Updated on 2022/05/21

写真a

 
KAWANO, Shin-ichiro
 
Organization
Graduate School of Science Lecturer
Graduate School
Graduate School of Science
Undergraduate School
School of Science Department of Chemistry
Title
Lecturer
Contact information
メールアドレス

Degree 1

  1. Doctor of Engineering ( 2006.3   Kyushu University ) 

Research Interests 7

  1. Supramolecular Chemistry

  2. Coordination Chemistry

  3. Self-assembly

  4. Liquid Crystals

  5. Materials Chemistry

  6. Macrocycles

  7. Molecular recognition

Research Areas 4

  1. Nanotechnology/Materials / Functional solid state chemistry  / Macrocycles

  2. Nanotechnology/Materials / Functional solid state chemistry  / Host–guest chemistry

  3. Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry  / Supramolecular Chemistry

  4. Nanotechnology/Materials / Nanometer-scale chemistry  / Liquid Crystals

Current Research Project and SDGs 1

  1. Exploration and Construction of Nanoporous Liquid Crystals

Research History 2

  1. Nagoya University   Graduate School of Science Division of Material Science Inorganic and Analytical Chemistry   Lecturer

    2015.12

  2. Assistant Professor

    2008.7

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    Country:Japan

Education 2

  1. Kyushu University   Graduate School, Division of Engineering   Department of Chemistry and Biochemistry

    2003.4 - 2006.3

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    Country: Japan

  2. Kyushu University   Faculty of Engineering

    1997.4 - 2001.3

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    Country: Japan

Professional Memberships 6

  1. The Chemical Society of Japan

  2. The Society of Polymer Science, Japan

  3. Japan Society of Coordination Chemistry

  4. 日本液晶学会

  5. NMR研究会

  6. 固体NMR・材料フォーラム

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Committee Memberships 2

  1. 錯体化学若手の会   事務局  

    2011.4 - 2013.3   

  2. 錯体化学若手の会   中部・東海地区 世話人  

    2008.4 - 2018.3   

Awards 4

  1. 2020年度 日本液晶学会学会賞 論文賞A部門

    2020.9   日本液晶学会  

    河野慎一郎, 宗宮伸弥, 中谷真人, 尾上順, 田中健太郎

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  2. 日本化学会 第99回春季年会 第33回若い世代の特別講演会 講演証

    2019.3   日本化学会  

    河野 慎一郎

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  3. SPSJ PMF Poster Award

    2016.11   Construction of Nanospace in Macrocyclic Columnar Liquid Crystals

    Shin-ichiro Kawano

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    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  4. Inoue Research Award for Young Scientists

    2007.2   Inoue Foundation for Science  

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    Country:Japan

 

Papers 31

  1. Thermally Stable Array of Discrete C<sub>60</sub>s on a Two-Dimensional Crystalline Adlayer of Macrocycles both in Vacuo and under Ambient Pressure Reviewed

    Shin-ichiro Kawano, Masato Nakaya, Masaaki Saitow, Atsuki Ishiguro, Takeshi Yanai, Jun Onoe, Kentaro Tanaka

    Journal of the American Chemical Society   Vol. 144   page: 6749 - 6758   2022.3

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/jacs.1c13610

  2. Mesogenic discrete metallofoldamer for columnar liquid crystal Reviewed

    Shin-ichiro Kawano, Kazutaka Narita, Yuka Ikemoto, Ako Sasaki, Kentaro Tanaka

    Chemical Communications   Vol. 58 ( 20 ) page: 3274 - 3277   2022.2

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry (RSC)  

    A helical metallofoldamer forms a columnar phase with high thermal stability owing to its rigid helical mesogenic structure.

    DOI: 10.1039/d2cc00310d

    Web of Science

  3. Specific and Oriented Encapsulation of Fullerene C70 into a Supramolecular Double-Decker Cage Composed of Shape-persistent Macrocycles Reviewed

    Shin-ichiro Kawano, Tomoaki Fukushima, Kentaro Tanaka

    Angew. Chem. Int. Ed.   Vol. 57 ( 45 ) page: 14827 - 14831   2018.11

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.201809167

    Web of Science

  4. Columnar Liquid Crystals from a Giant Macrocycle Mesogen Reviewed

    Shin-Ichiro Kawano, Masahiro Kato, Shinya Soumiya, Masato Nakaya, Jun Onoe, Kentaro Tanaka

    Angewandte Chemie - International Edition   Vol. 57 ( 1 ) page: 167 - 171   2018.1

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Wiley-VCH Verlag  

    Columnar liquid crystals composed of a giant macrocyclic mesogen were prepared. The giant macrocyclic mesogen has a square hollow with a 2.5 nm diagonal, which was bounded by diindolo[3,2-b:2′,3′-h]carbazole (diindolocarbazole) moieties as the edges and bis(salicylidene)-o-phenylenediamine (salphen) moieties as the corners. The shape and size of the macrocycle were directly observed by scanning tunneling microscopy (STM). Each side of the bright square in the STM image corresponds to a diindolocarbazole moiety, and the length of the sides was consistent with the result of the single crystal analysis of diindolocarbazole. Finally, we successfully obtained a giant macrocycle with long and branched side chains, which exhibited a rectangular columnar LC phase over a wide temperature range. To the best of our knowledge, it contained the largest discrete inner space of any thermotropic columnar liquid crystal composed of macrocyclic mesogens.

    DOI: 10.1002/anie.201709542

    Web of Science

    Scopus

  5. Columnar Liquid-Crystalline Metallomacrocycles Reviewed

    Shin-ichiro Kawano, Yukari Ishida, Kentaro Tanaka

    Journal of the American Chemical Society   Vol. 137   page: 2295-2302   2015.2

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja510585u

  6. Metalloporphyrins substituted with N-carbazolyl groups quadruply at meso positions Reviewed

    Shin-Ichiro Kawano, Sae Kawada, Atsuya Matsubuchi, Kentaro Tanaka

    Journal of Porphyrins and Phthalocyanines   Vol. 26   page: 140 - 146   2021.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  7. A Light-Harvesting/Charge-Separation Model with Energy Gradient Made of Assemblies of meta-Pyridyl Zinc Porphyrins Reviewed

    Otsuki Joe, Okumura Takumi, Sugawa Kosuke, Kawano Shin-ichiro, Tanaka Kentaro, Hirao Takehiro, Haino Takeharu, Lee Yu Jin, Kang Seongsoo, Kim Dongho

    CHEMISTRY-A EUROPEAN JOURNAL   Vol. 27 ( 12 ) page: 4053 - 4063   2021.2

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.202003327

    Web of Science

  8. Structure and dynamics of a chiral cubanoid complex composed of lithium and salphen Reviewed

    Shin-ichiro Kawano, Kyohei Tomita, Kentaro Tanaka

    Inorganica Chimica Acta   Vol. 512   page: 119894 - 119894   2020.11

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.ica.2020.119894

    Web of Science

  9. Liquid-crystalline Metallomacrocycles Composed of Bis(hydroxypyridono)toluene Ligand and Cu2+ Ions. Reviewed International journal

    Shin-Ichiro Kawano, Kohei Ideta, Tomohiko Banno, Kentaro Tanaka

    Chemistry, an Asian journal   Vol. 14 ( 23 ) page: 4415 - 4419   2019.12

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    A series of π-extended chelating scaffolds incorporating two hydroxypyridone moieties were synthesized. X-ray crystallographic analysis revealed that a bis(hydroxypyridono)toluene ligand possessed a unique π-extended structure and exhibited efficient phase segregation from the aliphatic chains attached at the heterocyclic nitrogen. The bis-bidentate ligand formed a metal-coordination-induced macrocycle with Cu2+ ions. During the complexation, a spectral change in the visible region was induced. Furthermore, the successful development of a liquid crystal of the metallomacrocycle with appropriate side chains was achieved. Examples of liquid-crystalline macrocycles formed via metal-mediated self-assembly are still rare. Among them, the macrocycle described in this paper showed an obvious hexagonal columnar phase reflecting the three-fold symmetric planar structure of the mesogenic metal complex.

    DOI: 10.1002/asia.201901323

    Web of Science

    PubMed

  10. Near-Infrared Absorption by Intramolecular Charge-Transfer Transition in 5,10,15,20-Tetra(N-carbazolyl)porphyrin through Protonation Reviewed

    S. Kawano, S. Kawada, Y. Kitagawa, R. Teramoto, M. Nakano, K. Tanaka

    Chemical Communications   Vol. 55 ( 20 ) page: 2992 - 2995   2019.3

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c8cc09667h

    Web of Science

  11. Liquid-crystalline Phthalocyanine with Short Intercolumnar Distance and Variation of the Liquid Crystallinity Induced by Square-planar Metal Ions Reviewed

    Kawano Shin-ichiro, Yamada Yasuyuki, Shu Rongfang, Ishihara Yu, Tanaka Kentaro

    CHEMISTRY LETTERS   Vol. 47 ( 10 ) page: 1262 - 1264   2018.10

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.180591

    Web of Science

  12. Columnar Liquid-Crystalline Macrocycles Synthesized via Metal Ion-Assisted Self-Assembly Reviewed

    Shin-Ichiro Kawano, Takafumi Murai, Takahiro Harada, Kentaro Tanaka

    Inorganic Chemistry   Vol. 57 ( 7 ) page: 3913 - 3919   2018.4

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society  

    Columnar assemblies of liquid-crystalline (LC) macrocycles hold promise for the construction of nanochannels in fluid materials. Metal-assisted self-assembly is an efficient way to prepare LC macrocycles. A large π-conjugated ligand, 9,10-diphenylanthracene (DPA) bearing two β-diketones, was prepared as a building unit for the macrocycle, and a series of side chains were incorporated into the DPA to yield LC materials. The bis(β-diketone) ligands on DPA allow for the efficient formation of triangular 3:3 metallomacrocycles in the presence of square-planar Cu2+ ions. The copper-containing 3:3 metallomacrocycle with the appropriate side chains exhibited thermotropic columnar LC phases in which the columns were arranged in rectangular arrays over a wide temperature range, and well-ordered birefringent textures were observed under a polarized microscope.

    DOI: 10.1021/acs.inorgchem.8b00046

    Web of Science

    Scopus

  13. Solid-State NMR Study of Dynamic Properties of a Columnar Liquid Crystalline Macrocycle Reviewed

    Shin-ichiro Kawano, Kentaro Tanaka

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   Vol. 90 ( 7 ) page: 826 - 830   2017.7

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    Authorship:Lead author   Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    A shape-persistent macrocycle composed of carbazole and salphen, which has a discrete 1.4-nm-sized inner cavity, forms four thermotropic columnar liquid crystalline (LC) phases. Both the structure and dynamics of the macrocyclic mesogens in the LC phases were investigated by solid-state NMR. Variable temperature H-1 and C-13 magic-angle spinning (MAS) experiments reveal that the peripheral side chains exhibited narrow line widths throughout the columnar phases, indicating that the side chains behave like liquids among the columns. In sharp contrast, the NMR signals related to the macrocyclic mesogen became highly symmetric and similar to signals in solution with increasing temperature. These results revealed that the LC macrocycle with an inherent inner cavity gains more mobility around the mesogenic framework as the macrocycle underwent phase transitions.

    DOI: 10.1246/bcsj.20170047

    Web of Science

  14. Self-Assembled Synthesis and Liquid Crystalline Property of Metallomacrocycle Composed of Naphthalenedihydroxamate and Cu2+ Ion Reviewed

    Shin-ichiro Kawano, Hiroshi Inada, Kentaro Tanaka

    Chemistry Letters   Vol. 45   page: 1105-1107   2016.9

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.160577

  15. Metal-Ion-Induced Switch of Liquid Crystalline Orientation of Metallomacrocycles Reviewed

    Shin-ichiro Kawano, Takashi Hamazaki, Atsushi Suzuki, Kenshin Kurahashi, Kentaro Tanaka

    Chemistry - A European Journal   Vol. 22   page: 15674-15683   2016.8

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/chem.201601941

  16. Coordination Oligomers and Polymers of an Oxazoley-appended Zinc Chlorophyll Derivative Reviewed

    Yoshinao Shinozaki, Isao Yoshikawa, Koji Araki, Kazuaki Ohara, Kentaro Ymaguchi Ohara, Shin-ichiro Kawano, Kentaro Tanaka, Yasuyuki Araki, Takehiko Wada, and Joe Otsuki

    Chemistry Letters   Vol. 43   page: 862-864   2014.3

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    Language:English   Publishing type:Research paper (scientific journal)  

  17. Electron donors and acceptors based on 2,7-functionalized pyrene-4,5,9,10-tetraone Reviewed

    Shin-ichiro Kawano, Martin Baumgarten, Dennis Chercka, Volker Enkelmann and Klaus Müllen

    Chemical Communications   Vol. 49   page: 5058-5060   2013

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c3cc39141h

  18. Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative Reviewed

    Yoshinao Shinozaki, Gary Richards, Keizo Ogawa, Akihito Yamano, Kazuaki Ohara, Kentaro Yamaguchi, Shin-ichiro Kawano, Kentaro Tanaka, Yasuyuki Araki, Takehiko Wada, and Joe Otsuki

    Journal of the American Chemical Society   Vol. 135 ( 14 ) page: 5262-5265   2013

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/ja400493e

  19. 白色に光るベシクル Invited Reviewed

    河野慎一郎

    化学   Vol. 65 ( 4 ) page: 63 - 64   2010.4

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    Authorship:Lead author, Corresponding author   Language:Japanese   Publishing type:Research paper (other academic)  

  20. Reversible Solubilization and Precipitation of Carbon Nanotubes through Oxidation-Reduction Reaction of a Solubilizing Agent Reviewed

    Kazuyuki Nobusawa, Atsushi Ikeda, Jun-ichi Kikuchi, Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

      Vol. 47   page: 4577-4580   2008.3

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    Language:English   Publishing type:Research paper (scientific journal)  

  21. Blue-Emitting Poly(2,7-pyrenylene)s: Synthesis and Optical Properties Reviewed

    Shin-ichiro Kawano, Changduk Yang, Marcos Ribas, Stanislav Baluschev, Martin Baumgarten, Klaus Müllen

    Macromolecules   Vol. 41   page: 7933   2008

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  22. Self-Sorting Organogels with p-n Heterojunction Points Reviewed

    Kazunori Sugiyasu, Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

    Chem. Mater.   Vol. 20   page: 2863–2865   2008

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm800043b

  23. Pyridine-containing Versatile Gelators for Post-modification of Gel Tissues towards Construction of Novel Porphyrin Nanotubes Reviewed

    Sudip Malik, Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

    Tetrahedron   Vol. 65   page: 7326   2007

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    Language:English   Publishing type:Research paper (scientific journal)  

  24. Spontaneous Colorimetric Sensing of the Positional Isomers of Dihydroxynaphthalene in a 1-D Organogel Matrix Reviewed

    Pritam Mukhopadhyay, Yuya Iwashita, Michihiro Shirakawa, Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

    Angew. Chem. Int. Ed.   Vol. 127   page: 1592   2006

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    Language:English   Publishing type:Research paper (scientific journal)  

  25. Creation of a Mixed-Valence State from One-Dimensionally Aligned TTF Utilizing the Self-Assembling Nature of a Low Molecular-Weight Gel Reviewed

    Tatsuya Kitahara, Michihiro Shirakawa, Shin-ichiro Kawano, Uwe Beginn, Norifumi Fujita, Seiji Shinkai

    J. Am. Chem. Soc.   Vol. 127   page: 14980   2005

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    Language:English   Publishing type:Research paper (scientific journal)  

  26. Quater, Quinque, and Sexi Thiophene Organogelators: Structure, Thermochromism, and Heating-Free Sol-Gel Phase Control Triggered by Redox-Stimuli Reviewed

    Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

    Chem. Eur. J.   Vol. 11   page: 4735   2005

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  27. A Coordination Gelator that Shows a Reversible Chromatic Change and a Sol-Gel Phase Transition Behavior upon Oxidative / Reductive Stimuli Reviewed

    Shin-ichro Kawano, Norifumi Fujita, Seiji Shinkai

    J. Am. Chem. Soc.   Vol. 126   page: 8592   2004

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  28. Sol-Gel Polycondensation of Tetraethyl Orthosilicate (TEOS) in Sugar-Based Porphyrin Organogels: Inorganic Conversion of Sugar-Directed Porphyrinic Fiber Library through Sol-Gel Transcription Processes Reviewed

    Shin-ichiro Kawano, Shun-ichi Tamaru, Norifumi Fujita, Seiji Shinkai

    Chem. Eur. J.   Vol. 10   page: 343   2004

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  29. Novel Host-guest Organogels as Stabilized by the Formation of Crown-ammonium Pseudo-rotaxane Complexes Reviewed

    Shin-ichiro Kawano, Norifumi Fujita, Seiji Shinkai

    Chem. Commun.     page: 1352   2003

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  30. Pyridine-containing Cholesterols as Versatile Galators of Organic Solvents and the Subtle Influence of Ag(I) on the Gel Stability Reviewed

    Shin-ichiro Kawano, Norifumi Fujita, Kjeld J. C. van Bommel, Seiji Shinkai

    Chem. Lett.   Vol. 32   page: 12   2003

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  31. Hydrogen-Bond-Assisted Control of H versus J Aggregation Mode of Porphyrins Stacks in an Organogel System Reviewed

    Michihiro Shirakawa, Shin-ichiro Kawano, Norifumi Fujita, Kazuki Sada, Seiji Shinkai

    J. Org. Chem.   Vol. 68   page: 5037   2003

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    Language:English   Publishing type:Research paper (scientific journal)  

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Books 8

  1. NMRによる有機材料分析と その試料前処理、データ解釈 Reviewed

    河野慎一郎、田中健太郎( Role: Contributor ,  第7章 4節)

    技術情報協会  2021.9  ( ISBN:978-4-86104-860-9

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    Total pages:10   Language:Japanese Book type:Scholarly book

  2. 巨大環状化合物をメソゲンとしたカラムナー液晶による 流動性ナノ空間の構築 Reviewed

    河野慎一郎,田中健太郎( Role: Joint author ,  解説)

    液晶  2021.1 

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    Total pages:6   Responsible for pages:40-45   Language:Japanese

  3. 液晶の中にナノ空間を創る Reviewed

    河野慎一郎, 田中健太郎( Role: Joint author ,  特集 空間を操る)

    高分子, 69巻, 8月号, 2020  2020.8 

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    Total pages:2   Responsible for pages:390-391   Language:Japanese

  4. 液晶の中のナノ空間開発 大環状化合物の自己組織化によるナノ空間の機能開拓 Reviewed

    河野慎一郎( Role: Sole author)

    化学と工業  2019.11 

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    Language:Japanese

  5. 錯体化合物事典

    大川尚士 ら他, 河野慎一郎、田中健太郎( Role: Joint author)

    朝倉書店  2019.9  ( ISBN:978-4-254-14105-4

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    Language:Japanese Book type:Dictionary, encyclopedia

  6. Construction of Nanospace in Macrocyclic Columnar Liquid Crystals

    Shin-ichiro Kawano( Role: Sole author ,  Hot Topics)

    2017.6 

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    Total pages:1   Responsible for pages:276   Language:English Book type:Scholarly book

  7. 海外研究で感じたこと Reviewed

    河野慎一郎( Role: Sole author ,  グローイングポリマー)

    高分子, 65巻, 5月号, 2016   2016.5 

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    Total pages:1   Responsible for pages:231   Language:Japanese Book type:Scholarly book

  8. Recent development of organic and low-moleculer gel system which responds to external stimuli Reviewed

    ( Role: Joint author)

    2005.3 

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    Responsible for pages:99-105   Language:Japanese Book type:Scholarly book

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Presentations 12

  1. カラムナー液晶性大環状化合物を用いたナノ空間開拓 Invited

    河野慎一郎、田中健太郎

    第23回 液晶化学研究会シンポジウム 

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    Event date: 2019.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  2. Exploration of Nanospaces Utilizing Self-assembled Macrocycles and Metallomacrocycles Invited

    S. Kawano, K. Tanaka

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    Event date: 2018.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  3. Nanoporous Liquid Crystals and Double-Decker Cages Utilizing Shape-Persistent Metallomacrocycle Invited International conference

    S. Kawano, K, Tanaka

    The International Symposium on Bioinorganic Chemistry 2018  

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    Event date: 2018.11 - 2018.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Okazaki Conference Center, Institute for Molecular Science   Country:Japan  

  4. 大環状化合物を用いた液晶性ナノ空間の創製 Invited

    河野慎一郎, 田中健太郎

    2018年日本液晶学会 液晶交流会 

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    Event date: 2018.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue: 岐阜大学サテライトキャンパス   Country:Japan  

  5. ソフトな包接場を目指したカラムナー液晶性を示す大環状化合物の構造評価と動的挙動 Invited

    河野慎一郎

    第17回固体NMR技術交流会 

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    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:日本電子株式会社(東京)   Country:Japan  

  6. Liquid crystalline metallomacrocycles toward soft materials with nanospaces Invited International conference

    Shin-ichiro Kawano, Kentaro Tanaka

    The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem) 

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    Event date: 2015.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:United States  

  7. Columnar Liquid Crystalline Macrocycles Toward Reversible Guest Inclusion

    Shinichiro Kawano

    Asian International Symposium-Coordination Chemistry, Organometallic Chemistry- 

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    Event date: 2014.3

    Language:English   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  8. 大環状化合物の自己組織化を利用した有機超分子マテリアルの開発 Invited

    河野慎一郎、田中健太郎

    第26回 FIT-ME セミナー  2020.2.28  福岡工業大学 宮元 展義

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    Event date: 2020.2

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:福岡工業大学  

  9. Exploration of Nanospaces Utilizing Self-assembled Macrocycles and Metallomacrocycles Invited International conference

    S. Kawano, K. Tanaka

    2018.12.18 

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    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  10. 大環状化合物を用いた液晶性ナノ空間の創製 Invited International conference

    河野慎一郎, 田中健太郎

    2018年日本液晶学会 液晶交流会  2018.9.3  一般社団法人 日本液晶学会

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    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:岐阜大学サテライトキャンパス  

  11. カラムナー液晶性大環状化合物を用いたナノ空間開拓 Invited International conference

    河野慎一郎, 田中健太郎

    第23回 液晶化学研究会シンポジウム  2019.7.27  液晶化学研究会

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    Language:Japanese   Presentation type:Oral presentation (invited, special)  

  12. Nanoporous Liquid Crystals and Double-Decker Cages Utilizing Shape-Persistent Metallomacrocycle Invited

    S. Kawano, K, Tanaka

    The International Symposium on Bioinorganic Chemistry 2018  2018.11.30 

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    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Okazaki Conference Center, Institute for Molecular Science  

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Research Project for Joint Research, Competitive Funding, etc. 9

  1. ガスを吸収するナノポーラス「液晶」の機能開拓に関する研究

    2022.8 - 2023.7

    2022年度 池谷科学技術振興財団 研究助成 

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    Authorship:Principal investigator  Grant type:Competitive

  2. ガスや有機分子を吸蔵するナノポーラス液晶に関する研究

    2022.4 - 2023.3

    公益財団法人 内藤科学振興財団 2022年度研究助成 

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    Authorship:Principal investigator  Grant type:Competitive

  3. 大環状化合物からなるカラムナー液晶中のナノ空間の開拓

    2022.4 - 2022.3

    徳山科学技術振興財団 2020年度国際交流助成 

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    Grant type:Competitive

  4. 多孔性液晶を活用する有機色素の配向制御と光電変換素子の開発

    2021.4 - 2023.3

    旭硝子財団 2021年度 研究助成  旭硝子財団 2021年度 研究助成 

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    Authorship:Principal investigator 

  5. 放射赤外分光による偏光顕微IR測定を用いた液晶組織中の水分子の特異的吸着挙動の構造解析

    2021.4 - 2022.3

    令和2年度 統合物質創製化学研究推進機構 融合創発研究 

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    Authorship:Principal investigator  Grant type:Competitive

  6. 129Xe NMRによる大環状化合物からなるカラムナー液晶のナノ空間解析

    2020.4 - 2021.3

    令和2年度 統合物質創製化学研究推進機構 融合創発研究 

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\500000

  7. 高度配向する液晶内の空間を活用したイオン伝導性および電子伝導性薄膜の開発

    2019.1 - 2020.12

    平成30年度 小笠原科学技術振興財団研究助成 

    河野 慎一郎

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    Grant type:Competitive

  8. イオンを異方的に輸送するカラムナー液晶性大環状化合物のナノ空間の機能評価に関する研究

    2018.4 - 2019.3

    平成30年度 統合物質創製化学研究推進機構 融合創発研究 

    河野慎一郎

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    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\500000

  9. ナノポーラス液晶を鋳型とする機能性ナノ周期構造の開発

    2015.4 - 2016.3

    戸部眞紀財団研究助成 

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    Grant type:Competitive

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KAKENHI (Grants-in-Aid for Scientific Research) 9

  1. 大環状化合物の特異的ナノ空間を利用する水・イオン輸送のための水圏機能材料の開発

    Grant number:22H04535  2022.4 - 2024.3

    科学研究費助成事業  新学術領域研究(研究領域提案型)

    河野 慎一郎

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    Authorship:Principal investigator 

    Grant amount:\4680000 ( Direct Cost: \3600000 、 Indirect Cost:\1080000 )

  2. Exploration of Nanoporous Liquid Crystals Realizing Size-selective Transporting Functional Materials

    Grant number:19K05493  2019.4 - 2022.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research (C)

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    Authorship:Principal investigator 

    Grant amount:\4290000 ( Direct Cost: \3300000 、 Indirect Cost:\990000 )

  3. Nanoporous Structures and Membranes Utilizing Shape-persistent Macrocycles for Aquatic Functional Materials

    Grant number:20H05216  2020.4 - 2022.3

    Grants-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

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    Authorship:Principal investigator 

    Grant amount:\3120000 ( Direct Cost: \2400000 、 Indirect Cost:\720000 )

  4. サイズ選択的な物質移動を実現するナノチャネル内包型ナノポーラス液晶の機能開拓

    2019.4 - 2022.3

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    河野慎一郎

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    Authorship:Principal investigator  Grant type:Competitive

  5. Functional Nanostructure Fabricated by Template Method Utilizing Nanoporous Liquid Crystals

    Grant number:15K05473  2015.4 - 2018.3

    Grant-in-Aid for Scientific Research  Grant-in-Aid for Scientific Research(C)

    Shin-ichiro Kawano

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    Authorship:Principal investigator 

    Grant amount:\4550000 ( Direct Cost: \3500000 、 Indirect Cost:\1050000 )

    Designable and programmable molecular nanospaces hold promise for molecular system to control chemical events, such as recognition, storage, arraying, transportation, and reaction of molecules. We have devoted ourselves to exploring thermotropic columnar liquid-crystals composed of macrocycles with a large cavity via efficient cyclization such as imine-formation and metal-coordination. 1. A giant macrocyclic mesogen composed of diindolocarbazole and salphen has been synthesized as the compound having largest discrete inner space of any thermotropic columnar liquid crystal composed of macrocyclic mesogens. 2.The copper-containing 3:3 metallomacrocycle with the appropriate side chains exhibited thermotropic columnar LC phases in which the columns were arranged in rectangular arrays over a wide temperature range. 3.We have investigated dynamic properties of a columnar LC macrocycle using solid-state NMR. 4. A 2D crystalline nanoporous network composed of LC macrocycle was obtained.

  6. Molecular architecture of molecular spaces through self-assembly

    Grant number:15H02167  2015.4 - 2018.3

    Tanaka Kentaro

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    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid) 

    The aim of this study was generation of emerging flexible molecular functions through formation of dimentionally-controled discrete or consecutive molecular spaces in molecular assemblies constructed via self-assembly. We have obtained the research findings listed below. 1) Invention of stimuli-responsive spin arrays and molecular reaction fields which were formed by reversible self-assembly reactions. 2) Invention of novel liquid crystals of macrocyclic mesogens. 3) Two-dimensional molecular assemblies to form novel electronic materials and molecular recognition sites. 4) Invention of discrete three-dimensional molecular spaces surrounded by pai-conjugated walls as molecular recognition sites.

  7. ナノポーラス液晶を鋳型とする機能性ナノ周期組織の創製

    2015.4 - 2018.3

    日本学術振興会  科学研究費助成事業  基盤研究(C)

    河野慎一郎

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    Authorship:Principal investigator  Grant type:Competitive

  8. 金属錯体型ナノポーラス液晶の創製

    Grant number:21750061  2009.4 - 2011.3

    科学研究費補助金  若手研究(B)

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    Authorship:Principal investigator 

  9. 多孔性液晶を活用する有機色素の配向制御と光電変換素子の開発

    旭硝子財団  旭硝子財団 2021年度研究助成 

    河野慎一郎

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    Grant type:Competitive

    Grant amount:\2000000

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Industrial property rights 3

  1. NOVEL POLYMERS

    Shin-Ichiro Kawano, Martin Baumgarten, Klaus Müllen, Peter Murer, Thomas Schäfer, Moussa Saleh

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    Application no:20140357898  Date applied:2014.8

    Announcement no:20140357898  Date announced:2014.12

    Country of applicant:Foreign country  

    The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).

  2. Polymers

    Shin-Ichiro Kawano, Martin Baumgarten, Klaus Müllen, Peter Murer, Thomas Schäfer, Moussa Saleh

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    Applicant:BASF SE

    Application no:20110152491  Date applied:2009.6

    Patent/Registration no:8841411  Date registered:2014.9 

    Country of applicant:Foreign country  

    The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).

  3. NOVEL POLYMERS

    Shin-Ichiro Kawano, Martin Baumgarten, Klaus Mullen, Peter Murer, Thomas Schafer, Moussa Saleh

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    Applicant:BASF SE

    Application no:20110152491  Date applied:2007.6

    Date published:2011.6

    Country of applicant:Foreign country  

    The present invention relates to polymers comprising repeating unit(s) of the formula (I), and their use in electronic devices. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high charge carrier mobilities and high temperature stability of the emission color are observed, if the polymers according to the invention are used in polymer light emitting diodes (PLEDs).

 

Social Contribution 4

  1. 2019名大 MIRAI GSC 事業 第三ステージ

    Role(s):Advisor

    2019.8 - 2020.3

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    Audience: High school students

  2. 2019名大 MIRAI GSC 事業 第二ステージ

    Role(s):Advisor

    2019.7 - 2019.8

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    Audience: High school students

    Type:Research consultation

  3. 特別講義(山梨県立韮崎高等学校SSH)

    Role(s):Lecturer

    2019.7

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    Audience: High school students

  4. 第24回英国科学実験講座 クリスマスレクチャー2013

    Role(s):Editer, Organizing member

    2013.8

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    Audience: Schoolchildren, Junior students, High school students, College students, Graduate students, Teachers, Guardians, General, Civic organization

Academic Activities 4

  1. The 69th Conference of Japan Society of Coordination Chemistry

    Role(s):Planning, management, etc.

    2019.9

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    Type:Academic society, research group, etc. 

  2. 11th JAPAN-CHINA Joint Symposium on Metal Cluster Compounds International contribution

    Role(s):Planning, management, etc.

    Hiroshi Nishihara  2017.10

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    Type:Competition, symposium, etc. 

  3. International Workshop on Topology/Geometry-driven Electron Systems toward New Horizon of Functional Materials International contribution

    Role(s):Planning, management, etc.

    2015.12

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    Type:Competition, symposium, etc. 

  4. 2010年度 錯体化学若手の会 夏の学校 International contribution

    Role(s):Planning, management, etc.

    錯体化学会 若手の会  2010.8

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    Type:Academic society, research group, etc.