記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Chemical Communications  

A metal-organic framework (MOF) comprised of cobalt ions and triptycene-based 3-fold symmetric bridging ligands 9,10-[1,2]benzenoanthracene-2,3,6,7,14,15(9H,10H)-hexaone (o-TT) was prepared. Single-crystal structure analysis revealed a 2D honeycomb network structure and the ideal trigonal prismatic geometry of the Co(ii) ion. The magnetic anisotropy of the Co(ii) ion in the trigonal prism coordination geometry was analyzed via magnetic measurements and model calculations.

DOI： 10.1039/d3cc02986g

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掲載種別：研究論文（学術雑誌）   出版者・発行元：Physical Review B  

We investigated polyhedral π-conjugated molecules with threefold rotation symmetry, which can be suitable building blocks for both Dirac cones and a topological flat-band system. The two dimensional network structures of such molecules can be characterized by intra- and intermolecular interactions. We constructed tight binding models of these structures by systematically changing the intra- (t0) and intermolecular (t1) transfer integrals as independent parameters. The degree of freedom for the interactions provides a topological flat band and a massless or massive Dirac cone. We analyzed the topological features and origins of the flat band and Dirac cone of a molecule-based triangular lattice.

DOI： 10.1103/PhysRevB.107.155123

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その他リンク： http://harvest.aps.org/v2/journals/articles/10.1103/PhysRevB.107.155123/fulltext

記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ACS Materials Au  

We report the circularly polarized luminescence (CPL) for [Ru(bpy)3]I2 (1) and [Ru(bpy)3][M2(ox)3] (M = Zn (2), Mn (3)). Whereas compound 1 is a simple salt of [Ru(bpy)3]2+, 2 and 3 are MOFs in which the chiral [Ru(bpy)3]2+ ions are encapsulated in a homochiral gyroidal skeleton of [M2(ox)3]2-. Whereas the solution of 1 exhibited weak CPL with a luminescence dissymmetry factor of |glum| ∼ 10-4, the CPL was significantly enhanced in solid-state 1-3 with |glum| = 2 × 10-2 for 1, 4 × 10-2 for 2, and 1 × 10-1 for 3. The enhanced CPL in 3 was attributable to an energy transfer between the homochiral guest and host in 3.

DOI： 10.1021/acsmaterialsau.2c00081

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掲載種別：研究論文（学術雑誌）   出版者・発行元：Applied Physics Express  

In this study, we fabricate MXene transparent conductive films via a transfer process. The results show that the transferred transparent conductive films using titanium carbide MXene have ca. 100 times higher electrical conductivity than conventional spray-coated samples. Transparency and electrical conductivity are easily controlled by changing the amount of MXene materials. The scanning electron microscopy observations reveal that the transferred films have a smooth and uniform MXene flake network. The closer interlayer distance of the MXene flakes when compared to the spray-coated sample, which enables superior electrical conductivity, is confirmed by the X-ray diffraction measurement.

DOI： 10.35848/1882-0786/acbbb8

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Chemistry Letters  

We report carbon nanotube (CNT) gels, formed by mechanically mixing CNTs, organic solvents, and a small molecule, Trip-Phz, that have a strong affinity for fullerene materials. There is a clear threshold value in the amount of Trip-Phz needed for the transition from soft to hard gels.

DOI： 10.1246/cl.220319

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Chemical Science  

The design and synthesis of nitrogen (N)-doped molecular nanocarbons are of importance since N-doped nanocarbons have received significant attention in materials science. Herein, we report the synthesis and X-ray crystal structure of a nitrogen-inserted nonalternant aromatic belt. The palladium-catalyzed six-fold annulative double N-arylation provided an aromatic belt bearing six nitrogen atoms in one step from cyclo[6]paraphenylene-Z-ethenylene, the precursor of the (6,6)carbon nanobelt. The C3i-symmetric structure of the aromatic belt in the solid state was revealed using X-ray crystallography. The multistep (electro)chemical oxidation behavior of the belt, which was facilitated by the six p-methoxyaniline moieties, was studied, and a stable dication species was successfully identified by X-ray crystallography. The present study not only shows the unique structure and properties of the N-doped nonalternant aromatic belt but also expands the scope of accessibility of synthetically difficult belt molecules by the conventional intramolecular contraction pathway.

DOI： 10.1039/d2sc02647c

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ACS Applied Materials and Interfaces  

Redox-active organic molecules are promising candidates for next-generation electrode materials. Nevertheless, finding low-molecular-weight organic materials with a long cycle life remains a crucial challenge. Herein, we demonstrate the application of tetrathiafulvalene and its vinyl analogue bearing triphenylamines as long-cycle-life electrodes for lithium-ion batteries (LIBs). These molecules were successfully synthesized using palladium-catalyzed C-H arylation. Electrochemical analysis revealed that a polymer formed on the electrode. LIBs comprising these molecules exhibited noteworthy charge-discharge properties with a long cycle life (the capacity after 100 cycles was greater than 90% of the discharge capacity in the third cycle) and a high utilization ratio (approximately 100%). "In-cell"polymerization during the first charge process is considered to contribute to the effect. This study indicates new avenues for the creation of organic materials for rechargeable batteries.

DOI： 10.1021/acsami.2c09302

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Frontiers in Chemistry  

This study describes the concise exfoliation of multilayer Ti3C2Tx MXene containing residual aluminum atoms. Treatment with tetramethylammonium base in a co-solvent of tetrahydrofuran and H2O produced single-layer Ti3C2Tx, which was confirmed via atomic force microscopy observations, with an electrical conductivity 100+ times that of Ti3C2Tx prepared under previously reported conditions. The scanning electron microscopy and X-ray diffraction measurements showed that the exfoliated single-layer Ti3C2Tx MXenes were reconstructed to assembled large-domain layered films, enabling excellent macroscale electric conductivity. X-ray photoelectron spectroscopy confirmed the complete removal of residual Al atoms and the replacement of surface fluorine atoms with hydroxy groups. Using the exfoliated dispersion, a flexible transparent conductive film was formed and demonstrated in an electrical application.

DOI： 10.3389/fchem.2022.841313

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担当区分：筆頭著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Journal of Materials Chemistry C  

Graph theory has demonstrated that only three lattices, namely, honeycomb, K4, and diamond lattices, possess a strong isotropic property. It is also recognized that their line graphs correspond to kagome, hyper-kagome, and pyrochlore lattices, respectively, which are well known as spin frustration lattices. This relation suggests that the materials with the strong isotropic lattices possess "hidden"frustration. In this review article, after introducing the strong isotropy and the line graph transformation, we describe the spin frustration and formation of the spin liquid state in a honeycomb MOF, Cu3(HHTP), and in a molecule-based K4, (-)-NDI-Δ. We also report the unusual phase transitions in a molecule-based diamond, bpBDTDA, which are considered to result from bond frustration: specific periodical lattice distortions in the strong isotropic lattices are forbidden, in such a way that long-range antiferromagnetic orderings are forbidden in the spin frustration lattices.

DOI： 10.1039/d1tc05161j

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記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CrystEngComm  

Supramolecular chiral crystals of radical anion salts of a rigid triangular chiral electron acceptor, (−)-naphthalene diimide (NDI)-Δ, were electrochemically grown in propylene carbonate (PC) solutions of electrolytes (M·ClO4, M = K, Rb, Cs) in the presence of cyclic multidentate ligands, such as 18-crown-6, 15-crown-5, and 2,2,2-cryptand. The crystal structures were found to be formed by three-way branched π-π interactions between (−)-NDI-Δ radical anions, including [Rb(or K)(18-crown-6)]+complexes. The theoretical calculations on this structure revealed a possible magnetic phase diagram, which was governed by the ratio between two types of antiferromagnetic interactions.

DOI： 10.1039/d1ce00628b

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：ACS Applied Materials and Interfaces  

Molecule-based ferroelectrics has attracted much attention because of its advantages, such as flexibility, light weight, and low environmental load. In the present work, we examined an organic metal|insulator|semiconductor|insulator|metal (MISIM) device structure to stabilize the interfacial polarization in the S layer and to induce polarization hysteresis even without bulk ferroelectrics. The MISIM devices with I = parylene C and S = TMB (=3,3′,5,5′-tetramethylbenzidine)-TCNQ (=tetracyanoquinodimethane) exhibited hysteresis loops in the polarization-voltage (P-V) curves not only at room temperature but also over a wide temperature range down to 80 K. The presence of polarization hysteresis for MISIM devices was theoretically confirmed by an electrostatic model, which also explained the observed thickness dependence of the I layers on the P-V curves. Polarization hysteresis curves were also obtained in MISIM devices using typical organic semiconductors (ZnPc, C60, and TCNQ) as the S layer, demonstrating the versatility of the interfacial polarization mechanism.

DOI： 10.1021/acsami.1c08417

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Applied Surface Science  

Oxidative vaporization in air using a flame with a temperature range of 1950–2300 K was employed for controlling the tip shape made from a nipper-cut metal molybdenum (Mo) wire edge. An extremely high vapor pressure of MoO3 generated on the Mo surface in flame is a driving force behind the tip shape formation. Since the MoO3 vaporization rate follows the flame temperature gradient, we could control the tip apex shape by selecting the proper flame etching condition. The best condition to obtain a sharp tip apex based on statistical tests of dozens of Mo tips was obtained by Mo wire edge insertion into the 2100 K flame from the side for one second. This was repeated twice, which reproducibly provided a tip apex with a radius of 50–100 nm and a cone angle of 20–30 degrees. The present Mo tips, fabricated without aqueous solutions, were examined for their suitability as probe tips through air-scanning tunneling microscopy (STM), ultrahigh vacuum STM, field emission spectroscopy, and conductance measurements.

DOI： 10.1016/j.apsusc.2020.148642

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Crystal Growth and Design  

We synthesized a phenazine analogue of triptycene acceptor, Trip-Phz, and found a honeycomb network of Trip-Phz with a wide 1D channel running through it. The interior surface of this channel was covered by the πelectrons of Trip-Phz. Even though there was no interaction between Trip-Phz and an organic donor, tetrathiafulvalene (TTF), in their solutions, the honeycomb crystals of Trip-Phz exhibited a host-guest charge-transfer (CT) interaction with TTF, specifically a reversible adsorption/desorption of TTF with the appearance/disappearance of a CT band.

DOI： 10.1021/acs.cgd.0c01176

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記述言語：日本語   掲載種別：研究論文（学術雑誌）  

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担当区分：筆頭著者   記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：分子科学会  

<p>In the graph theory, it is known that the line graphs of the <i>K</i>₄ and diamond lattices are the hyper-kagome and pyrochlore lattices, respectively. The hyper-kagome and pyrochlore lattices are possible frustration lattices, because they consist of a triangular or tetrahedral component. In the present article, we describe the crystal structures and physical properties of a molecule-based <i>K</i>₄, (–)-NDI-Δ, and a molecule-based diamond, bpBDTDA. The line graph transformation reveals a spin frustration in (–)-NDI-Δ, which results in a spin liquid ground state, and a bond frustrations in bpBDTDA, which induces a stepwise and inhomogeneous lattice dimerization.</p>

DOI： 10.3175/molsci.14.a0113

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Scientific Reports  

Scanning tunneling microscopy (STM) observation reveals that a cyclic thiazyl diradical, BDTDA (= 4,4′-bis(1,2,3,5-dithiadiazolyl)), forms a well-ordered monolayer honeycomb lattice consisting of paramagnetic corners with unpaired electrons on a clean Cu(111) surface. This BDTDA lattice is commensurate with the triangular lattice of Cu(111), with the former being 3 x 3 larger than the latter. The formation of the BDTDA monolayer structure, which is significantly different from its bulk form, is attributed to an interaction with the metal surface as well as the intermolecular assembling forces. STM spectroscopy measurements on the BDTDA molecules indicate the presence of a characteristic zero-bias anomaly centered at the Fermi energy. The origin of this zero-bias anomaly is discussed in terms of the Dirac cones inherent to the honeycomb structure.

DOI： 10.1038/srep18359

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Journal of the American Chemical Society  

The K4 structure was theoretically predicted for trivalent chemical species, such as sp2 carbon. However, since attempts to synthesize the K4 carbon have not succeeded, this allotrope has been regarded as a crystal form that might not exist in nature. In the present work, we carried out electrochemical crystallization of the radical anion salts of a triangular molecule, naphthalene diimide (NDI)-Δ, using various electrolytes. X-ray crystal analysis of the obtained crystals revealed the K4 structure, which was formed by the unique intermolecular π overlap directed toward three directions from the triangular-shape NDI-Δ radical anions. Electron paramagnetic resonance and static magnetic measurements confirmed the radical anion state of NDI-Δ and indicated an antiferromagnetic intermolecular interaction with the Weiss constant of θ = -10 K. The band structure calculation suggested characteristic features of the present material, such as a metallic ground state, Dirac cones, and flat bands.

DOI： 10.1021/jacs.5b04180

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担当区分：筆頭著者   記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Journal of Materials Chemistry C  

A heterocyclic thiazyl diradical, bis(1,2,3,5-dithiadiazolyl)-4,4′-biphenylene (1), was synthesized, and its structural and thermodynamic properties were characterized. This compound exhibits unique spatially inhomogeneous, first-order phase transitions at 306 and 359 K, in a stepwise fashion. The unit cell in the high-temperature phase above 359 K consists of four regular π-stacking columns with the same stacking manners having a uniform interplanar distance d. These four columns are connected by intermolecular S⋯S and S⋯N contacts between the thiazyl radical moieties, but the molecular planes are shifted by a distance of d/4 due to a steric hindrance between the bulky biphenylene moieties. Below 359 K, three of the four stacking columns exhibit structural transitions toward zigzag chain structures, formed by an alternating dimerization between the radical moieties, while one column maintains the uniform π stacking. In the low-temperature phase below 306 K, the last column finally exhibits the radical dimerization toward a zigzag chain structure. These unique phase transitions in 1 can be understood in terms of the stepwise transitions from a "dimer liquid" to a "dimer solid" through a "dimer soliton phase".

DOI： 10.1039/c5tc01410g

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Nature Communications  

The neutral radical 1,3,5-trithia-2,4,6-triazapentalenyl (TTTA) is a prototype of molecule-based bistable materials. TTTA crystals undergo a first-order phase transition between their low-temperature diamagnetic and high-temperature paramagnetic phases, with a large hysteresis loop that encompasses room temperature. Here, based on ab initio molecular dynamics simulations and new X-ray measurements, we uncover that the regular stacking motif of the high-temperature polymorph is the result of a fast intra-stack pair-exchange dynamics, whereby TTTA radicals continually exchange the adjacent TTTA neighbour (upper or lower) with which they form an eclipsed dimer. Such unique dynamics, observed in the paramagnetic phase within the whole hysteresis loop, is the origin of a significant vibrational entropic gain in the low-temperature to high-temperature transition and thereby it plays a key role in driving the phase transition. This finding provides a new key concept that needs to be explored for the rational design of novel molecule-based bistable magnetic materials. © 2014 Macmillan Publishers Limited.

DOI： 10.1038/ncomms5411

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記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Journal of Physical Chemistry C  

Thin films of a thiazyl biradical, naphtho[2,1-d:6,5-d′]bis([1,2,3] dithiazole), abbreviated as NT, exhibit nonlinear optical properties with a large third-order nonlinear susceptibility of 2.1 × 10-11 esu. The electroabsorption and low-temperature-absorption measurements reveal a series of degenerate electronic states, which is probably caused by the biradical character of NT. It is concluded that this degeneracy should enhance the third-order nonlinear optical properties. © 2014 American Chemical Society.

DOI： 10.1021/jp4093332

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Bulletin of the Chemical Society of Japan  

Heterocyclic thiazyl radicals possess unique chemical and physical properties as building blocks for molecule-based conductors and magnetic materials. They do not need protecting groups on their molecular skeletons, and the lack of such substituents permits close packing in the solid state. Moreover, thiazyl radical solids often involve a multidimensional network consisting of π-π overlaps and S⋯N contacts. The electronic structures of the thiazyl radicals can be compared to highly-correlated electron systems. In this account, we describe various electron-transfer processes in the solids of the thiazyl radicals, which manifest themselves by external stimuli such as temperature change, electric field, and photoillumination. © 2013 The Chemical Society of Japan.

DOI： 10.1246/bcsj.20130248

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Inorganic Chemistry  

The crystal structures and magnetic properties of seven kinds of [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline 1,1-dioxide (tdapO2) radical-anion salts, namely, K·tdapO2, K·tdapO 2·0.5MeCN, K·(tdapO2)2, Rb·(tdapO2)2, Cs7·(tdapO 2)6·ClO4, (NH4) 2·tdapO2·I, and Hppda·tdapO 2·MeCN, were investigated. Single-crystal X-ray analyses of these radical-anion salts revealed formation of π-stacking columns and the presence of intercolumnar coordination bonding or hydrogen bonding. The intermolecular magnetic coupling constants in these salts range from strong antiferromagnetic (J/kB = -310 K) to ferromagnetic (J/kB = 24 K). Ab initio calculations performed on the nearest-neighbor radical pairs in the π-stacking columns suggested that the magnetic interactions are strongly governed by the overlap between the two anionic radical species and well explain the observed ferromagnetic and antiferromagnetic interactions. In addition, calculations of a hypothetical oxygen-less tdap analogue suggested that the presence of oxygen in tdapO2 significantly reduces the hopping integral and enhances the probability of ferromagnetic interaction. © 2013 American Chemical Society.

DOI： 10.1021/ic401078z

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記述言語：日本語   出版者・発行元：Journal of the Vacuum Society of Japan  

Most research in the fleld of organic electronics has focused on p-conjugated molecules with a closed-shell configuration, which accommodate their p-electrons in only bonding orbitals and are consequently quite stable. In general, closed-shell molecules have wide energy gaps, and they have significantly weaker intermolecular interactions. In contrast, recently organic biradicals have attracted considerable attention, owing to their interesting physical properties, e.g., a small energy gap and strong intermolecular interactions. Organic biradical molecules are composed of a pair of organic radicals that possess an open-shell configuration. Owing to their radical nature, biradical molecules exhibit unusual physical properties such as those listed above. This article is a review of our recent study on the electronic structure of two different types of organic biradical molecules that have potential as new materials for manufacturing electronic devices. In particular, our results show that organic biradicals are expected to form a new class of materials for use in organic electronics as new building blocks for highly ordered organic semiconducting films with wide energy band dispersion widths and a narrow energy gap.

DOI： 10.3131/jvsj2.56.32

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記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Inorganic Chemistry  

A novel phenanthlorine derivative, [1,2,5]thiadiazolo[3,4-f][1,10] phenanthroline 1,1-dioxide (tdapO2), was prepared to act as a radical-anion building block for coordination polymers. The crystal structures and magnetic properties of the monovalent and mixed-valent radical-anion salts K•tdapO2 and K•(tdapO2)2 were elucidated and confirm the possibility of tdapO2 to act as a bridging ligand and its capability to exhibit magnetic ordering at 15 K. © 2011 American Chemical Society.

DOI： 10.1021/ic201966t

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Physical Review B - Condensed Matter and Materials Physics  

As a significant drawback to organic electronics, poor mobility in organic materials makes it difficult for carriers to make long trips across thin film devices. In the present work, we show that a short carrier trip or even charge displacement can contribute to the functioning of optoelectronics without being influenced by the poor carrier mobility. Our findings are based on analysis of the current-voltage and capacitance-voltage characteristics, as well as the anomalous transient photocurrent of the photocells of a radical material, 4′4-bis(1,2,3,5-dithiadiazolyl). This photoinduced transient current was successfully analyzed based on the total current equation and was interpreted in terms of the polarization current induced by charge displacement in the films. This mechanism provides preliminary information with respect to the development of methods for high-speed organic optoelectronic conversion. © 2011 American Physical Society.

DOI： 10.1103/PhysRevB.84.205329

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Chemical Physics Letters  

Thin films of interacting dimers of 4,4′-bis(1,2,3,5-dithiadiazolyl), sandwiched by ITO and Al, exhibit an anomalous transient current, due to a significant imbalance between the hole and electron mobilities and bulk polarization. We propose a new operational principle for organic optoelectronic conversion systems, which efficiently generates alternating photocurrent without being affected by the disadvantages of organic materials, such as poor mobility. © 2009 Elsevier B.V. All rights reserved.

DOI： 10.1016/j.cplett.2009.11.013

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Angewandte Chemie - International Edition  

Fully interactive: Overlap between extended unoccupied molecular orbitals leads to the high photoconductivity of interactive radical dimers. Sandwich-type cells (see picture; ITO=indium tin oxide) comprising highly oriented thin films of a disjoint diradical, 4,4′-bis(1,2,3,5-dithiadiazolyl) (BDTDA) exhibit a photocurrent with a high on/off ratio at reverse bias voltages and photovoltaic behavior at zero bias voltage. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

DOI： 10.1002/anie.200900472

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記述言語：日本語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CrystEngComm  

We prepared an iron(II) spin crossover complex with a new ligand, [1,2,5]thiadiazolo[3,4-f][1,10]phenanthroline, which is a 1,10-phenanthroline analogue annulated with a thiadiazole moiety. X-Ray crystal analysis indicated a 3D network structure formed by short S⋯S contacts, and magnetic measurements revealed a broad transition above room temperature. © 2009 The Royal Society of Chemistry.

DOI： 10.1039/b906845g

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Physical Chemistry Chemical Physics  

The electronic structure of the thiazyl diradical, 4,4′-bis(1,2,3,5- dithiadiazolyl) (BDTDA), has been investigated by ultraviolet photoemission spectroscopy. Stacked BDTDA dimers showed an energy band dispersion of about 0.3 eV for the highest occupied molecular orbital in the direction of the surface normal of the BDTDA solid film. The π-orbital overlap between the stacked dimers therefore evolves into a quasi one-dimensional energy band along the dimer stacking direction. © 2009 the Owner Societies.

DOI： 10.1039/b916396d

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：Chemistry - A European Journal  

Single crystals and thin films of the sunflower 2 was prepared by X-ray single-crystal analysis. Single crystals of the parent compound 1 were grown by slow evaporation of the Et2O solution at room temperature. Single crystals of 2 were obtained as red needles by vacuum sublimation, and X-ray crystal analysis was carried out at 173 K. The space group was found to be the monoclinic P21/n, while it was assigned to the non-centrosymmetric P21 in the Rietveld analysis. The symmetry, obtained in the present re-determination of the crystal structure of 2, reduced the size of the asymmetric unit to one-half molecule. The out-of-plane measurements indicate several diffraction peaks. Thin-film XRD indicated a lamellar structure in which the molecular planes are nearly perpendicular to the substrates.

DOI： 10.1002/chem.200800519

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1016/j.jorganchem.2007.06.027

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1246/cl.2003.1024

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1039/b310822h

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1016/S0022-328X(02)01188-9

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1016/S0022-328X(01)01373-0

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記述言語：英語   掲載種別：研究論文（学術雑誌）  

DOI： 10.1021/om9802111

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記述言語：英語   掲載種別：研究論文（学術雑誌）   出版者・発行元：CHEMICAL SOC JAPAN  

Treatment of CpFe(CO)(2)SiR3 (R-3 = (pTol)(2)H, ((p)Tol)(2)Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH4 in ether or THF at room temperature gave CH3SiR3 as a major product in moderate to high yield. The labeling experiments using LiAlD4 and CpFe((CO)-C-13)(2)SiR(pTol)(2) (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH4 and coupled with the silyl group to give the methylsilane.

DOI： 10.1246/cl.1997.805

Web of Science

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記述言語：日本語  

Web of Science

記述言語：日本語  

J-GLOBAL

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記述言語：日本語   掲載種別：記事・総説・解説・論説等（学術雑誌）  

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記述言語：日本語   出版者・発行元：一般社団法人 日本物理学会  

CiNii Books

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記述言語：日本語   出版者・発行元：一般社団法人日本物理学会  

CiNii Books

J-GLOBAL

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記述言語：日本語   出版者・発行元：一般社団法人日本物理学会  

CiNii Books

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