Updated on 2026/04/20

写真a

 
SHIMOYAMA Daisuke
 
Organization
Graduate School of Science Assistant Professor
Undergraduate School
School of Science Department of Chemistry
Title
Assistant Professor

Degree 1

  1. 博士（理学） （ 2020.3   広島大学 ） 

To the head of Degree.▲

Research Interests 1

  1. 超分子化学

To the head of Research Interests.▲

Research Areas 2

  1. Nanotechnology/Materials / Polymer chemistry  / 精密重合

  2. Nanotechnology/Materials / Structural/physical organic chemistry  / 超分子化学，有機ホウ素

To the head of Research Areas.▲

Research History 5

  1. Nagoya University   Graduate School of Science   Assistant Professor

    2026.4

  2. Tokyo Metropolitan University   Assistant Professor

    2022.4 - 2026.3

  3. Rutgers University   Postdoctoral Associate

    2020.8 - 2022.3

    　 More details

    Country：United States

  4. Hiroshima University   Researcher

    2020.4 - 2020.7

  5. 日本学術振興会 特別研究員 DC2

    2018.4 - 2020.3

To the head of Research History.▲

Education 2

  1. Hiroshima University   Graduate School of Science   Department of Chemistry

    2015.4 - 2020.3

  2. Hiroshima University

    2011.4 - 2015.3

To the head of Education.▲

Professional Memberships 4

  1. 高分子学会

  2. 有機合成化学協会

  3. 日本化学会

  4. The American Chemical Society

To the head of Professional Memberships.▲

Committee Memberships 1

  1.   関東高分子若手研究会, 世話人，運営ワーキンググループ  

    2025.1   

To the head of Committee Memberships.▲

Awards 11

  1. 第63回学術奨励賞 UBE学術振興財団

    2023.4  

  2. 令和4年度コニカミノルタ画像科学奨励賞

    2023.3  

  3. 広島大学学生表彰

    2020.3  

  4. 広島大学大学院理学研究科長賞

    2020.3  

  5. 広島化学同窓会奨励賞及び博士賞

    2020.3  

  6. 広島大学エクセレントスチューデントスカラシップ

    2019.12  

  7. 第11回有機π電子系シンポジウム 優秀ポスター賞及びChemistry Letters賞

    2017.12  

  8. 第45回有機典型元素化学討論会 優秀ポスター賞

    2017.12  

  9. 第28回基礎有機化学討論会 ポスター賞

    2017.9  

  10. 広島大学理学部長賞

    2015.3  

  11. 第30回若手化学者のための化学道場 優秀ポスター賞

    2014.8  

▼display all

To the head of Awards.▲
 

Papers 32

  1. Synthesis of Well-Defined Halogenated Styrenic (CO)polymers: Polymerisation Catalyzed by Half-Titanocenes and Their Post-Modification Reviewed

    Youshu Jiang, Seiji Higashi, Hiroshi Hirano, Kotohiro Nomura, Daisuke Shimoyama

    Polymer Chemistry     2025.6

    　More details

    Authorship：Last author,　Corresponding author   Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    Well-defined halogenated syndiotactic polystyrenes and ethylene/styrene copolymers were synthesized by 1) coordination polymerisation of p-trimethylsilylstyrene (p-TMSSt) using half-titanocene catalysts and 2) subsequent post-modification under mild conditions. Syndiospecific styrene polymerisation of...

    DOI： 10.1039/d5py00412h

  2. End-Functionalized Biobased Aliphatic Polyesters Exhibiting Unique Emission/Thermal Properties Reviewed Open Access

    Daisuke Shimoyama, Shunsuke Sato, Shunta Ohsawa, Shunta Irisawa, Motoko S. Asano, Kotohiro Nomura

    ACS Polymers Au     2025.4

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acspolymersau.5c00016

    Open Access

  3. Conformation Regulation of Trisresorcinarene Directed by Cavity Solvation Reviewed Open Access

    Daisuke Shimoyama, Ryo Sekiya, Shoichiro Inoue, Naoyuki Hisano, Shin-ichi Tate, Takeharu Haino

    Chemistry – A European Journal     2024.8

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    This compound is a synthetic macrocycle comprising three pivaloyl‐protected resorcinarene units connected by six pentylene chains. We conducted a conformational study using 1H‐NMR, X‐ray diffraction (XRD), and computational analyses. The macrocycle adopts two conformers, one open, the other closed. The ratio of the open to closed forms depended on the solvent used. Only the open form existed in [D8]toluene, both forms coexisted in [D6]benzene, and the closed form was the major conformer in [D1]chloroform. The benzene‐solvated open form observed in the solid state suggests that cavity solvation by solvent molecules directs the open form. The open form was the major or only conformer in [D10]o‐ and [D10]m‐xylene and [D12]mesitylene, whereas the closed form was the major conformer in [D6]acetone. The open and closed forms were equally populated in [D10]p‐xylene, suggesting that the size, shape, and dimensions of the solvent molecules most likely influenced the conformation of the protected trisresocinarene.

    DOI： 10.1002/chem.202402922

  4. A New Platform of B/N-Doped Cyclophanes: Access to a π-Conjugated Block-Type B3N3 Macrocycle with Strong Dipole Moment and Unique Optoelectronic Properties Reviewed

    Pengfei Li, Daisuke Shimoyama, Niu Zhang, Yawei Jia, Guofei Hu, Chenglong Li, Xiaodong Yin, Nan Wang, Frieder Jäkle, Pangkuan Chen

    Angewandte Chemie - International Edition   Vol. 61 ( 20 )   2022.3

    　More details

    Language：English   Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    DOI： 10.1002/anie.202200612

    Scopus

    PubMed

  5. Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials Invited Reviewed Open Access

    Daisuke Shimoyama, Frieder Jäkle

    Aggregate   Vol. 3 ( 2 )   2022.1

    　More details

  6. Electrochromic Polycationic Organoboronium Macrocycles with Multiple Redox States Reviewed

    Daisuke Shimoyama, Nurcan Baser-Kirazli, Roger A. Lalancette, Frieder Jäkle

    Angewandte Chemie - International Edition   Vol. 60 ( 33 ) page： 17942 - 17946   2021.8

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/anie.202105852

    Scopus

    PubMed

  7. Feet‐to‐Feet‐Connected Multitopic Resorcinarene Macrocycles Invited Reviewed

    Daisuke Shimoyama, Takeharu Haino

    Asian Journal of Organic Chemistry   Vol. 9 ( 11 ) page： 1718 - 1725   2020.11

    　More details

    Authorship：Lead author   Publisher：Wiley  

    DOI： 10.1002/ajoc.202000302

    Scopus

    Other Link： https://onlinelibrary.wiley.com/doi/full-xml/10.1002/ajoc.202000302

  8. Absorption of chemicals in amorphous trisresorcinarene Reviewed

    Daisuke Shimoyama, Ryo Sekiya, Takeharu Haino

    Chemical Communications   Vol. 56 ( 83 ) page： 12582 - 12585   2020.10

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/d0cc05066k

    Scopus

    PubMed

  9. Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand Reviewed Open Access

    Daisuke Shimoyama, Ryo Sekiya, Takeharu Haino

    Chemical Communications   Vol. 56 ( 26 ) page： 3733 - 3736   2020.4

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/d0cc00933d

    Scopus

    PubMed

  10. Entropy-Driven Cooperativity in the Guest Binding of an Octaphosphonate Bis-cavitand Reviewed

    Daisuke Shimoyama, Takeharu Haino

    Chemistry - A European Journal   Vol. 26 ( 14 ) page： 3074 - 3079   2020.3

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/chem.201905036

    Scopus

    PubMed

  11. Feet-To-Feet Connected Trisresorcinarenes Reviewed

    Daisuke Shimoyama, Ryo Sekiya, Hiroto Kudo, Takeharu Haino

    Organic Letters   Vol. 22 ( 2 ) page： 352 - 356   2020.1

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.orglett.9b03693

    Scopus

    PubMed

  12. Conformational Characteristics of Feet-to-Feet-Connected Biscavitands Reviewed

    Daisuke Shimoyama, Takeharu Haino

    Journal of Organic Chemistry   Vol. 84 ( 21 ) page： 13483 - 13489   2019.11

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.joc.9b01730

    Scopus

    PubMed

  13. Synthesis and Structure of Feet-to-Feet Connected Bisresorcinarenes Reviewed

    Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    Journal of Organic Chemistry   Vol. 82 ( 24 ) page： 13220 - 13230   2017.12

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.joc.7b02301

    Scopus

    PubMed

  14. Fluctuation-Driven Switching of Magnetic Exchange and Charge Transport in Ni(dmit)2 Salts with [24]crown-8-Based Supramolecular Cations Reviewed Open Access

    Daisuke Ishikawa, Masato Haneda, Jun Manabe, Daisuke Shimoyama, Takeharu Haino, Kiyonori Takahashi, Takayoshi Nakamura, Sadafumi Nishihara

    Bulletin of the Chemical Society of Japan     2026.2

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：Oxford University Press (OUP)  

    Abstract

    Countercation dynamics play a crucial yet largely unexplored role in governing the electronic properties of molecular conductors. Herein, we demonstrate that the fluctuations of flexible supramolecular cations in [Ni(dmit)2]-based molecular conductors (dmit2− = 2-thioxo-1,3-dithiol-4,5-dithiolate) can directly modulate their correlated electronic states. Two salts with nearly spherical supramolecular cations featuring Na+ and Cs+ ions encapsulated by unsubstituted [24]crown-8, Na([24]crown-8)[Ni(dmit)2]3 and Cs2([24]crown-8)2[Ni(dmit)2]7, are synthesized and systematically compared. Detailed crystallographic, magnetic, and transport studies reveal a striking contrast between the two systems. In Na([24]crown-8)[Ni(dmit)2]3, the structural distortion of the Na+-encapsulating [24]crown-8 enables thermally activated large-amplitude out-of-plane fluctuations, thus selectively enhancing the vibrational motion of terminal S atoms in [Ni(dmit)2] layers and leading to the temperature-dependent modulation of transfer integrals, anomalous magnetic behavior requiring a temperature-dependent exchange interaction, and one-dimensional variable-range hopping transport. In contrast, Cs2([24]crown-8)2[Ni(dmit)2]7 features a planar-confined Cs+-based supramolecular cation and suppressed fluctuation transfer to anion layers, thus exhibiting conventional Heisenberg-chain magnetism and Arrhenius-type semiconducting behavior. These results establish supramolecular-cation dynamics as a powerful design parameter for controlling electronic correlation and transport in molecular conductors.

    DOI： 10.1093/bulcsj/uoag022

    Open Access

  15. Crystallization of Biobased Long-Chain Aliphatic Polyesters as Sustainable Polymers: Effects of the Diol Structure in the Monomer Unit Reviewed Open Access

    Hiroki Takeshita, Aki Nishiyama, Xiuxiu Wang, Mika Kojima, Mohamed Mehawed Abdellatif, Daisuke Shimoyama, Takumitsu Kida, Katsuhisa Tokumitsu, Kotohiro Nomura

    Biomacromolecules     2025.9

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acs.biomac.5c01043

    Open Access

  16. End-Functionalized Poly(9,9′-dialkyl-fluorene-2,7-vinylene)s Exhibiting Unique Emitting Properties, Prepared by Acyclic Diene Metathesis Polymerization, Coupled with Wittig-Type Coupling Reviewed Open Access

    Mikiko Kunisawa, Kyoko Ishibashi, Daisuke Shimoyama, Motoko S. Asano, Kotohiro Nomura

    ACS Polymers Au     2025.7

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acspolymersau.5c00042

    Open Access

  17. cis-/trans-Specific Synthesis of Functionalized Bottlebrush Ring Opening Metathesis Polymerization Polymers Containing Terthiophene and Pyrene That Exhibit Unique Thermal and Emission Properties. Reviewed International journal Open Access

    Kanticha Jaiyen, Sirilak Mekcham, Daisuke Shimoyama, Akihiro Ohira, Kotohiro Nomura

    ACS macro letters     page： 335 - 340   2025.3

    　More details

    Language：English   Publishing type：Research paper (scientific journal)  

    Z-Specific (99% cis) and E-specific (90% trans) syntheses of functionalized bottlebrush polymers (BBPs) by living ring opening metathesis polymerization (ROMP) of exo-N-substituted norbornene-2,3-dicarboximides (NDIs) containing terthiophene (3T) and pyrene (Pyr) moieties connected to a long methylene spacer (n-dodecyl) have been demonstrated by the (arylimido)-vanadium(V)-alkylidene catalysts in toluene at 50 °C. Thermal properties in the resultant BBPs measured by DSC thermograms are affected by the cis/trans selectivity; the resultant cis-BBPs containing 3T possessed a melting temperature at 111.2 °C, whereas the corresponding trans-BBPs are amorphous. The differences in cis-/trans-BBPs (containing 3T, Pyr) toward the emission properties have also been demonstrated due to a different degree in the inter/intra-polymer interaction through the functionality.

    DOI： 10.1021/acsmacrolett.4c00845

    Open Access

    PubMed

  18. Ethylene/Styrene Copolymerization by (Me3SiC5H4)TiCl2(O-2,6-iPr2-4-RC6H2) (R = H, SiEt3)-MAO Catalysts: Effect of SiMe3 Group on Cp for Efficient Styrene Incorporation Reviewed Open Access

    Tiantian Huang, Taiga Fujioka, Daisuke Shimoyama, Kotohiro Nomura

    Molecules   Vol. 29 ( 18 ) page： 4473 - 4473   2024.9

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：MDPI AG  

    The synthesis and structural analysis of (Me3SiC5H4)TiCl2(OAr) [OAr = O-2,6-iPr2-4-RC6H2; R = H, SiEt3] revealed that it exhibits higher catalytic activities than (tBuC5H4)TiCl2(OAr), Cp*TiCl2(OAr), with efficient comonomer incorporation in ethylene/styrene copolymerization in the presence of a methylaluminoxane (MAO) cocatalyst. The catalytic activity in the copolymerization increased upon increasing the charged styrene concentration along with the increase in the styrene content in the copolymers, whereas the activities of other catalysts showed the opposite trend. (Me3SiC5H4)TiCl2(O-2,6-iPr2C6H3) displayed the most suitable catalyst performance in terms of its activity and styrene incorporation, affording amorphous copolymers with styrene contents higher than 50 mol% (up to 63.6 mol%) and with random styrene incorporation confirmed by 13C-NMR spectra.

    DOI： 10.3390/molecules29184473

    Open Access

  19. Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Complexes Containing Fluorinated Alkoxide or Halogenated Phenoxide Ligands for the Syndiospecific ROMP of Cyclic Olefins Reviewed Open Access

    Kotohiro Nomura, Shuko Kuwahara, Jirapa Suthala, Yuta Kawamoto, Daisuke Shimoyama, Michael R. Buchmeiser

    New Journal of Chemistry     2024.7

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    [V(N-2,6-Cl<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CHSiMe<sub>3</sub>)(OC<sub>6</sub>X<sub>5</sub>)(NHC)] [X = F (1), Cl (2), NHC = 1,3-bis-(2,6-dimethylphenyl)-imidazol-2-ylidene], exhibited remarkable catalytic activities [TOF = 133-193 sec<sup>-1</sup> (1), 90.9-126 sec<sup>-1</sup> (2)] for ring opening metathesis polymerisation (ROMP) of norbornene...

    DOI： 10.1039/d4nj02537g

  20. Near‐Infrared Emissive B‐N Lewis Pair‐Functionalized Anthracenes via Selective LUMO Delocalization in Extended Conjugated Dimer and Polymer Reviewed Open Access

    Jingyao Zuo, Kanglei Liu, Jaren Harrell, Lujia Fang, Piotr Piotrowiak, Daisuke Shimoyama, Roger A. Lalancette, Frieder Jäkle

    Angewandte Chemie International Edition     2024.7

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：Wiley  

    Acenes are attractive as building blocks for low gap organic materials with applications, for example, in organic light emitting diodes, solar cells, bioimaging and diagnostics. Previously, we have shown that modification of dipyridylanthracene via B‐N Lewis pair fusion (BDPA) strongly redshifts the emission, while facilitating self‐sensitized reactivity toward O2 to reversibly generate the corresponding endoperoxides. Herein, we report on the further expansion of the p‐system of BDPA to a vinyl‐substituted monomer, vinylene‐bridged dimer, and a polymer with an average of 20 chromophores. The extension of π‐conjugation results in largely reduced band gaps of 1.8 eV for the dimer and 1.7 eV for the polymer, the latter giving rise to NIR emission with a maximum at 731 nm and an appreciable quantum yield of 7%. Electrochemical and computational studies reveal efficient delocalization of the lowest unoccupied molecular orbital (LUMO) along the pyridyl‐anthracene‐pyridyl axis, which results in effective electronic communication between BDPA units, selectively lowers the LUMO, and ultimately narrows the band gap. Time‐resolved emission and transient absorption (TA) measurements offer insights into the pertinent photophysical processes. Extension of π‐conjugation also slows down the self‐sensitized formation of endoperoxides, while significantly accelerating the thermal release of singlet oxygen to regenerate the parent acenes.

    DOI： 10.1002/anie.202411855

    Open Access

  21. Synthesis of ethylene copolymers with 2-allylphenol by using half-titanocene catalysts containing SiEt<sub>3</sub>-, Si<sup>i</sup>Pr<sub>3</sub>-substituted phenoxide ligands, Cp*TiCl<sub>2</sub>(O-2,6-<sup>i</sup>Pr<sub>2</sub>-4-SiR<sub>3</sub>-C<sub>6</sub>H<sub>2</sub>) (R = Et, <sup>i</sup>Pr) Reviewed

    Youshu Jiang, Daisuke Shimoyama, Jiahao Gao, Kotohiro Nomura

    Catalysis Science & Technology     2024.6

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：Royal Society of Chemistry (RSC)  

    Efficient synthesis of ethylene copolymers with 2-allylphenol has been achieved by using the Cp*TiCl<sub>2</sub>(O-2,6-<sup>i</sup>Pr<sub>2</sub>-SiEt<sub>3</sub>-C<sub>6</sub>H<sub>2</sub>)–MAO catalyst system.

    DOI： 10.1039/d4cy00578c

  22. Synthesis of Network Biobased Aliphatic Polyesters Exhibiting Better Tensile Properties than the Linear Polymers by ADMET Polymerization in the Presence of Glycerol Tris(undec-10-enoate) Reviewed Open Access

    Lance O’Hari P. Go, Mohamed Mehawed Abdellatif, Ryoji Makino, Daisuke Shimoyama, Seiji Higashi, Hiroshi Hirano, Kotohiro Nomura

    Polymers   Vol. 16 ( 4 )   2024.2

    　More details

    Publishing type：Research paper (scientific journal)  

    DOI： 10.3390/polym16040468

    Open Access

    Scopus

  23. Synthesis of High Molecular Weight Biobased Aliphatic Polyesters Exhibiting Tensile Properties Beyond Polyethylene Reviewed Open Access

    Mika Kojima, Xiuxiu Wang, Lance O’Hari P. Go, Ryoji Makino, Yuichi Matsumoto, Daisuke Shimoyama, Mohamed Mehawed Abdellatif, Joji Kadota, Seiji Higashi, Hiroshi Hirano, Kotohiro Nomura

    ACS Macro Letters   Vol. 12 ( 10 ) page： 1403 - 1408   2023.10

    　More details

    Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society (ACS)  

    DOI： 10.1021/acsmacrolett.3c00481

    Scopus

    PubMed

  24. Synthesis of Ethylene/Isoprene Copolymers Containing Cyclopentane/Cyclohexane Units as Unique Elastomers by Half-Titanocene Catalysts Reviewed

    Lijuan Guo, Ryoji Makino, Daisuke Shimoyama, Joji Kadota, Hiroshi Hirano, Kotohiro Nomura

    Macromolecules   Vol. 56 ( 3 ) page： 899 - 914   2023.1

    　More details

    Language：English   Publishing type：Research paper (scientific journal)   Publisher：American Chemical Society ({ACS})  

    DOI： 10.1021/acs.macromol.2c02399

    Scopus

  25. Chiral Supramolecular Polymer Formed via Host-Guest Complexation of an Octaphosphonate Biscavitand and a Chiral Diammonium Guest Reviewed

    Koki Hamada, Daisuke Shimoyama, Takehiro Hirao, Takeharu Haino

    Bulletin of the Chemical Society of Japan   Vol. 95 ( 4 ) page： 621 - 627   2022.3

    　More details

    Language：English   Publishing type：Research paper (scientific journal)   Publisher：The Chemical Society of Japan  

    DOI： 10.1246/bcsj.20210452

    Scopus

  26. Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes Reviewed

    Joydeb Goura, James McQuade, Daisuke Shimoyama, Roger A. Lalancette, John B. Sheridan, Frieder Jäkle

    Chemical Communications   Vol. 58 ( 7 ) page： 977 - 980   2022.1

    　More details

    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/d1cc06181j

    Scopus

    PubMed

  27. Negative Cooperativity in Guest Binding of a Ditopic Self-Folding Biscavitand Reviewed

    Haruna Fujimoto, Daisuke Shimoyama, Katsuo Katayanagi, Naomi Kawata, Takehiro Hirao, Takeharu Haino

    Organic Letters   Vol. 23 ( 16 ) page： 6217 - 6221   2021.8

    　More details

    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.orglett.1c01837

    Scopus

    PubMed

  28. Programmed Dynamic Covalent Chemistry System of Addition-condensation Reaction of Phenols and Aldehydes Reviewed Open Access

    Hiroto Kudo, Daisuke Shimoyama, Ryo Sekiya, Takeharu Haino

    Chemistry Letters   Vol. 50 ( 4 ) page： 825 - 831   2021.4

    　More details

    Publisher：The Chemical Society of Japan  

    DOI： 10.1246/cl.200773

    Scopus

  29. Conformation of K<sup>+</sup>(Crown Ether) Complexes Revealed by Ion Mobility-Mass Spectrometry and Ultraviolet Spectroscopy Reviewed

    Sota Tainaka, Tomoyuki Ujihira, Mayuko Kubo, Motoki Kida, Daisuke Shimoyama, Satoru Muramatsu, Manabu Abe, Takeharu Haino, Takayuki Ebata, Fuminori Misaizu, Keijiro Ohshimo, Yoshiya Inokuchi

    Journal of Physical Chemistry A   Vol. 124 ( 48 ) page： 9980 - 9990   2020.12

    　More details

    Publishing type：Research paper (scientific journal)  

    DOI： 10.1021/acs.jpca.0c09068

    Scopus

    PubMed

  30. One-dimensional arrangement of NORIA in the solid-state Reviewed

    Daisuke Shimoyama, Ryo Sekiya, Hiroyuki Maekawa, Hiroto Kudo, Takeharu Haino

    CrystEngComm   Vol. 22 ( 28 ) page： 4740 - 4747   2020.7

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/d0ce00650e

    Scopus

  31. Pseudorotaxanes in the gas phase: structure and energetics of protonated dibenzylamine-crown ether complexes Reviewed Open Access

    Motoki Kida, Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino, Takayuki Ebata, Christophe Jouvet, Yoshiya Inokuchi

    Physical Chemistry Chemical Physics   Vol. 20 ( 27 ) page： 18678 - 18687   2018

    　More details

    Publishing type：Research paper (scientific journal)  

    DOI： 10.1039/C8CP02707B

    Scopus

    PubMed

  32. Allostery in Guest Binding of Rim-to-Rim-Connected Homoditopic Biscavitands Reviewed

    Daisuke Shimoyama, Hitomi Yamada, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    European Journal of Organic Chemistry   Vol. 2016 ( 20 ) page： 3300 - 3303   2016.7

    　More details

    Authorship：Lead author   Publishing type：Research paper (scientific journal)  

    DOI： 10.1002/ejoc.201600410

    Scopus

▼display all

To the head of Papers.▲

MISC 1

  1. コロナ禍における米国ラトガース大学 Jäkle Group での研究生活 Invited Reviewed

    Organometallic News「海外研究室レポート」     2026.3

To the head of MISC.▲

Presentations 74

  1. ホスホン酸エステルによって水酸基を架橋したビスキャビダントの合成とアンモニウム塩の包接における協同性(

    下山大輔, 山田仁美, 関谷亮, 池田俊明, 灰野岳晴

    第13回ホスト・ゲスト化学シンポジウム  2015.6 

    　More details

    Presentation type：Poster presentation  

  2. ホスホン酸エステルによって水酸基を架橋されたビスキャビタントの協同的ゲスト包接

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第14回ホスト・ゲスト化学シンポジウム  2016.6 

    　More details

    Presentation type：Poster presentation  

  3. ビスレゾルシーンアレーン分子を基盤とした超分子ポリマーの合成

    浜田幸希, 下山大輔, 平尾岳大, 灰野岳晴

    第72回高子分子討論会  2023.9 

    　More details

    Presentation type：Oral presentation (general)  

  4. ビスレゾルシンアレーンの改良合成法と超分子ポリマーの構築

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第66回高分子学会年次大会  2017.5 

    　More details

    Presentation type：Oral presentation (general)  

  5. ビスレゾルシンアレーンの合成

    下山大輔, 山田仁美, 関谷亮, 灰野岳晴

    日本化学会第97春季年会  2017.3 

    　More details

    Presentation type：Oral presentation (general)  

  6. ビスキャビタンド分子の自己集合により生じる超分子らせんポリマー

    浜田幸希, 下山大輔, 平尾岳大, 灰野岳晴

    2021年日本化学会中国四国支部大会高知大会  2021.11 

    　More details

    Presentation type：Oral presentation (general)  

  7. ビスキャビタンドの金属配位により生じる超分子らせんポリマー

    浜田幸希, 下山大輔, 平尾岳大, 灰野岳晴

    第31回基礎有機化学討論会  2021.9 

    　More details

    Presentation type：Poster presentation  

  8. ビスキャビタンドの自己集合を駆動力とした超分子らせんポリマーの合成

    浜田幸希, 下山大輔, 平尾岳大, 灰野岳晴

    第18回ホストーゲスト・超分子化学シンポジウム  2021.6 

    　More details

    Presentation type：Poster presentation  

  9. ビスキャビタンドの自己集合により生じる超分子らせんポリマー

    下山大輔, 灰野岳晴

    第30回基礎有機化学討論会  2019.9 

    　More details

    Presentation type：Poster presentation  

  10. ハーフチタノセン触媒によるエチレンとα－メチルスチレンとの共重合

    小島輝竜, 下山大輔, 野村琴広

    第132回触媒討論会  2023.9 

    　More details

    Presentation type：Oral presentation (general)  

  11. ハロゲン含有ポリスチレン及びエチレン共重合体の精密合成と官能基変換 Invited

    下山大輔

    19回 次世代ポリオレフィン総合研究会  2025.8.8 

    　More details

    Presentation type：Oral presentation (invited, special)  

  12. トリスレゾルシンアレーンの立体配座における溶媒効果

    井上翔一朗, 下山大輔, 関谷亮, 灰野岳晴

    第21回ホストゲスト超分子化学シンポジウム  2024.6.1 

    　More details

    Presentation type：Poster presentation  

  13. トリスレゾルシンアレーンの構造と分子認識

    井上翔一朗, 下山大輔, 関谷亮, 灰野岳晴

    第37回若手化学者のための化学道場  2024.9 

    　More details

    Presentation type：Poster presentation  

  14. トリスレゾルシンアレーンの構造と分子認識

    井上翔一朗, 下山大輔, 関谷 亮, 灰野岳晴

    第33回基礎有機化学討論会  2023.9 

    　More details

    Presentation type：Poster presentation  

  15. オレフィンメタセシス重合によるバイオベースポリエステルの末端官能基化ポリマーの合成と特性解析

    佐藤俊輔, 下山大輔, 野村琴広

    第54回石油・石油化学討論会  2024.11.26 

    　More details

    Presentation type：Oral presentation (general)  

  16. オレフィンメタセシスによるバイオベースポリエステルの末端官能基化と特性解析

    佐藤 俊輔, 下山 大輔, 野村 琴広

    第70回高分子研究発表会  2024.7.12 

  17. エントロピー駆動によるビスキャビタンドの協同的ゲスト包接

    下山大輔, 灰野岳晴

    日本化学会第99春季年会  2019.3 

    　More details

    Presentation type：Oral presentation (general)  

  18. Synthesis of Syndiotactic Poly(silylstyrene)s by Nonbridged Half-titanocene Catalysts

    Youshu Jiang, Daisuke Shimoyama, Kotohiro Nomura

    第69回高分子研究発表会（神戸）  2023.7 

    　More details

    Presentation type：Oral presentation (general)  

  19. Synthesis of supported half-titanocene catalysts on bottlebrush surface by living ROMP method

    R. Ichikawa, K. Jaiyen, D. Shimoyama, K. Nomura

    The 20th Japan-Korea Symposium on Catalysis  2025.5.20 

    　More details

    Language：English   Presentation type：Poster presentation  

  20. Synthesis of new titanium complexes containing imidazolin-2-iminato ligands for efficient synthesis of cyclic olefin copolymers

    2023.12 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  21. Synthesis of New Titanium Complexes Containing Imidazolin-2-iminato Ligands and their use in Catalysis for Olefin Polymerization

    Jantawan Ketsanee, Chatchaipaiboon Kanchan, Tamm Matthias, Daisuke Shimoyama, Kotohiro Nomura

    第132回触媒討論会  2023.9 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  22. Synthesis of new phenoxide-modified half-titanicenes for olefin polymerization

    Jiahao Gao, Daisuke Shimoyama, Kotohiro Nomura

    2023.12 

    　More details

    Language：English   Presentation type：Poster presentation  

  23. Synthesis of functionalized bottlebrush polymers by cis-specific metathesis polymerization by vanadium-alkylidene catalysts

    2023.11 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  24. Synthesis of conjugated bottlebrush polymers containing all trans-poly(fluorene-2,7-vinylene) side chains

    2023.12 

    　More details

    Language：English   Presentation type：Poster presentation  

  25. Synthesis of Biobased Polyesters by Olefin Metathesis and the End-Functionalization

    Daisuke Shimoyama, Shunsuke Sato, Kento Hashiguchi, Kotohiro Nomura

    第72回高分子討論会  2023.9 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  26. Synthesis and Cooperative Molecular Recognition of Homoditopic Host Molecule with Rebek's Cavitands

    Haruna Fujimoto, Daisuke Shimoyama, Takehiro Hirao, Takeharu Haino

    日本化学会第101回春季年会  2021.3 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  27. Synthesis and Conformational Characteristics of Feet-to-Feet Connected Bisresorcinarenes

    Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    日本化学会第98春季年会  2018.3 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  28. SYNTHESIS AND CONFORMATIONAL BEHAVIOR OF FEET-TO-FEET CONNECTED BISRESORCINARENES

    Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    13th International Symposium on Macrocyclic and Supramolecular Chemistry (2018 ISMSC)  2018.7 

    　More details

    Presentation type：Poster presentation  

  29. Syntheses of Syndiotactic Poly(silylstyrene)s and the Ethylene Copolymers: A New Route for Synthesis of Halogenated Styrenic (Co)polymers

    Daisuke Shimoyama, Yoshu Jiang, Kotohiro Nomura

    ACS Fall 2024  2024.8.21 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  30. Syndiospecific polymerization of trialkylsilylstyrene and the ethylene copolymerization by half-titanocene catalysts (best poster prize)

    Youshu Jiang, Daisuke Shimoyama, Kotohiro Nomura

    2023.12 

    　More details

    Language：English   Presentation type：Poster presentation  

  31. Supramolecular helical polymers generated by metal coordination of biscavitand

    Koiki Hamada, Daisuke Shimoyama, Takehiro Hirao, Takeharu Haino

    The 19th Nano Bio Info Chemistry Symposium  2022.12 

    　More details

    Presentation type：Oral presentation (general)  

  32. Rebek キャビタンドを導入したビスレゾルシンアレーンホスト分子の合成と協同的分子認

    藤本陽菜, 下山大輔, 平尾岳大, 灰野岳晴

    第31回基礎有機化学討論会  2021.9 

    　More details

    Presentation type：Poster presentation  

  33. Precision Z-/E-specific synthesis of functionalized bottlebrush polymers by living ROMP using (arylimido)vanadium(V)-alkylidene catalysts

    Jaiyen Kanticha, 下山大輔, 野村琴広

    第70回有機金属化学討論会  2024.9.10 

  34. Precise synthesis of syndiotactic poly(halogenated styrene)s and the ethylene copolymers through coordination polymerization and the post-modification

    Daisuke Shimoyama, Youshu Jiang, Kotohiro Nomura

    第73回高分子討論会  2024.9 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  35. Precise Synthesis of Functionalized Polymeric Materials via Coordination Polymerization and Post-Modification Invited

    Daisuke Shimoyama

    SPECIAL SEMINAR (Rutgers University, USA)  2025.3.27 

    　More details

    Language：English   Presentation type：Public lecture, seminar, tutorial, course, or other speech  

  36. Precise synthesis of end-functionalized biobased polyesters by combined olefin metathesis with Wittig-type coupling

    Shunsuke Sato, Daisuke Shimoyama, Motoko S. Asano, Kotohiro Nomura

    第71回有機金属化学討論会  2025.9.17 

    　More details

    Presentation type：Poster presentation  

  37. Precise Synthesis of End-functionalized Biobased Aliphatic Polyesters by Olefin Metathesis

    Daisuke Shimoyama, Shunsuke Sato, Kotohiro Nomura

    ACS Spring 2025  2025.3.25 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  38. Precise Synthesis of bottlebrush conjugated polymer based on poly(fluorene vinylene) by olefin metathesis

    73rd SPSJ Annual Meeting  2024.6.5 

  39. Polycationic organoboronium macrocycles with reversibly accessible multiple redox states

    Daisuke Shimoyama, Nurcan Baser-Kirazli, Roger A Lalancette, Frieder Jäkle

    The 2021 International Chemical Congress of Pacific Basin Societies  2021.12 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  40. Helical supramolecular polymer formed by coordination-driven selfassembly of biscavitands

    Daisuke Shimoyama, Yuta Tsunoda, Takeharu Haino

    日本化学会第100春季年会  2020.3 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  41. Functionalization of tris(pyridyl)borate scorpionate complexes at the bridgehead: Electrophilic and nucleophilic substitution

    James McQuade, Joydeb Goura, Daisuke Shimoyama, John Sheridan, Frieder Jäkle

    ACS Fall  2022.8 

    　More details

    Presentation type：Oral presentation (general)  

  42. Biobased linear/network aliphatic polyesters exhibiting promising tensile properties

    K. Nomura, K. Tao, M. Kojima, X. Wang, L.O.P. Go, D. Shimoyama, M. M. Abdellatif, S. Higashi, H. Hirano

    12th Workshop on Fats and Oils as Renewable Feedstock for the Chemical Industry  2024.6 

    　More details

    Language：English   Presentation type：Poster presentation  

  43. B-N Lewis Functinaled Anthracenes; From Monomers to Polymers

    Jingyao Zuo, Daisuke Shimoyama, Frieder Jäkle

    2022.6 

    　More details

    Language：English   Presentation type：Poster presentation  

  44. Allostery in Guest Binding of Homoditopic Octaphosphonate Biscavitands

    Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    The 13th Nano Bio Info Chemistry Symposium  2016.12 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  45. Allosteric Molecular Recognition of Octaphosphonate Biscavitands

    Daisuke Shimoyama, Hitomi Yamada, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    The 11th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC-2016)  2016.7 

    　More details

    Presentation type：Poster presentation  

  46. Allosteric in Guest Binding and Asymmetric Induction of Octaphosphonate Biscavitands

    Daisuke Shimoyama, Toshiaki Ikeda, Ryo Sekiya, Takeharu Haino

    Chirality 2017; ISCD-29  2017.7 

    　More details

    Language：English   Presentation type：Poster presentation  

  47. Allosteric guest binding of octaphosphonate biscavitands

    Daisuke Shimoyama, Hitomi Yamada, Toshiaki Ikeda, Takeharu Haino

    The International Chemical Congress of Pacific Basin Societies 2015  2015.12 

    　More details

    Language：English   Presentation type：Poster presentation  

  48. ホスホン酸エステルにより水酸基を架橋したビスキャビダントの合成とゲスト包接挙動

    下山大輔, 山田仁美, 関谷亮, 池田俊明, 灰野岳晴

    日本化学会第95春季年会  2015.3 

    　More details

    Presentation type：Oral presentation (general)  

  49. 超分子カプセル分子を連結したらせんポリマーの合成と機能

    浜田幸希, 下山大輔, 平尾岳大, 灰野岳晴

    日本化学会第103春季年会  2023.3 

    　More details

    Presentation type：Oral presentation (general)  

  50. 芳香族イミド配位バナジウムーアルキリデン錯体触媒による開環メタセシス重合による立体特異的Bottlebrushポリマーの合成と特性解析

    Jaiyen Kanticha, 下山大輔, 野村 琴広

    第54回石油・石油化学討論会  2024.11.26 

    　More details

    Language：English   Presentation type：Oral presentation (general)  

  51. 第9回超分子若手懇談会

    下山大輔, 関谷亮, 池田俊明, 灰野岳晴

    第9回超分子若手懇談会  2015.11 

    　More details

    Presentation type：Poster presentation  

  52. 発光性末端基をプローブとした分解性ポリエステルのフィルム化における積層構造

    浅野 素子, 大澤 俊太, 柳沼 基, 佐藤 俊輔, 下山大輔, 野村 琴広

    2025年光化学討論会  2025.9.4 

    　More details

    Presentation type：Poster presentation  

  53. 溶媒分⼦の構造に依存して変化するトリスレゾルシンアレーンの⽴体配座

    井上 翔一朗, 下山 大輔, 関谷 亮, 久野 尚之, 楯 真一, 灰野 岳晴

    2024年日本化学会中国四国支部大会岡山大会  2024.11.16 

    　More details

    Presentation type：Oral presentation (general)  

  54. 機能化された新規大環状分子の合成 Invited

    下山大輔

    化学科コロキウム 東京都立大学  2022.9 

    　More details

    Presentation type：Public lecture, seminar, tutorial, course, or other speech  

  55. 柔軟な大環状トリスレゾルシンアレーンの構造と分子認識

    久野尚之, 井上翔一朗, 下山大輔, 関谷亮, Riyanka Das, 灰野岳晴

    日本化学会第105回春季年会  2025.3.27 

    　More details

    Presentation type：Oral presentation (general)  

  56. 末端官能基化バイオベースポリエステルの合成と物性への末端効果

    佐藤俊輔, 下山大輔, 野村琴広

    第55回石油・石油化学討論会  2025.10.30 

    　More details

    Presentation type：Oral presentation (general)  

  57. 新規フェノキシ配位ハーフチタノセン触媒によるエチレンとスチレンとの共重合

    黄 天天, 下山大輔, 野村琴広

    第53回石油・石油化学討論会  2023.10.27 

    　More details

    Presentation type：Oral presentation (general)  

  58. 四本のアルキル鎖で連結されたビスレゾルシンアレーンの改良合成法と物性

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第65回高分子討論会  2017.9 

    　More details

    Presentation type：Poster presentation  

  59. 四本のアルキル鎖で連結されたビスレゾルシンアレーンの改良合成法と構造

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第44回有機典型元素化学討論会  2017.12 

    　More details

    Presentation type：Poster presentation  

  60. 四本のアルキル鎖で連結されたビスレゾルシンアレーンの合成と構造

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第11回有機π電子系シンポジウム  2017.12 

    　More details

    Presentation type：Poster presentation  

  61. 四本のアルキル鎖で連結されたビスキャビタンド分子の合成と分子認識

    藤本陽菜, 下山大輔, 平尾岳大, 灰野岳晴

    2019年日本化学会中国四国支部大会徳島大会  2019.11 

    　More details

    Presentation type：Oral presentation (general)  

  62. 四本のアルキル鎖で架橋したビスレゾルシンアレーンの改良合成法とその物性

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第28回基礎有機化学討論会  2017.9 

    　More details

    Presentation type：Poster presentation  

  63. 四本のアルキル鎖で架橋されたビスレゾルシンアレーンの改良合成法とアロステリックなゲスト包接

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第111回有機合成シンポジウム  2017.6 

    　More details

    Presentation type：Poster presentation  

  64. 四本のアルキル鎖で架橋されたビスレゾルシンアレーンの改良合成法

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第15回ホスト-ゲスト・超分子化学シンポジウム  2017.6 

    　More details

    Presentation type：Poster presentation  

  65. 四本のアルキル基で連結されたビスキャビタンド分子の協同的分子認識

    藤本陽菜, 下山大輔, 平尾岳大, 灰野岳晴

    第19回ホストゲスト・超分子化学シンポジウム  2022.6 

    　More details

    Presentation type：Oral presentation (general)  

  66. 共役ポリマーを側鎖に有するボトルブラシポリマーの合成とその特性解析

    石井祐成, 下山大輔, 千野浩輝, 國澤実希子, 野村琴広

    第74回高分子討論会  2025.9.16 

    　More details

    Presentation type：Poster presentation  

  67. 八つのホスホン酸エステルにより架橋されたビスキャビタンドの合成と錯形成における協同性

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第50回反応有機若手の会  2015.7 

    　More details

    Presentation type：Poster presentation  

  68. 八つのホスホン酸エステルにより架橋されたビスキャビタンドの協同的錯形成

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第64回高分子討論会  2015.9 

    　More details

    Presentation type：Poster presentation  

  69. 八つのホスホン酸エステルによって架橋されたビスキャビタンドのゲスト包接における協同性

    下山大輔, 関谷亮, 池田俊明, 灰野岳晴

    第26回基礎有機化学討論会  2015.9 

    　More details

    Presentation type：Poster presentation  

  70. レゾルシンアレーン骨格を持つビスキャビタンドの協同的ゲスト包接

    下山大輔, 池田俊明, 関谷亮, 灰野岳晴

    第27回基礎有機化学討論会  2016.9 

    　More details

    Presentation type：Poster presentation  

  71. レゾルシンアレン誘導体のアルキル鎖の偶奇性の評価

    関谷 亮, 下山大輔, 灰野岳晴

    第33回基礎有機化学討論会  2023.9 

    　More details

    Presentation type：Poster presentation  

  72. リン酸エステルにより水酸基を架橋したビスキャビタンドの協同的ゲスト包接

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第30回若手化学者のための化学道場  2014.8 

    　More details

    Presentation type：Poster presentation  

  73. リン酸エステルにより架橋したビスキャビタンドの協同的ゲスト包接

    下山大輔, 山田仁美, 池田俊明, 関谷亮, 灰野岳晴

    第25回基礎有機化学討論会  2014.9 

    　More details

    Presentation type：Poster presentation  

  74. ポリフルオレンビニレンを側鎖に有する櫛型ポリマーの精密合成

    千野 浩輝, 下山 大輔, 野村琴広

    第69回高分子研究発表会（神戸）  2023.7 

    　More details

    Presentation type：Oral presentation (general)  

▼display all

To the head of Presentations.▲

KAKENHI (Grants-in-Aid for Scientific Research) 3

  1. 精密合成された有機ホウ素含有ポリマーが拓く革新的機能創出

    Grant number：24K17727  2024.4 - 2026.3

    日本学術振興会  科学研究費助成事業  若手研究

    下山 大輔

  2. 可逆的な結合を利用した新規不斉テンプレート重合法の開発

    Grant number：22K20540  2022.8 - 2024.3

    日本学術振興会  科学研究費助成事業 研究活動スタート支援  研究活動スタート支援

    下山 大輔

  3. 不斉増殖により誘導される超分子らせんポリマーの不斉空間

    Grant number：18J13703  2018.4 - 2020.3

    日本学術振興会  科学研究費助成事業 特別研究員奨励費  特別研究員奨励費

    下山 大輔

    　 More details

    (1.トリスレゾルシンアレーンの合成)複数の包接サイトをもつホスト分子は分子触媒や超分子ネットワークポリマーへの応用が期待できる。しかし，複数の包接サイトを連結したホスト分子の合成は多段階を要する。出発物質として奇数のアルキル鎖で連結されたジアセタールを用いた縮環反応を行ったところ，三つのレゾルシンアレーンが六本のアルキル鎖によって連結されたトリスレゾルシンアレーンが得られた。
    (2.ビスキャビタンドの配座解析)ビスレゾルシンアレーンは二つの包接部位がねじれたらせん構造を有する。らせん反転における活性化パラメータを求めたところ，らせん反転は対称性の高い構造を遷移構造として起こっていることが示唆された。さらに，分子構造とらせん反転機構の相関を詳細に調査するために，様々な置換基により修飾したビスキャビタンド分子を合成した。同様に活性化パラメータを求めたところ，置換基の構造に関わらずらせん反転機構は同じであることがわかった。
    (3.ビスキャビタンドのエントロピー駆動によるゲスト包接)生体分子を模倣するためにアロステリックレセプターは盛んに開発されてきた。ビスキャビタンド分子のアンモニウム塩に対する会合挙動について調べたところ，ゲスト包接はエントロピー駆動の協同性を発現していることがわかった。
    (4.不斉増殖により誘導される超分子らせんポリマーの不斉空間)人類はキラルな配位子場を用いた不斉合成法の開発に成功しているが，不斉空間を利用した分子変換技術に関して知見は限られている。我々は自己集合キラルカプセルを開発している。そこで，キラルカプセルを構造的に連結させた超分子らせんポリマー合成し，不斉増殖効果により空の不斉空間を提供することを考えた。我々が開発したビスキャビタンド分子は構造的にリンクしているため，ビスキャビタンド分子の自己集合により超分子らせんポリマーを与えることがわかった。

To the head of KAKENHI (Grants-in-Aid for Scientific Research).▲
 

Teaching Experience (On-campus) 3

  1. 無機化学演習

    2026

  2. [G30]理学部化学実験

    2026

  3. 分析化学実験

    2026

To the head of Teaching Experience (On-campus).▲

Teaching Experience (Off-campus) 2

  1. 有機及生物化学演習

    2022.4 - 2026.3 （Tokyo Metropolitan University）

    　More details

    Level：Undergraduate (specialized) 

  2. 化学専門実験II（有機化学）

    2022.4 - 2026.3 （Tokyo Metropolitan University）

To the head of Teaching Experience (Off-campus).▲
 

Social Contribution 2

  1. キャリアセミナー 広島大学理学部化学科

    Role(s)：Lecturer

    2025.6

  2. 神戸市立葺合高等学校 高校生向けキャリアセミナー

    Role(s)：Lecturer

    2024.7

To the head of Social Contribution.▲