2026/03/11 更新

写真a

チェ サンウー
蔡 尚佑
CHAE Sangwoo
所属
未来社会創造機構 マテリアルイノベーション研究所 環境マテリアル研究部門 助教
職名
助教

学位 1

  1. 博士(工学) ( 2019年3月   名古屋大学 ) 

研究キーワード 5

  1. ソリューションプラズマ

  2. グラフェン

  3. 触媒

  4. ナノ材料

  5. 電極材料

研究分野 3

  1. ナノテク・材料 / ナノ材料科学

  2. ナノテク・材料 / ナノ構造化学

  3. ナノテク・材料 / ナノ材料科学

経歴 4

  1. 芝浦工業大学 SIT総合研究所 特任准教授

    2022年4月 - 2024年5月

  2. 芝浦工業大学

    2022年4月 - 2024年5月

  3. 名古屋大学 未来社会創造機構 マテリアルイノベーション研究所 企画戦略室 講師

    2021年4月 - 2022年3月

  4. 名古屋大学 未来社会創造機構 社会イノベーションデザイン学センター 特任助教

    2019年4月 - 2021年3月

学歴 1

  1. 名古屋大学大学院工学研究科博士後期課程マテリアル理工学専攻 博士課程

    2014年10月 - 2019年3月

 

論文 32

  1. Unique Pt-C coordination on inner SWCNT surfaces enhances stability of confined Pt nanoparticles 査読有り

    Deng, ZY; Wang, PF; Yun, HJ; Liu, YY; Pakkang, N; Akceoglu, GA; Chae, S; Sawada, Y; Saito, N

    APPLIED PHYSICS EXPRESS   19 巻 ( 2 )   2026年2月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.35848/1882-0786/ae3358

    Web of Science

  2. Dry-Transferred MoS<sub>2</sub> Films on PET with Plasma Patterning for Full-Bridge Strain-Gauge Sensors 査読有り Open Access

    Kim, J; Lee, M; Lee, W; Lee, M; Kang, CM; Jung, D; Son, H; Kim, E; Chae, S; Kim, J

    SENSORS   26 巻 ( 2 )   2026年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Sensors  

    In this study, a high-performance MoS<inf>2</inf>-based strain-gauge pressure was sensor fabricated entirely below 80 °C, enabling direct integration onto flexible polyethylene terephthalate (PET) substrates. The sensor comprised a three-layer MoS<inf>2</inf> channel (~2 nm) patterned via dry transfer and O<inf>2</inf>/Ar plasma etching, interfaced with Cr/Au electrodes. This wafer-scale and cost-effective fabrication route preserves the crystallinity of the film and prevents substrate degradation. The sensor achieved a gauge factor of ~104 under compression, representing a fifty-fold improvement over conventional metal foil gauges (~2), with a linear response across both compressive and tensile regimes. Mechanical robustness was confirmed through repeated bending and tape adhesion tests, with no degradation in electrical performance. When configured as a Wheatstone bridge, this device exhibits normalized sensitivity suitable for real-time monitoring, with response and recovery times below 200 ms. These results establish O<inf>2</inf>/Ar-plasma-patterned MoS<inf>2</inf> architectures as a scalable, cost-effective platform for next-generation flexible sensors, outperforming metal-foil technology in applications including seat-occupancy detection, wearable physiological monitoring, and tactile interfaces for soft robotics.

    DOI: 10.3390/s26020585

    Open Access

    Web of Science

    Scopus

    PubMed

  3. Dual Structure-Directing Agents for Superstructure Formation in PtCoCu Ternary Alloy Electrocatalysts 査読有り

    Wang, PF; Chae, S; Yun, H; Liu, YY; Deng, Z; Baek, S; Pakkang, N; Akceoglu, GA; Sawada, Y; Saito, N

    JOURNAL OF PHYSICAL CHEMISTRY C   129 巻 ( 51 ) 頁: 22390 - 22402   2025年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Physical Chemistry C  

    The development of high-performance Pt-based electrocatalysts with reduced metal loading is crucial for advancing proton exchange membrane fuel cell technology. Herein, we present a dual structure-directing agent approach for the precise formation of superstructures in uniform PtCoCu ternary alloy nanoparticles. Using zinc phthalocyanine for coordination-based composition control and dicyandiamide for carbon-mediated sintering suppression enabled molecular-level mixing and formation of an L1<inf>0</inf> face-centered cubic superstructure with exceptional uniformity and controlled electronic properties. The optimized L1<inf>0</inf>-Pt<inf>45</inf>Co<inf>24</inf>Cu<inf>31</inf> electrocatalyst exhibited remarkable oxygen reduction reaction activity with a mass activity of 2.13 A/mg<inf>Pt</inf> at 0.9 V vs the reversible hydrogen electrode, representing a 7-fold improvement over commercial Pt/C and exceeding the DOE 2025 target by 483%. The electrocatalyst also demonstrated excellent durability, retaining more than 70% of its initial mass activity after 30 000 potential cycles. Comprehensive density functional theory calculations revealed that ternary alloying optimized the Pt and overall d-band centers, which were located at −2.87 and −2.50 eV, respectively, clarifying the electronic origin of the enhanced electrocatalytic performance. This dual structure-directing strategy overcomes the conventional trade-off between ordered phase formation and particle size control, demonstrating the potential of a tailored precursor design for developing next-generation electrocatalysts with precisely controlled superstructures.

    DOI: 10.1021/acs.jpcc.5c06519

    Web of Science

    Scopus

  4. Tuning electronic structure and ORR performance of PtPdCu catalysts via composition-controlled alloying 査読有り

    Ukai, J; Wang, PF; Akceoglu, GA; Chae, S; Pakkang, N; Sawada, Y; Saito, N

    JOURNAL OF ELECTROANALYTICAL CHEMISTRY   996 巻   頁: 119370 - 119370   2025年11月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Electroanalytical Chemistry  

    Developing compositionally optimized low-Pt catalysts for the oxygen reduction reaction (ORR) remains a key challenge in advancing electrochemical energy conversion technologies. In this study, Pt-Pd-Cu ternary nanoalloys with varying compositions (Pt₅₁Pd₃₄Cu₁₅, Pt₄₀Pd₂₅Cu₃₅, and Pt₃₅Pd₂₃Cu₄₂) and a binary Pt₆₀Pd₄₀ alloy were synthesized via a modified polyol process under controlled conditions. The resulting nanoparticles exhibited improved morphological uniformity and alloy homogeneity. X-ray photoelectron spectroscopy (XPS) revealed composition-dependent electronic structure modulation, which influenced oxygen adsorption and desorption properties. Electrochemical characterization using cyclic voltammetry (CV), linear sweep voltammetry (LSV), and rotating disk electrode (RDE) measurements demonstrated that the Pt₄₀Pd₂₅Cu₃₅ alloy delivered the highest ORR mass activity (455 mA mg<sup>−1</sup> Pt + Pd), outperforming both the binary alloy and commercial Pt/C (197 mA mg<sup>−1</sup> Pt). The enhanced performance is attributed to the synergistic effects of controlled alloying, electronic redistribution, and increased electrochemical active surface area. While membrane electrode assembly (MEA) testing remains for future validation, these findings highlight the potential of Pt-Pd-Cu ternary alloys, particularly Pt₄₀Pd₂₅Cu₃₅, as promising ORR catalysts for next-generation fuel cells.

    DOI: 10.1016/j.jelechem.2025.119370

    Web of Science

    Scopus

  5. Fabrication of Pt nanoparticles encapsulated by N, P co-doped carbon via solution plasma for the oxygen reduction reaction 査読有り

    Ukai, J; Wang, PF; Chae, S; Akceoglu, GA; Pakkang, N; Sawada, Y; Saito, N

    JOURNAL OF ELECTROANALYTICAL CHEMISTRY   994 巻   2025年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Electroanalytical Chemistry  

    The oxygen reduction reaction (ORR) remains a performance-limiting step in fuel cells due to sluggish kinetics and the high cost of platinum-based catalysts. In this study, we report the synthesis of nitrogen and phosphorus co-doped carbon (NPC) encapsulating Pt nanoparticles via a solution plasma process, aiming to reduce Pt usage while enhancing catalyst activity and durability. Structural characterization confirmed a core–shell morphology, with Pt cores uniformly embedded in a conductive, heteroatom-doped carbon shell. X-ray photoelectron spectroscopy revealed active nitrogen species (pyridinic and graphitic N) and P-doping contributing to electron redistribution and active site formation. Electrochemical tests in alkaline media demonstrated that the resulting NPC@Pt catalyst exhibits superior ORR activity, with a four-electron transfer pathway, higher limiting current density, and significantly improved long-term stability compared to commercial Pt/C. These findings highlight the synergy of heteroatom doping and core–shell structuring in advancing cost-effective, durable ORR electrocatalysts for alkaline fuel cells.

    DOI: 10.1016/j.jelechem.2025.119273

    Web of Science

    Scopus

  6. One nanometer matters: quantum-induced discontinuity in the oxygen reduction reaction catalyzed by platinum nanoparticles 査読有り

    Deng, ZY; Liu, YY; Wang, PF; Zhu, ZD; Pakkang, N; Akceoglu, GA; Chae, S; Sawada, Y; Yang, L; Saito, N

    JOURNAL OF MATERIALS CHEMISTRY A     2025年8月

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/d5ta04934b

    Web of Science

  7. Single-step solution plasma synthesis of bifunctional CoSn(OH)<sub>6</sub>-carbon composite electrocatalysts for oxygen evolution and oxygen reduction reactions 査読有り

    Chae, S; Shio, A; Imamura, T; Yamamoto, K; Fujiwara, Y; Panomsuwan, G; Ishizaki, T

    SUSTAINABLE ENERGY & FUELS   9 巻 ( 14 ) 頁: 3875 - 3888   2025年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/d5se00370a

    Web of Science

  8. Highly Dispersed PtPdCu Nanoparticles for Oxygen Reduction Catalytic Performance and Electronic State 査読有り

    Wang, PF; Chae, S; Deng, ZY; Liu, YY; Zhu, ZD; Sawada, Y; Saito, N

    JOURNAL OF PHYSICAL CHEMISTRY C   129 巻 ( 20 ) 頁: 9302 - 9313   2025年5月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Physical Chemistry C  

    In this study, we aimed to synthesize a ternary PtPdCu nanoalloy catalyst supported on commercially available carbon black. A one-step solvothermal method with the addition of urea was adopted to obtain alloy nanoparticles of uniform size. Results showed that the adsorption and desorption of oxygen intermediates were improved in Pt<inf>48</inf>Pd<inf>32</inf>Cu<inf>20</inf> nanoparticles, and the overpotential was greatly reduced. In addition, the RDE test demonstrated a mass activity of 917 mA mg-1 Pt + Pd, which is approximately five times higher than the mass activity of commercial Pt/C (197 mA mg-1 Pt). Furthermore, the accelerated stress test showed that PtPdCu exhibited superior stability compared with commercial Pt/C. In the H<inf>2</inf>-O<inf>2</inf> fuel cell, the maximum power output was 887 mW cm<sup>-2</sup>, with low Pt and Pd loading (13 wt % PtPd/C) on the cathode. X-ray photoelectron spectroscopy (XPS) analysis revealed that the introduction of Pd causes the center of the Pt valence band to shift to an appropriate position, thereby weakening the adsorption of oxygen-containing intermediates throughout the PtPdCu alloy and improving the catalytic performance.

    DOI: 10.1021/acs.jpcc.5c01985

    Web of Science

    Scopus

  9. Synthesis of size-controlled PtPdIr nanoparticles by solution plasma sputtering and their catalytic properties 査読有り

    Liu, YY; Zhu, ZD; Deng, ZY; Wang, PF; Chae, S; Sawada, Y; Saito, N

    RSC ADVANCES   15 巻 ( 16 ) 頁: 12677 - 12688   2025年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:RSC Advances  

    Platinum-based catalysts are widely used in polymer electrolyte fuel cells (PEMFCs) due to their excellent catalytic activity for the oxygen reduction reaction (ORR) and hydrogen oxidation reaction (HOR). In this study, a PtPdIr ternary alloy catalyst was synthesized by a solution plasma (SP) sputtering process with PtPd and PtIr erelctrodes, which provides a non-equilibrium reaction field in solution. The ratio of Ir in the PtPdIr nanoparticles increased as the ratio of Ir in the PtIr electrode increased. However, the ratio reamined constant at about 10%. The size of the nanoparticles could be controlled in the range of 1-3 nm. In addition, the nanoparticles were well dispersed when supported on carbon and no agglomeration was observed. The electrochemical properties of the obtained nanoparticles were investigated in terms of ORR and HOR, and the particle-c (79 : 14 : 7) nanoparticle exhibited the highest ORR and HOR performance. XPS analysis showed that the intensity of IPd(ii) and IPd(0) in particle-c (79 : 14 : 7) was at the same level, and that the chemical bonding state of these elements enhances ORR and HOR activity.

    DOI: 10.1039/d5ra01747e

    Web of Science

    Scopus

    PubMed

  10. Solution plasma process synthesis of dual heteroatom-carbon nanosheets and their application in electrocatalysis: Without heat treatment 査読有り

    Hyun, K; Chae, S

    JOURNAL OF ELECTROANALYTICAL CHEMISTRY   980 巻   2025年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Electroanalytical Chemistry  

    In this study, we successfully synthesized nitrogen and sulfur-doped dual heteroatom graphene carbon nanosheets via a solution plasma process without thermal treatment, recognized for effectively promoting the oxygen reduction reaction (ORR) as non-precious metal catalysts. TEM images revealed large area nanosheets with a crumpled morphology, while EDS elemental mapping confirmed the uniform distribution of carbon, oxygen, nitrogen, and sulfur throughout the nanosheets. Additionally, powder XRD and Raman analysis suggested the presence of turbostratic stacking with an average of around three graphene layers in NSCNs. XPS results confirmed the successful incorporation of nitrogen and sulfur atoms into the graphene structure using our approach. Lastly, NSCNs exhibited lower ORR catalytic activity compared to 20 wt% Pt/C but demonstrated excellent electrochemical stability, highlighting their potential for electrical catalytic applications.

    DOI: 10.1016/j.jelechem.2025.118946

    Web of Science

    Scopus

  11. Synthesis of High-Entropy Perovskite Hydroxides as Bifunctional Electrocatalysts for Oxygen Evolution Reaction and Oxygen Reduction Reaction 査読有り

    Sangwoo Chae, Akihito Shio, Tomoya Kishida, Kosuke Furutono, Yumi Kojima, Gasidit Panomsuwan, Takahiro Ishizaki

    Materials   17 巻 ( 12 ) 頁: 2963 - 2963   2024年6月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:MDPI AG  

    Oxygen reduction reaction (ORR) and oxygen evolutionc reaction (OER) are important chemical reactions for a rechargeable lithium–oxygen battery (LOB). Recently, high-entropy alloys and oxides have attracted much attention because they showed good electrocatalytic performance for oxygen evolution reaction (OER) and/or oxygen reduction reaction (ORR). In this study, we aimed to synthesize and characterize CoSn(OH)6 and two types of high-entropy perovskite hydroxides, that is, (Co0.2Cu0.2Fe0.2Mn0.2Mg0.2)Sn(OH)6 (CCFMMSOH) and (Co0.2Cu0.2Fe0.2Mn0.2Ni0.2)Sn(OH)6 (CCFMNSOH). TEM observation and XRD measurements revealed that the high-entropy hydroxides CCFMMSOH and CCFMNSOH had cubic crystals with sides of approximately 150–200 nm and crystal structures similar to those of perovskite-type CSOH. LSV measurement results showed that the high-entropy hydroxides CCFMMSOH and CCFMNSOH showed bifunctional catalytic functions for the ORR and OER. CCFMNSOH showed better catalytic performance than CCFMMSOH.

    DOI: 10.3390/ma17122963

  12. Solution-Plasma Synthesis and Characterization of Transition Metals and N-Containing Carbon–Carbon Nanotube Composites 査読有り Open Access

    Kodai Sasaki, Kaiki YAMAMOTO, Masaki Narahara, Yushi Takabe, Sangwoo Chae, Gasidit Panomsuwan, Takahiro Ishizaki

    Materials   17 巻   頁: 320   2024年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.3390/ma17020320

    Open Access

  13. Fabrication of Bifunctional Electrocatalytic Macroporous Carbon Materials Including Fe-N-C Bonds and Application to Lithium-Air Batteries

    Kenichi TANAKA, Kaito FUKUSHIMA, Kaiki YAMAMOTO, Kodai SASAKI, Soichiro ANDO, Sangwoo CHAE, Takahiro ISHIZAKI

    Journal of The Surface Finishing Society of Japan   74 巻 ( 2 ) 頁: 118 - 124   2023年2月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:The Surface Finishing Society of Japan  

    DOI: 10.4139/sfj.74.118

  14. Effect on percolation threshold of catalytic layer: Pt/N-Doped graphene shell onto SWCNT for ORR electrode 査読有り

    Dechojarassri, D; Wang, XY; Chae, S; Sawada, Y; Hashimoto, T; Saito, N

    FUEL CELLS   23 巻 ( 1 ) 頁: 4 - 14   2023年2月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Fuel Cells  

    A high-rate oxygen reduction reaction (ORR) is necessary for polymer electrolyte membrane fuel cells (PEMFC). In this work, by using a solution plasma technique, Pt catalytic particles coated with N-doped graphene (Pt-NG) were effectively produced at 25°C. According to transmission electron microscope images, the average diameter of Pt particles was 4 nm, while the graphene layer thickness was less than 1 nm. A catalytic layer of Pt-NG supported on single-walled carbon nanotubes (Pt-NG/SWCNT) was synthesized. Cyclic voltammetry was used to assess the ORR characteristics of Pt-NG/SWCNT catalytic layers. Only at a density of SWCNT to solvent ratio of 0.75 mg ml−1 were the ORR peaks clearly visible. Because of the high resistivity of SWCNT layers, the ORR peaks in other ranges, 0.4 mg ml−1 to 2.0 mg ml−1, were not clearly observed. The effect of SWCNT concentration on conductivity was proven to follow the basic concept of the percolation threshold.

    DOI: 10.1002/fuce.202200020

    Web of Science

    Scopus

    その他リンク: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/fuce.202200020

  15. Solution plasma synthesis of perovskite hydroxide CoSn(OH)<sub>6</sub> nanocube electrocatalysts toward the oxygen evolution reaction 査読有り

    Masaki Narahara, So Yoon Lee, Kodai Sasaki, Kaito Fukushima, Kenichi Tanaka, Sangwoo Chae, Xiulan Hu, Gasidit Panomsuwan, Takahiro Ishizaki

    Sustainable Energy &amp; Fuels   7 巻 ( 11 ) 頁: 2582 - 2593   2023年

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry (RSC)  

    Perovskite-type CoSn(OH)<sub>6</sub> (CSO) with sizes of 100 to 300 nm synthesized by solution plasma process showed superior electrocatalytic properties for oxygen evolution reaction (OER).

    DOI: 10.1039/d3se00221g

  16. One-step synthesis of sulfur-containing carbon nanosheets via solution plasma process for enhanced electrochemical catalyst 査読有り

    Koangyong Hyun, Sangwoo Chae

    New Journal of Chemistry     2023年

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    掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/D3NJ03539E

  17. Morphology control of ZnO nanostructures using Zn and W electrodes in solution plasma process 査読有り Open Access

    Kim, K; Chae, S; Masuda, Y; Saito, N

    MATERIALS LETTERS   309 巻   頁: 131349 - 131349   2022年2月

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    記述言語:日本語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials Letters  

    The morphology of ZnO nanostructures was controlled by the type of electrodes used, without chemical additives in the solution plasma process. Nanorod and nanosheet-type ZnO were synthesized using Zn and W electrodes, respectively. In the solution plasma process, the ZnO nanostructure can be fabricated because of the unique reaction between ions and radicals at the plasma/liquid interface. During this reaction, ions generated from the metal electrode influence the morphology of ZnO by adsorption on the (0 0 1) facet. Zn(OH)42− ions promoted crystal growth in the [0 0 1] direction, resulting in a rod structure. In contrast, the sheet structure was formed owing to the inhibition of growth in the [0 0 1] direction by WO42− ions.

    DOI: 10.1016/j.matlet.2021.131349

    Web of Science

    Scopus

  18. カチオン化窒素ドープグラフェンの有機太陽電池のホール輸送材料PEDOT:PSSへの利用 Open Access

    金子 拓平, 林 昊升, 蔡 尚佑, 八名 拓実, 齋藤 永宏, 松尾 豊

    「次世代の太陽光発電システム」シンポジウム(日本太陽光発電学会学術講演会)予稿集   1 巻 ( 0 ) 頁: 119 - 119   2021年10月

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    記述言語:日本語   出版者・発行元:日本太陽光発電学会  

    DOI: 10.57295/jpvsproc.1.0_119

    Open Access

    CiNii Research

  19. Structure and properties of nanocarbons-encapsulated WC synthesized by solution plasma process in palm oils 査読有り

    Islam, MZ; Watthanaphanit, A; Chae, S; Niitsu, K; Saito, N

    MATERIALS EXPRESS   11 巻 ( 9 ) 頁: 1602 - 1607   2021年9月

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    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1166/mex.2021.2034

    Web of Science

  20. High electrical conductivity and oxidation reduction reaction activity of tungsten carbide/carbon nanocomposite synthesized from palm oil by solution plasma process 査読有り

    Islam, MZ; Watthanaphanit, A; Chae, S; Niitsu, K; Saito, N

    MATERIALS EXPRESS   11 巻 ( 9 ) 頁: 1587 - 1593   2021年9月

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    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1166/mex.2021.2035

    Web of Science

  21. Facile synthesis of ZnO nanobullets by solution plasma without chemical additives Open Access

    Kim, K; Chae, S; Choi, PG; Itoh, T; Saito, N; Masuda, Y

    RSC ADVANCES   11 巻 ( 43 ) 頁: 26785 - 26790   2021年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:RSC Advances  

    ZnO nano-bullets were synthesized using solution plasma from only Zn electrode in water without any chemical agents. In this sustainable synthesis system, the rapid quenching reaction at the interface between the plasma/liquid phases facilitates the fast formation of nano-sized materials. The coil-to-pin type electrode geometry, which overcomes the discharge interruption owing to the electrode gap broadening of the typical pin-to-pin type enables the synthesis of numerous nanomaterials through a stable discharge for 1 h. The as-prepared samples exhibited a high crystalline ZnO structure without post calcination, and the length and width were 71.8 and 29.1 nm, respectively. The main exposed facet of ZnO nano-bullets was the (100) crystal facet, but interestingly, the (101) facet was confirmed at the inclined surfaces in the edges. The (101) crystal facet has an asymmetric Zn and O atom arrangement, and it could result in a focused electron density area with relatively high reactivity. Therefore, ZnO nano-bullets are promising materials for applications in advanced technologies.

    DOI: 10.1039/d1ra05008g

    Open Access

    Web of Science

    Scopus

    PubMed

  22. Cationic nitrogen-doped graphene as a p-type modifier for high-performance PEDOT:PSS hole transporters in organic solar cells 査読有り

    Lin, HS; Kaneko, T; Ishikawa, S; Jeon, I; Chae, S; Yana, T; Saito, N; Matsuo, Y

    JAPANESE JOURNAL OF APPLIED PHYSICS   60 巻 ( 7 ) 頁: 070902 - 070902   2021年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Japanese Journal of Applied Physics  

    This research paper reports the enhanced hole-transporting ability of widely utilized poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) achieved by applying cationic nitrogen-doped graphene (CNG) as a p-type modifier for efficient organic solar cells (OSCs). The power conversion efficiency (PCE) of the CNG-coated PEDOT:PSS-applied OSC reaches 2.76%, which is an increase of 40% compared to that of the pristine PEDOT:PSS-applied OSC (1.96%). The significantly enhanced performance is contributed by the increased hole-transporting ability, and the improved interfacial morphology of PEDOT:PSS, which affords high-quality active layers.

    DOI: 10.35848/1347-4065/ac00fc

    Web of Science

    Scopus

  23. Li-air battery and ORR activity of nanocarbons produced with good synthesis rate by solution plasma process 査読有り Open Access

    Islam, MZ; Watthanaphanit, A; Chae, S; Saito, N

    MATERIALS ADVANCES   2 巻 ( 8 ) 頁: 2636 - 2641   2021年4月

     詳細を見る

    掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials Advances  

    Nanocarbons were successfully synthesized from benzene (BZ), nitro-benzene (BZ-NO2) and aniline (BZ-NH2) by solution plasma process (SPP). The SPP was generated by a bipolar pulsed power supply between two tungsten electrodes at room temperature. The synthesized nanocarbons were investigated. The highest synthesis rate, 40 mg min-1, was for the BZ nanocarbon. The transmission electron microscopy (TEM) morphology showed that the nanocarbon sizes were 15-25 nm. The Brunauer-Emmett-Teller (BET) analysis shows a highest surface area of 220 m2 g-1, pore size of 0.45 cm3 g-1, and average pore diameter of 20.0 nm for the BZ nanocarbon. Cyclic voltammetry (CV) in an acidic medium exhibited the oxygen reduction reaction (ORR) of the nanocarbons. The nanocarbon from BZ-NH2 obtained a high special capacity of 15 500 mA h per g of carbon at the discharge rate of 0.1 mA cm-2 with 1.0 mg carbon loading for the lithium (Li)-air battery. The ORR is an important reaction in Li-air batteries and fuel cells for the application of next-generation batteries and energy conversion devices.

    DOI: 10.1039/d0ma00926a

    Open Access

    Web of Science

    Scopus

  24. Solution Plasma Synthesis of B-Doped Graphene Derivatives with Enhanced Photocatalytic Properties

    Xiaoyang Wang, Sangwoo Chae, Nagahiro Saito

    ECS Meeting Abstracts   MA2020-02 巻 ( 7 ) 頁: 1140 - 1140   2020年11月

     詳細を見る

    掲載種別:研究論文(学術雑誌)   出版者・発行元:The Electrochemical Society  

    At present, human beings are facing two major problems: energy crisis and environmental pollution. Massive anthropogenic emissions of carbon dioxide (CO<sub>2</sub>) associated with increased consumption of fossil fuels have contributed to global warming and the energy crisis. The photocatalytic CO<sub>2</sub> reduction (PCCR) to solar fuels such as methane, methanol and carbon monoxide is considered to be one of the best solutions to solve these problems. In recent years, with the invention of graphene and its derivatives, heterographene photocatalytic materials have become the focus of attention, especially for the development of photocatalysts and the application of photocatalysis. Heterographene and its derivatives can overcome the limitations of traditional photocatalysts, due to their excellent physicochemical and electrical properties like high specific surface area, stability, corrosion resistance, photosensitivity, and electrical conductivity. Therefore, heterographene-based photocatalysts could be a viable strategy to break new grounds in the area of PCCR to useful chemicals/fuels, i.e. converting sunlight to fuels. The current methods for the synthesis of heterographene are complex or harsh conditions, so it is urgent to develop new methods for the synthesis of doped graphene. In this study, the B-doped graphene derivatives were synthesized for PCCR by solution plasma (SP), which can provide us a rapid synthesis at room temperature and atmospheric pressure.

    Acknowledgements

    This work was financially supported by JST-OPERA (JPMJOP1843), JST-SICORP (JPMJSC18H1) and JSPS-KAKENHI (JP18K18998).

    DOI: 10.1149/ma2020-0271140mtgabs

    その他リンク: https://iopscience.iop.org/article/10.1149/MA2020-0271140mtgabs/pdf

  25. Facile Solution Plasma Synthesis of Cationic Nitrogen-Doped Graphene

    Sangwoo Chae, Nagahiro Saito

    ECS Meeting Abstracts   MA2020-02 巻 ( 7 ) 頁: 1139 - 1139   2020年11月

     詳細を見る

    掲載種別:研究論文(学術雑誌)   出版者・発行元:The Electrochemical Society  

    Cationic N-doped graphene (CNG) was synthesized through a new method called Solution Plasma (SP) in a mixture of ionic liquid and organic solution, at ambient temperature and atmospheric pressure. The originality of the research consists in two things. First, the process allows one-step, rapid, substrate-free synthesis and simultaneously doping of CNG. X-ray diffraction, transmission electron microscopy, X-ray photoelectron and Raman spectroscopy confirmed that the graphene synthesis had proceeded, the material contains a high-level of nitrogen (13.4 at%) with the presence of cationic nitrogen, and has a few-layer structure (about 3-layer). Second, CNG behave like p-type semiconductor with a high sheet resistance of 16 Ω sq<sup>−1</sup> and a high carrier concentration of 10<sup>19</sup> cm<sup>−3</sup>; indicating that process can significantly control the electrical properties of graphene. The combination of SP and ILs shows a promising strategy for the design and synthesis of NG using cationic N-doping, which cannot be achieved with other methods.

    Acknowledgements

    This work was financially supported by JST-OPERA (JPMJOP1843), JST-SICORP (JPMJSC18H1) and JSPS-KAKENHI (JP18K18998).



    Figure 1

    <p></p>

    DOI: 10.1149/ma2020-0271139mtgabs

    その他リンク: https://iopscience.iop.org/article/10.1149/MA2020-0271139mtgabs/pdf

  26. Relationship between Carbon Structure-Electrical Conductivity By Cluster Analysis for Li-Ion Battery Application

    J.M. Moon, S.W. Chae, P. Pornaroontham, R. Naraprawatphong, X. Wang, N. Saito

    ECS Meeting Abstracts   MA2020-02 巻 ( 7 ) 頁: 1138 - 1138   2020年11月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:The Electrochemical Society  

    Carbon materials are widely used as anode on Li-ion battery (LIB). In particular, the effect of electrical conductivity (EC) on the anode is related to capacity and retention, which are important factors for LIB performance. However, the relationship between carbon properties and battery performance is still unclear. This uncertainty is due to the sp3 and sp2 bond states, the diversity of carbon like amorphous structures, and impurities.

    In this study, we investigate the structure-EC relationship from over 50 carbon samples. The carbon used was graphite, carbon nanotube (CNT), carbon black (CB), hetero atom doped carbon, and the ones synthesized by solution plasma. The carbon materials are evaluated by X-ray diffraction (XRD), Raman spectroscopy, Thermogravimetric analysis (TGA), Energy-dispersive X-ray spectroscopy (EDX), and four-point probe (FPP) measurement. The characterized values were extracted from the results and analyzed by Cluster analysis (CA) with JMP software. CA was used to classify how carbons are related to each other.

    The clusters were divided into 3 big groups according to the presence of 002 peak and the degree of defects. Some clusters have been shown high conductivity when they have high crystallinity. It was also found that the heteroatomic effect was higher than the crystallinity in the part showing low EC range. However overall correlation with EC is still unclear. This is because XRD and Raman can only provide information of symmetric or periodic structures rather than the effect of disorder or amorphous parts, sizes and shapes are not considered. Thus, analysis of shapes and sizes such as SEM and BET, and additional measurements related to amorphous structures may be helpful to clarifying the correlation.



    Figure 1

    <p></p>

    DOI: 10.1149/ma2020-0271138mtgabs

    その他リンク: https://iopscience.iop.org/article/10.1149/MA2020-0271138mtgabs/pdf

  27. Single-Walled Carbon Nanotubes Wrapped by Cationic Nitrogen-Doped Carbon for Electrocatalytic Applications 査読有り

    Chae, S; Phan, PQ; Panomsuwan, G; Bratescu, MA; Hashimoto, T; Teshima, K; Saito, N

    ACS APPLIED NANO MATERIALS   3 巻 ( 10 ) 頁: 10183 - 10189   2020年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ACS Applied Nano Materials  

    The exploration of novel carbon material systems has emerged as a promising strategy for yielding unique and unconventional functional properties. In this study, a cationic nitrogen-doped carbonwrapped single-walled carbon nanotube (CN-C@SWCNT) was synthesized for the first time via solution plasma (SP) by using an aniline aqueous solution with the SWCNT dispersion under ambient conditions. The reactive species produced from SP led to the formation of cationic nitrogendoped carbon (CN-C) completely wrapped around SWCNT. Raman spectroscopy, electron diffraction, and X-ray photoelectron spectroscopy confirmed the presence of cationic nitrogen. CN-C@SWCNT exhibited an excellent electrical conductivity of 120.30 S cm-1. Room-temperature halleffect measurements revealed p-type semiconducting behavior for CN-C@ SWCNT, with a carrier concentration of 4.6 × 1020 cm-3. The electrical conductivity and carrier concentration of p-type CN-C@SWCNT were greater than those reported previously for carbon-based materials. The high electrical properties of CN-C@SWCNT were synergistically related to a conducting bridge between CN-C and SWCNT conducting domains and the presence of doped cationic nitrogen. The SP-synthesized CN-C@SWCNT demonstrates immense potential as an emerging class of p-type carbon materials in advanced electrocatalytic applications.

    DOI: 10.1021/acsanm.0c02164

    Web of Science

    Scopus

  28. <i>In situ</i>synthesis of copper nanoparticles encapsulated by nitrogen-doped graphene at room temperature<i>via</i>solution plasma 査読有り Open Access

    Phan, PQ; Chae, S; Pornaroontham, P; Muta, Y; Kim, K; Wang, XY; Saito, N

    RSC ADVANCES   10 巻 ( 60 ) 頁: 36627 - 36635   2020年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:RSC Advances  

    Metal-carbon core-shell nanostructures have gained research interest due to their better performances in not only stability but also other properties, such as catalytic, optical, and electrical properties. However, they are limited by complicated synthesis approaches. Therefore, the development of a simple method for the synthesis of metal-carbon core-shell nanostructures is of great significance. In this work, a novel Cu-core encapsulated by a N-doped few-layer graphene shell was successfully synthesized in a one-pot in-liquid plasma discharge, so-called solution plasma (SP), to our knowledge for the first time. The synthesis was conducted at room temperature and atmospheric pressure by using a pair of copper electrodes submerged in a DMF solution as the precursor. The core-shell structure of the obtained products was confirmed by HR-TEM, while further insight information was explained from the results of XRD, Raman, and XPS measurements. The obtained Cu-core encapsulated by the N-doped few-layer graphene shell demonstrated relatively high stability in acid media, compared to the commercial bare Cu particles. Moreover, the stability was found to depend on the thickness of the N-doped few-layer graphene shell which can be tuned by adjusting the SP operating conditions. This journal is

    DOI: 10.1039/d0ra07162e

    Open Access

    Web of Science

    Scopus

    PubMed

  29. Nitriding an Oxygen-Doped Nanocarbonaceous Sorbent Synthesized via Solution Plasma Process for Improving CO<sub>2</sub> Adsorption Capacity 査読有り Open Access

    Pornaroontham, P; Panomsuwan, G; Chae, S; Saito, N; Thouchprasitchai, N; Phongboonchoo, Y; Pongstabodee, S

    NANOMATERIALS   9 巻 ( 12 )   2019年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Nanomaterials  

    The synthesis of carbon nanoparticles (Cn) and oxygen-doped nanocarbon (OCn) was successfully done through a one-step synthesis by the solution plasma process (SPP). The Cn and OCn were nitrogen-doped by nitridation under an ammonia atmosphere at 800◦C for 2 h to yield NCn and NOCn, respectively, for carbon dioxide (CO2) adsorption. The NOCn exhibited the highest specific surface area (~570 m2 g−1) and highest CO2 adsorption capacity (1.63 mmol g−1 at 25◦C) among the synthesized samples. The primary nitrogen species on the surface of NOCn were pyridinic-N and pyrrolic-N. The synergistic effect of microporosity and nitrogen functionality on the NOCn surface played an essential role in CO2 adsorption enhancement. From the thermodynamic viewpoint, the CO2 adsorption on NOCn was physisorption, exothermic, and spontaneous. The NOCn showed a more negative enthalpy of adsorption, indicating its stronger interaction for CO2 on the surface, and hence, the higher adsorption capacity. The CO2 adsorption on NOCn over the whole pressure range at 25–55◦C best fitted the Toth model, suggesting monolayer adsorption on the heterogeneous surface. In addition, NOCn expressed a higher selective CO2 adsorption than Cn and so was a good candidate for multicycle adsorption.

    DOI: 10.3390/nano9121776

    Open Access

    Web of Science

    Scopus

    PubMed

  30. p-Type Doping of Graphene with Cationic Nitrogen 査読有り

    Chae, S; Panomsuwan, G; Bratescu, MA; Teshima, K; Saito, N

    ACS APPLIED NANO MATERIALS   2 巻 ( 3 ) 頁: 1350 - 1355   2019年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ACS Applied Nano Materials  

    Tailoring electrical properties of graphene by nitrogen doping is currently of great significance in a broad area of advanced applications. Bonding configuration of nitrogen atoms in graphene plays a vital role in controlling its electrical, chemical, and optical properties. Here, we report for the first time a simple bottom-up synthesis of a novel cationic nitrogen-doped graphene (CNG) by a solution plasma (SP). A mixture of ionic liquid and organic solvent was used as starting precursor. CNG exhibited an orthorhombic structure possibly due to the presence cationic nitrogen in hexagonal graphene lattice. Nitrogen doping content was found to be as high as 13.4 atom %. Electrical characterization demonstrated that the CNG exhibited a p-type semiconducting behavior with superior electrical conductivity and carrier concentration. Such unique electrical characteristics of CNG are mainly attributed to the presence of cationic nitrogen with preserved planar structure.

    DOI: 10.1021/acsanm.8b02237

    Web of Science

    Scopus

  31. The Nano-Structure and Their Properties of Exfoliation Several Layers-Stacked Graphene Prepared from Graphite Dispersed in Aqueous Solutions by Solution Plasma 査読有り

    Chae, S; Hashimi, K; Bratescu, MA; Saito, N

    NANOSCIENCE AND NANOTECHNOLOGY LETTERS   10 巻 ( 5-6 ) 頁: 784 - 789   2018年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1166/nnl.2018.2716

    Web of Science

  32. Synthesis of Few-Layer Graphene by Peeling Graphite Flakes via Electron Exchange in Solution Plasma 査読有り

    Chae, S; Bratescu, MA; Saito, N

    JOURNAL OF PHYSICAL CHEMISTRY C   121 巻 ( 42 ) 頁: 23793 - 23802   2017年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Physical Chemistry C  

    Compared with conventional graphene, few-layer graphene is an easy-to-use material because of its interesting mechanical and chemical properties. Meanwhile, solution plasma (SP) represents a nonequilibrium discharge, which induces electron exchange similar to a catalyst. Thus, SP serves as an electron donor and acceptor between organic molecules and graphite flakes in a solution. Finally, electron exchange leads to the formation of few-layer graphene by peeling graphite flakes. Furthermore, CN-functionalized few-layer graphene (f-FLG) exhibits excellent stability and dispersibility because of the balance of attractive and repulsive forces, i.e., the van der Waals force between the planes and the electrostatic force of the nitrile functional groups on the edges. In this study, f-FLG was successfully synthesized by peeling graphite flakes via electron exchange induced by SP in an aqueous solution containing an ionic liquid (IL) (1-ethyl-3-methylimidazolium dicyanamide (EMIM-DCA)). X-ray diffraction measurements revealed that the intensity of the 002 diffraction of graphite and the crystallite size along the [001] direction decreased to about 5 nm after SP treatment, indicating the progress of graphite flake peeling. Furthermore, the purified product comprised three layers with a crystallite size along the basal plane of about 80 nm evaluated by the deconvolution of the Raman 2D band. X-ray photoelectron spectroscopy confirmed that the synthesized f-FLG contains 7.7 atom % nitrogen, and the IR spectrum revealed the presence of the CN functional group. To understand the peeling mechanism, the ionization potential (IP) and electron affinity (EA) of the IL in water, and the averaged electron excitation temperature (Te) in plasma were estimated by ab initio molecular orbital calculations, cyclic voltammetry, and optical emission spectroscopy. An energy diagram of IP, EA, and Te shows that SP served to pump electrons for their circulation via EMIM-DCA and to remove electrons from graphite flakes and inject into f-FLG.

    DOI: 10.1021/acs.jpcc.7b08516

    Web of Science

    Scopus

▼全件表示

講演・口頭発表等 62

  1. Cocktail-Effect-Driven Multifunctional Electrocatalysis in a Pt–Ru–Co–Fe–Ni High-Entropy Alloy 国際会議

    P. Wang, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  2. Biomimetic Carbon Shells for Atomic-Scale Molecular and Ionic Transport Enabled by Topological Defects and Chemical Selectivity 国際会議

    N. Saito, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

  3. Alkali Metal-Enhanced Solution-Based Synthesis of MoS2 国際会議

    C. Hussakan, N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  4. Carbon-Environment-Engineered PtCo3 Intermetallic Nanocatalysts with Graphene Shells for Highly Active and Durable ORR in PEMFCs 国際会議

    S. J. Back, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  5. Early SEI Formation on Graphite anodes driven by the coupled effects of plasma-induced surface functionalization and morphological reconstruction 国際会議

    B. Zhang, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  6. Quantum-Confined Platinum Nanoparticles in Carbon Nanotubes for Efficient Oxygen Reduction 国際会議

    Z. Deng, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  7. Flexible Zinc-Ion Batteries Enabled by Solution Plasma-Reinforced SWCNT Buckypaper Current Collectors and V2O5 Cathodes 国際会議

    C. Yonchai, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The International Symposium on Biomimetic Materials Processing 2026  2026年1月22日 

     詳細を見る

    開催年月日: 2026年1月

    記述言語:英語   会議種別:ポスター発表  

  8. Graphene-Encapsulated Pt–Co Electrocatalysts Synthesized by Solution Plasma Process for Highly Durable ORR 国際会議

    S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 8th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年11月20日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:China, Shanghai  

  9. Enhancing Fluoride Ion Mobility via Multi-Cation Substitution in PbSnF-Based Solid Electrolytes 国際会議

    G. A. Akceoglu, S. W. Chae, N. Pakkang, Y. Sawada, N. Saito.

    The 8th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年11月20日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:China, Shanghai  

  10. Hierarchical Porous Carbon Synthesis by Solution Plasma for Supercapacitor Applications 国際会議

    N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 8th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年11月20日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:China, Shanghai  

  11. Effect of Substrate Surface Topography and Chemical Bonding State on the Crystallinity of Molybdenum Disulfide Thin Films 国際会議

    K. Sugiyama, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 8th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年11月21日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:China, Shanghai  

  12. Synthesis of Carbon-Coated Pt–Ni Alloy Nanoparticles for Fuel Cell Catalysts via the Solution Plasma Process 国際会議

    R. Tanaka, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 8th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年11月20日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:China, Shanghai  

  13. Plasma Technique and Its Application to Materials for Energy Storage Devices and Several Other Applications 国際会議

    Y. Sawada, A. Akceoglu, N. Pakkang, S. W. Chae, G. N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月2日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

    開催地:Thailand, Phuket  

  14. Development Of Graphene- Encapsulated Silicon Composite Anodes Via Solution Plasma Processing For High- Performance Lithium-Ion Batteries 国際会議

    A. Akceoglu, N. Pakkang, S. W. Chae, G. Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月2日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  15. N-doped Carbonencapsulated RuCo Alloy Supported On Carbon For Efficient Acidic Oxygen Evolution Reaction 国際会議

    J. Y. Kim, S. W. Chae, A. Akceoglu, N. Pakkang, G. Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月4日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  16. Modulation Of Work Function And Lithium Intercalation Kinetics On HOPG Via Biased Plasma Jet Treatment 国際会議

    B. Zhang, S. W. Chae, A. Akceoglu, N. Pakkang, G. Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月4日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  17. Hierarchical Porosity Engineering Of Solution Plasma- Derived Carbon For High-Voltage EDLCs Using Ionic Liquid Electrolytes 国際会議

    N. Pakkang, A. Akceoglu, S. W. Chae, G. Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月4日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  18. Alkali Metal-Promoted Scalable Solution Synthesis Of High-Quality MoS2 Films 国際会議

    C. Hussakan, N. Pakkang, A. Akceoglu, S. W. Chae, G. Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月3日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  19. Selective Removal Of Organic Pollutants Using MnO2 Recovered From Spent Alkaline Batteries 国際会議

    C. Buaphet, N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    AEPSE 2025, ICSE & R-INTERFINISH  2025年11月4日 

     詳細を見る

    開催年月日: 2025年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Phuket  

  20. Microporosity Tailoring of Solution Plasma-Derived Carbon via ZnO Templating and Thermal Air Treatment for EDLC 国際会議

    N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月11日 

     詳細を見る

    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  21. Plasma Processing and Its Application to Materials for Energy Storage Devices and Several Other Applications 国際会議

    Y. Sawada, A. Akceoglu, N. Pakkang, S. W. Chae, G. N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月12日 

     詳細を見る

    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  22. Alkali Metal-Induced Monolayer Growth of MoS2 Enables Scalable Solution-Based Synthesis 国際会議

    C. Hussakan, N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月12日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  23. N-Doped Carbon-Encapsulated RuCo Alloy for Highly Efficient Oxygen Evolution under Acidic Conditions 国際会議

    J. Y. Kim, S. J. Baek, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月12日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  24. Fluoride-Ion Mobility through Multi-Cation Substitution in PbSnF-Based Solid Electrolytes 国際会議

    A. Akceoglu, N. Pakkang, S. W. Chae, G. Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月11日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  25. Graphene-Encapsulated platinum-based electrocatalyst via Solution Plasma Process for Robust Oxygen Reduction Reaction 国際会議

    S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月11日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  26. Development of Self-Standing Electrodes Based on Solution Plasma-Modified Buckypaper and Mesoporous V2O5 for Flexible Rechargeable Zn-ion Batteries 国際会議

    C. Yonchai, N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月11日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  27. Solution-Plasma Synthesis of Ordered PtCo₃@N-Graphene on Defect-Engineered Highly Graphitized Carbon for Ultralow-Pt, Durable ORR 国際会議

    S. J. Baek, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    The 7th Symposium on Socio-technical Innovation for Zero Carbon in Asian   2025年9月11日 

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    開催年月日: 2025年9月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  28. Carbon-Encapsulated RuCo Alloy Nanoparticles via Solution Plasma for High-Activity Acidic Oxygen Evolution 国際会議

    J. Y. Kim, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  29. Toward Sustainable Anode Materials for Li-ion batteries: Surface Engineering of Recycled Graphite from Spent Zn–C Batteries 国際会議

    H. Yun, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  30. Strain-Regulated Fabrication of Small-Sized Ordered Pt2CoCu Ternary Intermetallic Compounds for Efficient Oxygen Reduction and Hydrogen Evolution Reactions 国際会議

    P. Wang, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  31. Advanced Pt–Co Alloy Catalysts Protected by Defective Carbon Shells for High-Performance and Durable Oxygen Reduction 国際会議

    S. J. Back, S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  32. Pt–M@Graphene Core–Shell Nanoparticles as Efficient Electrocatalysts for the Oxygen Reduction Reaction 国際会議

    S. W. Chae, N. Pakkang, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Bangkok  

  33. Solution Plasma Process 国際会議

    N. Pakkang, S. W. Chae, G. A. Akceoglu, Y. Sawada, N. Saito.

    PPC AND PERTOMAT SYMPOSIUM 2025  2025年6月26日 

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    開催年月日: 2025年6月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Thailand, Bangkok  

  34. Solution plasma synthesis and characterization of perovskite hydroxide CoSn(OH)6 electrocatalysts 国際会議

    M. Nanahara, S. W. Chae, T. Ishizaki

    21st International Conference on Surface Engineering (ICSE2023)  2023年11月19日 

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    開催年月日: 2023年11月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Busan  

  35. Enhanced Performance of Pt Nanoparticles on N-P Co-Doped Graphene for Oxygen Reduction Reaction 国際会議

    S. W. Chae, T. Ishizaki

    21st International Conference on Surface Engineering (ICSE2023)  2023年11月19日 

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    開催年月日: 2023年11月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Korea, Busan  

  36. Pt nanoparticles Encapsulated by N, P co-doped Graphene for Bifunctional Oxygen Electrodes 国際会議

    S. W. ChaeU, T. Ishizaki

    21st International Nanotech Symposium (NANOKOREA 2023)  2023年7月4日 

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    開催年月日: 2023年7月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Ilsan  

  37. Identification of Structural Descriptors of Carbon Materials for Lithium-ion Batteries by Unsupervised Cluster Analysis 国際会議

    J. M. Moon, S. W. Chae, N. Saito

    20th International Union for Surface Finishing (Interfinish 2020)  2021年9月6日 

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    開催年月日: 2021年9月

    記述言語:英語   会議種別:口頭発表(一般)  

  38. The Study of the Correlation between Shape of Carbon Particle in Li-ion Battery and Its Powder Resistance by Cluster Analysis 国際会議

    S. W. Chae, M. Muta, N. Saito

    20th International Union for Surface Finishing (Interfinish 2020)  2021年9月6日 

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    開催年月日: 2021年9月

    記述言語:英語   会議種別:口頭発表(一般)  

  39. Facile Solution Plasma Synthesis of Cationic Nitrogen-Doped Graphene 国際会議

    S. W. Chae, N. Saito

    The Electrochemical Society (ECS 2020)  2020年10月4日 

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    開催年月日: 2020年10月

    記述言語:英語   会議種別:ポスター発表  

  40. Solution Plasma Synthesis of B-Doped Graphene Derivatives with Enhanced Photocatalytic Properties 国際会議

    X. Wang, S. W. Chae, N. Saito

    The Electrochemical Society (ECS 2020)  2020年10月4日 

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    開催年月日: 2020年10月

    記述言語:英語   会議種別:ポスター発表  

  41. Relationship between Carbon Structure-Electrical Conductivity By Cluster Analysis for Li-Ion Battery Application 国際会議

    J. M. Moon, S. W. Chae, N. Saito

    The Electrochemical Society (ECS 2020)  2020年10月4日 

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    開催年月日: 2020年10月

    記述言語:英語   会議種別:ポスター発表  

  42. N+-doped Graphene by Solution Plasma 国際会議

    S. W. Chae, P. Pornaroontham, R. Naraprawatphong, X. Wang N. Saito

    Plasma Surface Engineering Satellite 2020 (PSE Satellite 2020)  2020年6月15日 

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    開催年月日: 2020年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Czech  

  43. Quantitative Structure-Activity Relationship for Carbons prepared by Solution Plasma 国際会議

    J.M. Moon, US.W. ChaeU, P. Pornaroontham, R. Naraprawatphong, X. Wang, T. Watanabe, N. Saito

    Plasma Surface Engineering Satellite 2020 (PSE Satellite 2020)  2020年6月15日 

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    開催年月日: 2020年6月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Czech  

  44. One-Pot Synthesis of Cationic Nitrogen-doped Graphene 国際会議

    S. W. Chae, G. Panomsuwan, N. Saito

    The 2nd International Conference on Materials Research and Innovation (ICMARI 2019)  2019年12月16日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  45. Solution Plasma Process: a Novel Method for Wastewater Treatment 国際会議

    P. Pornaroontham, M. Tipplook, S. W. Chae, N. Saito

    Materials Research Meeting Materials Innovation for Sustainable Development Goals (MRM 2019)  2019年12月11日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Japan, Yokohama  

  46. Highly Cationic Nitrogen-doped Graphene to Enhance Electric Properties via Solution Plasma 国際会議

    S. W. Chae, G. Panomsuwan, N. Saito

    Materials Research Meeting Materials Innovation for Sustainable Development Goals (MRM 2019)  2019年12月10日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Japan, Yokohama  

  47. Analyzing Properties of Nitrogen, Boron and Nitrogen-Boron Doped Few-Layer Graphene Coated Copper Nanoparticles Synthesized by Solution Plasma for Oxygen Reduction Reaction Catalyst 国際会議

    P. Q. Phan, S. Kim, Y. Muta, S. W. Chae, K. S. Kim, M. Tipplook, N. Saito

    Materials Research Meeting Materials Innovation for Sustainable Development Goals (MRM 2019)  2019年12月10日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:シンポジウム・ワークショップ パネル(公募)  

    開催地:Japan, Yokohama  

  48. Synergistic Effect of Electrical Properties of Cationic Nitrogen-Doped Carbon and Carbon Nanotubes Composites Synthesized via Plasma Solution 国際会議

    S. W. Chae, T. Yana, G. Panomsuwan, N. Saito

    Materials Research Meeting Materials Innovation for Sustainable Development Goals (MRM 2019)  2019年12月10日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Japan, Yokohama  

  49. Solution Plasma and Hetero-Graphene 国際会議

    S. W. Chae, G. Panomsuwan, N. Saito

    Materials Research Meeting Materials Innovation for Sustainable Development Goals (MRM 2019)  2019年12月10日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:口頭発表(一般)  

    開催地:Japan, Yokohama  

  50. One-Step Synthesis and Properties of Cationic Nitrogen-doped Graphene by Solution Plasma, 国際会議

    S. W. Chae, G. Panomsuwan, N. Saito

    2019 Materials Research Society Fall Meeting & Exhibit (2019 MRS)  2019年12月3日 

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    開催年月日: 2019年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:USA, Boston  

  51. Synthesis of Cationic N-doped Graphene via Solution Plasma 国際会議

    S. W. Chae, M. A. Bratescu, N. Saito

    Asian-European International Conference on Plasma Surface Engineering 2019 (AEPSE 2019)  2019年9月2日 

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    開催年月日: 2019年9月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Jeju  

  52. A Study of Cationic Nitrogen-doped Carbon Wrapping Carbon Nanotubes with Excellent Electrical Conductivity and High Carrier Concentration 国際会議

    S. W. Chae, T. Yana, N. Saito

    Asian-European International Conference on Plasma Surface Engineering 2019 (AEPSE 2019)  2019年9月4日 

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    開催年月日: 2019年9月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Jeju  

  53. Solution Plasma Synthesis of Nitrogen-doped Few-layer Graphene Coated Copper and Silver Nanoparticles for Oxygen Reduction Reaction Catalyst under Acid Condition 国際会議

    P. Q. Phan, S. W. Chae, K. S. Kim, Y. Muta, M. Tipplook, N. Saito

    Asian-European International Conference on Plasma Surface Engineering 2019 (AEPSE 2019)  2019年9月3日 

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    開催年月日: 2019年9月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Jeju  

  54. Synthesis of Core-Shell Copper Particle Protected by Nitrogen Doped Graphene as an Oxygen Reduction Reaction Catalyst by Solution Plasma 国際会議

    P. Q. Phan, S. W. Chae, S. Kim, Y. Muta, K. S. Kim, M. Tipplook, M.A. Bratescu, N. Saito

    The International Conference on Advanced and Applied Petroleum, Petrochemicals, and Polymers (ICAPPP 2018)  2018年12月19日 

     詳細を見る

    開催年月日: 2018年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  55. Synthesis of Cationic Nitrogen-Doped Carbon Wrapping Carbon Nanotubes with High Electrical Conductivity 国際会議

    S. W. Chae, M. A. Bratescu, N. Saito

    The International Conference on Advanced and Applied Petroleum, Petrochemicals, and Polymers (ICAPPP 2018)  2018年12月18日 

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    開催年月日: 2018年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Thailand, Bangkok  

  56. Synthesis and Properties of Cationic Nitrogen-Doped Carbon Wrapped SWCNTs 国際会議

    N. Saito, S. W. Chae, K. S. Kim, Y. Muta, M. A. Bratescu

    The Final Seminar on JSPS Core-to-Core Program (B. Asia-Africa Science Platforms) Establishment of Research Hub for Compact Mobility Model in the ASEAN Region  2018年12月13日 

     詳細を見る

    開催年月日: 2018年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Japan, Nagoya  

  57. Solution Plasma Synthesis of Core-Shell Copper Particle Protected by Nitrogen Doped Multilayer Graphene as an Oxygen Reduction Reaction Catalyst 国際会議

    P. Q. Phan, S. W. Chae, S. Kim, Y. Muta, K. S. Kim, M. Tipplook, M.A. Bratescu, N. Saito

    The Final Seminar on JSPS Core-to-Core Program (B. Asia-Africa Science Platforms) Establishment of Research Hub for Compact Mobility Model in the ASEAN Region  2018年12月12日 

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    開催年月日: 2018年12月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Laos, Vientiane  

  58. Solution Plasma Catalyst and the CH activation 国際会議

    N. Saito, S. W. Chae, K. S. Kim, Y. Muta, M. Tipplook

    The 6th International Workshop and the 5th International Mini Workshop on Solution Plasma and Molecular Technology (SPM-6 & Mini SPM-5)  2018年6月 

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    開催年月日: 2018年6月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

  59. Solution Plasma and Hetero-graphene 国際会議

    N. Saito, S. W. Chae, K. S. Kim, Y. Muta, M. Tipplook

    Symposium on Biomimetic Materials Processing (BMMP 2018)  2018年1月 

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    開催年月日: 2018年1月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

  60. Few-Layers Graphene Sheets Synthesis from Graphite by Solution Plasma 国際会議

    S. W. Chae, M. A. Bratescu, N. Saito

    2017 workshop on Biomimetic Materials and Energy-Saving Materials  2017年11月25日 

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    開催年月日: 2017年11月

    記述言語:英語   会議種別:ポスター発表  

    開催地:China, Shanghai  

  61. The Nano-Structure and Their Properties of Exfoliation Several Layers-Stacked Graphene Prepared by Solution Plasma in Graphite Dispersed in Aqueous Solutions 国際会議

    S. W. Chae, M. A. Bratescu, N. Saito

    The 4th International Symposium on Hybrid Materials and Processing (HyMaP 2017)  2017年11月6日 

     詳細を見る

    開催年月日: 2017年11月

    記述言語:英語   会議種別:ポスター発表  

    開催地:Korea, Busan  

  62. Peeled and CN-Graphene from Graphite by Ionic Liquid via Solution Plasma 国際会議

    S. W. Chae, M. A. Bratescu, N. Saito

    The 5th International Workshop & The 4th International Mini Workshop on Solution Plasma and Molecular Technology (SPM-5 & Mini SPM-4)  2017年6月27日 

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    開催年月日: 2017年6月

    開催地:Germany, Greifswald  

▼全件表示

科研費 1

  1. 低白金・非白金触媒を用いた空気電池の電極

    研究課題/研究課題番号:23K13565  2023年4月 - 2025年3月

    科学研究費助成事業  若手研究

    蔡 尚佑

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    担当区分:研究代表者 

    配分額:4680000円 ( 直接経費:3600000円 、 間接経費:1080000円 )

    リチウム空気電池を高性能化するには優れた酸素還元反(ORR)触媒材料の開発が必要不可欠である。既存の金属空気電池では、ORR活性は白金が最も優れていますが、耐久性に乏しく、価格が高いという欠点を有する。この課題を解決するため、ソリューションプラズマ(SP)を用いることで、従来の原子状窒素のドープではなくカチオニック窒素ドープグラフェン(CNDG)の合成を世界で始めて実現する。本研究では、申請者が開発したCNDGを、優れた触媒能を有する遷移金属系バイメタルコア粒子に被覆するためのSP技術を開発し、優れたORR活性と高い化学的安定性を兼ね備えたコアシェル構造の触媒材料を創出することを目的とする。

産業財産権 1

  1. カーボン材料

    齋藤 永宏, ブラテスク マリア, アントワネッタ, 蔡 尚佑, 橋見 一生, 虎澤 研示, 橋本 剛, 八名 拓実

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    出願人:株式会社名城ナノカーボン, 国立大学法人名古屋大学

    出願番号:特願2018-085585  出願日:2018年4月

    公開番号:特開2019-189495  公開日:2019年10月

    J-GLOBAL