Updated on 2021/10/14

写真a

 
SHIN Jiyoung
 
Organization
Graduate School of Engineering Graduate School of Engineering Professor
Graduate School
Graduate School of Engineering
Undergraduate School
School of Engineering Chemistry and Biotechnology
Title
Professor
Profile
Ji-Young Shin is a professor of the Engineering Graduate School at Nagoya University, Nagoya, Japan. She received her Ph.D. (research supervisor: professor Atsuhiro Osuka) at Kyoto University, Kyoto, Japan, in 2001. She did postdoctoral and research associate fellowships at the University of British Columbia (UBC), Vancouver, Canada (research director: Professor David Dolphin), and research at Pohang University of Science and Technology (Postech), Korea (research director: professor Kimono Kim), then Nagoya University Japan. Since 2019, she has been a tenured professor at Nagoya University. Her research laboratory focuses on the electronic and magnetic properties of organic compounds and metal-organic complexes and the exploration of novel functional molecules created with polypyrrolyl oligomers.

Degree 1

  1. Doctor (Science) ( 2001.7   Kyoto University ) 

Current Research Project and SDGs 2

  1. Exploration of facile synthesis for functional porphyrinoids and investigation of their applications

  2. Self-healing antiaromatic batteries

Research History 4

  1. Nagoya University

    2017.9

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    Country:Japan

  2. Designated Associate Professor, Graduate School of Engineering (G30 program), Nagoya University

    2011.9 - 2017.8

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    Country:Japan

  3. Research Assistant Professor, Division of Advance Material Science, Pohang University of Science & Technology

    2009.9 - 2011.8

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    Country:Korea, Republic of

  4. Research Associate, Department of Chemistry, University of British Columbia (UBC)   Research Associate

    2006.1 - 2009.8

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    Country:Canada

Education 1

  1. Kyoto University   Graduate School, Division of Natural Science   Organic Chemistry

    1998.4 - 2001.7

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    Country: Japan

Professional Memberships 4

  1. American Chemical Society   Member

  2. Chemical Society of Japan   member

  3. Royal Society of Chemistry   member

  4. Society of Porphyrins and Phthalocyanines

 

Papers 51

  1. Dual-Ion NiNc battery: A Sustainable Revolution for Sodium Organic Batteries Reviewed

    Jinkwang Hwang, Kazuhiko Matsumoto, Rika Hagiwara, Shusaku Ukai, Hiroshi Shinokubo, Ji-Young Shin

    Batteries and Supercaps   Vol. 4 ( 10 ) page: 1605 - 1610   2021.8

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    DOI: 10.1002/batt.202100193

  2. Dual-ion charge-discharge behaviors of Na-NiNc and NiNc-NiNc batteries Reviewed

    Jinkwang Hwang, Rika Hagiwara, Hiroshi Shinokubo, Ji-Young Shin

    Materials Advances   Vol. 2   page: 2263 - 2266   2021.3

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    Authorship:Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D1MA00007A

  3. Exquisite chemistries of meso-pentafluorophenyl and meso- (2,6-dichlorophenyl) dipyrromethanes Invited Reviewed

    Ji-Young Shin, An Quang Nguyen

    Journal of Porphyrins and Phthalocyanines     2021.12

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  4. The synthesis and characterization of the octahedral CoIII complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin Reviewed

    Ji-Young Shin

    RSC Advances   Vol. 11 ( 4 ) page: 2015 - 2019   2021.1

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    Authorship:Lead author, Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D0RA09452H

  5. Reactions of Antiaromatic Norcorrole Ni(II) Complex with Carbenes Reviewed

    Si-Yu Liu, Takaki Fukuoka, Norihito Fukui, Ji-Young Shin, Hiroshi Shinokubo

    Organic Letters   Vol. 22 ( 11 ) page: 4400 - 4403   2020.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.orglett.0c01402

  6. Meso-1,4-phenylene bridged nickel norcorrole dimer Invited Reviewed

    Ji-Young Shin

    Journal of Porphyrins and Phthalocyanines   Vol. 24   page: 181 - 190   2020.1

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    Authorship:Lead author, Last author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1142/S1088424619501074

  7. Synthesis of pyrrolo[3',2':4,5][1,3]diazepino[2,1,7- cd]pyrrolizine derivatives from dicyanovinylene- bis(meso-aryl)dipyrrin Reviewed

    Ji-Young Shin

    RSC Advances   Vol. 9 ( 68 ) page: 40031 - 40036   2019.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c9ra08850d

  8. Exploration of Li-organic batteries using hexaphyrin as an active cathode material Invited Reviewed

    Ji-Young Shin, Zhongyue Zhang, Kunio Awaga, Hiroshi Shinokubo

    Molecules   Vol. 24 ( 13 ) page: 2433   2019.7

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/molecules24132433

  9. Highly-conducting molecular circuits based on antiaromaticity Reviewed

    Shintaro Fujii, Santiago Marques-Gonzalez, Ji-Young Shin, Hiroshi Shinokubo, Takuya Masuda, Tomoaki Nishino, Narendra P. Arasu, Hector Vazquez, Manabu Kiguchi

    Nature Communications   Vol. 8   2017.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/ncomms15984

  10. A synthesis of novel expanded porphyrinoids: NiII- induced nitrile cyclization of dicyanovinylene-bis (meso-aryl)dipyrrin Reviewed

    Nathan H. Faialaga, Satoru Ito, Hiroshi Shinokubo, Younghoon Kim, Kimoon Kim, Ji-Young Shin

      Vol. 46 ( 33 ) page: 10802 - 10808   2017.6

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    DOI: 10.1039/c7dt01838j

  11. E-Bodipy fluorescent chemosensor for Zn2+ ion

    Indranil Roy, Ji-Young Shin, Dinesh Shetty, Jayshree K. Khedkar, Jun Heuk Park, Kimoon Kim

    Journal of Photochemistry and Phtobiology A:Chemistry   Vol. 331   page: 233 - 239   2016.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.photochem.2015.08.015

  12. Staked antiaromatic porphyrins Reviewed

    Ryo Nozawa, Hiroko Tanaka, Won-Young Cha, Yonseok Hong, Ichiro Hisaki, Soji Shimizu, Ji-Young Shin, Tim Kowalczyk, Stephan Irle, Dongho Kim, hiroshi Shinokubo

    Nature Communications     2016.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1038/ncomms13620

  13. Ni(II) tetrahydronocorroles: antiaromatic porphyrinoids with saturated pyrrole units

    Ryo Nozawa, Keitaro Yamamoto, Ichiro Hisaki, Ji-Young Shin, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 52 ( 44 ) page: 7106 - 7109   2016.9

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    DOI: 10.1039/C6CC02918C

  14. Regioselective Nucleophilic Functionalization of Antiaromatic Nickel(II) Norcorroles

    Ryo Nozawa, Keitaro Yamamoto, Ji-Young Shin, Satoru Hiroto, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 54 ( 29 ) page: 8454 - 8457   2015.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201502666

  15. Macrocyclic dipyrrin dimer bridged by ethylene and dioxyphenylene linkers

    Ji-Young Shin, Satoru Hiroto, Hiroshi Shinokubo

    Journal of Porphyrins and Phthalocyanines   Vol. 19 ( 01n03 ) page: 135 - 139   2015.1

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    DOI: 10.1142/S108842461450093X

  16. A 3-Pyridyl-5,15-Diazaporphyrin Nickel(II) Complex as a Bidentate Metalloligand for Transition Metals

    Ayaka Yamaji, Ji-Young Shin, Yoshihiro Miyake. Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 53 ( 50 ) page: 13924 - 13927   2014.12

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  17. Synthesis, reactivity and property of 5,15-dithiaporphyrin copper(II) complex

    Naruhiko Wachi, Takeshi Kondo, Satoru Ito, Ji-Young Shin, Hiroshi Shinokubo

    Journal of Porphyrins and Phthalocyanines   Vol. 18 ( 09 ) page: 675 - 678   2014.9

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  18. Ring and Volcano Structures Formed by a Metal Dipyrromethene Complex

    Seung Bae Son, Qing Miao, Ji-Young Shin, David Dolphin, Jae Ryang Hahn

    Bulletin of the Korean Chemical Society   Vol. 35 ( 6 ) page: 1727 - 1731   2014.6

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  19. Photodynamics of [26]- and [28]hexaphyrin-bodipy hybrids

    Ji-Young Shin, Kilsuk Kim, Jong Min Lim, Takayuki Tanaka, Dongho Kim, Kimoon Kim, Hiroshi Shinokubo, Atsuhiro Osuka

    Chemistry-A European Journal   Vol. 20 ( 16 ) page: 4574 - 4582   2014.4

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201400315

  20. An Antiaromatic Electrode- Active Material Enabling High Capacity and Stable Performance of Rechargeable Batteries

    Ji-Young Shin, Tetsuya Yamada, Hirofumi Yoshikawa, Kunio Awaga, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 53 ( 12 ) page: 3096 - 3101   2014.3

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    DOI: 10.1002/anie.201310374

  21. Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole

    Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 53 ( 6 ) page: 1506 - 1509   2014.2

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  22. Selective Synthesis of a [32]Octaphyrin(1.0.1.0.1.0.1.0) Bis(palladium) Complex by a Metal-Templated Strategy

    Hiromitsu Kido, Ji-Young Shin, Hiroshi Shinokubo

    Angew. Chem. Int. Ed.   Vol. 52 ( 51 ) page: 13727 - 13730   2013.10

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    DOI: 10.1002/anie.201306905

  23. Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins

    Ayaka Yamaji, Satoru hiroto, Ji-Young Shin, hiroshi Shinokubo

    Chemical Communication   Vol. 49 ( 44 ) page: 5064 - 5066   2013.4

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    DOI: 10.1039/C3CC41907J

  24. Gram-Scale Synthesis of Nickel(II) Norcorrole: The Smallest Antiaromatic Porphyrinoid Reviewed

    Tomohiro Ito, Yosuke Hayashi, Soji Shimizu, Ji-Young Shin, Nagao Kobayashi, Hiroshi Shinokubo

    Angewandte Chemie International Edition   Vol. 51 ( 34 ) page: 8542 - 8545   2012.8

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    A ring-contracted sister of porphyrin, norcorrole, has been synthesized efficiently as a stable molecule by a nickel-templated strategy. The norcorrole complex is stable but exhibits a distinct antiaromatic character according to the Hückel rule. Oxidation of the norcorrole complex provides an aromatic oxacorrole complex.

    DOI: 10.1002/anie.201204395

  25. Synthesis of a class of 5-((5-(pyrrol-2-yl-methylene)-pyrrol-2-yl)methylene)- furan-2-ones and the formation of a furanone dipyrrin imino ether Reviewed

    Ji-Young Shin, David Dolphin

    New Journal of Chemistry   Vol. 35 ( 11 ) page: 2483 - 2487   2011.11

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    A class of a-furanyl dipyrrins 2 were prepared by refluxing THF solutions of DDQ adducts 1 with the appropriate alcohols in the presence of AlCl3 and further subsequent reaction of the cyano-group results in the formation of an imino ether upon MeOH addition.

    DOI: 10.1039/C1NJ20415G

  26. Structural Studies of the Self-Assemblies Created with Dipyrrins Reviewed

    Ji-Young Shin, Brian O. Patrick, Seung Bae Son, Jae Ryang Hahn, David Dolphin

    Bulletin of the Korean Chemical Society   Vol. 31 ( 4 ) page: 1004 - 1012   2010.4

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    Three-dimensional superstructures of unique self-assemblies generated by exploring the conformational flexibility of various dipyrromethenes through creation of hydrogen-bonds with metal-halide anions are reported and the conformational diversity is thoroughly described in the solid and in solution by X-ray diffraction anal. and variable temperature NMR spectroscopy. The tetrahedral or octahedral structures of their precursors, various metal-dipyrromethene complexes, are also reported, based on the crystallographic data. STM images of the self-assemblies observed on graphite surfaces present interesting arrangements and appear as tubular bunches.

    DOI: 10.5012/bkcs.2010.31.4.1004

  27. BODIPY-hexaphyrin hybrids Reviewed

    Ji-Young Shin, Takayuki Tanaka, Atsuhiro Osuka, Qing Miao, David Dolphin

    Chemistry-A European Journal   Vol. 15 ( 47 ) page: 12955 - 12959   2009.12

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    BODIPY-appended [28]- and [26]hexaphyrins (see figure) were prepared and the efficient intramolecular excitation energy transfer from the BODIPY part to the hexaphyrin part was revealed in both hybrids. Importantly this is the first example of the intramolecular energy transfer with a Möbius aromatic [28]hexaphyrin as an energy acceptor.

    DOI: 10.1002/chem.200902407

  28. Linear fully-conjugated meso-aryl pentaphyrin Reviewed

    Ji-Young Shin, Steven S. Hepperle, David Dolphin

    Tetrahedron Letters   Vol. 50 ( 49 ) page: 6909 - 6912   2009.12

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    A meso-2,6-dichlorophenyl pentapyrrin was prepared using a modified method for dipyrrane synthesis followed by simple DDQ oxidation. The fully conjugated structures formed via redox inter-conversions were studied using crystallographic as well as observed and calculated spectral data.

    DOI: 10.1016/j.tetlet.2009.09.145

  29. Observation of coexistence of 1D and 2D nanostructures in cobalt dipyrromethene trimer complexes adsorved on a graphite surface Reviewed

    Sung Bae Son, Su Jin Kee, Jae Ryang Hahn, Li Ma, Ji-Young Shin, David Dolphin

    Applied Surface Science   Vol. 259 ( 4 ) page: 1176 - 1179   2009.11

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  30. Facile synthesis of dicyanovinyl-di(meso-aryl)dipyrromethenes via a dipyrromethene-DDQ adduct Reviewed

    Ji-Young Shin, Brian O. Patrick, David Dolphin

    Organic and Biomolecular Chemistry   Vol. 7 ( 10 ) page: 2032 - 2035   2009.5

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    The dicyano-substituted vinyl dipyrromethene 4 and com- pound 5 are near-planar and were prepared from a simple meso-aryl dipyrromethane via the DDQ adduct 3; the unique structures of 3, 4 and 5 were confirmed by X-ray diffraction analysis.

    DOI: 10.1039/b904446a

  31. Oxidized forms of triyrrane: alpha-tripyrrinone, beta-tripyrrinone and C2 symmetric hexapyrrole Reviewed

    Ji-Young Shin, Steven S. Hepperle, Brian O. Patrick, David Dolphin

    Chemical Communication   Vol. 2009 ( 17 ) page: 2323 - 2325   2009.5

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    Alpha- and beta-tripyrrinone isomers and a C2 symmetric hexapyrrole were isolated from the oxidation of meso-perfluorophenyl tripyrrane withDDQ under aerobic conditions, and the structure of the alpha-triyrrinone was determined by X-ray crystallographic analysis.

    DOI: 10.1039/b901171b

  32. Self-assembly of oligomeric linear dipyrromethene metal complexes Reviewed

    Qing Miao, Ji-Young Shin, Brian O. Patrick, David Dolphin

    Chemical Communication     page: 2541 - 2543   2009.5

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    BF2 capped dipyrrin dimers were synthesized and have been used to terminate oligomerization to form a series of controlled length oligomers; the crystal structures of the metal complexes were investigated and correlations between the structures and optical properties were established.

    DOI: 10.1039/b820461f

  33. facile synthesis of unsubstituted beta,beta'-linked diformyldipyrromethanes Reviewed

    Zhan Zhang, Ji-Young Shin, David Dolphin

    Journal of Organic Chemistry   Vol. 73 ( 23 ) page: 9515 - 9517   2008.12

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    Unsubstituted beta,beta'-linked diformyldipyrromethanes are promising precursors for the synthesis of novel poly dipyrromethene ligands and N-confused porphyrins. A strategy has been developed to selectively synthesize unsubstituted beta,beta'-linked diformyldipyrromethanes in moderate yields starting from 2-formylpyrrole.

    DOI: 10.1021/jo802114h

  34. Metal Complexes of dipyrromethenes linked by rigid spacer arms Reviewed

    Li Ma, Ji-Young Shin, Brian O. Patrick, David Dolphin

    Crystal Engineering Communication   Vol. 10 ( 11 ) page: 1531 - 1533   2008.11

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    Metal complexes using ligands where two terminal dipyrromethenes are connected by rigid spacers, having different dihedral angles, show unique macrocyclic structures which contain large cavities in their centers and produce crystals with tunnels of varying structures depending upon their crystal packing motifs.

    DOI: 10.1039/b814586e

  35. Self-assembly via intermolecular hydrogen-bonding between o-/m-/p-NH2 and BF2 groups on dipyrromethenes Reviewed

    Ji-Young Shin, Brian O. Patrick, David Dolphin

    Tetrahedron Letters   Vol. 49 ( 38 ) page: 5515 - 5518   2008.9

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    Boron difluoride dipyrromethenes bearing configurationally different amine groups on a meso-phenyl ring were prepared and crystallized. The ortho- and para-amino groups allow the phenyl group to inductively release greater electron density into the dipyrromethenes resulting in relatively strong inter- molecular hydrogen-bonding with the terminal BF2 groups, whereas the meta-analog formed weaker hydrogen-bonds. The intensities of the 1H NMR peaks in concentrated solutions all increased with F-decoupling.

    DOI: 10.1016/j.tetlet.2008.07.045

  36. Conformational flexibility of dipyrromethenes: supramolecular assemblies with hydroquinones Reviewed

    Ji-Young Shin, Brian O. Patrick, David Dolphin

    Crystal Engineering Communication   Vol. 10 ( 8 ) page: 1539 - 1541   2008.8

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    The structure of a self-assembled system containing a protonated dipyrromethene with deprotonated/reduced dichlorodicyanoquinone (DDQ) was determined by X-ray diffraction analysis. The assembly exhibits a highly hydrogen-bonded structure, with an unusual asymmetric conformation for the dipyrromethene.

    DOI: 10.1039/b800367j

  37. Structure, formation and catalytic studies of a meso palladioporphyrin intermediate in a heck coupling Reviewed

    Michael M. Jang, Ji-Young Shin, Brian O. Patrick, David Dolphin

    Dalton Transaction     page: 2598 - 2062   2008.5

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    A meso-palladioporphyrin intermediate was isolated from a Heck reaction between an iodoporphyrin and a non-activated olefin using a Pd(PPh3)2Cl2/Et3N system; its structure was characterized by NMR, MS and X-ray crystallography. Studies on its formation indicate that the Pd(II) catalyst was reduced in situ by Et3N with the assistance of water. The catalytic activity of the intermediate was confirmed by stoichiometric and catalytic reactions using a more reactive olefin, ethyl acrylate.

    DOI: 10.1039/b801163j

  38. Facile synthesis of large meso-pentafluorophenyl-substituted expanded porphyrin Reviewed

    Yashuo Tanaka, Ji-Young Shin, Atsuhiro Osuka

    European Journal of Organic Chemistry     page: 1341 - 1349   2008.3

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    Acid-catalyzed condensation of meso-pentafluorophenyl di- pyrromethane and pentafluorobenzaldehyde at 0 degrees gave a series of expanded porphyrins with even number of pyrrolic subunits up to octadecaphyrin(1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1) in improved yields, particularly for larger expanded porphyrins. The solid-state structure of decaphyrin(1.1.1.1.1.1.1.1.1.1) was revealed by X-ray diffraction analysis to be a crescent-like conformation. The Soret-like absorption bands are increasingly redshifted as the size of the ring increases, but such a trend becomes nearly saturated for hexadecaphyrins (1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1) which exhibit bands in the near-infrared region at 939 and 953 nm, respectively.

    DOI: 10.1002/ejoc.200701132

  39. Möbius aromaticity in N-fused [24]pentaphyrin upon Rh(I) metalation Reviewed

    Jong Kang Park, Zin Seok Yoon, Min-Chul Yoon, Kil Suk Kim, Shegeki Mori, Ji-Young Shin, Atsuhiro Osuka, Dongho Kim

    Journal of the American Chemical Society   Vol. 130 ( 6 ) page: 1824 - 1825   2008.2

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    NFP5s are interesting platfroms to realize Huckel aromaticity, Huckel antiaromaticity, and Moebius aromaticity depending on the number of pai-electrons, meso-substituent, and metalation. Rh-[24]NFP5 has been comfirmed as a Moebius aromatic molecule by the crystal structure, 1H NMR spectrum, NICS calculation, and TPA cross-section values. This molecule is the smallest Moebius aromatic system with distinct diatropic ring current.

    DOI: 10.1021/ic7004216

  40. Group 12 metal complexes of [26]hexaphyrin(1,1,1,1,1,1) Reviewed

    Shigeki Mori, Soji Shimizu, Ji-Young Shin, Atsuhiro Osuka

    Inorganic Chemistry   Vol. 46 ( 11 ) page: 4374 - 4376   2007.5

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  41. New Zn complexes derivatives for red OLEDs host materials Reviewed

    Ae-Ran Hyun, Soo-Kang Kim, In-Nam Kang, Jong-Wook Pack, Ji-Young Shin, OK-Keun Son

    Molecular Crystal and Liquid Crystal   Vol. 463   page: 33 - 39   2007.2

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    New two metal complexes, di-(Phenyl dipyrrylmethene)zinc (Zn(PPM)2) and di-(Pentafluorophenyl dipyrrylmethene)zinc (Zn(PFPPM)2) as a host material instead of Alq3 were synthesized. To evaluate electroluminescent properties, multi- layered organic light-emitting devices were fabricated by using 4-(dicyanomethy- lene)-2-tert-buthyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) as a dopant and Alq3 as an electron transporting layer. Alq3 and Zn(PPM)2 host EL devices exhibited DCJTB emission peak at around 617 nm due to energy transfer from Alq3 and Zn(PPM)2 to DCJTB. However Zn(PFPPM)2 host device shows no DCJTB emission peak because Zn(PFPPM)2 device emit EL light of 563 and 700 nm. The Zn(PPM)2 device showed same luminance efficiency as Alq3 device, but showed better power efficiency of 1.2 times than Alq3 device.

    DOI: 10.1080/15421400601021471

  42. N-fused Pentaphyrins and Their Rhodium Complexes: Oxidation-Induced Rhodium Rearrangement Reviewed

    Shigeki Mori, Ji-Young Shin, Soji Shimizu, Fumiaki Ishikawa, Hiroyuki Furuta, Atsuhiro Osuka

    Chemistry-A European Journal   Vol. 11 ( 8 ) page: 2417 - 2425   2005.4

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    meso-Aryl-substituted pentaphyrins were isolated in the modified Rothemund-Lindsey porphyrin synthesis and a [22]NFP5 and [24]NFP5, which were reversibly interconvertible by means of two electron reduction with NaBH4 or two-electron oxidation with DDQ. Judging from 1H NMR data, [22]NFP5 is aromatic and possesses a diatropic ring current, while [24]NFP5 exhibits partial antiaromatic character. Metalation of [22]NFP5 with rhodium(I) salt led to isolation of rhodium complexes, whose structures were unambiguously characterized by X-ray diffraction analyses and were assigned as conjugated 24- and 22-pai electronic systems, respectively. Upon the treatment with DDQ, those are interconvertible with an unprecedented rearrangement of the rhodium atom.

    DOI: 10.1002/chem.200401042

  43. Protonated Dipyrromethenes and Tetrahalozinc Anions as Synthons in the Solid State Reviewed

    Ji-Young Shin, David Dolphin, Brian, O. Patrick

    Crystal Growth & Design   Vol. 4 ( 4 ) page: 659 - 661   2004.6

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    (HL)2ZnBr4 and (HL)2ZnCl4 were prepared by the addition of HBr and Hcl into a acetonitrile solution of Zn(II)L2, and their structures were determined by X-ray diffraction analysis. The X-ray crystallographic data show super structures that have hydrogen bonds between the terahalozinc anions and the protonated dipyrromethene cations.

    DOI: 10.1021/cg049979g

  44. Regioselective nucleophilic substitution reaction of meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin

    Masaaki Suzuki, Soji Shimizu, Ji-Young Shin, Atsuhiro Osuka

    Tetrahedron Letters   Vol. 44 ( 24 ) page: 4597 - 4601   2003.6

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  45. Ring size selective synthesis of meso-aryl expanded porphyrins

    Ryuichiro Taniguchi, Soji Shimizu, Masaaki Suzuki, Ji-Young Shin, Hiroyuki Furuta, Atsuhiro Osuka

    Tetrahedron Letters   Vol. 44 ( 12 ) page: 2505 - 2507   2003.3

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  46. Perfluorinated meso-Aryl Substituted Expaned Porphyrins Reviewed

    Soji Shimizu, Ji-Young Shin, Hiroyuki Furuta, Rami Ismael, Atsuhiro Osuka

    Angewandte Chemie International Edition   Vol. 42 ( 1 ) page: 78 - 82   2003.1

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    A ring-contracted sister of porphyrin, norcorrole, has been synthesized efficiently as a stable molecule by a nickel-templated strategy. The norcorrole complex is stable but exhibits a distinct antiaromatic character according to the Hückel rule. Oxidation of the norcorrole complex provides an aromatic oxacorrole complex.

    DOI: 10.1002/anie.200390058

  47. meso-Aryl Substituted Expanded Porphyrins

    Ji-Young Shin, Hiroyuki Furuta, Kenji Yoza, Shinetsu Igarashi, Atsuhiro Osuka

    Journal of the American Chemical Society   Vol. 123 ( 29 ) page: 7190-7191   2001.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja0106624

  48. N-Fused Pentaphyrin Reviewed

    Ji-Young Shin, Hiroyuki Furuta, Atsuhiro Osuka

    Angewandte Chemie International Edition   Vol. 40 ( 3 ) page: 619 - 621   2001.2

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    Language:English   Publishing type:Research paper (scientific journal)  

    A ring-contracted sister of porphyrin, norcorrole, has been synthesized efficiently as a stable molecule by a nickel-templated strategy. The norcorrole complex is stable but exhibits a distinct antiaromatic character according to the Hückel rule. Oxidation of the norcorrole complex provides an aromatic oxacorrole complex.

    DOI: 10.1002/1521-3773(20010202)40:3<619::AID-ANIE619>3.0.CO;2-X

  49. Orientation Effects on Excited State Dynamics of Zinc Porphyrin-Free Base Porphyrin-Pyromellitimide Triads

    Atsuhiro Osuka, Ji-Young Shin, Ryusho Yoneshima, Hideo Shiratori, Takeshi Ohno, Koichi Nozaki, Yoshinobu Nishimura, Iqao Yamazaki, Seiji Taniguchi, Takenori Shimizu, Tadashi Okada

    Journal of Porphyrins and Phthalocyanines   Vol. 3 ( 8 ) page: 729 - 741   1999.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/(SICI)1099-1409(199912)3:8<729::AID-JPP162>3.0.CO;2-F

  50. An efficient model of cytochrome P-450 monooxygenase reactivity: polymer-supported metalloprotoporphyrin IX (M=Fe, Mn)

    Ji-Young Shin, Kyung-A Kim, Hye Gyun Kim, Insook Rhee Pang, Do-Gyun Kim, Ki-Jung Paeng

    Bulletin of the Korean Chemical Society   Vol. 19 ( 8 ) page: 875 - 878   1998.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  51. Simultaneous observation of Fe-F and F-Fe-F stretching vibrations of fluoride anion ligated tetraphenylporphyrin iron(III) by resonance raman spectroscopy

    Insook Rhee Paeng, Ji-Young Shin, Hakhyun Nam, Do-Gyun Kim, Ki-Jung Paeng

    Bulletin of the Korean Chemical Society   Vol. 18 ( 7 ) page: 730 - 733   1997.7

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    Language:English   Publishing type:Research paper (scientific journal)  

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Presentations 21

  1. Synthesis and Characterization of Octahedral Co(III) Complex of Pyrrolopyrrolizine Derivative International conference

    Ji-Young Shin

    11th International Conference on Porphyrins and Phthalocyanines  2021.7.3  Society of Porphyrins and Phthalocyanines

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Poster presentation  

    Venue:Beffalo, USA   Country:United States  

  2. Nickel(II) Norcorrole (NiNc) Batteries International conference

    Ji-Young Shin

    11th International Conference on Porphyrins and Phthalocyanines  2021.6.28  Society of Porphyrins and Phthalocyanines

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    Event date: 2021.6 - 2021.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Buffalo, USA   Country:United States  

  3. Electrochemistry of Antiaromatic NiNC Invited International conference

    Ji-Young Shin

    NU-PKU Workshop on "solid-State Electrochemistry for Coordination Complexes" 

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    Event date: 2019.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Lecture Hall, Noyori Materials Science Laboratory, Higashiyama Campus, Nagoya University, Japan   Country:Japan  

  4. Contracted and Expanded Porphyrinoids from Dipyrrin Precursors Invited International conference

    Ji-Young Shin

    A3 Joint Seminar 2019 

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    Event date: 2019.1

    Language:English   Presentation type:Poster presentation  

    Venue:Kanpo no Yado Atami, Atami, Japan   Country:Japan  

  5. Some achievements on dipyrrin chemistry

    Ji-Young Shin

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    Event date: 2018.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Royal Hotel Munakata, Fukuoka   Country:Japan  

  6. Synthesis of Novel Expanded Porphyrinoids: Ni(II)-Induced Nitrile Cyclizationof Dicyanovinylene-bis(meso-aryl)dipyrrin International conference

    Ji-Young Shin, Nathan H. Faialaga, Hiroshi Shinokubo

    10th International Conference on Porphyrins and Phthalocyanines (ICCP-10) 

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    Event date: 2018.7

    Language:English   Presentation type:Poster presentation  

    Venue:Munich, Germany   Country:Japan  

  7. Organic Batteries Using Multiple-Oxidation-State Hexaphyrin as an Active Electrode Material

    Ji-Young Shin, Hiroshi Shinokubo, Kunio Awaga

    The 98th CSJ Annual Meeting 

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    Event date: 2018.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Nihon University   Country:Japan  

  8. A study on organic batteries using porphyrinoid electrodes International conference

    Ji-Young Shin

    PreICMM2016 

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    Event date: 2016.9

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  9. Antiaromatic nororrole batteries International conference

    Ji-Young Shin, Tetsuya Yamad, Hirofumi Yoshikawa, Kunio Awaga, Hiroshi Shinokubo

    Pacifichem 2015  

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    Event date: 2015.12

    Language:English   Presentation type:Poster presentation  

    Country:United States  

  10. Antiaromatic Norcorrole Batteries

    Ji-Young Shin, Tetsuya Yamada, Hirofumi Yoshikawa, Kunio Awaga, Hiroshi Shinokubo,

    IGER Workshop on Molecular Electronics for Young Researchers 

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    Event date: 2014.10

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  11. 反芳香族性ノルコロールとシリレンの反応

    福岡 嵩規・内田 健哉・辛 知映 ・石田 真太郎・岩本 武明・忍久保 洋

    第 60 回 有機金属化学討論会 

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    Event date: 2013.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  12. ピリジルジアザポルフィリンを二座配位子として有する遷移金属錯体の合成と物性

    山路文香, 辛 知映, 三宅由寛, 忍久保 洋

    第24回基礎有機化学討論会 

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    Event date: 2013.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  13. meso置換反芳香族性ノルコロールの合成と物性

    木戸 裕允, 田中博子, 辛 知映, 忍久保 洋

    第24回基礎有機化学討論会 

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    Event date: 2013.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  14. 反芳香族性ノルコロールとカルベンの反応

    福岡嵩規、辛 知映、忍久保 洋

    第24回基礎有機化学討論会 

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    Event date: 2013.9

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  15. 反芳香族性ノルコロールの合成と物性

    田中博 子・伊藤智裕・辛 知映・忍久保 洋

    日本化学会第92春季年会 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  16. 反芳香族性ノルコロールとシリレンおよびカルベンの反応

    福岡嵩規, 辛 知映, 内田健哉, 石田真太郎, 岩本武明, 忍久保 洋

    日本化学会第92春季年会 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  17. ジアザポルフィリンの外部配位金属錯体の合成とその物性

    山路文香, 辛 知映, 忍久保 洋

    日本化学会第92春季年会 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  18. ジピリン金属錯体を用いた[32]オクタフィリン(1.0.1.0.1.0.1.0) 金属錯体の合成

    木戸裕允, 辛 知映, 忍久保 洋

    日本化学会第92春季年会 

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    Event date: 2013.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  19. DDQ-oxidation of meso-aryl polypyrranes and the novel products International conference

    Ji-Young Shin, Hiroshi Shinokubo, David Dolphin

    7th International Conference on Porphyrins and Phthalocyanines 

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    Event date: 2012.7

    Language:English   Presentation type:Oral presentation (general)  

    Country:Korea, Republic of  

  20. Novel polypyrrole derivatives obtained from DDQ oxidation of dipyrromethanes

    Jiyoung Shin, Hiroshi Shinokubo

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    Event date: 2012.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  21. Energy Transfer Dynamics of [26] /[28]Hexaphyrin-Bodipy Hybrids

    Jiyoung Shin, Kilsuk Kim, Jong Min Lim, Kimoon Kim, Dongho Kim

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    Event date: 2012.3

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

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Teaching Experience (On-campus) 49

  1. Organic Chemistry I

    2020

     詳細を見る

    The primary purpose of this course is to help students acquire a logical framework for understanding fundamental organic chemistry. This framework emphasizes how the organic molecular structures and the electron density configurations are related to patterns of chemical reactions. Based on the knowledge educated following the course contents, participants are expected to explain organic reaction sequences happening on the aliphatic substrates and solve progressive problems sequentially.

  2. Organic Chemistry III

    2020

     詳細を見る

    The primary purpose of the course is to acquire a logical framework for understanding fundamental organic chemistry. This outline essentially provides the reactions of the organic compounds having critical functional groups, such as hydroxy, carbonyl, and amino groups, as well as their derivatives. Based on the knowledge educated following the course contents, the participants are expected to understand the reactions converting one functional group to another and solve the progressive problems sequentially.

  3. Organic Chemistry V

    2020

     詳細を見る

    The primary purpose of the course is to learn the spectroscopic analysis of organic molecules and the interpretation of the spectral data. The course begins with theoretical/fundamental knowledge on the chromatographic and spectroscopic techniques (GC, HPLC, NMR, UV, IR, Raman, Mass, and so on) and continues to assignments of organic molecular structures with Spectra-type problems. Furthermore, it covers problem-solving regarding organic reactions to reinforce students’ understanding of the molecular structures/reactivities. The participants are expected to solve the progressive problems sequentially.

  4. Organic Chemistry IV

    2020

     詳細を見る

    The primary purpose of this course is to acquire a logical framework for understanding advanced organic chemistry. The course begins with condensation reactions of carbonyl and amine compounds and moves on to various reactions comprising migration steps. It also continues heterocyclic chemistry and organometallic chemistry, which are rapidly-expanding fields. Organometallic compounds that incorporate the carbon-metal bonds as powerful nucleophiles have been widely used for effective synthetic transformation. Replacement of the first metal by a new one can activate or control the chemical reactions' outcomes. Based on the knowledge, the participants are expected to conduct how to perceive appropriate answers to challenging problems in organic chemistry.

  5. Fundamentals of Chemistry 2

    2020

     詳細を見る

    This course's primary goal is to grasp what chemistry is all about and learn fundamental principles and elementary knowledge in different chemistry subjects. Fundamentals of Chemistry II begins with chemical kinetics and equilibrium, advances to thermodynamics and electronics, and finishes with chemical structures, properties, and reactions.
    Based on the knowledge, educated following the course contents, the students will be able to solve chemistry problems in each subject of physical, electro-, nuclear, inorganic, solid-state, organic, and biological chemistries, from pretty simple to much complex and hybrid.

  6. Organic Chemistry II

    2020

     詳細を見る

    The primary purpose of this course is to acquire a logical framework for understanding fundamental organic chemistry. Many chemical reactions of organic compounds begin with nucleophile-electrophile interactions. This framework provides an influence for chemical reactions of the organic molecules having -bonds. Based on the knowledge educated following the course contents, the participants are expected to understand organic reaction sequences happening with unsaturated organic molecules, including aromatic compounds, and solve the progressive problems sequentially.

  7. Core Organic Chemistry

    2020

     詳細を見る

    The purpose of this course is to learn systematically important features of basic/advanced organic chemistry. This course will assist the student to understand the intellectual roots of organic chemistry under the specific topics selectively chosen in basic/advanced organic chemistry and to develop the knowledge and appreciation of the organic molecular structures, characterizations, preparations, and reactions, as well as the corresponding mechanisms in organic chemistry. Students will be able to solve progressive problems in organic chemistry sequentially.

  8. Fundamentals of Chemistry 2

    2019

  9. Organic Chemistry 4

    2019

  10. Organic Chemistry 2

    2019

  11. Organic Chemistry 1

    2019

  12. Organic Chemistry 3

    2019

  13. Organic Chemistry 5

    2019

  14. Fundamentals of Chemistry 2

    2018

  15. Organic Chemistry 1

    2018

  16. Organic Chemistry 5

    2018

  17. Core Organic Chemistry

    2018

  18. Organic Chemistry 4

    2018

  19. Organic Chemistry 2

    2018

  20. Organic Chemistry 3

    2018

  21. 有機化学4

    2017

  22. 有機化学2

    2017

  23. 有機化学1

    2017

  24. 有機化学5

    2017

  25. 有機化学3

    2017

  26. Core organic chemistry

    2016

  27. Organic Chemistry 5

    2016

  28. Organic Chemistry 3

    2016

  29. Organic Chemistry 1

    2016

  30. Organic Chemistry 4

    2016

  31. Organic Chemistry 2

    2016

  32. Fundamentals of Chemistry 2

    2016

  33. Organic Chemistry 1

    2015

  34. Organic Chemistry 4

    2015

  35. Organic Chemistry 2

    2015

  36. Fundamentals of Chemistry 2

    2015

  37. Organic Chemistry 5

    2015

  38. Organic Chemistry 3

    2015

  39. Fundamentals of Chemistry 2

    2014

  40. Core Organic Chemistry

    2014

  41. Organic Chemistry 4

    2014

  42. Organic Chemistry 2

    2014

  43. Organic Chemistry 1

    2014

  44. Organic Chemistry 5

    2014

  45. Organic Chemistry 3

    2014

  46. Organic Chemistry 1

    2013

  47. Organic Chemistry 5

    2013

  48. Organic Chemistry 3

    2013

  49. Fundamentals of Chemistry 2

    2012

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