記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1038/s41467-019-10641-y

記述言語：日本語   出版者・発行元：Chemistry - A European Journal  

Intermediary radical cations, generated through single-electron oxidation of enol silyl ethers by excited Ir-based photocatalysts, can be exploited as Brønsted acids for the activation of heteroarylcyanides. This strategy enables the direct allylic C−H heteroarylation of enol silyl ethers under visible-light irradiation.

DOI： 10.1002/chem.202101352

Web of Science

Scopus

PubMed

記述言語：日本語   出版者・発行元：Organic and Biomolecular Chemistry  

The synergy of an Ir-based photosensitizer with mild oxidizing ability and a thiol catalyst enables efficient allylic C-H functionalization of enol silyl ethers with imines under visible light irradiation. Subsequent transformations of the aminoalkylated enol silyl ethers allow for the facile construction of unique molecular frameworks such as functionalized octahydroisoindol-4-one.

DOI： 10.1039/d0ob01862g

Web of Science

Scopus

PubMed