    Language:English

  5. Handbook of Porphyrin Science "Electrochemical Organic Electronics Based on Robust Thin-Films of Porphyrazines"

    Simon Dalgleish and Kunio Awaga, in Karl M. Kadish, Kevin M. Smith, Roger Guilard (ed.)( Role: Joint author)

    World Scientific  2012 

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    Language:English

  6. ナノラジカル界面からの電子機能発現

    阿波賀邦夫( Role: Sole author)

    未来材料  2011 

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    Language:Japanese

  7. Magnetic and Optical Properties of Submicron-size Hollow Spheres

    Q.-L. Ye, H. Yoshikawa and K. Awaga( Role: Joint author)

    Materials  2010 

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    Language:English

  8. 新しい電池の可能性「分子クラスター電池」とは何か?

    阿波賀邦夫、吉川浩史( Role: Sole author)

    in MATERIAL STAGE  2009.8 

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    Language:Japanese

  9. 分子がつくる新しい磁石

    阿波賀邦夫( Role: Sole author)

    現代化学  2004 

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  10. 発展する物性化学

    阿波賀邦夫( Role: Sole author)

    現代代物性化学の基礎 化学結合論によるアプローチ (小島憲道、下井守)(講談社)  2003 

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  11. 分子集合体とその物性化学

    阿波賀邦夫( Role: Sole author)

    現代物性化学の基礎 化学結合論によるアプローチ (小島憲道、下井守) (講談社)  2003 

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    Language:Japanese

  12. 有機結晶の分子磁性

    阿波賀邦夫( Role: Sole author)

    日本結晶学会誌  2001 

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    Language:Japanese

  13. 有機分子磁性体の新しい展開

    阿波賀邦夫( Role: Sole author)

    応用物理  2001 

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  14. Hybrid organic/inorganic magnets

    K. Awaga, E. Coronado, M. Drillon( Role: Joint author)

    MRS Bull.  2000 

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  15. 層状銅水酸化物Cu2(OH)3Xのユニークな磁気特性

    藤田渉、阿波賀邦夫( Role: Joint author)

    化学総説,「無機有機ナノ複合物質」  1999 

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  16. Unusual crystal structures and properties of nitronylnitroxide radicals. Possible RVB states in molecule-based magnets

    K. Awaga, N. Wada, I. Watanabe, T. Inabe,( Role: Joint author)

    Phil. Trans. R. Soc. Lond. A,  1999 

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  17. Design of Solid-State Ferromagnetic Materials

    Kunio Awaga( Role: Sole author)

    in P. M. Lahti (ed.), “Magnetic Properties of Organic Materials",Marcel Dekker, Inc., New York.  1999 

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  18. Magnetic properties of layered organic/inorganic hybrid materials

    Wataru Fujita, Toshihiko Yokoyama and Kunio Awaga( Role: Joint author)

    in H. Sasabe (ed.), “Hyper-Structured Molecule I",Gordon and Breach Science Publishers.  1999 

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  19. 有機強磁性と有機ラジカルの化学

    阿波賀邦夫( Role: Sole author)

    化学と工業  1999 

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  20. 超微小磁性体Mn12

    阿波賀邦夫( Role: Sole author)

    パリティー  1999 

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  21. Exotic Crystal Structures and Magnetic Properties of Nitronylnitroxide Cation Radical Salts

    K. Awaga, A. Yamaguchi and N. Wada( Role: Joint author)

    J. Veciana, C. Rovira and D.B. Amabilino (ed.), "Superamolecular Engineering of Synthetic Metallic Materials ",Kluwer Academic Publishers, Netherlands.  1999 

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    Language:Japanese

  22. “分子性ナノスケール磁性体 Mn12

    武田啓司,阿波賀邦夫( Role: Joint author)

    固体物理  1999 

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  23. 強磁性的分子間相互作用のメカニズム

    阿波賀邦夫( Role: Sole author)

    化学総説, vol. 35,「&#61552; 電子系有機固体」  1998 

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    Language:Japanese

  24. 新しい分子磁性を求めて

    阿波賀邦夫( Role: Sole author)

    化学  1997 

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  25. Organic Kagome Antiferromagnet, m-MPYNN+・X-

    K. Awaga and N. Wada, in O. Kahn (ed.)( Role: Joint author)

    Kluwer Academic Publishers  1996 

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  26. 分子間磁気相互作用の解明

    阿波賀邦夫・木下実( Role: Joint author)

    分子磁性,伊藤公一編,学会出版センター  1996 

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    Language:Japanese

  27. 有機ラジカル結晶と磁性発現

    木下実・阿波賀邦夫( Role: Joint author)

    分子磁性、伊藤公一編,学会出版センター  1996 

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  28. 有機・分子磁性研究の新しい展開

    阿波賀邦夫( Role: Sole author)

    個体物理  1995 

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  29. 主役を演じるスピン(磁性体の開発)

    阿波賀邦夫( Role: Sole author)

    新・分子の世界 分子科学振興会編,化学同人  1995 

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  30. 磁石になる分子

    阿波賀邦夫( Role: Sole author)

    化学  1994 

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  31. Faraday 法による高圧下での磁気測定

    阿波賀邦夫・丸山有成( Role: Joint author)

    固体物理  1992 

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    Language:Japanese

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Presentations 158

  1. Molecular Mimics of Carbon Materials: Rational Design, Physical Properties, and Solid-State Electrochemistry Invited

    2024.3.20 

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    Event date: 2024.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  2. Molecular Mimics of Carbon Materials: Rational Design, Physical Properties, and Solid-State Electrochemistry Invited

    Energy Storage and Conversion with Molecule-Based Materials  2023.10.10  Paris-Saclay University

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    Event date: 2023.11

    Language:English   Presentation type:Public lecture, seminar, tutorial, course, or other speech  

    Venue:Paris   Country:France  

  3. Energy Storage and Conversion with Molecule-Based Materials Invited International conference

    Energy Storage and Conversion with Molecule-Based Materials  2023.11.9  Hangynag University

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    Event date: 2023.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Seoul   Country:Korea, Republic of  

  4. Optoelectronic conversion and polarization hysteresis in organic MISIM devises with DA-type single component molecules Invited International conference

    Faraday Discusssion: Optoelectronic conversion and polarization hysteresis in organic MISIM devises with DA-type single component molecules  2023.11.6  Royal Society of Chemistry

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    Event date: 2023.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  5. 有機中性ラジカル、ガルビノキシルの反磁性低温相の結晶構造

    阿波賀 邦夫

    第31回有機結晶シンポジウム  2023.11.3 

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    Event date: 2023.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:大阪   Country:Japan  

  6. Solid-State Electrochemistry on Supramolecular Assemblies with Strong Isotropic Property Invited International conference

    2023.5.28  THE ELECTROCHEMICAL SOCIETY

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    Event date: 2023.5 - 2023.6

    Language:English  

    Venue:Boston, MA   Country:United States  

  7. Physics and Chemistry of Strongly-Isotropic Structures

    日野研究会(E-USE 研究会2023) 

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    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  8. 想像の共有がもたらすウェルビーイング

    阿波賀 邦夫

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    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  9. Photo-induced displacement current and field-induced polarization in organic MISIM cells International conference

    Kunio Awaga

    The China-Japan Bilateral Symposium on Material Science 2022 

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    Event date: 2022.12

    Language:English   Presentation type:Oral presentation (keynote)  

    Country:Japan  

  10. Carrier Injection through Electroc Double Layer at Metal-Electrolyte Interface in Field Effect Transistors International conference

    Kunio Awaga

    IVC-22 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  11. Chemical potentials of electric double layers at metal-electrolyte interfaces: application to eield-effect transistors and photocells Invited International conference

    Kunio Awaga

    Pacifichem2021  2021.12.20 

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    Event date: 2021.12

    Language:English   Presentation type:Oral presentation (invited, special)  

  12. Developments of molecule-based carbon allotropes Invited International conference

    Kunio Awaga

    Pacifichem2021  2021.12.20  Pacifichem 2021 Organizing

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    Event date: 2021.12

    Language:English   Presentation type:Oral presentation (invited, special)  

  13. 固液界面電気二重層トランジスタと光電変換

    阿波賀 邦夫

    第11回イオン液体討論会  2021.11.19 

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    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (keynote)  

    Country:Japan  

  14. トポロジカル分子スピン系の物質科学

    阿波賀 邦夫

    日本磁気学会 第80回スピントロニクス専門研究会  2021.9.30 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  15. Topological Properties Generated by Molecule-Based Strongly Isotropic Structures: Materials Science Driven by Mathematics International conference

    Kunio Awaga

    International Conference on Discrete Geometric Analysis for Materials Design  2021.9.26 

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    Event date: 2021.9

    Language:English   Presentation type:Oral presentation (keynote)  

    Country:Japan  

  16. 界面分極を利用した有機デバイス:光電変換と分極ヒステリシス

    阿波賀 邦夫

    日本学術振興会「分子系の複合電子機能第181委員会」第37回研究会「先端電子材料」  2021.7.28 

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    Event date: 2021.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  17. 分子性強等方性構造が生み出すトポロジー物性:数学に後押しされた物質科学

    阿波賀 邦夫

    第10回分子性固体セミナー  2021.6.3 

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    Event date: 2021.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  18. Development of Molecular Mimics of Carbon Allotropes Invited

    Kunio Awaga

    The 4th international symposium of RCMS  2021.3.15 

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    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  19. Development of Molecular Mimics of Carbon Allotropes Invited

    Kunio Awaga

    1st Asian Conference Molecular Magnetism  2021.3.10 

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    Event date: 2021.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  20. Quantum Spin Liquid State in Organic Hyper-Kagome Lattice of Mott Dimers Invited

    Kunio Awaga

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    Event date: 2019.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  21. Quantum Spin Liquid State in Organic Hyper-Kagome Lattice of Mott Dimers Invited

    Kunio Awaga

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    Event date: 2019.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  22. 有機エレクトロニクスの基礎から最先端まで Invited

    阿波賀 邦夫

    有機固体若手の会 2018秋の学校 

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    Event date: 2018.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  23. 有機エレクトロニクスの基礎から最先端まで Invited

    阿波賀 邦夫

    有機固体若手の会 2018秋の学校 

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    Event date: 2018.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  24. 分極電流を利用した有機光電変換 Invited

    阿波賀 邦夫

    第22回VBLシンポジウム 

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    Event date: 2018.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  25. 分極電流を利用した有機光電変換 Invited

    阿波賀 邦夫

    第22回VBLシンポジウム 

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    Event date: 2018.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  26. Molecule-Based Mimics of Carbon Allotropes Invited

    Kunio Awaga

    The Toyota Riken International Workshop 

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    Event date: 2018.10

    Language:English   Presentation type:Oral presentation (invited, special)  

  27. Molecule-Based Mimics of Carbon Allotropes Invited

    Kunio Awaga

    The Toyota Riken International Workshop 

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    Event date: 2018.10

    Language:English   Presentation type:Oral presentation (invited, special)  

  28. Fundamentals and Applications of Highly-Correlated Electron Systems, Formed by Organic Radicals Invited

    Kunio Awaga

    Universite de Rennes1 Seminar, 

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    Event date: 2018.9

    Language:English   Presentation type:Oral presentation (invited, special)  

  29. Fundamentals and Applications of Highly-Correlated Electron Systems, Formed by Organic Radicals Invited

    Kunio Awaga

    Universite de Rennes1 Seminar, 

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    Event date: 2018.9

    Language:English   Presentation type:Oral presentation (invited, special)  

  30. Fundamentals and Applications of Highly-Correlated Electron Systems, Formed by Organic Radicals Invited

    Kunio Awaga

    8th International Workshop“Organic Electronics of Highly-Correlated Molecular Systems” 

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    Event date: 2018.9

    Language:English   Presentation type:Oral presentation (invited, special)  

  31. Fundamentals and Applications of Highly-Correlated Electron Systems, Formed by Organic Radicals Invited

    Kunio Awaga

    8th International Workshop“Organic Electronics of Highly-Correlated Molecular Systems” 

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    Event date: 2018.9

    Language:English   Presentation type:Oral presentation (invited, special)  

  32. Multi-dimensional magnetic systems formed by polyhedral π-conjugated radicals Invited

    Kunio Awaga

    ICCC2018 

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    Event date: 2018.7 - 2018.8

    Language:English   Presentation type:Oral presentation (keynote)  

  33. Multi-dimensional magnetic systems formed by polyhedral π-conjugated radicals Invited

    Kunio Awaga

    ICCC2018 

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    Event date: 2018.7 - 2018.8

    Language:English   Presentation type:Oral presentation (keynote)  

  34. Spin Liquid States in Spin-Frustrated Systems of Organic Radicals Invited

    Kunio Awaga

    ICM2018 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  35. Spin Liquid States in Spin-Frustrated Systems of Organic Radicals Invited

    Kunio Awaga

    ICM2018 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  36. Physics and Chemistry of Molecule-Based Mimics of Carbon Allotropes Invited

    Kunio Awaga

    Colloquium in Freie University 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  37. Physics and Chemistry of Molecule-Based Mimics of Carbon Allotropes Invited

    Kunio Awaga

    Colloquium in Freie University 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  38. Template Effects on Porphyrazine Thin Films toward Application to Organic Electronics Invited

    Kunio Awaga

    ICPP-10 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  39. Template Effects on Porphyrazine Thin Films toward Application to Organic Electronics Invited

    Kunio Awaga

    ICPP-10 

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  40. 分子ジャイロイドとその波及効果 Invited

    阿波賀邦夫

    東北大学金属材料研究所共同利用・共同研究ワークショップ「多自由度・多階層性が協奏する物質材料システムの科学」 

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    Event date: 2017.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:仙台市(東北大学金属材料研究所講堂)   Country:Japan  

  41. 有機ラジカル分子が魅せる幾何学的フラストレーション Invited

    阿波賀邦夫

    離散幾何解析とその周辺 2017 

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    Event date: 2017.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京都(CIC東京 5F501)    Country:Japan  

  42. リチウムー硫黄電池の正極材料の開発 Invited

    阿波賀 邦夫、Yang Wu、Zhongyue Zhang、山﨑郁乃

    分子・物質合成プラットフォーム 平成29年度シンポジウム 

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    Event date: 2017.6

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  43. Energy and Information Conversion Assisted by Electric Double Layers at Liquid-Solid Nano-Interfaces International conference

    Kunio Awaga

    231st ECS Meeting 

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    Event date: 2017.5 - 2017.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:New Orleans, USA   Country:United States  

  44. Template Effects of Tetrakis(thiadiazole) Porphyrazine to the Structures of Phthalocyanine Thins Films International conference

    Kunio Awaga

    231st ECS Meeting 

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    Event date: 2017.5 - 2017.6

    Language:English   Presentation type:Oral presentation (general)  

    Venue:New Orleans, USA   Country:United States  

  45. 分子性ポーラス物質を利用した2次電池の開発 Invited

    阿波賀邦夫

    一般社団法人近畿化学協会 機能性色素部会「有機材料と二次電池」 

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    Event date: 2017.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:大阪(大阪化学技術センター)   Country:Japan  

  46. 分子性K4 構造の化学構築 Invited International conference

    阿波賀邦夫

    統合物質創製化学研究推進機構 第2回国内シンポジウム「統合物質創製を目指す融合研究」 

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    Event date: 2017.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:札幌   Country:Japan  

  47. Organic Transistors and Opto-Electronic Conversion Assisted by Electric Double Layers at Liquid-Solid Interfaces Invited International conference

    Kunio Awaga

    The 2016 MRS Fall Meeting & Exhibit 

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    Event date: 2016.11 - 2016.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue: Boston, USA   Country:United States  

  48. Redox-Active Molecule-Based Frameworks for Energy Storage- Rechargeable Li Batteries of Molecular Clusters, MOFs and COFs Invited International conference

    Kunio Awaga

    The 2016 MRS Fall Meeting & Exhibit 

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    Event date: 2016.11 - 2016.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue: Boston, USA   Country:United States  

  49. 三角πラジカルがつくる K4 構造とハイパーカゴメ格子   Invited

    阿波賀邦夫・水野麻人・ 珠玖良昭,・松下未知雄,・土射津昌久,・和田信雄

    第55回電子スピンサイエンス学会2016年11月11日 

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    Event date: 2016.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:大阪市(大阪市立大学)   Country:Japan  

  50. EDL Organic Transistors and Photocells Invited International conference

    Kunio Awaga

    The 12th Japan-China bilateral symposium  

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    Event date: 2016.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue: Tokyo(Waseda Univ.)   Country:Japan  

  51. Core-to-Core Project on Organic electronics of highly-correlated molecular systems International conference

    Kunio Awaga

    JSPS Core-to-Core / Leverhulme Trust 5th Joint Workshop on Organic Electronics of Highly-Correlated Molecular Systems 

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    Event date: 2016.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Novosibirsk, Russia   Country:Russian Federation  

  52. Structural and Physical Properties of Highly-Correlated Electron Systems in Thiazyl Radicals Invited International conference

    Kunio Awaga

    MolMag-2016 

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    Event date: 2016.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Novosibirsk, Russia   Country:Russian Federation  

  53. K4 Structure Formed by a Triangular π Radical Anion Invited International conference

    Kunio Awaga

    ICMM2016 

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    Event date: 2016.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  54. 物性化学と固体電気化学の融合から生まれる新しいエネルギー Invited

    阿波賀邦夫

    XAFS討論会 

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    Event date: 2016.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:名古屋   Country:Japan  

  55. Organic Electronics of Phthalocyanines Assisted by Electric Double Layers in Ionic Liquids Invited International conference

    Kunio Awaga

    ICPP-9 

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    Event date: 2016.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Nangin, China   Country:China  

  56. Crossroads between Organic Electronics and Solid-State Electrochemistry Invited International conference

    Kunio Awaga

    ICCMSE2016 

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    Event date: 2016.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Athens, Greece   Country:Greece  

  57. 分子性K4構造の構築とその物性 Invited

    阿波賀邦夫

    第8回東北大学研究会 

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    Event date: 2016.2

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:仙台(東北大学)   Country:Japan  

  58. 電気2重層光電セルが生み出す情報変換とエネルギー変換 Invited

    阿波賀邦夫

    情報科学用有機材料 第142委員B部会研究会 

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    Event date: 2016.1

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京(東京理科大学)   Country:Japan  

  59. Versatile electric and magnetic properties of radical-anion salts with multidimensional crystal structures Invited International conference

    Kunio Awaga

    PACIFICHEM 2015 

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Hawaii, USA   Country:United States  

  60. Molecular magnetism controlled by solid-state electrochemistry Invited International conference

    Kunio Awaga

    PACIFICHEM 2015 

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Hawaii, USA   Country:United States  

  61. Molecular cluster batteries of nano-hybrid materials between POMs and nanocarbon Invited International conference

    Kunio Awaga

    PACIFICHEM 2015 

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Hawaii, USA   Country:United States  

  62. Solid-State Electrochemistry For Energy and Information Conversions Invited International conference

    Kunio Awaga

    2015 CAMPUS Asia Symposium Chemical Frontier and Advanced Materials 

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    Event date: 2015.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Shanghai, China   Country:China  

  63. Electron-Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals and Related Materials International conference

    Kunio Awaga

    Core-to-Core / Leverhulme Trust Third Joint Workshop on Organic Electronics of Highly-Correlated Molecular Systems 

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    Event date: 2015.10

    Language:English   Presentation type:Oral presentation (general)  

    Country:Russian Federation  

  64. 物性化学と固体電気化学の接点

    阿波賀邦夫

    第9回分子科学討論会 

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    Event date: 2015.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京(東工大)   Country:Japan  

  65. 物性化学と固体電気化学の接点

    阿波賀邦夫

    錯体化学若手の会 夏の学校2015 

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    Event date: 2015.8

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:山口   Country:Japan  

  66. Organic Radical Crystals: From Structural Transformations to Electronic Functions International conference

    Kunio Awaga

    the 22nd International Conference on the Chemistry of the Organic Solid State (ICCOSS XXII) 

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    Event date: 2015.7

    Language:English   Presentation type:Oral presentation (keynote)  

    Country:Japan  

  67. Solid-State Electrochemistry of Organic Macrocycles and Mofs: Application to Organic Electronics and Energy Storage International conference

    Kunio Awaga

    227th ECS Meeting 

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    Event date: 2015.5

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  68. 分子磁性体研究

    阿波賀邦夫

    所長招聘研究会「分子導体研究の展開」 

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    Event date: 2015.4

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:岡崎   Country:Japan  

  69. 有機スピン系に現れる新しいスピン構造とフラストレーション

    阿波賀邦夫

    第14回CROSSroads「スピン系とフラストレーション」 

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    Event date: 2015.2

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:いばらぎ東海村   Country:Japan  

  70. 物性化学と電気化学の接点

    阿波賀邦夫

    短期研究会「有機固体化学の最前線」 

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    Event date: 2014.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:松山   Country:Japan  

  71. Crystal Structures and Solid-State Properties of Thiazyl Radicals and Their Related Compounds International conference

    Kunio Awaga

    JSPS Core-to-Core/Leverhulme Trust Joint Workshop, Otaru 2014 

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    Event date: 2014.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  72. Paramagnetic n-type organic semiconductor VOTTDPz and ambipolar transport in phase-separated thin-films with p-type VOPcH International conference

    Kunio Awaga

    5th International Meeting on Spin in Organic Semiconductors 

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    Event date: 2014.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  73. Organic Transistors and Photocells Assisted by Ionic Liquids International conference

    Kunio Awaga

    XXIII INTERNATIONAL MATERIALS RESEARCH CONGRESS 2014  

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    Event date: 2014.8

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Mexico  

  74. Solid-State Properties of Organic Radicals: Fundamentals and Applications in International conference

    Kunio Awaga

    Gordon Research Conferences 2014 

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    Event date: 2014.8

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  75. Molecular magnetism and organic electronics under solid-state electrochemistry International conference

    Kunio Awaga

    International Conference on Molecule-Based Magnets (ICMM 2014) 

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    Event date: 2014.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Russian Federation  

  76. Organic Electronics Assisted by Electric Double Layers in Ionic Liquids International conference

    Kunio Awaga

    NIMS Conference 2014 

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    Event date: 2014.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  77. Electrochemical Carrier Injections in the Thin-Films of Porphyrazines and International conference

    Kunio Awaga

    International Conference on Porphyrins and Phthalocyanines (ICPP-8) 

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    Event date: 2014.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Turkey  

  78. イオン液体を利用した電気二重層トランジスタと光電流変換

    阿波賀 邦夫

    平成26年イオン液体研究会 

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    Event date: 2014.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京   Country:Japan  

  79. 分子磁性研究の新潮流:有機エレクトロニクスと固体電気化学への発展

    阿波賀 邦夫

    日本磁気学会 第196回研究会 

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    Event date: 2014.5

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京   Country:Japan  

  80. 固液界面がもたらす新しい分子機能―蓄電機能と光電流変換

    阿波賀 邦夫

    第24回神奈川大学平塚シンポジウム 

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    Event date: 2014.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:平塚   Country:Japan  

  81. 固液界面がもたらす新しい分子機能―蓄電機能と光電流変換

    阿波賀 邦夫

    分子システム研究成果報告シンポジウム 

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    Event date: 2014.2

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:つくば   Country:Japan  

  82. ナノラジカル界面からの電子機能発現

    阿波賀 邦夫

    短期研究会「有機固体化学の最前線」 

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    Event date: 2013.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:松山   Country:Japan  

  83. Battery application of Nanocarbon Materials International conference

    Kunio Awaga

    SKKU-NU Joint Symposium on Synthesis, Properties and Applications of Carbon Nano Tubes and Graphene 

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    Event date: 2013.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  84. Electron Transfer Processes in Highly-Correlated Electron Systems of Thiazyl Radicals International conference

    Kunio Awaga

    7th Japanese- Russian International Workshop on Open Shell Compounds and Molecular Spin Devices 

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    Event date: 2013.11

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  85. Solid-State Electrochemistry for Molecular Magnetism and Organic Electronics International conference

    Kunio Awaga

    Seminar in Universite Pierre et Marie Curie 

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    Event date: 2013.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:France  

  86. Organic Electronics with Ionic Liquids International conference

    Kunio Awaga

    16th IRTG Joint Symposium 

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    Event date: 2013.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Germany  

  87. Organic Electronics Assisted by Ionic Liquids International conference

    Kunio Awaga

    International Workshop on Organic Magneto-Optics,Magneto-Electronics, and Magneto-Thermoelectrics 

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    Event date: 2013.10

    Language:English   Presentation type:Oral presentation (keynote)  

    Country:China  

  88. Anomalous Transient Photocurrent in Organic Photocells and its Application to Optical Communication International conference

    Kunio Awaga

    The 11th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena 

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    Event date: 2013.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:China  

  89. 電池反応における in operando 計測

    阿波賀 邦夫

    黒田・太田シンポジウム 

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    Event date: 2013.8

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:つくば   Country:Japan  

  90. Electric-Double-Layer Interfaces Applied to Organic Electronics: Optoelectronic Conversion and Molecular Cluster Batteries

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    Event date: 2013.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  91. Electric-Double-Layer Interfaces Applied to Organic Electronics: Optoelectronic Conversion and Molecular Cluster Batteries International conference

    Kunio Awaga

    11th International Conference on Materials Chemistry (MC11) 

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    Event date: 2013.7

    Language:English   Presentation type:Oral presentation (keynote)  

    Country:United Kingdom  

  92. ナノラジカル界面の電子機能発現 International conference

    阿波賀 邦夫

    日本化学会第93春季年会 「分子エレクトロニクスから分子スピントロニクスへの展望」 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:滋賀 びわ湖   Country:Japan  

  93. 多重機能分子性界面がもたらす光・電子物性

    阿波賀 邦夫

    日本化学会第93春季年会 「次元性がもたらす分子性材料の多重機能化」 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:滋賀 びわ湖   Country:Japan  

  94. 女性博士リーダーの育成:グリーン自然科学国際研究教育プログラムの取組

    阿波賀 邦夫

    日本化学会第93春季年会 「日本化学会男女共同参画推進委員会企画 第13回シンポジウム あなたがリーダーになるために~第1回女性化学者奨励賞受賞者紹介~」 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:滋賀 びわ湖   Country:Japan  

  95. 分子クラスター二次電池の発展

    阿波賀邦夫、吉川浩史、山田哲也

    大阪電気通信大学 エレクトロニクス基礎研究所 ワークショップ「革新型二次電池の開発現状と将来展望」 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:大阪   Country:Japan  

  96. Redox-Active Nano-Interfaces in Organic/Molecular Electronics International conference

    Kunio Awaga

    The fourth China-Japan bilateral workshop on materials Science 

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    Event date: 2013.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:China  

  97. 固液界面の電子移動に起因する新しい物性化学

    阿波賀邦夫

    文部科学省 「革新的ハイパフォーマンス・コンピューティング・インフラ(HPCI)の構築」第2回実験化学との交流シンポジウム 

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    Event date: 2012.11

    Language:English   Presentation type:Oral presentation (general)  

    Venue:京都   Country:Japan  

  98. Molecular Magnetism of Redox Active Materials at Electrode Interfaces International conference

    Kunio Awaga

    13th International Conference on Molecule-based Magnets 

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    Event date: 2012.10

    Language:English   Presentation type:Oral presentation (general)  

    Country:United States  

  99. Paramagnetic n-Type Transistors of Porphyrazine Compounds International conference

    kunio Awaga

    4th International Meeting on Spins in Organic Semiconductors 

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    Event date: 2012.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:United Kingdom  

  100. グリーン自然科学国際教育研究プログラムより見る高度人材育成

    阿波賀邦夫

    分子科学研究所所長招聘研究会「未来を拓く学術のあり方:化学が率いる持続社会」 

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    Event date: 2012.8

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:岡崎   Country:Japan  

  101. Electrochemical Organic Electronics Based on Robust Thin-Films of Porphyrazines International conference

    Kunio Awaga, Takuya Fujimoto, Chihiro Nanjo, Kouji Takahashi, SimonDalgleish and Michio M. Matsushita

    International Conference on Porphyrins and Phthalocyanines (ICPP-7) 

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    Event date: 2012.7

    Language:English   Presentation type:Oral presentation (general)  

    Country:Korea, Republic of  

  102. Electric-Double-Layer Interfaces For Organic Electronics: Opto-Electronic Conversion And Molecular Cluster Batteries International conference

    Kunio Awaga

    International Workshop on Novel Nanomagnetic and Multifunctional Materials 2012 (IW-NMM 2012 ) 

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    Event date: 2012.6

    Language:English   Presentation type:Oral presentation (general)  

    Country:Korea, Republic of  

  103. 有機ラジカルの光電流変換や非線形光学効果

    阿波賀邦夫

    「有機スピントロニクスの新展開」特別企画講演、日本化学会 第92春季年会 

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    Event date: 2012.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:横浜   Country:Japan  

  104. 強相関有機ラジカルの新奇物性開拓と有機エレクトロニクスへの展開

    阿波賀邦夫

    学術賞受賞講演、日本化学会 第92春季年会 

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    Event date: 2012.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:横浜   Country:Japan  

  105. Electric-Double-Layer Interfaces for Organic Electronics International conference

    Kunio Awaga

    workshop for "Organic Electronics and Spintronics" in Strategic Japanese-UK Cooperative Program 

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    Event date: 2012.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:United Kingdom  

  106. Rechargeable Molecular Cluster Batteries International conference

    Kunio Awaga

    GRI Symposium III on Cluster Science -Functionality of Clusters- 

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    Event date: 2012.2

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  107. Electric and Magnetic Properties of Organic Radicals with Multi-Dimensional Crystal Structures International conference

    kunio Awaga

    Half-day workshop: Grant-in-Aid for Scientific Research(S) 

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    Event date: 2012.1

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  108. 界面電気化学2重層を利用した有機エレクトロニクス International conference

    阿波賀邦夫

    熊本大学セミナー 

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    Event date: 2011.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:熊本市   Country:Japan  

  109. Anomalous Transient Photocurrent in Organic Photocells International conference

    kunio Awaga

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    Event date: 2011.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  110. Anomalous Transient Photocurrent in Organic Photocells International conference

    kunio Awaga

    International Photonics and OptoElectronics Meetings (POEM2011) 

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    Event date: 2011.11

    Language:English   Presentation type:Oral presentation (general)  

    Country:China  

  111. 有機エレクトロニクス – 化学と物理の学際領域研究

    阿波賀邦夫

    第2回知多地区理科教育(物理化学部会)研究会 

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    Event date: 2011.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:半田市   Country:Japan  

  112. Organic electronics based on open-shell compounds

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    Event date: 2011.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  113. ナノラジカル界面からの電子機能発現-光電流変換と2次電池

    阿波賀邦夫

    先端化学・材料技術部会 高選択性反応分科会 

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    Event date: 2011.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京   Country:Japan  

  114. Organic Electronics based on Paramagnetic Species International conference

    Kunio Awaga

    International School & Symposium on Multifunctional Molecule-based Materials 

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    Event date: 2011.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  115. Optical and electrical responses of organic radical materials International conference

    Kunio Awaga

    Pacifichem 2010  

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    Event date: 2010.12

    Language:English   Presentation type:Oral presentation (general)  

  116. Electronic and Electrochemical Functions of Molecular Spin/Electrode International conference

    Kunio Awaga

    Workshop - Radical New Materials for Electronics 

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    Event date: 2010.12

    Language:English   Presentation type:Oral presentation (general)  

    Country:United Kingdom  

  117. Electronic and Electrochemical Functions of Molecular Spin/Electrode Interface : Optoelectronic Conversion and Electricity Storage International conference

    Zhejiang University of Technologyセミナー 

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    Event date: 2010.11

    Language:English   Presentation type:Oral presentation (invited, special)  

  118. ナノラジカル界面を利用した有機/分子エレクトロニクス

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    Event date: 2010.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  119. 分子クラスターを用いたLi電池の特性と構造評価

    阿波賀 邦夫

    ナノテクノロジー・ネットワークH22年度成果報告会 

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    Event date: 2010.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  120. Optoelectric Conversion

    10th Japan-China joint Symposium on Conduction and Photoconduction in Organics Solids and Related Phenomena 

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    Event date: 2010.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  121. lectronic and Magnetic Properties of Thiazyl Radicals and their Related Materials International conference

    International Conference on Molecule-based Magnets 

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    Event date: 2010.10

    Language:English   Presentation type:Oral presentation (invited, special)  

  122. Application of Thiazyl Radicals and Related Materials to Organic Electronics International conference

    Japan-Taiwan Joint Symposium on Innovative Synthesis for New Materials Chemistry 

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    Event date: 2010.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  123. Anomalous Transient Photocurrent in Organic Radical Photocells International conference

    International conference on science and technology of synthetic metals 

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    Event date: 2010.7

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  124. Anomalous Transient Photocurrent of Organic Radical Photocells International conference

    International Workshop on Organic Electronics and Spintronics, 

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    Event date: 2010.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  125. Organic Radical Electronics

    The 5th edition of the international workshop on "Electronic Structure and Processes at Molecular-Based Interfaces" (ESPMI-V) 

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    Event date: 2010.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  126. Sympathetic Approaches toward Organic Radical Electronics The 3rd International Conference on Joint Project of Chemical International conference

    The 3rd International Conference on Joint Project of Chemical Synthesis Core Research Institutions 

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    Event date: 2010.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  127. 有機強構造薄膜の光電気物性

    第3回東北大学G-COE研究会「金属錯体の固体物性科学最前線—錯体化学と固体物性物理と生物物性の連携新領域創成をめざしてー」 

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    Event date: 2009.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  128. マクロサイクル化合物の結晶および薄膜構造制御と電気化学物性

    第18回有機結晶シンポジウム 

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    Event date: 2009.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  129. Organic Radical Electronics

    KINKEN Workshop "Group-IV Spintronics" 

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    Event date: 2009.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  130. Organic radical electronics International conference

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    Event date: 2009.9

    Language:English  

  131. Organic radical electronics International conference

    , International Balkan Workshop on Applied Physics 

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    Event date: 2009.7

    Language:English  

  132. Visible-Light Scattering on Submicron-Scale Hollow Spheres of Magnetite and Titania

    MRS Fall Meeting 

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    Event date: 2008.12

    Language:English  

  133. Electrical and Electrochemical Applications of Molecular Spins International conference

    Friday Workshop on Organic Electronics 

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    Event date: 2008.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  134. Electrical and electrochemical processes in self-assembling molecular spins International conference

    The 11th International Conference on Molecule-based Magnets (ICMM2008) 

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    Event date: 2008.9

    Language:English   Presentation type:Oral presentation (invited, special)  

  135. Solid-State Electrochemistry and Photoconductivity of Self-Assembling Thin Films of Tetrakis(thiadiazole)porphyrazines International conference

    Fifth International Conference on Porphyrins and Phthalocyanines (ICPP-5) 

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    Event date: 2008.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  136. Electronics of Organic / Molecular Spin International conference

    WUN-Hangzhou International Summer School on Spintronics 

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    Event date: 2008.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  137. Dipolar-Biased Tunneling of Magnetization in Crystals of Single Molecule Magnets International conference

    2007 American Physical Society (APS) March Meeting, Denver 

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    Event date: 2007.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  138. Spin, charge and lattice correlation in the phase transitions of organic radical crystals International conference

    The 3rd International Workshop Hangzhou 2006 on Simulational Physics 

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    Event date: 2006.11

    Language:English   Presentation type:Oral presentation (invited, special)  

  139. Electric and Magnetic Properties of Thiazyl Radicals and their Related Materials International conference

    10th International Conference on Molecule-based Magnets (ICMM2006) 

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    Event date: 2006.8

    Language:English   Presentation type:Oral presentation (invited, special)  

  140. Crystal Structures and Thin-Film Growths of Tetrakis(1,2,5-thiadiazole)porphyrazines International conference

    Fourth International Conference on Porphyrins and Phthalocyanines (ICPP-4) 

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    Event date: 2006.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  141. Variable Magnetic Properties of Single Molecule Magnets and Spherical Hollow Magnets International conference

    Variable Magnetic Properties of Single Molecule Magnets and Spherical Hollow Magnets 

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    Event date: 2006.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  142. バルクと分子をつなぐ中空球殻磁性体

    阿波賀邦夫

    日本化学会第86春季年会 

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    Event date: 2006.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  143. Multi-dimensional network structures and unique solid-state properties of cyclic thiazyl radicals and related materials International conference

    International Chemical Congress of Pacific Basin Societies 

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    Event date: 2005.12

    Language:English   Presentation type:Oral presentation (invited, special)  

  144. 分子磁石とナノ磁石の設計と制御

    第7回九州大学ナノ物質合成・解析支援講習・研究会 

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    Event date: 2005.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  145. Spin, charge and lattice correlation in thiazyl radicals and related materials International conference

    International symposium on “Spin- and charge-correlations in molecule-based materials 

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    Event date: 2005.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  146. スピンと分子機能-特定領域研究「分子スピンの概要とその成果」

    ICMMポストコンファレンス 

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    Event date: 2005.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  147. Spherical hollow magnets; a material filling the gap of bulk and molecular magnetism International conference

    Unconventional Magnetic and Electronic Materials: A Symposium in Honor of Art Epstein's 60th Birthday 

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    Event date: 2005.6

    Language:English   Presentation type:Oral presentation (invited, special)  

  148. Template synthesis of spherical hollow nanomagnets International conference

    International workshop on “Molecular and Nano-particle Magnetism" 

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    Event date: 2005.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  149. 分子およびナノ磁性体の合成と物性探索

    第2期菅野シンポジウム 

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    Event date: 2005.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  150. 分子スピン物性とその展開

    電気通信研究所共同プロジェクト研究「有機デバイスの基礎と応用」 

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    Event date: 2004.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  151. Exotic Crystal Structures and Physical Properties of Thiazyl Radicals International conference

    Exotic Materials: A Symposium in Honor of Joel S. Miller's 60th Birthday 

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    Event date: 2004.10

    Language:English   Presentation type:Oral presentation (invited, special)  

  152. 分子磁性体における室温双安定性の構築とその制御

    第28 回日本応用磁気学会学術講演会 

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    Event date: 2004.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  153. Crystal growth and magnetic measurements on metallo- and metal-free tetrakis(thiadiazole)porphyrazine International conference

    Third International Conference on Porphyrins and Phthalocyanines (ICPP-3) 

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    Event date: 2004.7

    Language:English   Presentation type:Oral presentation (invited, special)  

  154. 分子およびナノ磁性体の化学構築と物性探索

    金属学会分科会セミナー「最先端スピンエレクトロニクス技術の基礎と応用-21世紀を切開く新技術の現状と今後の展望-」 

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    Event date: 2004.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  155. Molecular spins- from organic radicals to nano-magnets International conference

    ndia-Japan seminar on Molecular and Supramolecular materials 

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    Event date: 2004.3

    Language:English   Presentation type:Oral presentation (invited, special)  

  156. Chemical syntheses of spherical hollow nano-magnets International conference

    International workshop on "Physics on Nanoscale Magnets" 

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    Event date: 2003.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  157. Structure and magnetic properties of Mn11Cr with a half-integer spin International conference

    International workshop on "Physics on Nanoscale Magnets" 

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    Event date: 2003.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  158. Quantum spin systems in Molecule-based Magnetic Materials International conference

    International workshop on quantum dynamics of molecular magnets 

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    Event date: 2002.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

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Research Project for Joint Research, Competitive Funding, etc. 17

  1. 導電性シリカ多孔体を利用した高性能電極材料の開発

    2017.4 - 2018.3

    企業からの受託研究 

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    近年、環境問題やエネルギー問題などから、効率よくエネルギーを保存し、ユビキタスにエネルギーを供給できる新しい二次電池の開発が重要となっている。現在、二次電池として広く普及しているリチウムイオン電池は、高価で、かつ希少金属を利用している点が問題視され、また充放電速度も遅い欠点がある。そこで本研究では、急速充電が可能な大容量二次電池の実現に向け、これまでの導電性シリカの研究で得られたノウハウを基に、高性能な電極材料の開発を目的とする。

  2. 微粒子がつくる固液界面を利用した蓄電機能と光電子機能

    2014.4 - 2018.3

    旭硝子財団研究助成金 

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    Grant type:Competitive

  3. 導電性シリカ多孔体を利用した高性能電極材料の開発

    2014.4 - 2015.3

    企業からの受託研究 

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    炭素材料とシリカを複合化させることによって形成される導電性シリカ多孔体に、Liをインターカレートした様々な物質の開発を行い、これを作用電極、Li金属を対極とするハーフセルを甲が作製し、負極特性の検討を行う。最終的には、グラファイトよりもLiをインターカレートするような材料の実現を目指す。

  4. Organic Electronics of Highly-Correlated Molecular Systems

    2013.4 - 2018.3

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    Grant type:Competitive

  5. 導電性シリカ多孔体を利用した高性能電極材料の開発

    2013.4 - 2014.3

    企業からの受託研究 

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    炭素材料とシリカを複合化させることによって形成される導電性シリカ多孔体に、Liをインターカレートした様々な物質の開発を行い、これを作用電極、Li金属を対極とするハーフセルを甲が作製し、負極特性の検討を行う。最終的には、グラファイトよりもLiをインターカレートするような材料の実現を目指す。

  6. ナノラジカル界面からの電子機能発現

    2010.10 - 2016.3

    独立行政法人 科学技術振興機構 (CREST) 

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    Grant type:Competitive

  7. ナノハイブリッド化に基づく高エネルギー密度型分子クラスター電池の開発

    2010.6 - 2011.3

    財団法人 科学技術交流財団 

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    Grant type:Competitive

  8. 単分散サブミクロン磁性中空殻の光電子機能

    2009.4 - 2010.3

    旭硝子財団研究助成金 

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    Grant type:Competitive

  9. 有機エレクトロニクスのための新しいラジカル物質科学

    2009.1 - 2011.3

    独立行政法人 科学技術振興機構 

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    Grant type:Competitive

  10. 分子磁性体を用いたスピンエレクトロニクスの発展

    2003

    財団法人 村田学術振興財団 

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    Grant type:Competitive

  11. 超分子磁性体における双安定特性

    2001 - 2002

    科学技術振興事業団 基礎的研究発展推進事業 (研究発展) 

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    Grant type:Competitive

  12. 分子磁性体における双安定性の発見とその展開

    2001 - 2002

    財団法人 豊田理化学研究所 

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    Grant type:Competitive

  13. 分子磁性体における双安定性の発見とその展開

    2001

    公益信託分子科学研究奨励森野基金 

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    Grant type:Competitive

  14. 分子磁性体における双安定性の発現とその応用

    2001

    財団法人 三菱財団 

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    Grant type:Competitive

  15. 超分子磁性体における双安定特性

    1997 - 2000

    科学技術振興事業団個人研究推進事業(さきがけ研究21) 

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    Grant type:Competitive

  16. 有機・無機複合ナノコンポジットの磁性に関する研究

    1995

    住友財団 研究助成 

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    Grant type:Competitive

  17. 分子間および分子内に磁気的相互作用を与えるπ−電子系有機物質を実現するための基礎研究

    1993 - 1995

    新エネルギー産業技術総合開発機構 国際共同研究助成 

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    Grant type:Competitive

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KAKENHI (Grants-in-Aid for Scientific Research) 30

  1. Chemistry and Physics of Molecular Systems with Mathematically-Defined Strong Isotropic Lattice Structures

    Grant number:20H05621  2020.7 - 2025.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Specially Promoted Research

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    Authorship:Principal investigator 

    Grant amount:\554450000 ( Direct Cost: \426500000 、 Indirect Cost:\127950000 )

  2. フラットバンドの化学構築とバンドフィリング制御

    Grant number:19K22167  2019.6 - 2021.3

    科学研究費助成事業  挑戦的研究(萌芽)

    阿波賀 邦夫

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    Authorship:Principal investigator 

    Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )

    これまでの研究により、C3対称性をもつ分子がハニカム格子に結晶化すれば、必然的にDirac coneやフラットバンドが形成されることを見出している。この物質設計指針に従い、トリプチセン骨格に、ドナーやアクセプター性、あるいは金属イオンへの配位能をもつさまざまな置換基を導入し、分子間の電荷移動相互作用や配位結合によって強固な分子性ハニカム格子を合成する。その次のステップとして、固体電気化学などの手法を用いて、分子性ハニカム格子に関するバンドフィリング制御に挑戦する。すなわち、当該物質を電極上に配して電解質に浸し、電極電位の制御によって系のフェルミエネルギーを連続的に制御する。
    我々はこれまの研究により、C3対称性をもつ分子がハニカム格子に結晶化すれば、必然的にDirac coneやフラットバンドが形成されることを見出している。本研究ではこの物質設計指針に従い、C3対称性をもつ分子骨格としてトリプチセンを選び、ドナーやアクセプター性、あるいは金属イオンへの配位能をもつさまざまな置換基を導入しながら、分子性ハニカム格子の合成すを目指した。
    本年度は、ハニカム格子の類縁格子であるカゴメ格子を有するMOFを合成した。カゴメ格子には、スピンフラストレーションが期待される。得られた系について、極低温域までの磁気測定と熱測定を行った。この結果、多次元的な相互作用をもつにもかかわらず、磁気的秩序状態に転移することなく、低温ではスピン液体状態にあることが結論された。これは、スピンフラストレーションが長距離の磁気的秩序を阻害したためと考えられる。極低温域における磁気測定と熱測定から、スピン液体状態の磁化率と比熱の温度依存性を実験的に決定することができた。さらに、これを説明するためのモデルについても検討した。
    さらに本年度は、いくつかの新規トリプチセン誘導体の合成に成功している。ドナー性とアクセプター性を系について、それぞれその合成に成功した。現在、再結晶法や昇華法によって結晶作製を進めており、いくつかの系では、結晶構造解析や物性測定に取り掛かっている。また現在、電解結晶化によってラジカル塩の作製も行っている。

  3. Novel Energy and Information Conversions, Created by Solid-State Electrochemical Processes

    Grant number:16H06353  2016.5 - 2021.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (S)

    AWAGA Kunio

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    Authorship:Principal investigator 

    Grant amount:\185900000 ( Direct Cost: \143000000 、 Indirect Cost:\42900000 )

    We have synthesized molecular nanoporous materials with unique topologies such as honeycomb and gyroid, and explored their physical properties, aiming interdisciplinary research between molecular science and solid-state electrochemistry. We realized excellent electric power storages, by using these materials as cathode active materials for rechargeable batteries, and by inserting redox-active materials and/or organic conductive polymers into their cavity spaces. Furthermore, we fabricated organic devices which contained a solid-liquid interfacial electric double layer and achieved excellent transistor characteristics and high efficiency photoelectric conversion. We also developed various operando measurements in solid-state electrochemistry and proposed a potential junction model that continuously links the work function of the metal to the chemical potential of the electrolyte.

  4. Novel solid-state properties by combination of carbon allotropes' topology and molecular freedom

    Grant number:18H04482  2018.4 - 2020.3

    Grant-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

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    Authorship:Principal investigator 

    Grant amount:\7800000 ( Direct Cost: \6000000 、 Indirect Cost:\1800000 )

  5. 固体電気化学プロセスから発現する新しいエネルギーおよび情報変換

    2016.4 - 2022.3

    科学研究費補助金  基盤研究(S)

    阿波賀 邦夫

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    Authorship:Principal investigator 

  6. K4分子結晶化学の構築

    2016.4 - 2019.3

    科学研究費補助金  挑戦的萌芽研究

    阿波賀 邦夫

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    Authorship:Principal investigator 

  7. Crystal engineering for molecule-based K4 structure

    Grant number:16K13977  2016.4 - 2019.3

    Grant-in-Aid for Scientific Research 

    Awaga Kunio

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    Authorship:Principal investigator 

    Grant amount:\3900000 ( Direct Cost: \3000000 、 Indirect Cost:\900000 )

    Recently, graph theory proposed the strong isotropic property, which was realized only on the following three lattices, diamond, K4 and honeycomb. In the present project, we tried to synthesize molecule-based K4 and honeycomb lattices with polyhedral pi-conjugated molecules. It was found that [TBA]3[(-)-NDI-Δ]2 crystallized into a K4 lattice, in which unpaired electrons formed a hyperkagome lattice. Low-temperature physical measurements revealed a spin-liquid ground state in it. We also found a molecule-based honeycomb lattice in Rb3[p-TT] with an exotic band structure, which was similar to that of graphene.

  8. 開殻化合物を用いる新しい有機エレクトロニクスの発展

    2010.6 - 2014.3

    科学研究費補助金  基盤研究(A)

    阿波賀 邦夫

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    Authorship:Principal investigator 

  9. 強相関チアジルラジカルの光・電流応答

    2009.4 - 2010.3

    科学研究費補助金  新学術領域研究 21110515

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    Authorship:Principal investigator 

  10. 環状チアジルラジカルおよび関連物質の半導体特性とその展開

    2007.4 - 2010.3

    科学研究費補助金  基盤研究(A)

    阿波賀 邦夫

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    Authorship:Principal investigator 

  11. 中空球殻磁性体の2次元自己集積化と電気および磁気特性

    2006.11 - 2008.11

    科学研究費補助金  特別研究員奨励費,課題番号:68006354

    阿波賀 邦夫

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    Authorship:Principal investigator 

  12. ナノ球殻磁性金属の合成と物性測定

    2004.4 - 2006.3

    科学研究費補助金  萌芽研究,課題番号:16655055

    阿波賀 邦夫

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    Authorship:Principal investigator 

  13. 分子磁性体における双安定性の構築とその制御

    2003.10 - 2007.3

    科学研究費補助金  特定領域研究

    阿波賀 邦夫

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    Authorship:Principal investigator 

  14. 分子スピン:ナノ磁石から生体スピン系まで

    2003.10 - 2007.3

    科学研究費補助金  特定領域研究

    阿波賀 邦夫

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    Authorship:Principal investigator 

  15. ナノ球殻分子磁性体の開発

    2002.4 - 2004.3

    科学研究費補助金  萌芽研究 課題番号14654132

    阿波賀邦夫

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    Authorship:Principal investigator 

  16. 分子磁性体における双安定性の発現とその展開

    2001.4 - 2005.3

    科学研究費補助金  基盤研究(A)

    阿波賀 邦夫

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    Authorship:Principal investigator 

  17. 高スピン金属クラスター錯体に対する異種金属ドーピング

    1998.4 - 2000.3

    科学研究費補助金  文部省科学研究費 萌芽研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  18. 環状チオアミルラジカル超分子化合物の合成と新規物性開拓

    2001.4 - 2002.3

    科学研究費補助金  特定領域研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  19. Mn12核高スピン錯体の電子構造

    1999.4 - 2002.3

    科学研究費補助金  特定領域研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  20. 特異なスピン共役系の開発と展開

    1998.4 - 2001.3

    科学研究費補助金  特定領域研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  21. 新規低次元分子磁性体に現れるスピンギャップ状態の研究

    1997.4 - 2000.3

    科学研究費補助金  基盤研究(B)

    阿波賀邦夫

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    Authorship:Principal investigator 

  22. 超高圧下ファラデイ法磁化率測定システムの開発

    1997.4 - 1999.3

    科学研究費補助金  基盤研究(B)

    阿波賀邦夫

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    Authorship:Principal investigator 

  23. 複合機能性分子スピンシステムの研究

    1996.4 - 1998.3

    科学研究費補助金  文部省科学研究費 萌芽研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  24. 有機−無機複合ナノコンポジットの磁気的性質

    1995.4 - 1998.3

    科学研究費補助金  文部省科学研究費 重点領域研究(分子系超構造)公募研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  25. 光誘起相転移の制御に基づく分子素子の基礎研究

    1993.4 - 1995.3

    科学研究費補助金  文部省科学研究費 一般研究B

    阿波賀邦夫

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    Authorship:Principal investigator 

  26. ラジカル結晶の磁性

    1992.4 - 1995.3

    科学研究費補助金  文部省科学研究費 重点領域研究(分子磁性)計画研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  27. ニトロニルニトロキサイド陽イオンラジカルの電子状態と磁性

    1992.4 - 1993.3

    科学研究費補助金  文部省科学研究費 奨励研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  28. 高圧下の電子スピン共鳴−有機ラジカル物性への応用

    1991.4 - 1992.3

    科学研究費補助金  文部省科学研究費 奨励研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  29. 高圧下の静磁化率測定−有機磁性体への応用

    1990.4 - 1991.3

    科学研究費補助金  文部省科学研究費 奨励研究

    阿波賀邦夫

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    Authorship:Principal investigator 

  30. フリーラジカル磁性の設計と制御

    1990.3 - 1992.4

    科学研究費補助金  文部省科学研究費 重点領域研究(分子設計)公募研究

    阿波賀邦夫

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    Authorship:Principal investigator 

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Industrial property rights 13

  1. 炭素材料の製造方法、電極の製造方法、電極、及び電気化学デバイス

    阿波賀邦夫

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    Applicant:名古屋大学

    Application no:PCT/JP2020/008001  Date applied:2020.2

    Announcement no:WO2020/175616  Date announced:2020.9

  2. 正極活物質、正極、及び二次電池

    阿波賀邦夫、張中岳、WU、Yang、上村光浩、小川光輝

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    Applicant: 阿波賀邦夫、張中岳、WU、Yang、上村光浩、小川光輝

    Application no:特願2016-228992  Date applied:2016.11

    Country of applicant:Domestic  

  3. 光電変換素子

    阿波賀邦夫、松下未知雄、Karak Supravat、湯山佳奈子

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    Applicant:阿波賀邦夫、松下未知雄、Karak Supravat、湯山佳奈子

    Application no: 特許 PCT/JP2016/004890  Date applied:2016.11

    Country of applicant:Domestic  

  4. 光電変換素子

    阿波賀邦夫、松下未知雄、Karak Supravat、湯山佳奈子

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    Applicant:阿波賀邦夫、松下未知雄、Karak Supravat、湯山佳奈子

    Application no:特願2015-224403  Date applied:2015.11

    Country of applicant:Domestic  

  5. 光電変換素子

    阿波賀邦夫、 Dalgleish Simon、 Reissig Louisa、 湯山佳奈子

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    Applicant:阿波賀邦夫、 Dalgleish Simon、 Reissig Louisa、 湯山佳奈子

    Application no:特願2015-190362  Date applied:2015.9

    Country of applicant:Domestic  

  6. 二次電池

    阿波賀邦夫、吉川浩史、張中岳

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    Applicant:阿波賀邦夫、吉川浩史、張中岳

    Application no:特願2015-042831  Date applied:2015.3

    Country of applicant:Domestic  

  7. 電気二重層コンデンサ

    阿波賀邦夫、吉川浩史、佐藤正春

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    Applicant:阿波賀邦夫、吉川浩史、佐藤正春

    Application no:特願2012-207080  Date applied:2012.9

    Announcement no:特開2014-063824 

    Patent/Registration no:特開2014-063824  Date registered:2014.4 

    Country of applicant:Domestic  

  8. 光電変換素子、及び光電変換装置

    阿波賀邦夫、Hu Laigui、李博、佐藤正春

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    Applicant:阿波賀邦夫、Hu Laigui、李博、佐藤正春

    Application no:特願2012-089604  Date applied:2012.4

    Country of applicant:Domestic  

  9. 組成物、及び二次電池

    阿波賀邦夫、吉川浩史、信原一敬、上村光浩

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    Applicant:阿波賀邦夫、吉川浩史、信原一敬、上村光浩

    Application no:特願2012-013261  Date applied:2012.1

    Announcement no:特許第5583152号(P5583152) 

    Patent/Registration no:特許第5583152号(P5583152)  Date registered:2014.7 

    Country of applicant:Domestic  

  10. Organic photoelectric conversion device and imaging device

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    Application no:特願2010-57342  Date applied:2011.3

    Patent/Registration no:特許 PCT/JP2011/001500  Date registered:2011.9 

    Country of applicant:Domestic  

  11. Photoelectric conversion element and photoelectric conversion device

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    Application no:特許 PCT/JP2010/069493  Date applied:2010.11

    Patent/Registration no:特許 PCT/JP2010/069493  Date registered:2011.5 

    Country of applicant:Domestic  

  12. 光電変素子および光電変換装置

    阿波賀邦夫、 Hu-Laigui, 佐藤正春

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    Applicant:阿波賀邦夫、 Hu-Laigui, 佐藤正春

    Application no:特願2009-251766  Date applied:2009.11

    Country of applicant:Domestic  

  13. 分子クラスター2次電池

    阿波賀邦夫、吉川浩史、和田潤

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    Applicant:阿波賀邦夫、吉川浩史、和田潤

    Application no:特願2007-037128  Date applied:2007.2

    Announcement no:特許第5282259号(P5282259) 

    Patent/Registration no:特許第5282259号(P5282259)  Date registered:2013.6 

    Country of applicant:Domestic  

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Teaching Experience (On-campus) 14

  1. 量子化学Ⅰ

    2016

  2. 物性化学Ⅰ

    2016

  3. 物性化学Ⅰ

    2015

  4. 量子化学Ⅰ

    2015

  5. 量子化学Ⅰ

    2014

  6. 物性化学Ⅰ

    2014

  7. 量子化学Ⅰ

    2013

  8. 量子化学Ⅰ

    2012

  9. 物性化学Ⅰ

    2012

  10. 物性化学Ⅱ

    2011

  11. 量子化学Ⅰ

    2011

  12. 量子化学Ⅰ

    2010

  13. 物性化学Ⅱ

    2010

  14. 物性化学2

    2009

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Teaching Experience (Off-campus) 2

  1. 2009.4 - 2010.3 大阪大学)

  2. 2009.4 - 2010.3 東京工業大学)

 

Social Contribution 7

  1. 名古屋大学レクチャー2023

    Role(s):Organizing member

    名古屋大学高等研究院  2024.1

  2. 14th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena

    Role(s):Organizing member

    2023.11

  3. UBIAS Conference / Directors Meeting

    Role(s):Organizing member

    2023.10 - 2023.11

  4. 第30回有機結晶シンポジウム/第7回有機結晶プレシンポジウム

    Role(s):Organizing member

    日本化学会  2022.11

  5. 名古屋大学レクチャー2022

    Role(s):Organizing member

    名古屋大学高等研究院  名古屋大学レクチャー2022  2022.10

  6. 歴史的化学論文大賞受賞記念シンポジウム

    Role(s):Organizing member

    名古屋大学高等研究院  2022.7

  7. 名古屋大学オープンレクチャー2022

    Role(s):Lecturer

    名古屋大学学術研究・産学官連携推進本部  名古屋大学オープンレクチャー2022  名古屋大学東山キャンパス  2022.3

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    Audience: Junior students, High school students, College students

    Type:Lecture

    炭素の構造を分子でつくるはなし
    炭素同素体の結晶構造として、ハニカムやダイヤモンド、そして数学的に予見されたK4格子などが知られています。この3構造の特色を説明し、これらを分子で作ると、さまざまな基礎物性や2次電池などへの応用が見えてくることを紹介します。

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Media Coverage 1

  1. 変調光から交流電流 TV or radio program

    日刊工業新聞  29面  2019.12

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    Author:Other 

Academic Activities 7

  1. 東京大学物性研究所協議会委員

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

  2. 文部科学省 学術変革領域研究(A)「高密度共役」

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

    日本語

  3. 豊秋奨学会

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

  4. 北海道大学理学研究院・理学院・理学部外部評価

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

  5. International meeting on spin in organic semiconductors (SPINOS) 国際アドバイザリーボード

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

  6. International conference on molecule-based magnets (ICMM) 国際アドバイザリーボード

    Role(s):Review, evaluation

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    Type:Scientific advice/Review 

  7. 日本化学会有機結晶部会

    Role(s):Planning, management, etc.

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    Type:Academic society, research group, etc. 

    日本語

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