Updated on 2024/03/13

写真a

 
KOBAYASHI Makoto
 
Organization
Institute of Materials and Systems for Sustainability Division of Materials Research (DM) Associate professor
Graduate School
Graduate School of Engineering
Title
Associate professor
Contact information
メールアドレス
External link

Degree 2

  1. 博士(工学) ( 2011.3   東北大学 ) 

  2. 修士(工学) ( 2008.3   東北大学 ) 

Research Interests 1

  1. Solid state chemistry, Nanosheet, Inorganic material chemistry, Crystal growth

Research Areas 3

  1. Nanotechnology/Materials / Inorganic compounds and inorganic materials chemistry

  2. Nanotechnology/Materials / Inorganic materials and properties

  3. Nanotechnology/Materials / Inorganic/coordination chemistry

Current Research Project and SDGs 3

  1. Structures and design of functions for atomic layered materials

  2. Exploration and structural analysis of oxides and mixed anion compounds

  3. Selective synthesis and morphological control of oxide nano particles by aqueous solution methods

Research History 1

  1. Tohoku University   Institute of Multidisciplinary Research for Advanced Materials,   Assistant Professor

    2011.4 - 2018.9

      More details

    Country:Japan

Education 2

  1. Tohoku University   Graduate School, Division of Engineering

    2008.4 - 2011.3

      More details

    Country: Japan

  2. Tohoku University   Graduate School, Division of Engineering

    2008.4 - 2011.3

      More details

    Country: Japan

    researchmap

Professional Memberships 5

  1. The Ceramic Society of Japan

  2. The Chemical Society of Japan

  3. The Materials Research Society of Japan

  4. 希土類学会

  5. Japan Society of Powder and Powder Metallurgy

Committee Memberships 3

  1. 東海化学工業会   幹事  

    2023.6   

      More details

    Committee type:Academic society

  2. 公益社団法人日本セラミックス協会   行事企画委員 幹事  

    2022.4   

      More details

    Committee type:Academic society

  3. 公益社団法人日本セラミックス協会   行事企画委員  

    2020.4 - 2022.3   

      More details

    Committee type:Academic society

Awards 3

  1. 第57回東海化学工業会賞学術賞

    2022.5   東海化学工業会   水溶液プロセスによる無機結晶の構造形態制御と高機能化

    小林亮

     More details

    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  2. 第70回(平成27年度)日本セラミックス協会賞進歩賞

    2016.6   公益社団法人 日本セラミックス協会   多形・形態を制御した酸化チタンの合成とその展開

     More details

    Award type:Award from Japanese society, conference, symposium, etc.  Country:Japan

  3. 第25回(平成26年度)トーキン科学技術賞

    2015.3   公益財団法人 トーキン科学技術振興財団   水熱法による酸化チタンのナノマクロ構造制御と高機能化

     More details

    Award type:Award from publisher, newspaper, foundation, etc.  Country:Japan

 

Papers 127

  1. Z-scheme water splitting utilizing CuLi1/3Ti2/3O2 as a hydrogen-evolving photocatalyst with response up to 600 nm Invited Reviewed

    Shunya Yoshino, Tanya Kurutach, Qingshan Liu, Toshiki Yamanaka, Shunsuke Nozawa, Makoto Kobayashi, Hiromu Kumagai, Hideki Kato

    Sustainable Energy & Fuels   Vol. 8 ( 6 ) page: 1260 - 1268   2024.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D3SE01622F

  2. Multiemission of Ce3+ from Single Crystallographic Site Induced by Disordering of Ions Reviewed

    Takuya Yasunaga, Makoto Kobayashi, Kenji Oqmhula, Huan Qi, Tom Ichibha, Kenta Hongo, Shunsuke Yamamoto, Ryo Maezono, Masaya Mitsuishi, Minoru Osada, Hideki Kato, Masato Kakihana

    Inorganic Chemistry   Vol. 63 ( 2 ) page: 1288 - 1295   2024.1

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.3c03789

  3. Hetero-assembly design of 2D oxide nanosheets for tailored thermal shielding materials Reviewed

    Hirofumi Tsunematsu, Keita Nishibashi, Eisuke Yamamoto, Makoto Kobayashi, Tomohiro Yoshida, Minoru Osada

    Applied Physics Express   Vol. 17   page: 015002   2024.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.35848/1882-0786/ad13ce

  4. Facile Synthesis of Pd Nanosheets and Implications for Superior Catalytic Activity Reviewed

    Sumiya Ando, Eisuke Yamamoto, Makoto Kobayashi, Akichika Kumatani, Minoru Osada

    ACS Nano   Vol. 18 ( 1 ) page: 461 - 469   2023.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsnano.3c07861

  5. Gigantic Thermal Shielding in 2D Oxide Nanosheets Reviewed

    Hirofumi Tsunematsu, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Tomohiro Yoshida, Minoru Osada

    ACS Nano   Vol. 17 ( 2 ) page: 11396 - 11405   2023.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsnano.3c00815

  6. Ultrahigh Energy Storage in 2D High-κ Perovskites Reviewed

    Hyung-Jun Kim, Shu Morita, Ki-Nam Byun, Yue Shi, Takaaki Taniguchi, Eisuke Yamamoto, Makoto Kobayashi, Yasuo Ebina, Takayoshi Sasaki, Minoru Osada

    Nano Letters   Vol. 23 ( 9 ) page: 3788 - 3795   2023.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.nanolett.3c00079

  7. 2D Bismuth Oxyfluorides: A New Member of Cationic Nanosheets Reviewed

    Makoto Kobayashi, Tsubasa Tasaka, Eisuke Yamamoto, Minoru Osada

    Chemistry Letters   Vol. 52 ( 6 ) page: 449 - 451   2023.4

     More details

    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.230136

  8. Pseudo-Topotactic Transformation from Oxide Nanosheets to Amorphous Nanosheets Reviewed

    Hikaru Sugimoto, Makoto Kobayashi, Eisuke Yamamoto, Minoru Osada

    Chemistry Letters   Vol. 52 ( 5 ) page: 322 - 324   2023.4

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.230073

  9. Composite design of 2D inorganic nanosheets for flexible energy storage capacitors Reviewed

    Ki Nam Byun, Shi Yue, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    Journal of the Ceramic Society of Japan   Vol. 131 ( 4 ) page: 77 - 82   2023.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2109/jcersj2.22150

  10. Automated One-Drop Assembly for Facile 2D Film Deposition Reviewed

    Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    ACS Applied Materials & Interfaces   Vol. 15 ( 18 ) page: 22737 - 22743   2023.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acsami.3c02250

  11. Free-standing Molecularly Thin Amorphous Silica Nanosheets Reviewed

    Eisuke Yamamoto, Kosuke Fujihara, Yuma Takezaki, Kentaro Ito, Yue Shi, Makoto Kobayashi, Minoru Osada

    Small   Vol. 19 ( 22 ) page: 2300022   2023.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/smll.202300022

  12. Molecularly Thin BaTiO3 Nanosheets with Stable Ferroelectric Response Reviewed International coauthorship

    Kazuki Hagiwara, Ki Nam Byun, Shu Morita, Eisuke Yamamoto, Makoto Kobayashi, Xioyang Liu, Minoru Osada

    Advanced Electronic Materials   Vol. 9 ( 3 ) page: 2291239   2023.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/aelm.202201239

  13. Damage-free LED lithography for atomically thin 2D material devices Reviewed

    Yue Shi, Takaaki Taniguchi, Ki-Nam Byun, Daiki Kurimoto, Eisuke Yamamoto, Makoto Kobayashi, Kazuhito Tsukagoshi, Minoru Osada

    Scientific Reports   Vol. 13 ( 1 ) page: 2583   2023.2

     More details

    Language:English  

    DOI: 10.1038/s41598-023-29281-w

  14. Improved energy storage performance of PVDF nanocapacitors by utilizing 2D inorganic barrier Reviewed International coauthorship

    Byun Ki-Nam, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    Chemistry Letters   Vol. 52 ( 1 ) page: 51 - 54   2022.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.220466

  15. Tailored synthesis of molecularly thin platinum nanosheets using designed 2D surfactant solids Invited Reviewed

    Eisuke Yamamoto, Akiko Suzuki, Makoto Kobayashi, Minoru Osada

    Nanoscale   Vol. 14 ( 32 ) page: 11561 - 11567   2022.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D2NR01807A

  16. Influences of pulverization and annealing treatment on photocatalytic activity of BiVO4 for oxygen evolution Reviewed

    Kazuya Okuno, Hiromu Kumagai, Junie Jhon M. Vequizo, Kosaku Kato, Makoto Kobayashi, Akira Yamakata, Masato Kakihana, Hideki Kato

    Sustainable Energy Fuels   Vol. 6 ( 7 ) page: 1698 - 1707   2022.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/D2SE00065B

  17. Synthesis of brookite-type TiO2 nanoparticles by emulsion assisted hydrothermal method using titanium glycolate complex Reviewed

    Kohei Kasuya, Md. Shahiduzzaman, Makoto Kobayashi, Shu Yin, Masato Kakihana, Koji Tomita

    Journal of the Ceramic Society of Japan   Vol. 129 ( 12 ) page: 720 - 724   2021.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2109/jcersj2.21127

  18. Facile titania nanocoating using single droplet assembly of 2D nanosheets Reviewed International journal

    Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    Journal of the Ceramic Society of Japan     2021.4

  19. Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents Reviewed International journal

    Yusuke Asakura, Tomoyo Akahira, Makoto Kobayashi, Minoru Osada, Shu Yin

    Inorganic Chemistry   Vol. 59 ( 15 ) page: 10707 - 10716   2020.8

     More details

    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.inorgchem.0c01175

    Web of Science

    Scopus

  20. Z-scheme water splitting by microspherical Rh-doped SrTiO3 photocatalysts prepared by a spray drying method Reviewed International journal

    Hong Phong Duong, Takahiro Mashiyama, Makoto Kobayashi, Akihide Iwase, Akihiko Kudo, Yusuke Asakura, Shu Yin, Masato Kakihana, Hideki Kato

    Applied Catalysis B: Environmental   Vol. 252   page: 222 - 229   2019.9

     More details

    Publishing type:Research paper (scientific journal)   Publisher:Elsevier BV  

    DOI: 10.1016/j.apcatb.2019.04.009

    Web of Science

    researchmap

  21. Anisotropy in Stable Conformations of Hydroxylate Ions between the {001} and {110} Planes of TiO2 Rutile Crystals for Glycolate, Lactate, and 2-Hydroxybutyrate Ions Studied by Metadynamics Method. Reviewed International journal

    Hiroki Nada, Makoto Kobayashi, Masato Kakihana

    ACS omega   Vol. 4 ( 6 ) page: 11014 - 11024   2019.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    Control over TiO2 rutile crystal growth and morphology using additives is essential for the development of functional materials. Computer simulation studies on the thermodynamically stable conformations of additives at the surfaces of rutile crystals contribute to understanding the mechanisms underlying this control. In this study, a metadynamics method was combined with molecular dynamics simulations to investigate the thermodynamically stable conformations of glycolate, lactate, and 2-hydroxybutyrate ions at the {001} and {110} planes of rutile crystals. Two simple atom-atom distances were selected as collective variables for the metadynamics method. At the {001} plane, a conformation in which the COO- group was oriented toward the surface was found to be the most stable for the lactate and 2-hydroxybutyrate ions, whereas a conformation in which the COO- group was oriented toward water was the most stable for the glycolate ion. At the {110} plane, a conformation in which the COO- group was oriented toward the surface was the most stable for all three hydroxylate ions, and a second most stable conformation was also observed for the lactate ion at positions close to the {110} plane. For all three hydroxylate ions (α-hydroxycarboxylate ions), the stability of the most stable conformation was higher for the {110} plane than for the {001} plane. At both planes, the stability of the most stable conformation was highest for the 2-hydroxybutyrate ion and lowest for the glycolate ion. Supposing that all three hydroxylate ions serve to decrease the surface free energy at the rutile surface and that a more stable conformation at the rutile surface leads to a greater decrease in the surface free energy, the present results partially explain experimentally observed differences in the changes in growth rate and morphology of rutile crystals in the presence of glycolic, lactic, and 2-hydroxybutyric acids.

    DOI: 10.1021/acsomega.9b01100

    Web of Science

    PubMed

    researchmap

  22. Selective Synthesis and Photocatalytic Oxygen Evolution Activities of Tantalum/Nitrogen-Codoped Anatase, Brookite and Rutile Titanium Dioxide Reviewed International journal

    Nishioka, Shunta, Kobayashi, Makoto, Lu, Daling, Kakihana, Masato, Maeda, Kazuhiko

    Bulletin of the Chemical Society of Japan   Vol. 92 ( 6 ) page: 1032 - 1038   2019.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Tantalum/nitrogen codoped titanium dioxide (TiO2:Ta,N) having a rutile structure has recently been reported to be a good photocatalyst for visible-light water oxidation. In this work, three different polymorphs of TiO2:Ta,N (anatase, brookite and rutile) were synthesized by a hydrothermal method using water-soluble titanium/tantalum complexes as precursors, followed by thermal nitridation with dry ammonia gas. Effects of the physicochemical properties on photocatalytic activity for O-2 evolution from an aqueous silver nitrate solution under visible light (lambda > 400 nm) were investigated. Experimental results indicated that defect formation during the nitridation procedure was the dominant factor for photocatalytic activity. Anatase TiO2:Ta,N was the most active for O-2 evolution among the three polymorphs, and also served as an O-2 evolution photocatalyst in Z-scheme overall water splitting in combination with Rh-doped strontium titanate (SrTiO3:Rh) and an Fe3+/Fe2+ redox-shuttle mediator.

    DOI: 10.1246/bcsj.20190037

    Web of Science

    researchmap

  23. Synthesis of Ba1-xSr#x#IRYSi2O5N and Discussion Based on Structure Analysis and DFT Calculation Reviewed International journal

    Takuya Yasunaga, Makoto Kobayashi, Kenta Hongo, Kotaro Fujii, Shunsuke Yamamoto, Ryo Maezono, Masatomo Yashima, Masaya Mitsuishi, Hideki Kato, Masato Kakihana

    Journal of Solid State Chemistry   Vol. 276   page: 266-271   2019.5

     More details

    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.jssc.2019.05.012

    researchmap

  24. Crystal structures of Ca4+xY3-xSi7O15+xN5-x (0 <= x <= 1) comprising of an isolated [Si7(O,N)19] unit Reviewed International journal

    Kobayashi, Makoto, Yasunaga, Takuya, Kato, Hideki, Fujii, Kotaro, Yashima, Masatomo, Kakihana, Masato

    Acta Crystallographica Section E: Crystallographic Communications   Vol. 75   page: 260 - +   2019.2

     More details

    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:INT UNION CRYSTALLOGRAPHY  

    Single crystals of the solid solution series Ca(4+x)Y(3-x)Si(7)O(15+x)N(5-x )were obtained by a solid-state reaction method using a flux for x = 0, 0.5 and 1, resulting in Ca4Y3Si7O15N5 (tetracalcium triyttrium heptasilicon oxynitride), Ca-4.5 Y-2.5 Si7O15.5N4.5 and Ca5Y2Si7O16N4 (pentacalcium diyttrium heptasilicon oxynitride). Single-crystal X-ray analysis revealed that the three compounds are isotypic and belong to space-group type P6(3)/m. Ca2+ and Y3+ cations are distributed over two crystallographic sites (site symmetry (3) over bar.. and 1) in a disordered manner. The corresponding (Ca,Y)-centred polyhedra are connected by edge-sharing, resulting in the formation of a layer structure extending parallel to (001). Three [Si(O,N)](4) tetrahedra (two with point group symmetry m one with 3.. and half-occupancy) are condensed into an isolated [Si-7(O,N)(19)] unit, in which an [Si(O,N)](4) tetrahedron is located at the center of a 12-membered oxynitride ring with composition [Si6O15N3]. The present compounds are the first to have such an [Si-7(O,N)(1)(9)] unit in their structures.

    DOI: 10.1107/S2056989019001257

    Web of Science

    researchmap

  25. Hydrothermal Synthesis of Pseudocubic Rutile-Type Titania Particles International journal

    Makoto Kobayashi, Hideki Kato, Takamichi Miyazaki, Masato Kakihana

    Ceramics   Vol. 2 ( 1 ) page: 56-63   2019.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3390/ceramics2010005

    researchmap

  26. Sodium titanium oxide bronze nanoparticles synthesized via concurrent reduction and Na+-doping into TiO2(B) Reviewed International journal

    Hasegawa, George, Tanaka, Moeko, Vequizo, Junie Jhon M., Yamakata, Akira, Hojo, Hajime, Kobayashi, Makoto, Kakihana, Masato, Inada, Miki, Akamatsu, Hirofumi, Hayashi, Katsuro

    Nanoscale   Vol. 11 ( 3 ) page: 1442 - 1450   2019.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    A mixed valence compound, sodium titanium oxide bronze (NaxTiO2-B), combines intriguing properties of high electric conductivity and good chemical stability together with a unique one-dimensional tunnel crystal structure available for cation storage. However, this compound has not been studied for a long period because of the strongly reductive condition at high temperature required for its preparation, which limits the morphological control such as the preparation of nanocrystals. For the first time in this paper, the topotactic synthesis of nano-sized NaxTiO2-B with high specific surface area (>130 m(2) g(-1)) from TiO2(B) nanoparticles has been demonstrated. The reaction of metastable TiO2(B) with NaBH4 allows carrier electrons to be doped simultaneously with incorporation of Na+ ions into the interstitial sites of the host Ti-O lattice at relatively low temperature. An electrochemical investigation of Li+- and Na+-ion storage behaviors suggests that the incorporated Na+ ions are mainly placed in the 6-fold coordination sites of bronze. In addition, optical measurements including time-resolved transient spectroscopy revealed that the doped electrons in the NaxTiO2-B nanoparticles are predominantly in the Ti3+ state and behave as a small polaron. The pelletized NaxTiO2-B nanoparticles shows a good electronic conductivity of 1.4 x 10(-2) S cm(-1) at 30 degrees C with an activation energy of 0.17 eV, which is attributable to the thermal barrier for the polaron hopping.

    DOI: 10.1039/c8nr08372j

    Web of Science

    researchmap

  27. B-site-ordered Double-perovskite Oxide Up-conversion Phosphors Doped with Yb and Ho, Er, or Tm Reviewed International journal

    Kasuya, Kohei, Sato, Yasushi, Kobayashi, Makoto, Kato, Hideki, Kakihana, Masato, Tomita, Koji

    Journal of Photopolymer Science and Technology   Vol. 32 ( 4 ) page: 593 - 596   2019

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:TECHNICAL ASSOC PHOTOPOLYMERS,JAPAN  

    B-site-ordered double-perovskite oxide up-conversion phosphors La2ZnTiO6, La2MgTiO6, and Ba2LaTaO6 doped with Yb and Ho, Er, or Tm were synthesized by a citric acid complex gelation method and a polymerizable complex method. Under 980-nm excitation, the double-perovskite oxide phosphors doped with luminescent ions at the A-site (La2ZnTiO6 and La2MgTiO6) showed stronger up-conversion emission than the phosphor doped with luminescent ions at the B-site (Ba2LaTaO6). La2ZnTiO6 and La2MgTiO6, in which dopants occupied the A-site, showed different up-conversion emission behaviors because of structural distortion resulting from the substitution of B-site cations.

    DOI: 10.2494/photopolymer.32.593

    Web of Science

    researchmap

  28. Ce4+-based Compounds Capable of Photoluminescence by Charge Transfer Excitation under Near Ultraviolet-Visible Light Reviewed International journal

    Dawei Wen, Hideki Kato, Makoto Kobayashi, Shunsuke Yamamoto, Masaya Mitsuishi, Kotaro Fujii, Masatomo Yashima, Masato Kakihana

    Inorganic chemistry   Vol. 57 ( 23 ) page: 14524 - 14531   2018.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Ce4+-based charge transfer phosphor is not common and has been reported mainly in Sr2CeO4 with an excitation band peaking at ∼290 nm, mismatching with the near-ultraviolet light emitting diodes. Herein, we report a new series of Ce4+-based compounds Sr4.4Ce2.6REZnO12 (RE = Y, La, and Eu) capable of photoluminescence induced by O2--Ce4+ charge transfer excitation under near-ultraviolet-visible light. The crystal structure of Sr4.4Ce2.6EuZnO12 was determined by single crystal X-ray diffraction. The RE = La and Y samples were confirmed to be iso-structure compounds of the RE = Eu sample by powder X-ray diffraction. By introducing highly covalent Zn2+-O2- bonds into the framework, the Ce4+-O2- bonds are lengthened due to the effect of the Ce4+-O2--Zn2+ stretch. The lengthened Ce4+-O2- bond weakens the repulsion of the electrons between Ce4+ and O2-, thereby lowering the charge transfer energy to the visible light region. Incorporation of Eu3+ into the present compounds realized red emission under near-ultraviolet-visible excitation by the O2--Ce4+ charge transfer followed by energy transfer to Eu3+.

    DOI: 10.1021/acs.inorgchem.8b01900

    Scopus

    PubMed

    researchmap

  29. Expansion of Photoresponse Window of BiVO4 Photocatalyst by Doping of Chromium(VI) Reviewed International journal

    Kazuya Okuno, Hideki Kato, Junie Jhon, M. Vequizo, Yamakata Akira, Hisayoshi Kobayashi, Makoto Kobayashi, Masato Kakihana

    RSC Advances   Vol. 8 ( 67 ) page: 38140-38145   2018.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/C8RA07830K

    Scopus

    researchmap

  30. Photoluminescence Properties of Layered Perovskite-type Strontium Scandium Oxyfluoride Activated with Mn4+ Reviewed

    Hideki Kato*, Yohei Takeda, Makoto Kobayashi, Hisayoshi Kobayashi, Masato Kakihana

    Frontiers in Chemistry   Vol. 6   page: 467   2018.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.3389/fchem.2018.00467

  31. Structural Change in SrSiO3 Induced by Introduction of Nitrogen Reviewed

    Makoto Kobayashi, Jihae Kim, Hironori Sato, Takuya Yasunaga, Hideki Kato*, Kotaro Fujii, Masahiro Shiraiwa, Masatomo Yashima, Masato Kakihana

    Chemistry Letters   Vol. 47 ( 10 ) page: 1327-1329   2018.10

     More details

    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.180620

  32. Effects of Crystal Structure on Up-Conversion Luminescence in Er3+/Yb3+ Co-Doped SrTa4O11 Reviewed International journal

    Sayaka Tamura, Michio Iwaoka, Yasushi Sato, Makoto Kobayasi, Masato Kakihana, Koji Tomita

    Chemistry Letters   Vol. 47 ( 10 ) page: 1282-1284   2018.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.180605

    researchmap

  33. High Temperature Hydrogen Gas Sensing Property of GaN Prepared from α-GaOOH Reviewed

    Angga Hermawan, Yusuke Asakura, Makoto Kobayashi, Masato Kakihana, and Shu Yin*

    Sensors and Actuators B: Chemical   Vol. 276   page: 388-396   2018.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.snb.2018.08.021

  34. Development of Mixed Anion Phosphors Invited Reviewed

    Kobayashi Makoto, Kato Hideki, Kakihana Masato

    Ceramics Japan   Vol. 52 ( 12 ) page: 816-819   2017.12

     More details

    Authorship:Lead author   Language:Japanese  

    1518

  35. Synthesis of Rare Earth Niobate and Tantalate Powders via a Peroxo Complex Route Reviewed International journal

    Hideki Kato, Katsuya Shimizu, Kiyotaka Nakajima, Makoto Kobayashi, Masato Kakihana

    Chemistry Letters   Vol. 46 ( 10 ) page: 1515 - 1517   2017.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Powders of REMO4 (RE: rare earth, M: Nb and Ta) were synthesized by a coprecipitation method employing water-soluble peroxo Nb/Ta complexes. This peroxo-based method is an aqueous solution route free from organics and halides. REMO4 was directly crystallized by annealing the precursor under moderate conditions. It has been revealed that the precursors are also useful for synthesis of oxynitrides under mild nitriding conditions.

    DOI: 10.1246/cl.170652

    Web of Science

    researchmap

  36. Effect of hydroxy and carboxy groups on anisotropic growth of rutile-type titania under hydrothermal conditions Reviewed International journal

    Makoto Kobayashi, Sungho Lee, Hideki Kato, Masato Kakihana

    Journal of Asian Ceramic Societies   Vol. 5 ( 3 ) page: 320 - 325   2017.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier B.V.  

    Control of crystal growth leads to highly functional materials with desired morphologies. In this study, the relationship between select additives and the crystal growth of rutile-type titania under hydrothermal conditions using α-hydroxy acids, carboxylic acids, or alcohols as additives was systematically investigated. Without additives, rod-like rutile crystals with average dimensions of 295 nm × 67 nm were formed. Acceleration of the crystal growth was observed and the aspect ratios of the resulting rod-like crystals were found to increase in the presence of the additives. Alcohols promoted crystal growth along the c-axis, but not in the direction to perpendicular to [001]. Carboxylic acids accelerated the overall crystal growth and this increase was more enhanced along the c-axis than that along others. Both effects were observed using α-hydroxy acids. In addition, the present results implied that the size of the hydrocarbon groups in alcohols and α-hydroxy acids appeared to be related to the acceleration of crystal growth along the c-axis. Hydroxy groups may reduce the surface energy of the crystal facets perpendicular to the c-axis by their adsorption on those facets, resulting in the formation of rod-like crystals with high aspect ratio.

    DOI: 10.1016/j.jascer.2017.06.006

    Web of Science

    Scopus

    researchmap

  37. Growth of TiO2 microspheres with a radially oriented configuration Reviewed International journal

    Quang Duc Truong, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    CrystEngComm   Vol. 19 ( 32 ) page: 4832 - 4837   2017.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Crystalline mesoporous materials with oriented configurations are promising for high-performance energy storage and conversion devices. In this work, hierarchical microspheres constructed from radially oriented single-crystalline TiO2 nanorods have been fabricated by a facile hydrothermal approach using oxalic acid as a chelating and structure-directing agent. The obtained mesoporous TiO2 microspheres have been characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and Brunauer-Emmett-Teller specific surface area measurement to reveal their unique properties. The growth and assembly process of the nanorod-based microspheres were elucidated in view of chelation-assisted assembly. It was found that oxalic acid played a crucial role in the oriented assembly of nanorods into well-defined microspheres.

    DOI: 10.1039/c7ce01158j

    Web of Science

    researchmap

  38. Photoluminescence Properties of Double Perovskite Tantalates Activated with Mn4+, AE2LaTaO6:Mn4+ (AE = Ca, Sr, and Ba) Reviewed International journal

    Yohei Takeda, Hideki Kato, Makoto Kobayashi, Shunsuke Nozawa, Hisayoshi Kobayashi, Masato Kakihana

    Journal of Physical Chemistry C   Vol. 121 ( 34 ) page: 18837 - 18844   2017.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    Tetravalent manganese is known as one of the candidate luminous centers to obtain red emission. There are still unclear factors in Mn4+-activated oxide phosphors to achieve intense emission. In this paper, we studied the photoluminescence properties of double perovskite-type tantalates AE(2)LaTaO(6) (AE = Ca, Sr, and Ba) activated with Mn4+. All AE(2)LaTaO(6):Mn exhibited Mn4+-emission in the deep red region under excitation by near ultraviolet-green light (300-570 nm) at room temperature. Co-substitution of Mg2+, Al3+, and Ti4+ compensates unbalanced charge caused by oxygen defects, resulting in the enhancement of Mn4(+-)emission. The present cosubstitution effect is different from the usual cosubstitution, such as the replacement of two Al3+ by Mn4+ and Mg2+, taking into consideration the charge balance between cations. Theoretical calculation of band structures based on density functional theory suggests the presence of two kinds of quenching schemes in AE(2)LaTaO(6):Mn, photoionization and electron transfer from valence band to t(2g) orbitals of Mn.

    DOI: 10.1021/acs.jpcc.7b06280

    Web of Science

    Scopus

    researchmap

  39. Development of Crystal Growth Based on Aqueous Solution Processes Invited Reviewed

    Makoto Kobayashi

    Ceramics Japan   Vol. 52 ( 7 ) page: 502-503   2017.7

     More details

    Authorship:Lead author   Language:Japanese  

  40. Synthesis and photocatalytic properties of tetragonal tungsten bronze type oxynitrides Reviewed International journal

    Katsuya Shimizu, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    Applied Catalysis B: Environmental   Vol. 206   page: 444 - 448   2017.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER SCIENCE BV  

    Synthesis of a series of oxynitride Ba3-chi La chi Ta5O14-chi N1+x (x= 0-1.5) with a tetragonal tungsten bronze (TTB) structure was examined using moist-NH3 and 5% NH3-N-2 as nitriding atmosphere. The samples with x=0-1 were successfully obtained as phase pure TTB oxynitride whereas the x= 1.5 samples gave a mixture of TTB oxynitride, Ta3N5, and LaTaO4. Absorption of TTB oxynitrides in visible region was enhanced as increasing the content of nitrogen. TTB oxynitrides exhibited both of H-2 and O-2 evolution under visible light in the presence of methanol and silver ions, respectively, as sacrificial reagents. Nitrogen poor surface in the samples synthesized under moist-NH3 atmosphere was modified by annealing treatment using 5% NH3, resulting in improvement of photocatalytic activity for H2 evolution. Evaluation using monochromatic light revealed that the apparent quantum efficiency of Ba2LaTa5O13N2 was higher than that of Ba3Ta5O14N. (C) 2017 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.apcatb.2017.01.057

    Web of Science

    researchmap

  41. Synthesis, Structure, and Photoluminescence of a Novel Oxynitride BaYSi2O5N Activated by Eu2+ and Ce3+ Reviewed International journal

    Makoto Kobayashi, Takuya Yasunaga, Hironori Sato, Hideki Kato, Kotaro Fujii, Masatomo Yashima, Masato Kakihana

    Chemistry Letters   Vol. 46 ( 6 ) page: 795 - 797   2017.6

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    A novel oxynitride, BaYSi2O5N, has been synthesized by a solid-state reaction method. Its crystal structure was determined by single-crystal X-ray analysis. Eu2+- and Ce3+-doped BaYSi2O5N exhibit broad blue emission with peaks around 459 and 412 nm under excitation at 250-450 and 250-370 nm, respectively. This is the first report on the synthesis of oxynitrides in the BaO-Y2O3-SiO2-Si3N4 system.

    DOI: 10.1246/cl.170144

    Web of Science

    researchmap

  42. Site occupancy and luminescence properties of Ca3Ln(AlO)3(BO3)4:Ce3+,Tb3+,Mn2+ (Ln = Y, Gd) Reviewed International journal

    Dawei Wen, Hideki Kato, Makoto Kobayashi, Shunsuke Yamamoto, Masaya Mitsuishi, Masato Kakihana

    Journal of Materials Chemistry C   Vol. 5 ( 18 ) page: 4578 - 4583   2017.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    In this work, novel single-phase white emitting Ca(3)Ln(AlO)(3)(BO3)(4): Ce3+, Tb3+, Mn2+ (Ln = Y and Gd) phosphors were synthesized by a conventional solid-state reaction method. The crystal structure and photoluminescence properties were investigated for the first time. The structure of Ca(3)Ln(AlO) (3)(BO3)(4) was formed by AlO6 octahedral chains interconnected by BO3 triangles. Along the [001] direction, the Ca/Ln cations fill in the trigonal and hexagonal tunnels. For Ca(3)Ln(AlO)(3)(BO3)(4): Ce3+ and Ca(3)Ln(AlO)(3)(BO3)(4): Mn2+, large Ce3+ preferred to occupy the smaller coordination site, while small Mn2+ occupied the larger coordination site, which was explained by the space hindrance. Due to the cation disorder, the local environment of Ce3+ was complicated and the emission band was extremely broad. In Ca(3)Ln(AlO) (3)(BO3)(4), the emission color can be tuned from blue to green or red by tuning the Ce3+-Tb3+ or Ce3+-Mn2+ concentration based on energy transfer. Thus, the combination of blue, green and red emitting Ce3+, Tb3+ and Mn2+ generated white emission.

    DOI: 10.1039/c7tc00941k

    Web of Science

    researchmap

  43. Investigation of the Up-conversion Properties of Er-Yb-doped Calcium Tantalates with Various Ca/Ta Ratios Reviewed International journal

    Sayaka Tamura, Michio Iwaoka, Yasushi Sato, Makoto Kobayashi, Masato Kakihana, Koji Tomita

    Journal of Photopolymer Science and Technology   Vol. 30 ( 4 ) page: 507 - 512   2017

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:TECHNICAL ASSOC PHOTOPOLYMERS,JAPAN  

    Er3+/Yb3+ co-doped calcium tantalate up-conversion (UC) phosphors were synthesized via a parallel synthesis scheme using the gelable citrate complex method. Samples with various Ca/Ta atomic ratios were prepared, and their UC emission properties were compared. Under 980-nm near-infrared laser excitation, alpha-CazTa(2)O(7) : Er3+, Yb3+ showed an extremely weak UC emission intensity and CaTa4O11 : Er3+, Yb3+ demonstrated an excellent UC emission intensity. In addition, the local symmetry around the rare-earth dopant ions affected the UC luminescence properties.

    DOI: 10.2494/photopolymer.30.507

    Web of Science

    researchmap

  44. Exploration of New Oxynitride Phosphors Using a Vacuum-Pressure Sintering Furnace Invited

    Hideki Kato, Hironori Sato, Takuya Yasunaga, Makoto Kobayashi, Masato Kakihana, Fumiyoshi Isobe

    Shimadzu Review   Vol. 73 ( 3・4 ) page: 129-135   2016.12

     More details

    Language:Japanese  

  45. Synthesis and Development of Titania with Controlled Structures Invited Reviewed

    Makoto Kobayashi

    Journal of the Ceramic Society of Japan   Vol. 124 ( 9 ) page: 863-869   2016.9

     More details

    Authorship:Lead author   Language:English  

    DOI: 10.2109/jcersj2.16117

  46. Screening of Er3+/Yb3+ Co-doped RE-Ta-O and RE-Nb-O (RE = Y, La, or Gd) Up-conversion Phosphors Reviewed International journal

    Sayaka Tamura, Michio Iwaoka, Yasushi Sato, Makoto Kobayashi, Masato Kakihana, Koji Tomita

    Chemistry Letters   Vol. 45 ( 8 ) page: 890 - 891   2016.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Upconversion (UC) phosphors comprising Er3+/Yb3+ co-doped rare-earth complex oxides, RExTayOz and RExNbyOz (RE = Y, La, or Gd), were synthesized via the gelable citrate complex method, and their UC emission properties were compared. This led to the discovery of an intense green-emitting UC phosphor, YTa7O19:Er3+/Yb3+, which is the first example of a YTa7O19 UC phosphor host material. Green UC emission obtained using optimum Er3+ and Yb3+ content was 20 times stronger than that obtained using a Y2O3 host.

    DOI: 10.1246/cl.160413

    Web of Science

    researchmap

  47. Anomalous Orange Light Emitting (Sr,Ba)2SiO4:Eu2+ Phosphors for Warm White LEDs Reviewed International journal

    Dawei Wen, Hiroki Kuwahara, Hideki Kato, Makoto Kobayashi, Yasushi Sato, Takaki Masaki, Masato Kakihana

    ACS Applied Materials & Interfaces   Vol. 8 ( 18 ) page: 11615 - 20   2016.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Phosphors with sufficient red emission component are necessary for warm white light-emitting diodes. In this work on (Sr,Ba)2(1-x)Eu2xSiO4 phosphors, (Sr,Ba)1.5Eu0.5SiO4 achieved 75% of an internal quantum efficiency under excitation by blue light. Surprisingly, the (Sr,Ba)1.5Eu0.5SiO4 exhibited orange emission, against the well-known traditional green-yellow emission of (Sr,Ba)2SiO4:Eu(2+). Moreover, the concentration quenching of Eu(2+) in (Sr,Ba)2SiO4 was abnormally unobvious. With the help of calculations based on the density functional theory, it was discovered that the distinct local environment of luminescence centers rather than usual explanation such as self-absorption or intensified crystal field splitting, is responsible to the interesting red shifts in excitation and emission spectra. The refinement analysis based on X-ray diffraction revealed that the unequal distribution of Eu(2+) to two crystallographic sites caused low concentration of Eu(2+) at the 9-coordination site, inhibiting the concentration quenching. The (Sr,Ba)1.5Eu0.5SiO4 phosphor has warmer emission than the commercial Y3Al5O12:Ce(3+). This study also promotes research on the effect of site occupancy and the local environment of luminescence centers.

    DOI: 10.1021/acsami.6b02237

    PubMed

    researchmap

  48. Anisotropy in Conformation and Dynamics of a Glycolate Ion Near the Surface of a TiO2 Rutile Crystal Between Its {001} and {110} Planes: A Molecular Dynamics Study Reviewed International journal

    H. Nada, M. Kobayashi, M. Kakihana

    Journal of Physical Chemistry C   Vol. 120 ( 12 ) page: 6502 - 6514   2016.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:AMER CHEMICAL SOC  

    A molecular dynamics simulation was conducted to elucidate the conformation and dynamics of a glycolate ion (CH2(OH)COO-) at the surface of a TiO2 rutile crystal. The simulation was performed for the {001} and {110} planes of the crystal. The results indicate that, for both planes, the conformation and dynamics of the ion are strongly dominated by a layered structure of water on the surface. The simulation suggests that the ion binds to the surface more stably on the {110} plane than on the {001} plane, and that the stable conformation of the ion at the surface differs between the planes: on the {110} plane the carboxyl group of the ion is preferentially oriented toward the surface, whereas on the {001} plane it is oriented toward liquid water. These simulation results are compared with the growth shapes of rutile crystals synthesized in the presence of glycolic acid, and the role of glycolate ions in controlling the morphology of rutile crystals is discussed.

    DOI: 10.1021/acs.jpcc.5b11087

    Web of Science

    researchmap

  49. Effect of Site Occupancy on Deep-red Emission from Eu2+-activated Ca2SiO4 Phosphor Reviewed International journal

    Hiroki Kuwahara, Yasushi Sato, Hideki Kato, Makoto Kobayashi, Takaki Masaki, Masato Kakihana

    Chemistry Letters   Vol. 45 ( 3 ) page: 321 - 323   2016.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Calcium silicate cosubstituted with Sr2+ and Eu2+ was studied in order to examine the relationship between emission characteristics and Eu2+ occupancy at two types of Ca sites (Ca(1n) and Ca(2n)). The results clearly indicate that red emission of the Ca2SiO4:Eu2+ phosphor is caused by Eu2+ substitution at the Ca(2n) site. In addition, red shift in emission of Eu(2n) occurs when large amounts of Eu were substituted.

    DOI: 10.1246/cl.151145

    Web of Science

    researchmap

  50. Self-assembly of polyethyleneamine-intercalated H2Ti2O5 nanoparticles into spherical agglomerates Reviewed International journal

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Journal of Materials Research   Vol. 31 ( 5 ) page: 564 - 572   2016.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CAMBRIDGE UNIV PRESS  

    Although there are numerous reports on the synthesis of spherical materials, the development of new approaches remains important for theory construction to realize tailor-made synthesis of spherical materials. Herein, we report the synthesis of polydispersed spherical particles of H2Ti2O5 intercalated with a polyethyleneamine, such as an ethylenediamine, on the basis of a solvothermal treatment using concentrated polyethyleneamine aqueous solutions. The diameter of the micrometer-sized spheres enlarged with increasing amine concentration in the reaction solution. It was speculated that high ionic strength caused the self-assembly of polyethyleneamine-intercalated H2Ti2O5, resulting in the formation of spherical agglomerates. The spheres had a specific a surface area of 200 m(2) g(-1) and approximately 5 nm pores, and these values were controlled by amine concentration and treatment time. Conversion to single phase anatase and rutile without changes in spherical morphology was achieved by heat treatment. The present approach may assist with the design morphology of agglomerates.

    DOI: 10.1557/jmr.2016.67

    Web of Science

    researchmap

  51. Hydrothermal Synthesis of Barium Tantalate Nanosheet Photocatalyst and Its Water Splitting Activity Reviewed

    Soichi Takasugi, Koji Tomita, Michio Iwaoka, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Journal of the Society of Inorganic Materials, Japan   Vol. 23 ( 380 ) page: 25-29   2016

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

  52. Crystal Growth of Titania Polymorphs by Hydrothermal Method(<Special Issue>Topics of Crystal Growth Related to Water) Invited Reviewed International journal

    Kobayashi Makoto, Kato Hideki, Kakihana Masato

    Journal of the Japanese Association for Crystal Growth   Vol. 42 ( 4 ) page: 283-289   2016

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    Control of crystal growth is rather important in the field of materials, because the shape directly affects their functional abilities. Our research group engages in hydrothermal synthesis of titanium dioxide, which is regarded as one of the representative ceramics, using water-soluble titanium complexes. The high chemical stability and peculiar molecule structures of these titanium complexes allowed us to use various compounds which play a role in control of crystal growth, resulting in the selective synthesis of four titanium dioxide polymorphs, that is, rutile, anatase, brookite and TiO_2(B), with a controlled shape. This paper summarizes our past study and reported researches on synthesis of titania polymorph crystals by classification of zero-, one-, two-, and three-dimensional structures.

    DOI: 10.19009/jjacg.42.4_283

    researchmap

  53. Hydrothermal Synthesis of Barium Tantalate Nanosheet Photocatalyst and Its Water Splitting Activity Reviewed International journal

    Soichi Takasugi, Koji Tomita, Michio Iwaoka, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Journal of the Society of Inorganic Materials, Japan   Vol. 23 ( 380 ) page: 25-29   2016

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    researchmap

  54. Graphene/MxWO3 (M = Na, K) nanohybrids with excellent electrical properties Reviewed International journal

    Bin Liu, Shu Yin, Xiaoyong Wu, Yuhua Wang, Yunfang Huang, Jihuai Wu, Tohru Sekino, Junichi Matsushita, Soo Wohn Lee, Makoto Kobayashi, Masato Kakihana, Tsugio Sato

    CARBON   Vol. 94   page: 309 - 316   2015.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:PERGAMON-ELSEVIER SCIENCE LTD  

    Graphene/MxWO3 (M = Na, K) nanocomposites with different weight ratios were successfully synthesized using MBH4 as a reducing agent in aqueous solution, followed by crystallization of amorphous precursors under calcination in H-2 (5 vol.%)/N-2 atmosphere at 600 degrees C. The coupled samples showed good shielding properties in NIR wavelength range together with certain visible lights transparency. The as-prepared tungsten bronze nanoparticles are homogeneously anchored on graphene sheets, and the graphene/tungsten bronze nanocomposite showed an enhanced electrical conductivity with good shielding properties in the NIR range together with certain visible lights transparency. With the increment of graphene amount in the composites, the contact between the graphene sheets was enhanced, and the MxWO3 might enhance the charge transport properties of graphene by generating the short conductive path for electrons over the remained oxygenated functional groups. The synergistic effects could be observed in the composites. When 5 wt.% or more graphene were composed into MxWO3, the hybrid composite showed the higher electrical conductivity than those of uncoupled graphene and tungsten bronze alone. (C) 2015 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.carbon.2015.06.072

    Web of Science

    researchmap

  55. Photoluminescence Properties of Mn4+</sup>-activated Perovskite-type Titanates, La2MTiO6:Mn4+ (M = Mg and Zn) Reviewed International journal

    Yohei Takeda, Hideki Kato, Makoto Kobayashi, Hisayoshi Kobayashi, Masato Kakihana

    Chemistry Letters   Vol. 44 ( 11 ) page: 1541 - 1543   2015.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    It has been found that Mn4+-activated La2MTiO6 (M = Mg and Zn) functions as novel Eu-free phosphors for red emission in this work. La2MTiO6:Mn4+ exhibited emission with a peak at 710 nm under excitation by ultraviolet to blue light (300 550 nm). La2MgTiO6:Mn4+ exhibited stronger emission than La2ZnTiO6:Mn4+. The internal quantum yield of La2MgTiO6: Mn4+ was 58.7% under the excitation at 330 nm.

    DOI: 10.1246/cl.150748

    Web of Science

    researchmap

  56. Large Redshifts in Emission and Excitation from Eu2+-Activated Sr2SiO4 and Ba2SiO4 Phosphors Induced by Controlling Eu2+ Occupancy on the Basis on Crystal-Site-Engineering Reviewed International journal

    Yasushi Sato, Hiroki Kuwahara, Hideki Kato, Makoto Kobayashi, Takaki Masaki, Masato Kakihana

    Optics and Photonics Journal   Vol. 5 ( 11 ) page: 326-333   2015.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    8479

    DOI: 10.4236/opj.2015.511031

    researchmap

  57. A Facile One-Step Solvothermal Synthesis and Electrical Properties of Reduced Graphene Oxide/Rod-Shaped Potassium Tungsten Bronze Nanocomposite. Reviewed International journal

    Bin Liu, Shu Yin, Yuhua Wang, Chongshen Guo, Xiaoyong Wu, Qiang Dong, Makoto Kobayashi, Masato Kakihana, Tsugio Sato

    Journal of nanoscience and nanotechnology   Vol. 15 ( 9 ) page: 7305 - 10   2015.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Reduced graphene oxide (rGO)/rod-shaped potassium tungsten bronze nanocomposites with the different ratio were successfully synthesized by solvothermal reaction and followed by the reduction in H2(5 vol.%)/N2 atmosphere at 550 degrees C. The coupled samples showed excellent shielding ability of NIR light as well as certain visible lights transparency. The synergistic effects could be observed in the composites, i.e., when 15 wt% and 20 wt% of rGO which was fabricated by chemical reduction of graphene oxide, were composed into K(x)WO3, the composite showed the higher electrical conductivity than those of rGO and potassium tungsten bronze.

    DOI: 10.1166/jnn.2015.10579

    PubMed

    researchmap

  58. Synthesis of picolinate-iron(III) compounds through an aqueous solution process Reviewed International journal

    Junki Sato, Makoto Kobayashi, Hideki Kato, Eunsang Kwon, Masato Kakihana

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 123 ( 1441 ) page: 751 - 755   2015.9

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    A novel picolinate-iron(III) compound, Fe(C6H4NO2)(2)(OH) (1), was synthesized from an aqueous solution of a picolinate-iron(II) complex. Compound 1 was obtained by a thermal treatment of the picolinate-iron complex aqueous solution, whose pH was adjusted to 3-7, containing more than twice molar picolinic acid (Hpa) to Fe at 353K for 72 h. When the iron aqueous solution in the presence of more than six times molar Hpa to Fe at pH 2-5 was heated, Fe(C6H4NO2)(3)center dot H2O (2) appeared. Millimeter-sized yellow-green single crystals of 2 could be obtained by the heat treatment of the picolinate-iron aqueous solution, whose pH was adjusted to 3, with Fe2+:Hpa = 1: 10 at 373K for 72 h. Formation mechanism of 1 and 2 was also discussed through investigations of relationship between synthesis conditions and products. Our approach opens a promising new route for preparation of precursors for synthesis of high functional ceramics and development of new organic-inorganic hybrids. (C) 2015 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.123.751

    Web of Science

    researchmap

  59. Novel Titanium Complexes with a Reversible Structural Change on Solvent Adsorption and Desorption Reviewed International journal

    Makoto Kobayashi, Tatsuya Okuhara, Hideki Kato, Sota Sato, Masato Kakihana

    Chemistry Letters   Vol. 44 ( 8 ) page: 1050 - 1052   2015.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Two novel pyrazine-2-carboxylate titanium complexes were synthesized from an aqueous solution (1) and 1 in N,N-dimethylformamide (DMF) (2). The structure of 2 was determined to be [Ti6O8(C4H3N2COO)(8)(C3H7NO)(4)]center dot 4C(3)H(7)NO center dot H2O by single-crystal X-ray analysis. Both complexes exhibited solvent adsorption desorption accompanying reversible structural change. 1 and 2 were compatible, and 1 was vital for the synthesis of 2. The degassed 1 showed gate adsorption property for water vapor.

    DOI: 10.1246/cl.150393

    Web of Science

    researchmap

  60. Discovery of Novel Delafossite-type Compounds Composed of Copper(I) Lithium Titanium with Photocatalytic Activity for H2 Evolution under Visible Light Reviewed International journal

    Hideki Kato, Tsuyoshi Fujisawa, Makoto Kobayashi, Masato Kakihana

    CHEMISTRY LETTERS   Vol. 44 ( 7 ) page: 973 - 975   2015.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    Novel delafossite-type compounds Cu(Li1/3Ti2/3)O-2 with 3R- and 2H-type structures have been discovered through the reaction between Li4Ti5O12 and Cu2O. Cu(Li1/3Ti2/3)O-2 is the first Cu(I)-titanate containing no d(n) (n = 1-9) metal ions. It has been found that Cu(Li1/3Ti2/3)O-2 with a band gap of 2.1 eV functions as a photocatalyst for H-2 evolution under visible light irradiation.

    DOI: 10.1246/cl.150341

    Web of Science

    researchmap

  61. Hierarchical structures of rutile exposing high-index facets Reviewed International journal

    Quang Duc Truong, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    JOURNAL OF CRYSTAL GROWTH   Vol. 418   page: 86 - 91   2015.5

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER SCIENCE BV  

    Recently, shape-controlled synthesis of crystals exposing high-index facets has attracted much research interest due to their importance for both fundamental studies and technological applications. Herein, crystals of rutile-type TiO2 with hierarchical structures exposing high-index facets have been synthesized by a facile hydrothermal method using water-soluble titanium complex as a precursor and picolinic acid as structure-directing and shape-controlling agents. The synthesized particles were composed of several branches of pyramidal crystals with relatively smooth surface. On the basis of investigation results, it was speculated that the mutual pi-stacking and selective adsorption of picolinic acid on specific {111} facets resulted in the formation of rutile crystals bound by high-index surfaces such as {331}. (C) 2015 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jcrysgro.2015.02.056

    Web of Science

    researchmap

  62. Syntheses of silicate phosphors by aqueous solution techniques using water-dispersible inorganic Si cluster Reviewed International journal

    Yasushi Sato, Hideki Kato, Makoto Kobayashi, Jihae Kim, Masato Kakihana

    Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy   Vol. 62 ( 4 ) page: 127 - 133   2015.4

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)   Publisher:Journal of the Japan Society of Powder and Powder Metallurgy  

    In this paper, we demonstrated the synthesis of silicate-based phosphors by solution techniques using glycolmodified silane (GMS) as a Si source. GMS is a water-dispersible inorganic Si cluster, which is vitally involatile and nonflammable compounds, compared to volatile and flammable Si-alkoxides such as tetraethoxysilane (TEOS). Therefore, GMS has allowed the silicon containing compounds to be synthesized through various solution processes for ceramic compounds such as polymerizable complex (PC) and amorphous metal complex (AMC) methods. This paper provides examples of synthesis of new silicate-based phosphors such as NaAlSiO4:Eu2+, BaZrSi3O9:Eu2+, and CaSrSiO4:Eu2+. In addition, other examples of improvement of emission for conventional silicate-based phosphors, Y2SiO5:Ce3+-Tb3+ and Zn2SiO4:Mn2+, prepared by the above solution techniques including homogeneous precipitation using GMS are also given in this paper.

    DOI: 10.2497/jjspm.62.127

    Scopus

    researchmap

  63. Design of crystal structures, morphologies and functionalities of titanium oxide using water-soluble complexes and molecular control agents Invited Reviewed International journal

    Makoto Kobayashi, Minoru Osada, Hideki Kato, Masato Kakihana

    Polymer Journal   Vol. 47 ( 2 ) page: 78 - 83   2015.2

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:NATURE PUBLISHING GROUP  

    Nature produces materials with excellent physical and chemical properties using water as a medium under ambient temperature and pressure. The current need for more highly functional and compact materials makes the mimicking of natural processes to produce these materials a very interesting approach, not only to obtain highly functionalized materials but also to reduce the environmental impact. Our research group is engaged in the development of new stable water-soluble compounds that follow natural processes for the synthesis of materials using water as a medium. This paper summarizes a hydrothermal synthesis of rutile-type titanium oxide using water-soluble titanium complexes, controlling the crystal morphology by utilizing organic molecules as shape-control agents as well as their speculative formation mechanism and superior dielectric properties of unusually shaped titanium oxide crystals. By recapitulating our results, we indicate that control of the nano-and macro-structures and functional improvement are accomplished through the development of new precursor compounds.

    DOI: 10.1038/pj.2014.89

    Web of Science

    researchmap

  64. Crystal structures and luminescence properties of Eu2+-activated new NaBa0.5Ca0.5PO4 and Na3Ba2Ca(PO4)3. Reviewed International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Hisanori Yamane, Yasushi Sato, Masato Kakihana

    Dalton transactions   Vol. 44 ( 4 ) page: 1900 - 4   2015.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    NaBa(1-x)Ca(x)PO4:Eu(2+) were synthesized using polymerizable complex method. New phases were observed at x = 1/3 and 0.5, which were identified by single-crystal XRD analysis as Na3Ba2Ca(PO4)3 and NaBa0.5Ca0.5PO4 with a trigonal system. Though both phases pretend to be solid solutions between NaBaPO4 and NaCaPO4, they have different coordination environments and PO4 orderings. 1 mol% Eu(2+)-activated NaBaPO4, Na3Ba2Ca(PO4)3, and NaBa0.5Ca0.5PO4 exhibited an emission maximum at 435 nm, 458 nm, and 460 nm, respectively. The shift of the emission maximum might be due to a change in the Eu-O bond length.

    DOI: 10.1039/c4dt03024a

    PubMed

    researchmap

  65. Controlled radical polymerization of styrene with magnetic iron oxides prepared through hydrothermal, bioinspired, and bacterial processes Reviewed International journal

    Arihiro Kanazawa, Kotaro Satoh, Shokyoku Kanaoka, Masato Kakihana, Makoto Kobayashi, Junki Sato, Hiroaki Imai, Yuya Oaki, Atsushi Arakaki, Kiyofumi Katagiri, Masami Kamigaito, Sadahito Aoshima

    RSC ADVANCES   Vol. 5 ( 63 ) page: 51122 - 51129   2015

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Controlled/living radical polymerization was examined with the use of magnetic iron oxide (Fe3O4) prepared through various processes, including hydrothermal synthesis, a bioinspired process, and magnetotactic bacteria. Prior to the use of various types of Fe3O4, commercially available Fe3O4 was employed as a heterogeneous catalyst for styrene polymerization in conjunction with an alkyl halide as an initiator. Under appropriately optimized conditions, with the addition of Ph3P in a solvent mixture of toluene and DMF, the polymerization proceeded in a well-controlled manner. In addition, solid Fe3O4 was recovered using a magnetic approach and was reused for a polymerization reaction. The effects of stirring on the polymerization rate suggest that the surface of Fe3O4 is responsible for the catalysis in polymerization. Fe3O4 samples prepared through various processes were then used for styrene polymerization and showed different activities depending on the preparation process. In particular, Fe3O4 prepared through hydrothermal synthesis exhibited a much higher activity compared with commercial Fe3O4.

    DOI: 10.1039/c5ra09149g

    Web of Science

    researchmap

  66. Improvement of hydrogen evolution under visible light over Zn1-2x(CuGa)xGa2S4 photocatalysts by synthesis utilizing a polymerizable complex method Reviewed International journal

    Ciro Scheremeta Quintans, Hideki Kato, Makoto Kobayashi, Hiroshi Kaga, Akihide Iwase, Akihiko Kudo, Masato Kakihana

    Journal of Materials Chemistry A   Vol. 3 ( 27 ) page: 14239 - 14244   2015

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Single phase Zn1-2x(CuGa)(x)Ga2S4 was successfully synthesized by a two-step route: synthesis of an oxide precursor by a polymerizable complex (PC) method followed by sulfurization under a H2S-Ar flow. The samples thus obtained were porous aggregates consisting of fine crystals with 50 nm size. Among the examined compositions, Zn-0.4(CuGa)(0.3)Ga2S4 (x = 0.3) showed the highest activity for H-2 evolution from an aqueous solution containing S2- and SO32- as electron donors under visible light irradiation. The apparent quantum yield of the optimized sample with deposition of 2 wt% of Rh was 19% at 420 nm. This value is higher than that of the sample synthesized by a solid state reaction (15%). Therefore, improvement of the photocatalytic performance of Zn-0.4(CuGa)(0.3)Ga2S4 for H-2 evolution has been achieved by using the two-step synthesis method including the preparation of an oxide precursor by the PC method.

    DOI: 10.1039/c5ta02114f

    Web of Science

    researchmap

  67. Photocatalytic water oxidation under visible light by valence band controlled oxynitride solid solutions LaTaON2-SrTiO3 Reviewed International journal

    Hideki Kato, Koichiro Ueda, Makoto Kobayashi, Masato Kakihana Masato

    Journal of Materials Chemistry A   Vol. 3 ( 22 ) page: 11824-11829 - 11829   2015

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/c5ta02482j

    Web of Science

    researchmap

  68. A carbon modified NaTaO3 mesocrystal nanoparticle with excellent efficiency of visible light induced photocatalysis Reviewed International journal

    Xiaoyong Wu, Shu Yin, Bin Liu, Makoto Kobayashi, Masato Kakihana, Tsugio Sato

    Journal of Materials Chemistry A   Vol. 2 ( 48 ) page: 20832 - 20840   2014.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    A carbon modified NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    mesocrystal nanoparticle (ca. 20 nm) was successfully synthesized by a one-pot solvothermal method, employing TaCl&lt
    inf&gt
    5&lt
    /inf&gt
    and NaOH as the starting materials and distilled water/EG mixed solution as a reaction solvent in the presence of appropriate amounts of glucose. The mesocrystal sample presented a high specific surface area 90.8 m&lt
    sup&gt
    2&lt
    /sup&gt
    g&lt
    sup&gt
    -1&lt
    /sup&gt
    with large amounts of well-dispersed mesopores in the particle, owing to the co-effect of EG and glucose during the reaction process. A non-classic mechanism of formation was proposed for the growth of the NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    mesocrystal. Furthermore, the NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    mesocrystal exhibited considerably improved visible light absorption in addition to the intrinsic UV light absorption as a result of carbon modification originated from glucose. On the basis of the large specific surface area, high crystallinity and optical property, the carbon modified NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    mesocrystal demonstrated excellent efficiency for continuous NO gas destruction under irradiation of UV, short wavelength visible lights (&gt
    400 m) and even long wavelength visible light (&gt
    510 nm), considerably superior to those of the unmodified NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    specimen and commercial titania, P25. The carbon modified NaTaO&lt
    inf&gt
    3&lt
    /inf&gt
    mesocrystal nanoparticles prepared in this work would probably have potential utilization in environmental purification and energy conversion.

    DOI: 10.1039/c4ta04132a

    Web of Science

    Scopus

    researchmap

  69. Development of two novel Eu2+-activated phosphors in the Na-Sc-Si-O system and their photoluminescence properties Reviewed International journal

    Jihong Min, Taichi Yamaguchi, Hideki Kato, Makoto Kobayashi, Hisanori Yamane, Masato Kakihana

    Journal of Luminescence   Vol. 154   page: 285 - 289   2014.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER SCIENCE BV  

    Two novel Eu2+-activated phosphors in the Na-Sc-Si-O system were developed in this study, NaScSi2O6:Eu and Na3ScSi3O9:Eu. NaScSi2O6:Eu2+ showed yellow emission with a peak at 555 nm under excitation at 220-430 nm. When flux-treatment was performed for NaScSi2O6:Eu2+, we found the existence of a new phase. We then succeeded in synthesis of a high-purity sample of this new compound by a parallel solution synthesis method. It was revealed that the new phase was Na3ScSi3O9 with isostructure to Na3YSi3O9, and Eu2+-activated Na3ScSi3O9 exhibited photoluminescence. Na3ScSi3O9:Eu showed green emission with a peak at 530 nm and a corresponding broad excitation band up to 500 nm. However, photoluminescence of Eu2+ was negligible for Na3YSi3O9:Eu because of the stabilization of Eu3+ at the Y3+ site. (C) 2014 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jlumin.2014.05.006

    Web of Science

    researchmap

  70. Synthesis of (Ca1-xSrx)(4)Si2O7F2 oxyfluoride solid solutions and their photoluminescence properties activated by Eu2+ ions Reviewed International journal

    Jihong Min, Hideki Kato, Makoto Kobayashi, Yasushi Sato, Masato Kakihana

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 122 ( 1428 ) page: 630 - 633   2014.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    The synthesis of oxyfluoride solid solutions with the composition (Ca1-xSrx)(4)Si2O7F2 is reported in this study. (Ca1-xSrx)(4)Si2O7F2 is found to form a solid solution within the entire composition range. Synthesis of Sr4Si2O7F2, which is the first compound in the Sr-Si-O-F system, can be regarded as one of the interesting results of this study. The Eu2+-activated (Ca1-xSrx)(4)Si2O7F2 solid solutions, except for Sr4Si2O7F2 exhibited photoluminescence under excitation at 300-450nm at room temperature. The samples with x = 0.25-0.75 showed a broad red emission band with a peak around 630 nm, whereas the Ca4Si2O7F2:Eu2+ (x = 0) showed blue emission with a peak at 470 nm. Thus, the substitution of Sr for Ca in Ca4SiO7F2:Eu2+ changed the photoluminescence properties remarkably. (C) 2014 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.122.630

    Web of Science

    researchmap

  71. The significance of phosphate source in the preparation of functional luminescent phosphate materials Reviewed International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 122 ( 1428 ) page: 626 - 629   2014.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    The stability and reactivity of phosphate raw materials, including two water-soluble phosphates, ethylene glycol-conjugated phosphate (EG-P), and polyethylene glycol-conjugated phosphate (PEG-P) developed by our group, were examined with the aim of synthesizing phosphates with high functionalities. EG-P was found to gradually hydrolyze in an aqueous solution, resulting in the formation of H3PO4, while PEG-P was stable for more than two months. EG-P and PEG-P did not form insoluble materials in aqueous solution in the presence of many other cations, while precipitates were often observed using conventional phosphate raw materials. In particular, there were no precipitates in an aqueous solution of PEG-P in the presence of Ca2+ and Li+ ions, which easily formed insoluble phosphates in a given aqueous condition. Consequently, single-phase LiCaPO4 with high luminescence properties could be obtained by a polymerizable complex method employing PEG-P, while impurity phases were formed using other P sources, and KSrPO4 was formed as a single phase using EG-P and PEG-P. (C) 2014 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.122.626

    Web of Science

    researchmap

  72. Tailoring of deep-red luminescence in Ca2SiO4:Eu2+ Reviewed International journal

    Yasushi Sato, Hideki Kato, Makoto Kobayashi, Takaki Masaki, Dae-Ho Yoon, Masato Kakihana

    Angewandte Chemie (International ed. in English)   Vol. 53 ( 30 ) page: 7756 - 9   2014.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    We report a new dicalcium silicate phosphor, Ca(2-x)Eu(x)SiO4, which emits red light in response to blue-light excitation. When excited at 450 nm, deep-red emission at 650 nm was clearly observed in Ca1.2Eu0.8SiO4, the external and internal quantum efficiencies of which were 44 % and 50 %, respectively. The red emission from Ca(2-x)Eu(x)SiO4 was strongly related to the peculiar coordination environments of Eu(2+) in two types of Ca sites. The red-emitting Ca2SiO4:Eu(2+) phosphors are promising materials for next-generation, white-light-emitting diode applications.

    DOI: 10.1002/anie.201402520

    PubMed

    researchmap

  73. Photoluminescence properties of deep-red emitting Ca2SiO4:Eu2+ International journal

    Y. Sato, H. Kato, M. Kobayashi, M. Kakihana

    Rare Earths   Vol. 64   page: 122 - 123   2014.5

     More details

    Language:Japanese   Publishing type:Research paper (conference, symposium, etc.)  

    researchmap

  74. Insights into a selective synthesis of anatase, rutile, and brookite-type titanium dioxides by a hydrothermal treatment of titanium complexes Reviewed International journal

    Mitsuru Yoshizawa, Makoto Kobayashi, Valery Petrykin, Hideki Kato, Masato Kakihana

    JOURNAL OF MATERIALS RESEARCH   Vol. 29 ( 1 ) page: 90 - 97   2014.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CAMBRIDGE UNIV PRESS  

    Novel water-soluble titanium complexes coordinated by hydroxycarboxylic acids or amines were developed, and the hydrothermal treatment of the new complexes was carried out to elucidate the formation mechanism of the titania polymorphs including rutile, anatase, and brookite. An empirical relationship among the crystal structure of TiO2, the ligand, and the complex structure was found. Anatase, rutile, or a mixture of both was obtained by the hydrothermal treatment of the complexes coordinated by hydroxycarboxylic acids. The structure of complexes prepared using hydroxycarboxylic acids, which have one hydroxyl and one carboxylic groups, seems to be preferable for the formation of rutile. It was also found that the hydrothermal treatment of titanium complexes coordinated by amine with NAc2 structure resulted in the formation of brookite. Thus, the effect of ligand and complex structure on the crystal structure of TiO2 synthesized by the hydrothermal treatment of the complexes was proposed.

    DOI: 10.1557/jmr.2013.229

    Web of Science

    researchmap

  75. Hydrothermal synthesis of magnetite particles with uncommon crystal facets Reviewed International journal

    Junki Sato, Makoto Kobayashi, Hideki Kato, Takamichi Miyazaki, Masato Kakihana

    Journal of Asian Ceramic Societies   Vol. 2 ( 3 ) page: 258 - 262   2014

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier B.V.  

    Hydrothermal synthesis of Fe3O4 (magnetite) particles was carried out using organic compounds as morphology control agents to obtain magnetite crystals with uncommon facets. It was established that the morphology of Fe3O4 crystals obtained by hydrothermal treatment of an aqueous solution containing Fe2+ and organic compounds depended on the organic compound used. The shape of the Fe3O4 particles obtained when no additives were used was quasi-octahedral. In contrast, the addition of picolinic acid, citric acid or pyridine resulted in the formation of polyhedral crystals, indicating the presence of not only {111}, {100} and {110} facets but also high-index facets including at least {311} and {331}. When citric acid was used as an additive, octahedral crystals with {111} facets also appeared, and their size decreased as the amount of citric acid was increased. Thus, control of Fe3O4 particle morphology was achieved by a simple hydrothermal treatment using additives. © 2014 The Ceramic Society of Japan and the Korean Ceramic Society.

    DOI: 10.1016/j.jascer.2014.05.008

    Scopus

    researchmap

  76. Synthesis of Titanium Dioxide Nanocrystals with Controlled Crystal- and Micro-structures from Titanium Complexes Invited Reviewed

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Nanomaterials and Nanotechnology   Vol. 3 ( 23 ) page: 1-10   2013.12

     More details

    Authorship:Lead author   Language:English  

    Web of Science

  77. 水溶性チタン錯体を用いたbrookite型酸化チタン粒子の調製 Invited Reviewed

    小林亮

    Colloid and Interface Communication   Vol. 38 ( 4 ) page: 7-8   2013.12

     More details

    Authorship:Lead author   Language:Japanese  

  78. 水を反応場として用いた機能性無機材料の合成~環境調和型プロセスの設計と新規水溶性金属錯体の開発~ Invited Reviewed

    小林亮, 垣花眞人

    分離技術   Vol. 41 ( 6 ) page: 32(368)-36(372)   2013.12

     More details

    Authorship:Lead author   Language:Japanese  

  79. A Highly Luminous LiCaPOCa4:Eu#U2+ Phosphor Synthesized by a Solution Method Employing a Water-Soluble Phosphate Ester Reviewed International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Optics and Photonics Journal   Vol. 3 ( 6A ) page: 13-18   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    7678

    DOI: 10.4236/opj.2013.36A003

    researchmap

  80. Exploration of New Phosphors Using a Mineral-Inspired Approach in Combination with Solution Parallel Synthesis Invited Reviewed International journal

    Masato Kakihana, Jihae Kim, Tetsufumi Komukai, Hideki Kato, Yasushi Sato, Makoto Kobayashi, Yuji Takatsuka

    Optics and Photonics Journal   Vol. 3 ( 6A ) page: 5-12   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    7677

    DOI: 10.4236/opj.2013.36A002

    researchmap

  81. Development of a Novel Green Emitting Phosphate Phosphor KSrY(PO4)2:Eu+2 Reviewed International journal

    Akiko Saito, Hideki Kato, Makoto Kobayashi, Yasushi Sato, Masato Kakihana

    Optics and Photonics Journal   Vol. 3 ( 6A ) page: 19-24   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    7679

    DOI: 10.4236/opj.2013.36A004

    researchmap

  82. Synthesis of a Novel Bluish-Green Emitting Oxynitride Ca3Al8Si4O17N4:Eu+2 Phosphor in a CaAl4-xSixO7-xNx Solid Solution Reviewed International journal

    Jihae Kim, Hideki Kato, Makoto Kobayashi, Yasushi Sato, Masato Kakihana

    Optics and Photonics Journal   Vol. 3 ( 6A ) page: 29-33   2013.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    7680

    DOI: 10.4236/opj.2013.36A006

    researchmap

  83. Enhanced Dielectric Response Induced by Controlled Morphology in Rutile TiO2 Nanocrystals Reviewed

    Minoru Osada, Makoto Kobayashi, Masato Kakihana

    Journal of the Ceramic Society of Japan   Vol. 121 ( 8 ) page: 593-597   2013.8

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    7621

    DOI: 10.2109/jcersj2.121.593

  84. Luminescence properties of a novel green-emitting phosphate phosphor KSrY(PO4)2:Eu2+ Reviewed

    Akiko Saito, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    IMID 2013 Digest     page: 261-261   2013.8

     More details

    Language:English  

  85. Synthesis of new thiogallate phosphors (Ba1-xSrx)4Ga2S7:Eu and their luminescence properties Reviewed

    Kohei Takeuchi, Takahiko Hasegawa, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    IMID 2013 Digest     page: 260-260   2013.8

     More details

    Language:English  

  86. Luminescence properties of a novel green-emitting phosphate phosphor KSrY(PO4)2:Eu2+ Reviewed International journal

    Akiko Saito, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    IMID 2013 Digest     page: 261-261   2013.8

     More details

    Language:English   Publishing type:Research paper (other academic)  

    researchmap

  87. Synthesis of new thiogallate phosphors (Ba1-xSrx)4Ga2S7:Eu and their luminescence properties Reviewed International journal

    Kohei Takeuchi, Takahiko Hasegawa, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    IMID 2013 Digest     page: 260-260   2013.8

     More details

    Language:English   Publishing type:Research paper (other academic)  

    researchmap

  88. Synthesis of a LiCaPO4:Eu2+ phosphor by a polymerizable complex method using a novel water-soluble phosphate precursor International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    IMID 2013 Digest     page: 264 - 264   2013.8

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)  

    researchmap

  89. Photocatalytic Water Splitting over LaTa7O19 Composed of TaO7 Pentagonal Bipyramids and TaO6 Octahedra Reviewed International journal

    Hideki Kato, Arisa Takeda, Makoto Kobayashi, Masato Kakihana

    Chemistry Letters   Vol. 42 ( 7 ) page: 744 - 746   2013.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    It has been found that cocatalyst-loaded LaTa7O19 with a band gap of 4.1 eV functions as a photocatalyst for water splitting under ultraviolet irradiation. The activity of Rh0.5Cr1.5O3-loaded LaTa7O19 prepared by a polymerizable complex method exhibited double of that prepared by a solid-state reaction. An apparent quantum yield of Rh0.5Cr1.5O3-loaded LaTa7O19 was determined to be 9.0% at 254 nm.

    DOI: 10.1246/cl.130216

    Web of Science

    researchmap

  90. Effect of carboxyl group on the visible-light photocatalytic activity of SrTiO3 nanoparticles Reviewed International journal

    Huihui Li, Shu Yin, Yuhua Wang, Makoto Kobayashi, Satoko Tezuka, Masato Kakihana, Tsugio Sato

    RESEARCH ON CHEMICAL INTERMEDIATES   Vol. 39 ( 4 ) page: 1615 - 1621   2013.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:SPRINGER  

    SrTiO3 nanoparticles modified with a carboxyl group were successfully prepared by microwave-assisted solvothermal reaction of SrCl2 center dot 6H(2)O and Ti(OC3H7)(4) in methanol-organic acid solution. The as-prepared products were characterized using X-ray diffraction (XRD), diffuse reflectance spectroscopy, and Fourier-transform infrared (FTIR) spectroscopy. The photocatalytic activity was determined by DeNO (x) ability using a mercury arc with filters to control irradiation wavelengths to &gt; 290, &gt; 400, and &gt; 510 nm. Nanoparticles of perovskite-type SrTiO3 were successfully synthesized above pH 12. The photocatalytic activity of SrTiO3 under visible-light (&gt; 510 nm) irradiation could be promoted by surface modification of SrTiO3 with the carboxyl group (-COO), especially from oleic acid.

    DOI: 10.1007/s11164-012-0894-1

    Web of Science

    researchmap

  91. 水を溶媒に用いた機能性酸化物の低温合成のためのグリーンプレカーサーの開発 Invited Reviewed

    小林亮, 垣花眞人

    機能材料   Vol. 33 ( 1 ) page: 4-10   2013.1

     More details

    Authorship:Lead author   Language:Japanese  

  92. Control of Valence Band Potential and Photocatalytic Properties of NaxLa1-xTaO1+2xN2-2x Oxynitride Solid Solutions Reviewed International journal

    Koichiro Ueda, Hideki Kato, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    Journal of Materials Chemistry A   Vol. 1 ( 11 ) page: 3667 - 3674   2013

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    A series of oxynitride solid solutions, NaxLa1-xTaO1+2xN2-2x with x 0.1, 0.2, 0.25, 0.3, 0.5, 0.75 and 0.85, was successfully synthesized by nitridation of amorphous oxide precursors under an NH3 stream at 1273 K. The band gaps of the solid solutions increased with the Na content. Photoelectrochemical analysis was conducted to obtain information on the band potentials of the solid solutions. The valence band maxima of the solid solutions were at more positive potentials than that of LaTaON2 (x = 0). Solid solutions of NaxLa1-xTaO1+2xN2-2x with x = 0.20-0.85 exhibited photocatalytic activity for both H-2 and O-2 evolution under visible light irradiation in the presence of sacrificial reagents, while LaTaON2 had no activity for O-2 evolution. The achievement of O-2 evolution with these solid solutions is due to control of the valence band potential; therefore, control of the photocatalytic properties of LaTaON2 was achieved by the formation of solid solutions.

    DOI: 10.1039/c3ta10257b

    Web of Science

    researchmap

  93. Enhancement of luminescence properties of a KSrPO4:Eu2+ phosphor prepared using a solution method with a water-soluble phosphate oligomer Reviewed International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    JOURNAL OF MATERIALS CHEMISTRY C   Vol. 1 ( 36 ) page: 5741 - 5746   2013

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    A novel phosphate raw material having an oligomeric structure with desirable stability and solubility under aqueous conditions was prepared via an esterification reaction between H3PO4 and ethylene glycol under reflux. A blue emitting KSrPO4:Eu2+ phosphor with high luminescence was subsequently synthesized using a polymerizable complex (PC) method with the prepared phosphate oligomers as a source of P. KSrPO4:Eu2+ thus prepared exhibited higher emission intensity than samples prepared using a solid state reaction method or the PC method using H3PO4. This high luminescence was attributed to the excellent homogeneity of the constituents in the sample. It was found that KSrPO4 doped with more than 3 mol% of Eu2+ showed a new low-energy emission band at approximately 480 nm, in addition to the known emission band at 428 nm. This new feature was speculated to be derived from disordering of K and Sr ions caused by the high homogeneity of the constituents. Moreover, it was confirmed that thermal quenching of emission at 428 nm above 423 K was recovered in samples doped with more than 7% of Eu.

    DOI: 10.1039/c3tc31121j

    Web of Science

    researchmap

  94. Fabrication of SrTiO3 exposing characteristic facets using molten salt flux and improvement of photocatalytic activity for water splitting Reviewed International journal

    Hideki Kato, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    CATALYSIS SCIENCE & TECHNOLOGY   Vol. 3 ( 7 ) page: 1733 - 1738   2013

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Flux treatment using various molten salts was performed for SrTiO3 powders. Morphology of SrTiO3 crystals obtained by the flux treatment strongly depended on the kinds of molten salts used. Large cubic crystals exposing {100} facets with a size of 5-6 mm were obtained by the flux treatment with LiCl whereas truncated cubes exposing {100} and {110} facets with a size of 200-400 nm were obtained when NaCl or SrCl2 was used as a flux reagent. In contrast, the flux treatment with KCl gave characteristic shaped crystals with a size of 300 nm. Electron microscope observation and electron diffraction analysis revealed that the crystals treated with the KCl flux expose {100}, {120}, and {121} facets. SrTiO3 treated with the KCl flux exhibited higher activity by 20 times than the non-flux-treated sample. Thus, a remarkable improvement of activity has been achieved by the fabrication of SrTiO3 crystals exposing high-index facets, {120} and {121}, using the KCl flux.

    DOI: 10.1039/c3cy00014a

    Web of Science

    researchmap

  95. Photocatalytic activities of Cu3xLa1-xTa7O17 solid solutions for H2 evolution under visible light irradiation Reviewed International journal

    Hideki Kato, Arisa Takeda, Makoto Kobayashi, Michikazu Hara, Masato Kakihana

    Catalysis Science & Technology   Vol. 3 ( 12 ) page: 3147 - 3154   2013

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ROYAL SOC CHEMISTRY  

    Development of new visible-light-driven oxide photocatalysts for H2 evolution was conducted with a concept of formation of solid solutions containing Cu(I) ions. Band gaps of Cu3xLa1-xTa7O19 solid solutions were 2.57-2.71 eV being remarkably narrower than that of LaTa7O19 (x = 0, 4.14 eV). The remarkable narrowing of the band gaps was due to the contribution of Cu 3d orbitals to valence bands. The solid solutions were capable of photocatalytic H-2 evolution under visible light irradiation in the presence of methanol as an electron donor. Interestingly, the solid solutions with x = 0.2-0.8 showed higher activities than that of a native Cu(I)-tantalate, Cu3Ta7O19 (x = 0). Among the solid solutions, the x = 0.6 sample, Cu1.8La0.4Ta7O19, exhibited the highest activity. The apparent quantum yield of the optimized photocatalyst was 0.48% at 420 nm. Moreover, the good stability of Cu(I) ions in the solid solutions was proven through the investigation of photocatalytic properties and the XPS analysis. Thus, new visible-light-driven oxide photocatalysts capable of H-2 evolution were developed by the formation of the Cu(3x)La(1-x)Ta(7)O19 solid solutions.

    DOI: 10.1039/c3cy00557g

    Web of Science

    researchmap

  96. Orange emission from (Ba1-XSrX)4Al 2S7:Eu2+ thioaluminate phosphors with visible light excitation Reviewed International journal

    Takahiko Hasegawa, Hideki Kato, Yuji Takatsuka, Makoto Kobayashi, Hisanori Yamane, Masato Kakihana

    ECS Journal of Solid State Science and Technology   Vol. 2 ( 2 ) page: R3107 - R3111   2013

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Solid solutions of (Ba1-XSrX)4Al 2S7 (X = 0.2 to 0.6) novel thioaluminate compound were synthesized, whose crystal structure was determined. The crystal structure of the (Ba1-XSrX)4Al2S7 solid solution is related to that of monoclinic Ba4Ga 2S7 consisting of isolated Ga2S7 units. However, the local structures around Ba/Sr in (Ba1-XSr X)4Al2S7, such as coordination number and one unusually long bond (d(Ba,Sr)-S 4 Å) in 7- and 8-coordinated (Ba,Sr)-S, are different from those in Ba4Ga 2S7. Eu2+-activated (Ba1-XSr X)4Al2S7 exhibited orange emission with a peak maximum at 594 nm and a corresponding excitation band at 300 to 550 nm. This is the first report of an orange phosphor in the thioaluminate system. The thermal quenching of luminescence in the (Ba1-XSr X)4Al2S7:Eu2+ phosphor was comparable to that in a conventional Y3Al5O 12:Ce3+ phosphor. © 2012 The Electrochemical Society.

    DOI: 10.1149/2.019302jss

    Scopus

    researchmap

  97. Synthesis of spindle and square bipyramid-shaped anatase-type titanium dioxide crystals by a solvothermal method using ethylenediamine Reviewed International journal

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 120 ( 1407 ) page: 494 - 499   2012.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    Morphological control as well as formation of nanoparticles of anatase-type titanium dioxide has been achieved by a solvothermal treatment of a water-soluble citratoperoxotitanium (CPT) complex using ethylenediamine (EDA) as a key solvent in the presence of a given amount of water. When the EDA concentration in the whole solvent (EDA + H2O) remained low less than 12 M, the powder obtained after the solvothermal treatment consisted of spindle-like anatase particles. With an increase of the EDA concentration in the solvent, the shape of the obtained particles changed from spindle to square bipyramid. When another water-soluble oxoglycolatoperoxotitanate complex or TiCl4 was used as a starting source of Ti, similar shaped anatase particles could be obtained by a careful choice of synthetic conditions. Using a mixed solvent of EDA and water, sheet-like titanic acid was produced as an intermediate phase, regardless of the EDA concentration. Therefore, the formation of anatase in the current system may take place through dissolution-recrystallization of titanic acid. The formation of square bipyramidal anatase particle achieved in the present study is not agreement with a reported theoretical calculation of equilibrium phase, because the calculation reveals that truncated square bipyramid-like anatase is obtained under an acidic condition and spindle-like anatase was formed under a basic condition. An adsorption of EDA on particle surface and the pH of the solvent may contribute to the achievement of morphological control. (C)2012 The Ceramic Society of Japan All rights reserved.

    DOI: 10.2109/jcersj2.120.494

    Web of Science

    researchmap

  98. Synthesis of new thioaluminate phosphors (Ba1-XSrX)4Al2S7:Eu and their luminescence properties Reviewed

    Takahiko Hasegawa, Makoto Kobayashi, Hideki Kato, Hisanori Yamane, Masato Kakihana

    Technical digest of the 12th International Meeting on Information Display     page: 640-641   2012.8

     More details

    Language:English  

  99. Impact of synthesis methodology on the optimization of photoluminescence emission intensity of NaBaScSi2O7:Eu2+ phosphor Reviewed International journal

    Sudeshna Ray, Kenji Toda, Shinnosuke Kamei, Tadashi Ishigaki, Kazuyoshi Uematsu, Mineo Sato, Hideki Kato, Makoto Kobayashi, Masato Kakihana

    Technical digest of the 12th International Meeting on Information Display     page: 128 - 129   2012.8

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)  

    researchmap

  100. Synthesis of the new compound in a Na-Sc-Si-O system and Luminescence properties activated by Eu2+ Reviewed International journal

    Jihong Min, Hideki Kato, Makoto Kobayashi, Hisanori Yamane, Masato Kakihana

    Technical digest of the 12th International Meeting on Information Display     page: 638-639   2012.8

     More details

    Language:English   Publishing type:Research paper (other academic)  

    researchmap

  101. Synthesis of new thioaluminate phosphors (Ba1-xSrx)4Al2S7:Eu and their luminescence properties Reviewed International journal

    Takahiko Hasegawa, Makoto Kobayashi, Hideki Kato, Hisanori Yamane, Masato Kakihana

    Technical digest of the 12th International Meeting on Information Display     page: 640-641   2012.8

     More details

    Language:English   Publishing type:Research paper (other academic)  

    researchmap

  102. Synthesis of KSrPO4:Eu2+ Phosphor with High Luminescence Property Using a Water-Soluble Phosphorus Precursor Reviewed International journal

    Minsung Kim, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Technical digest of the 12th International Meeting on Information Display     page: 130-131   2012.8

     More details

    Language:English   Publishing type:Research paper (other academic)  

    researchmap

  103. Preparation of Hollow TiO2 Spheres of the Desired Polymorphs by Layer-by-Layer Assembly of a Water-Soluble Titanium Complex and Hydrothermal Treatment Reviewed International journal

    Kiyofumi Katagiri, Hitoshi Inami, Kunihito Koumoto, Kei Inumaru, Koji Tomita, Makoto Kobayashi, Masato Kakihana

    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY   ( 20 ) page: 3267 - 3272   2012.7

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY-V C H VERLAG GMBH  

    A facile approach, based on the polyelectrolyte-mediated electrostatic adsorption of a water-soluble titanium complex on colloid templates and hydrothermal treatment, is presented for the formation of hollow TiO2 spheres of the desired polymorphs. The coreshell particles were formed by the alternate deposition of titaniumglycolate complex 1 and positively charged polyelectrolyte, poly(allylamine hydrochloride) (PAH) on spherical polystyrene (PS) templates by utilizing electrostatic interactions for shell formation. Hollow spheres formed with the polyionic complex of 1 and PAH were obtained by removal of the PS templates. Formation of the polyionic complex affected the crystallization of TiO2 from 1 by hydrothermal treatment. Hollow spheres of brookite and anatase were obtained by hydrothermal treatment at pH 4 and 10, respectively. The approach presented here can be exploited for the fabrication of novel advanced titania-based materials with desired structures and polymorphs.

    DOI: 10.1002/ejic.201200421

    Web of Science

    researchmap

  104. Morphology-Controlled Synthesis of W18O49 Nanostructures and Their Near-Infrared Absorption Properties Reviewed International journal

    Chongshen Guo, Shu Yin, Mei Yan, Makoto Kobayashi, Masato Kakihana, Tsugio Sato

    Inorganic chemistry   Vol. 51 ( 8 ) page: 4763 - 71   2012.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    The morphology-controlled synthesis and near-infrared (NIR) absorption properties of W(18)O(49) were systematically investigated for the application of innovative energy-saving windows. Various morphologies of W(18)O(49), such as nanorods, nanofibers, nanograins, nanoassembles, nanoplates, and nanoparticles, with various sizes were successfully synthesized by solvothermal reactions using organic alcohols as reaction media and WCl(6), W(EtO)(6), and WO(3) solids as the tungsten source. W(18)O(49) nanorods of less than 50 nm in length showed the best optical performance as an effective solar filter, which realized high transmittance in the visible region as well as excellent shielding properties of NIR light. Meanwhile, the W(18)O(49) nanorods also exhibited strong absorption of NIR light and instantaneous conversion of the absorbed photoenergy to the local heat.

    DOI: 10.1021/ic300049j

    Web of Science

    PubMed

    researchmap

  105. Hydrothermal synthesis of brookite-type titanium dioxide with snowflake-like nanostructures using a water-soluble citratoperoxotitanate complex Reviewed International journal

    Makoto Kobayashi, Valery Petrykin, Koji Tomita, Masato Kakihana

    Journal of Crystal Growth   Vol. 337 ( 1 ) page: 30 - 37   2011.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    Hydrothermal synthesis of brookite-type titanium dioxide was performed with excellent reproducibility using an aqueous NH3 solution of a water-soluble citratoperoxotitanate (CPT) complex. X-ray diffraction confirmed that the brookite phase was formed by hydrothermal treatment of the CPT complex in NH3 solution with a concentration of more than 6.5 wt%, whereas single phase anatase was obtained when distilled water without any additives was applied as the solvent. The aspect ratios of the obtained rod-like brookite particles increased from 5 up to 20 with an increase of the NH3 concentration. Transmission electron microscopy and selected area electron diffraction measurements provided evidence that the growth of the brookite particles is along the c-axis. Hydrothermal treatment of the CPT complex at high NH3 concentrations resulted in the formation of agglomerated brookite particles with unusual shapes, where many rod-like particles were branched around a somewhat longer central particle, and the side view of the agglomerated particles revealed two-dimensional crystal growth within a given restricted plane. The multi-needle agglomerate of particles was snowflake shaped. The reason for the formation of brookite with this unique morphology may be attributed to an intrinsic character of the CPT complex itself, although the mechanism is yet to be clarified. © 2011 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jcrysgro.2011.09.046

    Scopus

    researchmap

  106. Hydrothermal synthesis of hierarchical TiO2 microspheres using a novel titanium complex coordinated by picolinic acid Reviewed International journal

    Quang Duc Truong, Makoto Kobayashi, Hideki Kato, Masato Kakihana

    Journal of the Ceramic Society of Japan   Vol. 119 ( 1390 ) page: 513 - 516   2011

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Ceramic Society of Japan  

    Phase- and morphology-control of TiO2 was performed by a facile hydrothermal method using a novel water-soluble titaniumpicolinato complex as a precursor. Single-phase rutile or brookite type titania can be obtained by tailoring the pH of the complex solution. Rutile with a hierarchical microstructure was synthesized using an excess amount of ligand as an additive and the final product consisted of microspheres with mesopores formed by a self-assembly of nanorods. The anisotropic growth of nanorods with a high aspect ratio was explained by a capping mechanism. © 2011 The Ceramic Society of Japan.

    DOI: 10.2109/jcersj2.119.513

    Web of Science

    Scopus

    researchmap

  107. Application of Water-Soluble Titanium Complexes as Precursors for Synthesis of Titanium-Containing Oxides via Aqueous Solution Processes Invited Reviewed International journal

    Masato Kakihana, Makoto Kobayashi, Koji Tomita, Valery Petrykin

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   Vol. 83 ( 11 ) page: 1285 - 1308   2010.11

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CHEMICAL SOC JAPAN  

    The growing significance of nanocrystalline inorganic functional materials in the fields of catalysis, electronics, and energy conversion together with the increasing demand of the society for safer, softer, and "greener" technologies has drawn considerable attention of the researchers toward water-based solution processes for synthesis of such materials. In this respect complex oxides, containing d(0)-transition metals, such as Ti, Nb, Ta, or Si represent an outstanding challenge. for materials chemists due to the extremely narrow range or almost complete absence of suitable precursor compounds compatible with aqueous systems. In the recent 10 years, a remarkable progress has been achieved in the development of new water-soluble complexes of titanium and considerable experience was accumulated in the application of these compounds for synthesis of nanocrystalline titanium-containing materials. The essential knowledge of coordination chemistry of such water-soluble titanium complexes is reviewed in this work, which succeeded to identify the key structural features responsible for stability of the compounds against hydrolysis and to provide guidelines for synthesis of these complexes. Finally, an extensive overview of highly selective aqueous solution based synthesis of TiO2 polymorphs as well as complex oxide materials with the help of the novel water-soluble titanium complexes is provided.

    DOI: 10.1246/bcsj.20100103

    Web of Science

    researchmap

  108. 酸化チタンのテーラメイド合成 Invited Reviewed

    小林亮, 垣花眞人

    現代化学   Vol. 465 ( 12 ) page: 57-62   2009.11

     More details

    Authorship:Lead author   Language:Japanese  

  109. Selective Synthesis of TiO<sub>2</sub> Polymorphs by Hydrothermal Method using New Water-Soluble Titanium Complexes Invited Reviewed International journal

    Masato Kakihana, Makoto Kobayashi, Valery Petrykin, Koji Tomita

    Journal of the Japan Society of Powder and Powder Metallurgy   Vol. 56 ( 4 ) page: 188-193   2009.4

     More details

    Language:Japanese   Publishing type:Research paper (scientific journal)  

    A panel of new stable and water soluble complexes of titanium (IV) with natural hydroxy-carboxylic acids such as citric, tartaric, lactic or glycolic acid as ligands was developed. A typical structure of these complex ions includes a peroxo-group, and a hydroxy-carboxylic acid molecule attached to the metal ion by carboxylic and hydroxylic groups to form stable species. The tight coordination and negative charge of complex ions are responsible for stability of these new compounds in water solutions in a wide range of temperatures and pH. Use of natural non-toxic ligands and ammonium as counterions make such titanium compounds convenient reagents for "green" synthesis of titanium containing materials by aqueous solution methods.<BR>The architecture of titanium complexes includes structural motifs of different polymorphic forms of TiO<SUB>2</SUB>, which allows for application of these compounds as building blocks (tecton) for synthesis of titania with different crystal structures by a simple hydrothermal processes. In this way anatase, rutile, TiO<SUB>2</SUB>(B) and brookite were prepared in a reproducible and highly selective way. For the first time TiO<SUB>2</SUB>(B) and brookite were synthesized as single phase nano-crystals by a "one-pot" hydrothermal process, and their outstanding photo-catalytic activities were revealed.

    DOI: 10.2497/jjspm.56.188

    researchmap

  110. Hydrothermal synthesis of brookite type TiO2 photocatalysts using a water-soluble Ti-complex coordinated by ethylenediaminetetraacetic acid Reviewed International journal

    Yusuke Morishima, Makoto Kobayashi, Valery Petrykin, Shu Yin, Tsugio Sato, Masato Kakihana, Koji Tomita

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 117 ( 1363 ) page: 320 - 325   2009.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    Nanocrystalline brookite titanium oxide was prepared by hydrothermal treatment of a water-soluble titanium complex with ethylenediaminetetraacetic acid (EDTA). In this work, we examined the effect of synthesis conditions such as reaction time, titanium concentration and solution pH on the brookite phase formation and its photocatalyitic performance. It was found that hydrothermal treatment of the titanium complex may yield anatase and brookite phases, and their ratio can be varied depending on titanium concentration. Single phase brookite could be prepared when titanium concentration in the starting solution was higher than 0.25 mol/dm(3), while lower concentration favors formation of anatase. Remarkably, brookite could be synthesized from the Ti-EDTA complex in the wide range of pH including both acidic and basic media. The samples prepared from Ti-EDTA complex demonstrated higher photocatalytic activity in terms of NO gas decomposition than the brookite powders synthesized from Ti-glycolate complex or commercial TiO2 photocatalyst P25. Higher photocatalytic activity of powders obtained from Ti-EDTA complex aqueous solution is explained by higher surface area of smaller but well-crystallized brookite particles that can be achieved when this new titanium complex is employed. (C) 2009 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.117.320

    Web of Science

    researchmap

  111. Photocatalytic activity of nanocrystalline TiO2(B) synthesized from titanium glycolate complex by hydrothermal method Reviewed International journal

    Kazuhiro Yamamoto, Hironori Shimoita, Koji Tomita, Kazumi Fujita, Makoto Kobayashi, Valery Petrykin, Masato Kakihana

    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN   Vol. 117 ( 1363 ) page: 347 - 350   2009.3

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    The metastable phase of TiO2(B), one of the polymorphs of titanium dioxide (TiO2), was prepared by a hydrothermal treatment of a titanium glycolate complex ([Ti-4(C2H2O3)(4)(C2H3O3)(2)(O-2)(4)O-2](6-)) at 473 K for 1-72 h in the presence of H2SO4. Characterization by X-ray diffraction (XRD) and transmission electron microscopy (TEM) revealed that the obtained samples were composed of single phase TiO2(B) and the particles had plate-like morphology. After post-synthetic hydrothermal crystal growth (PHCG) applied to the as-prepared sample, thicker plate-like shaped particles were obtained. The photocatalytic activities of the samples obtained by the hydrothermal treatment and after the subsequent PHCG were evaluated in terms of methanol decomposition. (C) 2009 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.117.347

    Web of Science

    Scopus

    researchmap

  112. チタン錯体水溶液からの酸化チタン光触媒の合成 Invited Reviewed

    小林亮, Petykin Valery, 垣花眞人, 冨田恒之

    化学工業   Vol. 60 ( 1 ) page: 71-77   2009.1

     More details

    Authorship:Lead author   Language:Japanese  

  113. Hydrothermal Synthesis and Photocatalytic Activity of Whisker-Like Rutile-Type Titanium Dioxide Reviewed International journal

    Makoto Kobayashi, Valery Petrykin, Masato Kakihana, Koji Tomita

    JOURNAL OF THE AMERICAN CERAMIC SOCIETY   Vol. 92 ( 1 ) page: S21 - S26   2009.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY-BLACKWELL PUBLISHING, INC  

    Nanowhiskers of rutile-type titanium dioxide (TiO(2)) were synthesized by a simple hydrothermal treatment of a water-soluble titanium-glycolate complex at 473 K. The aspect ratio of the obtained rutile particles could be controlled by changing the concentration of the glycolic acid additive in the starting aqueous solution of the titanium complex. According to high-resolution transmission electron microscopy, whisker-like nanoparticles grow along the c-axis of rutile, the side facets of which are (110), (-110), (1-10), and (-1-10). Glycolic acid controls promotion of the rutile particles in the specified direction due to its preferred adsorption on the titanium-rich facets. Evaluation of the photocatalytic activity of the synthesized TiO(2) was performed in terms of decomposition of oxalic acid in an aqueous system under ultraviolet irradiation. It turned out that this particular whisker-like shape is responsible for the tremendous enhancement of rutile photocatalytic activity, and even rutile samples with low surface area demonstrated photocatalytic performance comparable with one of the best nanosized anatase photocatalytic materials. Therefore, it can be concluded that the (110) rutile facet plays an important role in the photocatalytic oxidation reaction, and that it exhibits higher photocatalytic activity than the (001) facet in the decomposition of oxalic acid.

    DOI: 10.1111/j.1551-2916.2008.02641.x

    Web of Science

    researchmap

  114. Synthesis of TiO2(B) using glycolato titanium complex and post-synthetic hydrothermal crystal growth of TiO2(B) Reviewed International journal

    K. Yamamoto, K. Tomita, K. Fujita, M. Kobayashi, V. Petrykin, M. Kakihana

    Journal of Crystal Growth   Vol. 311 ( 3 ) page: 619 - 622   2009.1

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER SCIENCE BV  

    Titanium dioxide (TiO2(B), one of metastable polymorphs of TiO2 was prepared by hydrothermal reaction of glycolato peroxotitanium complex ([Ti-4(C2H2O3)(4)(C2H3O3)(2)(O-2)(2)](6) in the presence of H2SO4 as an additive. Characterization by X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM) revealed that the obtained powders were single-phase TiO2(B) with rod-like shape, Particle size and aspect ratio of TiO2(B) can be controlled by post-synthetic hydrothermal crystal growth (PHCG) of the as-prepared powder sample. (C) 2008 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.jcrysgro.2008.09.041

    Web of Science

    researchmap

  115. Selective synthesis of nano-crystalline TiO2 polymorphs from new water-soluble titanium complexes Reviewed

    Masato Kakihana, Makoto Kobayashi, Valery Petrykin, Koji Tomita

    Acta Crystallographica Section A   ( 64 ) page: C20   2008.8

     More details

    Language:English  

  116. Direct synthesis of brookite-type titanium oxide by hydrothermal method using water-soluble titanium complexes Reviewed International journal

    Makoto Kobayashi, Koji Tomita, Valery Petrykin, Masahiro Yoshimura, Masato Kakihana

    Journal of Materials Science   Vol. 43 ( 7 ) page: 2158 - 2162   2008.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:SPRINGER  

    It was demonstrated that brookite-type titanium oxide can be directly synthesized by the hydrothermal treatment of novel water-soluble titanium complexes under basic conditions in the presence of an additive. In particular, single-phase brookite was synthesized from the titanium-glycolate complex at a pH of about 10 in the presence of excess NH(3) aqueous solution or ethylenediamine, and powder thus obtained consisted of rod-like nanosized particles. It was suggested that the structures of titanium complexes are important for the formation of brookite.

    DOI: 10.1007/s10853-007-1912-3

    Web of Science

    researchmap

  117. Hydrothermal synthesis of TiO2 nano-particles using novel water-soluble titanium complexes Reviewed International journal

    Koji Tomita, Makoto Kobayashi, Valery Petrykin, Shu Yin, Tsugio Sato, Masahiro Yoshimura, Masato Kakihana

    Journal of Materials Science   Vol. 43 ( 7 ) page: 2217 - 2221   2008.4

     More details

    Language:English   Publishing type:Research paper (international conference proceedings)  

    Hydrothermal treatment of a series of water-soluble titanium complexes resulted in the formation of TiO2. Rutile, anatase or a mixture of both can be synthesized by varying the ligands. The titania obtained was composed of nano-sized particles with large specific surface areas. These TiO2 powders exhibited high photocatalytic activity for NO x decomposition. In particular, they demonstrated higher activity than P25 (Degussa) under visible-light irradiation. © 2007 Springer Science+Business Media, LLC.

    DOI: 10.1007/s10853-007-2113-9

    Scopus

    researchmap

  118. New water-soluble complexes of titanium with amino acids and their application for synthesis of TiO2 nanoparticles Reviewed International journal

    Makoto Kobayashi, Valery Petrykin, Koji Tomita, Masato Kakihana

    Journal of the Ceramic Society of Japan   Vol. 116 ( 1352 ) page: 578 - 583   2008.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    We prepared two new water-soluble complexes of titanium with L-serine and L(-)-threonine amino acids. It was demonstrated that these compounds can be outstanding precursors for a hydrothermal synthesis of nanocrystalline TiO2. The obtained powders were composed of anatase or a mixture of anatase and brookite. Particles diameters were -10 nm and BET surface areas were -120 m(2)/g. The powder composed of anallase and brookite synthesized by hydrothermal treatment of the titanium-threonine complex aqueous solution at 200 degrees C for 24 h exhibited higher photocatalytic activity for oxalic acid oxidation than the commercial anatase-type TiO2 photocatalyst (ST-01, Ishihara Sangyo Kaisya, average diameter: 7 nm, specific surface area: 257.5 m(2)/g). (c) 2008 The Ceramic Society of Japan. All rights reserved.

    DOI: 10.2109/jcersj2.116.578

    Web of Science

    researchmap

  119. INOR 1052-Synthesis of oxide materials using new water soluble titanium and tantalum complexes Reviewed International journal

    Valery Petrykin, Makoto Kobayashi, Koji Tomita, Masato Kakihana

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   Vol. 235   2008.4

     More details

    Language:English   Publishing type:Research paper (other academic)   Publisher:AMER CHEMICAL SOC  

    Web of Science

    researchmap

  120. Microwave-assisted hydrothermal synthesis of brookite nanoparticles from a water-soluble titanium complex and their photocatalytic activity Reviewed International journal

    Yusuke Morishinia, Makoto Kobayashi, Valery Petrykin, Masato Kakihana, Koji Tomita

    Journal of the Ceramic Society of Japan   Vol. 115 ( 1348 ) page: 826 - 830   2007.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    Nanoparticles of brookite titanium oxide were prepared by microwave-assisted hydrothermal (MH) method at 200 degrees C (heating time 5 min) for 0-60 minutes starting from the titanium peroxo glycolate complex in basic solution. The effect of microwave heating on the morphology of the brookite particles was examined. The samples were characterized by X-ray diffraction (XRD), Raman spectroscopy and transmission electron microscopy (TEM). It was found that all powders were composed of single phase brookite and contained two different types of particles. The activity in photodecomposition of oxalic acid by the samples prepared using MH method was higher than activities of brookite nanoparticles synthesized by the conventional hydrothermal method.

    DOI: 10.2109/jcersj2.115.826

    Web of Science

    researchmap

  121. Morphology control of rutile nanoparticles in a hydrothermal synthesis from water-soluble titanium complex aqueous solution Reviewed International journal

    Makoto Kobayashi, Valery Petrykin, Masato Kakihana, Koji Tomita

    Journal of the Ceramic Society of Japan   Vol. 115 ( 1348 ) page: 835 - 839   2007.12

     More details

    Language:English   Publishing type:Research paper (scientific journal)   Publisher:CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI  

    Single phase rutile was synthesized by a simple hydrothermal treatment of an aqueous titanium glycolate complex solution at 200 degrees C for 24 h. The obtained sample was composed of 50 x 150 nm rod-like nanoparticles. The aspect ratio of the prepared particles could be controlled by adding glycolic acid or lactic acid to reaction solution. Up to 30 x 2000 nm whisker-like particles could be obtained. The hydroxycarboxylic acids favor development of specific crystal facets and allow to control the aspect ratio of the rutile nanoparticles. We also proposed a model, which explains formation of anatase and rutile, and disappearance of anatase particles during rutile crystals development.

    DOI: 10.2109/jcersj2.115.835

    Web of Science

    researchmap

  122. One-step synthesis of TiO2(B) nanoparticles from a Water-Soluble titanium complex Reviewed International journal

    Makoto Kobayashi, Valery V. Petrykin, Masato Kakihana, Koji Tomita, Masahiro Yoshimura

    Chemistry of Materials   Vol. 19 ( 22 ) page: 5373-5376   2007.10

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/cm071370q

    researchmap

  123. ゾル-ゲルコーティング材料としての新規水溶性チタン錯体 Invited Reviewed

    垣花眞人, 冨田恒之, 小林亮

    化学工業   Vol. 57 ( 12 ) page: 13-19   2006.12

     More details

    Language:Japanese  

  124. Hydrothermal synthesis of nanosized titania photocatalysts using novel water-soluble titanium complexes Reviewed International journal

    Makoto Kobayashi, Koji Tomita, Valery Petrykin, Syu Yin, Tsugio Sato, Masahiro Yoshimura, Masato Kakihana

    Solid State Phenomena   Vol. 124-126   page: 723-726   2006.9

     More details

    Language:English   Publishing type:Research paper (other academic)  

    DOI: 10.4028/www.scientific.net/SSP.124-126.723

    researchmap

  125. A water-soluble titanium complex for the selective synthesis of nanocrystalline brookite, rutile, and anatase by a hydrothermal method. Reviewed International journal

    Koji Tomita, Valery Petrykin, Makoto Kobayashi, Motoo Shiro, Masahiro Yoshimura, Masato Kakihana

    Angewandte Chemie International Edition   Vol. 45 ( 15 ) page: 2378 - 81   2006.4

     More details

    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/anie.200503565

    PubMed

    researchmap

  126. 水溶液から酸化チタンを作る Invited Reviewed

    小林亮, 冨田恒之, 垣花眞人

    色材協会コラム   ( 20 ) page: 1   2006

     More details

    Authorship:Lead author   Language:Japanese  

  127. 水溶性プロセスを利用したセラミックスの合成 Invited Reviewed

    冨田恒之, 小林亮, 垣花眞人

    未来材料   Vol. 5 ( 10 ) page: 37 - 43   2005.10

     More details

    Language:Japanese  

▼display all

Books 11

  1. ゾル―ゲル法技術の最新動向 Reviewed

    垣花眞人, 小林亮, 加藤英樹, 冨田恒之, 佐藤泰史( Role: Contributor ,  III 第4章 無機クラスターを活用した水溶液プロセスによる蛍光体の合成)

    シーエムシー出版  2023.7  ( ISBN:978-4-7813-1743-4

     More details

    Total pages:436   Responsible for pages:177-188   Language:Japanese Book type:Scholarly book

  2. ゾル―ゲル法技術の最新動向 Reviewed

    小林亮, 長田実( Role: Contributor ,  IV 第6章 複合アニオンナノシートコロイド)

    シーエムシー出版  2023.7  ( ISBN:978-4-7813-1743-4

     More details

    Total pages:436   Responsible for pages:409-418   Language:Japanese Book type:Scholarly book

  3. 複合アニオン化合物の科学 Reviewed

    小林 亮, 垣花 眞人( Role: Contributor ,  2章2節2 ソルボサーマル合成)

    丸善  2021.3  ( ISBN:9784621306109

     More details

    Total pages:264   Responsible for pages:62-72   Language:Japanese Book type:Scholarly book

  4. 粉体の表面処理・複合化技術集大成-基礎から応用まで-

    垣花 眞人, 小林 亮, 加藤 英樹, 冨田 恒之, 佐藤 泰史( Role: Contributor ,  応用編 第3章 新製造技術への展開 "第5節 錯体重合法による機能性セラミックス粉体の作製")

    テクノシステム  2018.7  ( ISBN:9784924728813

     More details

    Total pages:752   Responsible for pages:653-661   Language:Japanese Book type:Scholarly book

    researchmap

  5. ゾル-ゲルテクノロジーの最新動向

    垣花 眞人, 小林 亮, 加藤 英樹, 冨田 恒之, 佐藤 泰史( Role: Contributor ,  第22章 無機クラスターを活用した水溶液プロセスによる蛍光体の合成)

    シーエムシー出版  2017.7  ( ISBN:9784781312583

     More details

    Total pages:416   Responsible for pages:217-226   Language:Japanese Book type:Scholarly book

    researchmap

  6. Titanium Dioxide Nanoparticles: Characterizations, Properties and Syntheses

    Makoto Kobayashi, Hideki Kato, Masato Kakihana( Role: Contributor ,  Chapter 3. Hydrothermal Synthesis of Brookite-Type Titania Crystals Using Water-Soluble Titanium Complexes)

    Nova Science Publishers  2017.4  ( ISBN:9781536110739

     More details

    Responsible for pages:71-92   Language:English Book type:Scholarly book

    researchmap

  7. Handbook of Sol-Gel Science and Technology, 2nd edition

    Makoto Kobayashi, Hideki Kato, Masato Kakihana( Role: Contributor ,  Water-Dispersed Silicates and Water-Soluble Phosphates, and Their Use in Sol-Gel Synthesis of Silicate- and Phosphate-Based Materials)

    Springer International Publishing  2016.11  ( ISBN:9783319321011

     More details

    Responsible for pages:1-27   Language:English Book type:Scholarly book

    researchmap

  8. Phosphors, Up Conversion Nano Particles, Quantum Dots and Their Applications

    Masato Kakihana, Hideki Kato, Makoto Kobayashi, Yasushi Sato, Koji Tomita, Tetsufumi Komukai( Role: Contributor ,  Exploration of New Phosphors Using a Mineral-Inspired Approach in Combination with Solution Parallel Synthesis)

    Springer Singapore  2016.10  ( ISBN:9789811015908

     More details

    Responsible for pages:1-40   Language:English Book type:Scholarly book

    researchmap

  9. 次世代蛍光体材料の開発

    佐藤 泰史, 冨田 恒之, 小林 亮, 加藤 英樹, 垣花 眞人( Role: Contributor ,  第2章 結晶サイト工学を用いた蛍光体の物質探索法―Eu<sup>2+</sup>賦活オルソシリケート蛍光体を例として―)

    シーエムシー出版  2016.7  ( ISBN:9784781311586

     More details

    Total pages:262   Responsible for pages:15-27   Language:Japanese Book type:Scholarly book

    researchmap

  10. 〈詳解〉無機材料合成・探索法

    垣花 眞人, 小林 亮, 加藤 英樹, 佐藤 泰史, 冨田 恒之( Role: Joint author)

    情報機構  2014  ( ISBN:9784865020625

     More details

    Total pages:262   Language:Japanese Book type:Scholarly book

    CiNii Books

  11. セラミックスデータブック 2009

    鈴木 義仁, 小林 亮, 垣花 眞人( Role: Contributor ,  22. 水溶液化学に立脚したナノセラミックス合成)

    工業製品技術協会  2009.12 

     More details

    Language:Japanese Book type:Scholarly book

▼display all

MISC 3

  1. 水溶液プロセスによる無機結晶の構造形態制御と高機能化 Invited Reviewed

    小林亮

    東海化学工業会会報   Vol. 315   page: 2 - 6   2022.7

     More details

    Authorship:Lead author, Corresponding author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

  2. 固体材料探索の新展開 Invited

    小林亮

    化学と工業   Vol. 73 ( 4 ) page: 342 - 342   2020.4

     More details

    Authorship:Lead author, Corresponding author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

  3. 表面機能材料の研究動向と将来展望 Invited Reviewed

    中島章, 垣花眞人, 加藤英樹, 小林亮, 清水陽一

    セラミックス   Vol. 54 ( 1 ) page: 48 - 51   2019.1

     More details

    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)  

Presentations 202

  1. 界面活性剤結晶を活用したアモルファスナノシートの精密合成

    山本瑛祐, 栗本大輝, 伊東健太郎, 小林亮, 長田実

    日本化学会第104春季年会(2024)  2024.3.18 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:日本大学理工学部 船橋キャンパス   Country:Japan  

  2. Zスキーム型水分解の高活性化を目指したFe2O3へのIr系助触媒担持

    宮下智臣,吉野隼矢, 小林亮, 加藤英樹

    第133回触媒討論会  2024.3.19 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:横浜国立大学常盤台キャンパス   Country:Japan  

  3. 単結晶性 Gd ドープセリアナノシートの合成と特性評価

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2024年年会  2024.3.14 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:熊本大学 黒髪キャンパス   Country:Japan  

  4. 無機材料を用いたペロブスカイト太陽電池の電子・正孔輸送層の開発

    岡崎晴雅, 冨田恒之, 磯村雅夫, 金子哲也, モハマド シャヒドゥザマン, 小林亮, 趙成訓, 垣花眞人

    日本セラミックス協会2024年年会  2024.3.14 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:熊本大学 黒髪キャンパス   Country:Japan  

  5. 層状ペロブスカイトCsSrn−1Nb3Tin−3O3n+1の合成と特性評価

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2024年年会  2024.3.14 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:熊本大学 黒髪キャンパス   Country:Japan  

  6. 原子層制御合成によるDion-Jacobson型ペロブスカイト強誘電体の開発

    森田秀,山本瑛祐,小林亮,漆原大典,浅香透,長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  7. 酸窒化チタンナノシートの合成と光電子分光法による電子構造評価

    小林亮, 萩島直樹, 山本瑛祐, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  8. 単結晶性セリアナノシート合成とガドリニウムドープ

    山本瑛祐, 伊東健太郎, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  9. Covalent functionalization of MXenes with photoactive molecules

    Rubén Cantón Vitoria, Shu Morita, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  10. 酸化タングステンナノシートの精密合成と日射遮蔽膜への応用

    常松裕史, 山本瑛祐, 小林亮, 吉田智大, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  11. パラジウムナノシートの精密合成と触媒特性

    安藤純也, 山本瑛祐, 小林亮, 熊谷明哉, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  12. Pb内包層状ペロブスカイトおよびその剥離ナノシートの強誘電特性

    島田将成, LI Yan, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  13. 固体界面活性剤を鋳型としたアモルファスシリカナノシートの精密合成

    竹崎佑麻, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  14. 層状ペロブスカイトRbBi2−xLaxTi2NbO10の構造物性相関

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト(DEJI2MA)令和5年度 公開討論会(第2回 出島コンソーシアムセミナー)  2024.3.9 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  15. 複合アニオンナノシートの合成と電子構造評価 Invited

    小林亮, 長田実

    日本結晶成長学会 新技術・新材料分科会 第3回研究会  2024.3.8 

     More details

    Event date: 2024.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東北大学 東京オフィス   Country:Japan  

  16. アモルファスジルコニアナノシートのボトムアップ合成及び特性評価

    山田諭, 山本瑛祐, 小林亮, 長田実

    2023年度 日本セラミックス協会東海支部 学術研究発表会  2023.12.2 

     More details

    Event date: 2023.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋工業大学   Country:Japan  

  17. 酸窒化物ペロブスカイトナノシート(Ca1−xSrx)2Nb3O10−yNyの合成と電子構造評価

    大藪一星, 小林亮, 山本瑛祐, 長田実

    2023年度 日本セラミックス協会東海支部 学術研究発表会  2023.12.2 

     More details

    Event date: 2023.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋工業大学   Country:Japan  

  18. Dion-Jacobson型層状ペロブスカイトCsPb2Nb3O10およびその剥離ナノシートの強誘電特性評価

    島田将成, Yan Li, 山本瑛祐, 小林亮, 長田実

    2023年度 日本セラミックス協会東海支部 学術研究発表会  2023.12.2 

     More details

    Event date: 2023.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋工業大学   Country:Japan  

  19. Cs2Ti5O11を出発物質とした酸窒化チタンナノシートの合成と電子構造評価

    萩島直樹, 小林亮, 山本瑛祐, 長田実

    2023年度 日本セラミックス協会東海支部 学術研究発表会  2023.12.2 

     More details

    Event date: 2023.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋工業大学   Country:Japan  

  20. Ultrafast assembly for 2D nanosheets using modified drop casting International conference

    Hong Li, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  21. SPM-based Characterization of Individual Perovskite Nanosheets International conference

    Yan Li, Masanari Shimada, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  22. Synthesis and Characterization of Titanium Oxynitride Nanosheets International conference

    Makoto Kobayashi, Naoki Hagishima, Hikaru Sugimoto, Eisuke Yamamoto, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Nagoya University, Japan   Country:Japan  

  23. Tailored synthesis of amorphous 2D oxide/oxyhydroxide nanosheets International conference

    Eisuke Yamamoto, Daiki Kurimoto, Kentaro Ito, Makoto Kobayashi, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Nagoya University, Japan   Country:Japan  

  24. Facile Synthesis of Pd Nanosheets and Mechanism of Boosted Catalytic Activity International conference

    Sumiya Ando, Eisuke Yamamoto, Makoto Kobayashi, Akichika Kumatani, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  25. Controlled gadolinium doping for ceria nanosheets utilizing solid surfactant crystals International conference

    Kentaro Ito, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  26. Controlled ferroelectric properties in RbBi2−xLaxTi2NbO10 and their exfoliated 2D nanosheets International conference

    Keita Nishibashi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  27. Controlled Synthesis of 2D Conducting Nanosheets toward Thermal Shielding Applications International conference

    Hirofumi Tsunematsu, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Tomohiro Yoshida, Minoru Osada

    International Conference on Materials and Systems for Sustainability 2023 (ICMaSS2023)  2023.12.2 

     More details

    Event date: 2023.12

    Language:English   Presentation type:Poster presentation  

    Venue:Nagoya University, Japan   Country:Japan  

  28. Dion-Jacobson 型層状ペロブスカイト強誘電体RbBi2Ti2NbO10の特性制御と剥離 ナノシート化

    西橋慧太,山本瑛祐,小林亮,長田実

    日本電子材料技術協会2023年度第60回秋期大会  2023.11.23 

     More details

    Event date: 2023.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  29. 固体界面活性剤を利用したアモルファスシリカナノシートの精密設計

    山本瑛祐, 竹崎佑麻, 小林亮, 長田実

    第42回無機高分子研究討論会  2023.11.16 

     More details

    Event date: 2023.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学 神楽坂キャンパス   Country:Japan  

  30. 単結晶性Gdドープセリアナノシートの合成とドープ量制御

    伊東健太郎,山本瑛祐,小林亮,長田実

    日本電子材料技術協会2023年度第60回秋期大会  2023.11.23 

     More details

    Event date: 2023.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:名古屋大学 東山キャンパス   Country:Japan  

  31. Emerging Inorganic Nanosheets: From Tailored Synthesis to Applications International conference

    Minoru Osada, Makoto Kobayashi, Eisuke Yamamoto

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  32. Characterization of RbBi2−xLaxTi2NbO10 and synthesis of 2D nanosheets International conference

    Keita Nishibashi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  33. Rational approach for controlled Gd doping into ceria nanosheet International conference

    Kentaro Ito, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  34. Atomic Layer Engineering of D-J type perovskites Cs(Bi2Srm−3)(Tim−1Nb)O3m+1 International conference

    Shu Morita, Eisuke Yamamoto, Makoto Kobayashi, Daisuke Urushihara, Toru Asaka, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  35. A noble synthesis method of palladium nanosheets and mechanism of boosted catalytic activity International conference

    Sumiya Ando, Eisuke Yamamoto, Makoto Kobayashi, Akichika Kumagai, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  36. Fabrication of Transparent Conducting Nanosheets toward Thermal Shielding Applications International conference

    Hirofumi Tsunematsu, Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Tomohiro Yoshida, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  37. Molecularly Thin Amorphous Silica Nanosheets with Controlled Thickness International conference

    Eisuke Yamamoto, Yuma Takezaki, Makoto Kobayashi, Minoru Osada

    The 3rd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA-3)  2023.10.20 

     More details

    Event date: 2023.10

    Language:English   Presentation type:Poster presentation  

    Venue:Waseda University, Japan   Country:Japan  

  38. パラジウムナノシートの新規合成と触媒特性

    安藤純也, 山本瑛祐, 小林亮, 熊谷明哉, 長田実

    第13回CSJ化学フェスタ(2023)  2023.10.17 

     More details

    Event date: 2023.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:タワーホール船堀   Country:Japan  

  39. 固体界面活性剤を利用した単結晶性Gdドープセリアナノシートの合成

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    第13回CSJ化学フェスタ(2023)  2023.10.18 

     More details

    Event date: 2023.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:タワーホール船堀   Country:Japan  

  40. Dion-Jacobson型層状ペロブスカイトRbBi2Ti2NbO10の合成と特性制御

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    第13回CSJ化学フェスタ(2023)  2023.10.17 

     More details

    Event date: 2023.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:タワーホール船堀   Country:Japan  

  41. パラジウムナノシートの新規合成と触媒特性

    安藤純也, 山本瑛祐, 小林亮, 熊谷明哉, 長田実

    第13回CSJ化学フェスタ(2023)  2023.10.18 

     More details

    Event date: 2023.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:タワーホール船堀   Country:Japan  

  42. Application of CuLi1/3Ti2/3O2 as a H2-evolving photocatalyst to Z-scheme water splitting International conference

    Qingshan Liu, Tanya Kurutach, Toshiki Yamanaka, Shunya Yoshino, Makoto Kobayashi, Hideki Kato

    International Symposium for 80th Anniversary of the Tohoku Branch of the Chemical Society of Japan  2023.9.10 

     More details

    Event date: 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Sendai, Japan   Country:Japan  

  43. 酸化物アップコンバージョン蛍光体の発光強度と発光波長に対するGd置換の影響

    寺島那哉,冨田恒之,佐藤泰史,小林亮,殷シュウ,垣花眞人

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.8 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:京都工芸繊維大学   Country:Japan  

  44. Bond Valence Sumを利用したCe3+賦活新規蛍光体の開発

    木内泰成,冨田恒之,佐藤泰史,小林亮,殷シュウ,垣花眞人

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  45. 材料コスト低減に向けたペロブスカイト太陽電池のサンドイッチプロセス

    岡崎晴雅,冨田恒之,磯村雅夫,金子哲也,モハマド シャヒドゥザマン,小林亮,趙成訓,垣花眞人

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  46. グリコール酸チタン錯体を用いたBrookite型TiO2合成とペロブスカイト太陽電池の電子輸送層への応用

    佐藤来希,冨田恒之,磯村雅夫,金子哲也,モハマド シャヒドゥザマン,小林亮,趙成訓,垣花眞人

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  47. 層状ペロブスカイトA(Ca1−xSrx)(Nb1−yTay)2O6F (A = Cs, Rb)の剥離ナノシート化および電子構造評価

    山梨真寛,小林亮,山本瑛祐,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  48. Dion-Jacobson 型層状ペロブスカイトCs(Bi2Srm−3)(Tim−1Nb)O3m+1の特性評価と剥離ナノシート化

    森田秀,山本瑛祐,小林亮,漆原大典,浅香透,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  49. Dion-Jacobson 型層状ペロブスカイトRbBi2Ti2NbO10の特性評価と剥離ナノシート化

    西橋慧太,山本瑛祐,小林亮,漆原大典,浅香透,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  50. 還元型酸化タングステンナノシートの合成と近赤外反射膜への応用

    常松裕史,施越,山本瑛祐,小林亮,吉田智大,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.7 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  51. 固体界面活性剤を鋳型としたアモルファスシリカナノシートの分子層制御

    竹崎佑麻,山本瑛祐,小林亮,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.7 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  52. 単結晶セリアナノシートの精密合成・集積およびイオン伝導性評価

    竹内希,山本瑛祐,小林亮,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.7 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  53. 単結晶性ガドリニウムドープセリアナノシートの精密合成

    伊東健太郎,山本瑛祐,小林亮,長田実

    日本セラミックス協会 第36回秋季シンポジウム  2023.9.6 

     More details

    Event date: 2023.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:京都工芸繊維大学   Country:Japan  

  54. Tailored Synthesis of Palladium Nanosheets and Mechanism of Boosted Catalytic Activity International conference

    Sumiya Ando, Eisuke Yamamoto, Makoto Kobayashi, Akichika Kumatani, Minoru Osada

    2023 A3 Joint Symposium of Emerging Materials Innovation  2023.9.1 

     More details

    Event date: 2023.8 - 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Jeju   Country:Korea, Republic of  

  55. Tailored Synthesis of Ce1−xGdxO1−δ Nanosheets with Controlled Gadolinium Content International conference

    Kentaro Ito, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    2023 A3 Joint Symposium of Emerging Materials Innovation  2023.9.1 

     More details

    Event date: 2023.8 - 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Jeju   Country:Korea, Republic of  

  56. Atomic Layer Engineering of 2D Ferroelectric Perovskites International conference

    Shu Morita, Eisuke Yamamoto, Makoto Kobayashi, Daisuke Urushihara, Toru Asaka, Minoru Osada

    2023 A3 Joint Symposium of Emerging Materials Innovation  2023.9.1 

     More details

    Event date: 2023.8 - 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Jeju   Country:Korea, Republic of  

  57. Characterization and Exfoliation of Layered Perovskite RbBi2Ti2NbO10 International conference

    Keita Nishibashi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    2023 A3 Joint Symposium of Emerging Materials Innovation  2023.9.1 

     More details

    Event date: 2023.8 - 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Jeju   Country:Korea, Republic of  

  58. Tailored Synthesis of Non-Layered Oxide Nanosheets Utilizing Solid-State Surfactants International conference

    Eisuke Yamamoto, Daiki Kurimoto, Kentaro Ito, Makoto Kobayashi, Minoru Osada

    2023 A3 Joint Symposium of Emerging Materials Innovation  2023.9.1 

     More details

    Event date: 2023.8 - 2023.9

    Language:English   Presentation type:Poster presentation  

    Venue:Jeju   Country:Korea, Republic of  

  59. Tailored Synthesis of Non-Layered Oxide Nanosheets Utilizing Solid-State Surfactants International conference

    Eisuke Yamamoto, Daiki Kurimoto, Kentaro Ito, Makoto Kobayashi, Minoru Osada

    2023 Taiwan-Japan Symposium on Reaction Control (2023 TJSReC)  2023.7.28 

     More details

    Event date: 2023.7

    Language:English   Presentation type:Poster presentation  

    Venue:Hsinchu   Country:Taiwan, Province of China  

  60. Design of the Molecularly Thin Amorphous Silica Nanosheets Utilizing Solid-State Layered Surfactant International conference

    Eisuke Yamamoto, Yuma Takezaki, Makoto Kobayashi, Minoru Osada

    EUROCLAY 2023 International Conference of European Clay Groups Association  2023.7.27 

     More details

    Event date: 2023.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Bari   Country:Italy  

  61. Precise Design of the Layered Surfactant Crystals for Tailored Synthesis of Gadolinium-doped Nanosheets International conference

    Kentaro Ito, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    EUROCLAY 2023 International Conference of European Clay Groups Association  2023.7.27 

     More details

    Event date: 2023.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Bari   Country:Italy  

  62. Redox-mediated Z-scheme water splitting utilizing CuLi1/3Ti2/3O2 as H2-evolving photocatalyst International conference

    Hideki Kato, Tanya Kurutach, Qingshan Liu, Toshiki Yamanaka, Shunya Yoshino, Makoto Kobayashi

    The 31st International Conference on Photochemistry (ICP2023)  2023.7.28 

     More details

    Event date: 2023.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Sapporo, Japan   Country:Japan  

  63. Band Engineering of Inorganic Nanosheets by Element Substitutions Invited International conference

    Makoto Kobayashi, Eisuke Yamamoto, Minoru Osada

    International LEIPS workshop  2023.6.20 

     More details

    Event date: 2023.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:online   Country:Japan  

  64. Ce1−xGdxO1−δナノシートの精密合成

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    第64回東海若手セラミスト懇話会2023年夏期セミナー  2023.6.15 

     More details

    Event date: 2023.6

    Language:Japanese   Presentation type:Poster presentation  

    Venue:伊勢志摩   Country:Japan  

  65. Dion-Jacobson型ペロブスカイト強誘電体の原子層制御

    森田秀,山本瑛祐,小林亮,漆原大典,浅香透,長田実

    第64回東海若手セラミスト懇話会2023年夏期セミナー  2023.6.15 

     More details

    Event date: 2023.6

    Language:Japanese   Presentation type:Poster presentation  

    Venue:伊勢志摩   Country:Japan  

  66. Dion-Jacobson型層状ペロブスカイトRbBi2Ti2NbO10のサイトエンジニアリング

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    第64回東海若手セラミスト懇話会2023年夏期セミナー  2023.6.15 

     More details

    Event date: 2023.6

    Language:Japanese   Presentation type:Poster presentation  

    Venue:伊勢志摩   Country:Japan  

  67. ナノシートのバンドエンジニアリングと次世代誘電体の創製 Invited

    小林亮, 山本瑛祐, 長田実

    第1回LEIPSワークショップ  2023.4.25 

     More details

    Event date: 2023.4

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン   Country:Japan  

  68. 固体界面活性剤を利用したアモルファスシリカナノシートの合成条件および剥離挙動の調査

    山本瑛祐, 竹崎佑麻, 小林亮, 長田実

    日本化学会第103春季年会(2023)  2023.3.22  日本化学会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス   Country:Japan  

  69. アモルファスジルコニアナノシートコロイドの作製と二次元精密集積

    山田諭, 山本瑛祐, 施越, 小林亮, 長田実

    日本化学会第103春季年会(2023)  2023.3.22  日本化学会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス   Country:Japan  

  70. パラジウムナノシートの新規合成と原子層制御

    安藤純也, 山本瑛祐, 小林亮, 長田実

    日本化学会第103春季年会(2023)  2023.3.22  日本化学会

     More details

    Event date: 2023.3

    Language:English   Presentation type:Oral presentation (general)  

    Venue:東京理科大学野田キャンパス   Country:Japan  

  71. 非イオン性界面活性剤を鋳型としたアモルファスシリカ層状複合体の形成条件の解明

    竹崎佑麻, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  72. 原子膜技術による新規環境・エネルギー材料の創製

    長田実, 山本瑛祐, 小林亮

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  73. 非層状化合物原子膜の精密合成

    山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  74. Dion-Jacobson型層状ペロブスカイトRbBi2Ti2NbO10の特性制御

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  75. 新規Dion-Jacobson型ペロブスカイト強誘電体の合成と特性評価

    森田秀, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  76. ガドリニウムドープセリアナノシートのボトムアップ合成とドープ量制御

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    国際・産学連携インヴァースイノベーション材料創出プロジェクト第1回公開討論会  2023.3.11 

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  77. Brookite型TiO2を用いたペロブスカイト太陽電池の電子輸送層の作製

    佐藤来希, 冨田恒之, 金子哲也, 礒村雅夫, ナス ソファル, 小林亮, 垣花眞人

    日本セラミックス協会2023年年会  2023.3.10  日本セラミックス協会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:神奈川大学みなとみらいキャンパス   Country:Japan  

  78. Dion-Jacobson型層状ペロブスカイトRbBi2Ti2NbO10の特性制御

    西橋慧太, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2023年年会  2023.3.8  日本セラミックス協会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:神奈川大学みなとみらいキャンパス   Country:Japan  

  79. 新規Dion-Jacobson型ペロブスカイト強誘電体Cs(Bi2Srn−3)(Tin−1Nb)O3n+1 (n ≥ 4)の合成と特性評価

    森田秀, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2023年年会  2023.3.8  日本セラミックス協会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:神奈川大学みなとみらいキャンパス   Country:Japan  

  80. ガドリニウムドープセリアナノシートのボトムアップ合成とドープ量制御

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2023年年会  2023.3.8  日本セラミックス協会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:神奈川大学みなとみらいキャンパス   Country:Japan  

  81. 非イオン性界面活性剤を鋳型としたアモルファスシリカ層状複合体の形成条件の解明

    竹崎佑麻, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2023年年会  2023.3.8  日本セラミックス協会

     More details

    Event date: 2023.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:神奈川大学みなとみらいキャンパス   Country:Japan  

  82. 結晶サイト工学に立脚した蛍光体の設計及び開発原理の構築 Invited

    垣花眞人, 小林亮, 冨田恒之, 加藤英樹, 佐藤泰史

    第15回日本セラミックス協会マテリアル・ファブリケーション・デザイン研究会  2022.12.21 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:浜名湖リゾート&スパ THE OCEAN   Country:Japan  

  83. Tailored Synthesis of Platinum Nanosheets Using Designed 2D Surfactant Solids International conference

    Eisuke Yamamoto, Akiko Suzuki, Makoto Kobayashi, Minoru Osada

    The 5th International Conference on Nanospace Materials (ICNM2022)  2022.12.13 

     More details

    Event date: 2022.12

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Pattaya   Country:Thailand  

  84. 酸窒化チタンナノシートの合成と電子構造評価

    萩島直樹, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  85. 新規Dion-Jacobson型ペロブスカイト強誘電体の合成と特性評価

    森田修, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  86. K(Ca1−xSrx)3Nb3TiO13ペロブスカイトの合成と剥離ナノシート化

    上田怜央, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  87. Dion-Jacobson型層状ペロブスカイトRbBi1−xLaxNb2O7の特性評価と剥離ナノシート化

    大原幹生, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  88. Na内包ペロブスカイトナノシートの熱安定性評価

    草間悠貴, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  89. 層状ペロブスカイトKCa2NaNb4O13のフラックス結晶成長と剥離ナノシート化

    後藤雄太, 小林亮, 山本瑛祐, 長田実

    2022年度 日本セラミックス協会東海支部 学術研究発表会  2022.12.3 

     More details

    Event date: 2022.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  90. Dion-Jacobson型ペロブスカイト強誘電体の精密合成と特性評価

    森田秀, 山本瑛祐, 小林亮, 長田実

    日本電子材料技術協会2022年度第59回秋期大会  2022.11.24 

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  91. 層状タングステン酸化物の剥離ナノシート化とその精密集積膜

    常松裕史, 山本瑛祐, 小林亮, 長田実

    日本電子材料技術協会2022年度第59回秋期大会  2022.11.25 

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  92. 非線形光学特性を有するカチオン性酸フッ化ビスマスナノシートの合成

    小林亮, 田坂翼, 山本瑛祐, 長田実

    第53回中部化学関係学協会支部連合秋季大会  2022.11.6 

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  93. アモルファス酸化ガリウムナノシートのボトムアップ合成と精密設計

    栗本大輝, 山本瑛祐, 小林亮, 長田実

    第53回中部化学関係学協会支部連合秋季大会  2022.11.6 

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  94. タングステン複合酸化物のナノシート化とその精密集積および光学特性評価

    常松裕史, 山本瑛祐, 小林亮, 長田実

    第53回中部化学関係学協会支部連合秋季大会  2022.11.6 

     More details

    Event date: 2022.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  95. Synthesis of Perovskite Oxynitride Nanosheets, Ca2Nb3O10−xNx, with Controlled Band Structures International conference

    Makoto Kobayashi, Hikaru Sugimoto, Eisuke Yamamoto, Minoru Osada

    The 6th International Symposium on Visualization in Joining (Visual-JW 2022) & Welding Science through Advanced Measurements and Simulation & The 2nd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA)  2022.10.25 

     More details

    Event date: 2022.10

    Language:English   Presentation type:Poster presentation  

    Venue:Osaka, Japan   Country:Japan  

  96. Band Engineering of Inorganic Nanosheets via Anion-substitution Invited International conference

    Makoto Kobayashi, Eisuke Yamamoto, Minoru Osada

    The 6th International Symposium on Visualization in Joining (Visual-JW 2022) & Welding Science through Advanced Measurements and Simulation & The 2nd International Symposium on Design & Engineering by Joint Inverse Innovation for Materials Architecture (DEJI2MA)  2022.10.25 

     More details

    Event date: 2022.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Osaka, Japan   Country:Japan  

  97. 界面活性剤結晶を鋳型としたガドリニウムドープセリアナノシートの合成

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.19 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  98. 電荷補償型元素置換による層状酸窒化チタンの合成と剥離ナノシート化

    萩島直樹, 小林亮, 山本瑛祐, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.19 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  99. 層状化合物(K, Rb, Cs)4Nb6O17の合成と剥離ナノシート化

    井原颯紀, 小林亮, 山本瑛祐, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.19 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  100. Dion-Jacobson型層状ペロブスカイトRbBi1−xLaxNb2O7の合成と剥離ナノシート化

    大原幹生, 小林亮, 山本瑛祐, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.19 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  101. Na含有ペロブスカイトナノシートの熱安定性評価

    草間悠貴, 小林亮, 山本瑛祐, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.19 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  102. 界面活性剤結晶を用いたアモルファス酸化ガリウムナノシートのボトムアップ合成

    栗本大輝, 山本瑛祐, 小林亮, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.20 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  103. 層状ポリタングステン酸塩の剥離ナノシート化と光学特性評価

    常松裕史, 山本瑛祐, 小林亮, 長田実

    第12回CSJ化学フェスタ(2022)  2022.10.20 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Poster presentation  

    Country:Japan  

  104. 無機クラスターを活用した水溶液プロセスによる高機能無機材料合成 Invited

    垣花眞人, 小林亮, 冨田恒之, 加藤英樹, 佐藤泰史

    第21回 日本金属学会東北支部研究発表大会  2022.10.4 

     More details

    Event date: 2022.10

    Language:Japanese   Presentation type:Oral presentation (keynote)  

    Venue:日本大学工学部   Country:Japan  

  105. 界面活性剤-アモルファスジルコニア層状複合体の合成と剥離ナノシート化

    山田諭, 山本瑛祐, 施越, 小林亮, 長田実

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.14 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  106. TiO2ナノ結晶の選択的合成と分散液の調製およびペロブスカイト太陽電池の電子輸送層への応用

    佐藤来希, 冨田恒之, Nuth Sophal, 金子哲也, 磯村雅夫, 小林亮, 垣花眞人

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.15 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  107. 固体界面活性剤結晶を鋳型としたガドリニウムドープセリアナノシートのボトムアップ合成

    伊東健太郎, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.15 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  108. 酸化タングステンナノシートの精密集積と光学特性評価

    常松裕史, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.15 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  109. 二次元界面活性剤固体の設計と原子層ブロックの新展開

    山本瑛祐, 鈴木晶子, 小林亮, 長田実

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.15 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  110. Bond Valence Sumを利用したEu2+及びCe3+賦活新規蛍光体の開発

    木内泰成, 冨田恒之, 佐藤泰史, 小林亮, 垣花眞人

    日本セラミックス協会 第35回秋季シンポジウム  2022.9.15 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  111. 界面活性剤固体でつくる新しい二次元材料 Invited

    山本瑛祐, 小林亮, 長田実

    第12回 酸化物研究の新機軸に向けた学際討論会  2022.9.9 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東北大学東京分室   Country:Japan  

  112. 界面活性剤固体を利用した二次元材料合成の新展開 Invited

    山本瑛祐, 小林亮, 長田実

    粘土学会若手の会 第13回若手研究者研究発表会  2022.9.6 

     More details

    Event date: 2022.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Country:Japan  

  113. Wet Chemical Synthesis of Molecularly-Thin Amorphous Silica Nanosheets and Their Two-Dimensional Assembly International conference

    Eisuke Yamamoyo, Kosuke Fujiwara, Yue Shi, Makoto Kobayashi, Minoru Osada

    IUMRS-ICYRAM 2022 

     More details

    Event date: 2022.8

    Language:English   Presentation type:Oral presentation (general)  

    Country:Japan  

  114. Colloidal Amorphous silica nanosheets and Their Two-dimensional Assembly International conference

    Eisuke Yamamoyo, Kosuke Fujiwara, Yue Shi, Makoto Kobayashi, Minoru Osada

    AIPEA – XVII INTERNATIONAL CLAY CONFERENCE  2022.7.29 

     More details

    Event date: 2022.7

    Language:English   Presentation type:Oral presentation (general)  

    Venue:Istanbul, Turkey   Country:Turkey  

  115. 水溶液プロセスによる無機結晶の構造形態制御と高機能化 Invited

    小林亮

    第57回 東海化学工業会賞 受賞記念講演会  2022.5.17 

     More details

    Event date: 2022.5

    Language:Japanese   Presentation type:Oral presentation (keynote)  

    Venue:オンライン   Country:Japan  

  116. アモルファスシリカナノシートのボトムアップ合成と精密集積

    山本瑛祐, 藤原康輔, 施越, 小林亮, 長田実

    日本化学会第102春季年会(2022)  2022.3.24  日本化学会

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  117. 2次元酸化タングステン多形体の合成と光学的応用性

    常松裕史, 山本瑛祐, 小林亮, 長田実

    日本化学会第102春季年会(2022)  2022.3.25  日本化学会

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  118. 界面活性剤結晶を用いたアモルファス酸化ガリウムナノシートのテンプレート合成

    栗本大輝, 山本瑛祐, 小林亮, 長田実

    日本化学会第102春季年会(2022)  2022.3.25  日本化学会

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  119. 酸窒化物の創製とその展開 Invited

    小林亮, 加藤英樹, 長田実, 垣花眞人

    複合アニオン化合物の創成と新機能-最終発表会-  2022.3.17  新学術領域研究「複合アニオン化合物の創製と新機能」総括班

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン  

  120. 層状ポリタングステン酸塩の剥離ナノシート化とその光学薄膜

    常松裕史, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2021年年会  2022.3.10  日本セラミックス協会

     More details

    Event date: 2022.3

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  121. Dion-Jacobson 型ペロブスカイト強誘電体と剥離ナノシートの特性評価

    中崎康太, 山本瑛祐, 小林亮, 長田実

    2021年度 日本セラミックス協会東海支部 学術研究発表会  2021.11.27  日本セラミックス協会東海支部

     More details

    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  122. 層状ペロブスカイトKCa2NaNb4O13のフラックス結晶成長条件の検討

    後藤雄太, 小林亮, 山本瑛祐, 長田実

    2021年度 日本セラミックス協会東海支部 学術研究発表会  2021.11.27  日本セラミックス協会東海支部

     More details

    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  123. 界面活性剤結晶を鋳型とした金ナノプレートの合成

    山下百華, 山本瑛祐, 小林亮, 長田実

    2021年度 日本セラミックス協会東海支部 学術研究発表会  2021.11.27  日本セラミックス協会東海支部

     More details

    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  124. Rb4Nb6O17の結晶構造解析と剥離ナノシート化

    井原颯紀, 小林亮, 山本瑛祐, 長田実

    2021年度 日本セラミックス協会東海支部 学術研究発表会  2021.11.27  日本セラミックス協会東海支部

     More details

    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  125. ビスマス含有酸フッ化物ナノシートの超音波剥離合成

    田坂翼, 小林亮, 山本瑛祐, 長田実

    2021年度 日本セラミックス協会東海支部 学術研究発表会  2021.11.27  日本セラミックス協会東海支部

     More details

    Event date: 2021.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  126. Facile ceramic nanocoating using single droplet assembly of 2D nanosheets

    Yue Shi, Eisuke Yamamoto, Makoto Kobayashi, Minoru Osada

    2021.11.27 

     More details

    Event date: 2021.11

    Language:English   Presentation type:Oral presentation (general)  

  127. 界面活性剤-シリカ層状複合体からのアモルファスシリカ原子膜の創製

    藤原康輔, 山本瑛祐, 施越, 小林亮, 長田実

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.30  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  128. 杉本光輝, 小林亮, 山本瑛祐, 長田実

    杉本光輝, 小林亮, 山本瑛祐, 長田実

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.30  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  129. 界面活性剤のラメラ結晶を前駆体とした白金ナノシートの合成

    鈴木晶子, 山本瑛祐, 小林亮, 長田実

    第52回 中部化学関係学協会支部連合秋季大会  2021.10.30  中部化学関係学協会支部連合協議会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  130. Bond Valence Sumを用いた新規蛍光体探索と 新規青緑色発光蛍光体Ba6Si10O26:Eu2+の開発

    森川崇志, 木内泰成, 冨田恒之, 佐藤泰史, 小林亮, 垣花眞人

    第11回CSJ化学フェスタ(2021)  2021.10.21  日本化学会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  131. アナターゼ型とブルッカイト型TiO2を混合した電子輸送層を用いた有機ペロブスカイト型太陽電池

    佐藤来希, 粕谷航平, 冨田恒之, Nuth Sophal, 磯村雅夫, 金子哲也, 小林亮, 垣花眞人

    第11回CSJ化学フェスタ(2021)  2021.10.20  日本化学会

     More details

    Event date: 2021.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  132. CuLi1/3Ti2/3O2光触媒のZスキーム型水分解への応用

    Kurutach Tanya, 山中俊輝, 小林亮, 熊谷啓, 加藤英樹

    第128回触媒討論会  2021.9.16  触媒学会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  133. 水溶媒を用いたセラミックスの構造・形態制御とその展開 Invited

    小林亮, 加藤英樹, 長田実, 垣花眞人

    日本ゾル-ゲル学会第19回討論会  2021.9.14  日本ゾルーゲル学会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン  

  134. 固体界面活性剤結晶を鋳型にした酸化ガリウムナノシートのボトムアップ合成

    栗本大輝, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.3  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  135. 界面活性剤-シリカ層状複合体からのアモルファスシリカナノシートの単層剥離

    藤原康輔, 山本瑛祐, 施越, 小林亮, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.3  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  136. BiNb2O7ペロブスカイトナノシートの合成における剥離条件の検討

    大原幹生, 小林亮, 山本瑛祐, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.2  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  137. 溶液化学プロセスによる層状酸フッ化物からのビスマス含有ナノシートの剥離合成

    田坂翼, 小林亮, 山本瑛祐, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.2  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  138. Ca2NaNb4O13ペロブスカイトナノシートの熱安定性評価

    草間悠貴, 小林亮, 山本瑛祐, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.2  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  139. Dion-Jacobson型ペロブスカイト強誘電体の特性評価と剥離ナノシート化

    中崎康太, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.2  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  140. 界面活性剤結晶の二次元成長を利用した白金ナノシートの合成

    鈴木晶子, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.2  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  141. 層状酸窒化物ペロブスカイトの剥離によるCa2Nb3O10−xNxナノシートの合成

    杉本光輝, 小林亮, 山本瑛祐, 長田実

    日本セラミックス協会 第34回秋季シンポジウム  2021.9.3  日本セラミックス協会

     More details

    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン   Country:Japan  

  142. Zスキーム系の拡張に向けた酸窒化物光触媒への助触媒検討

    森下直人, 小林亮, 加藤康作, 山方啓, 熊谷啓, 加藤英樹

    第40回光がかかわる触媒化学シンポジウム  2021.7.16  触媒学会

     More details

    Event date: 2021.7

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン   Country:Japan  

  143. 合成・計算・計測の融合によるナノ材料創出 Invited

    小林亮, 加藤英樹, 垣花眞人, 長田実

    第18回 新機能無機物質探索研究センター・シンポジウム 講演会  2021.3.26 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン  

  144. 界面活性剤-セリウム複合体結晶を利用したセリアナノシートのボトムアップ合成

    山本瑛祐, 林浩平, 小林亮, 長田実

    日本セラミックス協会2021年年会  2021.3.24 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  145. 有機ペロブスカイト型太陽電池への応用へ向けたエマルジョンを用いた Brookite 型 TiO2ナノ粒子の合成

    粕谷航平, 冨田恒之, 金子哲也, 磯村雅夫, 小林亮, 朝倉裕介, 垣花眞人

    日本セラミックス協会2021年年会  2021.3.24 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  146. BVS を活用した結晶サイト工学的アプローチによる新規 Ba 複合酸化物蛍光体の開発

    森川崇志, 中里暢宏, 冨田恒之, 佐藤泰史, 小林亮, 垣花眞人

    日本セラミックス協会2021年年会  2021.3.24 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  147. Langmuir-Blodgett 法を用いた磁性モザイク膜の作製および磁気光学特性評価

    濱上修, 谷口貴章, 山本瑛祐, 小林亮, 長田実

    日本セラミックス協会2021年年会  2021.3.24 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  148. Dion-Jacobson型ペロブスカイト強誘電体RbBi2Ti2NbO10の合成と剥離ナノシート化

    中崎康太, 櫻場俊徳, 山本瑛祐, 小林亮, 長田実

    日本化学会第101春季年会(2021)  2021.3.20 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  149. 層状酸フッ化ビスマスの剥離による酸フッ化物ナノシートの合成とその安定性評価

    田坂翼, 小林亮, 山本瑛祐, 長田実

    日本化学会第101春季年会(2021)  2021.3.21 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  150. 界面活性剤-シリカ層状メソ構造体を利用したアモルファスシリカナノシートの合成

    藤原康輔, 山本瑛祐, 小林亮, 長田実

    日本化学会第101春季年会(2021)  2021.3.20 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  151. C3N4を窒素源に用いた酸化物ナノシートの窒化の検討

    杉本光輝, 小林亮, 山本瑛祐, 長田実

    日本化学会第101春季年会(2021)  2021.3.20 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  152. 界面活性剤結晶を用いた鋳型合成法による白金ナノシートの合成

    鈴木晶子, 山本瑛祐, 小林亮, 長田実

    日本化学会第101春季年会(2021)  2021.3.20 

     More details

    Event date: 2021.3

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  153. Ti内包によるペロブスカイトナノシートの分極構造および誘電特性制御

    櫻場俊徳, 山本瑛祐, 小林亮, 長田実

    日本電子材料技術協会2020年度第57回秋期大会  2020.12.4 

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  154. セリアナノシートのテンプレート合成およびイオン伝導性評価

    林浩平, 山本瑛祐, 小林亮, 長田実

    日本電子材料技術協会2020年度第57回秋期大会  2020.12.4 

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  155. Langmuir-Blodgett法を用いた磁性ナノシートモザイク膜の作製

    濱上修, 谷口貴章, 山本瑛祐, 小林亮, 長田実

    日本電子材料技術協会2020年度第57回秋期大会  2020.12.4 

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  156. 水熱法により合成した酸化チタン多形ナノロッドの誘電特性

    横山政季, 小林亮, 山本瑛祐, 長田実

    日本電子材料技術協会2020年度第57回秋期大会  2020.12.4 

     More details

    Event date: 2020.12

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  157. 界面活性剤結晶を用いた白金ナノシートのボトムアップ合成

    鈴木晶子, 山本瑛祐, 小林亮, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  158. 酸フッ化ビスマスナノシートの合成

    田坂翼, 小林亮, 山本瑛祐, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  159. 固体窒素源を用いた窒化処理がペロブスカイトナノシートに与える影響

    杉本光輝, 小林亮, 山本瑛祐, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  160. 層状メソ構造体シリカの剥離によるシリカナノシートの合成

    藤原康輔, 山本瑛祐, 小林亮, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  161. Ti内包ペロブスカイトナノシートの誘電特性評価

    櫻場俊徳, 山本瑛祐, 小林亮, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  162. ルチル型およびブルッカイト型酸化チタンナノロッドの水熱合成と誘電特性評価

    横山政季, 小林亮, 山本瑛祐, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  163. 気液界面を利用した酸化亜鉛ナノシートの合成とフォトルミネッセンス特性評価

    森田佳典, 山本瑛祐, 小林亮, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  164. セリアナノシートのボトムアップ合成とイオン伝導性評価

    林浩平, 山本瑛祐, 小林亮, 長田実

    2020年度 日本セラミックス協会東海支部 学術研究発表会  2020.11.28 

     More details

    Event date: 2020.11

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  165. 界面活性剤結晶を鋳型とした白金ナノシートの合成

    鈴木晶子, 山本瑛祐, 小林亮, 長田実

    第10回CSJ化学フェスタ  2020.10.21 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  166. Ti内包によるペロブスカイトナノシートの誘電特性制御

    櫻場俊徳, 山本瑛祐, 小林亮, 長田実

    第10回CSJ化学フェスタ  2020.10.22 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  167. 酸化チタン多形ナノロッドの合成と誘電特性評価

    横山政季, 小林亮, 山本瑛祐, 長田実

    第10回CSJ化学フェスタ  2020.10.21 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  168. ZnOナノシートの気液界面合成とフォトルミネッセンス特性評価

    森田佳典, 山本瑛祐, 小林亮, 長田実

    第10回CSJ化学フェスタ  2020.10.21 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  169. 界面活性剤結晶をテンプレートにしたセリアナノシートの合成とイオン伝導性評価

    林浩平, 山本瑛祐, 小林亮, 長田実

    第10回CSJ化学フェスタ  2020.10.21 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  170. ビスマス含有酸フッ化物ナノシートの合成

    田坂翼, 小林亮, 山本瑛祐, 長田実

    第10回CSJ化学フェスタ  2020.10.21 

     More details

    Event date: 2020.10

    Language:Japanese   Presentation type:Poster presentation  

    Venue:オンライン  

  171. La0.5Sr0.5Ta0.5Ti0.5O2Nを酸素生成光触媒として用いた種々のZスキーム水分解系の構築

    熊谷啓, 青柳良輔, 高濱太一, 小林亮, 加藤英樹

    第126回触媒討論会  2020.9.16 

     More details

    Event date: 2020.9

    Language:Japanese   Presentation type:Oral presentation (general)  

    Venue:オンライン  

  172. 元素置換による新規酸窒化物の発見 Invited

    小林亮, 加藤英樹, 長田実, 垣花眞人

    第一回複合アニオンウェブセミナー  2020.7.7 

     More details

    Event date: 2020.7

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:オンライン  

  173. Application of Water-soluble Titanium Complexes for Synthesis of Titania Nanocrystals Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    43rd International Conference and Exposition on Advanced Ceramics and Composites (ICACC2019) 

     More details

    Event date: 2019.1 - 2019.2

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Daytona Beach, FL United States   Country:United States  

  174. Developmen of Phosphors with Mixed Anions Invited

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

     More details

    Event date: 2018.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Country:Japan  

  175. 複合アニオン化合物蛍光体の設計と開発 Invited

    小林亮, 加藤英樹, 垣花眞人

    第12回次世代先端光科学研究会 

     More details

    Event date: 2017.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:静岡大学 浜松キャンパス   Country:Japan  

  176. 複合アニオン化合物が拓く蛍光体開発 Invited

    小林亮, 加藤英樹, 安永拓矢, 工藤春佳, 垣花眞人, 藤井孝太郎, 八島正知

    第7回CSJ化学フェスタ2017 文科省科研費新学術領域研究「複合アニオン化合物の創製と新機能」特別企画:複合アニオン化合物が拓く新しい材料科学と夢 

     More details

    Event date: 2017.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:タワーホール船堀   Country:Japan  

  177. Synthesis and Development of Titania and Titanium Complexes by Aqueous Solution-based Methods Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    IUMRS-ICAM 2017 

     More details

    Event date: 2017.8 - 2017.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Kyoto University   Country:Japan  

  178. 水溶媒を用いた酸化チタンナノ結晶成長とチタン錯体の開発 Invited

    小林亮, 加藤英樹, 垣花眞人

    第5回アライアンス若手研究交流会 

     More details

    Event date: 2017.8

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東京工業大学 すずかけ台キャンパス   Country:Japan  

  179. BaYSi2O5Nの発見とその蛍光体母体としての可能性 Invited

    小林亮, 安永拓矢, 佐藤大典, 加藤英樹, 垣花眞人, 藤井孝太郎, 八島正知

    第3回構造科学と新物質探索研究会「新構造型機能性無機材料の探索: -現状と展望-」 

     More details

    Event date: 2017.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:日本大学 駿河台キャンパス   Country:Japan  

  180. 水溶液錯体を用いた多形・形態が制御された酸化チタンの合成およびその展開 Invited

    小林亮, 加藤英樹, 垣花眞人

    日本セラミックス協会 関西支部 第19回 若手フォーラム 

     More details

    Event date: 2016.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:関西セミナーハウス修学院きらら山荘   Country:Japan  

  181. 酸化チタン多形ナノクリスタルの水熱合成 Invited

    小林亮, 加藤英樹, 垣花眞人

    日本セラミックス協会 第28回秋季シンポジウム 

     More details

    Event date: 2016.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:広島大学 東広島キャンパス   Country:Japan  

  182. 多形・形態を制御した酸化チタンの合成とその展開 Invited

    小林亮

    日本セラミックス協会2016年年会 

     More details

    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  183. 水溶媒からのチタン系ナノ・ハイブリッドマテリアルの創出 Invited

    小林亮, 加藤英樹, 垣花眞人

    ナノマテリアル科学の最前線(日本セラミックス協会2016年年会 サテライトプログラム) 

     More details

    Event date: 2016.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:早稲田大学 西早稲田キャンパス   Country:Japan  

  184. Synthesis of Ceramics with Controlled Nano- and Micro-structures by Aqueous Solution Methods Invited International conference

    Makoto Kobayashi, Minsung Kim, Hideki Kato, Masato Kakihana

    EMN Meeting on Ceramics 2016 

     More details

    Event date: 2016.1

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Kowloon, Hong Kong   Country:Hong Kong  

  185. 水溶性化合物の開発による構造が制御されたセラミックスの合成と高機能化 Invited

    小林亮

    第3回ケミカルフィールド研究討論会(日本セラミックス協会2015年年会 サテライトプログラム) 

     More details

    Event date: 2015.3

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:岡山大学 津島キャンパス   Country:Japan  

  186. Hydrothermal Synthesis of Titania and Magnetite Crystals with Unique Morphologies International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    The 2014 Collaborative Conference on Crystal Growth (3CG2014) 

     More details

    Event date: 2014.11

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Phuket, Thailand   Country:Thailand  

  187. 分子制御剤による酸化チタンおよび酸化鉄粒子の結晶成長制御および高度機能発現 Invited

    小林亮, 佐藤淳貴, 長田実, 加藤英樹, 垣花眞人

    第63回高分子討論会 

     More details

    Event date: 2014.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:長崎大学 文教キャンパス   Country:Japan  

  188. 形態が制御された酸化チタンおよび酸化鉄結晶の水熱合成 Invited

    小林亮, 佐藤淳貴, 長田実, 加藤英樹, 垣花眞人

    日本セラミックス協会 第27回秋季シンポジウム 

     More details

    Event date: 2014.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:鹿児島大学 郡元キャンパス   Country:Japan  

  189. 水溶性クラスターの設計と機能性セラミックス合成への応用 Invited

    小林亮, 加藤英樹, 垣花眞人

    第23回日本MRS年次大会 

     More details

    Event date: 2013.12

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:横浜市開港記念会館   Country:Japan  

  190. 水熱法を用いた結晶型と形態が制御された酸化チタン結晶の合成 Invited

    小林亮, 加藤英樹, 垣花眞人

    第43回結晶成長国内会議(NCCG-43) 

     More details

    Event date: 2013.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:長野市生涯学習センター   Country:Japan  

  191. Application of Water-soluble Titanium Complexes for Synthesis of Titanium Dioxide with Controlled Structures Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    12th International Conference on Ceramic Processing Science (ICCPS-12) 

     More details

    Event date: 2013.8

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Portland, Oregon, United States   Country:United States  

  192. Morphological Control of Titanium Dioxide Nanocrystals by Solvothermal Method Employing Water-soluble Titanium Complexes Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    The 2013 Collaborative Conference on Crystal Growth (3CG2013) 

     More details

    Event date: 2013.6

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Cancun, Mexico   Country:Mexico  

  193. Synthesis of Titanium Dioxide Crystals from Water-soluble Titanium Complexes Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    The 2012 Collaborative Conference on Crystal Growth (3CG2012) 

     More details

    Event date: 2012.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Orland, Florida, United States   Country:United States  

  194. Solvothermal Synthesis of Titanium Dioxide Polymorphs with Various Morphologies using Water-soluble Titanium Complexes Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    1st International Conference on Emerging Advanced Nanomaterials (ICEAN-2012) 

     More details

    Event date: 2012.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Brisbane, Australia   Country:Australia  

  195. Synthesis of Titanium dioxide with Controlled Crystalline Phases and Morphologies from Aqueous Solutions of Water-soluble Titanium Complexes Invited International conference

    Makoto Kobayashi, Hideki Kato, Masato Kakihana

    2012 International Symposium on Chemical-Environmental-Biomedical Technology (isCEBT2012) 

     More details

    Event date: 2012.9

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Tainan, Taiwan   Country:Taiwan, Province of China  

  196. セラミックス合成のいろいろ―セラミックス合成における「低環境負荷」- Invited

    小林亮

    新学術領域研究「融合マテリアル:分子制御による材料創成と機能開拓」 第4回 若手スクール 

     More details

    Event date: 2012.6

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:慶応大学 日吉キャンパス   Country:Japan  

  197. 様々な結晶構造および形態を有する酸化チタンの合成 Invited

    小林亮, 垣花眞人

    グローバルCOEプログラムシンポジウム2011 

     More details

    Event date: 2011.11

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東北大学 片平キャンパス   Country:Japan  

  198. Design and Synthesis of Inorganic Clusters for Controlled Formation of Fusion Materials Invited

    Masato Kakihana, Makoto Kobayashi

    The 1st International Symposium on Fusion Materials 

     More details

    Event date: 2011.10

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:JAPAN Toba  

  199. セラミックス材料合成における水溶性金属錯体のポテンシャル Invited

    小林亮, 垣花眞人

    新学術領域研究「融合マテリアル:分子制御による材料創成と機能開拓」 第1回 若手スクール 

     More details

    Event date: 2011.9 - 2011.10

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:鷲羽山下電ホテル   Country:Japan  

  200. 水溶性チタン錯体を原料とする形態を制御した酸化チタン多形の合成 Invited

    小林亮, 加藤英樹, 垣花眞人

    平成23年度 化学系学協会東北大会 

     More details

    Event date: 2011.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東北大学 川内キャンパス   Country:Japan  

  201. Morphology Control of Titanium Dioxide by Hydrothermal Treatment of Novel water Soluble Titanium Complexes Invited International conference

    Makoto Kobayashi, Masato Kakihana, Valery Petrykin, Koji Tomita

    G-COE Dalian University of Technology-Tohoku University Joint Symposium 

     More details

    Event date: 2009.12

    Language:English   Presentation type:Oral presentation (invited, special)  

    Venue:Sendai, Japan   Country:Japan  

  202. 酸化チタン多形の選択的合成及び形態制御 Invited

    小林亮, Petrykin Valery, 冨田恒之, 垣花眞人

    ークショップ「固体材料合成および評価技術の新展開」  2008.9.13 

     More details

    Event date: 2008.9

    Language:Japanese   Presentation type:Oral presentation (invited, special)  

    Venue:東北大学 片平キャンパス   Country:Japan  

▼display all

Research Project for Joint Research, Competitive Funding, etc. 7

  1. 鉛・希土類フリー高誘電・強誘電ナノ材料の開発を志向した酸窒化チタンナノシートの開発

    2022.6 - 2023.5

    公益財団法人 徳山科学技術振興財団 研究助成 

      More details

    Grant type:Competitive

    Grant amount:\2000000 ( Direct Cost: \2000000 )

  2. 次世代誘電体の開発を志向した酸窒化物ナノシートの創製

    2022.4 - 2023.3

    令和3年度永井科学技術財団 特定課題研究奨励金 

      More details

    Grant type:Competitive

    Grant amount:\500000 ( Direct Cost: \500000 )

  3. 電荷補償型元素置換による酸窒化物誘電体ナノシートの合成

    2019.6 - 2020.3

    公益財団法人 池谷科学技術振興財団 単年度研究助成 

      More details

    Grant type:Competitive

  4. 固体窒素源を用いたペロブスカイト型酸窒化物ナノシートの創製

    2019.6 - 2020.3

    東海産業技術振興財団 助成研究(研究育成型) 

    小林亮

      More details

    Grant type:Competitive

  5. シリコン含有酸窒化物の創製とその蛍光体応用

    2018.4 - 2022.3

    日本板硝子材料工学助成会 国内研究助成 

      More details

    Grant type:Competitive

  6. 氷晶に学ぶ成長形を有する酸化チタン結晶の創製

    2016.10 - 2017.9

    積水化学 自然に学ぶものづくり助成研究プログラム研究助成 

      More details

    Grant type:Competitive

  7. 新規透明導電膜の開発に向けた5価および6価金属ドープTiO2(B)結晶の合成

    2016.4 - 2017.3

    稲盛財団研究助成 

      More details

    Grant type:Competitive

▼display all

KAKENHI (Grants-in-Aid for Scientific Research) 8

  1. 酸化物原子膜のアニオンエンジニアリングと次世代誘電体の創製

    Grant number:22H01907  2022.4 - 2026.3

    日本学術振興会  科学研究費補助金   基盤研究(B)

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\17810000 ( Direct Cost: \13700000 、 Indirect Cost:\4110000 )

  2. 原子膜技術による革新的蓄電デバイスの創成

    Grant number:21H05015  2021.7 - 2026.3

    日本学術振興会  科学研究費補助金  基盤研究(S)

      More details

    Authorship:Coinvestigator(s)  Grant type:Competitive

  3. 原子膜技術による革新的蓄電デバイスの創成

    Grant number:21H04617  2021.4 - 2021.7

    日本学術振興会  科学研究費補助金  基盤研究(A)

      More details

    Authorship:Coinvestigator(s)  Grant type:Competitive

  4. Development of electric properties induced by distortion of controlled structures

    Grant number:19K05647  2019.4 - 2022.3

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\4420000 ( Direct Cost: \3400000 、 Indirect Cost:\1020000 )

  5. Development of new mixed-anion compounds: synthesis and establishment of design rules International coauthorship

    Grant number:16H06439  2016.6 - 2022.3

    Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

      More details

    Authorship:Coinvestigator(s)  Grant type:Competitive

  6. Synthesis of titania polymorph crystals with controlled structures employing water-soluble titanium complexes and molecular control agents International coauthorship

    Grant number:26870048  2014.4 - 2016.3

    Kobayashi Makoto

      More details

    Authorship:Principal investigator  Grant type:Competitive

    Grant amount:\3900000 ( Direct Cost: \3000000 、 Indirect Cost:\900000 )

    In this project, I have attempted hydrothermal synthesis of titania polymorphs with controlled morphologies and development of methodology for the morphological control. On the morphological control using molecular control agents, the effect of functional groups in compounds used as the molecular control agent on the anisotropic growth of rutile-type titania along c-axis was clarified. On the other hand, it was succeeded on synthesis of rutile crystals exposing facets with high energy such as high-index ones under mild conditions. In addition, synthesis of high-index faceted or nanosized brookite-type titania, which was difficult to obtained as the single phase, was attained. These achievements produced novel knowledge for morphological control of crystals.

  7. Design and Synthesis of Inorganic Clusters for Controlled Formation of Fusion Materials International coauthorship

    Grant number:22107002  2010.4 - 2015.3

    Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)

    KAKIHANA Masato

      More details

    Authorship:Collaborating Investigator(s) (not designated on Grant-in-Aid)  Grant type:Competitive

    In this project, we have attempted development of ubiquitous element-based water-soluble compounds and their applications for synthesis of fusion and inorganic materials. We have succeeded in development of water-soluble compounds including titanium, silicon, phosphorus and iron, and synthesis and high-functionalization of materials. Collaborative works beyond research fields were also carried out and a lot of achievements were produced. For example, it was revealed that magnetite crystals exposing high-index facets synthesized by an aqueous solution method exhibited high catalytic activity for polymerization of styrene and computer simulation was applied for elucidation of formation mechanism of titania crystals in the presence of molecular control agents.

  8. 水溶液化学に立脚した低エネルギープロセスによる機能性材料の合成

    2008.4 - 2011.3

    科学研究費補助金 

      More details

    Authorship:Principal investigator 

▼display all

Industrial property rights 3

  1. 薄膜の製造方法及び薄膜

    山本瑛祐, 長田実, 小林亮, 林浩平

     More details

    Applicant:名古屋大学

    Application no:特願2020-036782  Date applied:2020.3

  2. 低アンモニウム型チタンペルオキソ化合物の合成方法

    小林亮, 冨田恒之, 垣花眞人, 樋口隆行, 吉野亮悦

     More details

    Applicant:電気化学工業株式会社,東北大学

    Application no:2007-091347  Date applied:2007.3

    Announcement no:特開2008-247811  Date announced:2008.10

    Patent/Registration no:5008028 

  3. ブルッカイト型二酸化チタンの製造方法

    垣花眞人, 冨田恒之, 小林亮, 佐藤次雄, 殷シュウ

     More details

    Applicant:マツモトファインケミカル株式会社,東北大学

    Application no:特願2006-068425   Date applied:2006.3

    Announcement no:特開2007-246301  Date announced:2007.8

    Patent/Registration no:4587485 

 

Teaching Experience (On-campus) 64

  1. Advanced Experiments and Exercises in Solid State Chemistry II

    2023

  2. Advanced Experiments and Exercises in Solid State Chemistry I

    2023

  3. Advanced Porous Materials Chemistry

    2023

  4. Advanced Functional Materials Engineering

    2023

  5. Advanced Nano Carbon Material Science

    2023

  6. Seminar on Solid State Chemistry 1C

    2023

  7. Seminar on Solid State Chemistry 1A

    2023

  8. Fundamentals of Solide State Chemistry

    2023

  9. [remote]Technical Visits in Industrial Plants

    2023

  10. Inorganic Chemistry 2 with Exercises

    2023

  11. Seminar on Solid State Chemistry 2E

    2023

  12. Seminar on Solid State Chemistry 2C

    2023

  13. Seminar on Solid State Chemistry 2A

    2023

  14. Fundamental Chemistry II

    2022

  15. Advanced Functional Materials Engineering

    2022

  16. Advanced Nano Carbon Material Science

    2022

  17. Seminar on Solid State Chemistry 1C

    2022

  18. Seminar on Solid State Chemistry 1A

    2022

  19. Fundamentals of Solide State Chemistry

    2022

  20. Inorganic Chemistry 2 with Exercises

    2022

  21. Inorganic Chemistry A

    2022

  22. Advanced Porous Materials Chemistry

    2022

  23. Seminar on Solid State Chemistry 2E

    2022

  24. Seminar on Solid State Chemistry 2C

    2022

  25. Seminar on Solid State Chemistry 2A

    2022

  26. Advanced Experiments and Exercises in Solid State Chemistry II

    2022

  27. Advanced Experiments and Exercises in Solid State Chemistry I

    2022

  28. Inorganic Chemistry 1 with Exercises

    2022

  29. Elements of Inorganic Chemistry

    2022

  30. Seminar on Solid State Chemistry 2D

    2022

  31. Seminar on Solid State Chemistry 2B

    2022

  32. Seminar on Solid State Chemistry 1D

    2022

  33. Seminar on Solid State Chemistry 1B

    2022

  34. Seminar on Solid State Chemistry 1A

    2021

  35. Selected Topics on Chemistry and Biotechnology

    2021

  36. Elements of Chemistry and Biotechnology

    2021

  37. Selected Topics in Applied Chemistry

    2021

  38. Seminar on Solid State Chemistry 1C

    2021

  39. Inorganic Chemistry 2 with Exercises

    2021

  40. Seminar on Solid State Chemistry 2E

    2021

  41. Seminar on Solid State Chemistry 2C

    2021

  42. Seminar on Solid State Chemistry 2A

    2021

  43. Advanced Experiments and Exercises in Solid State Chemistry II

    2021

  44. Advanced Experiments and Exercises in Solid State Chemistry I

    2021

  45. Advanced Porous Materials Chemistry

    2021

  46. Selected Topics on Solid State Chemistry II

    2021

  47. Selected Topics on Solid State Chemistry I

    2021

  48. Selected Topics on Applied Physical Chemistry II

    2021

  49. Selected Topics on Applied Physical Chemistry I

    2021

  50. Fundamental Chemistry II

    2021

  51. Advanced Inorganic Chemistry

    2021

  52. Inorganic Chemistry 1 with Exercises

    2021

  53. Elements of Inorganic Chemistry

    2021

  54. Seminar on Solid State Chemistry 2D

    2021

  55. Seminar on Solid State Chemistry 2B

    2021

  56. Advanced Functional Materials Engineering

    2021

  57. Seminar on Solid State Chemistry 1D

    2021

  58. Seminar on Solid State Chemistry 1B

    2021

  59. Fundamentals of Chemistry II

    2020

  60. Elements of Inorganic Chemistry

    2020

  61. Chemistry and Biotechnology Laboratory 4

    2020

  62. Inorganic Chemistry 2 with Exercises

    2020

  63. Inorganic Chemistry 1 with Exercises

    2020

  64. Inorganic Chemistry A

    2020

▼display all

 

Media Coverage 2

  1. 名大、厚さ0.9nmのアモルファスシリカナノシートの合成に成功 Newspaper, magazine

    日本経済新聞  2023.3

     More details

    Author:Other 

  2. 名大、チタン酸バリウムで「強誘電体ナノシート」合成 次世代電子デバイスに道 Newspaper, magazine

    日刊工業新聞  2023.2

     More details

    Author:Other