Faculty Profiles - MATSUDA Ryotaro

Papers - MATSUDA Ryotaro

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Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion Open Access

Watanabe, K; Toya, T; Toyota, Y; Kobayashi, Y; Usuba, J; Hijikata, Y; Matsuda, R; Nishimura, K; Sugiyama, H; Segawa, Y

CHEMICAL COMMUNICATIONS Vol. 61 ( 13 ) page： 2822 - 2825 2025.2

Adsorptive-dissolution of O2 into the potential nanospace of a densely fluorinated metal-organic framework Open Access

Kusaka, S; Itoh, Y; Hori, A; Usuba, J; Pirillo, J; Hijikata, Y; Ma, YS; Matsuda, R

NATURE COMMUNICATIONS Vol. 15 ( 1 ) 2024.11

An n-type semiconducting diazaporphyrin-based hydrogen-bonded organic framework Open Access

Sakurai, T; Tanabe, T; Iguchi, H; Li, ZW; Matsuda, W; Tsutsui, Y; Seki, S; Matsuda, R; Shinokubo, H

CHEMICAL SCIENCE Vol. 15 ( 32 ) page： 12922 - 12927 2024.8

A magnesium phosphonate metal-organic framework showing excellent performance for lead(<sc>ii</sc>) sensing and removal from aqueous solutions

Zhou, QK; Chen, M; An, YB; Tang, XY; Matsuda, R; Ma, YS

DALTON TRANSACTIONS Vol. 53 ( 25 ) page： 10416 - 10420 2024.6

Engineering Interface Defects and Interdiffusion at the Degenerate Conductive In2O3/Al2O3 Interface for Stable Electrodes in a Saline Solution

Zhu, ZT; Yasui, T; Zhao, XX; Liu, QL; Morita, S; Li, Y; Yonezu, A; Nagashima, K; Takahashi, T; Osada, M; Matsuda, R; Yanagida, T; Baba, Y

ACS APPLIED MATERIALS & INTERFACES Vol. 15 ( 30 ) page： 36866 - 36876 2023.7

Beyond the Conventional Limitation of Photocycloaddition Reaction in the Roomy Nanospace of a Metal-Organic Framework

Misaki Nakagawa, Shinpei Kusaka, Atsushi Kiyose, Toshinobu Nakajo, Hiroaki Iguchi, Motohiro Mizuno, Ryotaro Matsuda

Journal of the American Chemical Society Vol. 145 ( 22 ) page： 12059 - 12065 2023.5

Language：English Publishing type：Research paper (scientific journal)

Topochemical reactions provide selective products based on the molecular position; however, they generally require molecules to be placed in strictly limited orientations and distances, making them less versatile. In this study, we found that by confining trans-4-styrylpyridine (4-spy) as a reactive substrate in a flexible metal-organic framework (MOF) nanospace, [2+2] cycloadducts can be selectively obtained, even when the distance between two C═C bonds of 4-spy in the crystal is 5.9 Å, which is much larger than the conventionally observed upper limit (4.2 Å). Such an unusual cyclization reaction is suggested to occur due to the transient proximity of the 4-spy due to the “swing” motion in the nanospace. The MOF nanospace, with its high degree of molecular structural freedom, can be applied to different platforms that do not require the fine constraints of reactive distances for solid-phase reactions.

DOI： 10.1021/jacs.3c01225

Web of Science

Scopus

PubMed

Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities

Kang, CJ; Zhang, ZQ; Kusaka, S; Negita, K; Usadi, AK; Calabro, DC; Baugh, LS; Wang, YX; Zou, XD; Huang, ZH; Matsuda, R; Zhao, D

NATURE MATERIALS Vol. 22 ( 5 ) page： 636 - + 2023.5

Temperature Effect on Water Adsorption and Desorption Processes in the Mesoporous Metal-Organic Framework MIL-101(Cr) Reviewed

Fei Shubo, Gao Jiao, Matsuda Ryotaro, Endo Akira, Hsu Wei-Lun, Delaunay Jean-Jacques, Daiguji Hirofumi

JOURNAL OF PHYSICAL CHEMISTRY C 2022.9

Delicate and Fast Photochemical Surface Modification of 2D Photoresponsive Organosilicon Metal-Organic Frameworks Reviewed International coauthorship

Yuan Baoling, Gou Gaozhang, Fan Tao, Liu Mingxian, Ma Yunsheng, Matsuda Ryotaro, Li Liangchun

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION Vol. 61 ( 28 ) 2022.7

Heterobilayer membranes from isostructural metal-organic frameworks for efficient CO2 separation

Wang Xiaoguang, Kusaka Shinpei, Hori Akihiro, Sen Susan, Matsuda Ryotaro

MICROPOROUS AND MESOPOROUS MATERIALS Vol. 338 2022.6

Topochemical [2+2] Cycloaddition in a Two-Dimensional Metal-Organic Framework via SCSC Transformation Impacts Halogen center dot center dot center dot Halogen Interactions

Khan Samim, Frontera Antonio, Matsuda Ryotaro, Kitagawa Susumu, Mir Mohammad Hedayetullah

INORGANIC CHEMISTRY Vol. 61 ( 7 ) page： 3029 - 3032 2022.2

Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility

Ma Yunsheng, Tang Xiaoyan, Chen Ming, Mishima Akio, Li Liangchun, Hori Akihiro, Wu Xiaoyu, Ding Lifeng, Kusaka Shinpei, Matsuda Ryotaro

CHEMICAL COMMUNICATIONS Vol. 58 ( 8 ) page： 1139 - 1142 2022.1

Selective Photochemical Reaction by Fixing Reactant as a MOF Building Block

Ono Katsuya, Kusaka Shinpei, Matsuda Ryotaro

CHEMISTRY LETTERS Vol. 50 ( 12 ) page： 1987 - 1989 2021.12

Synthetic Strategy for Incorporating Carboxylate Ligands into Coordination Polymers under a Solvent-Free Reaction

Hinokimoto Akira, Izu Hitoshi, Wei Yong-Sheng, Nakajo Toshinobu, Matsuda Ryotaro, Horike Satoshi

CRYSTAL GROWTH & DESIGN Vol. 21 ( 11 ) page： 6031 - 6036 2021.11

Stabilization of radical active species in a MOF nanospace to exploit unique reaction pathways

Harada Yuki, Kusaka Shinpei, Nakajo Toshinobu, Kumagai Jun, Kim Cho Rong, Shim Joo Young, Hori Akihiro, Ma Yunsheng, Matsuda Ryotaro

CHEMICAL COMMUNICATIONS 2021.10

Water Confined in MIL-101(Cr): Unique Sorption-Desorption Behaviors Revealed by Diffuse Reflectance Infrared Spectroscopy and Molecular Dynamics Simulation

Gao Jiao, Fei Shubo, Ho Ya-Lun, Matsuda Ryotaro, Daiguji Hirofumi, Delaunay Jean-Jacques

JOURNAL OF PHYSICAL CHEMISTRY C Vol. 125 ( 32 ) page： 17786 - 17795 2021.8

Fabrication of a Kagome-type MOF Membrane by Seeded Growth on Amino-functionalized Porous Al2O3 Substrate

Wang Xiaoguang, Kusaka Shinpei, Hori Akihiro, Matsuda Ryotaro

CHEMISTRY-AN ASIAN JOURNAL Vol. 16 ( 15 ) page： 2018 - 2021 2021.8

Triplet Carbene with Highly Enhanced Thermal Stability in the Nanospace of a Metal-Organic Framework

Nakajo Toshinobu, Kumagai Jun, Kusaka Shinpei, Hori Akihiro, Hijikata Yuh, Pirillo Jenny, Ma Yunsheng, Matsuda Ryotaro

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Vol. 143 ( 21 ) page： 8129 - 8136 2021.6

Enhanced CO2 Adsorption by Insertion Reaction in the Nanospace of a Porphyrin-based MOF

Morita Masashi, Kusaka Shinpei, Yonezu Akira, Ohara Yuki, Sakamoto Hirotoshi, Matsuda Ryotaro

CHEMISTRY LETTERS Vol. 50 ( 4 ) page： 640 - 643 2021.4

Diruthenium(II,II) Complex Assemblies Showing Electrical Conduction via π-Stacked 2-Pyrenecarboxylate Moiety

Ren Takaki, Hiroaki Iguchi, Liyuan Qu, Jenny Pirillo, Shinpei Kusaka, Yuh Hijikata, Hisaaki Tanaka, Wakana Matsuda, Shu Seki, Ryotaro Matsuda

CHEMISTRY-AN ASIAN JOURNAL 2025.2

Language：English Publishing type：Research paper (scientific journal) Publisher：WILEY-V C H VERLAG GMBH

Through-space electrical conduction in paddlewheel-type homovalent dinuclear complexes remains poorly understood, despite the numerous reports on these complexes. Herein, the electrical conduction of new Ru2(II,II) complexes with 2-pyrenecarboxylate (pyrCOO-) ligands, [Ru2(pyrCOO)4X2] & sdot; n(X) (where X=DMF (Ru-DMF), NMP (Ru-NMP), DMA (Ru-DMA)), was investigated. The dimensionality of pi-stacking interactions between discrete molecules in Ru-DMA is higher (two-dimensional) than in Ru-DMF and Ru-NMP (stair-like one-dimensional). Nevertheless, Ru-DMF, which contains a slight amount of organic radicals, exhibited the highest electrical conductivity. This suggests that the large overlap and high dimensionality of pi-stacking interactions among the complexes, along with a slight organic radical impurity, contribute to the increased electrical conductivity.

DOI： 10.1002/asia.202401599

Web of Science

PubMed

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Papers - MATSUDA Ryotaro