研究者詳細 - 南保　正和

論文 - 南保　正和

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Desulfonylative Suzuki-Miyaura Cross-Coupling of Unactivated Aryl Sulfones through Ni Catalysis 査読有り

Ohkura, R; Tahara-Tezuka, Y; Yokogawa, D; Crudden, CM; Nambo, M

ACS CATALYSIS 15 巻 ( 11 ) 頁： 9909 - 9918 2025年5月

Inducible degradation of endogenous proteins by AlissAID system and development of a photoactivatable inducer

Yoshitaka Ogawa, Kohei Nishimura, Masakazu Nambo, Yuichiro Tsuchiya, Sanae Oka, Toshihiko Fujimori, Kazuya Ichihara, Akinobu Matsumoto, Keisuke Obara, Takumi Kamura

bioRxiv 2025年2月

Impact of Ligand Structure on Biological Activity and Photophysical Properties of NHC-Protected Au13 Nanoclusters 査読有り

Kulkarni, VK; Albright, EL; Zeinizade, E; Steele, E; Chen, J; Ding, LL; Malola, S; Takano, S; Harrington, K; Kwon, N; Levchenko, TI; Nambo, M; Tsukuda, T; Häkkinen, H; Stamplecoskie, K; Zheng, G; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 147 巻 ( 5 ) 頁： 4017 - 4025 2025年1月

Synthesis of gem-Difluoroalkenes through Ramberg-Bäcklund Reaction of Alkyltriflones 招待有り査読有り

Ohtsuka, M; Tahara-Tezuka, Y; Maekawa, Y; Crudden, CM; Nambo, M

ORGANIC SYNTHESES 102 巻頁： 315 - 334 2025年

Development of bright fluorescent auxin

Tsuyoshi Aoyama, Masakazu Nambo, Jia Xin Yap, Ayami Nakagawa, Marina Hayashi, Yuko Ukai, Motoo Ohtsuka, Ken-ichiro Hayashi, Yoshikatsu Sato, Yuichiro Tsuchiya

bioRxiv 2024年9月

Enantiospecific cross-coupling of cyclic alkyl sulfones 査読有り国際共著国際誌

Nolla-Saltiel, R; Ariki, ZT; Schiele, S; Alpin, J; Tahara, Y; Yokogawa, D; Nambo, M; Crudden, CM

NATURE CHEMISTRY 16 巻 ( 9 ) 頁： 1445 - 1452 2024年9月

If the Crown Fits: Sterically Demanding N-Heterocyclic Carbene Promotes the Formation of Au8Pt Nanoclusters 査読有り国際共著

Dejesus, JF; Jacob, SI; Phung, QM; Mimura, K; Aramaki, Y; Ooi, T; Nambo, M; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146 巻 ( 34 ) 頁： 23806 - 23813 2024年8月

Synthesis and preclinical testing of a selective beta-subtype agonist of thyroid hormone receptor ZTA-261 査読有り国際共著

Nambo, M; Nishiwaki-Ohkawa, T; Ito, A; Ariki, ZT; Ito, Y; Kato, Y; Yar, M; Yim, JCH; Kim, E; Sharkey, E; Kano, K; Mishiro-Sato, E; Okimura, K; Maruyama, M; Ota, W; Furukawa, Y; Nakayama, T; Kobayashi, M; Horio, F; Sato, A; Crudden, CM; Yoshimura, T

COMMUNICATIONS MEDICINE 4 巻 ( 1 ) 頁： 152 2024年8月

Visible-light-induced direct C-H alkylation of polycyclic aromatic hydrocarbons with alkylsulfones 査読有り国際共著

Ohtsuka, M; Ghosh, K; Yim, JCH; Sotome, H; Okamoto, T; Suda, K; Kobori, Y; Yokogawa, D; Miyasaka, H; Crudden, CM; Nambo, M

CHEMICAL SCIENCE 15 巻 ( 27 ) 頁： 10592 - 10599 2024年7月

N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters 査読有り国際共著

Albright, EL; Levchenko, TI; Kulkarni, VK; Sullivan, AI; Dejesus, JF; Malola, S; Takano, S; Nambo, M; Stamplecoskie, K; Häkkinen, H; Tsukuda, T; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146 巻 ( 9 ) 頁： 5759 - 5780 2024年2月

Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2 査読有り国際共著

Albright, EL; Malola, S; Jacob, SI; Yi, H; Takano, S; Mimura, K; Tsukuda, T; Häkkinen, H; Nambo, M; Crudden, CM

CHEMISTRY OF MATERIALS 36 巻 ( 3 ) 頁： 1279 - 1289 2024年1月

Lectureship Award MBLA 2021 and 2022 Lecture Tour Completed 招待有り査読有り

Nambo, M; Yamatsugu, K

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 82 巻 ( 4 ) 頁： 382 - 394 2024年

Visible-light photoredox-catalyzed coupling of alkylsulfones with α-(trifluoromethyl)styrenes 招待有り査読有り

Tahara, Y; Ghosh, K; Nambo, M

CANADIAN JOURNAL OF CHEMISTRY 101 巻 ( 7 ) 頁： 491 - 496 2023年7月

Photocatalytic Desulfonylative Homocoupling of Benzylic Sulfone Derivatives 招待有り査読有り国際共著

Ohkura, R; Ohtsuka, M; Yim, JCH; Nambo, M; Crudden, CM

SYNLETT 34 巻 ( 01 ) 頁： 81 - 85 2023年1月

Desulfonylative Coupling of Alkylsulfones with gem-Difluoroalkenes by Visible-Light Photoredox Catalysis 査読有り国際共著

Nambo, M; Ghosh, K; Yim, JCH; Tahara, Y; Inai, N; Yanai, T; Crudden, CM

ACS CATALYSIS 12 巻 ( 15 ) 頁： 9526 - 9532 2022年8月

NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters 査読有り国際共著 Open Access

Lummis, PA; Osten, KM; Levchenko, T; Hazer, MSA; Malola, S; Owens-Baird, B; Veinot, AJ; Albright, EL; Schatte, G; Takano, S; Kovnir, K; Stamplecoskie, KG; Tsukuda, T; Häkkinen, H; Nambo, M; Crudden, CM

JACS AU 2 巻 ( 4 ) 頁： 875 - 885 2022年4月

Desulfonylative Transformations of Sulfones by Transition-Metal Catalysis, Photocatalysis, and Organocatalysis 査読有り国際共著

Nambo, M; Maekawa, Y; Crudden, CM

ACS CATALYSIS 12 巻 ( 5 ) 頁： 3013 - 3032 2022年3月

Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape 査読有り国際共著

Man, RWY; Yi, H; Malola, S; Takano, S; Tsukuda, T; Häkkinen, H; Nambo, M; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 144 巻 ( 5 ) 頁： 2056 - 2061 2022年2月

Sequential Transformations of Organosulfones on the Basis of Properties of Sulfonyl Groups 査読有り

Nambo, M; Crudden, CM

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 80 巻 ( 3 ) 頁： 222 - 231 2022年

Transition Metal-Catalyzed Cross-Couplings of Benzylic Sulfone Derivatives 招待有り査読有り国際共著国際誌

Nambo, M; Crudden, CM

CHEMICAL RECORD 21 巻 ( 12 ) 頁： 3978 - 3989 2021年12月

Borenium-Catalyzed Reduction of Pyridines through the Combined Action of Hydrogen and Hydrosilane 査読有り国際共著

Clarke, JJ; Maekawa, Y; Nambo, M; Crudden, CM

ORGANIC LETTERS 23 巻 ( 17 ) 頁： 6617 - 6621 2021年9月

Synthesis and enantioseparation of chiral Au13 nanoclusters protected by bis-N-heterocyclic carbene ligands 査読有り国際共著 Open Access

Yi, H; Osten, KM; Levchenko, TI; Veinot, AJ; Aramaki, Y; Ooi, T; Nambo, M; Crudden, CM

CHEMICAL SCIENCE 12 巻 ( 31 ) 頁： 10436 - 10440 2021年8月

Synthesis of quaternary centres by single electron reduction and alkylation of alkylsulfones 査読有り国際共著国際誌 Open Access

Nambo, M; Tahara, Y; Yim, JCH; Yokogawa, D; Crudden, CM

CHEMICAL SCIENCE 12 巻 ( 13 ) 頁： 4866 - 4871 2021年4月

Alkyltriflones in the Ramberg-Backlund Reaction: An Efficient and Modular Synthesis of gem-Difluoroalkenes 査読有り国際共著国際誌

Maekawa, Y; Nambo, M; Yokogawa, D; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 142 巻 ( 37 ) 頁： 15667 - 15672 2020年9月

Synthesis and properties of an Au6cluster supported by a mixed N-heterocyclic carbene-thiolate ligand 査読有り国際共著

Salorinne, K; Man, RWY; Lummis, PA; Hazer, MSA; Malola, S; Yim, JCH; Veinot, AJ; Zhou, WX; Häkkinen, H; Nambo, M; Crudden, CM

CHEMICAL COMMUNICATIONS 56 巻 ( 45 ) 頁： 6102 - 6105 2020年6月

Modular synthesis of α-fluorinated arylmethanes via desulfonylative cross-coupling 査読有り国際共著 Open Access

Masakazu Nambo, Jacky C.-H. Yim, Luiza B, O. Freitas, Yasuyo Tahara, Zachary T. Ariki, Yuuki Maekawa, Daisuke Yokogawa, Cathleen M. Crudden

Nature Communications 10 巻 ( 1 ) 頁： 4528 2019年10月

Pyridine-catalyzed desulfonative borylation of benzyl sulfones 査読有り国際共著

Maekawa, Y; Ariki, ZT; Nambo, M; Crudden, CM

ORGANIC & BIOMOLECULAR CHEMISTRY 17 巻 ( 31 ) 頁： 7300 - 7303 2019年8月

Copper-catalyzed Desulfonylative Cross-coupling of Benzhydryl Sulfones with Azoles 査読有り国際共著国際誌

Yim, JCH; Nambo, M; Tahara, Y; Crudden, CM

CHEMISTRY LETTERS 48 巻 ( 8 ) 頁： 975 - 977 2019年8月

N-heterocyclic carbene-functionalized magic-number gold nanoclusters 査読有り国際共著 Open Access

Narouz, MR; Osten, KM; Unsworth, PJ; Man, RWY; Salorinne, K; Takano, S; Tomihara, R; Kaappa, S; Malola, S; Dinh, CT; Padmos, JD; Ayoo, K; Garrett, PJ; Nambo, M; Horton, JH; Sargent, EH; Häkkinen, H; Tsukuda, T; Crudden, CM

NATURE CHEMISTRY 11 巻 ( 5 ) 頁： 419 - 425 2019年5月

Cu-Catalyzed Desulfonylative Amination of Benzhydryl Sulfones 査読有り国際共著

Nambo, M; Tahara, Y; Yim, JCH; Crudden, CM

CHEMISTRY-A EUROPEAN JOURNAL 25 巻 ( 8 ) 頁： 1923 - 1926 2019年2月

Ultrastable Gold Nanoparticles Modified by Bidentate N-Heterocyclic Carbene Ligands. 査読有り国際共著

Man RWY, Li CH, MacLean MWA, Zenkina OV, Zamora MT, Saunders LN, Rousina-Webb A, Nambo M, Crudden CM

Journal of the American Chemical Society 140 巻 ( 5 ) 頁： 1576 - 1579 2018年2月

Preparation of Quaternary Centers via Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Tertiary Sulfones 査読有り国際共著国際誌

Ariki, ZT; Maekawa, Y; Nambo, M; Crudden, CM

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140 巻 ( 1 ) 頁： 78 - 81 2018年1月

Synthesis of Tetraarylmethanes by the Triflic Acid-Promoted Formal Cross-Dehydrogenative Coupling of Triarylmethanes with Arenes 査読有り国際共著国際誌 Open Access

Nambo, M; Yim, JCH; Fowler, KG; Crudden, CM

SYNLETT 28 巻 ( 20 ) 頁： 2936 - 2940 2017年12月

Pd-Catalyzed Desulfonative Cross-Coupling of Benzylic Sulfone Derivatives with 1,3-Oxazoles 査読有り国際共著国際誌

Yim, JCH; Nambo, M; Crudden, CM

ORGANIC LETTERS 19 巻 ( 14 ) 頁： 3715 - 3718 2017年7月

Water-Soluble N-Heterocyclic Carbene-Protected Gold Nanoparticles: Size-Controlled Synthesis, Stability, and Optical Properties 査読有り国際共著国際誌 Open Access

Salorinne, K; Man, RWY; Li, CH; Taki, M; Nambo, M; Crudden, CM

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56 巻 ( 22 ) 頁： 6198 - 6202 2017年5月

Development of Versatile Sulfone Electrophiles for Suzuki-Miyaura Cross-Coupling Reactions 査読有り国際共著国際誌

Nambo, M; Keske, EC; Rygus, JPG; Yim, JCH; Crudden, CM

ACS CATALYSIS 7 巻 ( 2 ) 頁： 1108 - 1112 2017年2月

Combination of Synthetic Chemistry and Live-Cell Imaging Identified a Rapid Cell Division Inhibitor in Tobacco and Arabidopsis thaliana 査読有り Open Access

Nambo, M; Kurihara, D; Yamada, T; Nishiwaki-Ohkawa, T; Kadofusa, N; Kimata, Y; Kuwata, K; Umeda, M; Ueda, M

PLANT AND CELL PHYSIOLOGY 57 巻 ( 11 ) 頁： 2255 - 2268 2016年11月

Arylative Desulfonation of Diarylmethyl Phenyl Sulfone with Arenes Catalyzed by Scandium Triflate 査読有り国際共著国際誌

Nambo, M; Ariki, ZT; Canseco-Gonzalez, D; Beattie, DD; Crudden, CM

ORGANIC LETTERS 18 巻 ( 10 ) 頁： 2339 - 2342 2016年5月

Iterative protecting group-free cross-coupling leading to chiral multiply arylated structures 査読有り国際共著 Open Access

Crudden, CM; Ziebenhaus, C; Rygus, JPG; Ghozati, K; Unsworth, PJ; Nambo, M; Voth, S; Hutchinson, M; Laberge, VS; Maekawa, Y; Imao, D

NATURE COMMUNICATIONS 7 巻頁： 11065 2016年4月

Recent Advances in the Synthesis of Triarylmethanes by Transition Metal Catalysis 査読有り国際共著国際誌

Nambo, M; Crudden, CM

ACS CATALYSIS 5 巻 ( 8 ) 頁： 4734 - 4742 2015年8月

The Concise Synthesis of Unsymmetric Triarylacetonitriles via Pd-Catalyzed Sequential Arylation: A New Synthetic Approach to Tri- and Tetraarylmethanes 査読有り国際共著国際誌

Nambo, M; Yar, M; Smith, JD; Crudden, CM

ORGANIC LETTERS 17 巻 ( 1 ) 頁： 50 - 53 2015年1月

Modular synthesis of triarylmethanes through palladium-catalyzed sequential arylation of methyl phenyl sulfone. 査読有り国際共著

Nambo M, Crudden CM

Angewandte Chemie (International ed. in English) 53 巻 ( 3 ) 頁： 742 - 6 2014年1月

Modular Synthesis of Triarylmethanes through Palladium-Catalyzed Sequential Arylation of Methyl Phenyl Sulfone 査読有り

Masakazu Nambo, Cathleen M. Crudden

Angewandte Chemie International Edition 53 巻 ( 3 ) 頁： 742-746 2014年1月

担当区分：筆頭著者記述言語：英語掲載種別：研究論文（学術雑誌）

Triarylmethanes, which are valuable structures in materials, sensing and pharmaceuticals, have been synthesized starting from methyl phenyl sulfone as an inexpensive and readily available template. The three aryl groups were installed through two sequential palladium-catalyzed C-H arylation reactions, followed by an arylative desulfonation. This method provides a new synthetic approach to multisubstituted triarylmethanes using readily available haloarenes and aryl boronic acids, and is also valuable for the preparation of unexplored triarylmethane-based materials and pharmaceuticals.

DOI： 10.1002/anie.201307019

Modular Synthesis of Triarylmethanes through Palladium-Catalyzed Sequential Arylation of Methyl Phenyl Sulfone 査読有り

Nambo, Masakazu, Crudden, Cathleen M.

Angewandte Chemie-International Edition 53 巻 ( 3 ) 頁： 742 - 746 2014年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：WILEY-V C H VERLAG GMBH

DOI： 10.1002/anie.201307019

Web of Science

Palladium-catalyzed tetraallylation of C60 with allyl chloride and allylstannane: mechanism, regioselectivity, and enantioselectivity 査読有り

Nambo, M; Wakamiya, A; Itami, K

CHEMICAL SCIENCE 3 巻 ( 12 ) 頁： 3474 - 3481 2012年12月