研究者詳細 - 山本　徹也

論文 - 山本　徹也

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Effect of Initiator Charge on Dispersion Stability of Polymer Particles Formed by Soap-free Emulsion Polymerization of 4-Vinylaniline or 4-Vinylpyridine 査読有り

Yamamoto Tetsuya, Furuta Ryo, Kawai Yusuke

CHEMISTRY LETTERS 48 巻 ( 3 ) 頁： 208 - 210 2019年3月

Synthesis of Polystyrene@Silica Particles through Soap-Free Emulsion Polymerization and Sol-Gel Reaction on Polymer Surfaces 査読有り

T. Yamamoto, and Y. Takahashi

Advanced Powder Technology 30 巻 ( 1 ) 頁： 214 - 218 2019年1月

界面特性を強化した熱可塑性炭素繊維強化プラスチックの作製

山本徹也

東燃ゼネラル石油研究奨励財団研究報告書 20 巻頁： in press 2018年12月

Antimicrobial activities of low molecular weight polymers synthesized through soap-free emulsion polymerization 査読有り

Yamamoto, Tetsuya, Arakawa, Kenji, Takahashi, Yuya, Sumiyoshi, Miho

European Polymer Journal 109 巻頁： 532-536 2018年12月

Antimicrobial activities of polymers synthesized through soap-free emulsion polymerization using a cationic initiator and styrene derivative monomers 査読有り

Yamamoto, Tetsuya; Arakawa, Kenji; Furuta, Ryo; Teshima, Aiko

Chemistry Letters 47 巻 ( 11 ) 頁： 1402-1404 2018年11月

Dispersion of carbon nanofibers modified with polymer colloids to enhance mechanical properties of PVA nanocomposite film 査読有り

Toyoda Naoya, Yamamoto Tetsuya

Colloids and Surfaces a-Physicochemical and Engineering Aspects 556 巻頁： 248 - 252 2018年11月

Design of polymer particles maintaining dispersion stability for the synthesis of hollow silica particles through sol-gel reaction on polymer surfaces 査読有り

Tetsuya Yamamoto, Yuya Takahashi

Colloids and Surfaces A: Physicochemical and Engineering Aspects 553 巻頁： 66 - 70 2018年9月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Elsevier B.V.

To synthesize polystyrene-silica core-shell particles and silica hollow particles, soap-free emulsion polymerization was carried out using styrene and N-vinylacetamide (NVA), and the Stöber method using tetraethyl orthosilicate (TEOS) was performed on the polymer particle surfaces. Here, NVA acts as a stabilizer for the polymer colloids, maintaining dispersion stability by synthesizing hydration layers even when the electrostatic adsorption of TEOS had occurred, and as a catalyst for the sol-gel reaction. NVA was polymerized by the cationic initiator located on the surface of the polystyrene particles to maintain dispersion stability by a steric effect. Therefore, the sol-gel reactions proceeded more efficiently on the surface of polymer particles, facilitated by the much larger surface area. Finally, the polymer core was removed by heating to prepare highly monodisperse silica hollow particles.

DOI： 10.1016/j.colsurfa.2018.05.036

Web of Science

Scopus

微粒子を利用した疎水性粉体の水への分散技術の開発

山本徹也

ホソカワ粉体工学振興財団年報 25 巻頁： 113-118 2018年5月

Effect of the surface properties of particle on the classification performance of a dry-cyclone 査読有り

Tetsuya Yamamoto, Motoharu Higashino

Particulate Science and Technology 36 巻 ( 1 ) 頁： 46 - 49 2018年1月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Taylor and Francis Inc.

The purpose of the present study was to investigate the effect of the surface properties of silica particles on the classification performance of a dry-cyclone. As a result, it was clear that the separation force between the surface of particle and the silicon was decreased by the AFM measurement when the surface of the silica particles could be modified with ethanol or acetone treatment. Fine particles in the original silica particles with the treatments were easily collected by the filter in a dry-cyclone system
hence, the particle classification performance was enhanced.

DOI： 10.1080/02726351.2016.1205691

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

Enhancement of mechanical properties of carbon fiber reinforced thermoplastic using colloidal techniques 査読有り

Tetsuya Yamamoto, Katsumasa Uematsu, Syo Yabushita

Procedia Manufacturing 15 巻頁： 1738 - 1745 2018年

炭素繊維強化熱可塑性樹脂の高性能化を実現する界面制御技術の開発

山本徹也

新東技報 35 巻頁： 70-72 2017年12月

Enhancement of surface adhesion between thermoplastic resin and carbon fiber using polymer colloids 査読有り

Tetsuya Yamamoto, Katsumasa Uematsu, Toshihira Irisawa, Yasuhiro Tanabe

The Journal of Adhesion 93 巻 ( 12 ) 頁： 943 - 948 2017年10月

Improved mechanical properties of PMMA composites: Dispersion, diffusion and surface adhesion of recycled carbon fiber fillers from CFRP with adsorbed particulate PMMA 査読有り

Tetsuya Yamamoto, Yuta Makino, Katsumasa Uematsu

Advanced Powder Technology 28 巻 ( 10 ) 頁： 2774 - 2778 2017年10月

In-situ Adsorption of Polymer Particles on Multi-wall Carbon Nanotubes Using Colloidal Techniques 査読有り

Tetsuya Yamamoto, Naoya Toyoda

Colloids and Interface Science Communications 20 巻頁： 1 - 4 2017年9月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Elsevier B.V.

A novel technique for the adsorption of polymer particles on carbon nanotubes was developed. First, the surfaces of multi-wall carbon nanotubes (MWCNTs) were coated with poly(N-vinyl acetamide) (PNVA) to confer them hydrophilicity together with good dispersion stability in water owing to a steric effect between the hydration layers. Second, the hydrophilic MWCNTs were covered with polymethyl methacrylate (PMMA) particles bearing positive charges—synthesized using V-50—through electrostatic interactions. These polymers were obtained by soap-free emulsion polymerization. The in-situ adsorption of PMMA particles on surface MWCNTs were attributed to the hydration layers of the modified MWCNTs, and electrostatic interactions between PMMA particles and the modified MWCNTs. It can be expected that the PMMA particles adsorbed on the carbon nanotubes hold the potential to serve as glue between carbon nanotube and PMMA in the composite.

DOI： 10.1016/j.colcom.2017.07.003

Web of Science

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

Synthesis and Electrical Properties of Composite Films Comprising Polymer Particles and Carbon Nanotubes 査読有り

Tetsuya Yamamoto, Kan Kawaguchi

Colloids and Interface Science Communications 20 巻頁： 5 - 8 2017年9月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Elsevier B.V.

In the present study, composite films were synthesized from composite polymer particles prepared with multi-wall carbon nanotubes (MWCNTs) by in situ polymerization. Because one of the advantages of MWCNTs compared to other preparation methods is high electrical conductivity, the electrical properties of the composite films were evaluated by the direct current two-terminal method. As a result, the composite film prepared by MWCNTs had conductive paths and showed higher conductivity even at lower mass fraction of MWCNTs compared with the previous works to keep transparency. This method was shown to decrease the mass fractions of MWCNTs and increase the transparency of the composite films.

DOI： 10.1016/j.colcom.2017.08.001

Web of Science

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

Synthesis of composite polymer particles with carbon nanotubes and evaluation of their mechanical properties 査読有り

Tetsuya Yamamoto, Kan Kawaguchi

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 529 巻頁： 765 - 770 2017年9月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：ELSEVIER SCIENCE BV

In the present study, a method for synthesizing composite polymer particles with multi-wall carbon nanotubes (MWCNTs) was developed, and the particles' mechanical properties were evaluated. First, the surfaces of MWCNTs were modified by acids to increase their hydrophilicity, resulting in surface-active MWCNTs. Then, a Pickering emulsion was formed using liquid benzyl methacrylate monomer and the surface-active MWCNTs. The surface charge of the surface-active MWCNTs greatly influenced the surface coverage and size of the composite particles. Furthermore, when untreated MWCNTs were added to the monomer phase, surface coverage of the resulting particles was enhanced because MWCNTs on the surface of the particles interacted with MWCNTs incorporated inside the particles, thus preventing the surface-active MWCNTs on the surface from being released into the bulk. As a result, the mechanical properties of the composite polymer particles were successfully improved because the incorporated MWCNTs worked well as fillers.

DOI： 10.1016/j.colsurfa.2017.05.075

Web of Science

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

Anomalous particle through soap-free emulsion polymerization of styrene using oil-soluble initiator 査読有り

Tetsuya Yamamoto, SeulChan Kim

JOURNAL OF POLYMER RESEARCH 24 巻 ( 9 ) 頁： 149 2017年8月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：SPRINGER

One of oil-soluble initiators, VF-096, might work as cross-linker. This initiator would enable to synthesize the particle with cross-linking, which was involved with the particle morphology. Soap-free emulsion polymerization of styrene using this initiator was carried out to develop the method to control the particle morphology in one batch system. As a result, it was found that anomalous particle was generated without stirring and the particle morphology changed to be spherical by increasing shear stress through the stirring. One of the origins of the anomalous particle was the phase separation of the water in the particle and release of it from inside of the particle to the bulk.

DOI： 10.1007/s10965-017-1316-2

Web of Science

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

Controlling the particle cut size of a dry cyclone using acetone 査読有り

Tetsuya Yamamoto, Motoharu Higashino

Particulate Science and Technology 35 巻 ( 2 ) 頁： 214 - 218 2017年3月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Taylor and Francis Inc.

In this study, we investigated the interaction between particles and the wall in the presence of mist to improve the particle classification performance of a dry cyclone. The interaction between a silica particle and a mica surface in the presence of a flowing acetone mist was measured by performing atomic force microscopy (AFM), which showed that an attractive force was generated and became stronger as time passed while acetone mist was supplied to the system, probably because of static electricity. In a dry cyclone system, this attractive force could enhance the classification performance. In particular, when acetone mist was supplied into the cyclone from the upper part of the dust box at higher flow rates, the classification performance was enhanced. Because acetone is highly volatile and has a low viscosity, the classification performance was improved by the evaporated acetone even when a cyclone with a dust box filled with acetone was used instead of a nozzle supplying the mist. In this case, the ratio of the mass of the particles collected by the upper part of the cyclone to the total mass of the feed powder was increased, probably because of the attractive force between the silica particles and the wall of the cyclone. Moreover, the cut size of the dry cyclone could be controlled by changing the amount of acetone in the dust box of the cyclone.

DOI： 10.1080/02726351.2016.1150370

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

CFRTPの高性能化を実現するコロイド技術招待有り

山本徹也

化学装置 59 巻 ( 3 ) 頁： 45 - 48 2017年3月

Synthesis of hydrocolloid through polymerization of styrene and N-vinyl acetamide by AIBN 査読有り

Tetsuya Yamamoto, Yuya Takahashi

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 516 巻頁： 80 - 84 2017年3月

担当区分：筆頭著者,　責任著者記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：ELSEVIER SCIENCE BV

The soap-free emulsion polymerization of styrene with hydrophilic monomer, N-vinyl acetamide (NVA), using oil-soluble initiator was carried out to synthesize polymeric particles with good dispersion stability and improve the polymer yield. As a result, it was found that the polymer yield and dispersion stability were enhanced by the promotion of polymerization by the dissolved monomers and hydrogen bonding between NVA on the particle surface and water molecules in the bulk. Accordingly, this polymer colloid showed the nature of hydrocolloid by their hydration layers because its dispersion stability was kept even when the electrolytes were added to the system. In the conventional soap-free emulsion polymerization, the counter ions including the water-soluble initiators were remained in the water phase. However, because all of chemical components in the present study were consumed for the polymerization, the impurities except polymers were hardly remained in the bulk. (C) 2016 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.colsurfa.2016.12.023

Web of Science

Scopus

その他リンク： http://orcid.org/0000-0001-8179-900X

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