Updated on 2023/09/21

写真a

 
TADA Mizuki
 
Organization
Research Center for Materials Science Professor
Graduate School
Graduate School of Science
Undergraduate School
School of Science Department of Chemistry
Title
Professor

Degree 1

  1. 博士(理学) ( 2005.11   東京大学 ) 

Research Interests 4

  1. operando imaging

  2. metal complex

  3. Heterogeneous catalyst

  4. 反応インフォグラフィ

Research Areas 2

  1. Nanotechnology/Materials / Fundamental physical chemistry

  2. Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Catalyst and resource chemical process

Research History 14

  1. Professor Research Center for Materials, Nagoya University

    2013.4

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    Country:Japan

  2. Professor Department of Chemistry, Graduate School of Science, Nagoya University

    2013.4

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    Country:Japan

  3. 理化学研究所客員研究員(兼職)

    2013.4 - 2014.3

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    Country:Japan

  4. 分子科学研究所物質分子科学研究領域教授(併任)

    2013.4 - 2014.3

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    Country:Japan

  5. 名古屋大学大学院理学研究科客員准教授(兼職)

    2012.4 - 2013.3

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    Country:Japan

  6. 分子科学研究所分子スケールナノサイエンスセンター准教授

    2009.4 - 2013.3

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    Country:Japan

  7. 京都大学大学院工学研究科非常勤講師(兼業)

    2009.4 - 2009.9

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    Country:Japan

  8. Associate Professor of Institute for Molecular Science

    2008.10 - 2013.3

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    Country:Japan

  9. Associate Professor of School of Physical Science,The Graduate Univ. for Advanced Studies(SOKENDAI)

    2008.10 - 2013.3

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    Country:Japan

  10. Visiting Researcher of JASRI SPring-8

    2008.4 - 2013.3

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    Country:Japan

  11. Associate Professor of Chemistry, The University of Tokyo

    2008.1 - 2008.9

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    Country:Japan

  12. 東京大学大学院理学系研究科化学専攻助教

    2007.4 - 2008.1

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    Country:Japan

  13. Assistant Professor of Chemistry, The University of Tokyo

    2004.9 - 2007.3

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    Country:Japan

  14. JSPS Fellowship

    2003.4 - 2004.8

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    Country:Japan

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Education 2

  1. The University of Tokyo

    - 2004.8

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    Country: Japan

  2. The University of Tokyo   Faculty of Science

    - 2001.3

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    Country: Japan

Awards 10

  1. 文部科学大臣表彰若手科学者賞

    2010.4   文部科学省  

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    Country:Japan

  2. 守田科学研究奨励賞

    2009.6   大学女性協会  

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    Country:Japan

  3. 井上リサーチアウォード

    2009.2   井上科学振興財団  

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    Country:Japan

  4. 奨励賞

    2009.1   日本放射光学会  

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    Country:Japan

  5. 東海化学工業会賞技術賞

    2008.5   東海化学工業会  

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    Country:Japan

  6. 進歩賞

    2008.3   日本化学会  

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    Country:Japan

  7. 東京大学グローバルCOE若手海外レクチャーシップ

    2007.11   東京大学  

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    Country:Japan

  8. 優秀講演賞

    2007.4   日本化学会  

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    Country:Japan

  9. PCCP Prize

    2007.3   Royal Society of Chemistry  

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    Country:United Kingdom

  10. 井上研究奨励賞

    2007.2   井上科学振興財団  

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    Country:Japan

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Papers 80

  1. Coordination-Induced Trigger for Activity: N-Heterocyclic Carbene- Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control International coauthorship

    Ikemoto Satoru, Koitaya Takanori, Tsuji Yuta, Das Mowpriya, Yoshizawa Kazunari, Glorius Frank, Muratsugu Satoshi, Tada Mizuki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY     2022.12

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    Authorship:Last author, Corresponding author  

    DOI: 10.1021/jacs.2c07290

    Web of Science

  2. Nitrogen Reduction by the Fe Sites of Synthetic [Mo3S4Fe] Cubes

    Ohki Yasuhiro, Munakata Kenichiro, Matsuoka Yuto, Hara Ryota, Kachi Mami, Uchida Keisuke, Tada Mizuki, Cramer Roger E., Sameera W. M. C., Takayama Tsutomu, Sakai Yoichi, Kuriyama Shogo, Nishibayashi Yoshiaki, Tanifuji Kazuki

    NATURE   Vol. 607 ( 7917 ) page: 86 - +   2022.7

  3. Pt-Co/C Cathode Catalyst Degradation in a Polymer Electrolyte Fuel Cell Investigated by an Infographic Approach Combining Three-Dimensional Spectroimaging and Unsupervised Learning Reviewed International journal

    Tan Yuanyuan, Matsui Hirosuke, Ishiguro Nozomu, Uruga Tomoya, Duong-Nguyen Nguyen, Sekizawa Oki, Sakata Tomohiro, Maejima Naoyuki, Higashi Kotaro, Dam Hieu Chi, Tada Mizuki

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 123 ( 31 ) page: 18844 - 18853   2019.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.9b05005

  4. Oxygen-diffusion-driven oxidation behavior and tracking areas visualized by X-ray spectro-ptychography with unsupervised learning Reviewed International journal

    Hirose Makoto, Ishiguro Nozomu, Shimomura Kei, Duong-Nguyen Nguyen, Matsui Hirosuke, Dam Hieu Chi, Tada Mizuki, Takahashi Yukio

    COMMUNICATIONS CHEMISTRY   Vol. 2   page: 50   2019.4

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s42004-019-0147-y

  5. N-2 activation on a molybdenum-titanium-sulfur cluster Reviewed International coauthorship International journal

    Ohki Yasuhiro, Uchida Keisuke, Tada Mizuki, Cramer Roger E., Ogura Takashi, Ohta Takehiro

    NATURE COMMUNICATIONS   Vol. 9   page: 3200   2018.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/s41467-018-05630-6

  6. Visualization of Heterogeneous Oxygen Storage Behavior in Platinum-Supported Cerium-Zirconium Oxide Three-Way Catalyst Particles by Hard X-ray Spectro-Ptychography Reviewed International journal

    Hirose Makoto, Ishiguro Nozomu, Shimomura Kei, Burdet Nicolas, Matsui Hirosuke, Tada Mizuki, Takahashi Yukio

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 57 ( 6 ) page: 1474 - 1479   2018.2

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201710798

  7. Operando 3D Visualization of Migration and Degradation of a Platinum Cathode Catalyst in a Polymer Electrolyte Fuel Cell Reviewed International journal

    Matsui Hirosuke, Ishiguro Nozomu, Uruga Tomoya, Sekizawa Oki, Higashi Kotaro, Maejima Naoyuki, Tada Mizuki

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 56 ( 32 ) page: 9371 - 9375   2017.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201703940

  8. Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes Reviewed International coauthorship International journal

    Ernst Johannes B., Schwermann Christian, Yokota Gen-Ichi, Tada Mizuki, Muratsugu Satoshi, Doltsinis Nikos L., Glorius Frank

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 139 ( 27 ) page: 9144 - 9147   2017.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.7b05112

  9. Imaging of Oxygen Diffusion in Individual Platinum/Ce2Zr2Ox Catalyst Particles During Oxygen Storage and Releas Reviewed International journal

    H. Matsui*, N. Ishiguro, K. Enomoto, O. Sekizawa, T. Uruga, M. Tada*

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 55   page: 12022 - 12025   2016.8

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

  10. Tunable Heterogeneous Catalysis: N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts to Tune Reactivity and Selectivity Reviewed International journal

    J. B. Ernst, S. Muratsugu, F. Wang, M. Tada, F. Glorius

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 138   page: 10718 - 10721   2016.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1149/07801.1327ecst

  11. 4D Visualization of a Cathode Catalyst Layer in a Polymer Electrolyte Fuel Cell by 3D-Laminography-XAFS Reviewed International journal

    T. Saida, O. Sekizawa, N. Ishiguro, K. Uesugi, M. Hoshina, T. Uruga, S. Ohkoshi, T. Yokoyama, and M. Tada*

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51   page: 10311 - 10314   2012.9

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  12. 5D Analysis of Capacity Degradation in Battery Electrodes Enabled by Operando CT-XANES Reviewed

    Y. Kimura, S. Huang, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, and K. Amezawa

    Small Methods     2023.7

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/smtd.202300310

  13. Oxidation and Phase Transfer of Individual Cr-Doped Dendric FeOx Particles Visualized by Full-field Nano-XAFS Spectroimaging Reviewed

    N. Ishiguro, H. Matsui, K. Wakamatsu, Y. Suzuki, O. Sekizawa, K. Nitta, Y. Terada, T. Uruga, and M. Tada

    Phys. Chem. Chem. Phys.   Vol. 25   page: 17197 - 17206   2023.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D3CP00907F

  14. Spatial Imaging of Catalyst Poisoning with SO2 on Pt/C PEFC Electrocatalyst by Operando Pt LIII-edge XAFS-CT Imaging Reviewed

      Vol. 13   page: 4360 - 4366   2023.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D3CY00241A

  15. CO Binding onto Heterometals of [Mo3S4M] (M = Fe, Co, Ni) Cubes Reviewed International coauthorship

    K. Tanifuji, Y. Sakai, Y. Matsuoka, M. Tada, W. M. C. Sameera, and Y. Ohki

    Bull. Chem. Soc. Jpn.   Vol. 95   page: 1190 - 1195   2022.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/bcsj.20220143

  16. Variation of Local Structure and Reactivity of Pt/C Catalyst for Accelerated Degradation Test of Polymer Electrolyte Fuel Cell Visualized by Operando 3D CT-XAFS Imaging Invited Reviewed International journal

    Matsui Hirosuke, Ishiguro Nozomu, Tan Yuanyuan, Maejima Naoyuki, Muramoto Yuta, Uruga Tomoya, Higashi Kotaro, Nguyen Duong-Nguyen, Dam Hieu-Chi, Samjeske Gabor, Tada Mizuki

    CHEMNANOMAT   Vol. 8 ( 4 )   2022.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cnma.202200008

    Web of Science

  17. Operando Imaging of Ce Radical Scavengers in a Practical Polymer Electrolyte Fuel Cell by 3D Fluorescence CT-XAFS and Depth-Profiling Nano-XAFS-SEM/EDS Techniques Reviewed International journal

    Matsui Hirosuke, Takao Shinobu, Higashi Kotaro, Kaneko Takuma, Samjeske Gabor, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro

    ACS APPLIED MATERIALS & INTERFACES   Vol. 14 ( 5 ) page: 6762 - 6776   2022.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.1c22336

    Web of Science

  18. Chromium Oxides as Structural Modulators of Rhodium Dispersion on Ceria to Generate Active Sites for NO Reduction Reviewed International journal

    Ikemoto Satoru, Muratsugu Satoshi, Koitaya Takanori, Tada Mizuki

    ACS CATALYSIS   Vol. 12 ( 1 ) page: 431 - 441   2022.1

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    DOI: 10.1021/acscatal.1c03807

  19. Ultrafine Pt-Ni nanoparticles in hollow porous carbon spheres for remarkable oxygen reduction reaction catalysis Reviewed International journal

    Wan Xian-Kai, Samjeske Gabor, Matsui Hirosuke, Chen Chaoqi, Muratsugu Satoshi, Tada Mizuki

    DALTON TRANSACTIONS   Vol. 50 ( 20 ) page: 6811 - 6822   2021.5

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    DOI: 10.1039/d1dt00647a

  20. Sulfur Poisoning of Pt and PtCo Anode and Cathode Catalysts in Polymer Electrolyte Fuel Cells Studied by Operando Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy Reviewed International coauthorship International journal

    Chaveanghong Suwilai, Nakamura Takahiro, Takagi Yasumasa, Cagnon Benjamin, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Yokoyama Toshihiko

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 23 ( 6 ) page: 3866 - 3873   2021.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0cp06020h

  21. Reversible structural transformation and redox properties of Cr-loaded iron oxide dendrites studied by in situ XANES spectroscopy Reviewed International journal

    Matsui Hirosuke, Ishiguro Nozomu, Suzuki Youya, Wakamatsu Kouhei, Yamada Chiharu, Sato Kanako, Maejima Naoyuki, Uruga Tomoya, Tada Mizuki

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 22 ( 48 ) page: 28093 - 28099   2020.12

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    DOI: 10.1039/d0cp04416d

  22. Oxygen Reduction Reaction Performance Tuning on Pt Nanoparticle/MWCNT Catalysts by Gd Species Reviewed International journal

    Ichihashi Kentaro, Muratsugu Satoshi, Matsui Hirosuke, Higashi Kotaro, Sekizawa Oki, Uruga Tomoya, Tada Mizuki

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 124 ( 49 ) page: 26925 - 26936   2020.12

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.0c09308

  23. Visualization and understanding of the degradation behaviors of a PEFC Pt/C cathode electrocatalyst using a multi-analysis system combining time-resolved quick XAFS, three-dimensional XAFS-CT, and same-view nano-XAFS/STEM-EDS techniques Reviewed International journal

    Higashi Kotaro, Takao Shinobu, Samjeske Gabor, Matsui Hirosuke, Tada Mizuki, Uruga Tomoya, Iwasawa Yasuhiro

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 22 ( 34 ) page: 18919 - 18931   2020.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0cp01356k

  24. Influence of Active Material Loading on Electrochemical Reactions in Composite Solid-State Battery Electrodes Revealed by Operando 3D CT-XANES Imaging Reviewed International journal

    Kimura Yuta, Fakkao Mahunnop, Nakamura Takashi, Okumura Toyoki, Ishiguro Nozomu, Sekizawa Oki, Nitta Kiyofumi, Uruga Tomoya, Tada Mizuki, Uchimoto Yoshiharu, Amezawa Koji

    ACS APPLIED ENERGY MATERIALS   Vol. 3 ( 8 ) page: 7782 - 7793   2020.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsaem.0c01186

  25. Quick Operando Ambient Pressure Hard X-ray Photoelectron Spectroscopy for Reaction Kinetic Measurements of Polymer Electrolyte Fuel Cells Reviewed International journal

    Nakamura Takahiro, Takagi Yasumasa, Chaveanghong Suwilai, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Yokoyama Toshihiko

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 124 ( 32 ) page: 17520 - 17527   2020.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.0c04871

  26. Synthesis of Dinuclear Mo-Fe Hydride Complexes and Catalytic Silylation of N-2 Reviewed International journal

    Ishihara Kodai, Araki Yuna, Tada Mizuki, Takayama Tsutomu, Sakai Yoichi, Sameera W. M. C., Ohki Yasuhiro

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 26 ( 43 ) page: 9537 - 9546   2020.8

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202000104

  27. A dinuclear Mo(2)H(8)complex supported by bulky C(5)H(2)(t)Bu(3)ligands Reviewed International coauthorship International journal

    Ohki Suhiro, Ishihara Kodai, Yaoi Moeko, Tada Mizuki, Sameera W. M. C., Cramer Roger E.

    CHEMICAL COMMUNICATIONS   Vol. 56 ( 58 ) page: 8035 - 8038   2020.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/d0cc03274c

  28. Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation Reviewed International coauthorship International journal

    Moock Daniel, Wiesenfeldt Mario P., Freitag Matthias, Muratsugu Satoshi, Ikemoto Satoru, Knitsch Robert, Schneidewind Jacob, Baumann Wolfgang, Schaefer Andreas H., Timmer Alexander, Tada Mizuki, Hansen Michael Ryan, Glorius Frank

    ACS CATALYSIS   Vol. 10 ( 11 ) page: 6309 - 6317   2020.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acscatal.0c01074

  29. 3D Operando Imaging and Quantification of Inhomogeneous Electrochemical Reactions in Composite Battery Electrodes Reviewed International journal

    Kimura Yuta, Tomura Aina, Fakkao Mahunnop, Nakamura Takashi, Ishiguro Nozomu, Sekizawa Oki, Nitta Kiyofumi, Uruga Tomoya, Okumura Toyoki, Tada Mizuki, Uchimoto Yoshiharu, Amezawa Koji

    JOURNAL OF PHYSICAL CHEMISTRY LETTERS   Vol. 11 ( 9 ) page: 3629 - 3636   2020.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpclett.0c00876

  30. Feed gas exchange (startup/shutdown) effects on Pt/C cathode electrocatalysis and surface Pt-oxide behavior in polymer electrolyte fuel cells as revealed using in situ real-time XAFS and high-resolution STEM measurements Reviewed International journal

    Samjeske Gabor, Kaneko Takuma, Gunji Takao, Higashi Kotaro, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 22 ( 17 ) page: 9424 - 9437   2020.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cp06895c

  31. Recent progress in molecularly imprinted approach for catalysis Invited Reviewed International journal

    Muratsugu Satoshi, Shirai Sora, Tada Mizuki

    TETRAHEDRON LETTERS   Vol. 61 ( 11-12 ) page: 151603   2020.3

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    DOI: 10.1016/j.tetlet.2020.151603

  32. Copper Complexes Bearing a Dianionic Diborane(4) Ligand: Synthesis and Evaluation of the Donor Property Reviewed International journal

    Akiyama Seiji, Ikemoto Satoru, Muratsugu Satoshi, Tada Mizuki, Yamashita Makoto

    ORGANOMETALLICS   Vol. 39 ( 4 ) page: 500 - 504   2020.2

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.organomet.0c00027

  33. Synthesis of A Pincer-Ir-V Complex with A Base-Free Alumanyl Ligand and Its Application toward the Dehydrogenation of Alkanes Reviewed International journal

    Morisako Shogo, Watanabe Seiya, Ikemoto Satoru, Muratsugu Satoshi, Tada Mizuki, Yamashita Makoto

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 58 ( 42 ) page: 15031 - 15035   2019.10

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201909009

  34. Reversible low-temperature redox activity and selective oxidation catalysis derived from the concerted activation of multiple metal species on Cr and Rh-incorporated ceria catalysts Reviewed International journal

    Ikemoto Satoru, Huang Xiubing, Muratsugu Satoshi, Nagase Shoko, Koitaya Takanori, Matsui Hirosuke, Yokota Gen-ichi, Sudoh Takatoshi, Hashimoto Ayako, Tan Yuanyuan, Yamamoto Susumu, Tang Jiayi, Matsuda Iwao, Yoshinobu Jun, Yokoyama Toshihiko, Kusaka Shinpei, Matsuda Ryotaro, Tada Mizuki

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 21 ( 37 ) page: 20868 - 20877   2019.10

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9cp04625a

  35. Operando XAFS Imaging of Distribution of Pt Cathode Catalysts in PEFC MEA Invited Reviewed International journal

    Matsui Hirosuke, Maejima Naoyuki, Ishiguro Nozomu, Tan Yuanyuan, Uruga Tomoya, Sekizawa Oki, Sakata Tomohiro, Tada Mizuki

    CHEMICAL RECORD   Vol. 19 ( 7 ) page: 1380 - 1392   2019.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/tcr.201800123

  36. SPring-8 BL36XU: Synchrotron Radiation X-Ray-Based Multi-Analytical Beamline for Polymer Electrolyte Fuel Cells under Operating Conditions Invited Reviewed International journal

    Uruga Tomoya, Tada Mizuki, Sekizawa Oki, Takagi Yasumasa, Yokoyama Toshihiko, Iwasawa Yasuhiro

    CHEMICAL RECORD   Vol. 19 ( 7 ) page: 1444 - 1456   2019.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/tcr.201800193

  37. Enhanced oxygen reduction reaction performance of size-controlled Pt nanoparticles on polypyrrole-functionalized carbon nanotubes Reviewed International journal

    Ichihashi Kentaro, Muratsugu Satoshi, Miyamoto Shota, Sakamoto Kana, Ishiguro Nozomu, Tada Mizuki

    DALTON TRANSACTIONS   Vol. 48 ( 21 ) page: 7130 - 7137   2019.6

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9dt00158a

  38. Synthesis of [Mo3S4] Clusters from Half-Sandwich Molybdenum(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes Reviewed International journal

    Ohki Yasuhiro, Hara Ryota, Munakata Kenichiro, Tada Mizuki, Takayama Tsutomu, Sakai Yoichi, Cramer Roger E.

    INORGANIC CHEMISTRY   Vol. 58 ( 8 ) page: 5230 - 5240   2019.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.9b00309

  39. Operando Observation of Sulfur Species Poisoning Polymer Electrolyte Fuel Cell Studied by Near Ambient Pressure Hard X-ray Photoelectron Spectroscopy Reviewed International journal

    Yu Liwei, Takagi Yasumasa, Nakamura Takahiro, Sakata Tomohiro, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Masaoka Shigeyuki, Yokoyama Toshihiko

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 123 ( 1 ) page: 603 - 611   2019.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.8b10611

  40. N-Heterocyclic Carbene-Modified Au-Pd Alloy Nanoparticles and Their Application as Biomimetic and Heterogeneous Catalysts Reviewed International coauthorship International journal

    Tegeder Patricia, Freitag Matthias, Chepiga Kathryn M., Muratsugu Satoshi, Moeller Nadja, Lamping Sebastian, Tada Mizuki, Glorius Frank, Ravoo Bart Jan

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 24 ( 70 ) page: 18682 - 18688   2018.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201803274

  41. Cubane-Type [Mo3S4M] Clusters with First-Row Groups 4-10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum Reviewed International coauthorship International journal

    Ohki Yasuhiro, Uchida Keisuke, Hara Ryota, Kachi Mami, Fujisawa Mayu, Tada Mizuki, Sakai Yoichi, Sameera W. M. C.

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 24 ( 64 ) page: 17138 - 17147   2018.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201804083

  42. Operando Time-Resolved X-ray Absorption Fine Structure Study for Pt Oxidation Kinetics on Pt/C and Pt3Co/C Cathode Catalysts by Polymer Electrolyte Fuel Cell Voltage Operation Synchronized with Rapid O-2 Exposure Reviewed International journal

    Ozawa Saki, Matsui Hirosuke, Ishiguro Nozomu, Tan Yuanyuan, Maejima Naoyuki, Taguchi Masahiro, Uruga Tomoya, Sekizawa Oki, Sakata Tomohiro, Nagasawa Kensaku, Higashi Kotaro, Tada Mizuki

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 122 ( 26 ) page: 14511 - 14517   2018.7

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.jpcc.8b02541

  43. Structural Kinetics of Cathode Events on Polymer Electrolyte Fuel Cell Catalysts Studied by Operando Time-Resolved XAFS Invited Reviewed International journal

    Ishiguro Nozomu, Tada Mizuki

    CATALYSIS LETTERS   Vol. 148 ( 6 ) page: 1597 - 1609   2018.6

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s10562-018-2383-7

  44. Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru-porphyrin catalyst Reviewed International journal

    Muratsugu Satoshi, Baba Hiroshi, Tanimoto Tatsuya, Sawaguchi Kana, Ikemoto Satoru, Tasaki Masahiro, Terao Yosuke, Tada Mizuki

    CHEMICAL COMMUNICATIONS   Vol. 54 ( 40 ) page: 5114 - 5117   2018.5

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c8cc00896e

  45. Tuning the structure and catalytic activity of Ru nanoparticle catalysts by single 3d transition-metal atoms in Ru-12-metalloporphyrin precursors Reviewed International journal

    Muratsugu Satoshi, Yamaguchi Atsuki, Yokota Gen-ichi, Maeno Tomoaki, Tada Mizuki

    CHEMICAL COMMUNICATIONS   Vol. 54 ( 38 ) page: 4842 - 4845   2018.5

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7cc09862f

  46. Ambient Pressure Hard X-ray Photoelectron Spectroscopy for Functional Material Systems as Fuel Cells under Working Conditions Invited Reviewed International journal

    Takagi Yasumasa, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Yokoyama Toshihiko

    ACCOUNTS OF CHEMICAL RESEARCH   Vol. 51 ( 3 ) page: 719 - 727   2018.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.accounts.7b00563

  47. Structural investigations of La0.6Sr0.4FeO3-delta under reducing conditions: kinetic and thermodynamic limitations for phase transformations and iron exsolution phenomena Reviewed International coauthorship International journal

    Goetsch Thomas, Schlicker Lukas, Bekheet Maged F., Doran Andrew, Gruenbacher Matthias, Praty Corsin, Tada Mizuki, Matsui Hirosuke, Ishiguro Nozomu, Gurlo Aleksander, Kloetzer Bernhard, Penner Simon

    RSC ADVANCES   Vol. 8 ( 6 ) page: 3120 - 3131   2018

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7ra12309d

  48. Non-contact electric potential measurements of electrode components in an operating polymer electrolyte fuel cell by near ambient pressure XPS Reviewed International journal

    Yu Liwei, Takagi Yasumasa, Nakamura Takahiro, Sekizawa Oki, Sakata Tomohiro, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Samjeske Gabor, Yokoyama Toshihiko

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 19 ( 45 ) page: 30798 - 30803   2017.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7cp05436j

  49. Size Regulation and Stability Enhancement of Pt Nanoparticle Catalyst via Polypyrrole Functionalization of Carbon-Nanotube-Supported Pt Tetranuclear Complex Reviewed International journal

    Muratsugu Satoshi, Miyamoto Shota, Sakamoto Kana, Ichihashi Kentaro, Kim Chang Kyu, Ishiguro Nozomu, Tada Mizuki

    LANGMUIR   Vol. 33 ( 39 ) page: 10271 - 10282   2017.10

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.langmuir.7b02114

  50. Synthesis and Characterization of Bioinspired [Mo2Fe2]-Hydride Cluster Complexes and Their Application in the Catalytic Silylation of N-2 Reviewed International journal

    Ohki Yasuhiro, Araki Yuna, Tada Mizuki, Sakai Yoichi

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 23 ( 53 ) page: 13240 - 13248   2017.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201702925

  51. X-ray photoelectron spectroscopy under real ambient pressure conditions Reviewed International journal

    Takagi Yasumasa, Nakamura Takahiro, Yu Liwei, Chaveanghong Suwilai, Sekizawa Oki, Sakata Tomohiro, Uruga Tomoya, Tada Mizuki, Iwasawa Yasuhiro, Yokoyama Toshihiko

    APPLIED PHYSICS EXPRESS   Vol. 10 ( 7 ) page: 076603   2017.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.7567/APEX.10.076603

  52. [Fe-4] and [Fe-6] Hydride Clusters Supported by Phosphines: Synthesis, Characterization, and Application in N-2 Reduction Reviewed International journal

    Araake Ryoichi, Sakadani Kazuki, Tada Mizuki, Sakai Yoichi, Ohki Yasuhiro

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 139 ( 15 ) page: 5596 - 5606   2017.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/jacs.7b01965

  53. Preparation and catalytic performance of a molecularly imprinted Pd complex catalyst for Suzuki cross-coupling reactions Reviewed International journal

    Muratsugu Satoshi, Maity Niladri, Baba Hiroshi, Tasaki Masahiro, Tada Mizuki

    DALTON TRANSACTIONS   Vol. 46 ( 10 ) page: 3125 - 3134   2017.3

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c7dt00124j

  54. In situ study of oxidation states of platinum nanoparticles on a polymer electrolyte fuel cell electrode by near ambient pressure hard X-ray photoelectron spectroscopy Reviewed International journal

    Takagi Yasumasa, Wang Heng, Uemura Yohei, Nakamura Takahiro, Yu Liwei, Sekizawa Oki, Uruga Tomoya, Tada Mizuki, Samjeske Gabor, Iwasawa Yasuhiro, Yokoyama Toshihiko

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 19 ( 8 ) page: 6013 - 6021   2017.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c6cp06634h

  55. Co6H8(PiPr3)6: A Cobalt Octahedron with Face-Capping Hydrides Reviewed International journal

    Y. Ohki*, Y. Shimizu, R. Araake, M. Tada, W. M. C. Sameera, J. Ito, H. Nishiyama

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 55   page: 15821 - 15825   2016.11

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  56. Kinetics and Mechanism of Redox Processes of Pt/C and Pt3Co/C Cathode Electrocatalysts in a Polymer Electrolyte Fuel Cell during an Accelerated Durability Test Reviewed International journal

    N. Ishiguro*, S. Kityakarn, O. Sekizawa, T. Uruga, H. Matsui, M. Taguchi, K. Nagasawa, T. Yokoyama, M. Tada

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 120   page: 19642 - 19651   2016.8

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  57. Formation and Nitrile Hydrogenation Performance of Ru Nanoparticles on a K-doped Al2O3 Surface Reviewed International journal

    Muratsugu, S. Kityakarn, F. Wang, N. Ishiguro, T. Kamachi, K. Yoshizawa, O. Sekizawa, T. Uruga, M. Tada

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 17   page: 24791 - 24802   2015.9

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1088/1742-6596/849/1/012022

  58. In situ Study of an Oxidation Reaction on a Pt/C Electrode by Ambient Pressure Hard X-ray Photoelectron Spectroscopy Reviewed International journal

    Y. Takagi, H. Wang, Y. Uemura, E. Ikenaga, O. Sekizawa, T. Uruga, H. Ohashi, Y. Senba, H. Yumoto, H. Yamazaki, S. Goto, M. Tada, Y. Iwasawa, and T. Yokoyama

    App. Phys. Lett.   Vol. 105   page: 131692 - 131692   2014.10

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  59. Rate Enhancements in Structural Transformations of Pt-Co and Pt-Ni Bimetallic Cathode Catalysts in Polymer Electrolyte Fuel Cells Studied by in situ Time-Resolved X-ray Absorption Fine Structure Reviewed International journal

    N. Ishiguro, S. Kityakarn, O. Sekizawa, T. Uruga, T. Sasabe, K. Nagasawa, T. Yokoyama, and M. Tada

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 118   page: 15874 - 15883   2014.7

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    DOI: 10.1021/jp504738p

  60. Dispersed RhMo Nanoclusters Prepared from Oxide-Supported Rh2Mo Heterometallic Complexes as Catalysts for Selective Alcohol Oxidation Reviewed International journal

    S. Muratsugu*, S. Tajima, and M. Tada

    Chem. Lett.   Vol. 43   page: 1321 - 1323   2014.5

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.140326

  61. Visualization of the Heterogeneity of Cerium Oxidation States in Single Pt/Ce2Zr2Ox Catalyst Particles by Nano-XAFS Reviewed International journal

    N. Ishiguro, T. Uruga, O. Sekizawa, T. Tsuji, M. Suzuki, N. Kawamura, M. Mizumaki, K. Nitta, T. Yokoyama, and M. Tada

    ChemPhysChem   Vol. 15   page: 1563 - 1568   2014.3

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/cphc.201400090

  62. In Situ Time-resolved XAFS of Transitional States of Pt/C Cathode Electrocatalyst in an MEA during Loading with Transient Voltages Invited Reviewed International journal

    S. Kityakarn, T. Saida, A. Sode, N. Ishiguro, O. Sekizawa, T. Uruga, K. Nagasawa, T. Yamamoto, T. Yokoyama, and M. Tada

    Topics Catal.   Vol. 57   page: 903 - 910   2014.2

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s11244-014-0250-3

  63. A Solid Chelating Ligand: Periodic Mesoporous Organosilica Containing 2,2'-Bipyridine within the Pore Walls Reviewed International journal

    M. Waki, Y. Maegawa, K. Hara, Y. Goto, S. Shirai, Y. Yamada, N. Mizoshita, T. Tani, W.-J. Chun, S. Muratsugu, M. Tada, A. Fukuoka, and S. Inagaki

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   Vol. 136   page: 4003 - 4011   2014.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja4131609

  64. Structural Kinetics on a Pt/C Cathode Catalyst with Practical Catalyst Loading in an MEA for PEFC Operating Conditions Studied by In Situ Time-Resolved XAFS Reviewed International journal

    N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, K. Nagasawa, K. Nitta, T. Yamamoto, S. Ohkoshi, T. Yokoyama, and M. Tada

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 15   page: 18827 - 18834   2013.9

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    DOI: 10.1039/C3CP52578C

  65. Rate Enhancement for Hexose Sugar Oxidation on an Ethynylpyridine-Functionalized Pt/Al2O3 Catalyst with Induced Chirality Reviewed International journal

    M. Waki, S. Muratsugu, and M. Tada

    CHEMICAL COMMUNICATIONS   Vol. 49   page: 7283 - 7285   2013.7

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  66. Potential-Dependent Restructuring and Hysteresis in the Structural and Electronic Transformations of Pt/C,Au(Core)-Pt(Shell)/C, and Pd(Core)-Pt(Shell)/C Cathode Catalysts in Polymer Electrolyte Fuel Cells Characterized by in situ X-ray Absorption Fine Structure Reviewed International journal

    S. Nagamatsu, T. Arai, M. Yamamoto, T. Ohkura, H. Oyanagi, T. Ishizaka, H. Kawanami, T. Uruga, M. Tada

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 117   page: 13094 - 13107   2013.6

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  67. Hard X-ray Time-resolved/Space-resolved X-ray Absorption Fine Structure Analysis for Heterogeneous Metal Catalysts Invited Reviewed International journal

    M. Tada

    Journal of the Physical Society of Japan   Vol. 82   page: 021013 - 021013   2012.12

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  68. Perovskite NaCeTi2O6-Supported Ni Catalysts for CH4 Steam Reforming Reviewed International journal

    S. Zhang*, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada*

    ChemCatChem   Vol. 4   page: 1783 - 1790   2012.11

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  69. Surface-Assisted Transfer Hydrogenation Catalysis on a γ-Al2O3-Supported Ir Dimer Reviewed International journal

    S. Muratsugu, Z. Weng, H. Nakai, K. Isobe, T. Sasaki, and M. Tada*

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 14   page: 16023 - 16031   2012.10

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  70. Molecularly Imprinted Ru Complex Catalyst Systems Integrated on Oxide Surfaces Invited Reviewed International journal

    S. Muratsugu and M. Tada*

    Accounts of Chemical Research   Vol. 46   page: 300 - 311   2012.10

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  71. The Active Phase of Nickel/Ordered Ce2Zr2Ox Catalysts with a Discontinuous (x = 7-8) in Methane Steam Reforming Reviewed International journal

    M. Tada*, S. Zhang, S. Malwadkar, N. Ishiguro, J. Soga, Y. Nagai, K. Tezuka, H. Imoto, S. O.-Y.-Matsuo, S. Ohkoshi, and Y. Iwasawa*

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   Vol. 51   page: 9361 - 9365   2012.8

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  72. Operando Time-resolved X-ray Absorption Fine Structure Study for Surface Events on a Pt3Co/C Cathode Catalyst in a Polymer Electrolyte Fuel Cell during Voltage-Operating Processes Reviewed International journal

    N. Ishiguro, T. Saida, T. Uruga, O. Sekizawa, S. Nagamatsu, K. Nitta, T. Yamamoto, S. Ohkoshi, Y. Iwasawa, T. Yokoyama, and M. Tada*

    ACS CATALYSIS   Vol. 2   page: 1319 - 1330   2012.5

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  73. Sulfoxidation on a SiO2-supported Ru Complex Using O2/Aldehyde System Reviewed International journal

    N. Maity, C. Wattanakit, S. Muratsugu, N. Ishiguro, Y. Yang, S. Ohkoshi, and M. Tada*

    DALTON TRANSACTIONS   Vol. 41   page: 4558 - 4565   2012.2

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  74. Preparation and Catalytic Performances of a Molecularly Imprinted Ru-Complex Catalyst with an NH2 Binding Site on a SiO2 Surface Reviewed International journal

    Y. Yang, Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada*

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 18   page: 1142 - 1153   2011.12

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  75. Normal and Inverted Redox Potentials and Structural Changes Tuned by Medium Effects in [M2Mo( η5-C5Me5)2(S2C6H4)2(CO)2] (M: Co, Rh) Reviewed International journal

    S. Muratsugu, K. Sodeyama, F. Kitamura, S. Tsukada, M. Tada, S. Tsuneyuki, and H. Nishihara*

    Chemical Science   Vol. 2   page: 1960 - 1968   2011.8

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  76. In situ Time-Resolved XAFS Study on the Structural Transformation and Phase Separation of Pt3Sn and PtSn Alloy Nanoparticles on Carbon in the Oxidation Process Reviewed International journal

    Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa*

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 13   page: 15833 - 15844   2011.7

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  77. μ-XAFS of A Single Particle of A Practical NiOx/Ce2Zr2Oy Catalyst Reviewed International journal

    M. Tada*, N. Ishiguro, T. Uruga, H. Tanida, Y. Terada, S. Nagamatsu, S. Ohkoshi, and Y. Iwasawa

    PHYSICAL CHEMISTRY CHEMICAL PHYSICS   Vol. 13   page: 14910 - 14913   2011.6

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  78. Core-Shell Phase Separation and Structural Transformation of Pt3Sn Alloy Nanoparticles Supported on γ-Al2O3 in the Reduction and Oxidation Processes Characterized by in-situ Time- Resolved XAFS Reviewed International journal

    Y. Uemura, Y. Inada, K. K. Bando, T. Sasaki, N. Kamiuchi, K. Eguchi, A. Yagishita, M. Nomura, M. Tada, and Y. Iwasawa*

    JOURNAL OF PHYSICAL CHEMISTRY C   Vol. 115   page: 5823 - 5833   2011.3

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  79. Preparation of Surface Molecularly Imprinted Ru-Complex Catalysts for Asymmetric Transfer Hydrogenation in Water Media Reviewed International journal

    Z. Weng, S. Muratsugu, N. Ishiguro, S. Ohkoshi, and M. Tada*

    DALTON TRANSACTIONS   Vol. 40   page: 2338 - 2347   2010.11

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  80. Surface-Mediated Design and Catalytic Properties of Active Metal Complexes for Advanced Catalysis Creation Invited Reviewed International journal

    M. Tada

    Bulletin of the Chemical Society of Japan   Vol. 83   page: 855 - 876   2010.7

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▼display all

Books 5

  1. 触媒化学

    岩澤康裕, 小林修, 冨重圭一, 関根泰, 上野雅晴, 唯美津木( Role: Joint author)

    裳華房  2019.5 

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    Total pages:242   Language:Japanese Book type:Textbook, survey, introduction

  2. XAFS Techniques for Catalysts, Nanomaterials, and Surfaces

    Y. Iwasawa, K. Asakura, M. Tada( Role: Joint author)

    Springer  2017 

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    Language:English Book type:Scholarly book

  3. ナノ材料解析の実際

    唯 美津木( Role: Contributor ,  第29章)

    講談社  2016 

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    Responsible for pages:316-321   Language:Japanese

  4. PEFCの内部現象・反応機構と評価・解析技術

    唯美津木, 石黒志, 松井公佑( Role: Contributor ,  第2章第1節)

    S&T出版  2015 

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    Responsible for pages:29-33   Language:Japanese Book type:Scholarly book

  5. 放射光が拓く化学の現在と未来

    唯 美津木( Role: Contributor ,  第11章)

    化学同人  2014 

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    Responsible for pages:99-103   Language:Japanese Book type:Scholarly book

Presentations 28

  1. Preparation of Atomically Dispersed Ruthenium and Copper Oxide Incorporated Ceria Catalyst and its Ammoxidation Performances of Aliphatic Alcohols

    C. Chen, S. Muratsugu, M. Tada

    2023.3.22 

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    Event date: 2023.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  2. Synthesis and Characterization of Novel Iron-Group Metal Nanoclusters Protected by Bulky Ligands

    T. Higaki, K. Tanaka, S. Oishi, K. Kawamoto, M. Tada, Y. Ohki

    2023.3.22 

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    Event date: 2023.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  3. 嵩高いPtBu3で保護された[Fe55]ナノクラスターの合成と同定

    田中奏多, 川本晃希, 大石峻也, 唯美津木, 檜垣達也, 大木靖弘

    日本化学会第103春季年会  2023.3.22  日本化学会

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    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:千葉   Country:Japan  

  4. X線CTイメージングによるPEFC内部の液水のその場観察

    太田智郎, 松井公佑, 唯美津木

    日本化学会第103春季年会  2023.3.25  日本化学会

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    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:千葉   Country:Japan  

  5. MOF-74粒子内の吸着拡散のin-situ時間分解X線分光イメージング

    五十嵐羽奏, 山田笑菜, 坂本裕俊, 松井公佑, 宇留賀朋哉, 唯美津木

    日本化学会第103春季年会  2023.3.25  日本化学会

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    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:千葉   Country:Japan  

  6. Preparation and oxygen reduction reaction performances of Pt-Gd alloy nanoparticle catalyst on a porous carbon support

    T. Moriyama, M. Sato, S. Muratsugu, M. Tada

    2023.3.22 

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    Event date: 2023.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  7. Immobilization of Terbium Complex on Solid Surface with Chiral Moiety

    S. Shirai, S. Muratsugu, H. Nakai, M. Tada

    2023.3.24 

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    Event date: 2023.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  8. オペランドCTイメージングによるPEFC内の液水の可視化

    松井公佑, 宇留賀朋哉, 唯美津木

    第36回日本放射光学会年会・放射光科学合同シンポジウム  2023.7.7 

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    Event date: 2023.1

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:滋賀   Country:Japan  

  9. 全固体電池の高空間分解オペランド3次元反応分布計測に基づく活物質粒子パラメータのデータ駆動最適化

    木村勇太, 黄溯, 中村崇司, 石黒志, 有吉欽吾, 奥村豊旗, 竹内友成, 関澤央輝, 新田清文, 宇留賀朋哉, 唯美津木, 内本喜晴, 雨澤浩史

    第48回固体イオニクス討論会  2022.12.6 

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    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:仙台   Country:Japan  

  10. 反応の可視化がもたらす知と物質科学の発展 Invited

    唯美津木

    日本学術会議物理学委員会主催公開シンポジウム「物理学のアプローチが拓く世界とその展開」  2022.11.20  日本学術会議物理学委員会

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    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京   Country:Japan  

  11. Go beyond Imaging: Infography for Material Sciences Invited International conference

    M.Tada

    Asia Oceania International Conference on Synchrotron Radiation Instruments 2022 (AO-SRI 2022)  2022.11.10 

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    Event date: 2022.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  12. Operando 3D Visualization of Practical Polymer Electrolyte Fuel Cell Invited International conference

    M.Tada

    The 6th Symposium for the Core Research Clusters for Materials Science and Spintronics  2022.10.25 

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    Event date: 2022.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Online  

  13. Preparation and Selective Oxidation Performances of Rutile-type IrO2 Nanoparticle Catalysts

    S. Muratsugu, T. Sudoh, D. Itoh, C. Chen, S. Ikemoto, M. Tada

    2022.9.26 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  14. Operando CT-XAFS三次元イメージングを用いたMOF-74Co結晶内の水分子吸着現象

    山田笑菜, 坂本裕俊, 松井公佑, 松田亮太郎, 宇留賀朋哉, 唯美津木

    錯体化学会第72回討論会  2022.9.27 

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    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:福岡   Country:Japan  

  15. Chirality Induction of a Terbium Complex on a Chiral Ligand Functionalized Silica Surface

    S. Shirai, S. Muratsugu, H. Nakai, M. Ehara, M. Tada

    2022.9.26 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  16. Preparation, Redox performances, and catalytic alcohol ammoxidation performances of Cu and Ru-incorporated Ceria Catalysts

    C. Chen, S. Ikemoto, Y. Gen-ich, S. Muratsugu, M. Tada

    2022.9.26 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  17. イメージングと情報技術が拓く材料反応の可視化 Invited

    唯美津木

    学際統合物質機構キックオフシンポジウム  2022.9.14 

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    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  18. 3D Operando Analysis of Cycle Degradation in Solid-state Battery Electrodes Using CT-XAFS International conference

    S. Huang, Y. Kimura, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, K. Amezawa

    17th Asian Conference on Solid State Ionics  2022.9.12 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  19. Operando 3D Imaging of Membrane Electrode Assembly of Polymer Electrolyte Fuel Cell Invited

    M.Tada

    The 22nd International Vacuum Congress (IVC-22)  2022.9.13 

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    Event date: 2022.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  20. キュバン型[Mo3S4Fe]クラスターのFeサイトを用いた触媒的窒素シリル化反応 International coauthorship

    谷藤一樹, 宗像健一郎, 原亮太, 内田圭亮, 唯美津木, R. E. Cramer, W. M. C. Sameera, 高山努, 酒井陽一, 栗山翔吾, 西林仁昭, 大木靖弘

    第68回有機金属化学討論会  2022.9.8 

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    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  21. オペランドイメージングによる燃料電池の可視化 Invited

    唯美津木

    日本MRS水素科学技術連携研究会第4回トピックス研究会~化学分科会~  2022.8.24 

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    Event date: 2022.8

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン   Country:Japan  

  22. Synthesis and Operando characterization of Pt-Bimetallic Oxygen Reduction Catalysts for Polymer Electrolyte Fuel Cell Invited

    M.Tada

    8th Asian Conference on Coordination Chemistry  2022.8.9 

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    Event date: 2022.8

    Language:English  

    Venue:Taiwan-online   Country:Taiwan, Province of China  

  23. 3D Operando High-Resolution Imaging of Inhomogeneous Electrochemical Reaction in Composite Solid-State Battery Electrodes International conference

    Y. Kimura, S. Huang, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, K. Amezawa

    23rd International Conference on Solid State Ionics  2022.7.17 

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    Event date: 2022.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Boston   Country:United States  

  24. 3D Operando Visualization and Quantification of Cycle Degradation in Solid State Battery Electrodes Using CT-XAFS International conference

    S. Huang, Y. Kimura, T. Nakamura, N. Ishiguro, O. Sekizawa, K. Nitta, T. Uruga, T. Takeuchi, T. Okumura, M. Tada, Y. Uchimoto, K. Amezawa

    23rd International Conference on Solid State Ionics  2022.7.17 

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    Event date: 2022.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Boston   Country:United States  

  25. 観ることで広がる化学の世界 Invited

    唯美津木

    歴史的化学論文大賞受賞記念シンポジウム  2022.7.2 

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    Event date: 2022.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:名古屋   Country:Japan  

  26. Preparation and Electrocatalytic Oxygen Reduction Performances of Size-controlled Pt Nanoparticle Catalysts Decorated with Polypyrrole Polymers and Lanthanide Hydroxides International conference

    S. Muratsugu, K. Ichihashi, M. Tada

    The 19th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis  2022.6.27 

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    Event date: 2022.6

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Oslo-online   Country:Norway  

  27. Reversible Low-temperature Redox Property and Catalytic Performances for NO Reduction of Cr and Rh-incorporated Ceria Catalysts International conference

    S. Ikemoto, S. Muratsugu, M. Tada

    The 19th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis  2022.6.29 

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    Event date: 2022.6

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Oslo-online   Country:Norway  

  28. 電極触媒の機能化とオペランド可視化による燃料電池反応解析 Invited

    唯美津木

    表面真空学会関東支部講演大会  2022.4.15  表面真空学会

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    Event date: 2022.4

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン   Country:Japan  

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KAKENHI (Grants-in-Aid for Scientific Research) 5

  1. オペランド三次元XAFS分光イメージングによる活性固体材料の新奇反応現象解明

    Grant number:22H02031  2022.4 - 2025.3

    科学研究費助成事業  基盤研究(B)

    唯 美津木, DAM HieuChi

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    Authorship:Principal investigator 

    Grant amount:\17680000 ( Direct Cost: \13600000 、 Indirect Cost:\4080000 )

    固体触媒やMOFなどの活性固体材料内の構造と化学状態を可視化する高感度オペランド三次元XAFS分光イメージングを開発し、活性固体材料の動的機能を生み出す活性金属種の分布、酸化状態、局所配位構造の三次元空間分布の高感度イメージングを実現する。また、計測ビッグデータを効率的に解析する方法を開拓し、触媒粒子の活性界面構造、反応機構、MOF粒子内の吸着反応起点、反応拡散、ゲート吸着機構等を明らかにする。

  2. オペランドSHINERS/イメージングXAFSによる電極触媒の構造-活性相関解明

    Grant number:20F20333  2020.11 - 2023.3

    科学研究費助成事業  特別研究員奨励費

    唯 美津木, WONDERGEM CATERINA

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    Authorship:Other  Grant type:Competitive

    本研究では、SHINERSラマン分光法を立ち上げ、燃料電池カソード電極触媒反応に展開し、触媒表面の化学種の構造解析とCT-XAFS分光による金属触媒の局所構造解析を組み合わせた新しいオペランドイメージング計測を行う。酸素還元反応のための電極触媒や複合酸化物触媒の触媒反応における化学種と活性構造の関係を明らかにし、触媒活性構造や反応の可視化を行うことを目指す。
    本研究では、SHINERSラマン分光法とXAFSイメージング計測法を互いに相補的に用いることで、電極触媒の反応過程と空間分布の解明を目的とした。そのために、SHINERS分光法に用いるSHIN粒子の合成とそれを利用した電極触媒の合成、オペランドSHINERS装置の立ち上げ、オペランドXAFSによる電極触媒の解析を行った。
    Agを用いたSHIN粒子の合成を検討し、15 nm程度のAu粒子を核として粒径のそろったAgナノ粒子を調製した。その表面に3-アミノプロピルトリメトキシシランを用いてシリカ薄層を作成した。Ag 粒子表面を覆いピンホールのないSHIN粒子の合成条件を様々検討し、ピンホールのないAg SHIN粒子を合成した。一方、合成した粒子は、安定性がAu SHIN粒子と比較して低いことがわかり、試料の保存ができないことが分かったため、Au SHIN粒子を新たに合成した。ローダミン6Gのラマンスペクトルでは、強い表面プラズモン共鳴が観察された一方、ピリジンを吸着させてもピリジン由来のラマンシグナルは観測されず、Au表面をシリカが完全に覆ったピンホールのない良質なSHIN粒子が合成できていることを明らかにした。
    このAu SHIN粒子を用いて、Pt触媒の担持を検討し、市販のPt/CやPt粒子を担持した触媒系を作成した。また、オペランドEC-SHINERS装置とセルの立ち上げを行い、電位をかけた条件でPt触媒-SHIN粒子の測定ができる測定環境を立ち上げた。SO2分子を触媒被毒剤として用い、Pt触媒表面をSO2で被毒した後、電気化学セルの電位を変化させて、表面の化学種を変化させ、SHINERSスペクトルを測定した。PtとSHIN粒子の接地条件を検討し、より良質なSHINERSスペクトルが得られる試料調製を検討している。
    当初計画したAg SHIN粒子については、本研究において新たに合成を行ったところ、目的とする化合物が合成できたが、安定性が低く電極反応実験に用いることが難しいことが分かったが、Au SHIN粒子を新たに合成し、それを用いてPt触媒のオペランドSHINERS測定を実現した。当初予定していた研究計画は進められており、新たな知見も得られ、今後これらの成果を発展して、Pt電極触媒の被毒機構の解明を進めていく予定である。
    外国人特別研究員の就職(特任助教)が決まり、本研究費課題は終了した。得られた知見を基に、代表者と共同研究者が研究を継続しており、本課題において作成したAu SHIN粒子およびオペランドEC-SHINERS測定システムを用いて、電極触媒の被毒種の同定を進めている。オペランドXAFSイメージングと連携して、触媒被毒種が電位に対してどのように反応して脱離していくか、触媒回復過程の解明を進める。

  3. 構造制御されたPtNiナノクラスターの合成と燃料電池電極触媒への展開

    Grant number:19F19035  2019.4 - 2021.3

    科学研究費助成事業  特別研究員奨励費

    唯 美津木, WAN XIAN-KAI

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    Authorship:Principal investigator  Grant type:Competitive

    本研究では、独自に合成したマイクロポーラスカーボン材料を利用して、その細孔内で燃料電池カソード触媒反応に有効なPt系合金電極触媒の合成し、電極触媒としての触媒活性を評価し、活性・耐久性に優れた電極触媒を開発する。回転ディスク電極を用いた電気化学評価を行い、酸素還元反応活性、活性比表面積、加速劣化試験に対する活性変化などを検討する。
    本研究では、中空多孔性カーボン材料を合成し、この細孔内を利用したPt-Ni合金電極触媒粒子を調製し、その構造、酸素還元反応特性、耐久性を明らかにすることを目的とした。中空多孔性シリカを鋳型として、中空多孔性カーボンHPCSを合成し、Pt及びNi錯体を2,2'ジピリジルアミン (dpa) 共存下含浸し、乾燥、水素による還元処理を行うことで、HPCSに担持されたPt-Ni合金ナノ粒子を調製した。TEM観察及びXRD解析の結果、HPCS内に平均粒径2.0±0.4 nmのPt-Ni合金ナノ粒子が形成されていることがわかった。dpaがない場合には、顕著な合金の相分離と粒径の増大が見られた。dpa以外の様々な有機配位子を用いた合成を検討したところ、ピリジン骨格を有する有機分子が粒径制御に有効であり、dpaで最も小さいPt-Ni合金ナノ粒子が得られることがわかった。
    Pt/Ni比の異なる複数のPt-Ni/HPCS触媒を合成し、RDEを用いた酸素還元反応(ORR)活性の評価を行ったところ、Pt-Ni/HPCS触媒は、市販のPt/C触媒やKBに担持したPt-Ni触媒と比較してECSAが大きく、MA, SAとも優れた活性値を示した。Pt/Ni=1.22の試料が最もORR活性が高く、0.9 Vで3.25 A mg-1_PtのMAを示し、市販のPt/Cと比較して13.5倍の値であった。加速劣化試験によって触媒の耐久性を評価したところ、加速劣化試験回数に伴ってECSAの低下は見られるものの、市販のPt/Cと比較してその低下は緩やかであり、60,000回の加速劣化試験後にも2.3±0.4 nmの粒径を維持していることが分かった。
    また、このdpaを利用したPt系合金ナノ粒子の触媒調製法を更に発展させ、メタノールを用いた電極酸化反応触媒の調製も行った。
    令和2年度が最終年度であるため、記入しない。
    令和2年度が最終年度であるため、記入しない。

  4. Visualization of Structure/Reactivity of Heterogeneous Catalysts by Operando Spatio/Temporal Imaging XAFS International coauthorship

    Grant number:18H01940  2018.4 - 2021.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (B)

    Tada Mizuki

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\17420000 ( Direct Cost: \13400000 、 Indirect Cost:\4020000 )

    We have developed XAFS-spectroscopy-imaging techniques combining hard X-ray imaging techniques and X-ray Absorption Fine Structure (spectroscopy) for the visualization of spatial element information inside solid materials. XAFS imaging provides spatial distribution of each element, oxidation state, local coordination structure inside solid particles and crystals and we visualized the reaction diffusions inside mixed oxides and solid catalysts by the XAFS imaging techniques. We succeeded in visualizing the oxidation reaction track inside ceria-zirconia solid-solution materials and redox reaction behaviors of Cr-doped iron oxide crystals for the first time.

  5. Preparation of Coordination Asymmetry at Solid Surfaces International coauthorship

    Grant number:16H06512  2016.6 - 2021.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    Tada Mizuki

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\38610000 ( Direct Cost: \29700000 、 Indirect Cost:\8910000 )

    Unique metal coordination asymmetry on solid surfaces were prepared by metal-complex attachment and surface functionalization techniques. By the collaborative works in the research unit, the attachment and functionalization of Co3 cluster, V complex, Tb complex were achieved on SiO2 surfaces and new asymmetric coordination structures were prepared at the surfaces. We characterized the prepared asymmetric coordination structures by XAFS, CD, CPL, theoretical calculation etc. and their unique reaction performances were investigated.

 

Academic Activities 12

  1. Editorial Advisory Board, J. Phys. Chem. Lett.

    Role(s):Review, evaluation

    2023

  2. 触媒学会 先端放射光活用研究会 委員長

    Role(s):Planning, management, etc.

    2022.4

  3. 北海道大学触媒科学研究所運営協議会委員

    Role(s):Planning, management, etc.

    2022.4 - 2024.3

  4. 分子科学研究所運営会議委員

    Role(s):Planning, management, etc.

    2022.4 - 2024.3

  5. Fellow of the Royal Society of Chemistry

    Role(s):Planning, management, etc.

    2022

  6. Editorial Advisory Board, Materials Today Sustainability

    Role(s):Review, evaluation

    2022

  7. Pacifichem 組織委員

    Role(s):Planning, management, etc.

    2022 - 2025

  8. 錯体化学会 将来計画委員会委員

    Role(s):Planning, management, etc.

    2020.4

  9. 分子科学研究所 共同研究専門委員会委員

    Role(s):Review, evaluation

    2018.4 - 2022.3

  10. 光科学イノベーションセンター 次世代放射光施設ビームライン検討委員会委員

    Role(s):Planning, management, etc.

    2018.4 - 2022.3

  11. 錯体化学会 男女共同参画委員会 委員長

    Role(s):Planning, management, etc.

    2017.4 - 2021.3

  12. Editorial Advisory Board, Catalysis Science & Technology

    Role(s):Review, evaluation

    2010 - 2018

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