Faculty Profiles - ISHIHARA Kazuaki

Papers - ISHIHARA Kazuaki

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Baeyer-Villiger Oxidation Using Hydrogen Peroxide Invited Reviewed

Muhammet Uyanik, Kazuaki Ishihara

ACS Catalysis Vol. 3 ( 4 ) page： 513-520 2013.2

Lanthanum(III) catalysts for highly efficient and chemoselective transesterification Invited Reviewed

Manabu Hatato, Kazuaki Ishihara

Chem. Commun. Vol. 49 ( 20 ) page： 1983-1997 2013.1

Conformationally-flexible chiral hypervalent Organoiodine catalysts for enantioselective Oxidative Transformations Invited Reviewed

Muhammet Uyanik, Kazuaki Ishihara

J. Synth. Org. Chem., Jpn Vol. 70 ( 11 ) page： 1116-1122 2012.11

テーラーメイド超分子触媒の設計 Invited Reviewed

波多野学，石原一彰

Vol. 57 ( 9 ) page： 56-61 2012.9

Baeyer-Villiger oxidation and oxidative cascade reactions with aqueous hydrogen peroxide catalyzed by lipophilic Li[B(C6F5)4] and Ca[B(C6F5)4]2 Reviewed

Muhammet Uyanik, Daisuke Nakashima, Kazuaki Ishihara

Angewandte Chemie International Edition Vol. 51 ( 36 ) page： 9093-9096 2012.8

alpha-Heterosubstituted beta-alkylacroleins as useful multisubstituted dienophiles for enantioselective Diels-Alder reactions Reviewed

Akira Sakakura, Hiroki Yamada, Kazuaki Ishihara

Asian J. Org. Chem. Vol. 1 ( 2 ) page： 133-137 2012.8

In situ generated "lanthanum(III) nitrate alkoxide" as a highly active and nearly neutral transesterification catalyst Reviewed

Manabu Hatano, Sho Kamiya, Kazuaki Ishihara

Chem. Commun. Vol. 48 ( 76 ) page： 9465-9467 2012.7

IBS-Catalyzed Regioselective Oxidation of Phenols to 1,2-Quinones with Oxone Invited Reviewed

Muhammet Uyanik, Tatsuya Mutsuga, Kazuaki Ishihara

Molecules Vol. 17 ( 7 ) page： 8604-8616 2012.7

N,N-Diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters Reviewed

Yoshiki Koshikari, Akira Sakakura, Kazuaki Ishihara

Organic Letters Vol. 14 ( 12 ) page： 3194-4197 2012.5

Enantioselective Diels-Alder reaction of alpha-(acylthio)acroleins: a new entry to sulfur-containing chiral quaternary carbons Reviewed

Akira Sakakura, Hiroki Yamada, Kazuaki Ishihara

Organi Letters Vol. 14 ( 12 ) page： 2972-2975 2012.5

Enantioselective direct aminalization with primary carboxamides catalyzed by chiral ammonium 1,1'-binaphthyl-2,2'-disulfonates Invited Reviewed

Manabu Hatano, Takuya Ozaki, Yoshihiro Sugiura, Kazuaki Ishihara

Chemical Communications Vol. 48 ( 41 ) page： 4986-4988 2012.4

医薬品製造のための毒性元素を用いない合成法の開拓

石原一彰

Nagoya University eブックシリーズ１「最先端メディカルエンジニアリング」 page： 36-40 2012.4

Conformationally flexible chiral supramolecular catalysts for enantioselective Diels-Alder reactions with anomalous endo/exo selectivities Invited Reviewed

Manabu Hatano, Kazuaki Ishihara

Chemical Communications Vol. 48 ( 36 ) page： 4273-4283 2012.3

2-Iodoxy-5-methylbenzenesulfonic acid-catalyzed selective oxidation of 4-bromobenzyl alcohol to 4-bromobenzaldehyde or 4-bromobenzoic acid with oxone Invited Reviewed

Muhammet Uyanik, Kazuaki Ishihara

Organic Syntheses Vol. 89 ( 1 ) page： 105-114 2012.1

Development of catalytic transesterification directed towards industrial application Invited Reviewed

Vol. 86 ( 1 ) page： 3-10 2012.1

Catalysis with in situ-generated (hypo)iodite ions for oxidative coupling reactions Invited Reviewed

Muhammet Uyanik, Kazuaki Ishihara

ChemCatChem Vol. 4 ( 2 ) page： 177-185 2011.12

Hydrophobic N,N-diarylammonium pyrosulfates as dehydrative condensation catalysts under aqueous conditions Reviewed

Akira Sakakura, Yoshiki Koshikari, Matsujiro Akakura, Kazuaki Ishihara

Organic Letters Vol. 14 ( 1 ) page： 30-33 2011.11

Intramolecular dehydrative condensation of dicarboxylic acids with Brønsted base-assisted boronic acid catalysts Invited Reviewed

Akira Sakakura, Risa Yamashita, Takuro Ohkubo, Matsujiro Akakura, Kazuaki Ishihara

Australian Journal of Chemistry Vol. 64 ( 11 ) page： 1458-1465 2011.11

Authorship：Lead author Language：English Publishing type：Research paper (scientific journal)

Bifunctional Broensted base-assisted boronic acid catalysts, arylboronic acids bearing two sterically bulky (N,N-dialkylamino)methyl groups at the 2,6-positions, exhibit remarkable activities for the dehydrative intramolecular condensation of dicarboxylic acids. The steric bulkiness of the (N,N-dialkylamino)methyl groups of 1, which prevents the formation of less active species such as the N to B chelated species and triarylboroxines 3, is crucial for the high catalytic activity. This is the first successful method for the catalytic dehydrative self-condensation of di- and tetracarboxylic acids.

Enantioselective Diels-Alder reactions with anomalous endo/exo selectivities using conformationally flexible chiral supramolecular catalysts Reviewed

Manabu Hatano, Tomokazu Mizuno, Atsuto Izumiseki, Ryota Usami, Takafumi Asai, Matsujiro Akakura, Kazuaki Ishihara

Angewandte Chemie International Edition Vol. 50 ( 51 ) page： 12189-12192 2011.11

Catalytic enantioselective alkyl and aryl addition to aldehydes and ketones with organozinc reagents derived from alkyl Grignard reagents or arylboronic acids Reviewed

Manabu Hatano, Riku Gouzu, Tokokazu Mizuno, Hitoshi Abe, Toshihide Yamada, Kazuaki Ishihara

Catalysis Science & Technology Vol. 1 ( 7 ) page： 1149-1158 2011.7

Authorship：Lead author Language：English Publishing type：Research paper (scientific journal)

A highly practical, catalytic enantioselective alkyl and aryl addition to aldehydes and ketones with organozinc reagents, which were prepared in situ from commercially available Grignard reagents or arylboronic acids, was developed. A chiral phosphoramide ligand was essential for promoting the addition reactions in high yields with high enantioselectivities.

DOI： 10.1039/C1CY00108F

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Papers - ISHIHARA Kazuaki