研究者詳細 - 町田　洋

論文 - 町田　洋

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Catalytic hydrotreatment of alkaline lignin and its consequent influences on fast pyrolysis

Zhang, LJ; Choi, C; Machida, H; Huo, ZB; Norinaga, K

CARBON RESOURCES CONVERSION 4 巻頁： 219 - 229 2021年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Carbon Resources Conversion

The current state of lignin has been characterized by these three: (1) as one of the main components in lignocellulosic biomass with an abundant amount; (2) not be taken seriously but treated as a waste product; (3) underutilized due to a complex and stubborn structure. However, lignin can be a rich source for hydrocarbons and aromatic compounds when gives appropriate utilization. In this work, we have studied the hydrotreatment of alkaline lignin (AL) under relatively mild conditions and further investigated the characterization of hydrogenated lignin (HL), especially the behavior during fast pyrolysis. The recovery of the HL decreased with increasing reaction temperature from 60 wt.% to 41 wt.% in the range of 150–250 ℃. The hydrotreated products were analyzed using Elemental Analysis, FTIR (for HL) and GC–MS (for bio-oil). The HL samples were found to have a higher hydrogen/carbon atomic effective ratio (H/Ceff ratio) and a higher degree of saturation than AL. Compared to the internal structure of the lignin before and after hydrotreatment, the side chain groups were removed from AL during the process. After that, from the fast pyrolysis of HL, it was observed that more light hydrocarbons and aromatic compounds were formed than that of AL. Furthermore, fast pyrolysis in the hydrogen atmosphere revealed that more volatile fractions were released compared to the Helium atmosphere. The total olefins yield was increased for HL compared AL from 1.02 wt.% to 3.1 wt.% at 250 ℃ for 7 hours. This study of HL is instructive to some extent for the industrial utilization of lignin.

DOI： 10.1016/j.crcon.2021.09.001

Web of Science

Scopus

A comprehensive study on butanolysis of furfuryl alcohol to butyl levulinate using tungstated zirconia and sulfonated carbon catalysts

Thuppati, UR; Choi, C; Machida, H; Norinaga, K

CARBON RESOURCES CONVERSION 4 巻頁： 111 - 121 2021年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Carbon Resources Conversion

This work presents the formation of butyl levulinate, a potential fuel additive, and an excellent renewable chemical obtained by the butanolysis of furfuryl alcohol (FAL) over a solid acid catalyst. The butanolysis of furfuryl alcohol reaction is a strong function of acidity for which tungstated zirconia (WO3-ZrO2), a robust solid acid catalyst, and a sulfonated carbon catalyst were employed to produce high yields of butyl levulinate targeting a lower initial molar ratio of butanol to FAL. A maximum of 28 mol% yield of butyl levulinate was obtained with tungstated zirconia catalyst. Easily prepared sulfonated carbon catalyst at high reaction temperatures facilitated the complete conversion of reaction intermediate, 2-butoxymethylfuran (2-BMF) through which butyl levulinate was formed, and as high as 80 mol% of butyl levulinate yield was produced at an initial mole ratio of 8.5:1 of butanol to FAL. The better results of sulfonated carbon catalyst could be attributed to the presence of -SO3H, carboxylic acid, and phenolic OH groups on the carbon surface.

DOI： 10.1016/j.crcon.2021.03.003

Web of Science

Scopus

Evaluation CO<inf>2</inf> solubility in biphasic solvent with AMP/Ether/Water for CO<inf>2</inf> capture

Esaki T., Ueno Y., Uchiyama H., Matsukuma Y., Machida H.

Proceedings of the International Conference on Power Engineering 2021, ICOPE 2021 2021年

記述言語：日本語掲載種別：研究論文（学術雑誌）出版者・発行元：Proceedings of the International Conference on Power Engineering 2021, ICOPE 2021

We suggest new CO2 absorption processes with biphasic phase separation type for reducing consumption energy. the CO2-rich solution liquid was separated hydrophilic liquid and hydrophobic liquid. In this work, we studied some kind of amine and ether mixture solvents, and observed phase separation phenomena. From the results of phase separation characteristics, we selected with 2-Amino-2-methyl-1-prophanol (AMP), diethylene diethyl ether (DEGDEE) and water pair. We measured the CO2 solubility at different temperature and CO2 patricidal pressure conditions, and evaluated the effect of component concentration in the solvents on CO2 absorption characteristics and phase separation phenomena. We adjusted the biphasic solvents. AMP, DEGDEE and H2O of biphasic solvent weight-composition ratio are 30, 20 and 50 wt% respectively. The CO2 solubility of absorption at 40 ℃, 0.1atm was obtained 0.647 mol-CO2/mol-AMINE. The CO2 solubility of desorption at 90℃, 1.0 atm was obtained 0.177 mol-CO2/mol-AMINE. The difference of CO2 loading of this solvent was high performance of CO2 capture compared with that of other solvents. These result is attributed to the additive phase assisting in the regeneration of CO2 by extracting the regenerated amine. The results of the present study show reduction of desorption temperature and high CO2 absorption performance.

Scopus

Durability and fire-hazardous-risk evaluation of unique phase separation solvent using high-boiling amine and ether

Maeda N., Kishimoto A., Machida H., Yamaguchi T., Yanase K., Norinaga K.

15th Greenhouse Gas Control Technologies Conference 2021, GHGT 2021 2021年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：15th Greenhouse Gas Control Technologies Conference 2021, GHGT 2021

Durability and fire hazard risk evaluation were conducted to determine the process feasibility on the unique phase separation solvent with low regeneration temperature (90 °C), consisting of amine, ether, and small amount of water. The results we obtained are as follows; I) The amine degradation rate of the phase separation solvent would be less than 1/10 of that of monoethanolamine (MEA), which was contributed by its high oxidative resistant nature and low regeneration temperature. II) The gas composition formed in the absorber was completely out of combustible range and almost no accumulations of explosive compounds such as peroxides were observed when in contact with 6 % oxygen containing gas (dry base). Therefore, we believe that the phase separation solvent is applicable to the treatment of exhaust gas from coal-fired thermal power plants.

Scopus

Energy analysis of CO<inf>2</inf> separation process with low energy consumption using phase separation solvent

Maeda N., Nakanishi K., Kishimoto A., Machida H., Yamaguchi T., Norinaga K.

15th Greenhouse Gas Control Technologies Conference 2021, GHGT 2021 2021年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：15th Greenhouse Gas Control Technologies Conference 2021, GHGT 2021

We calculated the energy required for regeneration when the phase separation solvent solvent is applied to the treatment of exhaust gas from coal-fired power plants. This solvent is characterized by regeneration at a low temperature of less than 100°C. As a result, it was clarified that under ideal conditions with no pressure drop and no heat loss, the required energy could be suppressed to 1.5 GJ/ton-CO2 by satisfying the following conditions; i) pinch point of the heat exchanger between rich-amine and lean-amine: 1 °C, ii) water concentration of the solvent: kept at 10 wt%, iii) COP of the heat pump: 5.5. However, increase of the pinch point, increase of the water concentration, and decrease of the COP will all result in a significant increase in the required energy. Therefore, in order to realize a process with low energy consumption, it is essential to meet these design constraints.

Scopus

Prediction of Phase Behavior of CO2 Absorbents Using Conductor-like Screening Model for Real Solvents (COSMO-RS): An Approach to Identify Phase Separation Solvents of Amine/Ether/Water Systems upon CO2 Absorption

Nakaoka Mana, Tran Khuyen V. B., Yanase Keiichi, Machida Hiroshi, Norinaga Koyo

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59 巻 ( 42 ) 頁： 19020-19029 2020年10月

Online composition analysis of phase separation solvent for carbon dioxide capture using ATR-FT-IR

Sato M., Tran K.V.B., Yamaguchi T., Machida H., Norinaga K.

Journal of Advanced Manufacturing and Processing 2 巻 ( 4 ) 頁： 1 - 12 2020年10月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Advanced Manufacturing and Processing

An amine solvent that undergoes phase change after absorption of CO2 has been studied to reduce the energy consumed during the CO2 capture process. Depending on the components of the solvent, the CO2-rich phase can be separated for the regeneration step or the component in CO2-lean phase accelerates the regeneration step in the solvent that undergoes liquid-liquid phase change. Since the homogeneous solvent separates into two liquid phases after CO2 absorption, an analysis method to track the change in chemical species during the absorption process, especially at the phase separation time, is necessary to illuminate the phenomenon. To establish an online method to analyze the components of the solvent, a Fourier-transform infrared (FT-IR) spectrometer equipped with an attenuated total reflection (ATR) probe was used during the CO2 absorption of phase separation solvent composed of amine, ether, and water. The calibration samples of amines, ethers, and CO2-loaded solutions were used to develop the partial least square regression model. The consumption of reactants, as well as the formation of products, can be monitored quantitatively using the FT-IR spectra. Utilizing this information, the changes in the chemical species shed light on the phase separation mechanism of this solvent: ether was pushed out of the solvent to form a CO2-lean phase due to its hydrophobicity, while CO2 and its products along with amine and water remain in the CO2-rich phase. Without sampling, this rapid and high-accuracy method is suitable for closed processes, especially for a high-pressure process.

DOI： 10.1002/amp2.10067

Scopus

Energy-Saving CO2 Capture by H-2 Gas Stripping for Integrating CO2 Separation and Conversion Processes

Machida Hiroshi, Esaki Takehiro, Yamaguchi Tsuyoshi, Norinaga Koyo

ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8 巻 ( 23 ) 頁： 8732-8740 2020年6月

Carbon Dioxide Absorption Heat in Liquid-Liquid and Solid-Liquid Phase-Change Solvents Using Continuous Calorimetry

Tran Khuyen V. B., Ando Ryuya, Yamaguchi Tsuyoshi, Machida Hiroshi, Norinaga Koyo

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59 巻 ( 8 ) 頁： 3475-3484 2020年2月

Computational fluid dynamics simulation of CO<inf>2</inf> methanation in a shell-and-tube reactor with multi-region conjugate heat transfer

Zhang W.

Chemical Engineering Science 211 巻 2020年1月

Rate of CO<inf>2</inf> absorption of a phase-separation absorbent

Esaki T., Machida H., Norinaga K.

Journal of Advanced Manufacturing and Processing 2 巻 ( 1 ) 頁： 1 - 7 2020年1月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：Journal of Advanced Manufacturing and Processing

In this study, we evaluated the CO2 absorption characteristics of a phase-separation amine absorbent. The phase-separation absorbent consists of a 30:60:10 (by weight percent) mixture of 2-(ethylamino)ethanol, diethylene glycol diethyl ether, and water. The CO2 absorption rate of the phase-separation absorbent was measured in a lab-scale counter flow absorber. In addition, the CO2 transport phenomena in the absorber were analyzed by performing model fitting. The experimental results revealed that the CO2 absorption rates are different before and after phase separation. In fact, the overall CO2 absorption capacity coefficient after phase separation is 4.5 times higher than that obtained before phase separation. By changing the gas-liquid ratio, we obtained a CO2 recovery ratio of over 80% using the model. Thus, the absorption temperature, CO2 loading, and gas-liquid ratio can be tuned to obtain the desired CO2 recovery ratio.

DOI： 10.1002/amp2.10033

Scopus

Modelling of CO<inf>2</inf> solubility in phase separation solvent composed of amine/ether/water system for CO<inf>2</inf> capture

Machida H.

Journal of Molecular Liquids 292 巻 2019年10月

Quantitative Analyses of Chemical Structural Change and Gas Generation Profile of Coal upon Heating toward Gaining New Insights for Coal Pyrolysis Chemistry

Fukuoka Tetsuya, Takeda Norihiro, Zhang Lu, Machida Hiroshi, Zhang Wei, Watanabe Masahiko, Nishibata Yuko, Hayashi Jun-ichiro, Norinaga Koyo

ISIJ INTERNATIONAL 59 巻 ( 8 ) 頁： 1376-1381 2019年

An approach for quantifying transferable hydrogen in pyrolyzing coals

Norinaga K., Fukuoka T., Machida H., Zhang W.

36th Annual International Pittsburgh Coal Conference: Clean Coal-Based Energy/Fuels and the Environment, PCC 2019 2019年

Reducing energy required for CO<inf>2</inf> separation and recovery process by employing phase separation solvents

Norinaga K., Nishio H., Khuyen T., Machida H.

36th Annual International Pittsburgh Coal Conference: Clean Coal-Based Energy/Fuels and the Environment, PCC 2019 2019年

Low temperature swing process for CO<sub>2</sub> absorption-desorption using phase separation CO<sub>2</sub> capture solvent

Machida, H; Ando, R; Esaki, T; Yamaguchi, T; Horizoe, H; Kishimoto, A; Akiyama, K; Nishimura, M

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL 75 巻頁： 1 - 7 2018年8月

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：International Journal of Greenhouse Gas Control

We have developed a phase separation solvent which transforms into two liquid phases after CO2 absorption, in order to establish an energy-saving CO2 capture process. The CO2 loading changes strongly with temperature increase during the phase separation, which enables us to reduce the temperature difference between absorber and desorber. The low temperature swing process economizes the energy requirement for the CO2 capture process with highly-effective reaction-heat recovery. We evaluated the energy consumption of the CO2 capture process with our novel phase separation solvent based on the CO2 solubility. The energy requirement was estimated to be as low as 1.6 GJ/ton-CO2.

DOI： 10.1016/j.ijggc.2018.05.010

Web of Science

Scopus

Shear Viscosity and Heterogeneous Structure of Alkylaminoethanol-Based CO2 Absorbents

Yamaguchi Tsuyoshi, Ando Ryuya, Yoshida Koji, Yamaguchi Toshio, Machida Hiroshi

JOURNAL OF PHYSICAL CHEMISTRY B 122 巻 ( 14 ) 頁： 4045-4050 2018年4月

Degradation Test for Energy-Saving CO<inf>2</inf> Absorbent based on Phase Separation Type Solvent by Aqueous (Amine + Ether) Solution

Maeda N., Kishimoto A., Machida H., Yamaguchi T.

GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies 2018年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies

The unique phase separation type amine/ether absorbent is expected to realize the CO2 separation process with low-energy consumption (1.5GJ/ton-CO2). In this study, a degradation test of the absorbent under thermal load of liquid regeneration was conducted in order to clarify 1) the behavior of its performance declination for CO2 capture and 2) the behavior of amine loss mainly caused by generation of by-product. The regeneration condition was chosen based on two assumptions that a) most likely to damage to the solution, which means high-oxidation atmosphere containing oxygen and sulfur oxide, and b) adopting actual operating temperature when absorbing or desorbing. As a result, only a small amount of the CO2 capture capability was lost through 48 hours cyclic thermal load of 50-90 °C. Consequently, it was found that the phase separation type solvent could be durable enough for the practical use. Besides, the running cost associated with make-up amine might be drastically reduced.

Scopus

Energy-saving CO<inf>2</inf> Capture Process Using Phase Separation Type Solvent by Aqueous (amine + ether) Solution

Machida H., Takehiro E., Yamaguchi T., Norinaga K., Kishimoto A., Akiyama K., Nishimura M.

GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies 2018年

記述言語：英語掲載種別：研究論文（学術雑誌）出版者・発行元：GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies

We have developed the phase separation solvent for CO2 capture. Our developed solvent consists amine, organic solvent and water and shows single liquid phase before CO2 absorption though it shows two liquid phases after CO2 absorption. Feature of phase separation solvent is reducing temperature difference between absorber and stripper. We apply the heat pump system for CO2 separation and evaluate the energy consumption. Low temperature swing process saves energy requirement for CO2 capture process with highly-effective reaction-heat recovering. To evaluate the CO2 capture system with our solvent, screening test for amine and organic solvent combination and CO2 solubility measurement were examined. In the phase separation test, three types of solvents were obtained by combining amine and ether, that is, no phase separation with CO2 scrubbing, phase separation with CO2 scrubbing, and thoroughly immiscible. The phase behaviour depends on the hydrophobicity of amines or organic solvents, and the types of solvents were classified using the hydrophobic parameter.

Scopus

Development of phase separation solvent for CO2 capture by aqueous (amine plus ether) solution

Machida Hiroshi, Oba Kazuki, Tomikawa Takashi, Esaki Takehiro, Yamaguchi Tsuyoshi, Horizoe Hirotoshi

JOURNAL OF CHEMICAL THERMODYNAMICS 113 巻頁： 64-70 2017年10月

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